CN110211483B - Printable surface adhesive double-anti-static label material and preparation method thereof - Google Patents

Printable surface adhesive double-anti-static label material and preparation method thereof Download PDF

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Publication number
CN110211483B
CN110211483B CN201910437626.1A CN201910437626A CN110211483B CN 110211483 B CN110211483 B CN 110211483B CN 201910437626 A CN201910437626 A CN 201910437626A CN 110211483 B CN110211483 B CN 110211483B
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coating
antistatic
polythiophene
label material
gms
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CN110211483A (en
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周荣杰
王益刚
黄伟
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Shenzhen Changmao Mucilage Glue New Material Co ltd
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Shenzhen Changmao Mucilage Glue New Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J191/00Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02Electrically-conducting adhesives
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)

Abstract

The invention provides a printable surface adhesive double-anti-static label material and a preparation method thereof, wherein the label comprises the following components from top to bottom: macromolecular GMS antistatic coating, transparent PET film, polythiophene coating, lithium sulfonate antistatic glue and glassine base paper. The printable surface adhesive double-anti-static label material has better shielding property, and the printable surface adhesive double-anti-static label material realizes high anti-static effect and has good performance and small influence on the physical property of glue water by arranging the special macromolecular anti-static printable coating GMS on the surface and matching the polythiophene anti-static coating with the high-viscosity oil adhesive doped with the lithium sulfonate antistatic agent.

Description

Printable surface adhesive double-anti-static label material and preparation method thereof
Technical Field
The invention belongs to the field of label materials, and particularly relates to a printable surface adhesive double-anti-static label material and a preparation method thereof.
Background
With the rapid development of the electronic industry, the integration level of electronic circuit boards is higher and higher, and the high density of electronic components on a mainboard, the compactness of wiring and even the wide adoption of surface-mounted components are easy to cause the electrostatic damage to the circuit board card.
In order to avoid damaging a circuit board and a component by electrostatic breakdown, a printable surface adhesive double-anti-static label material is needed.
Disclosure of Invention
The printable surface adhesive double-anti-static label material provided by the invention has better shielding property, and the high-static-resistance effect is realized by arranging the special macromolecular anti-static printable coating GMS on the surface and mixing the high-viscosity oil adhesive of the lithium sulfonate antistatic agent in the polythiophene anti-static coating, and meanwhile, the physical property of the adhesive is slightly influenced by good performance.
In order to achieve the purpose of the invention, the technical scheme adopted by the invention is as follows:
the utility model provides a printable face glue is anti static label material doubly which characterized in that: from top to bottom, the coating comprises a polymer GMS antistatic coating, a transparent PET film, a polythiophene coating, a lithium sulfonate antistatic adhesive and glassine base paper; the lithium sulfonate antistatic adhesive comprises the following raw materials of high-viscosity oil adhesive, a curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate, wherein the mass ratio of the high-viscosity oil adhesive to the curing agent is 100:1.73-2.11: 2-3: 0.4-0.6; the raw materials of the polythiophene coating comprise polythiophene antistatic coating liquid: purified water: isopropanol in a mass ratio of 1:2.5: 2.5; the polymer GMS antistatic coating comprises glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 2-4:1-2:80: 4-6.
Further, the raw materials of the lithium sulfonate antistatic adhesive comprise high-viscosity oil adhesive, a curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate, and the mass ratio of the lithium sulfonate antistatic adhesive to the lithium iron phosphate is 100:1.92: 2.5: 0.5.
further, the macromolecular GMS antistatic coating comprises glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 3:1.5:80: 5.
Further, the thickness of the transparent PET film is 50 um.
Further, the thickness of the polymer GMS antistatic coating is 20 um.
Further, the thickness of the polythiophene coating is 0.5 um.
Further, the thickness of the polymer GMS antistatic coating is 20 um.
A preparation method of a printable surface adhesive double-anti-static label material is characterized by comprising the following steps:
(1) coating a commercial 50um transparent PET film with a 0.5um polythiophene coating, and formulating polythiophene antistatic coating liquid: purified water: 1:2.5:2.5 isopropyl alcohol was gravure printed onto polyester film using a 200 mesh screen roller; (2) according to the weight ratio of high viscosity oil glue, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate of 100:1.73-2.11: 2-3: 0.4-0.6, preparing lithium sulfonate antistatic glue, and gluing at the rotation speed of 250-; (3) uniformly coating the lithium sulfonate antistatic adhesive at 80g/M by a comma blade coating mode2The glassine release film is adhered to the polythiophene coating surface of the PET film, glued with 20um and finally wound; (4) and (3) coating the surface of the semi-finished mask with a macromolecular GMS antistatic coating again, and directly printing a coating liquid concave on the polyester film surface by using a 200-mesh screen roller, wherein the macromolecular GMS antistatic coating is prepared from glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 2-4:1-2:80: 4-6.
The invention has the beneficial effects that: the printable surface adhesive double-anti-static label material has better shielding property, and the printable surface adhesive double-anti-static label material realizes high anti-static effect and has good performance and small influence on the physical property of glue water by arranging the special macromolecular anti-static printable coating GMS on the surface and matching the polythiophene anti-static coating with the high-viscosity oil adhesive doped with the lithium sulfonate antistatic agent. According to the label material, a very thin polythiophene coating is coated on a PET film, and then a lithium sulfonate antistatic coating is coated on the PET film, so that good bonding strength and a high antistatic effect are achieved. The lithium sulfonate antistatic adhesive realizes the synergistic antistatic effect by matching the lithium trifluoromethanesulfonate with the lithium iron phosphate. A layer of macromolecular GMS antistatic coating is arranged on the surface of the rolled semi-finished mask again, and the unique formula collocation of glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid realizes the printable performance, further improves the antistatic effect, has a lasting effect, and has strong firmness of combination with the PET film.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Any modifications that can be easily made by a person skilled in the art to the present invention without departing from the technical solutions of the present invention will fall within the scope of the claims of the present invention.
Example 1
A preparation method of a printable surface adhesive double-antistatic label material comprises the following steps: (1) coating a commercial 50um transparent PET film with a 0.5um polythiophene coating, and formulating polythiophene antistatic coating liquid: purified water: 1:2.5:2.5 isopropyl alcohol was gravure printed onto polyester film using a 200 mesh screen roller; (2) according to the weight ratio of high viscosity oil glue, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate of 100:1.92: 2.5: 0.5, preparing lithium sulfonate antistatic glue, and gluing at the rotating speed of 250-2000 r/min; (3) uniformly coating the lithium sulfonate antistatic adhesive at 80g/M by a comma blade coating mode2The glassine release film is adhered to the polythiophene coating surface of the PET film, glued with 20um and finally wound; (4) and (3) coating a 20-micrometer high-molecular GMS antistatic coating on the surface of the semi-finished mask again, and directly printing a concave coating on the polyester film surface by using a 200-mesh screen roller, wherein the high-molecular GMS antistatic coating is prepared from glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 3:1.5:80: 5.
Example 2
A preparation method of a printable surface adhesive double-antistatic label material comprises the following steps: (1) coating a commercial 50um transparent PET film with a 0.5um polythiophene coating, and formulating polythiophene antistatic coating liquid: purified water: 1:2.5:2.5 isopropyl alcohol was gravure printed onto polyester film using a 200 mesh screen roller; (2) according to the weight ratio of high viscosity oil glue, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate of 100:2.11: 2: 0.6, preparing lithium sulfonate antistatic glue, and gluing at the rotating speed of 250-2000 r/min; (3) uniformly coating the lithium sulfonate antistatic adhesive at 80g/M by a comma blade coating mode2The glassine release film is adhered to the polythiophene coating surface of the PET film, glued with 20um and finally wound; (4) coating the surface of the semi-finished facial mask again with a height of 20umThe molecular GMS antistatic coating is characterized in that a 200-mesh screen roller is used for directly gravure-printing a coating liquid on a polyester film surface, and raw materials of the molecular GMS antistatic coating comprise glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 2:2:80: 4.
Example 3
A preparation method of a printable surface adhesive double-antistatic label material comprises the following steps: (1) coating a commercial 50um transparent PET film with a 0.5um polythiophene coating, and formulating polythiophene antistatic coating liquid: purified water: 1:2.5:2.5 isopropyl alcohol was gravure printed onto polyester film using a 200 mesh screen roller; (2) according to the weight ratio of high viscosity oil glue, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate of 100:1.73: 3: 0.4, preparing lithium sulfonate antistatic glue, and gluing at the rotating speed of 250-2000 r/min; (3) uniformly coating the lithium sulfonate antistatic adhesive at 80g/M by a comma blade coating mode2The glassine release film is adhered to the polythiophene coating surface of the PET film, glued with 20um and finally wound; (4) and (3) coating a 20-micrometer high-molecular GMS antistatic coating on the surface of the semi-finished mask again, and directly printing a concave coating on the polyester film surface by using a 200-mesh screen roller, wherein the high-molecular GMS antistatic coating is prepared from glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 4:1:80: 6.
Comparative example 1
The procedure was carried out in the same manner as in example 1 except that lithium iron phosphate was not added to the raw material of the lithium sulfonate-based antistatic adhesive.
Comparative example 2
The same as example 1, except that polyglycerin-2 triisostearate, silicone, acrylic acid were not added to the raw materials of the polymeric GMS antistatic coating.
Comparative example 3
Same as example 1, except that polyglycerin-2 triisostearate was not added to the raw material of the polymeric GMS antistatic coating.
Comparative example 4
The same as example 1, except that no silicone was added to the raw material of the polymeric GMS antistatic coating.
Comparative example 5
Same as example 1, except that no acrylic acid was added to the raw material of the polymeric GMS antistatic coating.
Comparative example 6
Same as example 1 except that the polymeric GMS antistatic coating was not provided.
Comparative example 7
Same as example 1, except that the polythiophene coating layer was not provided.
The performance tests of examples 1-3 and comparative examples 1-7 are as follows.
TABLE 1
Figure BDA0002071013750000071

Claims (7)

1. The utility model provides a printable face glue is anti static label material doubly which characterized in that: from top to bottom, the coating comprises a polymer GMS antistatic coating, a transparent PET film, a polythiophene coating, a lithium sulfonate antistatic adhesive and glassine base paper; the lithium sulfonate antistatic adhesive comprises the following raw materials of high-viscosity oil adhesive, a curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate, wherein the mass ratio of the high-viscosity oil adhesive to the curing agent is 100:1.73-2.11: 2-3: 0.4-0.6; the raw materials of the polythiophene coating comprise polythiophene antistatic coating liquid: purified water: isopropanol in a mass ratio of 1:2.5: 2.5; the polymer GMS antistatic coating comprises glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 2-4:1-2:80: 4-6.
2. The printable surface adhesive double-anti-static label material as claimed in claim 1, wherein the lithium sulfonate antistatic adhesive comprises high viscous oil adhesive, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate in a mass ratio of 100:1.92: 2.5: 0.5.
3. the printable facestock dual anti-static label material of claim 1, wherein: the polymer GMS antistatic coating comprises glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 3:1.5:80: 5.
4. The printable facestock dual anti-static label material of claim 1, wherein: the thickness of transparent PET membrane is 50 um.
5. The printable facestock dual anti-static label material of claim 1, wherein: the thickness of the macromolecular GMS antistatic coating is 20 um.
6. The printable facestock dual anti-static label material of claim 1, wherein: the thickness of the polythiophene coating is 0.5 um.
7. A preparation method of a printable surface adhesive double-anti-static label material is characterized by comprising the following steps:
(1) coating a commercial 50um transparent PET film with a 0.5um polythiophene coating, and formulating polythiophene antistatic coating liquid: purified water: isopropanol =1:2.5:2.5, gravure printed onto polyester film using a 200 mesh screen roller; (2) according to the weight ratio of high viscosity oil glue, curing agent, lithium trifluoromethanesulfonate and lithium iron phosphate of 100:1.73-2.11: 2-3: 0.4-0.6, preparing lithium sulfonate antistatic glue, and gluing at the rotation speed of 250-; (3) uniformly coating the lithium sulfonate antistatic adhesive at 80g/M by a comma blade coating mode2The glassine release film is adhered to the polythiophene coating surface of the PET film, glued with 20um and finally wound; (4) and (3) coating the surface of the semi-finished mask with a macromolecular GMS antistatic coating again, and directly printing a coating liquid concave on the polyester film surface by using a 200-mesh screen roller, wherein the macromolecular GMS antistatic coating is prepared from glycerol monostearate, polyglycerol-2 triisostearate, silicone and acrylic acid in a mass ratio of 2-4:1-2:80: 4-6.
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CN1517425A (en) * 2003-01-15 2004-08-04 住友橡胶工业株式会社 Polymer type antistatic agent, antistatic behaviour polymer and its manufacturing method
CN1937009A (en) * 2005-09-20 2007-03-28 日东电工株式会社 Adhesive label for hard disk drive, and hard disk drive using the adhesive label for hard disk drive
CN102307963A (en) * 2009-02-27 2012-01-04 日东电工株式会社 Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet
CN103270549A (en) * 2010-12-22 2013-08-28 优泊公司 Electrostatic adhesive sheet
CN103958633A (en) * 2011-10-19 2014-07-30 日东电工株式会社 Water-dispersible acrylic adhesive composition, adhesive layer, and adhesive sheet
CN103946328A (en) * 2011-11-22 2014-07-23 日东电工株式会社 Surface protective film
EP2692809A1 (en) * 2012-07-30 2014-02-05 Seiko Instruments Inc. Pressure-sensitive adhesive label and label issuing device
CN107591511A (en) * 2016-07-07 2018-01-16 中国科学院物理研究所 Composite film material for lithium battery and its preparation method and application
CN109016769A (en) * 2018-06-27 2018-12-18 深汕特别合作区昌茂粘胶新材料有限公司 A kind of anti-static silica gel protective film and preparation method thereof
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