CN110253990A - 自扣型润滑轴承板材 - Google Patents
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Abstract
本发明公开了一种自扣型润滑轴承板材,包括润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层;散热层包括多孔纤维、气凝胶;多孔纤维位于气凝胶中;多孔纤维包括带孔纤维、多孔纤维胶层;多孔纤维胶层位于带孔纤维外表面;多孔纤维胶层的孔中设有石墨烯层结构;润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层依次设置;钢板层上,第一卷接侧边设有凹槽,第二卷接侧边设有凸起,第一卷接侧边与第二卷接侧边的外表面都设有粉末粘接剂层;提高自润滑轴承优异散热性能的同时,可以发挥弯曲效果。
Description
技术领域
本发明属于轴承生产技术领域,具体涉及一种自扣型润滑轴承板材。
背景技术
自润滑轴承由于适合于润滑不可靠或不可能之处而开始受到人们的重视。单一材料的自润滑轴承一般有铜粉末治金和塑料两种结构。铜粉末冶金结构强度比较低,难以适合高载荷的工作条件,在跑合期还很容易造成拉伤。在钢板背面采用高分子保护可以提高自润滑轴承寿命,但是带来了散热难题。发明人之前公开了一种散热板材,提高了板材散热效果,利用铜颗粒解决氟材料与钢板结合力的问题,但是此结构带来一些问题,比如铜颗粒主要利用物理作用对氟材料进行稳定,最主要的是烧结铜颗粒至钢板上的时候会对润滑铜粉产生较大影响,因为润滑铜粉的性能是轴承板材的核心,因此必须先烧结润滑铜粉,在其检验合格后再烧结铜颗粒,这样会产生润滑铜粉二次烧结,影响润滑性能,加大降低成品率。另外,现有轴承套无论针对低速还是中高速应用,都是采用焊接的方式对卷套进行缝接,结合力牢固,但是会增加卷套成本以及焊接对焊缝附近的材料会产生影响。
发明内容
本发明的目的是提供一种自扣型润滑轴承板材,通过结构设计以及思路创新的协同作用,使得自扣型润滑轴承板材具备良好的机械性能,同时具有优异的层间稳定性,尤其是散热性能优异,同时采用自扣结构使得板材卷套时无需焊接,可以作为低速轴承套使用。
为达到上述发明目的,本发明采用的技术方案是:一种自扣型润滑轴承板材,包括润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层;所述散热层包括多孔纤维、气凝胶;所述多孔纤维位于气凝胶中;所述多孔纤维包括带孔纤维、多孔纤维胶层;所述多孔纤维胶层位于带孔纤维外表面;所述多孔纤维胶层的孔中设有石墨烯层结构;所述润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层依次设置;所述钢板层上,第一卷接侧边设有凹槽,第二卷接侧边设有凸起;所述凸起可以插入凹槽中,第一卷接侧边与第二卷接侧边的外表面都设有粉末粘接剂层。
本发明中,导热胶层的厚度为0.6~0.7微米,一方面可以形成良好的粘接性,另一方面可以将热量传送。
本发明中,润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层依次设置是指这几层结构按次序设置,具体可以参见说明书附图;使用时,将润滑铜粉层置于最里边用于摩擦,将氧化锌层置于最外面,从而发热的热量通过环氧结构胶层迅速传导至气凝胶结构,从而有效散去,因此本发明不仅为一个有效散热结构,而且对板材制备的轴承套使用寿命有利,背层结构保证了轴承层应有的强度和稳定的尺寸,提高了耐磨性能,也避免了拉伤现象的发生。
本发明中,各材料都是现有产品,比如润滑铜粉层为常规结构,利用铜粉与润滑材料混合烧结即可得到,尤其是根据本发明设计的结构,润滑铜粉不会经过对性能影响很大的二次烧结;含氟层聚酰亚胺薄膜层的厚度为18.5微米,这个结构的设计可以提高轴承板材背面硬度,卷曲时可与气凝胶提供一定的缓冲效果,含氟层聚酰亚胺薄膜层由聚酰亚胺薄膜与氟材料组成,为双层结构,其中聚酰亚胺薄膜一侧与环氧结构胶层接触、氟材料一侧与导热胶层接触;氧化锌喷涂在散热层表面即可得到氧化锌层,可以起到保护作用;本发明创造性的设计此结构,首次应用在自润滑轴承的前料板材复合结构中,可以发挥自身性能效果以及提高复合材料的柔韧性,更主要的是与多孔纤维的结合,配合石墨烯提高散热能力自发热。
本发明中,散热层的厚度为48~50微米,除了本身的机械性能好的效果外,还可发挥散热效果,而且此厚度与铝板可提高整体弯曲能力;气凝胶为常规二氧化硅气凝胶,通过溶胶凝胶法结合干燥制备得到,在溶胶置换溶剂后,加入多孔纤维,最后进行程序升温,制备得到散热层。
本发明中,散热层包括多孔纤维、气凝胶,所述气凝胶结构的孔隙率为38~42%,将多孔纤维设置在低孔隙率气凝胶结构中,既可以利用现有气凝胶柔软舒适的特性缓解带孔纤维的刚性,特别是,气凝胶结构进一步保证石墨烯层稳定在胶层中,而且不会影响散热效果。
本发明中,多孔纤维胶层的孔隙率为68~70%,可以在带孔纤维外表面涂覆带有致孔剂/石墨烯复合物的柔性高分子溶液,热处理在带孔纤维表面形成多孔胶层,并且石墨烯层位于孔中,可以发挥散热性能,又能够保持稳定,纤维可为聚乙烯醇纤维等,尤其是本发明采用的结构不会对纤维本身产生影响,避免现有技术采用导热纤维带来的纤维本身性能有影响的问题。
自扣型润滑轴承板材在后续加工中会被卷成套结构,此时钢板的两个侧边会靠在一些,现有技术采用焊接将两个靠在一起钢板侧边结合,从而板材形成稳定的轴套;本发明定义在卷套过程中相靠的两个钢板的侧边分别为第一卷接侧边与第二卷接侧边,并分别设置凹槽与凸起,凸起与凹槽对应设置并且凸起可以插入凹槽中,优选凹槽与凸起都是圆柱形结构,凸起的外径与凹槽的内径一致,这样凸起插入凹槽中,从而形成稳定结合,进一步优选的,凹槽与凸起都为四个,根据现有常规轴承板材的结构尺寸,四对凹槽/凸起的设计可以满足轴套缝隙的结合,至于凹槽凸起的位置以及形成方法都是常规技术,很容易制备得到。同时本发明第一卷接侧边与第二卷接侧边的外表面都设有粉末粘接剂层、凸起的外表面设有粉末粘接剂层,粉末粘接剂层(铭远)相对于液体粘接剂在加热时流动性差一些,而且对于凸起插入凹槽有些正向作用,粉末粘接剂层的材料为现有技术,不会影响本发明的效果。
本发明首次公开了一种自扣型润滑轴承板材,得到的产品具有较好的硬度以及弯曲性,保持自润滑性能的同时,可以发挥散热效果,将自扣型润滑轴承板材采用常规技术卷,然后加热,制成轴承套(成年男子用手无法掰开钢板接缝),内部发热(110度)一段时间后关闭,通过内外平衡测试散热能力;通过纤维以及多层结构的设计,有效保障了散热稳定高效、各层界面效果好的优势;尤其是利用环氧-聚酰亚胺-氟材料良好的界面效应,使得高分子层与钢板结合良好,避免铜颗粒带来的系列问题。
附图说明
图1为自扣型润滑轴承板材结构示意图;
图2为散热层结构示意图;
图3为多孔纤维结构示意图;
图4为钢板结构示意图;
其中,润滑铜粉层1、钢板层2、凹槽21、凸起22、粉末粘接剂层23、粉末粘接剂层24、环氧结构胶层3、含氟层聚酰亚胺薄膜层4、聚酰亚胺薄膜一侧41、氟材料一侧42、导热胶层5、散热层6、氧化锌层7、多孔纤维8、气凝胶9、带孔纤维10、多孔纤维胶层11、石墨烯层结构12。
具体实施方式
下面结合附图以及实施例对本发明作进一步描述:
实施例一
参见附图1-4,自扣型润滑轴承板材包括润滑铜粉层1、钢板层2、环氧结构胶层3、含氟层聚酰亚胺薄膜层4、导热胶层5、散热层6、氧化锌层7;散热层包括多孔纤维8、气凝胶9;多孔纤维位于气凝胶中;多孔纤维包括带孔纤维10、多孔纤维胶层11;多孔纤维胶层位于带孔纤维外表面;多孔纤维胶层的孔中设有石墨烯层结构12;润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层依次设置,其中聚酰亚胺薄膜(12.5μm)一侧41与环氧结构胶层接触、氟材料一侧42与导热胶层接触;钢板层上,第一卷接侧边设有凹槽21,第二卷接侧边设有凸起22,凸起可以插入凹槽中,第一卷接侧边与第二卷接侧边的外表面都设有粉末粘接剂层23,凹槽与凸起都为四个,凹槽与凸起都是圆柱形结构,凸起的外表面设有粉末粘接剂层23,凸起的外径与凹槽的内径一致,都为钢板厚度的80%。环氧结构胶为市购产品,具体为威伏EP3051,导热胶为汉高乐泰315,专为电子材料使用,导热性能很好;粉末粘接剂为铭远150粉,VA含量高,粘接效果好。
上述含氟层聚酰亚胺薄膜层的厚度为18.5微米;气凝胶结构的孔隙率为40%;多孔纤维胶层的孔隙率为70%;散热层的厚度为50微米;导热胶层的厚度为0.6微米;环氧结构胶层的厚度为0.25微米;氧化锌层的厚度为25纳米;凹槽深度1毫米、凸起高度1毫米。图中凸起、凹槽、石墨烯结构、纤维等只标注一处,气凝胶的孔隙未标示,不影响本领域技术人员的理解。
对比例一
自润滑轴承板材包括润滑铜粉层、钢板层。
对比例二
自润滑轴承板材包括润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层。上述含氟层聚酰亚胺薄膜层的厚度为18.5微米;环氧结构胶层的厚度为0.25微米。
上述实施例中,含氟层聚酰亚胺薄膜层(12.5/6μm)来自凯英薄膜,润滑铜粉层、钢板层的烧结为现有技术,各层的制备也为现有技术,利用钢板弯曲强度测试仪测试(中创)弯曲强度;以对比例一为基础比较,性能测试发现,实施例一的自扣型润滑轴承板材弯曲强度提高1.62倍,散热能力为0.92倍;对比例二的自润滑轴承板材弯曲强度提高1.19倍,散热能力为0.67倍;散热层厚度变大、变小时,散热性能、弯曲性能较实施例一下降;采用剥离力测试仪测试比较,如果不设置环氧结构胶层,含氟层聚酰亚胺薄膜层剥离性能下降60%多。另外,与之前制备的铜颗粒散热型自润滑轴承板材相比,本发明的结构不会影响润滑铜粉的性能,产品良率100%(50块板材),而铜颗粒散热型自润滑轴承板材产品良率仅为24%(50块板材),其中38块板材的润滑铜粉层由于二次烧结都不符合使用要求。
Claims (10)
1.一种自扣型润滑轴承板材,其特征在于:所述自扣型润滑轴承板材包括润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层;所述散热层包括多孔纤维、气凝胶;所述多孔纤维位于气凝胶中;所述多孔纤维包括带孔纤维、多孔纤维胶层;所述多孔纤维胶层位于带孔纤维外表面;所述多孔纤维胶层的孔中设有石墨烯层结构;所述润滑铜粉层、钢板层、环氧结构胶层、含氟层聚酰亚胺薄膜层、导热胶层、散热层、氧化锌层依次设置;所述钢板层上,第一卷接侧边设有凹槽,第二卷接侧边设有凸起;所述凸起可以插入凹槽中,第一卷接侧边与第二卷接侧边的外表面都设有粉末粘接剂层。
2.根据权利要求1所述自扣型润滑轴承板材,其特征在于:所述含氟层聚酰亚胺薄膜层的厚度为18.5微米。
3.根据权利要求1所述自扣型润滑轴承板材,其特征在于:所述气凝胶结构的孔隙率为38~42%。
4.根据权利要求1所述自扣型润滑轴承板材,其特征在于:所述多孔纤维胶层的孔隙率为68~70%。
5.根据权利要求1所述自扣型润滑轴承板材,其特征在于:所述散热层的厚度为48~50微米。
6.根据权利要求1所述自扣型润滑轴承板材,其特征在于:所述导热胶层的厚度为0.6~0.7微米。
7.根据权利要求1所述自扣型润滑轴承板材,其特征在于:环氧结构胶层的厚度为0.2~0.3微米。
8.根据权利要求1所述自扣型润滑轴承板材,其特征在于:氧化锌层的厚度为25纳米。
9.根据权利要求1所述自扣型润滑轴承板材,其特征在于:凹槽与凸起都是圆柱形结构;凸起的外表面设有粉末粘接剂层;所述凸起的外径与凹槽的内径一致。
10.根据权利要求1所述自扣型润滑轴承板材,其特征在于:凹槽与凸起都为四个。
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