CN110240914A - A kind of vertical shaft type tubulation retort - Google Patents

A kind of vertical shaft type tubulation retort Download PDF

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Publication number
CN110240914A
CN110240914A CN201910587293.0A CN201910587293A CN110240914A CN 110240914 A CN110240914 A CN 110240914A CN 201910587293 A CN201910587293 A CN 201910587293A CN 110240914 A CN110240914 A CN 110240914A
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CN
China
Prior art keywords
retort
drying oven
charing
pipe
section
Prior art date
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Pending
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CN201910587293.0A
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Chinese (zh)
Inventor
项光辉
吴植仁
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Individual
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Individual
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Priority to CN201910587293.0A priority Critical patent/CN110240914A/en
Publication of CN110240914A publication Critical patent/CN110240914A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/02Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge
    • C10B47/04Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge in shaft furnaces
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/08Non-mechanical pretreatment of the charge, e.g. desulfurization
    • C10B57/10Drying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

A kind of vertical shaft type tubulation retort, belongs to the charing of carbonaceous organic material, especially suitable for the charing of agricultural stalk waste, is also applied for including the discarded raw charing for adoring matter such as municipal sludge.The advantage is that: 1, material is walked in pipe, blanking unevenness and dead angle will not be generated, bridging occurs, even if occurring, cleared up without blowing out;2, the yield of wood vinegar can be regulated and controled with the market according to wood vinegar;3, charger is respectively set in drying oven and retort, and preventing gas blowby may.

Description

A kind of vertical shaft type tubulation retort
1, technical field
The invention belongs to the charings of carbonaceous organic material, especially suitable for the charing of agricultural stalk waste, are also applied for wrapping Include the charing of the abandoned biomass such as municipal sludge.
2, background technique
China's agricultural production at present generates agricultural crop straw every year and exceedes 1,000,000,000 tons, except direct returning to farmland, fodder, energy, Materialized equal outside, there are also a large amount of agricultural crop straws to abandon by unordered burning or arbitrarily.Serious atmosphere pollution is autumn and winter mist One of haze main reason.
Experiments have shown that 3t stalk, through carbonizing, available straw charcoal about 1.5t, stalk vinegar liquid about 1t, pyrolysis gas is about 200Hm3, bio-oil about 100kg.
Straw charcoal is a kind of solid, porous particles substance with height aromatization, rich in carbon.It contains a large amount of carbon With plant nutrient substance, contain more oxygen-content active group with pore structure abundant, biggish specific surface area and surface, It is a kind of multifunctional material.It can not only improve gas permeability, the water-retaining property of soil, and increasing fertilizer efficiency has slowly releasing effect to fertilizer, The heavy metal and organic pollutant in soil or sewage can be adsorbed, and there is preferable fixed function to carbon nitrogen, is applied to soil In earth, it is possible to reduce CO2、N2O、CH4The discharge of isothermal chamber gas, slowing global warming.Therefore straw carbon returning to the field is optimal A kind of straw utilization ways.
Trimerization company, China is conceived to " being originated from agricultural, peasant is benefited in back feeding farmland ", " the straw biomass charing of proposition The Strategic Thought of comprehensive cyclic utilization " system engineering, using rotary furnace as charing main equipment.Unfortunately, due to there is wood Vinegar liquid " taking library " problem, makes to build up at home and the tens of sets revolution retort to put into operation is halted by local environmentally friendly authorities. To solve this problem, as with complete suitable meter, applicants have invented a kind of rotary charings of biomass for only generating substance charcoal Furnace.However this invention, inherent defect existing for rotary furnace is not solved fundamentally.
There are a variety of type of furnaces from being born over 200 years in solid fuel charring process, from the retort oven of early stage interval, to company Kinds of processes and the equipment such as continuous rotary furnace, vertical shaft type furnace, moving bed solid thermal carriers, microwave retort ....But it can be carried out quotient Industry operation only there are two types of, i.e., processing dusty raw materials rotary furnace and processing block stock vertical shaft type furnace.Shaping raw material is all It is preferential to select vertical shaft type furnace, this is because vertical shaft type furnace has unrivaled advantage than rotary furnace.For this purpose, applicant is for biology The charing of matter has invented " a kind of internal combustion type biological particles material is dry, carbonizes, activation integral furnace ", has been exactly using vertical shaft type Furnace.
However there are still some flaws for this invention: 1 material is walked outside pipe, is also easy to produce blanking unevenness and dead angle, bridging occurs, Blowing out is needed to clear up;Although 2 setting sealing gland sections, but still imprecision, it may occur that pyrolysis gaseous products scurry into dryer section or flue gas is altered Enter to carbonize section;3 pyrolysis gaseous products are all sent to condensation cooling recovery system, and the wooden vinegar cannot be regulated and controled with the market according to wood vinegar The yield of liquid.
3, summary of the invention
The technical problem to be solved in the present invention is to provide a kind of vertical shaft type tubulation retort, can solve above-mentioned " in one kind Flaw existing for the drying of combustion biological particles material, charing, activation integral furnace ".
The invention is realized by the following technical scheme:
A kind of vertical shaft type tubulation retort, is made of, it is characterised in that drying oven is provided separately drying oven and retort Drying oven charger is provided at the top of retort upper side, the retort, bottom is provided with drying oven unloader, described dry The side upper wall of dry furnace is equipped with the wet flue gas outlet for being connected to its inner cavity, and side lower wall is equipped with the drying oven cloth ballute for being connected to its inner cavity Drying oven hot fume inlet tube, drying oven unloader and retort charger are accepted, and the retort is successively arranged from the top down Feeding section, charing section, cooling section and unloading part, the feeding section are equipped with retort charger, the flat glassware of retort, the charing The upper side wall of section is equipped with the retort smoke outlet tube of connection flue gas inner cavity, and charing section sets heat exchanging pipe, with upper perforated plate and down tube Outer setting baffle plate is managed in plate closing, and the material of the charing section is walked in pipe, and hot fume is walked outside pipe, retort charing stove outer covering, Retort insulating layer and retort refractory layer are built into closed furnace body, and the lower outside of the charing section, setting is outer to burn nozzle for combustion gas And jet tube sheet is arranged in the lower end outside the heat exchanging pipe pipe in visor, it and lower perforated plate constitute cloth gas chamber, the gas distribution Room and personal combustion gas bend pipe connection are pyrolyzed gaseous products hot combustion gas outlet in the top of cooling section setting collection ballute Export is arranged cooling half garden in the outer surface of cone of cooling section and manages, and unloads charcoal machine in unloading part setting;
Further scheme of the invention is that the drying oven uses the hot fume of retort smoke outlet tube extraction as drying Heat carrier;
Further scheme of the invention is the aperture of uniformly distributed multiple φ 8- φ 12 on the jet tube sheet;
Further scheme of the invention is to be pyrolyzed gaseous products derived from hot combustion gas outlet, is divided into two-way with threeway, Cloth gas chamber another way, which is sent to, through self-produced combustion gas bend pipe all the way is sent to the yield that condensation cooling recovery system is used to adjust wood vinegar.
4, technological merit
The advantages of the present invention over the prior art are that:
4.1, material is walked in pipe, will not generate blanking unevenness and dead angle, bridging occurs, clear without blowing out even if occurring Reason;
4.2, the yield of wood vinegar can be regulated and controled with the market according to wood vinegar;
Charger is respectively set in 4.3 drying ovens and retort, and preventing gas blowby may.
5, Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the A of Fig. 1 to cross-sectional view, in figure: 1 drying oven charger, 2 drying ovens, the wet waste gas outlet pipe of 3 drying ovens, 4 Drying oven cloth ballute, 5 drying oven hot fume inlet tubes, 6 drying oven unloaders, 7 retort chargers, the flat glassware of 8 retorts, 9 Retort smoke outlet tube, 10 upper perforated plates, 11 baffle plates, 12 heat exchanging pipes, 13 charing stove outer coverings, 14 retort insulating layers, 15 Retort refractory layer, 16 it is outer burn nozzle for combustion gas, 17 visors, 18 jet tube sheets, 19 cloth gas chambers, 20 lower perforated plates, 21 self-produced combustion gas are curved Pipe, 22 collection ballutes, 23 hot combustion gas outlets, 24 cooling half garden pipes, 25 unload charcoal machine.
Specific embodiment:
A kind of vertical shaft type tubulation retort, is made of drying oven and retort, it is characterised in that the drying oven 2 separates Setting is provided with drying oven charger 1 at the top of retort upper side, the retort 2, and bottom is provided with drying oven unloader 6, by moisture content be 12-25% particle drying oven charger 1 be added, be dried in drying oven 2 moisture content be 2% with Under, drying oven unloader 6 and retort charger 7 are accepted, and are continuously sent to retort charger 7 with drying oven unloader 6, described Drying oven charger 1, preferably double-charging bell charger, the preferred oscillating feeder of the drying oven unloader 6, the drying oven 2 Equipped with the wet flue gas outlet 3 for being connected to its inner cavity, side lower wall is equipped with the 2 cloth ballute 4 of drying oven for being connected to its inner cavity and does upper side wall Dry furnace hot fume inlet tube 5 is sent to the hot cigarette of drying oven with connecting tube by about 500 DEG C of hot fume of retort smoke outlet tube 9 Gas inlet pipe 5 (as shown in phantom in FIG.) between hot fume is evenly arranged on particle to be dried through 2 cloth ballute 4 of drying oven, carries out straight Connect heat exchange drying, be higher than dew point at a temperature of, by 3 outlet of wet flue gas outlet, the retort is successively arranged from the top down Feeding section, charing section, cooling section and unloading part, the feeding section are equipped with retort charger 7, and retort charger 7 is preferably double The upper side wall of bell charger, the flat glassware 8 of retort, the charing section is equipped with the smoke outlet tube 9 of connection charing furnace chamber, charcoal Change section and set heat exchanging pipe 12, closed with upper perforated plate 10 and lower perforated plate 20, manages outer setting baffle plate 11, make hot fume along snakelike through-flow Tubulation is passed through, to give heat outside enhanced tube, the material of the charing section is walked in pipe, and hot fume is walked outside pipe, outside retort retort Shell 13, retort insulating layer 14 and retort refractory layer 15 are built into closed furnace body, and outer supply is arranged in the lower outside of the charing section Nozzle 16 and visor 17 are burnt in combustion gas, described outer for combustion gas burning nozzle 16, for retort at the initial stage of ignition, as self-produced gas quantity increases, Gradually reduce outer for gas quantity, until completely close outer for combustion gas, and combustion air is not closed, for self-produced fuel gas buring, The visor 17 regulates and controls coefficient of excess air for observing combustion position, in the lower end outside 12 pipe of heat exchanging pipe, if Jet tube sheet 18 is set, it and lower perforated plate 20 constitute cloth gas chamber 19, the cloth gas chamber 19 and self-produced 21 connection of combustion gas bend pipe, described The top setting collection ballute 22 of cooling section, pyrolysis gaseous products are exported with hot combustion gas outlet 23, in the cone appearance of cooling section Cooling half garden pipe 24 is arranged in face, unloads charcoal machine 25 in unloading part setting, described to unload charcoal machine 25, the preferably disk of applicant's invention Formula unloader, heat carrier of the hot fume that drying oven uses retort smoke outlet tube 9 to draw as drying;
The aperture of uniformly distributed multiple φ 8- φ 12 on the jet tube sheet 18;
The hot combustion gas outlet 23 is derived to be pyrolyzed gaseous products, can be divided into two-way with threeway, all the way through self-produced combustion gas Bend pipe 21 is sent to 19 another way of cloth gas chamber and is sent to condensation cooling recovery system;
The preferred vertical shaft type furnace of waste heat drying oven.Its structure can refer to a kind of internal combustion type biomass invented by applicant Particulate material is dry, carbonizes, the dryer section of activation integral furnace.
Use the waste heat of retort as the heat source of dry feedstock particle.The flue gas temperature as derived from retort is generally greater than 450 DEG C, a large amount of sensible heats are had, are ideal dry heat carriers.This measure also reduces hot dirt while improving the thermal efficiency Dye mitigates urban heat land effect.
It is preceding to have addressed, in wood vinegar and wood tar containing a large amount of oxygenatedchemicals form, which includes acetic acid, phenol, alcohol, Ketone and carbohydrate and some acetal compounds, their all considerable calorific values only generate H after burning2O and CO2, in raw material straw Substantially free of sulfide, SO can not be generated in flue gas2, the calorific value for being pyrolyzed gaseous products in addition is not high, and ignition temperature is not high, Therefore NO in flue gasxAlso not high, therefore flue gas can direct emission without desulphurization denitration.

Claims (4)

1. a kind of vertical shaft type tubulation retort, is made of drying oven and retort, it is characterised in that drying oven 2 is disposed on Retort upper side is provided with drying oven charger 1 at the top of the retort 2, and bottom is provided with drying oven unloader 6, described The side upper wall of drying oven 2 is equipped with the wet flue gas outlet 3 for being connected to its inner cavity, and side lower wall is equipped with 2 cloth of drying oven for being connected to its inner cavity Ballute 4 and drying oven hot fume inlet tube 5, drying oven unloader 6 and retort charger 7 are accepted, the retort on to Under be successively arranged feeding section, charing section, cooling section and unloading part, the feeding section is equipped with retort charger 7, the flat material of retort The upper side wall of device 8, the charing section is equipped with the smoke outlet tube 9 of connection charing furnace chamber, and charing section sets heat exchanging pipe 12, use Tube sheet 10 and lower perforated plate 20 are closed, and outer setting baffle plate 11 is managed, and the material of the charing section is walked in pipe, and hot fume is walked outside pipe, charcoal Change furnace charing stove outer covering 13, retort insulating layer 14 and retort refractory layer 15 are built into closed furnace body, the charing section Lower outside, setting is outer to burn nozzle 16 and visor 17 for combustion gas, and in the lower end outside 12 pipe of heat exchanging pipe, jet tube sheet is arranged 18, it and lower perforated plate 20 constitute cloth gas chamber 19, the cloth gas chamber 19 and self-produced 21 connection of combustion gas bend pipe, in the upper of the cooling section Portion's setting collection ballute 22, pyrolysis gaseous products are exported with hot combustion gas outlet 23, and cooling is arranged in the outer surface of cone of cooling section Half garden pipe 24 unloads charcoal machine 25 in unloading part setting.
2. a kind of vertical shaft type tubulation retort required such as power 1, it is characterised in that: drying oven retort smoke outlet tube 9 hot fumes drawn are as dry heat carrier.
3. a kind of vertical shaft type tubulation retort required such as power 1, it is characterised in that: uniformly distributed multiple φ on the jet tube sheet 18 The aperture of 8- φ 12.
4. a kind of vertical shaft type tubulation retort required such as power 1, it is characterised in that: the pyrolysis gas derived from hot combustion gas outlet 23 State product can be divided into two-way with threeway, be sent to 19 another way of cloth gas chamber through self-produced combustion gas bend pipe 21 all the way and be sent to condensation and cool back Receipts system.
CN201910587293.0A 2019-06-20 2019-06-20 A kind of vertical shaft type tubulation retort Pending CN110240914A (en)

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CN201910587293.0A CN110240914A (en) 2019-06-20 2019-06-20 A kind of vertical shaft type tubulation retort

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Application Number Priority Date Filing Date Title
CN201910587293.0A CN110240914A (en) 2019-06-20 2019-06-20 A kind of vertical shaft type tubulation retort

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149006A (en) * 2020-12-22 2022-03-08 吴植仁 Carbonization and activation integrated furnace for preparing activated carbon

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816581A (en) * 2012-07-12 2012-12-12 华中科技大学 Vertical tube moving bed continuous pyrolysis apparatus for biomass
CN104789236A (en) * 2015-04-30 2015-07-22 吴植仁 Internal-combustion type biomass particle material drying, carbonizing and activating integrated furnace
CN108641753A (en) * 2018-04-08 2018-10-12 王树宽 The system and method for vertical heater low order pyrolysis of coal preparing coal tar coal gas

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816581A (en) * 2012-07-12 2012-12-12 华中科技大学 Vertical tube moving bed continuous pyrolysis apparatus for biomass
CN104789236A (en) * 2015-04-30 2015-07-22 吴植仁 Internal-combustion type biomass particle material drying, carbonizing and activating integrated furnace
CN108641753A (en) * 2018-04-08 2018-10-12 王树宽 The system and method for vertical heater low order pyrolysis of coal preparing coal tar coal gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149006A (en) * 2020-12-22 2022-03-08 吴植仁 Carbonization and activation integrated furnace for preparing activated carbon

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Application publication date: 20190917