CN110299374A - A kind of global pixel cell structure and forming method reducing parasitic photoresponse - Google Patents

A kind of global pixel cell structure and forming method reducing parasitic photoresponse Download PDF

Info

Publication number
CN110299374A
CN110299374A CN201910560970.XA CN201910560970A CN110299374A CN 110299374 A CN110299374 A CN 110299374A CN 201910560970 A CN201910560970 A CN 201910560970A CN 110299374 A CN110299374 A CN 110299374A
Authority
CN
China
Prior art keywords
layer
interlayer dielectric
deep trench
dielectric layer
photoresponse
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910560970.XA
Other languages
Chinese (zh)
Inventor
顾学强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Micro Well Electronic Technology Co Ltd
Original Assignee
Shanghai Micro Well Electronic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Micro Well Electronic Technology Co Ltd filed Critical Shanghai Micro Well Electronic Technology Co Ltd
Priority to CN201910560970.XA priority Critical patent/CN110299374A/en
Publication of CN110299374A publication Critical patent/CN110299374A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/1463Pixel isolation structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/14634Assemblies, i.e. Hybrid structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/14636Interconnect structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14643Photodiode arrays; MOS imagers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/14687Wafer level processing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/14689MOS based technologies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/1469Assemblies, i.e. hybrid integration

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Solid State Image Pick-Up Elements (AREA)

Abstract

The invention discloses a kind of global pixel cell structures for reducing parasitic photoresponse, including the photodiode being set on substrate, transfer tube, memory node, and it is covered in the interlayer dielectric layer on substrate, metal interconnecting layer is equipped in interlayer dielectric layer, and metal interconnecting layer is located at the upper area between the photodiode of two pixel units of arbitrary neighborhood, deep trench is additionally provided in interlayer dielectric layer above photodiode, the bottom surface of deep trench and the upper surface of photodiode are isolated, one compound light-blocking structure is covered on the side wall of deep trench, it forms opening in the upper and lower ends of deep trench, and it extends on the upper surface of interlayer dielectric layer, by the completely insulated masking of metal interconnecting layer in interlayer dielectric layer below, therefore the signal of storage node not will receive the influence of incident ray, avoid the distortion of output signal.The invention also discloses a kind of forming methods of global pixel cell structure for reducing parasitic photoresponse.

Description

A kind of global pixel cell structure and forming method reducing parasitic photoresponse
Technical field
The present invention relates to cmos image sensor technical fields, reduce the complete of parasitic photoresponse more particularly, to a kind of Office's pixel cell structure and forming method.
Background technique
Imaging sensor refers to the device for converting optical signals to electric signal, usually extensive commercial imaging sensor core Piece includes charge-coupled device (CCD) and complementary metal oxide semiconductor (CMOS) image sensor chip two major classes.
Cmos image sensor is compared with traditional ccd sensor, have low-power consumption, low cost and with CMOS technology phase The features such as compatible, therefore have been more and more widely used.Present cmos image sensor has not only been applied to consumer electronics neck Domain, such as miniature digital camera (DSC), mobile phone camera, in video camera and digital single-lens reflex camera (DSLR), and in automotive electronics, Monitoring, the fields such as biotechnology and medicine are also widely used.
The pixel unit of cmos image sensor is that imaging sensor realizes photosensitive core devices, most common pixel list Member is the active pixel structure comprising a photodiode and four transistors.In these devices, photodiode is sense Light unit realizes collection and photoelectric conversion to light;Other MOS transistors are control units, main to realize to photoelectricity two Pole pipe is chosen, and resets, the control of signal amplification and reading.The number of MOS transistor, determines non-sense in one pixel unit Size shared by light region.Above-mentioned include the dot structure of four transistors is commonly referred to as 4T pixel unit.
Usually there are two types of shutter control modes in digital camera: i.e. mechanical shutter and electronic shutter.Mechanical shutter passes through The folding of the mechanical parts before cmos image sensor is mounted on to control the time for exposure;Electronic shutter by pixel unit when Sequence controls to change the time of integration, to achieve the purpose that control the time for exposure.Since mechanical shutter needs mechanical parts, can occupy The area of digital camera, therefore it is not suitable for portable digital camera.For video surveillance applications, due to be usually into Therefore row video acquisition generally controls the time for exposure using electronic shutter.Wherein electronic shutter is divided into two kinds again: i.e. roller shutter type With global exposure type.Time for exposure between every row of roller shutter type electronic shutter be it is inconsistent, hold when shooting high-speed object Easily cause motion blur phenomenon;And every a line of global exposure type electronic shutter is in same Time Exposure, then simultaneously by charge signal It is stored in the memory node of pixel unit, finally exports the signal of memory node line by line.Global exposure type electronic shutter due to All rows are exposed in the same time, so not will cause motion blur phenomenon.
It is right as cmos image sensor is more and more widely used in industrial, vehicle-mounted, road monitoring and high speed camera It is further increased in the demand for the imaging sensor that can capture high-speed moving object image.In order to monitor high-speed object, CMOS Imaging sensor needs the pixel unit (referred to as global pixel) using global exposure, and for depositing in global exposing pixels unit The memory node for storing up charge signal is a very important index for the spurious response of light source.In practical applications, according to Each pixel unit uses the number of transistor, and global exposing pixels unit has 4T, 5T, 6T, 8T and 12T etc..
As shown in Figure 1, the charge-storage node in existing 5T overall situation exposing pixels unit is exactly the junction capacity on 7 side of transfer tube 6.The parasitic photoresponse of memory node 6 refers to that memory node capacitor to the spurious response of incident light, for pixel unit, enters The light for being mapped to pixel unit surface cannot all focus on 2 surface of photodiode on substrate 1 due to reflect and scattering, There is portions incident light that may be entered on memory node 6 by multiple reflections, memory node 6 is under the irradiation of incident ray Photoelectric respone can be generated as photodiode 2, the charge generated on memory node 6 due to incident light will affect original It is stored in the voltage signal generated by photodiode 2 above, causes the distortion of signal.In order to reduce since storage saves Photoelectric respone caused by 6 light leakages of point, need to prevent using completely opaque metal screen layer 8 on memory node 6 into Penetrate the influence of light.
Compared with common CMOS process, the parasitic photoresponse of global pixel in order to prevent, conventional overall situation pixel unit is in layer Between one layer of metal shadowing layer 8 being additionally formed is equipped in dielectric layer 3.This layer of metal shadowing layer 8 is usually using lighttight tungsten, aluminium It is made with metal compound materials such as metals or tantalum nitride, titanium nitride such as copper.Since 8 large area of metal shadowing layer is covered with transmission Pipe 7 and memory node 6, in order to avoid the mutual crosstalk in the pixel course of work on transfer tube 7 and memory node 6, whole metals Masking layer 8 is finally grounded by metal interconnecting layer 4.
Metal shadowing layer is the special process in imaging sensor, needs to be developed on stand CMOS.Usually The metal shadowing layer forming method of global pixel is to be deposited before the formation of metal interconnecting layer 4 using one layer of additional tungsten And patterning process.But additional Metal deposition and etching, be easy to cause metal contamination, to influence pixel performance.And it is Achieve the effect that light-blocking, the area coverage of metal shadowing layer 8 is larger, this further increases the risks of metal contamination.Meanwhile it storing Node 6 needs to be connected to metal interconnecting layer 4 by contact hole 5, since memory node 6 is a constantly variation during the work time Dynamic Signal, therefore the contact hole 5 on memory node 6 cannot be connected with metal shadowing layer 8, it is necessary between keeping certain Away from.Thus light leakage gap is formed on memory node 6.There is no metal shadowing layer 8 or contact hole 5 in light leakage interstitial site Covering, therefore incident ray can pass through light leakage gap by the multiple reflections of metal interconnecting layer 4 and reach memory node 6, produce Raw parasitism photoresponse causes the distortion of global pixel storage signal and the decline of picture quality.
Summary of the invention
It is an object of the invention to overcome drawbacks described above of the existing technology, providing a kind of reduces the complete of parasitic photoresponse Office's pixel cell structure and forming method.
To achieve the above object, technical scheme is as follows:
A kind of global pixel cell structure reducing parasitic photoresponse, including the photodiode being set on substrate, transmission It manages, memory node, and the interlayer dielectric layer being covered on the substrate, metal interconnecting layer is equipped in the interlayer dielectric layer, And the metal interconnecting layer is located at the upper area between the photodiode of two pixel units of arbitrary neighborhood, the photoelectricity two Deep trench, the upper table of the bottom surface of the deep trench and the photodiode are additionally provided in the interlayer dielectric layer above pole pipe Face is isolated, and a compound light-blocking structure is covered on the side wall of the deep trench, is formed in the upper and lower ends of the deep trench Opening, and extend on the upper surface of the interlayer dielectric layer, by the metal in the interlayer dielectric layer below The completely insulated masking of interconnection layer.
Further, it is separated by between the bottom surface of the deep trench and the upper surface of the photodiode by an insulating layer From.
Further, be covered in the compound light-blocking structure in the zanjon groove sidewall lower end and the insulating layer Upper surface connects.
Further, photic zone is filled in the deep trench within the compound light-blocking structure.
Further, the compound light-blocking structure is using one of titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel Or a variety of formation, the photic zone are formed using organic material or inorganic material.
A kind of forming method for the global pixel cell structure reducing parasitic photoresponse, comprising the following steps:
One substrate is provided, uses conventional cmos image sensor process over the substrate, forms photodiode, transmission Pipe and memory node;
Full sheet deposits etching barrier layer materials on the substrate surface;
The lithography and etching on barrier layer is performed etching, the etching barrier layer materials of photodiode top position are only retained, Etching barrier layer is formed, and as insulating layer;
Full sheet deposits interlayer dielectric layer material on the substrate surface, forms interlayer dielectric layer;
Metal interconnecting layer is formed in the interlayer dielectric layer, and the metal interconnecting layer is made to be only located at arbitrary neighborhood two Upper area between the photodiode of pixel unit;
The lithography and etching for carrying out deep trench, the interlayer for being located at the deep trench above the photodiode are situated between In matter layer, and stop on the etching barrier layer;Wherein, the sectional dimension of the deep trench is less than or equal to the lower section quarter Lose the size on barrier layer;
The deposit that compound light-blocking structure material is carried out in the deep trench is covered in the compound light-blocking structure material On the bottom surface and side wall of the deep trench, and extend on the upper surface of the interlayer dielectric layer;
Lithography and etching is carried out to the compound light-blocking structure material, removal is located at described multiple in the zanjon groove bottom Light-blocking structure material is closed, the compound light-blocking knot in the zanjon groove sidewall and on the interlayer dielectric layer upper surface is retained Structure material forms compound light-blocking structure;Wherein, the compound light-blocking structure is by the gold in the interlayer dielectric layer below Belong to the completely insulated masking of interconnection layer;
The filling of light transmission layer material is carried out in the deep trench, it is rectangular at photic zone on the photodiode.
Further, the etching barrier layer materials are silicon nitride, silicon oxynitride or silicon carbide.
Further, the compound light-blocking structure material is one in titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel Kind is a variety of.
Further, the deposition thickness of the compound light-blocking structure material is between 10 angstroms to 10000 angstroms.
Further, the light transmission layer material is organic material or inorganic material.
It can be seen from the above technical proposal that the present invention is deep by being formed in interlayer dielectric layer square on the photodiode Groove, and the materials such as metal or metallic compound are filled in deep trench, forms lighttight metal layer, then by photoetching and Etching removes the metal layer in zanjon groove bottom above photodiode, only retains zanjon groove sidewall and inter-level dielectric layer surface Metal layer, formed surround entire metal interconnecting layer compound light-blocking structure, realize the complete shielding to incident ray, therefore The signal of memory node not will receive the influence of incident ray, ensure that signal in the storage capacitance of global exposing pixels unit Accuracy avoids the distortion of output signal.Also, it is different with the technique of routine large area covering tungsten, in the present invention It is isolated between metal layer and underlying photoelectric diode area in deep trench using etching barrier layer, and metal layer is each Only around a round figure is formed in the groove of pixel unit, global sections product is smaller, so that prevent metal contamination can Energy.Meanwhile light transmission reinforcing material is filled in deep trench to increase the sensitivity of pixel unit, further improve image sensing The performance of device.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of existing 5T overall situation exposing pixels unit.
Fig. 2 is a kind of domain knot of the global pixel cell structure of reduction parasitism photoresponse of a preferred embodiment of the present invention Structure schematic diagram.
Fig. 3 is a kind of global pixel cell structure schematic diagram of reduction parasitism photoresponse of a preferred embodiment of the present invention.
Fig. 4-Figure 11 is a kind of global pixel cell structure of reduction parasitism photoresponse of a preferred embodiment of the present invention The processing step schematic diagram of forming method.
Specific embodiment
With reference to the accompanying drawing, specific embodiments of the present invention will be described in further detail.
It should be noted that in following specific embodiments, when describing embodiments of the invention in detail, in order to clear Ground indicates structure of the invention in order to illustrate, spy does not draw to the structure in attached drawing according to general proportion, and has carried out part Amplification, deformation and simplified processing, therefore, should be avoided in this, as limitation of the invention to understand.
In specific embodiment of the invention below, Fig. 2-Fig. 3 is please referred to, Fig. 2 is a preferred embodiment of the present invention A kind of domain structure schematic diagram for the global pixel cell structure reducing parasitic photoresponse, Fig. 3 is a preferred embodiment of the present invention A kind of reduction parasitism photoresponse global pixel cell structure schematic diagram;Wherein, Fig. 3 shows side " A-B " of the domain along Fig. 2 To cross section structure figure.As shown in Fig. 2, the domain knot of the global pixel cell structure provided by the invention for reducing parasitic photoresponse Structure, compared with conventional global pixel, in order to avoid the light leakage gap between original metal screen layer and contact hole is to global pixel Memory node stores the influence (please referring to Fig. 1) of signal, top-level metallic interconnection layer 26 of the present invention in common metal interconnection layer Inner circle area (i.e. photodiode upper area) is respectively arranged with insulating layer (etching barrier layer) 31 and a circle zanjon groove layer 32. As shown in figure 3, the width of the top-level metallic interconnection layer 26 usually in pixel in metal interconnecting layer 21 is maximum, and deep trench 32 is necessary 21 certain distance of metal interconnecting layer is left, to avoid short circuit is formed between the metal in deep trench 32 and interconnection layer metal.Therefore, It is mutual between deep trench 32, insulating layer 31 and metal interconnecting layer 21 to illustrate with the top-level metallic interconnection layer 26 in Fig. 3 in Fig. 2 Relationship.
As shown in figure 3, a kind of global pixel cell structure of reduction parasitism photoresponse of the invention, it may include be set to substrate Photodiode 28 on 20, transfer tube 30, memory node 29, and the metal interconnecting layer 21 on substrate 20.Substrate 20 Semi-conductor silicon chip etc. can be used, and substrate 20 can be N-type or P-type silicon substrate.The invention is not limited thereto.
Interlayer dielectric layer 25 is covered on substrate 20;Metal interconnecting layer 21 is arranged in interlayer dielectric layer 25.Metal interconnection Layer 21 can be multilayered structure (it includes the top-level metallic interconnection layer 26 positioned at top layer).Also, in metal interconnecting layer 21 In upper area between two photodiodes 28 of two pixel units that interconnection metal is located at arbitrary neighborhood, so as in light The top of electric diode 28 forms optical channel.
Contact hole 27 can be used between memory node 29 and metal interconnecting layer 21 to be attached.
Deep trench 32 is additionally provided in the interlayer dielectric layer 25 of 28 top of photodiode;The bottom surface of deep trench 32 and photoelectricity two The upper surface of pole pipe 28 is isolated.Specifically, one can be passed through between the bottom surface of deep trench 32 and the upper surface of photodiode 28 A insulating layer 31 is isolated.Also, the lateral dimension (area) for illustrating insulating layer 31 should be greater than or be equal to 32 bottom surface of deep trench Lateral dimension (area), to realize being completely electrically isolated between deep trench 32 and photodiode 28.
Silicon nitride, silicon oxynitride or silicon carbide etc. can be used in insulating layer material.Also, insulating layer 31 can be one layer or more Layer structure.
Deep trench 32 is located at the inner circle area (please referring to Fig. 2), i.e. of the top-level metallic interconnection layer 26 in metal interconnecting layer 21 In the interlayer dielectric layer 25 of 28 upper area of photodiode.It is set in deep trench 32 and on the upper surface of interlayer dielectric layer 25 There is a compound light-blocking structure 23 and 22;Compound light-blocking structure 23 and 22 is covered on the side wall of deep trench 32, and to deep trench It extends over other than 32 on the upper surface of interlayer dielectric layer 25.
The upper of the lower end of the part 23 on 32 side wall of deep trench and insulating layer 31 is covered in compound light-blocking structure 23 and 22 Surface connects.In this way, compound light-blocking structure 23 and 22 just forms hatch frame in the upper and lower ends of deep trench 32, to reserve light The space in channel.
The metals such as titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel or metal can be used in compound light-blocking structure 23 and 22 One of compound-material or a variety of formation.I.e. compound light-blocking structure 23 and 22 uses lighttight metal-layer structure.
In this way, compound light-blocking structure 23 and 22 will just be disposed below the mutual of the metal interconnecting layer 21 in interlayer dielectric layer 25 Even metal completely obscured (encirclement) gets up, and is isolated with interconnection metal-insulator, to avoid the metal layer 23 in deep trench 32 and mutually Even short circuit is formed between metal.
The compound light-blocking structure 23 and 22 that entire metal interconnecting layer 21 is surrounded by being formed, realizes to the complete of incident ray Full-shield, therefore the signal of memory node 29 not will receive the influence of incident ray, avoid the distortion of output signal;Meanwhile The global sections product of 32 inner metal layer 23 of deep trench is smaller, can utmostly avoid metal contamination, make cmos image sensor most The image of high quality can be obtained eventually.
It can be filled out in the deep trench 32 being located within compound light-blocking structure 23 and 22 as a preferred embodiment Filled with photic zone 24, to increase the sensitivity of pixel unit, the performance of imaging sensor can be further promoted.
Photic zone 24 can be used with high light transmittance can organic material or inorganic material fill and to be formed.
Above structure of the invention can be applied to the various global pixels for needing storage capacitance such as 4T, 5T, 6T, 8T and 12T In structure, influence of the incident light to charge signal in memory node capacitor is avoided to realize.
Below by specific embodiment and attached drawing, to a kind of global pixel unit of reduction parasitism photoresponse of the invention The forming method of structure is described in detail.
Fig. 4-Figure 11 is please referred to, Fig. 4-Figure 11 is a kind of overall situation of reduction parasitism photoresponse of a preferred embodiment of the present invention The processing step schematic diagram of the forming method of pixel cell structure.A kind of global pixel list of reduction parasitism photoresponse of the invention The forming method of meta structure can be used for making a kind of global pixel unit for reduction parasitism photoresponse that above-mentioned such as Fig. 3 is shown Structure may particularly include following steps:
As shown in figure 4, providing a substrate 20, such as a N-type or P-type silicon substrate can be used.Firstly, can on substrate 20 Using conventional cmos image sensor process, the pixel units knots such as photodiode 28, transfer tube 30 and memory node 29 are formed Structure.
Secondly as shown in figure 5, full sheet deposits etching barrier layer materials 31 ' on 20 surface of substrate.Etching barrier layer materials 31 ' can be used the dielectric material of the etching high selectivity ratio such as silicon nitride, silicon oxynitride and silicon carbide.
Again as shown in fig. 6, performing etching the lithography and etching on barrier layer.Only retain 28 top of photodiode after etching Etching barrier layer materials 31 ' on position all remove the etching barrier layer materials 31 ' in other positions, form etching resistance Barrier 31.Also, using the etching barrier layer of formation 31 as between subsequent deep trench 32 and photodiode 28 to be formed Insulating layer 31.The lateral dimension (area) of etching barrier layer 31 should be greater than or equal to photodiode 28 lateral dimension (face Product).
Then as shown in fig. 7, full sheet deposits interlayer dielectric layer material, example on 20 surface of substrate for being formed with above structure Normal silica material such as can be used, form interlayer dielectric layer (rear track media layer) 25.And it is formed in interlayer dielectric layer 25 One to multiple layer metal interconnecting layer 21, such as the three-layer metal interconnection layer 21 of diagram, and formed and be used in interlayer dielectric layer 25 The contact hole 27 of metal interconnecting layer 21 and memory node 29 is connected, and metal interconnecting layer 21 is made to be only located at two pictures of arbitrary neighborhood Upper area between the photodiode 28 of plain unit.The optical channel region of 28 top of photodiode is exactly metal interconnecting layer The inner circle area of 21 top-level metallic interconnection layer 26.
Then as shown in figure 8, carrying out the lithography and etching of deep trench in interlayer dielectric layer 25.Make the depth to be formed when etching Groove 32 is located in the interlayer dielectric layer 25 of 28 top of photodiode, and deep trench 32 is etched through interlayer dielectric layer 25, stops On etching barrier layer 31.Wherein, it should ensure that the sectional dimension (area) for making deep trench 32 is less than or equal to lower section etch stopper The lateral dimension (area) of layer 31.
Then as shown in figure 9, carrying out metal filling processes, metal or metal compound material are carried out in deep trench 32 23 ' deposit, i.e., the deposit of the compound material of light-blocking structure 23 and 22.
Metal or metal compound material conventional in CMOS technology can be used in the compound material of light-blocking structure 23 and 22 It is formed, including one of metal materials such as titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel or several.Metal layer deposit Overall thickness can be between 10 angstroms to 10000 angstroms.
Final metal or metallic compound 23 ' realize filling to the bottom surface (bottom) of deep trench 32 and side wall, while rear Surface metal-layer 22 is formed above track media layer.
Then, as shown in Figure 10, lithography and etching is carried out to compound light-blocking structure material 23 ', i.e. progress photodiode 28 top metal layer etching, removal be located at 32 bottom surface of deep trench on metal layer material, retain 32 side wall of deep trench on and Metal layer material on 25 upper surface of interlayer dielectric layer, to be formed by 25 surface of trenched side-wall metal layer 23 and interlayer dielectric layer The compound light-blocking structure 23 and 22 that metal layer 22 forms.Compound light-blocking structure 23 and 22 is by the metal in lower section interlayer dielectric layer 25 Interconnection layer 21 is completely insulated to be covered up.
Finally, as shown in figure 11, the filling of light transmission layer material is carried out in deep trench 32, above photodiode 28 Photic zone 24 is formed in deep trench 32.That is a part of the composition of photic zone 24 optical channel.
The organic material or inorganic material that enhancing light transmission can be used form photic zone 24.
In conclusion the present invention, which passes through in interlayer dielectric layer square on the photodiode, forms deep trench, and in zanjon The materials such as metal or metallic compound are filled in slot, form lighttight metal layer, then pass through lithography and etching for photoelectricity two Metal layer above pole pipe in zanjon groove bottom removes, and only retains the metal layer of zanjon groove sidewall and inter-level dielectric layer surface, shape At the compound light-blocking structure for surrounding entire metal interconnecting layer, the complete shielding to incident ray is realized, therefore memory node Signal not will receive the influence of incident ray, ensure that the accuracy of signal in the storage capacitance of global exposing pixels unit, keeps away The distortion of output signal is exempted from.Also, it is different with the technique of routine large area covering tungsten, in the present invention in deep trench It is isolated between metal layer and underlying photoelectric diode area using etching barrier layer, and metal layer is in each pixel unit Only around a round figure is formed in groove, global sections product is smaller, to prevent the possibility of metal contamination.Meanwhile Light transmission reinforcing material is filled in deep trench to increase the sensitivity of pixel unit, further improves the performance of imaging sensor.
Above is merely a preferred embodiment of the present invention, the protection scope that embodiment is not intended to limit the invention, therefore It is all to change with equivalent structure made by specification and accompanying drawing content of the invention, it similarly should be included in protection of the invention In range.

Claims (10)

1. a kind of global pixel cell structure for reducing parasitic photoresponse, which is characterized in that including the photoelectricity two being set on substrate Pole pipe, transfer tube, memory node, and the interlayer dielectric layer being covered on the substrate are equipped with gold in the interlayer dielectric layer Belong to interconnection layer, and the metal interconnecting layer is located at the upper area between the photodiode of two pixel units of arbitrary neighborhood, Deep trench, the bottom surface of the deep trench and the photoelectricity two are additionally provided in the interlayer dielectric layer above the photodiode The upper surface of pole pipe is isolated, and a compound light-blocking structure is covered on the side wall of the deep trench, in the upper of the deep trench Lower both ends form opening, and extend on the upper surface of the interlayer dielectric layer, will be below in the interlayer dielectric layer The completely insulated masking of the metal interconnecting layer.
2. the global pixel cell structure according to claim 1 for reducing parasitic photoresponse, which is characterized in that the zanjon It is isolated between the bottom surface of slot and the upper surface of the photodiode by an insulating layer.
3. the global pixel cell structure according to claim 2 for reducing parasitic photoresponse, which is characterized in that be covered in institute The lower end for stating the compound light-blocking structure in zanjon groove sidewall connects with the upper surface of the insulating layer.
4. the global pixel cell structure according to claim 1 for reducing parasitic photoresponse, which is characterized in that described compound Photic zone is filled in the deep trench within light-blocking structure.
5. the global pixel cell structure according to claim 4 for reducing parasitic photoresponse, which is characterized in that described compound Light-blocking structure is used using one of titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel or a variety of formation, the photic zone Organic material or inorganic material are formed.
6. a kind of forming method for the global pixel cell structure for reducing parasitic photoresponse, which comprises the following steps:
One substrate is provided, over the substrate use conventional cmos image sensor process, formed photodiode, transfer tube and Memory node;
Full sheet deposits etching barrier layer materials on the substrate surface;
The lithography and etching on barrier layer is performed etching, the etching barrier layer materials of photodiode top position are only retained, is formed Etching barrier layer, and as insulating layer;
Full sheet deposits interlayer dielectric layer material on the substrate surface, forms interlayer dielectric layer;
Metal interconnecting layer is formed in the interlayer dielectric layer, and the metal interconnecting layer is made to be only located at two pixels of arbitrary neighborhood Upper area between the photodiode of unit;
The lithography and etching for carrying out deep trench, makes the deep trench be located at the interlayer dielectric layer above the photodiode In, and stop on the etching barrier layer;Wherein, the sectional dimension of the deep trench is less than or equal to the lower section etching resistance The size of barrier;
The deposit that compound light-blocking structure material is carried out in the deep trench is covered in the compound light-blocking structure material described On the bottom surface and side wall of deep trench, and extend on the upper surface of the interlayer dielectric layer;
Lithography and etching is carried out to the compound light-blocking structure material, removal is located at the compound gear in the zanjon groove bottom Photo structure material retains the compound light-blocking structure material in the zanjon groove sidewall and on the interlayer dielectric layer upper surface Material, forms compound light-blocking structure;Wherein, the compound light-blocking structure is mutual by the metal in the interlayer dielectric layer below The even completely insulated masking of layer;
The filling of light transmission layer material is carried out in the deep trench, it is rectangular at photic zone on the photodiode.
7. the forming method of the global pixel cell structure according to claim 6 for reducing parasitic photoresponse, feature exist In the etching barrier layer materials are silicon nitride, silicon oxynitride or silicon carbide.
8. the forming method of the global pixel cell structure according to claim 6 for reducing parasitic photoresponse, feature exist In the compound light-blocking structure material is one of titanium, titanium nitride, tantalum nitride, tungsten, aluminium, copper, cobalt and nickel or a variety of.
9. the forming method of the global pixel cell structure of the parasitic photoresponse of the reduction according to claim 6 or 8, feature It is, the deposition thickness of the compound light-blocking structure material is between 10 angstroms to 10000 angstroms.
10. the forming method of the global pixel cell structure according to claim 6 for reducing parasitic photoresponse, feature exist In the light transmission layer material is organic material or inorganic material.
CN201910560970.XA 2019-06-26 2019-06-26 A kind of global pixel cell structure and forming method reducing parasitic photoresponse Pending CN110299374A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910560970.XA CN110299374A (en) 2019-06-26 2019-06-26 A kind of global pixel cell structure and forming method reducing parasitic photoresponse

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910560970.XA CN110299374A (en) 2019-06-26 2019-06-26 A kind of global pixel cell structure and forming method reducing parasitic photoresponse

Publications (1)

Publication Number Publication Date
CN110299374A true CN110299374A (en) 2019-10-01

Family

ID=68028957

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910560970.XA Pending CN110299374A (en) 2019-06-26 2019-06-26 A kind of global pixel cell structure and forming method reducing parasitic photoresponse

Country Status (1)

Country Link
CN (1) CN110299374A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110429091A (en) * 2019-07-29 2019-11-08 上海集成电路研发中心有限公司 A kind of global pixel structure and forming method with light-blocking structure
CN112768482A (en) * 2021-01-20 2021-05-07 联合微电子中心有限责任公司 Back-illuminated global shutter pixel structure and manufacturing method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070052053A1 (en) * 2005-08-29 2007-03-08 Chiu-Te Lee Complementary metal oxide semiconductor image sensor and fabricating method thereof
CN102386193A (en) * 2010-08-30 2012-03-21 索尼公司 Solid-state imaging device and electronic apparatus
CN102468314A (en) * 2010-11-08 2012-05-23 索尼公司 Solid-state imaging device and manufacturing method thereof, and electronic apparatus

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070052053A1 (en) * 2005-08-29 2007-03-08 Chiu-Te Lee Complementary metal oxide semiconductor image sensor and fabricating method thereof
CN102386193A (en) * 2010-08-30 2012-03-21 索尼公司 Solid-state imaging device and electronic apparatus
CN102468314A (en) * 2010-11-08 2012-05-23 索尼公司 Solid-state imaging device and manufacturing method thereof, and electronic apparatus

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110429091A (en) * 2019-07-29 2019-11-08 上海集成电路研发中心有限公司 A kind of global pixel structure and forming method with light-blocking structure
CN110429091B (en) * 2019-07-29 2023-03-03 上海集成电路研发中心有限公司 Global pixel structure with light blocking structure and forming method
CN112768482A (en) * 2021-01-20 2021-05-07 联合微电子中心有限责任公司 Back-illuminated global shutter pixel structure and manufacturing method thereof
CN112768482B (en) * 2021-01-20 2023-03-24 联合微电子中心有限责任公司 Back-illuminated global shutter pixel structure and manufacturing method thereof

Similar Documents

Publication Publication Date Title
US9735196B2 (en) Photosensitive capacitor pixel for image sensor
CN108598100B (en) Global pixel structure for reducing light leakage of storage node and manufacturing method
US9978786B2 (en) Solid-state image-capturing device and production method thereof, and electronic appliance
US7880168B2 (en) Method and apparatus providing light traps for optical crosstalk reduction
JP6833597B2 (en) Solid-state image sensor
CN103258829A (en) Solid-state imaging device, image sensor, method of manufacturing image sensor, and electronic apparatus
CN107240593B (en) Stacked global exposure pixel unit structure and forming method thereof
CN106098714B (en) Back-illuminated type overall situation exposing pixels cellular construction and manufacturing method
TWI823157B (en) Method for forming led flickering reduction (lfr) film for hdr image sensor and image sensor having same
KR102651181B1 (en) Imaging elements and imaging devices
KR20080050434A (en) Solid-state imager and formation method using anti-reflective film for optical crosstalk reduction
TWI757894B (en) Image sensor and method of forming the same
CN110429091A (en) A kind of global pixel structure and forming method with light-blocking structure
CN107195648B (en) Low-noise high-sensitivity global pixel unit structure and forming method thereof
CN113130522B (en) Image sensor with partially encapsulated attenuation layer
CN108847418A (en) A kind of image sensor structure and forming method enhancing near-infrared quantum efficiency
CN110299374A (en) A kind of global pixel cell structure and forming method reducing parasitic photoresponse
JP2013168546A (en) Image sensor, method of manufacturing the same, and electronic apparatus
CN105762160B (en) Back-illuminated global pixel unit structure and preparation method thereof
CN112117291B (en) Backside-illuminated charge domain global shutter image sensor and manufacturing method thereof
CN109616487A (en) Back side illumination image sensor and its manufacturing method
CN108520885A (en) Imaging sensor and forming method thereof
CN109148497B (en) Global pixel structure for preventing parasitic light response and forming method
CN104282628B (en) A kind of preparation method of cmos image sensor overall situation pixel storage capacitance
CN105552097B (en) Global exposing pixels unit, capacitance structure and preparation method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191001