CN110218119A - A kind of synergy fertilizer and preparation method thereof - Google Patents
A kind of synergy fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN110218119A CN110218119A CN201910557416.6A CN201910557416A CN110218119A CN 110218119 A CN110218119 A CN 110218119A CN 201910557416 A CN201910557416 A CN 201910557416A CN 110218119 A CN110218119 A CN 110218119A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- added
- nitrification inhibitor
- metronidazole
- synergy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to a kind of synergy fertilizer and preparation method thereof, which is characterized in that contains nitrification inhibitor and metronidazole.The present invention can be further improved slow release effect, extend fertilizer efficiency, improve utilization rate of fertilizer.
Description
Technical field
The present invention relates to a kind of synergy fertilizer and preparation method thereof.
Background technique
China's grain yield accounts for the 16% of the world, and fertilizer amount accounts for 31%, and per hectare dosage is 4 times of world's average dose,
Wherein utilization rate of nitrogen fertilizer is 30% or so, currently in order to improving there are two ways to utilization rate of nitrogen fertilizer uses, one is use coating
Agent carries out coating to fertilizer and achievees the purpose that sustained release in a manner of package, is greatly represented with Nintaus;One kind presses down for nitrification is added
Preparation, by inhibiting NH4 +To NO3 -Conversion, to achieve the purpose that sustained release, using German BASF product En Taike as representative.
For coating agent mainly using resin and sulphur as raw material, there is degradation difficulty and acidification soil in the coating agent of resin and sulphur
The problem of earth;Although nitrification inhibitor can inhibit NH4 +To NO3 -Conversion, specially NH4 ++1.5O2—NO2 -+H2O+2H-, NO2 -
+0.5O2-- NO3 -;However soil acidification is hardened serious at present, the state of anoxic is in soil for a long time, under conditions of anaerobism
Anaerobic bacteria will do it denitrification, by NO3 -It is converted into N2Also nitrogen can be made to cause damages, specially NO2 -+ 3H(electronics donor-
Organic matter) -- 0.5N2+H2O+OH-;NO3 -+ 5H(electronics donor-organic matter) -- 0.5N2+2H2O+OH-, therefore, soil at present
Although nitrification inhibitor is added in situation, still there is also the losses of nitrogen, cause the waste of nutrient.
Meanwhile sulfatereducting bacteria can be by H in hardened soil2SO4It is reduced to H2S, H2S again can be by part beneficial to micro
Element and moderate-element are fixed, and so as to cause hunger sign in plant, such as bitter pit, cause crop failure, reduction reaction is
C6H12O2+3H2SO4—6CO2+6H2O+H2S;S2-+Ca2+--- CaS(precipitating).
At present there has been no on the basis of nitrification inhibitor product, nitrogen discharge is further prevented, utilization rate of fertilizer is improved
Product, also without improving the product in hardened soil beneficial to middle microelement utilization rate.
Summary of the invention
The present invention provides a kind of synergy fertilizer and preparation method thereof, and solving technical problem is 1) in the base of nitrification inhibitor product
On plinth, nitrogen discharge is further prevented, improves utilization rate of fertilizer;2) it improves beneficial to utilization of the middle microelement in hardened soil
Rate.
In order to solve the above-mentioned technical problem, the invention adopts the following technical scheme:
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.1~1:0.1~1:98~99.8.
Described be added in fertilizer includes being added in fertilizer slurry after mixing, carries out whitewashing or high-tower granulation;It is added to
It carries out squeezing in fertilizer material or roller is granulated;It is added in fertilizer material and mixes;It is added in liquid fertilizer and mixes.
Invention has following advantageous effects:
1. the present invention can further prevent nitrogen discharge, utilization rate of fertilizer is improved.
2. the utilization rate that middle microelement in hardened soil can be improved in the present invention.
Specific embodiment
The present invention is further illustrated below with reference to specific example.
Embodiment 1
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.3:0.4:99.3.
The fertilizer is compound fertilizer, and described be added to refers in fertilizer and be added in fertilizer material, is mixed with fertilizer material,
It is granulated through roller, compound fertilizer is made;The nitrification inhibitor is DMPP.
The compound fertilizer content is 15-15-15.
Embodiment 2
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.2:0.8:99.
The fertilizer is compound fertilizer, and described be added to refers in fertilizer and be added in fertilizer slurry, is mixed with slurry, through spraying
Slurry is granulated, and compound fertilizer is made.
The nitrification inhibitor is the mixture of DCD and DMPP according to mass ratio 1:1.
Embodiment 3
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.6:0.4:99.
The fertilizer is urea, it is described be added in fertilizer refer to be added to urine slurry in, with urine slurry mix, through whitewashing make
Urea is made in grain.
The nitrification inhibitor is DMPP.
Embodiment 4
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.8:0.5:98.7.
The fertilizer is biological organic fertilizer, and described be added to refers in fertilizer and be added in fertilizer material, passes through and squeezes, system
Obtain biological organic fertilizer.
The nitrification inhibitor is green crystalline substance N+.
Embodiment 5
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The preparation method of synergy fertilizer, nitrification inhibitor and metronidazole are added in fertilizer to get enhanced fertilizer.
The mass ratio of nitrification inhibitor, metronidazole and fertilizer is 0.4:0.4:99.2.
The fertilizer is Water soluble fertilizer, and the addition, which refers to, to be added in Water soluble fertilizer raw material, up to Water soluble fertilizer after mixing.
The nitrification inhibitor is DMPP.
Embodiment 6
A kind of synergy fertilizer, contains nitrification inhibitor and metronidazole.
The nitrification inhibitor is one or more of DMPP, CP and DCD.
Beneficial effects of the present invention are further illustrated below with reference to experimental data:
Material to be tested
1 materials and methods:
1.1 test sites: government's bank, Anqiu City town.
1.2 experiment detections: in corn yield and corn stover and seed in the content of crude protein and every 100g seed
Calcium, magnesium and Zn content.
1.3 materials to be tested: 1(is not in addition to being added metronidazole for comparison, and other preparation methods are consistent with embodiment 1), comparison 2
(in addition to nitrification inhibitor is not added, other preparation methods are consistent with embodiment 1) and embodiment 1.
1.4 experimental methods:
Experimental plot takes the close 6 mu of adjacent fields of ground condition, and Tanaka's soil is hardened soil, with every two mu for one group.Sowing is beautiful per acre
Rice kind 2.2kg, using mechanical planting, maize seed is grand flat 206, and every group is respectively adopted comparison 1(in addition to metronidazole is not added,
Its preparation method is consistent with embodiment 1), comparison 2(in addition to nitrification inhibitor is not added, other preparation methods with embodiment 1
Unanimously) and embodiment 1 is used as base fertilizer, and base applies 50kg/ mus.
1.5 detection methods: Kjeldahl's method detects the percentage composition (N%) of nitrogen in stalk and seed, crude protein content
(CPC%)=N%*6.25.
In addition to experiment process is different, other operations are consistent for this experiment.
2 results and analysis
Corn yield and corn kernel and straw crude protein content, calcium, magnesium and Zn content are shown in Table 1 in every 100g seed
Table 1
Yield (kg) | Seed crude protein content (%) | Straw crude protein (%) | Calcium (mg) | Magnesium (mg) | Zinc (mg) | |
Comparison 1 | 669.4 | 8.33 | 5.54 | 2.1 | 9.4 | 0 |
Comparison 2 | 651.6 | 8.25 | 5.43 | 2.4 | 10.2 | 0.1 |
Embodiment 1 | 698.4 | 8.43 | 5.60 | 5.3 | 15.5 | 0.2 |
As can be seen from Table 1, crop yield can be improved compared to comparison 1 and comparison 2 in the embodiment of the present application 1, improves seed
The utilization rate that crude protein and straw crude protein content, i.e. the application can be further improved nitrogen.Equally, as can be seen from Table 1, originally
Application can also improve in microelement utilization rate.That is metronidazole and nitrification inhibitor collective effect, can be further improved
The utilization rate of utilization rate of fertilizer and middle microelement.
Claims (4)
1. a kind of synergy fertilizer, which is characterized in that contain nitrification inhibitor and metronidazole.
2. the preparation method of synergy fertilizer, which is characterized in that nitrification inhibitor and metronidazole to be added in fertilizer to get synergy fertilizer
Material.
3. the preparation method of synergy fertilizer as claimed in claim 2, which is characterized in that the matter of nitrification inhibitor, metronidazole and fertilizer
Amount is than being 0.1~1:0.1~1:98~99.8.
4. the preparation method of synergy fertilizer as described in Claims 2 or 3, which is characterized in that described be added to includes being added in fertilizer
After mixing into fertilizer slurry, whitewashing or high-tower granulation are carried out;It is added in fertilizer material and carries out extruding or roller granulation;It is added
It is mixed into fertilizer material;It is added in liquid fertilizer and mixes.
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CN201910557416.6A CN110218119A (en) | 2019-06-25 | 2019-06-25 | A kind of synergy fertilizer and preparation method thereof |
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CN201910557416.6A CN110218119A (en) | 2019-06-25 | 2019-06-25 | A kind of synergy fertilizer and preparation method thereof |
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Citations (7)
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---|---|---|---|---|
CN101434503A (en) * | 2007-11-16 | 2009-05-20 | 中国科学院沈阳应用生态研究所 | Synergistic slow release urea fertilizer and preparation thereof |
CN101434504A (en) * | 2007-11-16 | 2009-05-20 | 中国科学院沈阳应用生态研究所 | Synergistic slow release nitrogen fertilizer and preparation thereof |
CN102992906A (en) * | 2012-12-27 | 2013-03-27 | 安徽帝元生物科技有限公司 | Effect-increasing loss-control agent for fertilizer and preparation method thereof |
CN103992193A (en) * | 2014-05-20 | 2014-08-20 | 陆佳乾 | Long-acting and slow-release blended fertilizer special for tomatoes |
CN104478583A (en) * | 2014-12-09 | 2015-04-01 | 南京信息工程大学 | Composition capable of reducing emission of greenhouse gas from cropland and application of composition |
CN108727140A (en) * | 2018-06-13 | 2018-11-02 | 天津富成源肥业有限公司 | Boron-rich bulk blended fertilizer of a kind of sustained release chelated zinc and preparation method thereof |
CN108794182A (en) * | 2018-07-11 | 2018-11-13 | 丽水地乐农业科技合伙企业(普通合伙) | Slow-releasing composite material and its preparation method and application |
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2019
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Patent Citations (7)
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CN101434503A (en) * | 2007-11-16 | 2009-05-20 | 中国科学院沈阳应用生态研究所 | Synergistic slow release urea fertilizer and preparation thereof |
CN101434504A (en) * | 2007-11-16 | 2009-05-20 | 中国科学院沈阳应用生态研究所 | Synergistic slow release nitrogen fertilizer and preparation thereof |
CN102992906A (en) * | 2012-12-27 | 2013-03-27 | 安徽帝元生物科技有限公司 | Effect-increasing loss-control agent for fertilizer and preparation method thereof |
CN103992193A (en) * | 2014-05-20 | 2014-08-20 | 陆佳乾 | Long-acting and slow-release blended fertilizer special for tomatoes |
CN104478583A (en) * | 2014-12-09 | 2015-04-01 | 南京信息工程大学 | Composition capable of reducing emission of greenhouse gas from cropland and application of composition |
CN108727140A (en) * | 2018-06-13 | 2018-11-02 | 天津富成源肥业有限公司 | Boron-rich bulk blended fertilizer of a kind of sustained release chelated zinc and preparation method thereof |
CN108794182A (en) * | 2018-07-11 | 2018-11-13 | 丽水地乐农业科技合伙企业(普通合伙) | Slow-releasing composite material and its preparation method and application |
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