CN110215031A - A kind of spectacle case and preparation method thereof with fog-proof lens - Google Patents
A kind of spectacle case and preparation method thereof with fog-proof lens Download PDFInfo
- Publication number
- CN110215031A CN110215031A CN201910584112.9A CN201910584112A CN110215031A CN 110215031 A CN110215031 A CN 110215031A CN 201910584112 A CN201910584112 A CN 201910584112A CN 110215031 A CN110215031 A CN 110215031A
- Authority
- CN
- China
- Prior art keywords
- fog
- film layer
- eyeglass
- glasses
- ultraviolet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 241000510164 Cumberlandia monodonta Species 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000011521 glass Substances 0.000 claims abstract description 31
- 230000006698 induction Effects 0.000 claims abstract description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- 229920005989 resin Polymers 0.000 claims description 31
- 239000011347 resin Substances 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 30
- 239000000377 silicon dioxide Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 18
- 239000004408 titanium dioxide Substances 0.000 claims description 13
- 238000007738 vacuum evaporation Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 238000003618 dip coating Methods 0.000 claims description 9
- 238000001704 evaporation Methods 0.000 claims description 9
- 230000008020 evaporation Effects 0.000 claims description 9
- 238000007711 solidification Methods 0.000 claims description 9
- 230000008023 solidification Effects 0.000 claims description 9
- 238000007747 plating Methods 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000006096 absorbing agent Substances 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000004014 plasticizer Substances 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000007872 degassing Methods 0.000 claims description 3
- 239000000539 dimer Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 230000001939 inductive effect Effects 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 230000010412 perfusion Effects 0.000 claims description 3
- 238000003672 processing method Methods 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 239000013638 trimer Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 229920002574 CR-39 Polymers 0.000 claims description 2
- -1 acrylic ester Chemical class 0.000 claims description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 2
- 238000004544 sputter deposition Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 229920003180 amino resin Polymers 0.000 claims 1
- JMPVESVJOFYWTB-UHFFFAOYSA-N dipropan-2-yl carbonate Chemical compound CC(C)OC(=O)OC(C)C JMPVESVJOFYWTB-UHFFFAOYSA-N 0.000 claims 1
- NUHSROFQTUXZQQ-UHFFFAOYSA-N isopentenyl diphosphate Chemical compound CC(=C)CCO[P@](O)(=O)OP(O)(O)=O NUHSROFQTUXZQQ-UHFFFAOYSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 230000003760 hair shine Effects 0.000 abstract description 3
- 239000010410 layer Substances 0.000 description 50
- 230000000694 effects Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 3
- 239000006117 anti-reflective coating Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45C—PURSES; LUGGAGE; HAND CARRIED BAGS
- A45C11/00—Receptacles for purposes not provided for in groups A45C1/00-A45C9/00
- A45C11/04—Spectacle cases; Pince-nez cases
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45C—PURSES; LUGGAGE; HAND CARRIED BAGS
- A45C13/00—Details; Accessories
- A45C13/001—Accessories
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45C—PURSES; LUGGAGE; HAND CARRIED BAGS
- A45C15/00—Purses, bags, luggage or other receptacles covered by groups A45C1/00 - A45C11/00, combined with other objects or articles
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Eyeglasses (AREA)
Abstract
A kind of spectacle case and preparation method thereof with fog-proof lens, it is formed by being coated with the glasses of the Anti-fog glasses eyeglass of titanium oxide film layer with the mirror case (5) equipped with ultraviolet source, it is characterized by: the circuit board (9) is equipped with two ultraviolet sources (6) and a pressure switch (8) above, the lower section of circuit board (9) is equipped with induction delay switch (7), lithium battery (10), side is equipped with charging jack (11), and the glasses for being coated with the Anti-fog glasses eyeglass of titanium oxide film layer are placed on the upper surface of ultraviolet source (6) and pressure switch (8).The present invention, the antifog film layer of the water of eyeglass in mirror case will generate Superhydrophilic after by the ultraviolet light source shines being mounted in mirror case, to keep anti-fog performance within a certain period of time, user wears the glasses of this fog-proof lens assembly, it can play and the phenomenon that lens surface influences sight because of the fogging that the temperature difference generates is mitigated or eliminated, there is certain practical value.
Description
Technical field
The present invention relates to Anti-fog glasses eyeglass and its auxiliary products design and manufacturing technology fields, particularly relate to a kind of Anti-fog mirror
Piece and matched mirror case product and preparation method thereof.
Background technique
The fog-proof lens of popular sale currently on the market, without exception be all that dip-coating is hydrophilic on transparent resin matrix piece
Property anti-fog coating after baking and curing be made, this eyeglass has two disadvantages: first is that antireflection film layer reduction cannot be deposited
The integral light-transmitting rate of eyeglass, makes the transmission of visible light of eyeglass be reduced to 88- from plated antireflection film layer 95-98%
90% or so, reduce the visibility that object is regarded under dark situation；Second is that losing lens surface in lens surface plating anti-reflection film layer
The blue that generates after plated film, green background color, reduce the aesthetics and quality sense of eyeglass, above-mentioned condition is all producer and consumption
Person institute is undesirable.
Summary of the invention
The present invention provides a kind of spectacle case with fog-proof lens, the eyeglass of this spectacle case is plating anti-reflection
The lens surface vacuum evaporation for penetrating film layer deposited the titanium dioxide TiO of one layer of 0.2-0.8um thickness2With silica SiO2Parent
The antifog film layer of water will generate Superhydrophilic after film layer is by the ultraviolet light source shines being mounted in mirror case, thus one
It fixes time interior holding anti-fog performance, user wears the glasses of this fog-proof lens assembly, so that it may play and eyeglass is mitigated or eliminated
The phenomenon that surface influences sight because of the fogging that the temperature difference generates, has certain practical value.It is anti-that invention also provides one kind
The production method of fog filter piece and matched mirror case product.
Above-mentioned purpose that the invention is realized by the following technical scheme: a kind of spectacle case with fog-proof lens, by being coated with dioxy
Change the glasses of the Anti-fog glasses eyeglass of titanium film layer and the mirror case composition equipped with ultraviolet source, the fog-proof lens are by resin base
Piece, stiffened film layer, antireflection film layer, antifog film layer are formed；The mirror case is by ultraviolet source, induction delay switch, pressure
Switch, circuit board, lithium battery and charging jack are formed；It is characterized by: the circuit board top is equipped with two ultraviolet lights
Source and a pressure switch, the lower section of circuit board are equipped with induction delay switch, lithium battery, and side is equipped with charging jack, is coated with two
The glasses of the Anti-fog glasses eyeglass of titanium oxide layer are placed on the upper surface of ultraviolet source and pressure switch.
The resin substrate uses the tree of 1.499,1.56,1.60,1.67,1.71,1.74,1.76 index of refraction of index of refraction
Rouge lens monomer, substrate monomer material chemical component are allyl diglycol carbonates, two acrylic ester of M-phthalic acid, amino tree
Alicyclic monomer material.
The antifog film layer uses titanium dioxide TiO2, silica SiO2Mixture, by titanium dioxide and titanium dioxide
The anti-reflection that silicon target is deposited in eyeglass with ion cloud is mixed into after the sputtering of high-voltage arc method in vacuum evaporation plating machine in the ratio of 3:1
It penetrates layer surface and forms antifog film layer, thicknesses of layers 0.2-0.8um.
The ultraviolet source uses the ultraviolet emissioning tube of 80 model of HK275S37CG-, emission peak wavelength 270-
285nm, radiant power 6-9.5mw, driving current 100ma, operating voltage 5-9.5V, light emitting angle 120, maximum operating currenbt
200ma, overall dimensions 3.7x3.7x1.7mm.Usage amount 2.
The induction delay switch uses GKi -2a type finished product inductive switch circuit board.
The pressure switch uses 10 type small microswitch of KW-, and switch has two groups of contacts of normally-open normally-close, this control
Normally opened contact is used in circuit processed.
Production method of the invention, comprising the following steps:
1) it, makes resin substrate: monomer will be selected to be sent into dedicated preparing tank at room temperature, and claim dicetyl peroxydicarbonate by weight
Diisopropyl ester initiator IPP, ultraviolet absorbing agent UVG and plasticizer DOP are added in tank, stir under certain temperature and pressure mixed
Close, degasification, make liquid and bubble separation, vacuumize purification, then low temperature cold storage -10 DEG C it is spare；Using for lPP measures 2.0%, purple
Ultraviolet absorbers dosage 0.04%, plasticizer consumption 0.01%；
2), die perfusion: will pour into the glass mold clearly cleaned after the spare monomer electricity consumption nitrogen pressurization of the configuration of cold storage,
Then it is transferred to solidified forming process；
3), solidified forming: the preset pregel after a certain period of time of the mold for being perfused with monomer is sent into curing apparatus and is heated, first
48 DEG C are heated up to, 2h is kept, then average rate rises to 90 DEG C, and accelerates to be down to 60 DEG C, completes monomer cure molding by 21h and is made
Resin substrate；
4), stablize processing: being made annealing treatment after eyeglass demoulding, internal stress is eliminated to reduce dimer or trimer, to mention
The stability of high eyeglass improves the image quality of eyeglass, and processing method is: eyeglass being heated up to about 110 DEG C, keeps 2h, is led to
It crosses above several programs and has just obtained resin substrate；
5), resin substrate surface stiffened and drying and processing: first hardening liquid is added in stainless steel dip tank, then the tree after solidification
Aliphatic radical piece is suspended on above dip-coating hanger with hanging tag 40 one group, is sent to above hardening liquid dip tank, hanger, which slowly falls, to be made
Eyeglass enters dip-coating silica hardening liquid in dip tank, and falling speed 2-3mm per second, slot is interior to impregnate residence time 5-10S, on
Pull rate 2-3mm per second is risen, time 30S is lifted, eyeglass is sent to dry solidification in far-infrared baking oven after lifting out immersion liquid slot
Eyeglass stiffened film layer, 80-100 DEG C of solidification temperature, curing time 30-60min；
6), vacuum evaporation antireflection film layer, antifog film layer: electric arc is successively successively drawn respectively by setup program in vacuum evaporation plating machine
Evaporation oxidation zirconium is lighted in evaporation, is deposited antireflection film layer (3)；Evaporation titanium dioxide and silica are lighted in arcing, are deposited antifog
Fog-proof lens finished product is made in film layer (4)；
7) fog-proof lens plated, are gone out into final lens product by user's optometry degree requirement cutting and grinding on slicing machine, it will be at
Product eyeglass is packed into the spectacle frame chosen, and one pair of complete Anti-fog glasses is made；
8), mirror case assembles: first ultraviolet source, induction delay switch, pressure switch, lithium battery and charging jack successively being installed
Face on circuit boards；Circuit board is put into the lower part of mirror case again and is screwed securely, then Anti-fog glasses are placed on circuit
On plate, the assembling of mirror case is completed.
The present invention, the eyeglass in mirror case deposited one in the lens surface vacuum evaporation for having plated antireflection film layer
The titanium dioxide TiO of layer 0.2-0.8um thickness2With silica SiO2Hydrophilic antifogging film layer, when film layer is mounted in mirror case
Ultraviolet light source shines after will generate Superhydrophilic, to keep anti-fog performance within a certain period of time, user wears this
The glasses of fog-proof lens assembly, so that it may play and lens surface is mitigated or eliminated because the fogging that the temperature difference generates influences showing for sight
As having certain practical value.
Detailed description of the invention
Fig. 1 is eyeglass film layer structure schematic diagram of the invention.
Fig. 2 is mirror case structural schematic diagram of the invention.
Fig. 3 is mirror case circuit diagram of the invention.
Fig. 4 is the hydrophilic antifogging timeliness schematic diagram of eyeglass of the present invention.
In figure: 1 resin substrate, 2 stiffened film layers, 3 antireflection film layers, 4 antifog film layers, 5 mirror cases, 6 ultraviolet sources, 7 inductions
Delay switch, 8 pressure switches, 9 circuit boards, 10 lithium batteries, 11 charging jacks.
Specific embodiment
By knowing in Fig. 1, a kind of spectacle case with fog-proof lens of the present invention, by resin substrate 1, stiffened film layer 2, antireflective coating
Layer 3, antifog film layer 4, mirror case 5, ultraviolet source 6, induction delay switch 7, pressure switch 8, circuit board 9, lithium battery 10 and charging
Socket 11 is formed, and the circuit board 9 is equipped with two ultraviolet sources 6 and a pressure switch 8, the lower section of circuit board 9 above
Equipped with induction delay switch 7, lithium battery 10, side is equipped with charging jack 11, is coated with the Anti-fog glasses eyeglass of titanium oxide film layer
Glasses be placed on the upper surface of ultraviolet source 6 and pressure switch 8.
The antireflective coating 3 refers to that the metal cloud formed in vacuum evaporation plating machine using zirconium oxide target is deposited on resin
Substrate surface obtains, thickness 100-300nm；The effect of antireflection film layer 3 is the visible light transmittance for improving resin substrate 1, is subtracted
The light loss of few 1 medium of resin substrate, the clear surrounding that can be also seen in rather dark environment.Add coated with antireflection film
After layer 3, the transmitance of resin substrate 1 can increase 3-5%, and 1 total visible light transmittance of resin substrate is made to reach 95% or more.
The antifog film layer 4 uses titanium dioxide TiO2, silica SiO2Mixture, can obtain ideal anti-
Fog effect and required anti-fog duration.Antifog principle process is as follows: long-term in general or in dark environment
When storage, TiO 2 coating film surface and water have biggish contact angle, and contact angle is 72 ± 10, but after ultraviolet light irradiates, it connects
Feeler is reduced to 0 ± 10, at this point, will be inhaled by the Superhydrophilic of titanium dioxide coating surface when droplet falls on lens surface
It is attached to be decomposed into thin layer moisture film rapidly, transparent state is presented, avoids the effect of blocking after the generation of white mist layer to sight.Two
The Superhydrophilic of titanium oxide coating surface is its variation in ultraviolet light lower surface configuration, two under the conditions of ultraviolet illumination
Titanium oxide valence-band electrons are excited to conduction band, in Surface Creation electron hole pair, electronics and T1 4+Reaction, hole then with surface bridge
Oxygen reaction, keeps Surface Oxygen hollow, thus T nearby1 4+Turn to T1 3+, T1 3+It is adsorbed suitable for free water.At this point, the hydrolysis in air
Ionic adsorption becomes chemical absorbed water (surface hydroxyl) in vacancy, and chemical absorbed water can further adsorb the moisture in air,
Object water adsorption layer is formed, i.e., in T1 3+The microcell of highly-hydrophilic is formd around defect, and surface residual region still keeps hydrophobic
Property, in this way in TiO2Surface constitutes the hydrophilic and oleophylic microcell for the nano-scale separation being evenly distributed, and is similar to two-dimensional capillary
Pipe phenomenon.Since the size of water droplet and oil droplet is far longer than the area in hydrophilic and oleophilic area, therefore macroscopically TiO2Surface exhibits are hydrophilic out
And oil-wet behavior, the water or oil to drip is not adsorbed by hydrophilic microcell or oleophylic microcell, to infiltrate surface, stops ultraviolet light
Irradiation, the hydroxyl of chemisorption are replaced by the oxygen in air, again appear as water delivery state, after stopping illumination, surface is super close
It is aqueous to maintain a few hours, be then slowly restored to shine before hydrophobic state, then use ultraviolet illumination, and surface be it is super hydrophilic
Property, i.e., surface can be made to remain super hydrophilic state using interval ultraviolet light.But titanium oxide film layer is under normal conditions
It will restore that hydrophobicity is no longer antifog, and to solve this problem, we introduce hydrophilic when for a long time without ultraviolet light
Earth silicon material is improved.Silica SiO2It is a kind of hydroaropic substance, film surface is rich in a large amount of hydroxyl, is in
Reveal hydrophily, it can adsorb the hydrone in air, improve the humidity of eyeglass film surface.When titanium dioxide and silica
Material is mixed into ion cloud after being sputtered in vacuum evaporation plating machine with high-voltage arc method in 3:1 certain ratio and is deposited in subtracting for eyeglass
Layer surface is reflected, the antifog film layer of the highly-hydrophilic with long period anti-fog function of our needs will be obtained.
Large size spectacle case of the mirror case 5 using commercially available irony outsourcing plastic film composite, apparent size
180x70x50mm.Charging jack is set in the right side lower edge of mirror case.
Ultraviolet emissioning tube of the ultraviolet source 6 using 80 model of HK275S37CG-, emission peak wavelength 270-
285nm, radiant power 6-9.5mw, driving current 100ma, operating voltage 5-9.5V, light emitting angle 120, maximum operating currenbt
200ma, overall dimensions 3.7x3.7x1.7mm.Usage amount 2.
The lithium battery 10 uses long 50mm, wide 30mm, the platypelloid type polymer Li-ion electricity of thick 4mm specifications and models
Pond, operating voltage 3.7V, capacitance 800-1000mA/h.
The charging jack 11 is using the 5 flat socket of needle of U8-5P type mobile phone connector for using international uniform standard, peace
It is connected on the left of mirror case with lithium battery.
The pressure switch 8 uses 10 type small microswitch of KW-, and switch has two groups of contacts of normally-open normally-close, this control
Normally opened contact is used in circuit processed.
The circuit board 9 applies copper circuit board using long 140x wide 40x thickness 1mm laminated fiber epoxy resins insulation, above
Ultraviolet source, induction delay switch, pressure switch, lithium battery and charging jack are installed.
The induction delay switch 7 uses GKi -2a type finished product inductive switch circuit module, is mounted on the inside of mirror case,
After opening mirror case 5 is put into glasses, pressure switch 8 is connected, and induction delay switch 7 controls 6 transmitting tube power supply of ultraviolet source, 3 minutes photographs
Fog-proof lens are penetrated, power supply irradiation is opened after then entering dormant state 3 hours, 3 hours again and keeps lens surface in eyeglass 3 minutes
Superhydrophilic loops back and forth like this, until glasses take out.
The stiffened film layer 2 uses commercially available silica hardening liquid, such as domestic CR 39 eyeglass stiffened XT-113, CH-
01-8H, TC2000, FC200 model hardening liquid, Japanese import TS-56-T resin lens hardening liquid, hardening liquid is in resin substrate table
The resin lens of the dip-coating thickness 1-2um in face, different indexs of refraction and material will be matched with the hardening liquid of corresponding model.?
The purpose of substrate surface dip-coating stiffened film layer is to improve the surface hardness of substrate, makes the surface hardness of resin substrate 1 by original
4-5H increases to 6-7H, improves the wear-resistant degree of scratch-resistant of eyeglass, keeps eyeglass more sturdy and durable during wearing.
The present invention the production method is as follows:
1, make resin substrate 1:1), monomer will be selected to be sent into dedicated preparing tank at room temperature, by weight claiming initiator IPP
(di-isopropyl peroxydicarbonate), ultraviolet absorbing agent (UVG) and plasticizer (DOP) are added in tank, in certain temperature and pressure
Under be stirred, degasification, make liquid and bubble separation, vacuumize purification, then low temperature cold storage (- 10 DEG C) it is spare.The dosage of lPP
Take 2.0%, ultraviolet absorbing agent dosage 0.04%, plasticizer consumption 0.01%.
2), die perfusion: the glass molds clearly cleaned will be poured into after the spare monomer electricity consumption nitrogen pressurization of the configuration of cold storage
In tool, it is then transferred to solidified forming process.
3), solidified forming: the mold for being perfused with monomer preset after a certain period of time (pregel) is sent into curing apparatus and is added
Temperature is heated up to 48 DEG C first, keeps 2h, and then average rate rises to 90 DEG C, and accelerates to be down to 60 DEG C, completes monomer cure by 21h
Resin substrate is made in molding.
4), stablize processing: being made annealing treatment after eyeglass demoulding, eliminate internal stress to reduce dimer or trimer, from
And the stability of eyeglass is improved, improve the image quality of eyeglass, processing method is: eyeglass is heated up to about 110 DEG C, keeps
2h has just obtained resin substrate 1 by above several programs.
2,1 surface stiffened of resin substrate and drying and processing: first hardening liquid is added in stainless steel dip tank, then after solidification
Resin substrate 1 be suspended on above dip-coating hanger with hanging tag 40 one group, be sent to above hardening liquid dip tank, hanger slowly under
Falling makes eyeglass enter dip-coating silica hardening liquid in dip tank, and falling speed 2-3mm per second, slot is interior to impregnate residence time 5-
10S rises pull rate 2-3mm per second, lifts time 30S, and eyeglass is lifted out to be sent to after immersion liquid slot in far-infrared baking oven and be done
Dry solidification eyeglass stiffened film layer, 80-100 DEG C of solidification temperature, curing time 30-60min.
3, vacuum evaporation antireflection film layer 3, antifog film layer 4: successively successively distinguish by setup program in vacuum evaporation plating machine
It draws arc evaporation to light evaporation oxidation zirconium, antireflection film layer 3 is deposited；Evaporation titanium dioxide and silica, vapor deposition are lighted in arcing
Fog-proof lens finished product is made in antifog film layer 4.
4, the fog-proof lens plated are gone out into final lens product by user's optometry degree requirement cutting and grinding on slicing machine, it will
Final lens product is packed into the spectacle frame chosen, and one pair of complete Anti-fog glasses is made.
5, referring to Fig. 2, the matched mirror case assembly method of product of the present invention is as follows:
Ultraviolet source 6, induction delay switch 7, pressure switch 8, lithium battery 10 and charging jack 11 are first sequentially arranged at circuit
Above plate 9；Circuit board 9 is put into the lower part of mirror case 5 again and is screwed securely, the assembling of mirror case is completed.
Fig. 2 Fig. 3 referring to Fig.1, application method of the invention are described as follows with the course of work: antifog eye is taken when night rest
Temple fold-back rear lens is lowered into mirror case 5 by mirror, covers mirror case lid, at this point, pressure switch 8 is pushed by mirror holder, power supply is connected,
Incude delay switch 7 to open, be distributed in mirror case two sides ultraviolet source 6 light after issue ultraviolet light and be irradiated to the tables of two eyeglasses
The Superhydrophilic of eyeglass titanium oxide film layer is activated in face, and circuit is transferred to dormant state automatically after delay irradiation 3 minutes；Work as suspend mode
Time is more than that circuit, which automatically opens, to continue to close after irradiating 3 minutes after 3 hours, keeps and consolidate the height Superhydrophilic of eyeglass,
It and so on carries out, until glasses wearer, which opens mirror case 5, takes out glasses.
Referring to Fig. 4, antifog timeliness of the invention is described as follows: 3 after fog-proof lens receive ultraviolet source intense irradiation are small
When interior hydrophily effect it is best, hydrophilic angle is almost 00；With extending to 6 hours for time, hydrophilic angle increases to 2-30, 12 is small
When after reach 5-60, anti-fog effect is gradually deteriorated backward, until losing anti-fog effect.At this moment glasses are put into box again and are irradiated,
Anti- fog effect restores, and can continue to wear holding anti-fog function after taking-up.
Claims (7)
1. a kind of spectacle case with fog-proof lens, by being coated with the glasses of the Anti-fog glasses eyeglass of titanium oxide film layer and equipped with ultraviolet
The mirror case (5) of light source forms, and the fog-proof lens are by resin substrate (1), stiffened film layer (2), antireflection film layer (3), antifog
Film layer (4) is formed；The mirror case (5) is by ultraviolet source (6), induction delay switch (7), pressure switch (8), circuit board
(9), lithium battery (10) and charging jack (11) are formed；It is characterized by: the circuit board (9) is ultraviolet equipped with two above
Light source (6) and a pressure switch (8), the lower section of circuit board (9) are equipped with induction delay switch (7), lithium battery (10), and side is set
There are charging jack (11), the glasses for being coated with the Anti-fog glasses eyeglass of titanium oxide film layer are placed on ultraviolet source (6) and pressure is opened
Close the upper surface of (8).
2. a kind of spectacle case with fog-proof lens according to claim 1, it is characterised in that: the resin substrate (1)
Using the resin lens monomer of 1.499,1.56,1.60,1.67,1.71,1.74,1.76 index of refraction of index of refraction, substrate monomer material
Expect that chemical component is allyl diglycol carbonates, two acrylic ester of M-phthalic acid, amino resins monomer material.
3. a kind of spectacle case with fog-proof lens according to claim 1, it is characterised in that: the antifog film layer (4)
Using titanium dioxide TiO2, silica SiO2Mixture, by titanium dioxide and silica target in the ratio of 3:1 true
Antifog film layer is formed with being mixed into ion cloud after the sputtering of high-voltage arc method and be deposited in the antireflection layer surface of eyeglass in empty evaporator,
Thicknesses of layers 0.2-0.8um.
4. a kind of spectacle case with fog-proof lens according to claim 1, it is characterised in that: the ultraviolet source (6)
Using the ultraviolet emissioning tube of 80 model of HK275S37CG-, emission peak wavelength 270-285nm, radiant power 6-9.5mw are driven
Streaming current 100ma, operating voltage 5-9.5V, light emitting angle 120, maximum operating currenbt 200ma, overall dimensions
3.7x3.7x1.7mm.Usage amount 2.
5. a kind of spectacle case with fog-proof lens according to claim 1, it is characterised in that: the induction delay switch
(7) GKi -2a type finished product inductive switch circuit board is used.
6. a kind of spectacle case with fog-proof lens according to claim 1, it is characterised in that: the pressure switch (8)
Using 10 type small microswitch of KW-, switch has two groups of contacts of normally-open normally-close, uses normally opened contact in this control circuit.
7. a kind of production method of the spectacle case according to claim 1 with fog-proof lens, which is characterized in that including following
Step:
1) it, makes resin substrate (1): monomer will be selected to be sent into dedicated preparing tank at room temperature, and claim peroxidating two by weight
Diisopropyl carbonate initiator IPP, ultraviolet absorbing agent UVG and plasticizer DOP are added in tank, stir under certain temperature and pressure
Mix mixing, degasification, make liquid and bubble separation, vacuumize purification, then low temperature cold store -10 DEG C it is spare；Using for lPP measures
2.0%, ultraviolet absorbing agent dosage 0.04%, plasticizer consumption 0.01%；
2), die perfusion: will pour into the glass mold clearly cleaned after the spare monomer electricity consumption nitrogen pressurization of the configuration of cold storage,
Then it is transferred to solidified forming process；
3), solidified forming: the preset pregel after a certain period of time of the mold for being perfused with monomer is sent into curing apparatus and is heated, first
48 DEG C are heated up to, 2h is kept, then average rate rises to 90 DEG C, and accelerates to be down to 60 DEG C, completes monomer cure molding by 21h and is made
Resin substrate (1)；
4), stablize processing: being made annealing treatment after eyeglass demoulding, internal stress is eliminated to reduce dimer or trimer, to mention
The stability of high eyeglass improves the image quality of eyeglass, and processing method is: eyeglass being heated up to about 110 DEG C, keeps 2h, is led to
It crosses above several programs and has just obtained resin substrate (1)；
5), resin substrate (1) surface stiffened and drying and processing: first hardening liquid is added in stainless steel dip tank, then after solidification
Resin substrate (1) be suspended on above dip-coating hanger with hanging tag 40 one group, be sent to above hardening liquid dip tank, hanger is slowly
Whereabouts makes eyeglass enter dip-coating silica hardening liquid in dip tank, and falling speed 2-3mm per second, slot is interior to impregnate residence time 5-
10S rises pull rate 2-3mm per second, lifts time 30S, and eyeglass is lifted out to be sent to after immersion liquid slot in far-infrared baking oven and be done
Dry solidification eyeglass stiffened film layer, 80-100 DEG C of solidification temperature, curing time 30-60min；
6), vacuum evaporation antireflection film layer (3), antifog film layer (4): successively successively distinguish by setup program in vacuum evaporation plating machine
It draws arc evaporation to light evaporation oxidation zirconium, is deposited antireflection film layer (3)；Evaporation titanium dioxide and silica are lighted in arcing, are steamed
Antifog film layer (4) are plated, fog-proof lens finished product is made；
7) fog-proof lens plated, are gone out into final lens product by user's optometry degree requirement cutting and grinding on slicing machine, it will be at
Product eyeglass is packed into the spectacle frame chosen, and one pair of complete Anti-fog glasses is made；
8), mirror case assembles: first ultraviolet source (6), induction delay switch (7), pressure switch (8), lithium battery (10) and charging
Socket (11) is sequentially arranged at circuit board (9) above；Circuit board (9) is put into the lower part of mirror case (5) again and is screwed jail
Gu then Anti-fog glasses are placed on circuit board (9), complete the assembling of mirror case.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910584112.9A CN110215031A (en) | 2019-07-01 | 2019-07-01 | A kind of spectacle case and preparation method thereof with fog-proof lens |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910584112.9A CN110215031A (en) | 2019-07-01 | 2019-07-01 | A kind of spectacle case and preparation method thereof with fog-proof lens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110215031A true CN110215031A (en) | 2019-09-10 |
Family
ID=67815407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910584112.9A Pending CN110215031A (en) | 2019-07-01 | 2019-07-01 | A kind of spectacle case and preparation method thereof with fog-proof lens |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110215031A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2022021808A (en) * | 2020-07-22 | 2022-02-03 | 株式会社ジンズホールディングス | UV irradiator |
| JP2022190843A (en) * | 2021-06-15 | 2022-12-27 | 株式会社ジンズホールディングス | Ultraviolet ray irradiator for eyewear |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1085022A (en) * | 1996-09-12 | 1998-04-07 | Toto Ltd | Glasses case |
| CN2437078Y (en) * | 2000-02-03 | 2001-06-27 | 吴亦军 | Circular timing switch for ultraviolet ray sterilizing lamp |
| CN2505084Y (en) * | 2001-09-03 | 2002-08-14 | 张嘉平 | Electronic sterilizer for oral cleaning device |
| CN1767777A (en) * | 2003-05-14 | 2006-05-03 | 株式会社村上开明堂 | Anti-fog mirror |
| JP3140316U (en) * | 2008-01-09 | 2008-03-21 | 正一 中村 | Glasses and eyeglass case |
| CN202777153U (en) * | 2012-09-20 | 2013-03-13 | 昆明理工大学 | Sterilization device of television remote controller |
| CN108261086A (en) * | 2017-01-03 | 2018-07-10 | 佛山市顺德区美的电热电器制造有限公司 | The preparation method of Anti-fog mirror, cooking apparatus and Anti-fog mirror |
| CN109946848A (en) * | 2019-04-24 | 2019-06-28 | 丹阳市精通眼镜技术创新服务中心有限公司 | A kind of phase-change thermal storage Anti-fog glasses piece and preparation method thereof |
| CN210299896U (en) * | 2019-07-01 | 2020-04-14 | 丹阳市精通眼镜技术创新服务中心有限公司 | Spectacle case with antifogging lens |
-
2019
- 2019-07-01 CN CN201910584112.9A patent/CN110215031A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1085022A (en) * | 1996-09-12 | 1998-04-07 | Toto Ltd | Glasses case |
| CN2437078Y (en) * | 2000-02-03 | 2001-06-27 | 吴亦军 | Circular timing switch for ultraviolet ray sterilizing lamp |
| CN2505084Y (en) * | 2001-09-03 | 2002-08-14 | 张嘉平 | Electronic sterilizer for oral cleaning device |
| CN1767777A (en) * | 2003-05-14 | 2006-05-03 | 株式会社村上开明堂 | Anti-fog mirror |
| JP3140316U (en) * | 2008-01-09 | 2008-03-21 | 正一 中村 | Glasses and eyeglass case |
| CN202777153U (en) * | 2012-09-20 | 2013-03-13 | 昆明理工大学 | Sterilization device of television remote controller |
| CN108261086A (en) * | 2017-01-03 | 2018-07-10 | 佛山市顺德区美的电热电器制造有限公司 | The preparation method of Anti-fog mirror, cooking apparatus and Anti-fog mirror |
| CN109946848A (en) * | 2019-04-24 | 2019-06-28 | 丹阳市精通眼镜技术创新服务中心有限公司 | A kind of phase-change thermal storage Anti-fog glasses piece and preparation method thereof |
| CN210299896U (en) * | 2019-07-01 | 2020-04-14 | 丹阳市精通眼镜技术创新服务中心有限公司 | Spectacle case with antifogging lens |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2022021808A (en) * | 2020-07-22 | 2022-02-03 | 株式会社ジンズホールディングス | UV irradiator |
| JP7473188B2 (en) | 2020-07-22 | 2024-04-23 | 株式会社ジンズホールディングス | Ultraviolet irradiator |
| JP2022190843A (en) * | 2021-06-15 | 2022-12-27 | 株式会社ジンズホールディングス | Ultraviolet ray irradiator for eyewear |
| JP7351536B2 (en) | 2021-06-15 | 2023-09-27 | 株式会社ジンズホールディングス | UV irradiator for eyewear |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110215031A (en) | A kind of spectacle case and preparation method thereof with fog-proof lens | |
| CN104076413B (en) | The optical goods of subgrade and temperature-resistant multi-layer anti-reflection coating are scribbled, its manufacture method | |
| CN110596911B (en) | Color-changing lens and preparation method and application thereof | |
| CN105861993B (en) | Color resin spectacle lens and preparation method thereof | |
| CN105866975A (en) | Color change resin spectacle lens and preparation method thereof | |
| CN106405691A (en) | Anti-fog optical resin lens and its preparation method | |
| CN106772707B (en) | A kind of preparation method of the antifog plated film resin lens of anti-blue light | |
| CN208207410U (en) | A kind of plated film resin lens containing sieve and silica-sesquioxide layer | |
| CN208569217U (en) | A kind of film layer discoloration polarized lenses of 1.499 refractive index | |
| CN105425418A (en) | Blue light filtering, radiation protection and wear resisting lens and preparation method thereof | |
| CN111929924A (en) | Goggles suitable for all-weather wearing and preparation method thereof | |
| CN109946848A (en) | A kind of phase-change thermal storage Anti-fog glasses piece and preparation method thereof | |
| CN108018527A (en) | A kind of anti glare anti static coatings lens coating method | |
| MX2015002810A (en) | Decorative glass panel having a reflective layer deposited on a textured substrate. | |
| CN1259187C (en) | Method for fabricating composite body of optical glasses applied in polarized light | |
| CN105425419A (en) | Blue light filtering and wear resisting lens and preparation method thereof | |
| CN210299896U (en) | Spectacle case with antifogging lens | |
| JP2008310007A (en) | Optical article and manufacturing method thereof | |
| CN203673162U (en) | Anti-blue-ray lens | |
| CN115490437B (en) | Coating process method for anti-reflection display cover plate glass | |
| CN203673091U (en) | Blue light radiation resistant lens | |
| CN108563036A (en) | A kind of six ring stone nanometer negative ion far infrared frame of illite and glasses | |
| CN217085447U (en) | Plasma wind discharge fog-dispersing lens | |
| CN208384155U (en) | A kind of composite film resin lens | |
| CN203673097U (en) | Blue light grade protection lens |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190910 |
|
| RJ01 | Rejection of invention patent application after publication |