CN110305687A - A kind of damaged tire low consumption higher value application device and method - Google Patents
A kind of damaged tire low consumption higher value application device and method Download PDFInfo
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- CN110305687A CN110305687A CN201910544909.6A CN201910544909A CN110305687A CN 110305687 A CN110305687 A CN 110305687A CN 201910544909 A CN201910544909 A CN 201910544909A CN 110305687 A CN110305687 A CN 110305687A
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- high temperature
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- pyrolytic carbon
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
Abstract
The invention belongs to technical field of energy utilization, are related to a kind of damaged tire low consumption higher value application device and method.Broken no steel wire damaged tire particle feeding is directly heated and carries out fast pyrogenation in pyrolysis installation, pyrolysis devolatilization product and pyrolytic carbon are generated during fast pyrogenation, pyrolytic carbon is sent into high temperature modified device, pyrolysis devolatilization product is sent into condensing recovery integrated apparatus, tar is recycled while by the condensation of pyrolysis devolatilization product, residue can not condense pyrolysis gas and be sent into combustion gas storage facility by pressurizing device;The combustible gas stored in combustion gas storage facility is heated via heat-exchanger rig is sent into high temperature imperfect combustion device progress imperfect combustion, it is pyrolytic carbon heat modification that unburnt gas product, which is sent into high temperature modified device, the high temperature modified pyrolytic carbon in part is back in a manner of thermoset carrier again directly heats pyrolysis installation, energy is provided without the fast pyrogenation of steel wire damaged tire particle for lower batch, extra high temperature modified pyrolytic carbon is sent into Modified Activated Carbon recyclable device and is collected.
Description
Technical field
The invention belongs to technical field of energy utilization, and in particular to a kind of damaged tire low consumption higher value application device and side
Method.
Background technique
With the continuous progress of science and technology and the continuous improvement of living standards of the people, automobile are gradually widely used, every at present
The damaged tire amount year generated is more than 15,000,000 tons, but its recovery utilization rate is less than 35%, therefore, the recycling treatment of damaged tire
Have become urgent problem to be solved.The main processing ways of damaged tire have renovation, rubber powder, reclaimed rubber, burning and pyrolysis etc..Mesh
Preceding internationally recognized pyrolysis oil preparation is the most potential processing mode of damaged tire recycling.
Heat carrier is widely used during fast pyrogenation, and heat carrier can be gas, liquid, the solid of high temperature, as in
State's patent of invention: it a kind of damaged tire oil recovery system and receives oily method (105441097 B of CN) and discloses one kind with high-temperature retorting gas
For the damaged tire recycling treatment mode of heat carrier, but gas-solid heat exchange coefficient is smaller, is likely to result in oil productivity using which
The low, problems such as device heat utilization is low.For gas, solid has heat transfer coefficient height, volume thermic load as heat carrier
The advantages that high, traditional thermoset carrier often uses the inert substances such as quartz sand, but applies it to during waste tyre pyrolytic, meeting
There is thermoset carriers the problems such as to separate with product carbon black difficulty.
Summary of the invention
The present invention is to overcome the shortcomings of existing production technology, and the present invention provides a kind of damaged tire low consumption higher value application dress
It sets and method, is pyrolytic carbon heat modification by unburnt fuel gas, and using high temperature modified pyrolytic carbon as thermosetting load
Body provides energy for no steel wire damaged tire particle, and then realizes the high-valued recycling of pyrolysis product, it is facilitated industrially to apply.
This is applied for a patent with China simultaneously: being made in a kind of waste tire catalytic pyrolysis method 201811580446.0 using pyrolytic carbon reuse
There is essential difference again for catalyst.
Technical solution of the present invention:
A kind of damaged tire low consumption higher value application device, including directly heat pyrolysis installation 1, condensing recovery and integrally disguise
Set 2, desulfurizer 3, pressurizing device A4, combustion gas storage facility 5, heat-exchanger rig 6, high temperature imperfect combustion device 7, high temperature modified
Device 8, Modified Activated Carbon recyclable device 9 and pressurizing device B10;
The pyrolysis installation 1 that directly heats is equipped with pyrolysis devolatilization product exit 11, pyrolytic carbon outlet 12, without the useless wheel of steel wire
Tire article inlet 13 and high temperature modified pyrolytic carbon import 14, are internally provided with removable baffle plate 15, are controlled by removable baffle plate 15
The residence time of pyrolytic carbon processed directly heats the pyrolysis devolatilization product exit 11 and condensing recovery integrated apparatus 2 of pyrolysis installation 1
Pyrolysis devolatilization product inlet 16 be connected, pyrolytic carbon outlet 12 is connected with the pyrolytic carbon import 31 of high temperature modified device 8;
The condensing recovery integrated apparatus 2 is equipped with pyrolysis devolatilization product inlet 16 and non-condensable gas outlet 17,
The pyrolysis devolatilization product for being sent into condensing recovery integrated apparatus 2 carries out indirect condensing, and the tar being precipitated in condensation process is in device
Bottom storage, the non-condensable gas outlet 17 and the non-condensable gas import of desulfurizer 3 of condensing recovery integrated apparatus 2
18 are connected;
The desulfurizer 3 is equipped with non-condensable gas import 18 and pure combustible gas outlet 19, in desulfurizer 3
Pure combustible gas is sent into pressurizing device A4 pressurization, the outlet pressurizing device A4 and combustion gas storage facility 5 by pure combustible gas outlet 19
Pure combustible gas import 20 be connected;
The combustion gas storage facility 5 is equipped with pure combustible gas import 20, gas outlet 21 and modified combustible gas import 22,
The gas outlet 21 of combustion gas storage facility 5 is connected with the fuel gas inlet 23 of heat-exchanger rig 6, and modified combustible gas import 22 is filled with pressurization
The outlet B10 is set to be connected;
The heat-exchanger rig 6 is equipped with fuel gas inlet 23, modified combustible gas exports 24, high temperature modified 25 and of combustible gas import
High-temperature fuel gas outlet 26, the modification combustible gas of heat-exchanger rig 6 outlet 24 are connected with the entrance of pressurizing device B10, it is high temperature modified can
Fuel gas inlet 25 is connected with the high temperature modified combustible gas of high temperature modified device 8 outlet 33, and high-temperature fuel gas outlet 26 is endless with high temperature
The high-temperature fuel gas import 27 of full burner 7 is connected;
The high temperature imperfect combustion device 7 is equipped with high-temperature fuel gas import 27, combustion-supporting medium import 28 and not exclusively combustion
Burn product gas outlet 29, the unburnt gas product exit 29 of high temperature imperfect combustion device 7 and high temperature modified device 8
Unburnt gas product inlet 30 be connected;
The high temperature modified device 8 is equipped with unburnt gas product inlet 30, pyrolytic carbon import 31, high temperature modified
Pyrolytic carbon outlet 32 and high temperature modified combustible gas outlet 33, the high temperature modified pyrolytic carbon of high temperature modified device 8 outlet 32 respectively with
Modified Activated Carbon recyclable device 9 and the high temperature modified pyrolytic carbon import 14 for directly heating pyrolysis installation 1 are connected.
Unburnt fuel gas is that pyrolytic carbon heating changes by a kind of damaged tire low consumption higher value application method
Property, and energy is provided for no steel wire damaged tire particle fast pyrogenation using high temperature modified pyrolytic carbon as thermoset carrier, and then realize
The high-valued recycling of pyrolysis product, steps are as follows:
I fast pyrogenation process: damaged tire, which is sent into after broken, pumping steel wire by no steel wire damaged tire article inlet 13, directly to be added
In hot pyrolysis installation 1, meanwhile, the high temperature modified pyrolytic carbon in high temperature modified device 8 is by the outlet 32 of high temperature modified pyrolytic carbon through height
The modified feeding of pyrolytic carbon import 14 of temperature directly heats in pyrolysis installation 1, and high temperature modified pyrolytic carbon is no steel wire damaged tire particle
Fast pyrogenation provides energy, generates pyrolysis devolatilization product and pyrolytic carbon during fast pyrogenation, pyrolytic carbon is successively via pyrolytic carbon
High temperature modified device 8 is sent into outlet 12 and pyrolytic carbon import 31, and pyrolysis devolatilization product is successively via pyrolysis devolatilization product exit 11
It is sent into condensing recovery integrated apparatus 2 with pyrolysis devolatilization product inlet 16 to be condensed, the tar being precipitated in condensation process is temporary
In 2 bottom of condensing recovery integrated apparatus, residue is not condensable successively to export 17 and not condensible gas via non-condensable gas
Desulfurizer 3 is sent into body import 18, and the pure combustible gas after desulfurization is sent into pressurizing device A4 pressurization by pure combustible gas outlet 19,
And combustion gas storage facility 5 is sent by pure combustible gas import 20;
II modified energy supply process: the combustible gas in combustion gas storage facility 5 is successively sent by gas outlet 21 and fuel gas inlet 23
Enter heat-exchanger rig 6, meanwhile, the high temperature modified combustible gas in high temperature modified device 8 successively exports 33 Hes by high temperature modified combustible gas
Heat-exchanger rig 6 is sent into high temperature modified combustible gas import 25, and combustible gas and high temperature modified combustible gas carry out indirect heat exchange, after heat exchange
High temperature modified combustible gas temperature is lower, and is sent into pressurizing device B10 pressurization by modified combustible gas outlet 24, then by modified combustible gas into
Mouthfuls 22 are sent into combustion gas storage facilities 5, and the combustible gas temperature after heat exchange increases, successively by high-temperature fuel gas outlet 26 and high-temperature fuel gas into
Mouth 27 is sent into high temperature imperfect combustion devices 7, is mixed with the combustion adjuvant from combustion-supporting medium import 28, is not exclusively fired
It burns, unburnt gas product mainly has CO, CO2、H2O、H2、CH4, by unburnt gas product successively by incomplete
Combustion gas product outlet 29 and unburnt gas product inlet 30 are sent into high temperature modified device 8, and with high temperature modified dress
The pyrolytic carbon mixing in 8 is set, on the one hand unburnt gas product will be pyrolyzed the coke tar reforming of carbon surface attachment, on the other hand
By pyrolytic carbon heat-activated, modified pyrolytic carbon specific surface area, pore volume relatively before pyrolytic carbon be substantially improved, while gas
Body product calorific value improve, the high temperature modified pyrolytic carbon in part successively through high temperature modified pyrolytic carbon outlet 32 and high temperature modified pyrolytic carbon into
Mouth 14 is sent into and directly heats pyrolysis installation 1, provides energy, remaining high temperature without steel wire damaged tire particle fast pyrogenation for lower batch
Modified pyrolytic carbon is sent into Modified Activated Carbon recyclable device 9 and is stored, and high temperature modified combustible gas is successively exported by high temperature modified combustible gas
33 and high temperature modified combustible gas import 25 be sent into heat-exchanger rig 6, the indirect heating for lower batch combustible gas provides energy.
Beneficial effects of the present invention:
(1) using high temperature modified pyrolytic carbon as thermoset carrier, instead of traditional inert material, so that obtaining maximum oil yield
Solid product recycling simultaneously is easy.
(2) on the one hand combustible gas will be pyrolyzed the coke of carbon surface attachment using imperfect combustion and for the modification of pyrolytic carbon
Oil is reformed, on the other hand by pyrolytic carbon heat-activated, modified pyrolytic carbon specific surface area, pore volume relatively before pyrolytic carbon have
It is substantially improved, it is meant that added value of product is substantially improved.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of package unit of the present invention.
In figure: 1 directly heats pyrolysis installation;2 condensing recovery integrated apparatus;3 desulfurizers;4 pressurizing device A;5 combustion gas
Storage facility;6 heat-exchanger rigs;7 high temperature imperfect combustion devices;8 high temperature modified devices;9 Modified Activated Carbon recyclable devices;10 pressurization dresses
Set B;11 pyrolysis devolatilization product exits;The outlet of 12 pyrolytic carbons;13 without steel wire damaged tire article inlet;14 high temperature modified pyrolytic carbons into
Mouthful;15 removable baffle plates;16 pyrolysis devolatilization product inlets;The outlet of 17 non-condensable gas;18 non-condensable gas imports;19 is pure
Net combustible gas outlet;20 pure combustible gas imports;21 gas outlets;22 modified combustible gas imports;23 fuel gas inlets;24 modifications can
Gas outlet;25 high temperature modified combustible gas imports;The outlet of 26 high-temperature fuel gas;27 high-temperature fuel gas imports;28 combustion-supporting medium imports;29
Unburnt gas product exit;30 unburnt gas product inlets;31 pyrolytic carbon imports;32 high temperature modified pyrolytic carbons
Outlet;33 high temperature modified combustible gas outlets.
Specific embodiment
Below in conjunction with attached drawing and technical solution, a specific embodiment of the invention is further illustrated.
Embodiment
Damaged tire is directly heated in pyrolysis installation 1 after broken, pumping steel wire by no steel wire damaged tire article inlet 13 feeding,
Meanwhile the high temperature modified pyrolytic carbon in high temperature modified device 8 exports 32, high temperature modified pyrolytic carbon import by high temperature modified pyrolytic carbon
14 feedings directly heat in pyrolysis installation 1, and high temperature modified pyrolytic carbon provides energy for the fast pyrogenation of no steel wire damaged tire particle,
Pyrolysis devolatilization product and pyrolytic carbon are generated during fast pyrogenation, pyrolytic carbon is sent via pyrolytic carbon outlet 12, pyrolytic carbon import 31
Enter high temperature modified device 8, pyrolysis devolatilization product is sent into condensation via pyrolysis devolatilization product exit 11, pyrolysis devolatilization product inlet 16
Recycling integrated apparatus 2 is condensed, and the tar being precipitated in condensation process is temporarily stored into 2 bottom of condensing recovery integrated apparatus, is remained
It is remaining not condensable via non-condensable gas outlet 17, the feeding desulfurizer 3 of non-condensable gas import 18, it is pure after desulfurization
Combustible gas is sent into pressurizing device A4 pressurization by pure combustible gas outlet 19, and is sent into combustion gas storage dress by pure combustible gas import 20
Set 5;
Combustible gas in combustion gas storage facility 5 is sent into heat-exchanger rig 6 by gas outlet 21, fuel gas inlet 23, meanwhile, high temperature
High temperature modified combustible gas in reforming apparatus 8 is changed by high temperature modified combustible gas outlet 33, high temperature modified combustible gas import 25 feeding
Thermal 6, combustible gas and high temperature modified combustible gas carry out indirect heat exchange, and the high temperature modified combustible gas temperature after heat exchange is lower, by
Pressurizing device B10 pressurization is sent into modified combustible gas outlet 24, then is sent into combustion gas storage facility 5 by modified combustible gas import 22, is changed
Combustible gas temperature after heat increases, and is sent into high temperature imperfect combustion device 7 by high-temperature fuel gas outlet 26, high-temperature fuel gas import 27
It is interior, it is mixed with the combustion adjuvant from combustion-supporting medium import 28, carries out imperfect combustion, unburnt gas product mainly has
CO、CO2、H2O、H2、CH4Deng by unburnt gas product by unburnt gas product exit 29, imperfect combustion
High temperature modified device 8 is sent into gaseous product import 30, and is mixed with the pyrolytic carbon in high temperature modified device 8, imperfect combustion gas
On the one hand body product will be pyrolyzed the coke tar reforming of carbon surface attachment, on the other hand by pyrolytic carbon heat-activated, modified pyrolysis
Charcoal specific surface area, pore volume relatively before pyrolytic carbon be substantially improved, while gaseous product calorific value improve, the high temperature modified heat in part
Solution charcoal directly heats pyrolysis installation 1 through high temperature modified pyrolytic carbon outlet 32, high temperature modified pyrolytic carbon import 14 feeding, for lower batch
No steel wire damaged tire particle fast pyrogenation provides energy, and remaining high temperature modified pyrolytic carbon is sent into Modified Activated Carbon recyclable device 9 and is carried out
Storage, high temperature modified combustible gas are sent into heat-exchanger rig 6 by high temperature modified combustible gas outlet 33, high temperature modified combustible gas import 25,
Indirect heating for lower batch combustible gas provides energy.
The present invention includes but is not limited to the present embodiment, it is noted that for those of ordinary skill in the art, not
Under the premise of being detached from the technology of the present invention principle, replacement can also be made using other modes, these replacements also should be regarded as the present invention
Protection scope.
Claims (2)
1. a kind of damaged tire low consumption higher value application device, which is characterized in that the damaged tire low consumption higher value application
Device includes directly heating pyrolysis installation (1), condensing recovery integrated apparatus (2), desulfurizer (3), pressurizing device A (4), combustion
Gas-reservoir cryopreservation device (5), heat-exchanger rig (6), high temperature imperfect combustion device (7), high temperature modified device (8), Modified Activated Carbon recycling dress
Set (9) and pressurizing device B (10);
Described directly heat pyrolysis installation (1) is equipped with pyrolysis devolatilization product exit (11), pyrolytic carbon outlet (12), useless without steel wire
Tyre crumbs import (13) and high temperature modified pyrolytic carbon import (14), are internally provided with removable baffle plate (15), by removable
Baffle (15) controls the residence time of pyrolytic carbon, directly heats pyrolysis devolatilization product exit (11) and the condensation of pyrolysis installation (1)
The pyrolysis devolatilization product inlet (16) for recycling integrated apparatus (2) is connected, and pyrolytic carbon exports (12) and high temperature modified device (8)
Pyrolytic carbon import (31) is connected;
The condensing recovery integrated apparatus (2) is equipped with pyrolysis devolatilization product inlet (16) and non-condensable gas exports
(17), the pyrolysis devolatilization product for being sent into condensing recovery integrated apparatus (2) carries out indirect condensing, the tar being precipitated in condensation process
Stored in bottom of device, the non-condensable gas of condensing recovery integrated apparatus (2) outlet (17) and desulfurizer (3) can not
Condensed gas import (18) is connected;
The desulfurizer (3) is equipped with non-condensable gas import (18) and pure combustible gas outlet (19), desulfurizer (3)
Interior pure combustible gas exports (19) by pure combustible gas and is sent into pressurizing device A (4) pressurization, the outlet pressurizing device A (4) and combustion gas
The pure combustible gas import (20) of storage facility (5) is connected;
The combustion gas storage facility (5) is equipped with pure combustible gas import (20), gas outlet (21) and modified combustible gas import
(22), the gas outlet (21) of combustion gas storage facility (5) is connected with the fuel gas inlet (23) of heat-exchanger rig (6), modified combustible gas
Import (22) is connected with pressurizing device B (10) outlet;
The heat-exchanger rig (6) is equipped with fuel gas inlet (23), modified combustible gas exports (24), high temperature modified combustible gas import
(25) and high-temperature fuel gas outlet (26), the modification combustible gas of heat-exchanger rig (6) export the entrance phase of (24) and pressurizing device B (10)
Even, high temperature modified combustible gas import (25) is connected with the high temperature modified combustible gas of high temperature modified device (8) outlet (33), high temperature combustion
Gas outlet (26) is connected with the high-temperature fuel gas import (27) of high temperature imperfect combustion device (7);
The high temperature imperfect combustion device (7) is equipped with high-temperature fuel gas import (27), combustion-supporting medium import (28) and incomplete
Combustion gas product exports (29), the unburnt gas product exit (29) and high temperature of high temperature imperfect combustion device (7)
The unburnt gas product inlet (30) of reforming apparatus (8) is connected;
The high temperature modified device (8) changes equipped with unburnt gas product inlet (30), pyrolytic carbon import (31), high temperature
Property pyrolytic carbon outlet (32) and high temperature modified combustible gas outlet (33), high temperature modified device (8) high temperature modified pyrolytic carbon outlet
(32) respectively with Modified Activated Carbon recyclable device (9) and directly heat the high temperature modified pyrolytic carbon import (14) of pyrolysis installation (1) and be connected.
2. a kind of damaged tire low consumption higher value application method, which is characterized in that by unburnt fuel gas be pyrolysis
Charcoal heat modification, and energy is provided for no steel wire damaged tire particle fast pyrogenation using high temperature modified pyrolytic carbon as thermoset carrier,
And then realize the high-valued recycling of pyrolysis product, steps are as follows:
(I) fast pyrogenation process: damaged tire, which is sent into after broken, pumping steel wire by no steel wire damaged tire article inlet (13), directly to be added
In hot pyrolysis installation (1), meanwhile, the high temperature modified pyrolytic carbon in high temperature modified device (8) is exported by high temperature modified pyrolytic carbon
(32) it is sent into and is directly heated in pyrolysis installation (1) through high temperature modified pyrolytic carbon import (14), high temperature modified pyrolytic carbon is no steel wire
The fast pyrogenation of damaged tire particle provides energy, generates pyrolysis devolatilization product and pyrolytic carbon during fast pyrogenation, pyrolytic carbon according to
It is secondary via pyrolytic carbon outlet (12) and the high temperature modified device (8) of pyrolytic carbon import (31) feeding, pyrolysis devolatilization product successively via
Pyrolysis devolatilization product exit (11) and pyrolysis devolatilization product inlet (16) are sent into condensing recovery integrated apparatus (2) and are condensed,
The tar being precipitated in condensation process is temporarily stored into condensing recovery integrated apparatus (2) bottom, remaining not condensable successively via can not
Condensed gas exports (17) and desulfurizer (3) are sent into non-condensable gas import (18), and the pure combustible gas after desulfurization is by pure
Net combustible gas outlet (19) is sent into pressurizing device A (4) pressurization, and is sent into combustion gas storage facility by pure combustible gas import (20)
(5);
(II) modified energy supply process: the combustible gas in combustion gas storage facility (5) is successively by gas outlet (21) and fuel gas inlet
(23) heat-exchanger rig (6) are sent into, meanwhile, the high temperature modified combustible gas in high temperature modified device (8) is successively by high temperature modified flammable
Gas exports (33) and heat-exchanger rig (6) are sent into high temperature modified combustible gas import (25), and combustible gas and high temperature modified combustible gas carry out
Indirect heat exchange, the high temperature modified combustible gas temperature after heat exchange are lower, and are sent into pressurizing device B (10) by modified combustible gas outlet (24)
Pressurization, then be sent into combustion gas storage facility (5) by modified combustible gas import (22), the combustible gas temperature after heat exchange increases, successively by
High-temperature fuel gas exports (26) and high-temperature fuel gas import (27) and is sent into high temperature imperfect combustion device (7), and from combustion-supporting medium
The combustion adjuvant of import (28) mixes, and carries out imperfect combustion, and unburnt gas product mainly has CO, CO2、H2O、H2、CH4,
By unburnt gas product successively by unburnt gas product exit (29) and unburnt gas product inlet
(30) it is sent into high temperature modified device (8), and is mixed with the pyrolytic carbon in high temperature modified device (8), unburnt gas product
On the one hand it will be pyrolyzed the coke tar reforming of carbon surface attachment, on the other hand by pyrolytic carbon heat-activated, modified pyrolytic carbon compares table
Area, pore volume relatively before pyrolytic carbon be substantially improved, while gaseous product calorific value improve, the high temperature modified pyrolytic carbon in part according to
It is secondary to directly heat pyrolysis installation (1) through high temperature modified pyrolytic carbon outlet (32) and high temperature modified pyrolytic carbon import (14) feeding, be
Lower batch provides energy without steel wire damaged tire particle fast pyrogenation, and remaining high temperature modified pyrolytic carbon is sent into Modified Activated Carbon recyclable device
(9) it is stored, high temperature modified combustible gas is successively by high temperature modified combustible gas outlet (33) and high temperature modified combustible gas import
(25) heat-exchanger rig (6) are sent into, the indirect heating for lower batch combustible gas provides energy.
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CN201910544909.6A CN110305687B (en) | 2019-06-21 | 2019-06-21 | Low-consumption high-value utilization device and method for waste tires |
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CN110938450A (en) * | 2019-12-16 | 2020-03-31 | 华中科技大学 | Method for preparing pyrolysis oil and limonene by utilizing waste tires through pressurization and pyrolysis |
CN111408350A (en) * | 2020-05-14 | 2020-07-14 | 沈阳鑫迪环境技术有限公司 | Method for preparing mercury-absorbing carbon material by using waste tire cracking slag |
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CN1699515A (en) * | 2004-05-18 | 2005-11-23 | 邢力 | Process for producing gasoline, diesel oil and active carbon by using waste rubbers |
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CN110938450A (en) * | 2019-12-16 | 2020-03-31 | 华中科技大学 | Method for preparing pyrolysis oil and limonene by utilizing waste tires through pressurization and pyrolysis |
CN110938450B (en) * | 2019-12-16 | 2020-10-09 | 华中科技大学 | Method for preparing pyrolysis oil and limonene by utilizing waste tires through pressurization and pyrolysis |
CN111408350A (en) * | 2020-05-14 | 2020-07-14 | 沈阳鑫迪环境技术有限公司 | Method for preparing mercury-absorbing carbon material by using waste tire cracking slag |
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