CN110305594A - A kind of 2D shakes ultra-thin thermosticking film of noctilucence and preparation method thereof - Google Patents

A kind of 2D shakes ultra-thin thermosticking film of noctilucence and preparation method thereof Download PDF

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Publication number
CN110305594A
CN110305594A CN201910613290.XA CN201910613290A CN110305594A CN 110305594 A CN110305594 A CN 110305594A CN 201910613290 A CN201910613290 A CN 201910613290A CN 110305594 A CN110305594 A CN 110305594A
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China
Prior art keywords
layer
tpu
noctilucence
film
grating
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Inventor
陈旭斌
林艺明
张道军
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Anse Guangdong New Material Technology Co Ltd
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Anse Guangdong New Material Technology Co Ltd
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Priority to CN201910613290.XA priority Critical patent/CN110305594A/en
Publication of CN110305594A publication Critical patent/CN110305594A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/10Presence of homo or copolymers of propene
    • C09J2423/106Presence of homo or copolymers of propene in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/006Presence of polyester in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • C09J2475/006Presence of polyurethane in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of 2D to shake the ultra-thin thermosticking film of noctilucence; including nanometer oleophobic coating, the side of nanometer oleophobic coating is successively pasted with wearing layer, ultraviolet resistant layer, PP grating layer, TPU grating layer, PU printing layer, noctilucence TPU layer, PET basal layer, TPU layer, nano ceramics heat insulating membrane layer, PP protective layer, explosion proof film layer, nanocomposite optical layer of silica gel.Nanometer oleophobic coating of the present invention can make surface waterproofing good; the wearability on surface can be improved in wearing layer; ultraviolet resistant layer can protect PP grating layer, TPU grating layer; noctilucence TPU layer can be shinny at night; the good heat-insulation effect of nano ceramics heat insulating membrane layer, PET basal layer, PP protective layer, explosion proof film layer, which have, keeps thin film shape and strong and play the role of supporting protection indeformable well during hot pressure;Nanocomposite optical layer of silica gel can make the viscosity of film good, preferably be bonded with object;Production process of the invention simultaneously is more compact and reasonable, easy to operate, and the product quality of preparation is high.

Description

A kind of 2D shakes ultra-thin thermosticking film of noctilucence and preparation method thereof
Technical field
The present invention relates to noctilucence technical field of membrane more particularly to a kind of 2D to shake the ultra-thin thermosticking film of noctilucence and its preparation side Method.
Background technique
Luminescent film is the industrial products made of materials such as activated by rare earth elements and alkaline earth aluminates, has good printing Property and computer delineate performance, be mainly used in fire protection safety sign, safety of ship mark, general orientation, instruction, distinguishing mark etc. Occasion.
Existing luminescent film integral strength is not high, supports protecting effect bad during hot pressure, and surface abrasion resistance ratio It is poor, it is penetrated readily through simultaneously as lacking protection ultraviolet light well, in use it was also found that due to being that basal layer is direct It is pasted onto the surface of object, firm pasting is not high, is easy to fall off, therefore it is proposed that a kind of 2D shakes the ultra-thin thermosticking film of noctilucence And preparation method thereof.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of computer proposed protection dress It sets.
To achieve the goals above, present invention employs following technical solutions:
A kind of 2D shaking ultra-thin thermosticking film of noctilucence, including nanometer oleophobic coating, the side of nanometer oleophobic coating are successively pasted with resistance to Grind layer, ultraviolet resistant layer, PP grating layer, TPU grating layer, PU printing layer, noctilucence TPU layer, PET basal layer, TPU layer, nanometer pottery The heat-insulated film layer of porcelain, PP protective layer, explosion proof film layer, nanocomposite optical layer of silica gel.
Preferably, noctilucence TPU layer with a thickness of 0.1mm~0.3mm, TPU grating layer with a thickness of 0.2mm~0.3mm.
A kind of 2D shakes the preparation method of the ultra-thin thermosticking film of noctilucence, comprising the following steps:
S1: passing through dehumidifier desiccant dehumidification for PET raw material, then put into screw extruder and squeeze out, obtain PET basal layer, Granulated TPU raw material is put into screw extruder and is squeezed out, TPU grating layer, TPU layer can be obtained, granulated PP raw material is put into It is squeezed out into screw extruder, PP grating layer, PP protective layer can be obtained;
S2: passing through dehumidifier desiccant dehumidification for granulated PU raw material, then put into screw extruder and squeeze out, obtain PU film, Dystectic ink raw materials are put into coating head ink tank, high-melting-point ink is coated on PU film by coating waste water mode, PU printing layer can be obtained;
S3: by granulated TPU raw material and noctilucence powder raw material by dehumidifier desiccant dehumidification, desiccant dehumidification passes through blender after the completion It is stirred, then mixed raw material is put into screw extruder and is squeezed out, and by clothes hanger type lamination head lamination in paper jam On, obtain noctilucence TPU layer;
S4: 50~60 DEG C at a temperature of, nanometer oleophobic coating, wearing layer, ultraviolet resistant layer are successively rolled into patch by roller It closes, obtains membrane body A, PP grating layer, TPU grating layer are successively rolled into fitting by roller, membrane body B is obtained, by PU printing layer, noctilucence TPU layer, PET basal layer successively roll fitting by roller, membrane body C are obtained, by TPU layer, nano ceramics heat insulating membrane layer, PP protective layer Fitting is successively rolled by roller, obtains membrane body D, and explosion proof film layer, nanocomposite optical layer of silica gel are successively rolled into fitting by roller, obtained Membrane body E, finally by membrane body A, B, C, D, E according to nanometer oleophobic coating, wearing layer, ultraviolet resistant layer, PP grating layer, TPU grating Layer, PU printing layer, noctilucence TPU layer, PET basal layer, TPU layer, nano ceramics heat insulating membrane layer, PP protective layer, explosion proof film layer, nanometer The sequence of optics layer of silica gel, which is pasted together, shakes the ultra-thin thermosticking film of noctilucence to get 2D.
Preferably, the luminescent powder in step S3 is rare earth.
Compared with prior art, the beneficial effects of the present invention are:
The present invention includes nanometer oleophobic coating, wearing layer, ultraviolet resistant layer, PP grating layer, TPU grating layer, PU printing layer, noctilucence TPU layer, PET basal layer, TPU layer, nano ceramics heat insulating membrane layer, PP protective layer, explosion proof film layer, nanocomposite optical layer of silica gel share 13 layers, nanometer oleophobic coating can make surface waterproofing good, and the wearability on surface can be improved in wearing layer, pass through setting Ultraviolet resistant layer can protect PP grating layer, TPU grating layer, and noctilucence TPU layer can be shinny at night, nano ceramics every The good heat-insulation effect of hotting mask layer, PET basal layer, PP protective layer, explosion proof film layer have the function of holding thin film shape and intensity, with And play the role of supporting protection indeformable well during hot pressure;Nanocomposite optical layer of silica gel can make the viscosity of film It is good, preferably it is bonded with object;Production process of the invention simultaneously is more compact and reasonable, easy to operate, the product quality of preparation It is high.
Detailed description of the invention
Fig. 1 is the structural schematic diagram that a kind of 2D proposed by the present invention shakes the ultra-thin thermosticking film of noctilucence.
In figure: 1 nanometer of oleophobic coating, 2 wearing layers, 3 ultraviolet resistant layers, 4PP grating layer, 5TPU grating layer, 6PU printing Layer, 7 noctilucence TPU layers, 8PET basal layer, 9TPU layers, 10 nano ceramics heat insulating membrane layers, 11PP protective layer, 12 explosion proof film layers, 13 receive Meter Guang Xue layer of silica gel.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Referring to Fig.1, a kind of 2D shaking ultra-thin thermosticking film of noctilucence, including nanometer oleophobic coating 1, the one of nanometer oleophobic coating 1 Side is successively pasted with wearing layer 2, ultraviolet resistant layer 3, PP grating layer 4, TPU grating layer 5, PU printing layer 6, noctilucence TPU layer 7, PET Basal layer 8, TPU layer 9, nano ceramics heat insulating membrane layer 10, PP protective layer 11, explosion proof film layer 12, nanocomposite optical layer of silica gel 13.
Wherein, light TPU layer 7 with a thickness of 0.1mm~0.3mm, TPU grating layer 5 with a thickness of 0.2mm~0.3mm.
A kind of 2D shakes the preparation method of the ultra-thin thermosticking film of noctilucence, comprising the following steps:
S1: passing through dehumidifier desiccant dehumidification for PET raw material, then put into screw extruder and squeeze out, obtain PET basal layer 8, Granulated TPU raw material is put into screw extruder and is squeezed out, TPU grating layer 5, TPU layer 9 can be obtained, granulated PP raw material is thrown Enter and squeezed out into screw extruder, PP grating layer 4, PP protective layer 11 can be obtained;
S2: passing through dehumidifier desiccant dehumidification for granulated PU raw material, then put into screw extruder and squeeze out, obtain PU film, Dystectic ink raw materials are put into coating head ink tank, high-melting-point ink is coated on PU film by coating waste water mode, PU printing layer 6 can be obtained;
S3: by granulated TPU raw material and noctilucence powder raw material by dehumidifier desiccant dehumidification, desiccant dehumidification passes through blender after the completion It is stirred, then mixed raw material is put into screw extruder and is squeezed out, and by clothes hanger type lamination head lamination in paper jam On, obtain noctilucence TPU layer 7;
S4: 50~60 DEG C at a temperature of, nanometer oleophobic coating 1, wearing layer 2, ultraviolet resistant layer 3 are successively rolled by roller Fitting, obtains membrane body A, and PP grating layer 4, TPU grating layer 5 are successively rolled fitting by roller, obtain membrane body B, by PU printing layer 6, Noctilucence TPU layer 7, PET basal layer 8 successively roll fitting by roller, membrane body C are obtained, by TPU layer 9, nano ceramics heat insulating membrane layer 10, PP protective layer 11 successively rolls fitting by roller, obtains membrane body D, explosion proof film layer 12, nanocomposite optical layer of silica gel 13 are passed through roller Cylinder successively rolling fitting, obtains membrane body E, finally by membrane body A, B, C, D, E according to nanometer oleophobic coating 1, wearing layer 2, antiultraviolet Layer 3, PP grating layer 4, TPU grating layer 5, PU printing layer 6, noctilucence TPU layer 7, PET basal layer 8, TPU layer 9, nano ceramics are heat-insulated Film layer 10, PP protective layer 11, explosion proof film layer 12, the sequence of nanocomposite optical layer of silica gel 13, which are pasted together, shakes noctilucence to get 2D Ultra-thin thermosticking film.
Wherein, the luminescent powder in step S3 is rare earth.
The present invention includes nanometer oleophobic coating 1, wearing layer 2, ultraviolet resistant layer 3, PP grating layer 4, TPU grating layer 5, PU print Brush layer 6, noctilucence TPU layer 7, PET basal layer 8, TPU layer 9, nano ceramics heat insulating membrane layer 10, PP protective layer 11, explosion proof film layer 12, Nanocomposite optical layer of silica gel 13 shares 13 layers, and nanometer oleophobic coating 1 can make surface waterproofing good, and wearing layer 2 can be improved The wearability on surface can protect PP grating layer 4, TPU grating layer 5, noctilucence TPU by the ultraviolet resistant layer 3 of setting Layer 7 can be shinny at night, the good heat-insulation effect of nano ceramics heat insulating membrane layer 10, PET basal layer 8, PP protective layer 11, rupture pressure disc Layer 12 has the function of keeping thin film shape and intensity, and plays support well during hot pressure and protect indeformable work With;Nanocomposite optical layer of silica gel 13 can make the viscosity of film good, preferably be bonded with object;Production process of the invention simultaneously More compact and reasonable, easy to operate, the product quality of preparation is high.
More than, it is merely preferred embodiments of the present invention, but scope of protection of the present invention is not limited thereto, it is any Those familiar with the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its invents Design is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of 2D shakes the ultra-thin thermosticking film of noctilucence, including nanometer oleophobic coating (1), which is characterized in that nanometer oleophobic coating (1) Side be successively pasted with wearing layer (2), ultraviolet resistant layer (3), PP grating layer (4), TPU grating layer (5), PU printing layer (6), Noctilucence TPU layer (7), PET basal layer (8), TPU layer (9), nano ceramics heat insulating membrane layer (10), PP protective layer (11), explosion proof film layer (12), nanocomposite optical layer of silica gel (13).
2. a kind of 2D according to claim 1 shakes the ultra-thin thermosticking film of noctilucence, which is characterized in that noctilucence TPU layer (7) with a thickness of 0.1mm~0.3mm, TPU grating layer (5) with a thickness of 0.2mm~0.3mm.
3. the preparation method that a kind of 2D shakes the ultra-thin thermosticking film of noctilucence, which comprises the following steps:
S1: PET raw material is passed through into dehumidifier desiccant dehumidification, then puts into screw extruder and squeezes out, obtain PET basal layer (8), granulated TPU raw material is put into screw extruder and is squeezed out, TPU grating layer (5), TPU layer (9) can be obtained, by granulated PP raw material, which is put into screw extruder, to be squeezed out, and PP grating layer (4), PP protective layer (11) can be obtained;
S2: passing through dehumidifier desiccant dehumidification for granulated PU raw material, then put into screw extruder and squeeze out, obtain PU film, Dystectic ink raw materials are put into coating head ink tank, high-melting-point ink is coated on PU film by coating waste water mode, PU printing layer (6) can be obtained;
S3: by granulated TPU raw material and noctilucence powder raw material by dehumidifier desiccant dehumidification, desiccant dehumidification passes through blender after the completion It is stirred, then mixed raw material is put into screw extruder and is squeezed out, and by clothes hanger type lamination head lamination in paper jam On, obtain noctilucence TPU layer (7);
S4: 50~60 DEG C at a temperature of, by nanometer oleophobic coating (1), wearing layer (2), ultraviolet resistant layer (3) by roller according to Secondary rolling fitting, obtains membrane body A, and PP grating layer (4), TPU grating layer (5) are successively rolled fitting by roller, obtain membrane body B, will PU printing layer (6), noctilucence TPU layer (7), PET basal layer (8) successively roll fitting by roller, obtain membrane body C, by TPU layer (9), Nano ceramics heat insulating membrane layer (10), PP protective layer (11) successively roll fitting by roller, obtain membrane body D, by explosion proof film layer (12), Nanocomposite optical layer of silica gel (13) successively rolls fitting by roller, obtains membrane body E, finally dredges membrane body A, B, C, D, E according to nanometer Oil coating (1), wearing layer (2), ultraviolet resistant layer (3), PP grating layer (4), TPU grating layer (5), PU printing layer (6), noctilucence TPU layer (7), PET basal layer (8), TPU layer (9), nano ceramics heat insulating membrane layer (10), PP protective layer (11), explosion proof film layer (12), the sequence of nanocomposite optical layer of silica gel (13), which is pasted together, shakes the ultra-thin thermosticking film of noctilucence to get 2D.
4. the preparation method that a kind of 2D according to claim 3 shakes the ultra-thin thermosticking film of noctilucence, which is characterized in that in step S3 Luminescent powder is rare earth.
CN201910613290.XA 2019-07-09 2019-07-09 A kind of 2D shakes ultra-thin thermosticking film of noctilucence and preparation method thereof Pending CN110305594A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519005A (en) * 2008-02-28 2009-09-02 Kba-美创力公司 Online grating printing method
CN206968218U (en) * 2017-04-13 2018-02-06 北京康得新功能材料有限公司 A kind of 3D rendering effect pre-coating film
CN207432912U (en) * 2017-11-13 2018-06-01 陈辉 A kind of two-sided colorful local laser Wear-resistant heat insulation home decoration film
CN108559417A (en) * 2018-05-24 2018-09-21 海安浩驰科技有限公司 A kind of photosensitive color-changing insulated-cover wagon film and preparation method thereof
CN208362248U (en) * 2018-05-15 2019-01-11 昆山玉寰包装材料有限公司 Self-luminous adhesive tape

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101519005A (en) * 2008-02-28 2009-09-02 Kba-美创力公司 Online grating printing method
CN206968218U (en) * 2017-04-13 2018-02-06 北京康得新功能材料有限公司 A kind of 3D rendering effect pre-coating film
CN207432912U (en) * 2017-11-13 2018-06-01 陈辉 A kind of two-sided colorful local laser Wear-resistant heat insulation home decoration film
CN208362248U (en) * 2018-05-15 2019-01-11 昆山玉寰包装材料有限公司 Self-luminous adhesive tape
CN108559417A (en) * 2018-05-24 2018-09-21 海安浩驰科技有限公司 A kind of photosensitive color-changing insulated-cover wagon film and preparation method thereof

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Application publication date: 20191008