CN110256880A - A kind of anti-flaming dope for fire-proof doors and windows - Google Patents
A kind of anti-flaming dope for fire-proof doors and windows Download PDFInfo
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- CN110256880A CN110256880A CN201910297348.4A CN201910297348A CN110256880A CN 110256880 A CN110256880 A CN 110256880A CN 201910297348 A CN201910297348 A CN 201910297348A CN 110256880 A CN110256880 A CN 110256880A
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- Prior art keywords
- fire
- parts
- proof doors
- flaming dope
- windows
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of anti-flaming dopes for fire-proof doors and windows of technical field of coatings, include liquid sodium silicate, organic resin, chemical assistant, methyl-monosilane alkyd sodium, melamine phosphate, aluminium hydroxide, amino phenyl sulfonyl hydrochlorate, inorfil and fire resistant infilling, intumescent and Non-expansive fireproof paint are combined, both contain intumescent component in formula, contain more fire resistant infilling component again, and addition has dystectic inorfil etc., so that coating is capable of forming the high strength carbonizing layer of low thermal expansion under thermal-flame effect, ensure expand coating can long-time refractory heat-insulating and do not fall off, flame retardance element uses melamine phosphate and aluminium hydroxide simultaneously, with good thermal stability and acid-alkali-corrosive-resisting, added with methyl-monosilane alkyd sodium, when it is exposed in air, it can quick solidification, and to fireproof coating Each component solidified, improve the curing rate of coating.
Description
Technical field
The present invention relates to technical field of coatings, specially a kind of anti-flaming dope for fire-proof doors and windows.
Background technique
Fireproof coating is to reduce by the combustibility of painting material surface for flammable substrates surface, block the fast of fire
Speed sprawling, to improve by a kind of sapecial coating of painting material fire endurance.It is applied to flammable substrates surface, to change material
Expect that surface burning characteristics, retardance fire are spread rapidly;Or it is applied on building element, the spy of the fire endurance to improve component
Kind coating, claims fireproof coating.
Fire-proof and thermal-insulation principle coated in ultrathin type or thin section steel structure fire-resisting paint on steel construction be fireproof coating layer by
It is expanded foamed when fiery, foam is formed, froth bed has not only completely cut off oxygen, but also has good heat-insulated because its quality is loose
Performance, can retardation heat be transmitted to the fire prevention by the speed of protection substrate, coated in the thicker fire-resistant coating for steel structure on steel member
Mechanism of heat insulation is that by coating when fire volume change is not occurred for fireproof coating substantially, but coating thermal conductivity is very low, retardation heat
It is transmitted to by the speed of guarantor's substrate.
Above two fireproof coating is belonging respectively to intumescent and Non-expansive fireproof paint, and wherein expanding fire-proof paint is in high temperature
Expansion rate under flame interaction is higher, fire resistance relative deficiency, although fire resistance is preferable at high temperature for Non-expansive fireproof paint,
But it is easy to fall off under long-time calcination, fire protecting performance is influenced, while when producing and using, the curing rate of conventional fireproof coating
It is relatively slow, wait curing time long when being coated on product, fireproof coating is resistance to when furthermore using under some particular surroundings
Acid-base property is bad, is easy to be corroded.
Summary of the invention
The purpose of the present invention is to provide a kind of anti-flaming dopes for fire-proof doors and windows, to solve to mention in above-mentioned background technique
Expansion rate of the expanding fire-proof paint out under the action of thermal-flame is higher, fire resistance relative deficiency, non-expansion type fire prevention
Although fire resistance is preferable at high temperature for coating, easy to fall off under long-time calcination, fire protecting performance is influenced, while making in production
The curing rate of used time, conventional fireproof coating are relatively slow, wait curing time long when being coated on product, furthermore in some spies
The problem of resistance to acid and alkali of fireproof coating is bad when using under different environment, is easy by corrosion.
To achieve the above object, the invention provides the following technical scheme: a kind of anti-flaming dope for fire-proof doors and windows, described to be used for
The anti-flaming dope of fire-proof doors and windows includes liquid sodium silicate, organic resin, chemical assistant, methyl-monosilane alkyd sodium, melamine phosphorus
Hydrochlorate, aluminium hydroxide, amino phenyl sulfonyl hydrochlorate, inorfil and fire resistant infilling, according to parts by weight, the parts by weight of each ingredient
Number is respectively as follows: 20-30 parts of liquid sodium silicate, and 15-20 parts of organic resin, 5-10 parts of chemical assistant, methyl-monosilane alkyd sodium 15-20
Part, 20-30 parts of melamine phosphate, 10-15 parts of aluminium hydroxide, 20-25 parts of amino phenyl sulfonyl hydrochlorate, 15-18 parts of inorfil,
20-25 parts of fire resistant infilling.
Preferably, the accounting of silica and sodium oxide molybdena is respectively 26.0% and 8.2% in the liquid sodium silicate.
Preferably, the organic resin includes polysiloxanes, poly- ethyl silicone resin and poly- aryl organic siliconresin, the poly- silicon oxygen
The weight proportion 2:3:5 of alkane, poly- ethyl silicone resin and poly- aryl organic siliconresin.
Preferably, the chemical assistant include salicylate and titanium oxide, the titanium oxide be it is powdered, the titanium oxide
Granule size is 40-80 microns, and the weight proportion of the salicylate and titanium oxide is 3:2.
Preferably, the inorfil is one of aluminium silicate wool, ceramic fibre and boron fibre.
Preferably, the fire resistant infilling includes magnesia and vermiculite powder, and the granularity size of the vermiculite powder is 0.2-0.3
Millimeter.
Compared with prior art, the beneficial effects of the present invention are: the anti-flaming dope for being used for fire-proof doors and windows, by intumescent and non-swollen
Swollen type fireproof coating combines, and intumescent component is not only contained in formula, but also contain more fire resistant infilling component, and addition has Gao Rong
The inorfil etc. of point, so that coating is capable of forming the high strength carbonizing layer of low thermal expansion under thermal-flame effect, it is ensured that swollen
Swollen coating can long-time refractory heat-insulating and do not fall off, while flame retardance element use melamine phosphate and aluminium hydroxide, tool
There are good thermal stability and acid-alkali-corrosive-resisting, be added with methyl-monosilane alkyd sodium, when exposing in air, can coagulate rapidly
Gu and each component of fireproof coating is solidified, improve the curing rate of coating.
Detailed description of the invention
Fig. 1 is that anti-flaming dope made of three embodiments of the invention is evenly applied to door and window surface progress high temperature sintering and coagulates
Gu time test table.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
Embodiment 1
The anti-flaming dope for fire-proof doors and windows of the present embodiment includes 20 parts of liquid sodium silicate, 3 parts of polysiloxanes, poly- ethyl silicon tree
4.5 parts of rouge, 7.5 parts of poly- aryl organic siliconresin, 3 parts of salicylate, 2 parts of titanium oxide, 15 parts of methyl-monosilane alkyd sodium, melamine
20 parts of amine phosphate, 10 parts of aluminium hydroxide, 20 parts of amino phenyl sulfonyl hydrochlorate, 15 parts of aluminium silicate wool, 10 parts of magnesia, vermiculite powder 10
Part, the accounting of silica and sodium oxide molybdena is respectively 26.0% and 8.2% in liquid sodium silicate, and the granularity size of vermiculite powder is
0.2 millimeter.
Embodiment 2
The anti-flaming dope for fire-proof doors and windows of the present embodiment includes 25 parts of liquid sodium silicate, 3.5 parts of polysiloxanes, poly- ethyl silicon
5 parts of resin, 8.5 parts of poly- aryl organic siliconresin, 5 parts of salicylate, 3 parts of titanium oxide, 18 parts of methyl-monosilane alkyd sodium, melamine
25 parts of amine phosphate, 12.5 parts of aluminium hydroxide, 22.5 parts of amino phenyl sulfonyl hydrochlorate, 17 parts of ceramic fibre, 11.5 parts of magnesia, vermiculite
11.5 parts of powder, the accounting of silica and sodium oxide molybdena is respectively 26.0% and 8.2%, the particle of vermiculite powder in liquid sodium silicate
Spending size is 0.25 millimeter.
Embodiment 3
The anti-flaming dope for fire-proof doors and windows of the present embodiment includes 30 parts of liquid sodium silicate, 4 parts of polysiloxanes, poly- ethyl silicon tree
6 parts of rouge, 10 parts of poly- aryl organic siliconresin, 6 parts of salicylate, 4 parts of titanium oxide, 20 parts of methyl-monosilane alkyd sodium, melamine
30 parts of phosphate, 15 parts of aluminium hydroxide, 25 parts of amino phenyl sulfonyl hydrochlorate, 18 parts of boron fibre, 12.5 parts of magnesia, vermiculite powder 12.5
Part, the accounting of silica and sodium oxide molybdena is respectively 26.0% and 8.2% in liquid sodium silicate, and the granularity size of vermiculite powder is
0.3 millimeter.
Anti-flaming dope made of above-described embodiment 1-3 is evenly applied to door and window surface and carries out high temperature sintering and setting time survey
Examination, test result such as Fig. 1.
Although hereinbefore having been made with reference to some embodiments, present invention is described, the scope of the present invention is not being departed from
In the case where, various improvement can be carried out to it and can be with equivalent without replacement component therein.Especially, as long as being not present
Structural conflict, the various features in presently disclosed each embodiment can be combined with each other by any way and be made
It is only in omitting length and economize on resources with, the description for not carrying out exhaustion to the case where these combinations in the present specification
Consider.Therefore, the invention is not limited to specific embodiments disclosed herein, and including falling within the scope of the appended claims
All technical solutions.
Claims (6)
1. a kind of anti-flaming dope for fire-proof doors and windows, it is characterised in that: the anti-flaming dope for fire-proof doors and windows includes liquid
Body sodium metasilicate, organic resin, chemical assistant, methyl-monosilane alkyd sodium, melamine phosphate, aluminium hydroxide, aminobenzenesulfonic acid
Salt, inorfil and fire resistant infilling, according to parts by weight, the parts by weight of each ingredient are respectively as follows: liquid sodium silicate 20-30
Part, 15-20 parts of organic resin, 5-10 parts of chemical assistant, 15-20 parts of methyl-monosilane alkyd sodium, melamine phosphate 20-30
Part, 10-15 parts of aluminium hydroxide, 20-25 parts of amino phenyl sulfonyl hydrochlorate, 15-18 parts of inorfil, 20-25 parts of fire resistant infilling.
2. a kind of anti-flaming dope for fire-proof doors and windows according to claim 1, it is characterised in that: the liquid sodium silicate
The accounting of middle silica and sodium oxide molybdena is respectively 26.0% and 8.2%.
3. a kind of anti-flaming dope for fire-proof doors and windows according to claim 1, it is characterised in that: the organic resin packet
Containing polysiloxanes, poly- ethyl silicone resin and poly- aryl organic siliconresin, the polysiloxanes, poly- ethyl silicone resin and poly- aryl have
The weight proportion 2:3:5 of machine silicone resin.
4. a kind of anti-flaming dope for fire-proof doors and windows according to claim 1, it is characterised in that: the chemical assistant packet
Containing salicylate and titanium oxide, the titanium oxide be it is powdered, the granule size of the titanium oxide is 40-80 microns, described
The weight proportion of salicylate and titanium oxide is 3:2.
5. a kind of anti-flaming dope for fire-proof doors and windows according to claim 1, it is characterised in that: the inorfil is
One of aluminium silicate wool, ceramic fibre and boron fibre.
6. a kind of anti-flaming dope for fire-proof doors and windows according to claim 1, it is characterised in that: the fire resistant infilling packet
Containing magnesia and vermiculite powder, the granularity size of the vermiculite powder is 0.2-0.3 millimeters.
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CN201910297348.4A CN110256880A (en) | 2019-04-15 | 2019-04-15 | A kind of anti-flaming dope for fire-proof doors and windows |
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CN201910297348.4A CN110256880A (en) | 2019-04-15 | 2019-04-15 | A kind of anti-flaming dope for fire-proof doors and windows |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112480721A (en) * | 2020-11-19 | 2021-03-12 | 湖南森云门窗有限公司 | Preparation method of door and window profile fireproof coating |
CN113122124A (en) * | 2021-04-06 | 2021-07-16 | 宋成镇 | Expansion type flame-retardant heat-insulating fireproof coating and preparation method thereof |
CN114752237A (en) * | 2022-04-22 | 2022-07-15 | 中铁华源(成都)环保科技有限公司 | Fireproof flame-retardant inorganic coating and preparation method thereof |
CN116285677A (en) * | 2023-03-20 | 2023-06-23 | 四川大学 | Transparent intumescent fireproof antibacterial coating and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112480721A (en) * | 2020-11-19 | 2021-03-12 | 湖南森云门窗有限公司 | Preparation method of door and window profile fireproof coating |
CN113122124A (en) * | 2021-04-06 | 2021-07-16 | 宋成镇 | Expansion type flame-retardant heat-insulating fireproof coating and preparation method thereof |
CN113122124B (en) * | 2021-04-06 | 2022-04-22 | 宋成镇 | Expansion type flame-retardant heat-insulating fireproof coating and preparation method thereof |
CN114752237A (en) * | 2022-04-22 | 2022-07-15 | 中铁华源(成都)环保科技有限公司 | Fireproof flame-retardant inorganic coating and preparation method thereof |
CN116285677A (en) * | 2023-03-20 | 2023-06-23 | 四川大学 | Transparent intumescent fireproof antibacterial coating and preparation method thereof |
CN116285677B (en) * | 2023-03-20 | 2024-03-01 | 四川大学 | Transparent intumescent fireproof antibacterial coating and preparation method thereof |
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Application publication date: 20190920 |