CN110258183A - A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark - Google Patents
A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark Download PDFInfo
- Publication number
- CN110258183A CN110258183A CN201910654791.2A CN201910654791A CN110258183A CN 110258183 A CN110258183 A CN 110258183A CN 201910654791 A CN201910654791 A CN 201910654791A CN 110258183 A CN110258183 A CN 110258183A
- Authority
- CN
- China
- Prior art keywords
- photosensitive
- water
- multistage
- layer
- marble paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000004579 marble Substances 0.000 title claims abstract description 20
- 238000012546 transfer Methods 0.000 title claims abstract description 14
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010931 gold Substances 0.000 claims abstract description 17
- 229910052737 gold Inorganic materials 0.000 claims abstract description 17
- 239000003921 oil Substances 0.000 claims abstract description 16
- 239000002199 base oil Substances 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 239000004411 aluminium Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000009413 insulation Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 230000001464 adherent effect Effects 0.000 claims description 4
- HTCXJNNIWILFQQ-UHFFFAOYSA-M emmi Chemical compound ClC1=C(Cl)C2(Cl)C3C(=O)N([Hg]CC)C(=O)C3C1(Cl)C2(Cl)Cl HTCXJNNIWILFQQ-UHFFFAOYSA-M 0.000 claims description 3
- -1 glue-line Substances 0.000 claims description 2
- 238000007747 plating Methods 0.000 claims 2
- 239000005439 thermosphere Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 238000004806 packaging method and process Methods 0.000 abstract description 8
- 230000001681 protective effect Effects 0.000 abstract description 7
- 238000010023 transfer printing Methods 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 abstract description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 6
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 6
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229940051250 hexylene glycol Drugs 0.000 description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 3
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/175—Transfer using solvent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
Abstract
The present invention relates to field of anti-counterfeit technology; there is provided a kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark comprising successively fold photosensitive multistage photochromic layer (optically variable effect), aluminium coated, glue-line, gold stamping base oil layer, water-soluble layer and the water-transfer printing paper of the protective film set, protection gloss oil, surface irregularity.The water identified with photosensitive multistage color-changing anti-counterfeit the transfer marble paper can be directly by water transfer in the Packaging Bottle of inside, such as vial or ceramic bottle, so as to effectively reach antifalse effect.
Description
Technical field
The present invention relates to field of anti-counterfeit technology more particularly to a kind of water with photosensitive multistage color-changing anti-counterfeit mark to shift flower
Paper.
Background technique
With the improvement of the national economy and the development of press-packaging industry, requirement of the people to product packaging are not only height
It is shelves, exquisite, environmental protection, full of individuality, while the packaging for also wishing through product can distinguish the true and false of product.Currently, various
Packaging pastes antifalsification label mostly using the outer packaging box with anti-counterfeit structure, or in external packing box.However it is wrapped in inside
There is no effectively anti-fake measure is used in bottling, to influence anti-counterfeiting power.
Summary of the invention
It is an object of the invention to overcome the above-mentioned prior art, provide a kind of with photosensitive multistage color-changing anti-counterfeit mark
The water of knowledge shifts marble paper.
In order to solve the above technical problems, invention uses technical solution as described below.One kind has the discoloration of photosensitive multistage anti-
The water of puppet mark shifts marble paper, and the water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark includes the successively folded protection set
Film, protection gloss oil, the photosensitive multistage photochromic layer of surface irregularity, coating, glue-line, gold stamping base oil layer, water-soluble layer and water transfer
Paper.
Preferably, the photosensitive multistage photochromic layer is coated on the protection gloss oil by the way that adherent coatings are made in photosensitive material
Surface carries out compacting formation using template.
Preferably, thermal insulation layer is additionally provided between the protection gloss oil and the photosensitive multistage photochromic layer.
Preferably, the thermal insulation layer with a thickness of 0.2-2 μm.
Preferably, the overall thickness of the protective film and protection gloss oil is 0.2-0.5 μm.
Preferably, the coating is aluminium layer.
Preferably, the coating with a thickness of 300-800 Ethylmercurichlorendimide.
The beneficial effects of the present invention are:
This can directly be transferred in internal Packaging Bottle with the water transfer marble paper that photosensitive multistage color-changing anti-counterfeit identifies, such as glass
Glass bottle or ceramic bottle, so as to effectively reach antifalse effect.And the photosensitive multistage photochromic layer of surface irregularity can be not
Different color effects are changing into after reflecting with angle light source.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the water transfer marble paper in the present invention with photosensitive multistage color-changing anti-counterfeit mark.
Fig. 2 is the structure of the water transfer marble paper in some preferred embodiments of the invention with photosensitive multistage color-changing anti-counterfeit mark
Schematic diagram.
Specific embodiment
To make those skilled in the art that the purposes, technical schemes and advantages of invention be more clearly understood, below
Invention is further elaborated in conjunction with the accompanying drawings and embodiments.
As shown in Figure 1, a kind of water with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, including successively folding the protection set
Film 10, protection gloss oil 20, gold stamping layer 30, gold stamping base oil layer 40, water-soluble layer 50 and water-transfer printing paper 60.There is photosensitive multistage to become for this
The water transfer marble paper of color anti-counterfeiting mark when in use, by using aqueous solvent by 60 separation of water-soluble layer 50 and water-transfer printing paper, makes
Obtaining protective film 10, protection gloss oil 20, gold stamping layer 30, gold stamping base oil layer 40 can transfer will be made directly in Packaging Bottle, to realize anti-
Pseudo- function.
Wherein, gold stamping layer 30 specifically include successively fold the photosensitive multistage photochromic layer 31 of surface irregularity set, coating 32,
Glue-line 33.Photosensitive multistage photochromic layer 31 is stacked with protection gloss oil 20 and sets, and glue-line 33 is stacked with gold stamping base oil layer 40 and sets.
Preferably, the photosensitive multistage photochromic layer 31 is coated on by the way that adherent coatings are made in photosensitive multistage off-color material
10 surface of protective film of protection gloss oil 20, using template carries out compacting formation.It is appreciated that the work of photosensitive multistage photochromic layer 31
With to show different colours, and different color effects can be changing into after the refraction of different angle light source.Specifically, lead to
It crosses and the protective film that adherent coatings have been coated on protection gloss oil 20 is made using the photosensitive multistage off-color material of a variety of different colours
10 surfaces carry out compacting formation using template, to obtain coloury pattern-information, so that gold stamping layer be made to have different light
Become effect, improves anti-counterfeit capability.In addition, template is made using binary optical, so that light according to polarisation principle calculating optical structure
Unwanted chromatography can be filtered and reflect required color by learning mother matrix, and rotation light becomes thermoprint and gorgeous multicolour variation is presented,
Template can be namely made according to actual needs, to obtain different photosensitive multistage photochromic layers 31, to realize different effects
Fruit.
In specific implementation, check that the angle of anti-counterfeiting information is more inclined, anti-counterfeit capability is stronger.To improve the anti-of transfer paste marble paper
Pseudo- effect, according to polarisation principle calculating optical structure, utilizes binary optical under the angle for not influencing security devices visualization of information
Template is made, so that the angle of the chromatography of optical master reflection increases, to obtain more inclined security devices information viewing angle.
Wherein, protective film 10 can be water wax layer or resin layer as made of wax solution or resin solution coating drying,
The overall thickness of protective film 10 and protection gloss oil 20 is generally 0.2-0.5 μm.Preferably, the coating 32 is aluminium layer, the coating
32 with a thickness of 300-800 Ethylmercurichlorendimide.
The gold stamping base oil layer 40 is printed on the water-transfer printing paper 60 for having applied water-soluble layer 50 and is toasted by gold stamping base oil
It arrives, the gold stamping base oil is the gold stamping base oil of UV, and wherein contains polyvinyl alcohol, and baking temperature is 160-180 DEG C, and when baking is a length of
0.5h。
In certain embodiments, the composition of the gold stamping base oil of used UV are as follows: 15-35 parts of EVA resin, methyl methacrylate
5-15 parts of ester (MMA), 5-15 parts of pentaerythritol triacrylate (PETA), trimethylolpropane trimethacrylate (TMPTMA)
10-25 parts, 1,6- 5-10 parts of hexylene glycol double methacrylate (HDDA), two 5-10 parts of contracting propylene glycol double methacrylates (DPGDA), 2,
0.5-10 parts of 4,6-trimethyl benzoyl diphenyl base phosphine oxides (TPO).Such as:
In one embodiment, the composition of the gold stamping base oil of used UV are as follows: 25 parts of EVA resin, methyl methacrylate
(MMA) 11 parts, 8 parts of pentaerythritol triacrylate (PETA), 17 parts of trimethylolpropane trimethacrylate (TMPTMA), 1,6-
9 parts of hexylene glycol double methacrylate (HDDA), two 6 parts of contracting propylene glycol double methacrylates (DPGDA), 2,4,6-trimethylbenzoyls
1.8 parts of diphenyl phosphine oxide (TPO).
In another embodiment, the composition of the gold stamping base oil of used UV are as follows: 28 parts of EVA resin, methyl methacrylate
(MMA) 7 parts, 10 parts of pentaerythritol triacrylate (PETA), 23 parts of trimethylolpropane trimethacrylate (TMPTMA), 1,6-
9 parts of hexylene glycol double methacrylate (HDDA), two 6 parts of contracting propylene glycol double methacrylates (DPGDA), 2,4,6-trimethylbenzoyls
3.5 parts of diphenyl phosphine oxide (TPO).
As shown in Figure 2, it is preferable that be additionally provided with thermal insulation layer between the protection gloss oil 20 and the photosensitive multistage photochromic layer 31
70, the photosensitive multistage photochromic layer 31 is covered on the thermal insulation layer 70 by ink for screen printing and solidification.Preferably, described heat-insulated
Layer 70 with a thickness of 0.2-2 μm.The thermal insulation layer 70 can be to be obtained using insulating moulding coating coating drying, and insulating moulding coating includes receiving
Rice heat-barrier material, nanometer heat insulation material are nano-stannic oxide or nanometer antimony oxide.
Claims (7)
1. a kind of water with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: including successively folding the protection set
Film, protection gloss oil, the photosensitive multistage photochromic layer of surface irregularity, coating, glue-line, gold stamping base oil layer, water-soluble layer and water transfer
Paper.
2. the water as described in claim 1 with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: the sense
Light multistage photochromic layer is coated on the protection gloss oil surface by the way that adherent coatings are made in photosensitive material, is suppressed using template
It is formed.
3. the water as described in claim 1 with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: the guarantor
Thermal insulation layer is additionally provided between shield gloss oil and the photosensitive multistage photochromic layer.
4. as claimed in claim 3 with photosensitive multistage color-changing anti-counterfeit mark water shift marble paper, it is characterised in that: it is described every
Thermosphere with a thickness of 0.2-2 μm.
5. the water as described in claim 1 with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: the guarantor
The overall thickness of cuticula and protection gloss oil is 0.2-0.5 μm.
6. the water as described in claim 1 with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: the plating
Layer is aluminium layer.
7. the water as claimed in claim 6 with photosensitive multistage color-changing anti-counterfeit mark shifts marble paper, it is characterised in that: the plating
Layer with a thickness of 300-800 Ethylmercurichlorendimide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910654791.2A CN110258183A (en) | 2019-07-19 | 2019-07-19 | A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910654791.2A CN110258183A (en) | 2019-07-19 | 2019-07-19 | A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110258183A true CN110258183A (en) | 2019-09-20 |
Family
ID=67927300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910654791.2A Pending CN110258183A (en) | 2019-07-19 | 2019-07-19 | A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110258183A (en) |
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|---|---|---|---|---|
| CN105636797A (en) * | 2013-06-28 | 2016-06-01 | 联邦国营企业"Goznak" | Multi-layer product containing a protective element on the surface of a paper or polymer carrier, and product authenticity determination method |
| CN106379014A (en) * | 2016-11-01 | 2017-02-08 | 苏州市兴丰强纺织科技有限公司 | Temperature sensing color change cloth and preparation method thereof |
| CN108725010A (en) * | 2018-06-04 | 2018-11-02 | 深圳市柏星龙创意包装股份有限公司 | Stamping systems and preparation method thereof |
| CN109050134A (en) * | 2018-07-02 | 2018-12-21 | 武汉华工图像技术开发有限公司 | Holographic gold stamping film, holographic water transfer marble paper and preparation method thereof |
| CN208497997U (en) * | 2018-07-02 | 2019-02-15 | 武汉华工图像技术开发有限公司 | The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper |
| CN208664513U (en) * | 2018-07-02 | 2019-03-29 | 武汉华工图像技术开发有限公司 | The high holographic gold stamping film of positioning accuracy and holographic water transfer marble paper |
| CN210766189U (en) * | 2019-07-19 | 2020-06-16 | 惠州柏星龙包装有限公司 | Water transfer stained paper with photosensitive multi-section color-changing anti-counterfeiting mark |
-
2019
- 2019-07-19 CN CN201910654791.2A patent/CN110258183A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105636797A (en) * | 2013-06-28 | 2016-06-01 | 联邦国营企业"Goznak" | Multi-layer product containing a protective element on the surface of a paper or polymer carrier, and product authenticity determination method |
| CN106379014A (en) * | 2016-11-01 | 2017-02-08 | 苏州市兴丰强纺织科技有限公司 | Temperature sensing color change cloth and preparation method thereof |
| CN108725010A (en) * | 2018-06-04 | 2018-11-02 | 深圳市柏星龙创意包装股份有限公司 | Stamping systems and preparation method thereof |
| CN109050134A (en) * | 2018-07-02 | 2018-12-21 | 武汉华工图像技术开发有限公司 | Holographic gold stamping film, holographic water transfer marble paper and preparation method thereof |
| CN208497997U (en) * | 2018-07-02 | 2019-02-15 | 武汉华工图像技术开发有限公司 | The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper |
| CN208664513U (en) * | 2018-07-02 | 2019-03-29 | 武汉华工图像技术开发有限公司 | The high holographic gold stamping film of positioning accuracy and holographic water transfer marble paper |
| CN210766189U (en) * | 2019-07-19 | 2020-06-16 | 惠州柏星龙包装有限公司 | Water transfer stained paper with photosensitive multi-section color-changing anti-counterfeiting mark |
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