CN102277781B - Transferring paper applied to sublimation type ink jetting, printing and transferring - Google Patents
Transferring paper applied to sublimation type ink jetting, printing and transferring Download PDFInfo
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- CN102277781B CN102277781B CN 201110221689 CN201110221689A CN102277781B CN 102277781 B CN102277781 B CN 102277781B CN 201110221689 CN201110221689 CN 201110221689 CN 201110221689 A CN201110221689 A CN 201110221689A CN 102277781 B CN102277781 B CN 102277781B
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Abstract
The invention discloses transferring paper applied to sublimation type ink jetting, printing and transferring. In the transferring paper, a filter resistant layer for sublimation type ink for jetting and printing is coated on one surface of body paper and a back layer is coated on the other surface of the body paper. The sublimation type ink jetting and printing transferring paper has high sublimation printing ink absorption property and quick drying property when ink is jetted to print an image, and the image is high in reproducibility; furthermore, the transferring paper has high transferring rate during thermal transferring; and the image of a printed material has high color saturation, image resolution and reproducibility.
Description
Technical field
The present invention relates to subliming type inkjet printing transfer paper, particularly be exactly to use the sublimation dye ink by the inkjet printing mode pattern to be printed on this transfer paper, the subliming type inkjet printing transfer paper that image on the transfer paper uses when being transferred to polyester textile through heating sublimation or scribbling on the object of polyester coatings.
Background technology
With regard to printing transferring method, there are substantially three kinds, namely dissolve the type transfer printing, offset printing transfer printing and sublimation transfer method.Dissolve the type transfer printing and use the printing ink that is formed by hot melt resin and pigment, original local flavor and the retractility variation of stock self after the printing.What the offset printing transfer printing used is the plastisol printing ink that polyvinyl chloride powder, plasticizer, pigment etc. form, and gas permeability and the feel of stock are bad after the printing.The subliming type transfer printing uses the sublimation dye ink, and it neither damages the style of the object self of undertaking the printing of, and transferability goes out the image of the distinctness that other transfer printing can't realize again, and this is the printing transferring method of present Major Epidemic.
With regard to the printing process of printing transfer paper, traditional printing process be with half tone or intaglio press image printing on transfer paper.The problems such as these two kinds of printing processes not only need printing machinery, and exist chromatography inaccurate, and printing precision is poor in addition, also are not suitable for personalization, the Production requirement of small lot, many kinds.In recent years a kind of contactless printing is to utilize digital technology, adopts sublimation dye in the inkjet printing mode image to be printed on the transfer paper with mirror phase orientation.This subliming type inkjet printing transfer paper has overcome the shortcoming of traditional transfer paper printing, more and more receives an acclaim.
So-called subliming type transfer printing, exactly the image printing face of subliming type transfer paper and polyesters fabric or the stock that scribbles polyester coatings coincide together, temperature driving fit heating about 200 ℃.Visual printing ink on the transfer paper is subjected to thermal dye sublimation transfer printing to stock.
The manufacture method of relevant subliming type inkjet printing transfer paper generally is the coated on one side ink-receiver layer at body paper from the document that in recent years can see as can be known.This ink-receiver layer mainly contains the sio2 micro mist, the water-soluble sizing materials such as polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC), and for example, the document that Japan issues in the special permission Room in recent years has: JP 2003-276309; JP 2003-266919; JP 2004-255717; JP 2010-058335; JP 2010-0889343.
General subliming type inkjet printing transfer paper absorbability and drying property to the distillation ink when the inkjet printing image is not enough, often at printing surface the printing ink wiping occurs dirty, directly has influence on flying print efficient and image quality; On the other hand, the most basic index of subliming type inkjet printing transfer paper is the distillation rate of transform.Difficulty be the to a certain extent mutually restriction of rate of drying and these two indexs of the rate of transform, that is to say that when inkjet printing to the fast transfer paper of distillation ink absorption rate of drying, the distillation rate of transform is but relatively on the low side when heating transfer.The temperature of subliming type inkjet printing transfer paper when transfer printing is in 180-210 ℃ of scope.The deformation warpage occurs in subliming type inkjet printing transfer paper Yin Gaowen general when this temperature, causes the transferred image dislocation, causes the transfer printing failure when serious.
Summary of the invention
In view of above-mentioned present situation, purpose of the present invention just provides a kind ofly not only has good absorbability and quick-drying to the distillation ink when inkjet printing, and have again the good rate of transform and the good subliming type inkjet printing transfer paper of dimensional stability when sublimation transfer.
The present invention adopts following technical scheme to achieve these goals:
The transfer paper that the paper mold inkjet printing transfer printing that is applied to distil is used, it is characterized in that: described transfer paper is for scribbling the resistance filtering layer of the distillation ink of inkjet printing in the light face side of body paper, matsurface at body paper scribbles back coating, described resistance filtering layer is comprised of little aggressiveness that polyvinyl alcohol, carboxymethyl cellulose and table chlorine enol polyamide resin cation, diallyl dimethyl ammoniumchloride reaction generate, and described back coating forms by inorganic pigment with adhesive.
The transfer paper that the described paper mold inkjet printing transfer printing that is applied to distil is used is characterized in that: described body paper is the one-side glazed paper that sulfate process wood oar is made, and its Surface absorption weight is not more than 35g/m.
The transfer paper that the described paper mold inkjet printing transfer printing that is applied to distil is used, it is characterized in that: described inorganic pigment is talcum powder, CaCO
3, kaolin.
The transfer paper that the described paper mold inkjet printing transfer printing that is applied to distil is used, it is characterized in that: described adhesive is selected from wherein a kind of or both mixtures of styrene-butadiene latex, polyvinyl alcohol.
The transfer paper that the described paper mold inkjet printing transfer printing that is applied to distil is used, it is characterized in that: the preparation method of described resistance filtering layer comprises sio
20.5-1.5 part, kaolin 10-50 part, carboxymethyl cellulose 40-120 part, polyvinyl alcohol 10-50 part, diallyl dimethyl ammoniumchloride 5-25 part, table chlorine enol amide resin 20-50 part, mix cohesion, in the process that forms agglomerate, reaction system is applied high shear, control is sheared peripheral velocity 800-1000m/min, below little aggressiveness planar dimension 35um, is controlled ph between 8-12.
The transfer paper that the described paper mold inkjet printing transfer printing that is applied to distil is used, it is characterized in that: the preparation method of described back coating comprises CaCO
350-200 part, talcum powder 20-50 part, water 150-400 part, dispersant 0.1-0.5 part, polyvinyl alcohol 5-20 part, lubricant 0.2-1 part, styrene-butadiene latex 10-20 part mix, and ph is between 8-12 in control.
Beneficial effect of the present invention:
The subliming type inkjet printing transfer paper that adopts the present invention to make has good distillation marking ink absorbability and quick-drying when the inkjet printing image, image reconstruction is good; When heating transfer, have the image color saturation degree of the good rate of transform, stock high, visual resolution ratio and repeatability good.
The specific embodiment
Embodiment: body paper used in the present invention is the one-side glazed paper take bleached wood pulp as main component.The dimensional stability of one-side glazed paper is good.Body paper quantitatively with 60-100g/m
2Be advisable, Surface absorption weight is not more than 35g/m
2(GB1540).
Light face side coating resistance filtering layer at above-mentioned body paper, this resistance filtering layer mainly is made of little aggressiveness that polyvinyl alcohol (hereinafter to be referred as PVA), carboxymethyl cellulose (hereinafter to be referred as CMC) and table chlorine enol polyamide resin cation (hereinafter to be referred as PAE), diallyl dimethyl ammoniumchloride (hereinafter to be referred as PDM) reaction generate, and the resistance filtering layer is " mortar plastic structure ".Because little aggressiveness is distributed in the surface of resistance filtering layer, the specific area of resistance filtering layer is significantly increased, thereby effectively promoted the ability that absorbs the distillation marking ink, improved rate of drying.On the other hand, as described later, because the resistance filtering layer of this " mortar plastic structure " has high specific area and weak elecrtonegativity, can effectively make with dye particles in electronegative distillation ink be trapped in the resistance filtering layer the surface on and make it to lose flowability, herewith obtain the good rate of transform and picture resolution.
Among the present invention the resistance filtering layer be coated with the degree of polymerization scope of PVA in the feed liquid can be 500～1700; Various degree of hydrolysis all can use.
The resistance filtering layer is coated with CMC optimum substitution value in the feed liquid for selecting in 〉=0.4～1.0 scopes among the present invention.
The resistance filtering layer is coated with in the feed liquid among the present invention PAE and PDM are the water-soluble cationic high polymers, and its suitable molecular weight should be 100,000～1,000,000 scopes.
The present invention hinders filtering layer can be sublimated the dispersible ink swelling at the utmost point in the short time, the dye particles moment of distillation in the ink lost flowability and fix.
The little aggressiveness of macromolecule among the present invention in the resistance filtering layer is to obtain like this: above-mentioned CMC is anionic, when it is prepared with an amount of cation type resin PAE, PDM, two kinds of electrical opposite resins condense, in forming the process of agglomerate reaction system is applied high shear, the agglomerate corpusculed forms little aggressiveness, and stably is scattered in and is coated with in the feed liquid under the effect of high shear force.Control shears peripheral velocity 800-1000m/min, below little aggressiveness planar dimension 35um.The feed liquid that is coated with that obtains like this has lower elecrtonegativity, and coating is " mortar plastic structure ".
The coating weight of resistance filtering layer is controlled at 5-8g/m
2, preferred coating weight is 7.0g/m
2For obtaining the good coating of tightness, preferably adopt comma scraper coating method coating resistance filtering layer.
The resistance filtering layer also can comprise the inorganic fine particles such as sio2, kaolin, can adjust in the 5%-25% scope specific requirement, the addition of properties of product according to the client.
The present invention has designed back coating in the matsurface side of body paper.Theoretically, the back of the body is coated with or primary coat can prevent that transfer paper is bleed-through in reverse distillation, the papermaking in heating sublimation transfer printing stage.But the actual tests proof back of the body is coated with than primary coat and more helps to improve the rate of transform.Another important function of being coated with of the back of the body is because the transfer paper that has the back of the body to be coated with has been realized two sided coatings, so can make the two sides of transfer paper obtain interior stress balance during at high temperature transfer printing, the volume of having alleviated transfer paper sticks up deformation, avoids the image dislocation, can obtain high-quality transfer printing effect.
Back coating of the present invention mainly is comprised of inorganic pigment and adhesive.Inorganic pigment mainly comprises talcum powder, CaCo
3, kaolin etc.; Adhesive can adopt styrene-butadiene latex, PVA etc.The back of the body is coated with coating weight 3-25g/m
2Scope all can, the coating weight mode do not limit.
The below is the example of describing invention:
The embodiment table;
Annotate: 1, comparative example is the pattern of buying in market.
2, printing and transfer printing performance are passed judgment on and are adopted inner 5 grades of point systems.Large person is effective for numerical value.
Claims (5)
1. one kind is applied to the transfer paper that the transfer printing of subliming type inkjet printing is used, it is characterized in that: described transfer paper is for scribbling the resistance filtering layer of the distillation ink of inkjet printing in the light face side of body paper, matsurface coating back coating at body paper, described resistance filtering layer mainly is comprised of little aggressiveness that polyvinyl alcohol, carboxymethyl cellulose and chloropropylene oxide polyamide resin cation, diallyl dimethyl ammoniumchloride reaction generate, described back coating is comprised of inorganic pigment and adhesive, and the preparation method of described resistance filtering layer comprises SiO
20.5-1.5 part, kaolin 10-50 part, carboxymethyl cellulose 40-120 part, polyvinyl alcohol 10-50 part, diallyl dimethyl ammoniumchloride 5-25 part, chloropropylene oxide polyamide 20-50 part, mix cohesion, in the process that forms agglomerate, reaction system is applied high shear, control is sheared peripheral velocity 800-1000m/min, below little aggressiveness planar dimension 35 μ m, is controlled pH between 8-12.
2. according to claim 1ly be applied to the transfer paper that the transfer printing of subliming type inkjet printing is used, it is characterized in that: described body paper is the one-side glazed paper that sulfate method pulp is made, and its Surface absorption weight is not more than 35g/m
2
3. according to claim 1ly be applied to the transfer paper that the transfer printing of subliming type inkjet printing is used, it is characterized in that: described inorganic pigment is talcum powder, CaCO
3, kaolin.
4. according to claim 1ly be applied to the transfer paper that the transfer printing of subliming type inkjet printing is used, it is characterized in that: described adhesive is selected from wherein a kind of or both mixtures of styrene-butadiene latex, polyvinyl alcohol.
5. according to claim 1ly be applied to the transfer paper that the transfer printing of subliming type inkjet printing is used, it is characterized in that: the preparation method of described back coating comprises CaCO
350-200 part, talcum powder 20-50 part, water 150-400 part, dispersant 0.1-0.5 part, polyvinyl alcohol 5-20 part, lubricant 0.2-1 part, styrene-butadiene latex 10-20 part mix, and pH is between 8-12 in control.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110221689 CN102277781B (en) | 2011-08-04 | 2011-08-04 | Transferring paper applied to sublimation type ink jetting, printing and transferring |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110221689 CN102277781B (en) | 2011-08-04 | 2011-08-04 | Transferring paper applied to sublimation type ink jetting, printing and transferring |
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| Publication Number | Publication Date |
|---|---|
| CN102277781A CN102277781A (en) | 2011-12-14 |
| CN102277781B true CN102277781B (en) | 2013-04-17 |
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| CN 201110221689 Active CN102277781B (en) | 2011-08-04 | 2011-08-04 | Transferring paper applied to sublimation type ink jetting, printing and transferring |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104652171A (en) * | 2013-11-25 | 2015-05-27 | 中国制浆造纸研究院 | Manufacturing method of quick-dry heat sublimation transfer paper with high transfer rate |
| CN105730120A (en) * | 2014-12-08 | 2016-07-06 | 上海东升新材料有限公司 | Heat transfer printing paper and preparing method thereof |
| ES2826405T3 (en) * | 2015-06-12 | 2021-05-18 | Coldenhove Know How B V | Improved transfer paper for inkjet printing |
| FR3061725B1 (en) * | 2017-01-12 | 2021-05-07 | Munksjo Oyj | TRANSFER PAPER FOR SUBLIMATION PRINTING CONTAINING A CATIONIC AGENT |
| CN107435276B (en) * | 2017-08-31 | 2020-06-19 | 宜兴市佳普林新材料有限公司 | Method for manufacturing quick-drying type thermal sublimation paper |
| CN110857541A (en) * | 2018-08-22 | 2020-03-03 | 全斯福新材料（苏州）有限公司 | Low-expansion-ratio flat transfer paper |
| CN109367313B (en) * | 2018-11-24 | 2024-08-02 | 赵慧哲 | Ultrathin thermal sublimation transfer paper |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL206929B1 (en) * | 1998-07-09 | 2010-10-29 | Grace W R & Co | Ink-receptive coatings and recording medium prepared therefrom |
| KR100809562B1 (en) * | 1998-07-29 | 2008-03-04 | 더블유.에이. 샌더스 페이피어패브리크 콜덴호브 비.브이. | Transfer paper for ink-jet printing |
| JP2001277706A (en) * | 2000-03-30 | 2001-10-10 | Mitsubishi Paper Mills Ltd | Medium to be recorded by ink jetting and transfer recording method to print medium |
| JP2004255717A (en) * | 2003-02-26 | 2004-09-16 | Mitsubishi Paper Mills Ltd | Inkjet recording medium for sublimation ink transferring, method of manufacturing it and transfer recording method |
| JP4413979B1 (en) * | 2008-09-02 | 2010-02-10 | 大王製紙株式会社 | Sublimation type inkjet printing transfer paper |
| JP4413980B1 (en) * | 2008-09-10 | 2010-02-10 | 大王製紙株式会社 | Sublimation type inkjet printing transfer paper |
| JP5300399B2 (en) * | 2008-10-07 | 2013-09-25 | 大王製紙株式会社 | Sublimation type inkjet printing transfer paper |
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