CN110278731A - A kind of salt-soda soil electrolysis quick improvement device and method - Google Patents

A kind of salt-soda soil electrolysis quick improvement device and method Download PDF

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Publication number
CN110278731A
CN110278731A CN201910729192.2A CN201910729192A CN110278731A CN 110278731 A CN110278731 A CN 110278731A CN 201910729192 A CN201910729192 A CN 201910729192A CN 110278731 A CN110278731 A CN 110278731A
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salt
piece
soda soil
electrolysed
catholyte
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CN201910729192.2A
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谭海龙
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B77/00Machines for lifting and treating soil

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses a kind of salt-soda soils to be electrolysed quick improvement device and method, which includes anode electrolysis piece, catholyte piece, the switch being connected between catholyte piece and anode electrolysis piece and power supply unit;It further include being handled for the draw-out device of aqueous solution, the aqueous solution extracted to draw-out device at groove where extracting anode electrode film, catholyte piece to obtain the processing unit of transformation substance.Using the present apparatus carry out alkaline land improving, it is at low cost, per acre only need 300 yuan, only need to once improve and can succeed, improved again without secondary, environmental protection and have secondary income, it is pollution-free.

Description

A kind of salt-soda soil electrolysis quick improvement device and method
Technical field
The present invention relates to alkaline land improving field, more particularly to a kind of salt-soda soil electrolysis quick improvement device and Method.
Background technique
Salt-soda soil whole world ranking at most preceding 10 countries, Chinese salt-soda soil quantity is first 3, and Chinese salt-soda soil is about more than 500000000 mu, account for cultivated area 10%.Minerals in alkaline land soil are mainly: sodium sulphate Na2SO290% is accounted for, sodium chloride Nacl is accounted for 6%, the Alkaline minerals such as other magnesium chlorides, calcium chloride account for 4%.All kinds of crops, forest, herbaceous plant etc. are 6.5 1 7.5 neutral in PH Well-grown in soil.Salinity in soil is nutriment necessary to plant growth, the pH value in salt-soda soil generally 9 one 11, Its salt content is more than 0.1%, and all kinds of plants can not grow.It wants all kinds of plants to reach 6.5 1 7.5 neutral soil of pH value, is most suitable for each The growth of class plant, it is necessary to by salt-soda soil drop alkali improvement.
There are many country's saline and alkali land improvement method at present, for example physically improved, chemical modifying, biological modification, water conservancy improvement, but It is, not exclusively success, the reasons are as follows: (1) improves salt-soda soil and needed for 3 one 5 years.(2) it needs to repeat to change for many years It is good.(3) improvement salt-soda soil is costly, and 3 one 5 years accumulative expenses are 800 1 1000 yuans per acre.(4) salt-soda soil is improved Effect is poor, and ideal indicator requirement is not achieved.(5) relevant device and reagent of improvement salt-soda soil investment cannot be reused.Therefore, Existing saline and alkali land improvement method is difficult to popularize.
Summary of the invention
In order to solve the above-mentioned technical problem the present invention provides a kind of salt-soda soil electrolysis quick improvement device and method.
The present invention is achieved through the following technical solutions:
A kind of salt-soda soil is electrolysed quick improvement device, including anode electrolysis piece, catholyte piece, is connected on catholyte piece and sun Switch and power supply unit between the electrolytic strip of pole;
It further include for the draw-out device of aqueous solution at groove where extracting anode electrode film, catholyte piece, to draw-out device The aqueous solution of extraction is handled to obtain the processing unit of transformation substance.
Inventor has found that carrying out improvement to salt-soda soil using electrolysis mode is a kind of best mode, drops alkali in long-term work Speed is fast, and existing alkaline land improving needed for 3 one 5 years, only needs 200 to alkaline land improving using electrolysis unit of the invention One 300 hours.Anode electrolysis piece, catholyte piece are individually positioned in the different irrigation canals and ditches in salt-soda soil, anode electrolysis piece, cathode electricity Solve piece, switch, power supply unit, the water in salt-soda soil and constitute a closed circuit, groove where positive electron passes through anode electrolysis piece and Salt-soda soil interlayer where catholyte piece between groove, flows to cathode.Sodium sulphate, sodium chloride mineral ion quilt in salt-soda soil Reduction and oxygenolysis go out sulfuric acid and sodium hydroxide, while oxygen and chlorine discharge are generated in anode slot solution.After the completion of electrolysis, It is dilute sulfuric acid, sodium hydroxide respectively at anode electrolysis piece, catholyte piece, processing unit further locates above-mentioned aqueous solution Reason, is converted into enabled production, further improves income.Alkaline land improving is carried out using the present apparatus, it is at low cost, per acre only As long as needing 300 yuan take and once improve successfully, improved again without secondary, it is environmentally friendly and have secondary income, it is pollution-free.
Preferably, the draw-out device includes acid-proof suction pump and alkaline suction pump, the processing unit includes successively The first filtering ponds, reaction tank, drying device and the material adding mouth being connected on reaction tank, the processing unit, which is arranged, further includes The second filtering ponds, concentrator, the drying equipment set gradually.
Preferably, the power supply unit includes using power grid alternating current, stand-by generator, wind-driven generator, solar energy At least one of volt power generation power supply unit.
Preferably, the anode electrolysis piece, catholyte piece are fixed on floating material or are fixed on bracket.
A kind of salt-soda soil electrolysis quick improvement method, comprising the following steps:
A, two grooves are excavated in salt-soda soil region;
B, water is occupied in salt-soda soil and is impregnated at least 24 hours;
C, in the trench by the anode electrolysis piece of above-mentioned salt-soda soil electrolysis quick improvement device, the installation of catholyte piece, opening is opened Put capable electrolysis into;
D, after the completion of electrolysis, the solution of two grooves is handled respectively using draw-out device and processing unit.
Compared with prior art, the present invention having the following advantages and benefits:
1, alkaline land improving is carried out using the present apparatus, it is at low cost, 300 yuan are only needed per acre, only need to once be improved and can be succeeded, Need not it is secondary improve again, environmental protection and have secondary income, it is pollution-free.
2, salt-soda soil is improved using the present apparatus, byproduct can be made, turn waste into wealth, realize increment.
Detailed description of the invention
Attached drawing described herein is used to provide to further understand the embodiment of the present invention, constitutes one of the application Point, do not constitute the restriction to the embodiment of the present invention.
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is partial sectional view of the invention.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer, below with reference to embodiment and attached drawing, to this Invention is described in further detail, and exemplary embodiment of the invention and its explanation for explaining only the invention, are not made For limitation of the invention.
Embodiment 1
A kind of salt-soda soil as shown in Figure 1, 2 is electrolysed quick improvement device, including anode electrolysis piece 6, catholyte piece 7, series connection Switch and power supply unit between catholyte piece and anode electrolysis piece;In use, being excavated in the salt-soda soil region that need to be improved Two grooves, anode electrolysis piece 6, catholyte piece 7 are respectively placed in two grooves, water are occupied in salt-soda soil, is closed the switch, anode electricity Solution piece, catholyte piece are electrically connected under the effect of salt-soda soil aqueous solution, can be electrolysed to salt-soda soil, catholyte piece generates Hydrogen, anode electrolysis piece generate oxygen and chlorine.Anode electrolysis piece, catholyte piece can be fixed on floating material or be fixed on branch On frame 9, hollow insulation system is can be used in bracket 9, with the quick dismounting of realization device.It is power supply unit power grid alternating current, spare At least one of generator, wind-driven generator, solar energy power generating power supply unit, generally setting device with multiple power supplier, with suitable Salt-soda soil environment is answered to use needs.
After the completion of electrolysis, groove where anode electrolysis piece is dilution heat of sulfuric acid, and groove where catholyte piece is hydroxide Sodium solution, in order to recycle above-mentioned solution, entire salt-soda soil electrolysis quick improvement device further includes for extracting anode electrode The draw-out device of aqueous solution at groove where piece, catholyte piece handles to obtain the aqueous solution that draw-out device extracts The processing unit of transformation substance.Draw-out device uses two, and groove is molten where the first draw-out device 12 extracts anode electrolysis piece Acid-proof suction pump and alkaline suction pump can be selected in liquid, the solution of groove where two draw-out devices 13 extract catholyte piece respectively.
Processing unit includes setting gradually the first filtering ponds 14, reaction tank, drying device and the object being connected on reaction tank Expect adding mouth.First filtering ponds are Acidic Liquid filtering ponds, the dilution heat of sulfuric acid of groove where filtering anode electrolysis piece, in reaction tank It is that ammonium sulfate solids crystallize that middle addition ammonium hydroxide, ammonium hydroxide and dilute sulfuric acid, which neutralize, it, which is dried, can be made ammonium sulfate.
Processing unit further includes neutralizing agitating device, and anode electrolysis piece bubbing is passed through neutralization after gas collector Emulsification oxygen calcium is added in agitating device, in Xiang Zhonghe agitating device can be prepared by bleaching powder.
Processing unit further includes the second filtering ponds 15, the concentrator, drying equipment set gradually.Alkaline suction pump will be negative Pole water is evacuated in the second filtering ponds, and groove where catholyte piece is sodium hydroxide solution, and the concentrated equipment of the solution, drying are set Solid sodium hydroxide can be made in standby negative pressure heating concentration.
Sedimentation basin 10 can be also distinguished in the trench, and preliminary sedimentation is carried out to the water in groove, reduces the equipment of follow-up link Burden.
Using above-mentioned apparatus, reusable and mobility is strong, can get sulfuric acid by draw-out device, processing unit Ammonium, bleaching powder, sodium hydroxide byproduct are truly realized waste utilization, realize profit in improved, process also by-product.
Embodiment 2
Device based on the above embodiment, the present embodiment disclose a kind of salt-soda soil electrolysis quick improvement method, comprising the following steps:
A, two grooves 8 are excavated in salt-soda soil region 11, in order to dispose anode electrolysis piece, catholyte piece.
B, the essential mineral in alkaline land soil is sodium sulphate, sodium chloride etc., at this time, it may be necessary to occupy water in salt-soda soil simultaneously It impregnates at least 24 hours, so that sodium sulphate, sodium chloride, which sufficiently dissolve, becomes ion like.
C, it in the trench by the anode electrolysis piece of above-mentioned salt-soda soil electrolysis quick improvement device, the installation of catholyte piece, beats Switch is electrolysed, and power supply unit uses alternating voltage, and the tunable arrangement of alternating voltage equipment adjusts voltage as needed 380 1 5000 volts of AC voltage ranges, AC rectification are direct current.By controllable DC power supply, it is supplied respectively to install Anode electrolysis piece well, catholyte piece.
D, after the completion of electrolysis, processing is carried out to the solution of two grooves respectively using draw-out device and processing unit and obtains sulfuric acid Ammonium, bleaching powder, sodium hydroxide.
The present invention is suitble to the method for all kinds of alkaline land improvings, and apparatus can be reused, and improvement salt-soda soil speed is fast, former It improves salt-soda soil and needs 3 one 5 years, as long as once improveing and not needing using apparatus and method of the present invention 200 1 300 hours Secondary repetition improves again, as long as 300 yuans per acre of salt-soda soil expense of improvement.The present invention is easy to promote and popularize, final mesh Be used successfully to all kinds of salt-soda soil quick improvements in the whole world, benefit the whole mankind.
Above-described specific embodiment has carried out further the purpose of the present invention, technical scheme and beneficial effects It is described in detail, it should be understood that being not intended to limit the present invention the foregoing is merely a specific embodiment of the invention Protection scope, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include Within protection scope of the present invention.

Claims (6)

1. a kind of salt-soda soil is electrolysed quick improvement device, which is characterized in that including anode electrolysis piece, catholyte piece, be connected on Switch and power supply unit between catholyte piece and anode electrolysis piece;
It further include for the draw-out device of aqueous solution at groove where extracting anode electrode film, catholyte piece, to draw-out device The aqueous solution of extraction is handled to obtain the processing unit of transformation substance.
2. a kind of salt-soda soil according to claim 1 is electrolysed quick improvement device, which is characterized in that the draw-out device packet Include acid-proof suction pump and alkaline suction pump, the processing unit include set gradually the first filtering ponds, reaction tank, drying device and The material adding mouth being connected on reaction tank, the processing unit further include the second filtering ponds set gradually, concentrator, do Dry equipment.
3. a kind of salt-soda soil according to claim 1 is electrolysed quick improvement device, which is characterized in that the processing unit is also It is described to neutralize the gas collection being communicated on agitating device for collecting anode electrolysis piece bubbing including neutralizing agitating device Device.
4. a kind of salt-soda soil according to claim 1 is electrolysed quick improvement device, which is characterized in that the power supply unit packet It includes at least one of power grid alternating current, stand-by generator, wind-driven generator, solar energy power generating power supply unit.
5. a kind of salt-soda soil according to claim 1 is electrolysed quick improvement device, which is characterized in that the anode electrolysis Piece, catholyte piece are fixed on floating material or are fixed on bracket.
6. a kind of salt-soda soil is electrolysed quick improvement method, which comprises the following steps:
A, two grooves are excavated in salt-soda soil region;
B, water is occupied in salt-soda soil and is impregnated at least 24 hours;
C, anode electrolysis piece, the catholyte piece of any salt-soda soil electrolysis quick improvement device of the claims 1 to 5 are pacified Dress in the trench, is turned on the switch and is electrolysed;
D, after the completion of electrolysis, the solution of two grooves is handled respectively using draw-out device and processing unit.
CN201910729192.2A 2019-08-08 2019-08-08 A kind of salt-soda soil electrolysis quick improvement device and method Pending CN110278731A (en)

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Application Number Priority Date Filing Date Title
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Application publication date: 20190927