CN110271867A - Solid-state hydrogenation plant - Google Patents
Solid-state hydrogenation plant Download PDFInfo
- Publication number
- CN110271867A CN110271867A CN201810211858.0A CN201810211858A CN110271867A CN 110271867 A CN110271867 A CN 110271867A CN 201810211858 A CN201810211858 A CN 201810211858A CN 110271867 A CN110271867 A CN 110271867A
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- China
- Prior art keywords
- feed back
- hydrogen
- solid
- hydrogenation plant
- blower
- Prior art date
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- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 104
- 239000000463 material Substances 0.000 claims abstract description 72
- 238000011084 recovery Methods 0.000 claims abstract description 50
- 238000004064 recycling Methods 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims description 64
- 229910052987 metal hydride Inorganic materials 0.000 claims description 60
- 150000004681 metal hydrides Chemical class 0.000 claims description 60
- 239000000376 reactant Substances 0.000 claims description 34
- 239000006227 byproduct Substances 0.000 claims description 30
- 229910044991 metal oxide Inorganic materials 0.000 claims description 20
- 150000004706 metal oxides Chemical class 0.000 claims description 20
- 238000012544 monitoring process Methods 0.000 claims description 20
- 238000005303 weighing Methods 0.000 claims description 20
- 239000001257 hydrogen Substances 0.000 abstract description 202
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 202
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 104
- 239000007787 solid Substances 0.000 abstract description 26
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 description 97
- 239000002994 raw material Substances 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 14
- 238000001514 detection method Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 238000001816 cooling Methods 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 230000001502 supplementing effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000007306 turnover Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004678 hydrides Chemical class 0.000 description 4
- 239000002184 metal Chemical group 0.000 description 4
- 229910052751 metal Chemical group 0.000 description 4
- 230000001360 synchronised effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000110 cooling liquid Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 229910012375 magnesium hydride Inorganic materials 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011897 real-time detection Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 238000010396 two-hybrid screening Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
- B60K15/10—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks concerning gas-producing plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
- B65G53/00—Conveying materials in bulk through troughs, pipes or tubes by floating the materials or by flow of gas, liquid or foam
- B65G53/04—Conveying materials in bulk pneumatically through pipes or tubes; Air slides
- B65G53/24—Gas suction systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
- B65G53/00—Conveying materials in bulk through troughs, pipes or tubes by floating the materials or by flow of gas, liquid or foam
- B65G53/34—Details
- B65G53/66—Use of indicator or control devices, e.g. for controlling gas pressure, for controlling proportions of material and gas, for indicating or preventing jamming of material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Sustainable Development (AREA)
- Transportation (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
The present invention relates to equipment technology fields, and in particular to a kind of solid-state hydrogenation plant, including Material supply system, feed back recovery system, water system, blower fan system and control system.It is characterized in that charge pipe, feed back pipe, water pipe come together in the integral structure of feeding gun.It is mainly used for the charging and recycling to solid hydrogen fuel battery car.It can also be used for other solid state hydrogen energy-accumulating power stations or the charging of solid state hydrogen heat energy system and recycling.
Description
Technical field
The present invention relates to equipment technology fields, and in particular to a kind of solid-state hydrogenation plant.
Background technique
In recent years, the environmental problem of the earth is on the rise: especially CO2, CO, S compound etc. of motor vehicle exhaust emission was both given
Atmosphere brings greenhouse effects, also causes serious air pollution to atmosphere.The new-energy automobile of internal-combustion engines vehicle is substituted, it is more next
More concerned, especially hydrogen cell automobile is strong and famous with zero-emission, cruising ability.And current hydrogenation plant, with
Based on Gaseous Hydrogen or liquified hydrogen, solid-state hydrogen production device can not be added.Solid state hydrogen, the solid forms of hydrogen in non-traditional meaning,
But by hydrogen and metal bonding, with metal hydride existing for solid forms.Solid state hydrogen is compared with liquified hydrogen, Gaseous Hydrogen, not only
Can store at normal temperature, and with high security the advantages of.
Existing hydrogenation plant has the following problems generally based on gas hydrogen or liquid hydrogen:
1. entire link needs torpedo car to transport liquid hydrogen or gas hydrogen to hydrogenation plant, gasified and (be only used for liquid hydrogen), pressurization,
The processes such as dry are finally in 30MPa-70MPa hydrogen storage tank by the air pressure that hydrogen energy source automobile is added in air filling gun, transportational process and make
There is biggish security risk with process；
2. liquid hydrogen hydrogenation plant needs the equipment such as liquid hydrogen tank, gasifier, compressor, gas hydrogen hydrogenation plant then needs high pressure gas
Bottle group, compressor, stand in the equipment such as gas cylinders group, equipment and operation cost are high；
3. hydrogenation stations addressing is extremely difficult, keep the universal comparison of hydrogen energy source vehicle industrialization slow.
Therefore, it is badly in need of releasing a kind of not only safety but also convenient and fast solid-state hydrogenation plant.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, provide it is a kind of can be achieved charging and recycling simultaneously operating,
The good solid-state hydrogenation plant of safety.
To achieve the above object, present invention employs following technical solutions:
A kind of solid-state hydrogenation plant comprising hydrogenation plant control system, feeding gun 28, for storing metal hydride
Material supply system, the feed back recycling for storing the by-product obtained after the metal hydride of recycling is reacted with liquid reactants
System, hydrogenation plant control system are connect with Material supply system and feed back recovery system, for conveying the water of liquid reactants
Pipe 4, Material supply system are connected with feeding gun 28 by charge pipe 22 and feed back recovery system by feed back pipe 32 respectively.
It preferably, further include blower fan system, the hydrogenation plant control system includes metering control instrument 5, metering control instrument 5
It is connected with blower fan system, blower fan system is connected with Material supply system, feed back recovery system respectively.
Preferably, the blower fan system includes the blower system for delivery air and the suction for being used to form negative pressure
Draught fan system；The blower system is connected with Material supply system, and blower fan system is attracted to be connected with feed back recovery system.
Preferably, the blower system includes blower 6, the first filter being successively connected with blower 6
81, the first air switching valve 8, and the second air hose 82, the 4th air hose 83 that are connected respectively with the first air switching valve 8；
The blower 6, the first air switching valve 8 are connected with metering control instrument 5 respectively, the 4th air hose 83 and feed back recovery system
It is connected, the second air hose 82 is connected with Material supply system；The attraction blower fan system include attract blower 7, successively with attraction
The second connected filter 91 of blower 7, the second air switching valve 9, and first to be connected respectively with the second air switching valve 9 are empty
Tracheae 92, third air hose 93；The attraction blower 7, the second air switching valve 9 are connected with metering control instrument 5 respectively, and first is empty
Tracheae 92 is connected with Material supply system, and third air hose 93 is connected with feed back recovery system.
Preferably, the Material supply system includes the head tank 2 for storing metal oxide, and head tank 2 is by adding
Expects pipe 22 is connected with feeding gun 28.
Preferably, the head tank 2 further includes the first weighing instrument 17 of the metal hydride weight in it for real-time monitoring,
First weighing instrument 17 is connected with the metering control instrument 5 of hydrogenation plant control system.
Preferably, the Material supply system further includes that the first bucket 18 coupled below head tank 2 is arranged in,
First bucket 18 is connected by charge pipe 22 with feeding gun 28.
It preferably, further include blower fan system, blower fan system includes the attraction blower fan system for being used to form negative pressure, and raw material supplies
The the second trapping bucket 10 for answering system to further include and blower fan system is attracted to be connected, the second trapping bucket 10 includes coupled mother tube
23。
Preferably, the head tank 2 is connected with the second trapping bucket 10 of Material supply system by the first revolving valve 11, former
Batch can 2 is connected with the first bucket 18 of head tank 2 by the 5th revolving valve, and the second revolving valve is arranged in 18 lower end of the first bucket
12, the first revolving valve 11, the 5th revolving valve and the second revolving valve 12 with 5 phase of metering control instrument of hydrogenation plant control system
Even；It further include blower fan system, blower fan system includes the blower system for delivery air, and the second revolving valve 12 passes through charging
Pipe 22 is connected with feeding gun 28, and is connected with blower system.
Preferably, the feed back recovery system includes feed back tank 3 for storing by-product and is arranged in feed back tank 3
The first coupled trapping bucket 13 of side, the first trapping bucket 13 are connected by feed back pipe 32 with feeding gun 28.
Preferably, the first trapping bucket 13 further includes the second bucket 19 that its underpart is arranged in, the second bucket 19
It is connected with the metering control instrument 5 of hydrogenation plant control system.
Preferably, the feed back tank 3 further includes the second weighing instrument 16 of the by-product weight in it for real-time monitoring, and second
Weighing instrument 16 is connected with the metering control instrument 5 of hydrogenation plant control system.
It preferably, further include blower fan system, blower fan system includes being used to form the attraction blower fan system of negative pressure and being used for
The blower system of delivery air, the first trapping bucket 13 are connected with feed back tank 3 by third revolving valve 14, the first trapping bucket 13
It is connected with blower fan system is attracted, third revolving valve 14 is connected with the metering control instrument 5 of hydrogenation plant control system.
Preferably, the feed back tank 3 further includes the metering control instrument 5 that its lower end is arranged in hydrogenation plant control system
The 4th connected revolving valve 15, the 4th revolving valve 15 are connected with recovery tube 33, and are connected with blower system.
It preferably, further include water system, the water system includes that water pipe 4 is connected with feeding gun 28, and water pipe 4 includes setting
Set water pump 42 and flowmeter 43 on it.
Preferably, the water pump 42 and flowmeter 43 are connected with the metering control instrument 5 of hydrogenation plant control system respectively, meter
Measure unlatching/closing of 5 automatically controlled water pump 42 of controller, the amount of the liquid reactants of 43 real-time monitoring water pipe 4 of flowmeter output
And feed back to metering control instrument 5.
Preferably, the arrival end of the water pipe 4 of the water system is connected with local water source 45.
Preferably, the metering control instrument 5 of the hydrogenation plant control system is according to the first weighing instrument 17 and raw material supply system
The data of the first bucket 18 feedback of system, calculate the amount of the metal hydride of output.
Preferably, the metering control instrument 5 of the hydrogenation plant control system according to the second bucket 19 and feed back tank 3
The data of two weighing instruments 16 feedback, calculate the amount of the by-product of recycling.
Preferably, the metal hydride is solid, and the liquid reactants are for liquid water or dissolved with acidic materials
Aqueous solution, the by-product are solid or solidliquid mixture.
Preferably, the charge pipe 22, feed back pipe 32 and water pipe 4 are integrated in a feeding gun 28；Alternatively, charge pipe 22,
Feed back pipe 32 and water pipe 4 are three pipe separate structures, are respectively connected with a feeding gun 28；Alternatively, the charge pipe 22, feed back pipe 32
It is connected with Guan Yuyi feeding gun of any two 28 of water pipe 4, another pipe is connected with another feeding gun 28.
Solid-state hydrogenation plant of the invention includes Material supply system, feed back recovery system and feeding gun, and water pipe is for defeated
Liquid reactants are sent, are stored with metal hydride in Material supply system, can be stored at normal temperature, highly-safe, feed back recycling
The by-product that the metal hydride that system is used to store recycling obtains after reacting with liquid reactants；Solid-state hydrogenation plant is by adding
Spray gun is that hydrogen transmitting apparatus adds metal hydride and/or liquid reactants, while recycling the by-product in hydrogen transmitting apparatus by feeding gun
Object, realizes the integration operation of raw material addition and the recycling of reacting rear material, and high degree of automation operates convenient and efficiency
It is high.
Detailed description of the invention
Fig. 1 be the present invention automatically can continuous hydrogen transmitting apparatus structural schematic diagram；
Fig. 2 is the structural schematic diagram of solid-state hydrogenation plant of the present invention；
Fig. 3 is the cooperation schematic diagram of solid-state hydrogenation plant of the present invention and material turnover area, hydrogen transmitting apparatus；
Fig. 4 is the cooperation schematic diagram of solid-state hydrogenation plant of the present invention and material-conveying vehicle, hydrogen transmitting apparatus.
Specific embodiment
Below in conjunction with the embodiment that attached drawing 1-4 is provided, solid-state hydrogenation plant and hydrogen transmitting apparatus of the invention are further illustrated
Specific embodiment.Solid-state hydrogenation plant of the invention is not limited to the following description.
Solid-state hydrogenation plant of the invention comprising hydrogenation plant control system, feeding gun 28, for providing liquid reactions
The water system of object, the Material supply system for storing metal hydride, metal hydride and liquid for storing recycling
The feed back recovery system of gained by-product after reactant reaction,
Water system is divided by charge pipe 22, feed back recovery system by feed back pipe 32 by water pipe 4, Material supply system
Be not connected with feeding gun 28, feeding gun 28 for being connected with hydrogen transmitting apparatus, by Material supply system metal hydride and/or
The liquid reactants of water system are added to hydrogen transmitting apparatus, and recycle by-product to feed back recovery system.
Solid-state hydrogenation plant of the invention includes water system, Material supply system, feed back recovery system and feeding gun 28,
Water system is used to provide liquid reactants, is stored with metal hydride in Material supply system, can store at normal temperature, safety
Property it is high, feed back recovery system is used to store the by-product obtained after the metal hydride recycled is reacted with liquid reactants；Solid-state
Hydrogenation plant is that hydrogen transmitting apparatus adds metal hydride and/or liquid reactants, while being recycled by feeding gun by feeding gun 28
By-product, realizes the integration operation of raw material addition and the recycling of reacting rear material, and high degree of automation is operated convenient and imitated
Rate is high.
It as in Figure 2-4, is the embodiment of solid-state hydrogenation plant of the present invention.
The solid-state hydrogenation plant of the present embodiment includes hydrogenation plant control system, is connected respectively with hydrogenation plant control system
Material supply system, feed back recovery system, water system, feeding gun 28, Material supply system, feed back recovery system, supply water
System is connected with feeding gun 28 respectively.
The Material supply system supplies raw material (i.e. metal hydride) to hydrogen transmitting apparatus by feeding tube；
The feed back recovery system recycles feed back (i.e. by-product) from hydrogen transmitting apparatus by recovery channel；
The water system supplies water (i.e. liquid reactants) to hydrogen transmitting apparatus by waterway pipe；
The hydrogenation plant control system controls the operation of Material supply system, feed back recovery system, water system, with
And the supply metering and the recycling of feed back metering of raw material and water.
The water system passes through feed back by charge pipe 22, feed back recovery system by water pipe 4, Material supply system
Pipe 32 is connected with feeding gun 28 respectively.Preferably, embodiment as shown in Figure 2, the charge pipe 22, feed back pipe 32 and water pipe 41
A feeding gun 28 is come together in, three pipe integrated structures are formed, three is connected with a feeding gun 28, is used for and Fig. 1 institute
The feed opening 9000 of the hydrogen transmitting apparatus shown is connected, or for connecting with the automobile for having hydrogen transmitting apparatus shown in Fig. 4.Certainly, such as Fig. 3
Shown in another embodiment, the charge pipe 22, feed back pipe 32 and water pipe 4 be three pipe separate structures, three respectively with one feed
Rifle 28 is connected, corresponding with the material box 24 of hydrogen transmitting apparatus, water tank 44 and feed back case 34 respectively by three feeding guns 28.More or
Person, the charge pipe 22, feed back pipe 32 are connected with Guan Yuyi feeding gun of any two 28 of water pipe 4, another pipe is individually set
It sets and is connected with another feeding gun 28.Preferably, the raw material is powdery or granular metal hydride, feed back (i.e. by-product)
The solid metal oxide generated after being reacted for metal hydride with water.
Embodiment as in Figure 2-4, the hydrogenation plant control system include metering control instrument 5, and the solid-state adds
Hydrogen production device further includes blower fan system, and blower fan system is connected with metering control instrument 5, blower fan system respectively with Material supply system, return
Expect that recovery system is connected, for the power as driving raw material supply and feed back recycling.Preferably, the blower fan system includes using
In delivery air blower system and be used to form the attraction blower fan system of negative pressure, metering control instrument 5 respectively with blow
Blower fan system is connected with attraction blower fan system, controls the starting/stopping of the two.
The Material supply system is connected by the second air hose 82 with blower system, and by charge pipe 22 and is added
Spray gun 28 is connected；The feed back recovery system is connected by third air hose 93 with blower fan system is attracted, and passes through feed back pipe 32
It is connected with feeding gun 28；The water system is connected by water pipe 4 with feeding gun 28, water pipe 4 equipped with water pump 42, water pump 42 and
Metering control instrument 5 is connected.The feeding gun 28 further includes detection unit, and detection unit includes being connected with metering control instrument 5
Each pipeline amount level sensor or the detection interface for measuring level sensor, the detection interface can be used for and is arranged in hydrogen transmitting apparatus
Multiple amount level sensors be connected.Such as multiple amount level sensors in hydrogen transmitting apparatus include at least respectively and in hydrogen transmitting apparatus
The first amount level sensor that material box 24, water tank 44 are correspondingly arranged, the second amount level sensor, the first amount level sensor is for real-time
The amount of metal hydride in monitoring material box 24 simultaneously feeds back to metering control instrument 5, and the second amount level sensor is used for real-time monitoring
The amount of water in water tank 44 simultaneously feeds back to metering control instrument 5；The detection unit can also include and feed back recycling system is arranged in
The detection interface that sensor in system is connected, the amount of the metal oxide of sensor Real-time Feedback feed back recovery system recycling is simultaneously
Feed back to metering control instrument 5.
It is described further below with reference to the solid-state hydrogenation plant of Fig. 2-4 and specific embodiment.
The feeding gun 28 includes pipette tips for being connected with hydrogen transmitting apparatus and for controlling pipette tips unlatching/closing hand
Handle.
Preferably, after the feeding gun 28 is connect with hydrogen transmitting apparatus, when handle is opened, then metering control instrument 5 starts automatically
Blower fan system and water system.
Preferably, the feeding gun 28 further includes feeding gun switch, after feeding gun 28 is connect with hydrogen transmitting apparatus, closure charging
Rifle switch, then metering control instrument 5 starts blower fan system and water system automatically.
Preferably, the charge pipe 22, feed back pipe 32, water pipe 4 come together in feeding gun 28, form three pipe integrated knots
Structure；The pipe integrated structure of feeding gun 28 3 also includes each line sensor being connected with metering control instrument 5 or sensing
The line interface of device.
The water system includes water pipe 4, and water pipe 4 is connected with feeding gun 28, and water pipe 4 includes the water set gradually on it
Pump 42 and flowmeter 43, water pump 42 and flowmeter 43 are connected with metering control instrument 5 respectively, 5 automatically controlled water pump of metering control instrument
42 unlatching/closing the output quantity of water and feeds back to metering control instrument 5 in 43 real-time monitoring water pipe 4 of flowmeter.
Preferably, the water system can also be water tank, arrival end and the water tank phase of the water pipe 4 of the water system
Even.
Preferably, the arrival end of the water pipe 4 of the water system is connected with the local water source 45 of solid-state hydrogenation plant.
As in Figure 2-4, the Material supply system includes second trapping bucket 10 setting up and down and for storing metal
The head tank 2 of hydride, the second trapping 10 lower ends of bucket are connected by the first revolving valve 11 with head tank 2, and 2 lower end of head tank passes through
Second revolving valve 12 is connected with charge pipe 22 and is connected by the second air hose 82 with blower system, 11 He of the first revolving valve
Second revolving valve 12 is connected with metering control instrument 5 respectively.
Preferably, the first bucket 18 is additionally provided between the head tank 2 and the second revolving valve 12,2 lower end of head tank is logical
The 5th revolving valve to be crossed to be connected with the first bucket 18, the 5th revolving valve, the first bucket 18 are connected with metering control instrument 5 respectively,
The weight of the metal hydride of hydrogen transmitting apparatus is added every time and feeds back to metering control instrument 5 for first bucket, 18 real-time monitoring.
Preferably, the head tank 2 further includes the first weighing instrument 17 that its underpart is arranged in, the first weighing instrument 17 and metering
Controller 5 is connected, and the weight of metal hydride and feeds back to metering control instrument 5 in 17 real-time monitoring head tank 2 of the first weighing instrument.
Preferably, the second trapping bucket 10 further includes coupled mother tube 23, mother tube 23 and material turnover area
65 or material-conveying vehicle 55 raw material cabin 25 be connected.
As in Figure 2-4, the feed back recovery system includes then the first trapping bucket 13 setting up and down and recycles for storing
Metal oxide feed back tank 3, the first trapping bucket 13 is connected by third revolving valve 14 with feed back tank 3, and first traps and struggle against 13
Upper end is connected by third air hose 93 with blower fan system is attracted, and 13 middle part of the first trapping bucket passes through feed back pipe 32 and feeding gun 28
It is connected.
Preferably, the first trapping bucket 13 further includes the second bucket 19 that its underpart is arranged in, the second bucket 19
Lower end is connected by third revolving valve 14 with feed back tank 3, and the second bucket 19 is connected with metering control instrument 5, the second bucket 19
The amount for the metal oxide that real-time monitoring is recycled from hydrogen transmitting apparatus every time simultaneously feeds back to metering control instrument 5.
Preferably, sensor is set in the first trapping bucket 13, sensor is connected with metering control instrument 5, and sensor is real
When the first trapping of detection bucket 13 in metal oxide amount, and feed back to metering control instrument 5.
Preferably, the feed back tank 3 further includes the second weighing instrument 16 that its underpart is arranged in, and the second weighing instrument 16 is supervised in real time
The amount of metal oxide in survey time batch can 3 simultaneously feeds back to dosage controller 5, and the 4th revolving valve 15 is arranged in 3 lower end of feed back tank, the
Four revolving valves 15 are connected with blower system and are connected with recovery tube 33 by the 4th air hose 83, recovery tube 33 and material week
The feed back storehouse 35 for turning area 65 or material-conveying vehicle 55 is connected.
As in Figure 2-4, the blower fan system includes the blower system for delivery air and is used to form angrily
The attraction blower fan system of pressure.
The blower system includes the blower 6 being connected with metering control instrument 5, is successively connected with blower 6
First filter 81, the first air switching valve 8, and be connected respectively with the first air switching valve 8 the second air hose 82,
Four air hoses 83；The metering control instrument 5 is connected with the first air switching valve 8 and controls the switching of the first air switching valve 8, meter
Measure starting/stopping that controller 5 controls blower 6.
The attraction blower fan system includes the attraction blower 7 being connected with metering control instrument 5, is successively connected with blower 7 is attracted
The second filter 91, the second air switching valve 9, and be connected respectively with the second air switching valve 9 the first air hose 92,
Three air hoses 93；The metering control instrument 5 is connected with the second air switching valve 9 and controls the switching of the second air switching valve 9, meter
Measure starting/stopping that the control of controller 5 attracts blower 7.
As in Figure 2-4, the solid-state hydrogenation plant of the present embodiment further includes control system cabinet 1, metering control instrument 5, blower
System, the water pump 42 of water system and flowmeter 43 are arranged in control system cabinet 1.
Preferably, as shown in figure 4, the solid-state hydrogenation plant of the present embodiment is fixed station, cooperate with material-conveying vehicle 55
It uses, material-conveying vehicle 55 includes raw material cabin 25 and feed back storehouse 35, and raw material cabin 25 is for storing solid metal hydride, feed back storehouse
35 for storing solid metal oxide.
Preferably, as shown in figure 3, the solid-state hydrogenation plant of the present embodiment is moveable, such as by solid-state hydrogenation plant
It is mounted on motor vehicle, is hydrogen energy source vehicle, solid-state hydrogen energy source power station and/or solid-state to meet the mobility of solid-state hydrogenation plant
Hydrogen energy source heat energy system supplements the demand of solid state hydrogen, and moveable solid-state hydrogenation plant and material turnover area 65 cooperate, material week
Turning area 65 includes raw material cabin 25 and feed back storehouse 35, and solid metal hydride of the raw material cabin 25 for storage, feed back storehouse 35 is for depositing
Store up solid metal oxide.
As in Figure 2-4, the course of work of the present embodiment solid-state hydrogenation plant is as follows:
Step 1: supplementing metal hydride for head tank 2
It (11) will be in the raw material cabin 25 of 23 insertion material turnover area 65 of mother tube or material-conveying vehicle 55；
(12) metering control instrument 5 is operated, solid-state hydrogenation plant is made to enter supplement feed states, the attraction blower of blower fan system
System starting；
(13) it is described attract blower fan system attraction blower 7 work, by the first air hose 92 make the second trapping bucket 10 into
Enter angrily pressure condition, metal hydride enters in the second trapping bucket 10 through mother tube 23；
(14) after appropriate metal hydride enters the second trapping bucket 10, metering control instrument 5, which is automatically stopped, attracts blower 7, and
The first revolving valve 11 is opened, enters metal hydride in head tank 2；
The amount of metal hydride in 17 real-time monitoring head tank 2 of (15) first weighing instrument, and metering control instrument 5 is fed back to,
When reaching predetermined value, stop supplementing metal hydride to head tank 2；
Step 2: recycling metal oxide from feed back tank 3
It (21) will be in the feed back storehouse 35 of 33 insertion material turnover area 65 of feed back pipe or material-conveying vehicle 55；
(22) metering control instrument 5 is operated, solid-state hydrogenation plant is made to enter feed back recycling state, the blower of blower fan system
System starting；
(23) blower 6 of the blower system works, and metering control instrument 5 controls the 4th revolving valve 15 and opens,
Metal oxide is delivered in feed back storehouse 35 by the air-flow that blower 6 exports；
(24) amount of feed back and metering control instrument 5 is fed back in the 16 real-time monitoring feed back tank 3 of the second weighing instrument, when returning
When feed back in batch can 5 is all transferred to feed back storehouse 35, metering control instrument 5 is automatically stopped blower 6 and closes the 4th time
Rotary valve 15；
It should be pointed out that step 1 synchronous can both have been carried out with step 2, it can also separate and carry out.Preferably, step 1 and
Step 2 is synchronous to be carried out, to save program and operating time.
Step 3: supplementing metal hydride and water for hydrogen transmitting apparatus, and recycle metal oxide
(31) feeding gun 28 is connected with the feed opening 9000 of hydrogen transmitting apparatus, i.e., by the head tank 2 of solid-state hydrogenation plant, confession
Water system and feed back tank 3 are corresponded with the material box 24 of hydrogen transmitting apparatus, water tank 44 and feed back case 34 respectively；
(32) start the feeding gun switch of feeding gun 28, metering control instrument 5 starts blower fan system, water system automatically；
(33) metering control instrument 5 controls the 5th revolving valve and opens, and appropriate metal hydride is made to enter the by head tank 2
One bucket 18 is then shut off the 5th revolving valve, the amount of metal hydride and anti-in 17 real-time monitoring head tank 2 of the first weighing instrument
It feeds metering control instrument 5；
Then, the metering control instrument 5 opens the second revolving valve 12, the air-flow of the blower system output of blower fan system
Raw material is delivered in material box 24 from the first bucket 18, what 18 real-time monitoring of the first bucket was conveyed to material box 24 every time
The amount of metal hydride simultaneously feeds back to metering control instrument 5；
When the first amount level sensor being arranged in material box 24 detects that the amount of the metal hydride in material box 24 reaches
To predetermined value and metering control instrument 5 is fed back to, metering control instrument 5, which controls solid-state hydrogenation plant, to be stopped supplementing metal to hydrogen transmitting apparatus
Hydride；Or metering control instrument 5 is added according to preset value, after being added to predetermined amount, control solid-state hydrogenation plant stops
Only metal hydride is supplemented to hydrogen transmitting apparatus；
(34) 150 automatically controlled water pump 42 of metering control instrument is opened, and 43 real-time monitoring of flowmeter is inputted to water tank 44
Water amount and feed back to metering control instrument 5；When the second amount level sensor in water tank 44 detects the amount of the water in water tank 44
When reaching predetermined value, metering control instrument 5, which controls solid-state hydrogenation plant, to be stopped supplementing water to hydrogen transmitting apparatus；Alternatively, metering control instrument 5
It is added according to preset value, after being added to predetermined amount, control solid-state hydrogenation plant stops supplementing water to hydrogen transmitting apparatus；
(35) the attraction blower fan system makes the first trapping bucket 13 enter pressure condition of doing something in a fit of pique, and the first trapping bucket 13 is (secondary by several times
Number is different according to the difference of the amount of the metal oxide in feed back case 34) metal oxide, the second weighing are recycled from feed back case 34
The amount for the metal oxide that 19 real-time monitorings first that struggle against trapping bucket 13 is recycled from feed back case 34 every time simultaneously feeds back to metering control instrument
5；
After appropriate feed back enters the first trapping bucket 13, metering control instrument 5 is automatically stopped attraction blower fan system, and opens the
Three revolving valves 14, feed back are entered in feed back tank 3 by the first trapping bucket 13, feed back in 16 real-time monitoring feed back tank 3 of the second weighing instrument
It measures and feeds back to metering control instrument 5；
It repeats the above steps, until whole metal oxides in hydrogen transmitting apparatus are recovered into feed back tank 3；
It should be pointed out that entering trapping bucket by feed back case 34 when the sensor being arranged in the first trapping bucket 13 is detected
When the amount of 13 metal oxide does not increase, metering control instrument 5 is fed back to, metering control instrument 5 controls feed back recovery system and stops
Only metal oxide is recycled to hydrogen transmitting apparatus；
It should be pointed out that step (33), (34), (35) can synchronize progress, step (33), (34), (35) can also be with
Distribution carries out.Preferably, step (33), (34), (35) synchronous progress, to save program and operating time.
After step 3, the metering control instrument 5 is according to the first weighing instrument 17, the data meter of the first bucket 18 feedback
The amount for calculating the metal hydride supplemented to hydrogen transmitting apparatus, the data fed back according to the second weighing instrument 16, the second bucket 19 calculate
The amount of the metal oxide recycled to hydrogen transmitting apparatus, the amount of the water supplemented to hydrogen transmitting apparatus is calculated according to flowmeter 43.
The above content is the specific preferred embodiments of combination to further detailed made by solid-state hydrogenation plant of the invention
Describe in detail bright, and it cannot be said that specific implementation of the invention is only limited to these instructions.
Such as another embodiment of solid-state hydrogenation plant of the invention, the solid-state hydrogenation plant are not provided with blower system
System carries out the supply of raw material by pump power system and feed back recycles.The pump power system includes being arranged on water pipe 4
First rear pump, the second rear pump being arranged on charge pipe 22 and the first recovery pump being arranged on feed back pipe 32, first is defeated
Pump, the second rear pump and the first recovery pump are connect with the metering control instrument 5 of hydrogenation plant control system out.
Such as another embodiment of solid-state hydrogenation plant of the invention, the solid-state hydrogenation plant can not pass through title
Hopper and weighing instrument are measured, and can also be used the first output stream meter being arranged on water pipe 4, are arranged on charge pipe 22
The second output stream meter and the first recovery pump flowmeter for being arranged on feed back pipe 32 measured, the first output stream meter,
Second output stream meter and the first recovery pump flowmeter are connect with the metering control instrument 5 of hydrogenation plant control system.First is defeated
Flow meter can use fluid flowmeter, and the second output stream meter and the first recovery pump flowmeter can use solid flow
Meter, such as U.S. 0mega, the flowmeter of German MUTEC.
Specifically, the water pipe 4 is equipped with the first delivery valve connecting with metering control instrument 5, the first rear pump and the
One output stream meter, the charge pipe 22 be equipped with connect with metering control instrument 5 the second delivery valve, the second rear pump and
Second output stream meter, the feed back pipe 32 are equipped with the first recovery valve connecting with metering control instrument 5, the first recovery pump
With the first recovery pump flowmeter.The solid-state hydrogenation plant includes control system cabinet 1, metering control instrument 5, the first delivery valve,
First rear pump, the first output stream meter, the second delivery valve, the second rear pump, the second output stream meter, the first recovery valve,
One recovery pump and the first recovery pump flowmeter are arranged in control system cabinet 1.
Certainly, the solid-state hydrogenation plant can also using blower fan system and pump power system mixing by the way of come into
Row charging and recycling can also be fed and be recycled by the way of flexible screw conveying.In addition, blower fan system can also be only with
One blower does so as to will lead to output effect poor and increase system simultaneously as attracting wind to attract blower and blower certainly
The complexity of system.
It can continuous hydrogen transmitting apparatus as shown in Figure 1, invention additionally discloses one kind.
As shown in Figure 1, of the invention can hydrogen transmitting apparatus include continuously feed opening 9000, hydrogen transmitting apparatus control system
8000, for storing the material box 24 of metal hydride, the water tank 44 for storing liquid reactants, for storing metal hydride
Object and liquid reactants reaction gained hydrogen hydrogen container 3000, for store metal hydride and liquid reactants reaction after institute
The feed back case 34 of by-product is obtained, material box 24 sends out storehouse 1000 with hydrogen by its third input pipe 2001 and is connected, and water tank 44 passes through it
4th input pipe 4001 is connected with hydrogen hair storehouse 1000, and hydrogen container 3000 sends out 1000 phase of storehouse by its second efferent duct 3001 and hydrogen
Even, feed back case 34 sends out storehouse 1000 with hydrogen by its third efferent duct 5001 and is connected；
The material box 24 is connected by the first charge pipe 2003 with feed opening 9000, and water tank 44 passes through the second charge pipe
4004 are connected with feed opening 9000, and feed back case 34 is connected by the first recovery tube 5008 with feed opening 9000.
Of the invention can hydrogen transmitting apparatus include continuously feed opening 9000, hydrogen hair storehouse 1000, material box 24, water tank 44, hydrogen storage
Tank 3000, feed back case 34 and hydrogen transmitting apparatus control system 8000, hydrogen hair storehouse 1000 can obtain liquid reactants and metal in batches
Hydride and as the two reactor, feed back case 34 is used to obtain the by-product of reaction, can discharge the sky that hydrogen sends out storehouse 1000 in time
Between, hydrogen container 3000 from hydrogen hair storehouse 1000 obtain reaction generate hydrogen and storage, realize hydrogen hair reaction serialization and can
Controlization realizes the recycling and storage of byproduct of reaction, moreover, material box 24, water tank 44, feed back case 34 respectively with feed opening
9000 connection addition metal hydrides and liquid reactants, while feed back case 34 connect with feed opening 9000 and exports back by-product
Receive, substantially increase the present invention automatically can continuous hydrogen transmitting apparatus convenience and safety, reduce costs.
As shown in Figure 1, for it is of the invention can continuous hydrogen transmitting apparatus one embodiment.
It is of the invention it is automatic can continuous hydrogen transmitting apparatus include hydrogen transmitting apparatus control system 8000 and be controlled with hydrogen transmitting apparatus
System 8000 connected hydrogen hair storehouse 1000, material box 24, hydrogen container 3000, water tank 44, feed back case 34 and feed opening 9000.
The material box 24 passes through third input pipe above hydrogen hair storehouse 1000 for storing metal hydride, setting
2001 are connected with hydrogen hair storehouse 1000, and third input pipe 2001 includes the third transfer valve 2002 in the portion that is disposed therein, third input
Valve 2002 is connected with hydrogen transmitting apparatus control system 8000, and 24 top of material box also passes through the first charge pipe 2003 and feed opening 9000
It is connected.Certainly, a front pump can also be set in third input pipe 2001.
Preferably, first for metal hydride reserves in real-time detection material box 24 is additionally provided in the material box 24
Measure level sensor.For metal hydride in the material box 24 after the opening of third transfer valve 2002, metal hydride falls into hydrogen
It sends out in storehouse 1000, when quantitative metal hydride (i.e. hydrogen hair storehouse 1000 obtain every time the amount of metal hydride) outflow, hydrogen
Transmitting apparatus control system 8000 controls third transfer valve 2002 and closes.Gold in first amount level sensor real-time monitoring material box 24
The reserves for belonging to hydride, feed back to hydrogen transmitting apparatus control system 8000 to monitor reserves, hydrogen transmitting apparatus control system 8000
The amount that the metal hydride flowed out every time can be calculated by the first amount level sensor, when quantitative metal hydride (i.e. send out by hydrogen
The amount for the metal hydride that storehouse 1000 obtains every time) outflow when, hydrogen transmitting apparatus control system 8000 control third transfer valve 2002
It closes.
The water tank 44 is connected by the 4th input pipe 4001 with hydrogen transmitting apparatus 1000 for storing liquid reactants,
4th input pipe 4001 includes the 4th transfer valve 4002 and the 4th front pump 4003 in the portion that is disposed therein, the 4th transfer valve 4002
It is connected respectively with hydrogen transmitting apparatus control system 8000 with the 4th front pump 4003, water tank 44 also by the second charge pipe 4004 and adds
Material mouth 9000 is connected.
Preferably, second amount level sensor is set in the water tank 44, the second amount level sensor can real-time monitoring water tank 44
The reserves of interior liquid reactants.The hydrogen transmitting apparatus control system 8000 controls the 4th transfer valve 4002 opening, the 4th input
When pump 4003 is opened, liquid reactants flow into hydrogen hair storehouse 1000, the second amount level sensor under the action of the 4th front pump 4003
Can liquid reactants in real-time monitoring water tank 44 reserves, feed back to hydrogen transmitting apparatus control system 8000 to monitor reserves,
Hydrogen transmitting apparatus control system 8000 can also calculate the amount of the liquid reactants flowed out every time by the second amount level sensor, work as prison
When measuring quantitative liquid reactants (i.e. hydrogen hair storehouse obtain every time the amounts of liquid reactants) outflow, then hydrogen transmitting apparatus control system
8000 the 4th transfer valve 4002 of control of system is closed, and the 4th front pump 4003 stops.
Preferably, the feed back case 34 is used to obtain from hydrogen hair storehouse 1000 and stores solidliquid mixture, and feed back case 34 includes
Solid case 5003 and catch box 5004, are arranged filter screen 5005 between solid case 5003 and catch box 5004, filter screen 5005 is
Funnel-shaped structure, 5003 top of solid case send out 1000 lower end of storehouse with hydrogen by third efferent duct 5001 and are connected, third efferent duct
5001 include the third delivery valve 5002 in the portion that is disposed therein, third rear pump 5002 and 8000 phase of hydrogen transmitting apparatus control system
Even, the lower end of solid case 5003 is connected by the first recovery tube 5008 with feed opening 9000,5008 ingress port of the first recovery tube
It is connected across catch box 5004 with the lower end of filter screen 5005,5004 lower part of catch box passes through the first liquid back pipe 5006 and water tank 44
Top is connected, and the first liquid back pipe 5006 includes first time liquid pump 5007 in the portion that is disposed therein, and first time liquid pump 5007 and hydrogen are sent out
Apparatus control system 8000 is connected.
Preferably, liquid level sensor, liquid level sensor and hydrogen transmitting apparatus control system are set in the catch box 5004
8000 are connected, and after liquid reaches certain liquid level in catch box 5004, liquid level sensor is to hydrogen transmitting apparatus control system 8,000 1
A feedback signal, hydrogen transmitting apparatus control system 8000 controls first time liquid pump 5007 and opens, by the liquid pump in catch box 5004
Enter in water tank 44.
It should be pointed out that the feed back case 34 obtains in hydrogen hair storehouse 1000 by the Hydrogen Vapor Pressure in hydrogen hair storehouse 1000
By-product, after hydrogen sends out the acquisition metal hydride of storehouse 1000 and liquid reactants, the two reacts in hydrogen hair storehouse 1000, obtains
By-product, at this point, the third delivery valve 5002 that hydrogen transmitting apparatus control system 8000 controls third efferent duct 5001 is opened, by-product
Under the action of Hydrogen Vapor Pressure, flow into the solid case 5003 of feed back case 34, the liquid in solid case 5003 is under the effect of gravity
Catch box 5004 is flowed into naturally through filter screen 5005, and obtains the solid for being deposited on 5005 top of filter screen.Certainly it is sent out in hydrogen
Setting pump is also possible between storehouse 1000 and feed back case 34.It should be pointed out that the solid obtains after referring to filtering
Solidliquid mixture containing a small amount of liquid.
Preferably, the present invention continuously can also wrap the sensor interface being arranged at feed opening 9000 by hydrogen transmitting apparatus automatically, pass
Sensor interface is connected with the first amount level sensor, the second amount level sensor respectively, sensor interface by with solid-state hydrogenation plant
The detection interface of detection unit be connected with hydrogenation plant control system, the first amount level sensor, the second amount level sensor difference
It is fed back for detecting the solid state hydrogen reserves in material box 24, the liquid reactants reserves in water tank 44, and by sensor interface
Give hydrogenation plant control system.Certainly, sensor interface can also be connect with hydrogen transmitting apparatus control system 8000, sensor interface
It is connected with the detection interface of the detection unit of solid-state hydrogenation plant, makes hydrogen transmitting apparatus control system 8000 and solid-state hydrogenation plant
Hydrogenation plant control system is connected.
The hydrogen container 3000 is used to obtain from hydrogen hair storehouse 1000 and stores hydrogen and provide hydrogen for hydrogen power-equipment,
It sends out storehouse 1000 with hydrogen by the second efferent duct 3001 to be connected, the second efferent duct 3001 includes second delivery valve in the portion that is disposed therein
3002 and second rear pump 3003, the second delivery valve 3002 and the second rear pump 3003 respectively with hydrogen transmitting apparatus control system 8000
It is connected.
Preferably, the hydrogen container 3000 further includes the pressure sensor for detecting air pressure in hydrogen container 3000.
It is noted that 3000 domestic demand of hydrogen container keeps certain hydrogen reserves and air pressure, when in hydrogen container 3000
Air pressure < air pressure lower limit when, then hydrogen transmitting apparatus control system 8000 control the second delivery valve 3002 open, the second rear pump
3003 open, and hydrogen is sent out the hydrogen in storehouse 1000 and is sent into hydrogen container 3000, when air pressure in hydrogen container 3000 >=atmospherically prescribe a time limit,
Then hydrogen transmitting apparatus control system 8000 controls the closing of the second delivery valve 3002, the second rear pump 3003 stops；If hydrogen container 3000
When inside needing hydrogen make-up, and no hydrogen in hydrogen hair storehouse 1000, then hydrogen hair storehouse 1000 obtains respectively from material box 24 and water tank 44
Metal hydride and liquid reactants, after reaction generation hydrogen reaches rated value, in the control of hydrogen transmitting apparatus control system 8000
It is lower that hydrogen is sent into hydrogen container 3000.
Preferably, the hydrogen container 3000 further includes the first coupled hydrogen feeding pipe 3004, the first hydrogen feeding pipe 3004 with
Hydrogen power-equipment is connected, and the first hydrogen feeding pipe 3004 includes the first defeated hydrogen valve 3005 in the portion that is disposed therein, the first defeated hydrogen valve
3005 are connected with the control system of hydrogen energy source vehicle or hydrogen power-equipment.
It is of the invention can continuous hydrogen transmitting apparatus feed pattern it is flexible, can both dock automatic charging (feeding) equipment, can also be manual
Charging.The feed opening 9000 can also feed manually for being connected with hydrogenation plant.Preferably, for consolidating with of the invention
The connection of state hydrogenation plant.
Hydrogen hair storehouse 1000 in batches obtain metal hydride and liquid reactions from material box 24 and water tank 44 respectively
Object simultaneously makes the two hybrid reaction, obtains hydrogen and solidliquid mixture.
In storehouse 1000 chemical reaction MgH occurs for the hydrogen hair2+H2O→Mg(OH)2+H2↑, when real reaction, water or acid
The aqueous solution of property substance be it is excessive, to ensure MgH2Fully reacting, therefore, it is anti-that hydrogen sends out metal hydride and liquid in storehouse 1000
It answers object to react, respectively obtains hydrogen and by-product, by-product is solid or solidliquid mixture.
It should be pointed out that the hydrogen transmitting apparatus control system 8000 control hydrogen hair storehouse 1000 in batches respectively from raw material
Case 24 and water tank 44 obtain metal hydride and liquid reactants, real by the programming Control to hydrogen transmitting apparatus control system 8000
It is existing, it could dictate that the amount for the metal hydride that hydrogen hair storehouse 1000 obtains every time and the amount of liquid reactants in a program, and with reference to each
Tank reserves.
Preferably, hydrogen hair storehouse 1000 further includes cooling device.
Preferably, it is that hydrogen sends out storehouse 1000 that the mode of liquid cooling, heat dissipation film or air cooling-down, which can be used, in the cooling device
Cooling.
Preferably, the cooling device includes the pipeline or cavity that 1000 outside of hydrogen hair storehouse is arranged in, and the liquid that cools down is in pipe
Flowing thinks that hydrogen hair storehouse 1000 cools down in road or cavity.Further, cooling liquid can be using the liquid reactions in water tank 44
Object, it is that hydrogen sends out the cooling of storehouse 1000 that other cooling liquid, which also can be used,.
It is of the invention it is automatic can the course of work of continuous hydrogen transmitting apparatus be divided into charging process and hydrogen generating process, wherein
Charging process is identical as the charging process of solid-state hydrogenation plant.
It is of the invention it is automatic can continuous hydrogen transmitting apparatus hydrogen generating process it is as follows:
(1) the third transfer valve 2002 that the hydrogen transmitting apparatus control system 8000 controls third input pipe 2001 is opened, to
Hydrogen sends out the metal hydride that rated capacity is added in storehouse 1000, finishes, and hydrogen transmitting apparatus control system 8000 controls third transfer valve 2002
It closes；
(2) the 4th transfer valve 4002 that the hydrogen transmitting apparatus control system 8000 controls the 4th input pipe 4001 open, the
Four front pumps 4003 are opened, and the liquid reactants of rated capacity are added to hydrogen hair storehouse, finish, hydrogen transmitting apparatus control system 8000 controls
4th transfer valve 4002 is closed, the 4th front pump 4003 stops, and obtains hydrogen and by-product；
(3) when the pressure in hydrogen hair storehouse 1000 reaches rated value, the control of hydrogen transmitting apparatus control system 8,000 second
Second delivery valve 3002 of efferent duct 3001 is opened, the second rear pump 3003 is opened, effect of the hydrogen in the second rear pump 3003
Under, hydrogen container 3000 is entered by hydrogen hair storehouse 1000, when the pressure in hydrogen hair storehouse 1000 is less than setting value, hydrogen transmitting apparatus control system
8000 the second delivery valve 3002 of control of system is closed, the second rear pump 3003 stops.Meanwhile hydrogen transmitting apparatus control system 8000 controls
Third delivery valve 5002 is opened, and by-product is flowed into feed back case 34 under the pressure of hydrogen by hydrogen hair storehouse 1000, after, hydrogen
Transmitting apparatus control system 8000 controls third transfer valve 5002 and closes；
(4) while by-product enters feed back case 34, filter screen 5005 is filtered by-product, and liquid enters catch box
5004, when the liquid level of the liquid in catch box 5004 reaches certain value, hydrogen transmitting apparatus control system 8000 controls first time liquid
Pump 5007 is opened, and the liquid in catch box 5004 is transferred in liquid reactants storage tank 4000.
It should be pointed out that the reserves when metal hydride in material box 24 are insufficient, water tank 44 is insufficient or feed back case 34
When middle by-product is excessive, solid-state hydrogenation plant adding raw materials can be passed through and recycle by-product simultaneously.
The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be said that
Specific implementation of the invention is only limited to these instructions.For those of ordinary skill in the art to which the present invention belongs, exist
Under the premise of not departing from present inventive concept, a number of simple deductions or replacements can also be made, all shall be regarded as belonging to of the invention
Protection scope.
Claims (10)
1. a kind of solid-state hydrogenation plant, which is characterized in that it includes hydrogenation plant control system, feeding gun (28), for storing
The Material supply system of metal hydride, for storing obtained by-product after the metal hydride of recycling is reacted with liquid reactants
The feed back recovery system of object, hydrogenation plant control system are connect with Material supply system and feed back recovery system,
Water pipe (4), Material supply system for conveying liquid reactants is logical by charge pipe (22) and feed back recovery system
Feed back pipe (32) is crossed to be connected with feeding gun (28) respectively.
2. solid-state hydrogenation plant according to claim 1, it is characterised in that:
It further include blower fan system, the hydrogenation plant control system includes metering control instrument (5), metering control instrument (5) and blower
System is connected, and blower fan system is connected with Material supply system, feed back recovery system respectively.
3. solid-state hydrogenation plant according to claim 2, it is characterised in that:
The blower fan system includes the blower system for delivery air and the attraction blower fan system for being used to form negative pressure；
The blower system is connected with Material supply system, and blower fan system is attracted to be connected with feed back recovery system.
4. solid-state hydrogenation plant according to claim 3, it is characterised in that:
The blower system includes blower (6), the first filter (81) that is successively connected with blower (6),
One air switching valve (8), and the second air hose (82), the 4th air hose that are connected respectively with the first air switching valve (8)
(83)；The blower (6), the first air switching valve (8) are connected with metering control instrument (5) respectively, the 4th air hose (83)
It is connected with feed back recovery system, the second air hose (82) is connected with Material supply system；
The attraction blower fan system includes attracting blower (7), successively with the second filter (91) for attracting blower (7) to be connected, the
Two air switching valves (9), and the first air hose (92), the third air hose that are connected respectively with the second air switching valve (9)
(93)；The attraction blower (7), the second air switching valve (9) are connected with metering control instrument (5) respectively, the first air hose (92)
It is connected with Material supply system, third air hose (93) is connected with feed back recovery system.
5. solid-state hydrogenation plant according to claim 1, it is characterised in that:
The Material supply system includes for storing the head tank of metal oxide (2), and head tank (2) passes through charge pipe (22)
It is connected with feeding gun (28).
6. solid-state hydrogenation plant according to claim 5, it is characterised in that:
The head tank (2) further includes the first weighing instrument (17) of the metal hydride weight in it for real-time monitoring, and first claims
Weight instrument (17) is connected with the metering control instrument (5) of hydrogenation plant control system.
7. solid-state hydrogenation plant according to claim 5, it is characterised in that:
The Material supply system further includes setting the first bucket (18) coupled below head tank (2), and first claims
Hopper (18) is connected by charge pipe (22) with feeding gun (28).
8. solid-state hydrogenation plant according to claim 5: it is characterized by:
It further include blower fan system, blower fan system includes the attraction blower fan system for being used to form negative pressure, and Material supply system also wraps
The the second trapping bucket (10) for including and blower fan system being attracted to be connected, the second trapping bucket (10) includes coupled mother tube (23).
9. solid-state hydrogenation plant according to claim 5, it is characterised in that:
The head tank (2) is connected with the second trapping bucket (10) of Material supply system by the first revolving valve (11), head tank
(2) it is connected with the first bucket (18) of head tank (2) by the 5th revolving valve, the first bucket (18) lower end is arranged second time
Rotary valve (12), the first revolving valve (11), the metering of the 5th revolving valve and the second revolving valve (12) with hydrogenation plant control system
Controller (5) is connected；
It further include blower fan system, blower fan system includes the blower system for delivery air, and the second revolving valve (12) passes through
Charge pipe (22) is connected with feeding gun (28), and is connected with blower system.
10. solid-state hydrogenation plant according to claim 1, it is characterised in that:
The feed back recovery system include feed back tank (3) for storing by-product and setting above feed back tank (3) and its
The first connected trapping bucket (13), the first trapping bucket (13) are connected by feed back pipe (32) with feeding gun (28).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810211858.0A CN110271867A (en) | 2018-03-14 | 2018-03-14 | Solid-state hydrogenation plant |
| PCT/CN2018/123006 WO2019174352A1 (en) | 2018-03-14 | 2018-12-24 | Solid hydrogenation unit |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810211858.0A CN110271867A (en) | 2018-03-14 | 2018-03-14 | Solid-state hydrogenation plant |
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| CN110271867A true CN110271867A (en) | 2019-09-24 |
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Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000136953A (en) * | 1998-08-27 | 2000-05-16 | Mitsui Chemicals Inc | Device for supplying fixed quantity of powder, and method for supplying fixed quantity of powder using the same |
| US20020029820A1 (en) * | 1999-11-06 | 2002-03-14 | Ovshinsky Stanford R. | Hydrogen infrastructure, a combined bulk hydrogen storage/single stage metal hydride hydrogen compressor therefor and alloys for use therein |
| CN1826492A (en) * | 2003-07-25 | 2006-08-30 | 丰田自动车株式会社 | Gas supply system |
| CN101092917A (en) * | 2007-07-21 | 2007-12-26 | 郑国璋 | Automobile fuel supply system |
| TWM411434U (en) * | 2011-04-29 | 2011-09-11 | Tension Energy Inc | Hydrogen gas production system |
| CN202988788U (en) * | 2012-12-13 | 2013-06-12 | 武汉海王新能源工程技术有限公司 | Modular-type catalytic hydrogenation deoxidization device for nuclear power station |
| CN204137906U (en) * | 2014-09-22 | 2015-02-04 | 中国石化扬子石油化工有限公司 | A kind of pulsed powder feeding device |
| CN106287208A (en) * | 2016-09-27 | 2017-01-04 | 北京市燃气集团有限责任公司 | A kind of natural gas scattered gas recoverable ANG of intelligence adsorbs bottle group device |
| CN106969259A (en) * | 2017-03-16 | 2017-07-21 | 石家庄新华能源环保科技股份有限公司 | Method and change station that a kind of metal hydride is changed |
| CN107605559A (en) * | 2017-08-04 | 2018-01-19 | 上海柯来浦能源科技有限公司 | Heat engine hydrogen reaction bed combined cycle system |
| CN206918640U (en) * | 2017-03-04 | 2018-01-23 | 张祖豪 | New hydrogen filling station |
| CN209113109U (en) * | 2018-03-14 | 2019-07-16 | 正泰集团股份有限公司 | Solid-state hydrogenation plant |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060269470A1 (en) * | 2004-04-14 | 2006-11-30 | Qinglin Zhang | Methods and devices for hydrogen generation from solid hydrides |
| CN101100285A (en) * | 2006-07-07 | 2008-01-09 | 中国科学院金属研究所 | Chemical hydride hydrogen storing material system, hydrogen preparing method and hydrogen preparing device |
| CN101186275A (en) * | 2007-12-03 | 2008-05-28 | 天津海蓝德能源技术发展有限公司 | Mobile hydrogen-generating hydrogen-storing integrated device and hydrogen supplying method thereof |
| CN101264863B (en) * | 2008-04-18 | 2010-10-13 | 浙江大学 | Method for synthesizing metal coordinate hydride hydrogen-storing material directly by reaction ball milling |
| CN101597023A (en) * | 2008-06-03 | 2009-12-09 | 中国科学院金属研究所 | Be applicable to the chemical hydride catalytic-hydrolysis device for producing hydrogen and the method for onboard hydrogen source |
| CN101891151A (en) * | 2010-07-07 | 2010-11-24 | 四川大学 | Magnesium-aluminum based hydride composite material for hydrolytic hydrogen production |
| CN104528649A (en) * | 2015-01-09 | 2015-04-22 | 华南理工大学 | CaMg2-based alloy hydride hydrolysis hydrogen production material and preparation method and application thereof |
| CN104649225B (en) * | 2015-02-15 | 2017-01-25 | 北京明德清源科技开发有限公司 | Portable all-solid hydrogen production material as well as preparation method and application thereof |
-
2018
- 2018-03-14 CN CN201810211858.0A patent/CN110271867A/en active Pending
- 2018-12-24 WO PCT/CN2018/123006 patent/WO2019174352A1/en active Application Filing
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000136953A (en) * | 1998-08-27 | 2000-05-16 | Mitsui Chemicals Inc | Device for supplying fixed quantity of powder, and method for supplying fixed quantity of powder using the same |
| US20020029820A1 (en) * | 1999-11-06 | 2002-03-14 | Ovshinsky Stanford R. | Hydrogen infrastructure, a combined bulk hydrogen storage/single stage metal hydride hydrogen compressor therefor and alloys for use therein |
| CN1826492A (en) * | 2003-07-25 | 2006-08-30 | 丰田自动车株式会社 | Gas supply system |
| CN101092917A (en) * | 2007-07-21 | 2007-12-26 | 郑国璋 | Automobile fuel supply system |
| TWM411434U (en) * | 2011-04-29 | 2011-09-11 | Tension Energy Inc | Hydrogen gas production system |
| CN202988788U (en) * | 2012-12-13 | 2013-06-12 | 武汉海王新能源工程技术有限公司 | Modular-type catalytic hydrogenation deoxidization device for nuclear power station |
| CN204137906U (en) * | 2014-09-22 | 2015-02-04 | 中国石化扬子石油化工有限公司 | A kind of pulsed powder feeding device |
| CN106287208A (en) * | 2016-09-27 | 2017-01-04 | 北京市燃气集团有限责任公司 | A kind of natural gas scattered gas recoverable ANG of intelligence adsorbs bottle group device |
| CN206918640U (en) * | 2017-03-04 | 2018-01-23 | 张祖豪 | New hydrogen filling station |
| CN106969259A (en) * | 2017-03-16 | 2017-07-21 | 石家庄新华能源环保科技股份有限公司 | Method and change station that a kind of metal hydride is changed |
| CN107605559A (en) * | 2017-08-04 | 2018-01-19 | 上海柯来浦能源科技有限公司 | Heat engine hydrogen reaction bed combined cycle system |
| CN209113109U (en) * | 2018-03-14 | 2019-07-16 | 正泰集团股份有限公司 | Solid-state hydrogenation plant |
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