CN110211483A - A kind of dual anti-electrostatic label material of printable face glue and preparation method thereof - Google Patents
A kind of dual anti-electrostatic label material of printable face glue and preparation method thereof Download PDFInfo
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- CN110211483A CN110211483A CN201910437626.1A CN201910437626A CN110211483A CN 110211483 A CN110211483 A CN 110211483A CN 201910437626 A CN201910437626 A CN 201910437626A CN 110211483 A CN110211483 A CN 110211483A
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- Prior art keywords
- glue
- antistatic
- coating
- gms
- polythiophene
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/023—Adhesive
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0257—Multilayer
Abstract
The present invention provides a kind of dual anti-electrostatic label material of printable face glue and preparation method thereof, and the label includes: macromolecule GMS antistatic coating, transparent PET film, polythiophene coating, the antistatic glue of Sulfonic Lithium system, Ge Laxin base stock from top to bottom.The dual anti-electrostatic label material of printable face glue of the invention, with preferable shielding, it can print coating GMS by the way that special polymeric antistatic is arranged on surface, and pass through the high-viscosity oil glue of incorporation Sulfonic Lithium system antistatic agent in the collocation of polythiophene antistatic coating, it is functional small to glue material properties affect itself while realizing high-antistatic effect.
Description
Technical field
The invention belongs to label material fields, and in particular to a kind of dual anti-electrostatic label material of printable face glue and its preparation
Method.
Background technique
With the fast development of electronics industry, electronic circuit board integrated level is higher and higher, electronic component on motherboard
High density, wiring compact, even surface-adhered type element be widely used, all easily lead to electrostatic damage route board.
In order to avoid electrostatic breakdown damages wiring board and component, a kind of dual anti-electrostatic label material of printable face glue is needed
Material.
Summary of the invention
The present invention provides a kind of dual anti-electrostatic label material of printable face glue, has preferable shielding, by surface
Special polymeric antistatic, which is arranged, can print coating GMS, and by mixing Sulfonic Lithium system in the collocation of polythiophene antistatic coating
The high-viscosity oil glue of antistatic agent is functional small to glue material properties affect itself while realizing high-antistatic effect.
In order to achieve the above-mentioned object of the invention, The technical solution adopted by the invention is as follows:
A kind of dual anti-electrostatic label material of printable face glue, it is characterised in that: from top to bottom include macromolecule GMS antistatic
Coating, transparent PET film, polythiophene coating, the antistatic glue of Sulfonic Lithium system, Ge Laxin base stock;The antistatic glue of Sulfonic Lithium system
Raw material includes high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, LiFePO4, mass ratio 100:1.73-2.11:2-3:
0.4-0.6;The raw material of the polythiophene coating includes polythiophene antistatic coating liquid: pure water: isopropanol, mass ratio 1:
2.5:2.5;It include monostearin, three isostearate of polyglycereol -2, silicon in the macromolecule GMS antistatic coating
Ketone, acrylic acid, mass ratio 2-4:1-2:80:4-6.
Further, the raw material of the antistatic glue of Sulfonic Lithium system includes high-viscosity oil glue, curing agent, trifluoromethane sulfonic acid
Lithium, LiFePO4, mass ratio 100:1.92:2.5:0.5.
It further, include monostearin, the different tristearin of polyglycereol -2 three in the macromolecule GMS antistatic coating
Acid esters, silicone, acrylic acid, mass ratio 3:1.5:80:5.
Further, the transparent PET film with a thickness of 50um.
Further, the macromolecule GMS antistatic coating with a thickness of 20um.
Further, the polythiophene coating with a thickness of 0.5um.
Further, the macromolecule GMS antistatic coating with a thickness of 20um.
A kind of preparation method of the dual anti-electrostatic label material of printable face glue, which comprises the steps of:
(1) the coating 0.5um polythiophene coating on commercially available 50um transparent PET film is formulated polythiophene antistatic coating liquid: pure
Water purification: isopropanol=1:2.5:2.5, using in the recessed painting printing to polyester film of 200 mesh anilox rolls;(2) by high-viscosity oil glue, solidification
Agent, trifluoromethyl sulfonic acid lithium, LiFePO4, mass ratio are that 100:1.73-2.11:2-3:0.4-0.6 carries out preparing Sulfonic Lithium system
Antistatic glue carries out gluing, revolving speed 250-2000r/min;(3) Sulfonic Lithium system is resisted in such a way that comma scraper is coated with quiet
Electric glue is uniformly coated on 80g/M2Ge Laxin release film on and be bonded with the polythiophene coat side of PET film, glue 20um, most
After wind;(4) the facial mask surface of semi-finished product is carried out once being coated with macromolecule GMS antistatic coating again, uses 200 mesh anilox rolls
Directly by the recessed painting printing to polyester film surface of coating solution, the raw material of macromolecule GMS antistatic coating is monostearin, is gathered
Three isostearate of glycerol -2, silicone, acrylic acid, mass ratio 2-4:1-2:80:4-6.
The beneficial effects of the present invention are: the dual anti-electrostatic label material of printable face glue of the invention has preferable hide
Covering property can print coating GMS by the way that special polymeric antistatic is arranged on surface, and be arranged in pairs or groups by polythiophene antistatic coating
The high-viscosity oil glue of interior incorporation Sulfonic Lithium system antistatic agent, it is functional to glue object itself while realizing high-antistatic effect
Property influence it is small.Then label material of the invention is coated with Sulfonic Lithium system by the polythiophene coating of one layer very thin of coating on PET film
After antistatic coating, good adhesion strength and high-antistatic effect are realized.The antistatic glue of Sulfonic Lithium system passes through trifluoromethyl
Sulfonic Lithium, LiFePO4 collocation use, and realize synergistic antistatic effect.Winding semi-finished product facial mask surface again
One layer of macromolecule GMS antistatic coating of secondary setting, by monostearin, three isostearate of polyglycereol -2, silicone, third
This unique formula collocation of olefin(e) acid, while realizing printing performance, further increases antistatic effect and has persistently
Effect, and have the very strong firmness in conjunction with PET film.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate this hair
It is bright, rather than limit the scope of the invention.Under the premise of without departing substantially from technical solution of the invention, the present invention is made
Those of ordinary skill in the art's any change easy to accomplish fall within scope of the presently claimed invention.
Embodiment 1
A kind of preparation method of the dual anti-electrostatic label material of printable face glue, includes the following steps: that (1) is saturating in commercially available 50um
Coating 0.5um polythiophene coating on bright PET film is formulated polythiophene antistatic coating liquid: pure water: isopropanol=1:2.5:2.5,
Using in the recessed painting printing to polyester film of 200 mesh anilox rolls;(2) high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, ferric phosphate are pressed
Lithium, mass ratio are that 100:1.92:2.5:0.5 carries out preparing the antistatic glue of Sulfonic Lithium system, carry out gluing, revolving speed 250-2000r/
min;(3) the antistatic glue of Sulfonic Lithium system is uniformly coated on 80g/M in such a way that comma scraper is coated with2Ge Laxin it is release
It is bonded on film and with the polythiophene coat side of PET film, glues 20um, finally wind;(4) the facial mask surface of semi-finished product is carried out again
The macromolecule GMS antistatic coating of primary coating 20um, using 200 mesh anilox rolls directly by the recessed painting printing of coating solution to polyester film
On face, the raw material of macromolecule GMS antistatic coating is monostearin, three isostearate of polyglycereol -2, silicone, propylene
Acid, mass ratio 3:1.5:80:5.
Embodiment 2
A kind of preparation method of the dual anti-electrostatic label material of printable face glue, includes the following steps: that (1) is saturating in commercially available 50um
Coating 0.5um polythiophene coating on bright PET film is formulated polythiophene antistatic coating liquid: pure water: isopropanol=1:2.5:2.5,
Using in the recessed painting printing to polyester film of 200 mesh anilox rolls;(2) high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, ferric phosphate are pressed
Lithium, mass ratio are that 100:2.11:2:0.6 carries out preparing the antistatic glue of Sulfonic Lithium system, carry out gluing, revolving speed 250-2000r/
min;(3) the antistatic glue of Sulfonic Lithium system is uniformly coated on 80g/M in such a way that comma scraper is coated with2Ge Laxin it is release
It is bonded on film and with the polythiophene coat side of PET film, glues 20um, finally wind;(4) the facial mask surface of semi-finished product is carried out again
The macromolecule GMS antistatic coating of primary coating 20um, using 200 mesh anilox rolls directly by the recessed painting printing of coating solution to polyester film
On face, the raw material of macromolecule GMS antistatic coating is monostearin, three isostearate of polyglycereol -2, silicone, propylene
Acid, mass ratio 2:2:80:4.
Embodiment 3
A kind of preparation method of the dual anti-electrostatic label material of printable face glue, includes the following steps: that (1) is saturating in commercially available 50um
Coating 0.5um polythiophene coating on bright PET film is formulated polythiophene antistatic coating liquid: pure water: isopropanol=1:2.5:2.5,
Using in the recessed painting printing to polyester film of 200 mesh anilox rolls;(2) high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, ferric phosphate are pressed
Lithium, mass ratio are that 100:1.73:3:0.4 carries out preparing the antistatic glue of Sulfonic Lithium system, carry out gluing, revolving speed 250-2000r/
min;(3) the antistatic glue of Sulfonic Lithium system is uniformly coated on 80g/M in such a way that comma scraper is coated with2Ge Laxin it is release
It is bonded on film and with the polythiophene coat side of PET film, glues 20um, finally wind;(4) the facial mask surface of semi-finished product is carried out again
The macromolecule GMS antistatic coating of primary coating 20um, using 200 mesh anilox rolls directly by the recessed painting printing of coating solution to polyester film
On face, the raw material of macromolecule GMS antistatic coating is monostearin, three isostearate of polyglycereol -2, silicone, propylene
Acid, mass ratio 4:1:80:6.
Comparative example 1
It is same as Example 1, in addition to not adding LiFePO4 in the raw material of the antistatic glue of Sulfonic Lithium system.
Comparative example 2
It is same as Example 1, it is different hard in addition to not adding polyglycereol -2 three in the raw material of the macromolecule GMS antistatic coating
Resin acid ester, silicone, acrylic acid.
Comparative example 3
It is same as Example 1, it is different hard in addition to not adding polyglycereol -2 three in the raw material of the macromolecule GMS antistatic coating
Resin acid ester.
Comparative example 4
It is same as Example 1, in addition to not adding silicone in the raw material of the macromolecule GMS antistatic coating.
Comparative example 5
It is same as Example 1, in addition to not adding acrylic acid in the raw material of the macromolecule GMS antistatic coating.
Comparative example 6
It is same as Example 1, in addition to being not provided with macromolecule GMS antistatic coating.
Comparative example 7
It is same as Example 1, in addition to being not provided with polythiophene coating.
The performance test of embodiment 1-3 and comparative example 1-7 are as follows.
Table 1
Claims (8)
1. a kind of dual anti-electrostatic label material of printable face glue, it is characterised in that: from top to bottom include the antistatic painting of macromolecule GMS
Layer, transparent PET film, polythiophene coating, the antistatic glue of Sulfonic Lithium system, Ge Laxin base stock;The original of the antistatic glue of Sulfonic Lithium system
Material includes high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, LiFePO4, mass ratio 100:1.73-2.11:2-3:0.4-
0.6;The raw material of the polythiophene coating includes polythiophene antistatic coating liquid: pure water: isopropanol, mass ratio 1:2.5:
2.5;In the macromolecule GMS antistatic coating include monostearin, three isostearate of polyglycereol -2, silicone, third
Olefin(e) acid, mass ratio 2-4:1-2:80:4-6.
2. the dual anti-electrostatic label material of printable face glue according to claim 1, which is characterized in that the Sulfonic Lithium system is anti-
The raw material of electrostatic glue includes high-viscosity oil glue, curing agent, trifluoromethyl sulfonic acid lithium, LiFePO4, mass ratio 100:1.92:2.5:
0.5。
3. the dual anti-electrostatic label material of printable face glue according to claim 1, it is characterised in that: the macromolecule GMS
In antistatic coating include monostearin, three isostearate of polyglycereol -2, silicone, acrylic acid, mass ratio 3:1.5:
80:5。
4. the dual anti-electrostatic label material of printable face glue according to claim 1, it is characterised in that: the transparent PET film
With a thickness of 50um.
5. the dual anti-electrostatic label material of printable face glue according to claim 1, it is characterised in that: the macromolecule GMS
Antistatic coating with a thickness of 20um.
6. the dual anti-electrostatic label material of printable face glue according to claim 1, it is characterised in that: the polythiophene coating
With a thickness of 0.5um.
7. the dual anti-electrostatic label material of printable face glue according to claim 1, it is characterised in that: the macromolecule GMS
Antistatic coating with a thickness of 20um.
8. a kind of preparation method of the dual anti-electrostatic label material of printable face glue, it is characterised in that include the following steps:
(1) the coating 0.5um polythiophene coating on commercially available 50um transparent PET film is formulated polythiophene antistatic coating liquid: pure
Water: isopropanol=1:2.5:2.5, using in the recessed painting printing to polyester film of 200 mesh anilox rolls;(2) by high-viscosity oil glue, curing agent,
Trifluoromethyl sulfonic acid lithium, LiFePO4, mass ratio be 100:1.73-2.11:2-3:0.4-0.6 carry out prepare Sulfonic Lithium system resist it is quiet
Electric glue carries out gluing, revolving speed 250-2000r/min;(3) by the antistatic glue of Sulfonic Lithium system in such a way that comma scraper is coated with
Uniformly it is coated on 80g/M2Ge Laxin release film on and be bonded with the polythiophene coat side of PET film, glue 20um, finally receive
Volume;(4) the facial mask surface of semi-finished product is carried out again being once coated with macromolecule GMS antistatic coating, it is direct using 200 mesh anilox rolls
By in the recessed painting printing to polyester film surface of coating solution, the raw material of macromolecule GMS antistatic coating is monostearin, is gathered sweet
Oily -2 three isostearates, silicone, acrylic acid, mass ratio 2-4:1-2:80:4-6.
Priority Applications (1)
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CN201910437626.1A CN110211483B (en) | 2019-05-24 | 2019-05-24 | Printable surface adhesive double-anti-static label material and preparation method thereof |
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CN201910437626.1A CN110211483B (en) | 2019-05-24 | 2019-05-24 | Printable surface adhesive double-anti-static label material and preparation method thereof |
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CN110211483A true CN110211483A (en) | 2019-09-06 |
CN110211483B CN110211483B (en) | 2021-05-28 |
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