CN110256878A - A kind of liquid shell powder paint and preparation method thereof - Google Patents
A kind of liquid shell powder paint and preparation method thereof Download PDFInfo
- Publication number
- CN110256878A CN110256878A CN201910600749.2A CN201910600749A CN110256878A CN 110256878 A CN110256878 A CN 110256878A CN 201910600749 A CN201910600749 A CN 201910600749A CN 110256878 A CN110256878 A CN 110256878A
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- parts
- shell powder
- mass fraction
- powder paint
- liquid
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Abstract
The embodiment of the invention discloses a kind of liquid shell powder paints and preparation method thereof, the shell powder paint includes filler and auxiliary agent, wherein the filler includes the raw material of following mass fraction: 40-60 parts of calcined shell powder, 15-20 parts of titanium dioxide, 30-50 parts of calcium carbonate, 5-20 parts of sericite, 10-20 parts of kaolin, 10 parts of wollastonite, 3-8 parts of hydroxypropyl methyl cellulose, 40-50 parts of water；The auxiliary agent includes the raw material of following mass fraction: 15 parts of alkaline-resisting VAE resin, and 8-12 parts of sticky rice syrup, 1-5 parts of aluminium-magnesium silicate solution.The method includes by the calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, wollastonite, hydroxypropyl methyl cellulose form base-material after being sufficiently mixed, the base-material mixed well with water, obtains base-material mixing slurry；The calcination temperature of the calcined shell powder is lower than 850 DEG C.The liquid shell powder coating of the embodiment of the present invention uses calcined shell powder pulverized powder, and 95% main component is calcium hydroxide, and there are also a small amount of amino acid and polysaccharide materials.
Description
Technical field
The present embodiments relate to building material technical fields, and in particular to a kind of liquid shell powder paint and its preparation side
Method.
Background technique
Currently, interior decoration largely uses emulsion paint, paint, composite board, leather, foam insert, plastic facing etc.
Material contains a large amount of volatility toxic compounds in material, the health for seriously polluting living and working environment, endangering people；
In addition, the dope for inner wall of architecture used in the market is mainly emulsion paint, emulsion paint is soft in the prevalence of paint film, drying time is long,
The disadvantages of storage stability is poor, after being moistened, bacterium easy to breed generates phenomena such as falling off, changing colour, seriously to emulsion paint class coating
Influence service life and indoor beauty.
In order to overcome emulsion paint etc. to fit up the defect of pollutant existing for coating used, currently, also occurring in the market very
More environment-friendly type coatings, for example, environmental protection coating material in the market is first is that water paint, second is that powdery paints.Powdery paints has percentage
Hundred film forming the advantages of, but these coating can really can not accomplish pure natural no pollution from raw material, while adsorb point
The coating of solution pollutions such as formaldehyde within doors.
In conclusion traditional coating is there is pollution environment, the feature of environmental protection is poor, it is poor to remove effect of formaldehyde, it would be highly desirable to further change
Into.
Summary of the invention
For this purpose, the embodiment of the present invention provides a kind of liquid shell powder paint and preparation method thereof, to solve in the prior art
Not environmentally, the problem of the removing effect difference of PARA FORMALDEHYDE PRILLS(91,95).
To achieve the goals above, the embodiment of the present invention provides the following technical solutions:
A kind of liquid shell powder paint, the shell powder paint includes filler and auxiliary agent, wherein the filler includes following
The raw material of mass fraction: 40-60 parts of calcined shell powder, 15-20 parts of titanium dioxide, 30-50 parts of calcium carbonate, 5-20 parts of sericite, high
Soil 10-20 parts of ridge, 10 parts of wollastonite, 3-8 parts of hydroxypropyl methyl cellulose, 40-50 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 10-20 parts of alkaline-resisting VAE resin, and 8-12 parts of sticky rice syrup, magnesium silicate
1-5 parts of aluminum solutions, 4-8 parts of calcium hydroxide modifying agent.
Preferably, the auxiliary agent further includes calcium hydroxide modifying agent, and the mass fraction of the calcium hydroxide modifying agent is 4-8
Part.
Preferably, the shell powder paint further includes alkaline-resisting iron oxide series mill base, the alkaline-resisting iron oxide series mill base
Mass fraction be 1-3 parts.
Preferably, the filler includes the raw material of following mass fraction: 40-60 parts of calcined shell powder, titanium dioxide 18-19
Part, 35-50 parts of calcium carbonate, 8-20 parts of sericite, 10-20 parts of kaolin, 10 parts of wollastonite, hydroxypropyl methyl cellulose, 3-8
Part, 40-50 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 15-18 parts of alkaline-resisting VAE resin, and 8-12 parts of sticky rice syrup, magnesium silicate
2-4 parts of aluminum solutions.
Preferably, the filler includes the raw material of following mass fraction: 50 parts of calcined shell powder, 18.5 parts of titanium dioxide, and carbon
40 parts of sour calcium, 10 parts of sericite, 16 parts of kaolin, 10 parts of wollastonite, 5.5 parts of hydroxypropyl methyl cellulose, 46 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 15 parts of alkaline-resisting VAE resin, 10 parts of sticky rice syrup, aluminium-magnesium silicate is molten
3 parts of liquid, 10 parts of calcium hydroxide modifying agent.
Preferably, the calcium carbonate is the calcium carbonate of 1250 mesh of 98% whiteness.
The embodiment of the present invention also provides a kind of method for preparing the liquid shell powder paint comprising:
By the calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, wollastonite, hydroxypropyl methyl cellulose
Base-material is formed after being sufficiently mixed, and the base-material and water are mixed well into high speed dispersion, obtain base-material mixing slurry；The calcined shell
The calcination temperature of powder is lower than 850 DEG C；
The auxiliary agent is sufficiently mixed with water, glue is obtained and joins mixture；
The base-material mixing slurry and glue connection mixture are sufficiently mixed, primary coating material is formed；
After the primary coating material is fully ground, the liquid shell coating is formed.
Preferably, calcium hydroxide modifying agent is additionally added inside the primary coating material.
Preferably, the liquid shell powder paint is additionally added alkaline-resisting iron oxide series mill base.
In the embodiment of the present invention, the mass fraction of aluminum magnesium silicate is 80% in aluminum magnesium silicate solution.
In the embodiment of the present invention, the mass concentration range of sticky rice syrup is 60-90%.
The embodiment of the present invention has the advantages that
The liquid shell coating of the embodiment of the present invention uses calcined shell powder pulverized powder, and 95% main component is hydrogen-oxygen
Change calcium, there are also a small amount of amino acid and polysaccharide materials.The chitin contained when the calcination temperature of conch meal is lower than 850 DEG C, in shell
It will not decompose, have the effect of environmental protection.Calcium hydroxide modifying agent and glutinous is added in the liquid shell powder paint of the embodiment of the present invention
Rice & peanut milk, without peculiar smell, bacteriostasis property is good, and it is good and lasting to remove formaldehyde performance.
Specific embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book is understood other advantages and efficacy of the present invention easily, it is clear that described embodiment is the present invention one
Section Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing
Every other embodiment obtained under the premise of creative work out, shall fall within the protection scope of the present invention.
Embodiment 1
The kind liquid shell coating of the embodiment of the present invention comprising filler and auxiliary agent, wherein filler includes following quality point
Several raw material: calcined shell powder 40kg, titanium dioxide 15kg, calcium carbonate 30kg, sericite 5kg, kaolin 10kg, wollastonite
15kg, hydroxypropyl methyl cellulose 4kg, water 40kg；
Auxiliary agent includes the raw material of following mass fraction: alkaline-resisting VAE resin 15kg, sticky rice syrup 8kg, aluminium-magnesium silicate solution
3kg,。
In the present embodiment, auxiliary agent further includes the calcium hydroxide modifying agent of 7kg.
In the present embodiment, calcium carbonate is the calcium carbonate of 1250 mesh of 98% whiteness.
A kind of method preparing liquid shell coating of the present embodiment comprising:
By calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, wollastonite, hydroxypropyl methyl cellulose is abundant
Base-material is formed after mixing, specifically, can launch above-mentioned raw materials in blender, stirs 25min, it is made to be mixed to form base-material,
Base-material and water are mixed well into high speed dispersion in the second reaction kettle, the revolving speed of the second reaction kettle is 1500, time 30min,
Obtain base-material mixing slurry；The calcination temperature of calcined shell powder is lower than 850 DEG C.
Auxiliary agent and water are sufficiently mixed in the first reaction kettle, glue is obtained and joins mixture；
Glue connection mixture in first reaction kettle by diaphragm pump with the second reaction kettle base-material mixing slurry is fully dispersed mixes,
The revolving speed of second reaction kettle is 800, jitter time 20min, forms primary coating material；
After primary coating material is fully ground, it is additionally added calcium hydroxide modifying agent inside primary coating material, forms liquid conch meal
Coating.Finished product will be formed after liquid shell powder paint packaging.
Embodiment 2
The kind liquid shell coating of the embodiment of the present invention comprising filler and auxiliary agent, wherein filler includes following quality point
Several raw material: calcined shell powder 60kg, titanium dioxide 20kg, calcium carbonate 50kg, sericite 20kg, kaolin 20kg, hydroxypropyl first
Base cellulose 8kg, water 50kg；
Auxiliary agent includes the raw material of following mass fraction: alkaline-resisting VAE resin 20kg, sticky rice syrup 15kg, aluminium-magnesium silicate solution
5kg。
In the present embodiment, auxiliary agent further includes the calcium hydroxide modifying agent of 10kg.Shell coating further includes the alkaline-resisting oxidation of 1kg
Iron series column mill base.
In the present embodiment, calcium carbonate is the calcium carbonate of 1250 mesh of 98% whiteness.
A kind of method preparing liquid shell coating of the present embodiment comprising:
Calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, hydroxypropyl methyl cellulose are sufficiently mixed rear shape
At base-material, specifically, can by above-mentioned raw materials launch in blender, stir 25min, so that it is mixed to form base-material, by base-material with
Water mixes well in the second reaction kettle, and the revolving speed of the second reaction kettle is 1500, and time 30min obtains base-material mixing slurry；It forges
The calcination temperature for burning conch meal is lower than 850 DEG C.
Auxiliary agent and water are sufficiently mixed in the first reaction kettle, glue is obtained and joins mixture；
Glue connection mixture in first reaction kettle is sufficiently mixed by diaphragm pump and the second reaction kettle base-material mixing slurry, and second
The revolving speed of reaction kettle is 800, jitter time 20min, forms primary coating material；
After primary coating material is fully ground, it is additionally added calcium hydroxide modifying agent inside primary coating material, forms liquid shell and applies
Material, liquid shell coating are additionally added alkaline-resisting iron oxide series mill base.Finished product will be formed after liquid shell coating packing.
Embodiment 3
The kind liquid shell coating of the embodiment of the present invention comprising filler and auxiliary agent, wherein filler includes following quality point
Several raw material: calcined shell powder 50kg, titanium dioxide 18.5kg, calcium carbonate 40kg, sericite 10kg, kaolin 16kg, hydroxypropyl
Methylcellulose 5.5kg, water 46kg；
Auxiliary agent includes the raw material of following mass fraction: alkaline-resisting VAE resin 15kg, sticky rice syrup 20kg, aluminium-magnesium silicate solution
3kg。
In the present embodiment, auxiliary agent further includes the calcium hydroxide modifying agent of 6kg.
Shell powder paint further includes the alkaline-resisting iron oxide series mill base of 2.5kg.
In the present embodiment, calcium carbonate is the calcium carbonate of 1250 mesh of 98% whiteness.
A kind of method preparing liquid shell powder paint of the present embodiment comprising:
It is according to above-mentioned mass ratio that calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, hydroxypropyl methyl is fine
Dimension element forms base-material after being sufficiently mixed, specifically, can launch above-mentioned raw materials in blender, stirs 25min, it is made to mix shape
At base-material, base-material and water are mixed well in the second reaction kettle, the revolving speed of the second reaction kettle is 1500, and time 30min is obtained
To base-material mixing slurry；
Auxiliary agent and water are sufficiently mixed in the first reaction kettle, glue is obtained and joins mixture；The calcination temperature of calcined shell powder
Lower than 850 DEG C.
Glue connection mixture in first reaction kettle is sufficiently mixed by diaphragm pump and the second reaction kettle base-material mixing slurry, and second
The revolving speed of reaction kettle is 800, jitter time 20min, forms primary coating material；
After primary coating material is fully ground, it is additionally added calcium hydroxide modifying agent inside primary coating material, forms liquid shell and applies
Material, liquid shell powder paint are additionally added alkaline-resisting iron oxide series mill base.Finished product will be formed after liquid shell coating packing.
Comparative example 1
In this comparative example, the calcined shell powder in embodiment 1 is changed into unmodified conch meal, other steps and embodiment
1 it is identical, liquid shell powder paint is prepared.
Comparative example 2
In this comparative example, it is modified calcium hydroxide in the preparation process of the liquid shell powder material in embodiment 1, will not be added
Agent.Other steps are identical as embodiment 1, and liquid shell powder paint is prepared.
Comparative example 3
In this comparative example, by the preparation process of the liquid shellfish material in embodiment 1, sticky rice syrup is not added.Other steps
Suddenly identical with embodiment 1, liquid shell powder paint is prepared.
Test example
It is tested: the liquid shell powder paint in embodiment 1-3 and comparative example 1-3 (1) according to JC/T as follows
The test method of 1074-2008 carries out purifying formaldehyde performance and the test of formaldehyde persistence；(2) according to the survey of GB/T21866-2008
Method for testing carries out the test of antibiotic property, and test result is as shown in table 1.
Table 1
As can be seen from the data in table 1, the liquid shell powder material that the present invention is implemented can be good at adsorbing peculiar smell, adsorb first
Aldehyde effect is good.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements without departing from theon the basis of the spirit of the present invention are fallen within the scope of the claimed invention.
Claims (9)
1. a kind of liquid shell powder paint, which is characterized in that the shell powder paint includes filler and auxiliary agent, wherein the filler
Raw material including following mass fraction: 40-60 parts of calcined shell powder, 15-20 parts of titanium dioxide, 30-50 parts of calcium carbonate, sericite 5-
20 parts, 10-20 parts of kaolin, 10 parts of wollastonite, 3-8 parts of hydroxypropyl methyl cellulose, 40-50 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 10-20 parts of alkaline-resisting VAE resin, 8-12 parts of sticky rice syrup, aluminium-magnesium silicate is molten
1-5 parts of liquid, 4-8 parts of calcium hydroxide modifying agent.
2. liquid shell powder paint as described in claim 1, which is characterized in that
The auxiliary agent further includes calcium hydroxide modifying agent, and the mass fraction of the calcium hydroxide modifying agent is 4-8 parts.
3. liquid shell powder paint as described in claim 1, which is characterized in that
The shell powder paint further includes alkaline-resisting iron oxide series mill base, and the mass fraction of the alkaline-resisting iron oxide series mill base is
1-3 parts.
4. liquid shell powder paint as described in claim 1, which is characterized in that
The filler includes the raw material of following mass fraction: 40-60 parts of calcined shell powder, 18-19 parts of titanium dioxide, and calcium carbonate 35-
50 parts, 8-20 parts of sericite, 10-20 parts of kaolin, 10 parts of wollastonite, hydroxypropyl methyl cellulose, 3-8 parts, 40-50 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 15-18 parts of alkaline-resisting VAE resin, 8-12 parts of sticky rice syrup, aluminium-magnesium silicate is molten
2-4 parts of liquid.
5. liquid shell powder paint as described in claim 1, which is characterized in that
The filler includes the raw material of following mass fraction: 50 parts of calcined shell powder, 18.5 parts of titanium dioxide, and 40 parts of calcium carbonate, thin,tough silk
10 parts of mica, 16 parts of kaolin, 10 parts of wollastonite, 5.5 parts of hydroxypropyl methyl cellulose, 46 parts of water；
The auxiliary agent includes the raw material of following mass fraction: 15 parts of alkaline-resisting VAE resin, and 10 parts of sticky rice syrup, aluminium-magnesium silicate solution 3
Part, 10 parts of calcium hydroxide modifying agent.
6. liquid shell powder paint according to any one of claims 1 to 5, which is characterized in that
The calcium carbonate is the calcium carbonate of 1250 mesh of 98% whiteness.
7. a kind of method for preparing liquid shell powder paint described in claim 1, characterized by comprising:
By the calcined shell powder, titanium dioxide, calcium carbonate, sericite, kaolin, wollastonite, hydroxypropyl methyl cellulose is abundant
Base-material is formed after mixing, and the base-material and water are mixed well into high speed dispersion, obtain base-material mixing slurry；The calcined shell powder
Calcination temperature is lower than 850 DEG C；
The auxiliary agent is sufficiently mixed with water, glue is obtained and joins mixture；
The base-material mixing slurry and glue connection mixture are sufficiently mixed, primary coating material is formed；
After the primary coating material is fully ground, the liquid shell coating is formed.
8. the method for claim 7, which is characterized in that
Calcium hydroxide modifying agent is additionally added inside the primary coating material.
9. the method for claim 7, which is characterized in that
The liquid shell powder paint is additionally added alkaline-resisting iron oxide series mill base.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910600749.2A CN110256878A (en) | 2019-07-04 | 2019-07-04 | A kind of liquid shell powder paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910600749.2A CN110256878A (en) | 2019-07-04 | 2019-07-04 | A kind of liquid shell powder paint and preparation method thereof |
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| CN110256878A true CN110256878A (en) | 2019-09-20 |
Family
ID=67924472
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| CN201910600749.2A Pending CN110256878A (en) | 2019-07-04 | 2019-07-04 | A kind of liquid shell powder paint and preparation method thereof |
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| CN113929360A (en) * | 2021-10-28 | 2022-01-14 | 云浮市新丽新岗石发展有限公司 | Water-ripple beige artificial granite and production process thereof |
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Application publication date: 20190920 |