CN101108677A - Aluminum foil for packaging food and medicine and preparation method thereof - Google Patents

Aluminum foil for packaging food and medicine and preparation method thereof Download PDF

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Publication number
CN101108677A
CN101108677A CNA2007100258545A CN200710025854A CN101108677A CN 101108677 A CN101108677 A CN 101108677A CN A2007100258545 A CNA2007100258545 A CN A2007100258545A CN 200710025854 A CN200710025854 A CN 200710025854A CN 101108677 A CN101108677 A CN 101108677A
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China
Prior art keywords
aluminum foil
printing
component polymeric
agent
food
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CNA2007100258545A
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CN101108677B (en
Inventor
张军
徐根华
何建忠
单宁
刘涛
杨少军
瞿世军
徐学凯
宋雪梅
朱永希
卢正军
张艳华
周立军
张兴洋
梁裕波
陈强
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Jiangsu Zhongjin Matai Medicinal Packaging Co Ltd
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Jiangsu Zhongjin Matai Medicinal Packaging Co Ltd
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Priority to CN2007100258545A priority Critical patent/CN101108677B/en
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Abstract

The invention relates to an aluminum foil for packaging food and medicine, which comprises an aluminum foil layer and is characterized in that one surface of the aluminum foil layer is provided with an adhesive layer, and the other surface is provided with a bi-component polymer primer layer. The invention also discloses a preparation method of the aluminum foil for food and medicine packaging. The aluminum foil for packaging food and medicine has a simple structure, can be used for carrying out UV flexographic printing or UV letterpress printing on the aluminum foil, and the printing ink can not fall off through a tape test after printing, so that the aluminum foil is beneficial to environmental protection, and has good printing effect, bright color and low loss of printing materials.

Description

A kind of food and medicine Packaging Aluminum Foil and preparation method thereof
Technical field
The present invention relates to a kind of food and medicine packing, particularly a kind of food and medicine Packaging Aluminum Foil; The invention still further relates to this manufacturing aluminum foil.
Background technology
China just introduces flexographic printing technology in the seventies initial stage, through technical innovation repeatedly, has established the status in the packages printing field so far.Up to nineteen fifty-two, on the print session that Stockholm, SWE is held, negate that the participant agrees unanimously and changes Flexography into to the address of aniline printing.The implication that it is discussed was at that time, because photoresist is rudiment, the appearance of polyethylene, polyester, the carrier that is made for stock greatly increases, so the application approach high resilience of Flexography can be suitable for the printing of various uses, so life is this name, domestic translator comes for flexographic printing has passed from literal literal translation under the situation of the background of not understanding it, and is so far sanctified by usage.Arrived twentieth century first half, be used after the bright nonabsorbable packing of the printthrough glass paper, it uses expansion rapidly, relates to polyethylene and various film of synthetic resin, as the printing process of packing, lays a good foundation in European and American countries.Japan then just introduces this technology from earlier 1900s, be used for printing fluting board, paper bag etc., different with the America and Europe, originally never be applied to flexible packing material and carton field, reason has two, the one, not satisfied to the quality of flexographic printing, the 2nd, introduce gravure already and offset printing has satisfied demand.Recently, along with the environment of flexographic printing technology has been caught up with gravure and offset printing, so the speed of expanding is accelerated.
Relief printing with the longest history the most universal, space of a whole page image and literal projection are accepted printing ink, and the part that falls in is not accepted printing ink, and when version and letterweight were tight, printing ink will be imprinted on the paper.Printing plate mainly contains: type form, stereotype, photo zincography, copper coin, photopolymer plate etc.Some books and periodicals, bill, envelope, business card etc. are also using relief printing; For example need special processing: gold stamping, silver-colored, indentation is protruding etc. generally also used relief printing.
UV is the abbreviation of English Ultraviolet Rays, i.e. ultraviolet light.Ultraviolet ray (UV) is that naked eyes are invisible, is one section electromagnetic radiation beyond the visible purple light, and wavelength is in the scope of 10~400nm.The UV ink printing has following characteristics: 1. instantaneous solidification; Can in seconds solidify behind the UV ink printing, obviously improve production efficiency; Particularly aspect tin graphed sheet, utilize this characteristics, can omit the baking dry run.And drying equipment is simple, saves space.2. environmental protection; UV printing ink does not use solvent, and exhaust emission material not during curing can improve operating environment, air conservation.Because do not need solvent processing equipment and special environmental protecting device, can reduce equipment investment greatly simultaneously.3. photopolymerization drying mode; UV printing ink or UV gloss oil, only otherwise the contact ultraviolet ray just can not solidify, from this aspect, its keeping is fairly simple.And photopolymerization reaction and volatile dry are different, are a kind of chemosettings, and other printing ink ink film hardness height of film forming hardness ratio are applicable to the printing that film hardness is had relatively high expectations.4. high-quality; The glossiness height of UV printed matter has good rub resistance, solvent resistance, resistance to effect of heat etc., the product specification height.In packages printing, be extensive use of.5. save the energy; UV solidifies little power consumption, saves the energy.
In the prior art, printing on food and medicine Packaging Aluminum Foil material all is to adopt organic solvent type printing ink, and this is not only bad for environmental protection, and the colored printing effect is undesirable, the energy consumption height.Though UV flexographic printing or UV relief printing have plurality of advantages, but it fails to use on food and medicine Packaging Aluminum Foil material, reason just is that printing ink easily comes off, and also can't address this problem so far in the prior art when aluminium foil surface carries out the UV printing.
Summary of the invention
Technical matters to be solved by this invention is at the deficiencies in the prior art, and a kind of food and medicine Packaging Aluminum Foil new, that can carry out UV flexographic printing or UV relief printing thereon is provided.
Another technical matters to be solved by this invention provides a kind of preparation method of aforesaid food and medicine Packaging Aluminum Foil.
Technical matters to be solved by this invention is to realize by following technical scheme.The present invention is a kind of food and medicine Packaging Aluminum Foil, and it comprises aluminium foil layer, is characterized in, is provided with adhesive phase in the one side of aluminium foil layer, and another side is provided with bi-component polymeric basecoat agent layer.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described food and medicine Packaging Aluminum Foil is characterized in, the thickness of described aluminium foil layer is 7~80 microns.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described food and medicine Packaging Aluminum Foil is characterized in, is provided with on bi-component polymeric basecoat agent layer by UV flexographic printing or formed plane of UV relief printing or three-dimensional pattern and literal.
Technical matters to be solved by this invention can also further realize by following technical scheme.The present invention also provides a kind of preparation method of as the described food and medicine Packaging Aluminum Foil of above technical scheme, be characterized in, get aluminium foil, simultaneously be coated with adhesives at it, when being used to use and other material (materials such as pvc, pvdc are selected according to using needs to carry out material) heat-sealing; Another side forms bi-component polymeric basecoat agent layer by following technology: the host of getting in the agent of bi-component polymeric basecoat is diluted with organic solvent, add the curing agent in the agent of bi-component polymeric basecoat again, coat aluminium foil surface after stirring, after the coating, it is dried, be cured again after the oven dry, promptly.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, after being cured, carries out UV flexographic printing or UV relief printing on bi-component polymeric basecoat agent layer, forms plane or three-dimensional pattern and literal.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 15~22: 1.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, bake out temperature is 150~250 ℃, and the time is 8~15 seconds.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, bake out temperature is 180~220 ℃, and the time is 10~13 seconds.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, solidification temperature is 30~80 ℃, and the time is 10~72 hours.
Technical matters to be solved by this invention can also further realize by following technical scheme.Above-described preparation method is characterized in, solidification temperature is 30~50 ℃, and the time is 20~30 hours.
Bi-component polymeric basecoat agent described in the present invention, it is made of two components, is respectively host and curing agent, is milky or little yellow liquid, and the main chemical compositions of host is the polyurethanes material, and the curing agent main chemical is the isocyanates material.Organic solvent of the present invention refers to that all can dissolve the organic solvent of host, and organic solvent do not participate in reaction, and one or more in ethyl acetate, butanone, butyl acetate and the ethanol are pressed the compound of arbitrary proportion.The general chemical enterprise of bi-component polymeric basecoat agent is all on sale.The bi-component polymeric basecoat agent of for example producing, the not adept trade Co., Ltd in Shanghai sells by Shanghai Licai Ink Co., Ltd., oil at the bottom of the host commodity PTP by name, the curing agent trade mark is GH-75, the dealer address: Room 203, No. 6269 silver-colored clouds mansion Building B of Shanghai, Shanghai City Min Lu.Bi-component polymeric basecoat agent described in the present invention also can replace with the disclosed any silane coupling agent in packages printing field that is applicable in the prior art.
Compared with prior art, food and medicine Packaging Aluminum Foil of the present invention is simple in structure, and can carry out UV flexographic printing or UV relief printing thereon, printing back printing ink can not come off through scotch tape test, not only help environmental protection, and printing effect is good, ink color is bright-coloured, and the printing material loss is low.Preparation method's advantages of simple of food and medicine Packaging Aluminum Foil provided by the present invention, workable, prepared food and medicine Packaging Aluminum Foil quality of coming out is good, can be implemented in fully and carry out UV flexographic printing or UV relief printing on it.
The specific embodiment
Embodiment 1.A kind of food and medicine Packaging Aluminum Foil, it comprises aluminium foil layer, is provided with adhesive phase in the one side of aluminium foil layer, another side is provided with bi-component polymeric basecoat agent layer.
Embodiment 2.In embodiment 1, the thickness of described aluminium foil layer is 7 microns.
Embodiment 3.In embodiment 1, the thickness of described aluminium foil layer is 80 microns.
Embodiment 4.In embodiment 1, the thickness of described aluminium foil layer is 40 microns.
Embodiment 5.In embodiment 1, the thickness of described aluminium foil layer is 60 microns.
Embodiment 6.In embodiment 1, the thickness of described aluminium foil layer is 20 microns.
Embodiment 7.In embodiment 1, on bi-component polymeric basecoat agent layer, be provided with by UV flexographic printing or formed plane of UV relief printing or three-dimensional pattern and literal.
Embodiment 8.In embodiment 1, the thickness of described aluminium foil layer is 30 microns; On bi-component polymeric basecoat agent layer, be provided with by UV flexographic printing or formed plane of UV relief printing or three-dimensional pattern and literal.
Embodiment 9.A kind of preparation method as any one described food and medicine Packaging Aluminum Foil among the embodiment 1-6 gets aluminium foil, simultaneously is coated with adhesives at it, when being used to use and the heat-sealing of other material; Another side forms bi-component polymeric basecoat agent layer by following technology: the host of getting in the agent of bi-component polymeric basecoat is diluted with organic solvent, add the curing agent in the agent of bi-component polymeric basecoat again, coat aluminium foil surface after stirring, after the coating, it is dried, be cured again after the oven dry, promptly.
Embodiment 10.Embodiment 9 described preparation methods after being cured, carry out UV flexographic printing or UV relief printing on bi-component polymeric basecoat agent layer, form plane or three-dimensional pattern and literal.
Embodiment 11.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 15: 1.
Embodiment 12.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 22: 1.
Embodiment 13.Among any one described preparation method, bake out temperature is 150 ℃ among the embodiment 9-11, and the time is 15 seconds.
Embodiment 14.Among any one described preparation method, bake out temperature is 250 ℃ among the embodiment 9-11, and the time is 8 seconds.
Embodiment 15.Among any one described preparation method, bake out temperature is 200 ℃ among the embodiment 9-11, and the time is 12 seconds.
Embodiment 16.Among any one described preparation method, bake out temperature is 180 ℃ among the embodiment 9-11, and the time is 10 seconds.
Embodiment 17.Among any one described preparation method, bake out temperature is 220 ℃ among the embodiment 9-11, and the time is 13 seconds.
Embodiment 18.Among any one described preparation method, solidification temperature is 30 ℃ among the embodiment 9-17, and the time is 72 hours.
Embodiment 19.Among any one described preparation method, solidification temperature is 80 ℃ among the embodiment 9-17, and the time is 10 hours.
Embodiment 20.Among any one described preparation method, solidification temperature is 55 ℃ among the embodiment 9-17, and the time is 40 hours.
Embodiment 21.Among any one described preparation method, solidification temperature is 50 ℃ among the embodiment 9-17, and the time is 50 hours.
Embodiment 22.Among any one described preparation method, solidification temperature is 60 ℃ among the embodiment 9-17, and the time is 30 hours.
Embodiment 23.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 16: 1; Bake out temperature is 160 ℃, and the time is 14 seconds; Solidification temperature is 40 ℃, and the time is 15 hours.
Embodiment 24.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 17: 1; Bake out temperature is 170 ℃, and the time is 9 seconds; Solidification temperature is 70 ℃, and the time is 65 hours.
Embodiment 25.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 18: 1; Bake out temperature is 190 ℃, and the time is 11 seconds; Solidification temperature is 60 ℃, and the time is 55 hours.
Embodiment 26.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 19: 1; Bake out temperature is 210 ℃, and the time is 12 seconds; Solidification temperature is 45 ℃, and the time is 45 hours.
Embodiment 28.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 20: 1; Bake out temperature is 230 ℃, and the time is 10 seconds; Solidification temperature is 30 ℃, and the time is 30 hours.
Embodiment 29.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 21: 1; Bake out temperature is 225 ℃, and the time is 11 seconds; Solidification temperature is 40 ℃, and the time is 35 hours.
Embodiment 30.Among embodiment 9 or the 10 described preparation methods, the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 19: 1; Bake out temperature is 200 ℃, and the time is 12 seconds; Solidification temperature is 50 ℃, and the time is 30 hours.

Claims (10)

1. food and medicine Packaging Aluminum Foil, it comprises aluminium foil layer, it is characterized in that, is provided with adhesive phase in the one side of aluminium foil layer, another side is provided with bi-component polymeric basecoat agent layer.
2. food and medicine Packaging Aluminum Foil according to claim 1 is characterized in that, the thickness of described aluminium foil layer is 7~80 microns.
3. food and medicine Packaging Aluminum Foil according to claim 1 and 2 is characterized in that, is provided with on bi-component polymeric basecoat agent layer by UV flexographic printing or formed plane of UV relief printing or three-dimensional pattern and literal.
4. the preparation method of a food and medicine Packaging Aluminum Foil as claimed in claim 1 is characterized in that, gets aluminium foil, simultaneously is coated with adhesives at it, when being used to use and the heat-sealing of other material; Another side forms bi-component polymeric basecoat agent layer by following technology: the host of getting in the agent of bi-component polymeric basecoat is diluted with organic solvent, add the curing agent in the agent of bi-component polymeric basecoat again, coat aluminium foil surface after stirring, after the coating, it is dried, be cured again after the oven dry, promptly.
5. preparation method according to claim 4 is characterized in that, after being cured, carries out UV flexographic printing or UV relief printing on bi-component polymeric basecoat agent layer, forms plane or three-dimensional pattern and literal.
6. according to claim 4 or 5 described preparation methods, it is characterized in that the weight ratio that the host of bi-component polymeric basecoat agent adds curing agent and organic solvent is 15~22: 1.
7. according to claim 4 or 5 described preparation methods, it is characterized in that bake out temperature is 150~250 ℃, the time is 8~15 seconds.
8. preparation method according to claim 7 is characterized in that, bake out temperature is 180~220 ℃, and the time is 10~13 seconds.
9. according to claim 4 or 5 described preparation methods, it is characterized in that solidification temperature is 30~80 ℃, the time is 10~72 hours.
10. preparation method according to claim 9 is characterized in that, solidification temperature is 30~50 ℃, and the time is 20~30 hours.
CN2007100258545A 2007-08-06 2007-08-06 Aluminum foil for packaging food and medicine and method of manufacturing the same Active CN101108677B (en)

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CN101108677B CN101108677B (en) 2011-07-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103252944A (en) * 2013-05-28 2013-08-21 无锡市华泰医药包装有限公司 Aluminum foil for anti-fake medicine package and production technique thereof
CN108501490A (en) * 2018-04-10 2018-09-07 南通恒鑫新材料有限公司 A kind of preparation process of the reinforced high double-deck aluminum-plastic composite membrane of masking
CN115179669A (en) * 2022-08-22 2022-10-14 东莞市新唛标签制品有限公司 Relief printing method for aluminum foil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103252944A (en) * 2013-05-28 2013-08-21 无锡市华泰医药包装有限公司 Aluminum foil for anti-fake medicine package and production technique thereof
CN103252944B (en) * 2013-05-28 2016-01-27 无锡市华泰医药包装有限公司 A kind of anti-counterfeiting drug Packaging Aluminum Foil and production technology thereof
CN108501490A (en) * 2018-04-10 2018-09-07 南通恒鑫新材料有限公司 A kind of preparation process of the reinforced high double-deck aluminum-plastic composite membrane of masking
CN115179669A (en) * 2022-08-22 2022-10-14 东莞市新唛标签制品有限公司 Relief printing method for aluminum foil

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