CN110283520A - A kind of high scratch resistance UV of high rigidity mute clear finish and preparation method thereof entirely applied to the transfer of ABS water - Google Patents
A kind of high scratch resistance UV of high rigidity mute clear finish and preparation method thereof entirely applied to the transfer of ABS water Download PDFInfo
- Publication number
- CN110283520A CN110283520A CN201910541619.6A CN201910541619A CN110283520A CN 110283520 A CN110283520 A CN 110283520A CN 201910541619 A CN201910541619 A CN 201910541619A CN 110283520 A CN110283520 A CN 110283520A
- Authority
- CN
- China
- Prior art keywords
- scratch resistance
- transfer
- agent
- high rigidity
- clear finish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to technical field of coatings, more particularly to a kind of high scratch resistance UV of high rigidity mute clear finish and preparation method thereof entirely applied to the transfer of ABS water, this is applied to the high scratch resistance UV of high rigidity that ABS water transfers, and mute clear finish is by amino modified epoxy acrylate entirely, urethane acrylate, acetylbutyrylcellulose, monomer, flatting silica, photoinitiator, defoaming agent, dispersing agent, levelling agent, wetting agent and anti-settling agent are made, this is applied to the high scratch resistance UV of high rigidity that ABS water transfers, and mute clear finish enables to different workpieces color uniformity entirely, and gloss is stablized, and avoid coating that flooding phenomenon occurs in use, and the hardness of the paint film after solidifying is good, has the advantages that high scratch resistance.This is applied to the preparation method of the high scratch resistance UV of the high rigidity mute clear finish entirely of ABS water transfer, has simple process, and production cost is low, and the characteristics of can be suitable for large-scale production.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of high scratch resistance UV of high rigidity applied to the transfer of ABS water
Complete mute clear finish and preparation method thereof.
Background technique
UV paint is photocureable coating, it is current using more extensive coating, and solid content height can be energy saving, raw
It is fast to produce speed, pollution is few, by the irradiation of intensive ultraviolet light can instantaneous solidification form a film, can be continuous by using mechanized operation
Large-scale production, coating surface for a long time Chang Xin, so being widely used in terms of cabinet family property.
Existing bottle is usually to be made of glass material, and bottle during storage is placed directly on table top, slightly
Have and be easy for being knocked down and being crushed accidentally, in addition, the shape of bottle be all it is unified, put during usually with ambient enviroment not
Coordinate.When so many producers can provide a kind of wine bottle seat, the stability of bottle storage can be increased, and bottle storage can be increased
Aesthetic feeling.Currently, many wine bottle seats are to carry out water transfer processing again with ABS injection molding.And water transfer printing film easily scratches, intolerant to molten
Agent, not resistant.Coast of paint film is sprayed above can protect substrate, also can increase decorative effect.
During spraying application, since the distinct device of different clients in work progress causes paint film state not
Together, the difference of coating weight, paint film form and aspect are different, and coating cyclic causes viscosity of the coating in solidification energy difference and work progress
Variation, the glossiness of finishing coat can be had an impact, to cause occur the unstable phenomenon of product in same batch, be influenced
The final effect of coating.
In order to which the unstable phenomenon of this gloss is alleviated or avoided, needs to select the uniform flatting silica of particle diameter distribution, be come with this
The extinction effect for ensuring finishing coat avoids surface of the paint film from the disadvantages such as particle, out-of-flatness occur.However, finishing coat made from the prior art
After coating application, different workpieces uneven color is consistent, and gloss is not sufficiently stable, and coating is easy to happen floating in use
Color phenomenon.In addition, the hardness of the paint film after solidifying is not good enough, it is easy to be scratched, and then product quality.
Summary of the invention
It is hard it is an object of the present invention in view of the deficiencies of the prior art, providing a kind of height applied to the transfer of ABS water
High scratch resistance UV mute clear finish entirely is spent, should being applied to the high scratch resistance UV of high rigidity that ABS water transfers, mute clear finish enables to entirely
Different workpieces color uniformity, and gloss is stablized, and avoids coating that flooding phenomenon occurs in use, and after solidification
Paint film hardness it is good, have the advantages that high scratch resistance.
The second object of the present invention is in view of the deficiencies of the prior art, to provide a kind of applied to the high hard of ABS water transfer
Spend the preparation method of high scratch resistance UV mute clear finish entirely.
One of to achieve the goals above, the present invention adopts the following technical scheme:
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water is provided, it is by following weight hundred
Divide and be made than raw material:
Preferably, described a kind of high scratch resistance UV of high rigidity applied to the transfer of ABS water mute clear finish entirely, it be by with
Lower weight percent raw material is made:
More preferably, described a kind of high scratch resistance UV of high rigidity applied to the transfer of ABS water mute clear finish entirely, it is
It is made of following weight percent raw material:
The urethane acrylate is six degree of functionality aromatic urethane acrylates；
The monomer is contracting tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, 1,6 hexylene glycol, two propylene
One of acid esters or hydroxyethyl methacrylate or any two or more composition；
The photoinitiator be 1- hydroxyl-cyclohexyl-phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone or 2,
One of 4,6 (trimethylbenzoyl) diphenyl phosphine oxides or any two or more composition.
The defoaming agent is acrylic acid defoaming agent；
The dispersing agent is one of fatty acid dispersing agent, aliphatic amide type dispersing agent or esters dispersing agent or appoints
It anticipates two or more compositions；
The levelling agent is the composition of one or both of acrylic acid levelling agent or alkyl-modified polysiloxanes；
The wetting agent is acrylic compounds wetting agent.
To achieve the goals above two, the present invention adopts the following technical scheme:
A kind of preparation method of the high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water is provided, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent, it is then certain with the dispersion of certain revolving speed
Time obtains the first mixture；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
Dispersion certain time is carried out with certain revolving speed afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse certain time with certain revolving speed, obtain the high scratch resistance of high rigidity applied to the transfer of ABS water
UV mute clear finish entirely.
In above-mentioned technical proposal, in the step 1, then with the revolving speed of 900rpm~1100rpm dispersion 20min~
40min obtains the first mixture.
In above-mentioned technical proposal, in the step 2, then with the revolving speed of 900rpm~1100rpm dispersion 20min~
40min obtains the second mixture.
In above-mentioned technical proposal, in the step 3, then with the revolving speed of 400rpm~600rpm dispersion 12min~
25min obtains the high scratch resistance UV of high rigidity applied to the transfer of ABS water mute clear finish entirely.
Compared with prior art, beneficial effect is the present invention:
(1) a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water provided by the invention, is by amine
Base modified epoxy acrylic ester, urethane acrylate, acetylbutyrylcellulose, monomer, flatting silica, photoinitiator, defoaming agent,
Dispersing agent, levelling agent, wetting agent and anti-settling agent are made, wherein pass through amino modified epoxy acrylate and polyurethane acroleic acid
Ester has selected the dispersing agent good with film-forming resin, monomer compatibility as film-forming resin, so that flatting silica disperses in coating
Uniformly, construction cyclic process in be not in flatting silica degree variation, and avoid surface of the paint film occur part
Significantly gloss difference and the phenomenon that shallow nebulous gloss difference and uneven color.In addition, due to having selected compatibility
Fabulous acetylbutyrylcellulose, can be conducive to pigment, flatting silica aligns, so that after coating application, different workpieces face
Color uniformity, and gloss is stablized, and is avoided that flooding phenomenon occurs in use for coating.In addition, passing through amino modified
The cooperation of epoxy acrylate, urethane acrylate and monomer enables to the hardness of the paint film after solidifying that can permanently reach
To 2H, so that paint film is avoided that easily scuffing, problem easy to damage.Therefore, the high rigidity highly resistance of ABS water transfer should be applied to
Scratching UV, mute clear finish enables to different workpieces color uniformity entirely, and gloss is stablized, and avoids coating in use process
Middle generation flooding phenomenon, and the hardness of the paint film after solidifying is good, has the advantages that high scratch resistance.
(2) a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water provided by the invention, is preparing
When water transfer article, whole production efficiency can be improved, and can protect and produce with the surface picture and text of decorative water transfer article, promotion
Product quality, and overall appearance effect is good, being capable of the daily pollution such as anti-oil stains, sweat, moreover it is possible to solvent resistant, and the hardness of product,
Resistance to scraping and feel are splendid.
(3) preparation of a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water provided by the invention
Method has simple process, and production cost is low, and can be suitable for the characteristics of being mass produced.
Specific embodiment
In order to which the technical problems, technical solutions and beneficial effects solved by the present invention is more clearly understood, below in conjunction with
Embodiment, the present invention will be described in further detail.It should be appreciated that specific embodiment described herein is only to explain this
Invention, is not intended to limit the present invention.
Embodiment 1.
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it is by following weight percent
Raw material is made:
Wherein, urethane acrylate is six degree of functionality aromatic urethane acrylates.
In the present embodiment, monomer is contracting tripropylene glycol diacrylate.
In the present embodiment, photoinitiator is 1- hydroxyl-cyclohexyl-phenyl ketone.
Wherein, defoaming agent is acrylic acid defoaming agent.
In the present embodiment, dispersing agent is fatty acid dispersing agent.
In the present embodiment, levelling agent is acrylic acid levelling agent.
Wherein, wetting agent is acrylic compounds wetting agent.
A kind of preparation method of the above-mentioned high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent, then with the revolving speed of 1000rpm point
30min is dissipated, the first mixture is obtained；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
30min is dispersed with the revolving speed of 1000rpm afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse 18min with the revolving speed of 500rpm, it is anti-zoned to obtain the high rigidity height applied to the transfer of ABS water
Hurt UV mute clear finish entirely.
Embodiment 2.
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it is by following weight percent
Raw material is made:
Wherein, urethane acrylate is six degree of functionality aromatic urethane acrylates.
In the present embodiment, monomer is trimethylolpropane trimethacrylate.
In the present embodiment, photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- acetone.
Wherein, defoaming agent is acrylic acid defoaming agent.
In the present embodiment, dispersing agent is aliphatic amide type dispersing agent.
In the present embodiment, levelling agent is alkyl-modified polysiloxanes.
Wherein, wetting agent is acrylic compounds wetting agent.
A kind of preparation method of the above-mentioned high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Then acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent are dispersed with the revolving speed of 900rpm
40min obtains the first mixture；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
40min is dispersed with the revolving speed of 900rpm afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse 25min with the revolving speed of 400rpm, it is anti-zoned to obtain the high rigidity height applied to the transfer of ABS water
Hurt UV mute clear finish entirely.
Embodiment 3.
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it is by following weight percent
Raw material is made:
Wherein, urethane acrylate is six degree of functionality aromatic urethane acrylates.
In the present embodiment, 1,6 hexanediyl ester of monomer.
In the present embodiment, photoinitiator 2,4,6 (trimethylbenzoyl) diphenyl phosphine oxide.
Wherein, defoaming agent is acrylic acid defoaming agent.
In the present embodiment, dispersing agent is esters dispersing agent.
In the present embodiment, levelling agent is the composition of acrylic acid levelling agent and alkyl-modified polysiloxanes.
Wherein, wetting agent is acrylic compounds wetting agent.
A kind of preparation method of the above-mentioned high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent, then with the revolving speed of 1100rpm point
20min is dissipated, the first mixture is obtained；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
20min is dispersed with the revolving speed of 1100rpm afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse 12min with the revolving speed of 600rpm, it is anti-zoned to obtain the high rigidity height applied to the transfer of ABS water
Hurt UV mute clear finish entirely.
Embodiment 4.
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it is by following weight percent
Raw material is made:
Wherein, urethane acrylate is six degree of functionality aromatic urethane acrylates.
In the present embodiment, the composition of monomer 1,6 hexanediyl ester and hydroxyethyl methacrylate.
In the present embodiment, photoinitiator is 2- hydroxy-2-methyl -1- phenyl -1- acetone and 2,4,6 (trimethylbenzoyls
Base) diphenyl phosphine oxide composition.
Wherein, defoaming agent is acrylic acid defoaming agent.
In the present embodiment, dispersing agent is the composition of aliphatic amide type dispersing agent and esters dispersing agent.
In the present embodiment, levelling agent is the composition of acrylic acid levelling agent and alkyl-modified polysiloxanes.
Wherein, wetting agent is acrylic compounds wetting agent.
A kind of preparation method of the above-mentioned high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Then acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent are dispersed with the revolving speed of 950rpm
35min obtains the first mixture；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
35min is dispersed with the revolving speed of 950rpm afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse 22min with the revolving speed of 450rpm, it is anti-zoned to obtain the high rigidity height applied to the transfer of ABS water
Hurt UV mute clear finish entirely.
Embodiment 5.
A kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it is by following weight percent
Raw material is made:
Wherein, urethane acrylate is six degree of functionality aromatic urethane acrylates.
In the present embodiment, monomer be contracting tripropylene glycol diacrylate, trimethylolpropane trimethacrylate and 1,6 oneself two
The composition of alcohol diacrylate.
In the present embodiment, photoinitiator is 1- hydroxyl-cyclohexyl-phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- third
The composition of ketone and 2,4,6 (trimethylbenzoyl) diphenyl phosphine oxides.
Wherein, defoaming agent is acrylic acid defoaming agent.
In the present embodiment, dispersing agent is the group of fatty acid dispersing agent, aliphatic amide type dispersing agent and esters dispersing agent
Close object.
In the present embodiment, levelling agent is acrylic acid levelling agent.
Wherein, wetting agent is acrylic compounds wetting agent.
A kind of preparation method of the above-mentioned high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water, it includes
Following steps:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane of formula ratio being added in a reservoir
Acrylate, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent, then with the revolving speed of 1050rpm point
25min is dissipated, the first mixture is obtained；
Step 2: the second mixture of preparation: the flatting silica of formula ratio being added into the first mixture that step 1 obtains, so
25min is dispersed with the revolving speed of 1050rpm afterwards, obtains the second mixture；
Final products are made in step 3: levelling agent, the wetting of formula ratio being added into the second mixture that step 2 obtains
Then agent and monomer disperse 15min with the revolving speed of 550rpm, it is anti-zoned to obtain the high rigidity height applied to the transfer of ABS water
Hurt UV mute clear finish entirely.
Performance test:
To the complete mute clear face the high scratch resistance UV of high rigidity for being applied to the transfer of ABS water made from above-described embodiment 1 to embodiment 5
Paint is tested for the property, and specific test result refers to table 1.
Table 1 is applied to the performance test table of the high scratch resistance UV of the high rigidity mute clear finish entirely of ABS water transfer
As it can be seen that from the test data of table 1 it is found that the high rigidity high scratch resistance produced by the present invention applied to the transfer of ABS water
Mute clear finish has good appearance characteristics to UV entirely, and the performances such as richness, adhesive force, hardness, scratch resistance, resistance to soiling are excellent
It is different.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (9)
1. a kind of, resist the high scratch resistance UV of the high rigidity mute clear finish entirely applied to the transfer of ABS water, it is characterised in that: it be by with
Lower weight percent raw material is made:
2. a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 1, special
Sign is: it is made of following weight percent raw material:
3. a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 1, special
Sign is: it is made of following weight percent raw material:
4. a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 1, special
Sign is: the urethane acrylate is six degree of functionality aromatic urethane acrylates；
The monomer is contracting tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, 1,6 hexanediyl esters
Or one of hydroxyethyl methacrylate or any two or more composition；
The photoinitiator is 1- hydroxyl-cyclohexyl-phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone or 2,4,6
One of (trimethylbenzoyl) diphenyl phosphine oxide or any two or more composition.
5. a kind of high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 1, special
Sign is: the defoaming agent is acrylic acid defoaming agent；
The dispersing agent is one of fatty acid dispersing agent, aliphatic amide type dispersing agent or esters dispersing agent or any two
Kind or more composition；
The levelling agent is the composition of one or both of acrylic acid levelling agent or alkyl-modified polysiloxanes；
The wetting agent is acrylic compounds wetting agent.
6. a kind of complete mute clear face high scratch resistance UV of high rigidity applied to the transfer of ABS water described in claim 1 to 5 any one
The preparation method of paint, it is characterised in that: it the following steps are included:
Step 1: the first mixture of preparation: amino modified epoxy acrylate, the polyurethane propylene of formula ratio being added in a reservoir
Acid esters, acetylbutyrylcellulose, defoaming agent, photoinitiator, anti-settling agent and dispersing agent, then with one timing of certain revolving speed dispersion
Between, obtain the first mixture；
Step 2: preparation the second mixture: into the first mixture that step 1 obtains addition formula ratio flatting silica, then with
Certain revolving speed carries out dispersion certain time, obtains the second mixture；
Final products are made in step 3: into the second mixture that step 2 obtains the addition levelling agent of formula ratio, wetting agent and
Then monomer disperses certain time with certain revolving speed, it is complete to obtain the high scratch resistance UV of high rigidity applied to the transfer of ABS water
Mute clear finish.
7. a kind of system of the high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 6
Preparation Method, it is characterised in that: in the step 1,20min~40min is then dispersed with the revolving speed of 900rpm~1100rpm, is obtained
To the first mixture.
8. a kind of system of the high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 6
Preparation Method, it is characterised in that: in the step 2,20min~40min is then dispersed with the revolving speed of 900rpm~1100rpm, is obtained
To the second mixture.
9. a kind of system of the high scratch resistance UV of high rigidity mute clear finish entirely applied to the transfer of ABS water according to claim 6
Preparation Method, it is characterised in that: in the step 3,12min~25min is then dispersed with the revolving speed of 400rpm~600rpm, i.e.,
The high scratch resistance UV of high rigidity applied to the transfer of ABS water mute clear finish entirely is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910541619.6A CN110283520B (en) | 2019-06-21 | 2019-06-21 | High-hardness high-scratch-resistance UV full-matte top-coat paint applied to ABS water transfer printing and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910541619.6A CN110283520B (en) | 2019-06-21 | 2019-06-21 | High-hardness high-scratch-resistance UV full-matte top-coat paint applied to ABS water transfer printing and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110283520A true CN110283520A (en) | 2019-09-27 |
| CN110283520B CN110283520B (en) | 2021-05-07 |
Family
ID=68004782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910541619.6A Active CN110283520B (en) | 2019-06-21 | 2019-06-21 | High-hardness high-scratch-resistance UV full-matte top-coat paint applied to ABS water transfer printing and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110283520B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
| CN103589324A (en) * | 2013-11-12 | 2014-02-19 | 惠州市长润发涂料有限公司 | UV (ultraviolet) anti-scratch matte finishing paint |
| CN104804620A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Weather-resistant UV curing coating |
| CN108192495A (en) * | 2017-12-15 | 2018-06-22 | 北京钢研新冶工程设计有限公司 | A kind of UV nano metals coating |
-
2019
- 2019-06-21 CN CN201910541619.6A patent/CN110283520B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102229779A (en) * | 2011-06-20 | 2011-11-02 | 上虞市佑谦特种材料有限公司 | UV (Ultraviolent) deglossing paint and preparation method thereof |
| CN103589324A (en) * | 2013-11-12 | 2014-02-19 | 惠州市长润发涂料有限公司 | UV (ultraviolet) anti-scratch matte finishing paint |
| CN104804620A (en) * | 2015-04-23 | 2015-07-29 | 黎司华 | Weather-resistant UV curing coating |
| CN108192495A (en) * | 2017-12-15 | 2018-06-22 | 北京钢研新冶工程设计有限公司 | A kind of UV nano metals coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110283520B (en) | 2021-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105968253B (en) | It is a kind of water-based from mat acrylic emulsion and preparation method and application | |
| CN103031051A (en) | Preparation method of scratch-resistant bicomponent polyurethane carpentry matt varnish | |
| CN104387945A (en) | Odorless staining-resistant anti-yellowing UV coated matt finish paint coating, and preparation method and construction technology thereof | |
| CN100588691C (en) | Coating for UV cured plastic and use | |
| CN102876143A (en) | Marble paint and preparation method thereof | |
| CN103602224A (en) | White solvent-free finish paint as well as preparation method and construction process of white solvent-free finish paint | |
| CN103589324B (en) | The anti-scratch matte varnish of a kind of UV | |
| CN103937401A (en) | Preparation method of scratch resistant double-component polyurethane woodenware glossy vanish | |
| CN111484798B (en) | Matte UV coating for white board film and preparation method thereof | |
| CN107987632A (en) | A kind of aqueous double-component matte varnish and its production technology | |
| CN104046225A (en) | High-definition silky finish and preparation method thereof | |
| CN109486407A (en) | A kind of dedicated polyurethane paint of Recombinant Wood and preparation method thereof | |
| CN104073040A (en) | UV-cured white curtaining paint and preparation method thereof | |
| CN102146264A (en) | Low-gloss polishing agent composition | |
| CN110028820A (en) | A kind of water-based gloss oil and preparation method thereof suitable for the online coding of high speed | |
| CN103937400B (en) | A kind of preparation method of scratch resistance anti-yellowing polyurethane woodenware Brilliant white paint | |
| CN102732117B (en) | Multifunctional water-base high light emulsion paint suitable for various substrates | |
| CN103436156A (en) | Modified polyurethane scratch-resistant matte transparent finish paint applicable to American coating process, and preparation method of transparent finish paint | |
| CN106221373B (en) | A kind of high-weatherability glass ink and preparation method thereof, application method | |
| CN110283520A (en) | A kind of high scratch resistance UV of high rigidity mute clear finish and preparation method thereof entirely applied to the transfer of ABS water | |
| CN104774543B (en) | Imitation leather paint | |
| CN108774416A (en) | A kind of ceramics soil resistance buffing wax and preparation method thereof | |
| US5122395A (en) | Methods for the production of faux finishes | |
| CN110406287A (en) | The highlighted color face oil glazing process of one kind | |
| CN110240858A (en) | A kind of height energetic interaction curable water-borne UV woodenware lacquer and preparation method thereof and construction technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |