CN208497997U - The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper - Google Patents

The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper Download PDF

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Publication number
CN208497997U
CN208497997U CN201821048363.2U CN201821048363U CN208497997U CN 208497997 U CN208497997 U CN 208497997U CN 201821048363 U CN201821048363 U CN 201821048363U CN 208497997 U CN208497997 U CN 208497997U
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holographic
layer
positioning
gold stamping
temperature tolerance
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徐晓光
鲁琴
徐向荣
牟靖文
杨志方
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Wuhan Huagong Image Technology & Development Co Ltd
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Wuhan Huagong Image Technology & Development Co Ltd
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Abstract

A kind of holographic gold stamping film that temperature tolerance is high and holographic water transfer marble paper, are related to anti-counterfeit package printing technology.The high holographic gold stamping film of the temperature tolerance of the utility model embodiment includes the base membrane layer for being sequentially overlapped setting from the bottom to top, release layer, thermal insulation layer, chromatograph, positioning holographic layer, coating and glue-line, positioning holographic patterns are provided on positioning holographic layer, the holographic gold stamping film increases thermal insulation layer and chromatograph, improves the temperature tolerance that water transfers the water to be formed transfer marble paper.The holographic water transfer marble paper of the utility model embodiment includes the release layer for being sequentially overlapped setting from the bottom to top, thermal insulation layer, chromatograph, positioning holographic layer, coating, glue-line, gold stamping base oil layer and water-transfer printing paper, multiple positioning holographic patterns are intervally distributed on positioning holographic layer, positioning holographic patterns are provided on positioning holographic layer, the temperature tolerance which transfers marble paper is high.

Description

The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper
Technical field
The utility model relates to anti-counterfeit package printing technologies, scald in particular to a kind of holography that temperature tolerance is high Golden film and holographic water transfer marble paper.
Background technique
It is lucuriant in design that water at low temperature transfers marble paper, and has the characteristics such as ethanol-tolerant, wear-resisting, and when use only needs low-temperature bake, It can be widely applied to the product surfaces such as glass wine bottle, ceramics, metal, plastics.Common water transfer marble paper does not have holographic false proof figure Case has significant limitations in terms of antifalsification and aesthetics.Therefore holographic security technology is combined with water transfer technique obtained Holographic water transfer marble paper have great application prospect and market potential.
If holographic water transfer marble paper is for product surfaces such as glass wine bottle, ceramics, metals, it is necessary to pass through one of Roaster Sequence, it is desirable that toasted under the conditions of 160~210 DEG C at least 30 minutes, baking temperature is higher, and water transfer pattern is adhered to product surface Fastness it is stronger.But baking temperature is higher, also higher to the temperature tolerance requirement of holographic water transfer marble paper, if holographic water transfer flower The temperature tolerance of paper is insufficient, it may appear that the problems such as cracking, bubble, discoloration or holography loss of gloss.
The temperature tolerance of the holographic water transfer marble paper made at present can reach the realistic scale toasted at 210 DEG C 30 minutes, but This is only limitted to light color/silver color holography water transfer marble paper, transfers marble paper for dark holographic water, temperature tolerance is not still able to satisfy reality With requiring, such as the temperature tolerance of the holographic water transfer marble paper of current navy blue, green is unable to satisfy real requirement.Because of dark material Material needs to would necessarily affect the heat resistance of dark holographic water transfer marble paper using greater proportion of toner.With society It continues to develop, there is an urgent need to more kinds of water to transfer marble paper in market, both include various hologram patterns, it is also desirable to more colour system materials Material.Only solve the problems, such as that the temperature tolerance of dark holographic water transfer marble paper, holographic water transfer marble paper just have higher practical valence Value.
Therefore, it is necessary to a kind of high holographic water of temperature tolerance to transfer marble paper.
Utility model content
The purpose of this utility model is to provide a kind of holographic gold stamping films that temperature tolerance is high, and which increase thermal insulation layers and color Layer improves the temperature tolerance that water transfers the water to be formed transfer marble paper.
The another object of the utility model is to provide a kind of holographic water transfer marble paper, temperature tolerance height.
The embodiments of the present invention are achieved in that
A kind of holographic gold stamping film that temperature tolerance is high comprising be sequentially overlapped from the bottom to top the base membrane layer of setting, release layer, every Thermosphere, chromatograph, positioning holographic layer, coating and glue-line are provided with positioning holographic patterns on positioning holographic layer.
In the utility model preferred embodiment, it is complete that the upper surface of above-mentioned positioning holographic layer is intervally distributed with multiple positioning Cease pattern.
In the utility model preferred embodiment, above-mentioned thermal insulation layer with a thickness of 0.5~3 μm;Thermal insulation layer be using every Hot coating coating drying obtains, and insulating moulding coating includes nanometer heat insulation material, and nanometer heat insulation material is nano-stannic oxide or nanometer Tin-antiomony oxide.
In the utility model preferred embodiment, above-mentioned chromatograph with a thickness of 0.6~2 μm.
In the utility model preferred embodiment, above-mentioned positioning holographic layer with a thickness of 0.6~1.5 μm.
In the utility model preferred embodiment, above-mentioned coating is metallic aluminum or zinc sulphide dielectric layer;The thickness of coating Degree is 300~500 Ethylmercurichlorendimides.
In the utility model preferred embodiment, above-mentioned glue-line with a thickness of 0.5~2 μm.
A kind of holography water transfer marble paper comprising be sequentially overlapped the release layer of setting from the bottom to top, thermal insulation layer, chromatograph, determine Position hologram layer, coating, glue-line, gold stamping base oil layer and water-transfer printing paper, are intervally distributed with multiple positioning holographics on positioning holographic layer Pattern is provided with positioning holographic patterns on positioning holographic layer.
In the utility model preferred embodiment, above-mentioned further includes the printing layer being superposed under release layer.
In the utility model preferred embodiment, it is above-mentioned further include be superposed under printing layer can dyestripping.
The beneficial effect of the utility model embodiment is: the high holographic gold stamping film packet of the temperature tolerance of the utility model embodiment The base membrane layer for being sequentially overlapped setting from the bottom to top, release layer, thermal insulation layer, chromatograph, positioning holographic layer, coating and glue-line are included, is positioned Positioning holographic patterns are provided on hologram layer, which increases thermal insulation layer and chromatograph, improves water and transfers the water to be formed Transfer the temperature tolerance of marble paper.The utility model embodiment holographic water transfer marble paper include be sequentially overlapped from the bottom to top setting from Type layer, thermal insulation layer, chromatograph, positioning holographic layer, coating, glue-line, gold stamping base oil layer and water-transfer printing paper, are spaced on positioning holographic layer Multiple positioning holographic patterns are distributed with, are provided with positioning holographic patterns on positioning holographic layer, which transfers the heatproof of marble paper Property it is high.
Detailed description of the invention
It, below will be to use required in embodiment in order to illustrate more clearly of the technical solution of the utility model embodiment Attached drawing be briefly described, it should be understood that the following drawings illustrates only some embodiments of the utility model, therefore should not be by Regard the restriction to range as, for those of ordinary skill in the art, without creative efforts, may be used also To obtain other relevant attached drawings according to these attached drawings.
Fig. 1 is a kind of structural schematic diagram for holographic gold stamping film that the utility model embodiment 1 provides;
Fig. 2 is that a kind of holographic water that the utility model embodiment 2 provides transfers the structural schematic diagram of marble paper;
Fig. 3 is that a kind of holographic water that the utility model embodiment 3 provides transfers the structural schematic diagram of marble paper;
Fig. 4 is that a kind of holographic water that comparative example 1 provides transfers the structural schematic diagram of marble paper.
Icon: 100- holographic gold stamping film;110- base membrane layer;120- release layer;130- thermal insulation layer;140- chromatograph;150- is fixed Position hologram layer;151- positioning holographic patterns;160- coating;170- glue-line;200- holography water transfers marble paper;210- water-transfer printing paper ?;The gold stamping base oil layer of 220-;300- holography water transfers marble paper;310- can dyestripping;320- printing layer;400- holography positions water transfer Marble paper;410- can dyestripping;420- printing layer;430- release layer;440- positioning holographic layer;441- positioning holographic patterns;450- plating Layer;460- glue-line;The gold stamping base oil layer of 470-;480- water-transfer printing paper.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.The present invention being usually described and illustrated herein in the accompanying drawings is implemented The component of example can be arranged and be designed with a variety of different configurations.
Therefore, the detailed description of the embodiment of the present invention provided in the accompanying drawings is not intended to limit below claimed The scope of the present invention, but be merely representative of selected embodiment of the invention.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without creative efforts belongs to the model that the present invention protects It encloses.
It should also be noted that similar label and letter indicate similar terms in following attached drawing, therefore, once a certain Xiang Yi It is defined in a attached drawing, does not then need that it is further defined and explained in subsequent attached drawing.
In the description of the present invention, it should be noted that the orientation or position of the instructions such as term " on ", "lower", "inner", "outside" Set relationship be based on the orientation or positional relationship shown in the drawings or the invention product using when the orientation or position usually put Relationship is set, is merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning are necessary It with specific orientation, is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.
In the description of the present invention, it is also necessary to which explanation is unless specifically defined or limited otherwise, term " setting " is answered It is interpreted broadly, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can be mechanical connect It connects, is also possible to be electrically connected;It can be directly connected, can also can be in two elements indirectly connected through an intermediary The connection in portion.For the ordinary skill in the art, the tool of above-mentioned term in the present invention can be understood with concrete condition Body meaning.
Embodiment 1
It please refers to shown in Fig. 1, the present embodiment provides a kind of holographic gold stamping films 100 that temperature tolerance is high comprising from the bottom to top It is sequentially overlapped base membrane layer 110, release layer 120, thermal insulation layer 130, chromatograph 140, positioning holographic layer 150, coating 160 and the glue of setting Layer 170, chromatograph 140 can be light coating or dark coating, and specifically for dark coating, it is fixed to be provided on positioning holographic layer 150 Position hologram pattern 151.
Wherein, base membrane layer 110 can be PET, BOPP, BOPET or PVC film, the thickness of base membrane layer 110 is generally 10~ 35μm.In the present embodiment, base membrane layer 110 is the BOPP film with a thickness of 20 μm.
Wherein, release layer 120 can be the water wax layer as made of wax solution or resin solution coating drying or resin is release Layer 120, the thickness of release layer 120 is generally 0.2~0.5 μm.In the present embodiment, release layer 120 is the water wax with a thickness of 0.5 μm Layer removes the base membrane layer 110 on release layer 120 after holographic gold stamping film 100 and water-transfer printing paper Zhang Fuhe.
Wherein, thermal insulation layer 130 is obtained using insulating moulding coating coating drying, and insulating moulding coating includes nanometer heat insulation material, is received Rice heat-barrier material is nano-stannic oxide or nano antimony tin oxide, and insulating moulding coating specifically includes according to the mass fraction: vinyl chloride-vinegar 10-20 parts of vinyl acetate resin;5-15 parts of acrylic resin;3-5 parts of nanometer heat insulation material;80-92 parts of solvent, nano heat-insulating material Material is nano-stannic oxide or nano antimony tin oxide, and solvent is butanone, ethyl ester, one kind of n-propyl acetate or at least two appoints Meaning combination.The thickness of thermal insulation layer 130 is generally 0.5~3 μm.In the present embodiment, thermal insulation layer 130 is using by vinyl chloride-acetic acid Vinylester resin 10g, acrylic resin 5g, nano-stannic oxide 5g and butanone/n-propyl acetate (mass ratio 1:1) 80g composition Insulating moulding coating coating drying obtain, and thermal insulation layer 130 with a thickness of 3 μm.
Wherein, chromatograph 140 can be is obtained using colored paint coating drying, and colored paint includes: according to the mass fraction 10~20 parts of methacrylic resin;5~15 parts of acrylic resin;5~15 parts of curing agent;5~20 parts of toner;Solvent 60~ 160 parts, curing agent is-the OH ,-NH that can contain with acrylic resin2Or the isocyanates or acyl chloride compound of-SH reaction One of or at least two any combination;Solvent be butanone, ethyl ester, one kind of n-propyl acetate or at least two it is any Combination.The thickness of chromatograph 140 is generally 0.6~2 μm.In the present embodiment, chromatograph 140 be using by methacrylic resin 20g, Acrylic resin 5g, isocyanic acid 10g, blue powder 10g, butanone/n-propyl acetate (mass ratio 1:1) 160g composition colored paint Coating drying obtain, and chromatograph 140 with a thickness of 0.6 μm.
Wherein, positioning holographic layer 150 can be using holographic dope coating drying obtains, and on it surface modes swaging at Multiple positioning holographic patterns 151 being spaced apart, holographic dope include: methacrylic resin 10~20 according to the mass fraction Part;5~15 parts of acrylic resin;8~15 parts of curing agent;50~160 parts of solvent, curing agent is that can contain with acrylic resin - OH ,-NH2- SH reaction isocyanates or one of acyl chloride compound or at least two any combination;It is molten Agent be butanone, ethyl ester, one kind of n-propyl acetate or at least two any combination.The thickness of positioning holographic layer 150 is generally 0.6~1.5 μm.In the present embodiment, positioning holographic layer 150 is using by methacrylic resin 10g, acrylic resin 5g, different The holographic dope coating drying of cyanic acid 15g, butanone/n-propyl acetate (mass ratio 1:1) 120g composition obtains, and positioning holographic layer 150 with a thickness of 1 μm.
Wherein, coating 160 can be metallic aluminum or zinc sulphide dielectric layer;The thickness of coating 160 is generally 300~500 Ethylmercurichlorendimide.In the present embodiment, coating 160 is with a thickness of the metallic aluminum of 400 Ethylmercurichlorendimides.
Wherein, glue-line 170 with a thickness of 1 μm.
The holographic gold stamping film 100 of the present embodiment increases thermal insulation layer 130 and chromatograph 140, when use water transfer technique will be complete After breath gilding film 100 is transferred to substrate surface, in the high temperature baking and curing stage, heat is from printing layer 320 to positioning holographic layer 150 In transmittance process, thermal insulation layer 130 plays certain heat insulation, so that the temperature of positioning holographic layer 150 is lower than environment temperature, Advantageously ensure that the heat resistance of positioning holographic layer 150.In addition, for holographic gold stamping film 100, with powder dark in coloring layer 140 The increase of ratio, 140 heat resistance of chromatograph can reduce, if hologram pattern (holographic microstructure) is directly arranged at 140 table of chromatograph Face, under high-temperature situation, chromatograph 140 is easy to crack, blister, and the holographic microstructure on 140 surface of chromatograph is easily deformable to lead to holography The obfuscation of pattern loss of gloss, the present embodiment is due to being respectively provided with chromatograph 140 and positioning holographic layer 150, in same baking temperature condition Under, the generation of temperature tolerance problem is avoided, is also beneficial to avoid the problem that occurring directly being embossed in version easy to stick on chromatograph 140.
Embodiment 2
Shown in referring to figure 2., the present embodiment provides a kind of holographic water to transfer marble paper 200, mainly by the complete of embodiment 1 Breath gilding film 100 and water-transfer printing paper 210 are combined.Holographic water transfer marble paper 200 specifically includes to be sequentially overlapped from the bottom to top Release layer 120, thermal insulation layer 130, chromatograph 140, positioning holographic layer 150, coating 160, glue-line 170, the gold stamping base oil layer 220 of setting 210 are opened with water-transfer printing paper, is intervally distributed with multiple positioning holographic patterns 151 on positioning holographic layer 150, chromatograph 140 can be shallowly Color coating or dark coating are provided with positioning holographic patterns 151 specifically for dark coating on positioning holographic layer 150.
The present embodiment also provides a kind of production method of holographic water transfer marble paper 200 comprising following steps:
S1, the holographic gold stamping film 100 for making embodiment 1.
S2, positioning transfer: it is first printed on water-transfer printing paper 210 with the positioning of gold stamping base oil, then will be complete with positioning bronzing machine Breath gilding film 100 carries out composite transferring with the water-transfer printing paper 210 for being printed on gold stamping base oil, and positioning holographic patterns 151 are transferred to On water-transfer printing paper 210, gold stamping base oil becomes gold stamping base oil layer 220, then removes base membrane layer 110, obtains holographic water transfer marble paper 200。
Embodiment 3
Shown in referring to figure 3., the present embodiment provides a kind of holographic water to transfer marble paper 300, mainly by the complete of embodiment 1 Breath gilding film 100 and water-transfer printing paper 210 are combined.Holographic water transfer marble paper 300 specifically includes to be sequentially overlapped from the bottom to top Be arranged can dyestripping 310, printing layer 320, release layer 120, thermal insulation layer 130, chromatograph 140, positioning holographic layer 150, coating 160, Glue-line 170, gold stamping base oil layer 220 and water-transfer printing paper open 210, are intervally distributed with multiple position holograms on positioning holographic layer 150 Case 151, chromatograph 140 can be light coating or dark coating, and specifically for dark coating, it is fixed to be provided on positioning holographic layer 150 Position hologram pattern 151.
The present embodiment also provides a kind of production method of holographic water transfer marble paper 300 comprising following steps:
S1, the holographic gold stamping film 100 for making embodiment 1.
S2, positioning transfer: it is first printed on water-transfer printing paper 210 with the positioning of gold stamping base oil, then will be complete with positioning bronzing machine Breath gilding film 100 carries out composite transferring with the water-transfer printing paper 210 for being printed on gold stamping base oil, and positioning holographic patterns 151 are transferred to On water-transfer printing paper 210, gold stamping base oil becomes gold stamping base oil layer 220, then removes base membrane layer 110.
(3) positioning printing: in 120 surface printing picture and text of release layer, brush protection gloss oil, printing layer 320 is formed, then being superimposed can Dyestripping 310 obtains holographic water transfer marble paper 300.
Comparative example 1
Shown in Figure 4, comparative example 1 discloses a kind of holographic positioning water transfer marble paper 400 comprising from the bottom to top successively What is be superposed can dyestripping 410, printing layer 420, release layer 430, positioning holographic layer 440, coating 450, glue-line 460, gold stamping bottom Oil reservoir 470, water-transfer printing paper open 480.It wherein can dyestripping 410, printing layer 420, release layer 430, coating 450, water-transfer printing paper 480 With in embodiment 2 material and thickness it is identical, positioning holographic layer 440 is directly to be molded positioning holographic patterns 441 on chromatograph surface It is formed.
The holographic positioning water transfer marble paper of this comparative example produces to obtain using following common process:
(1) holographic positioning bronzing film is made, from top to bottom sequentially connected base membrane layer, release layer 430, positioning holographic layer 440, coating 450 and glue-line 460.
(2) it positioning transfer: is first printed on water-transfer printing paper 480 with the positioning of gold stamping base oil, then will be complete with positioning bronzing machine Breath positioning bronzing film carries out composite transferring with the water-transfer printing paper 480 for being printed on gold stamping base oil, and positioning holographic patterns 151 are transferred to On water-transfer printing paper 480, gold stamping base oil becomes gold stamping base oil layer 220, then removes base membrane layer 110.
(3) positioning printing: printing image-text, protection gloss oil form printing layer 420, add can dyestripping 410, obtain holographic fixed Position water transfers marble paper 400.
The temperature tolerance of the product of embodiment 2, comparative example 1, alcohol resistance, thermoprint, molding brightness are detected respectively, examined The results are shown in Table 1 for survey.
1 testing result of table
As can be seen from the above table, the temperature tolerance of the holographic positioning water transfer marble paper of the present embodiment is substantially better than according to conventional work Holography made from skill positions the temperature tolerance of water transfer marble paper.
In conclusion the high holographic gold stamping film of the temperature tolerance of the utility model increases thermal insulation layer and chromatograph, improves water and turn Impression at water transfer marble paper temperature tolerance;The temperature tolerance of the holographic water transfer marble paper of the utility model is high.
The above descriptions are merely preferred embodiments of the present invention, is not intended to limit the utility model, for this For the technical staff in field, various modifications and changes may be made to the present invention.It is all in the spirit and principles of the utility model Within, any modification, equivalent replacement, improvement and so on should be included within the scope of protection of this utility model.

Claims (10)

1. a kind of holographic gold stamping film that temperature tolerance is high, which is characterized in that it include the base membrane layer for being sequentially overlapped setting from the bottom to top, Release layer, thermal insulation layer, chromatograph, positioning holographic layer, coating and glue-line are provided with positioning holographic patterns on the positioning holographic layer.
2. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the upper table of the positioning holographic layer Multiple positioning holographic patterns are distributed in face interval.
3. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the thermal insulation layer with a thickness of 0.5~3 μm;The thermal insulation layer is obtained using insulating moulding coating coating drying, and the insulating moulding coating includes nanometer heat insulation material, institute Stating nanometer heat insulation material is nano-stannic oxide or nano antimony tin oxide.
4. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the chromatograph with a thickness of 0.6 ~2 μm.
5. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the thickness of the positioning holographic layer It is 0.6~1.5 μm.
6. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the coating be metallic aluminum or Zinc sulphide dielectric layer;The coating with a thickness of 300~500 Ethylmercurichlorendimides.
7. the high holographic gold stamping film of temperature tolerance according to claim 1, which is characterized in that the glue-line with a thickness of 0.5 ~2 μm.
8. a kind of holography water transfers marble paper, which is characterized in that it includes the release layer for being sequentially overlapped setting from the bottom to top, heat-insulated Layer, chromatograph, positioning holographic layer, coating, glue-line, gold stamping base oil layer and water-transfer printing paper, are spaced apart on the positioning holographic layer There are multiple positioning holographic patterns, is provided with positioning holographic patterns on the positioning holographic layer.
9. holography water according to claim 8 transfers marble paper, which is characterized in that it further includes being superposed described release Printing layer under layer.
10. holography water according to claim 9 transfers marble paper, which is characterized in that it further includes being superposed in the print Under brush layer can dyestripping.
CN201821048363.2U 2018-07-02 2018-07-02 The high holographic gold stamping film of temperature tolerance and holographic water transfer marble paper Active CN208497997U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110258183A (en) * 2019-07-19 2019-09-20 惠州柏星龙包装有限公司 A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110258183A (en) * 2019-07-19 2019-09-20 惠州柏星龙包装有限公司 A kind of water transfer marble paper with photosensitive multistage color-changing anti-counterfeit mark

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