CN110204992A - A kind of primary coat of Laser Jet and composite coating - Google Patents
A kind of primary coat of Laser Jet and composite coating Download PDFInfo
- Publication number
- CN110204992A CN110204992A CN201910425472.4A CN201910425472A CN110204992A CN 110204992 A CN110204992 A CN 110204992A CN 201910425472 A CN201910425472 A CN 201910425472A CN 110204992 A CN110204992 A CN 110204992A
- Authority
- CN
- China
- Prior art keywords
- mass parts
- primary coat
- laser jet
- coating
- coat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Invention is related to coatings for tin plate printing field, and in particular to the primary coat and composite coating, the primary coat of a kind of Laser Jet include the matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5 ~ 15 mass parts；The adhesion promoter of 1~5 mass parts；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；The tripoli of 1 ~ 10 mass parts；The addition that the present invention passes through tripoli, promote the scratch resistant and heat-resisting quantity of primary coat, the primary coat of Laser Jet is obtained by the chemical compounding of matrix resin, crosslinking agent, solvent, adhesion promoter, catalyst, defoaming agent and tripoli, so that entire primary coat will not be punctured in Laser Jet, guarantee that packing jar ground is not exposed, rust will not be played after cooking sterilization or long-term placement, guarantee that stamp mark is long-term clear, discrimination is high, greatly improves application of the planar bar code technology on packing jar.
Description
Technical field
The present invention relates to the technical fields of coatings for tin plate printing, and in particular to a kind of primary coat of Laser Jet and composite coating.
Background technique
It is conventional process that Laser Jet, which makes a check mark, on the packing jars such as can, beverage can, and with Internet technology
Progress, scans the two-dimensional code the information and identity to identify product, more and more common, therefore, two dimensional code is introduced into food, beverage
And on the packing jar of other common consumer products.
Currently, the two dimensional code on packing jar is largely made by way of Laser Jet, on packing jar generally at least
Layer of transparent protective coating, laser, which directly burns coating, gets two dimensional code；Due to coating transparent, compared colour difference is unobvious, and applies
For layer because breakdown has destruction, long-term exposed ground can play rust, easily cause two dimensional code mark unintelligible, discrimination is low.Therefore, producer's meeting
On packing jar after first printing ink layer, then upper layer of transparent protective layer, with the stamp on ink layer, to solve compared colour difference
Unconspicuous problem.But when Laser Jet, laser power control difference equally will appear the problem of puncturing ink layer, especially
It is that after food cans are placed by sterilization process or for a long time, will appear the defects of ground plays rust, two dimensional code is unintelligible.
Summary of the invention
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, one object of the present invention
It is to provide a kind of primary coat of Laser Jet.The primary coat can solve Laser Jet burn coating, cause two dimensional code it is unintelligible, know
The not low problem of rate, while the primary coat has excellent scratch resistance, machinability and cooking, especially marresistance obvious
Better than the scheme of not primary coat, to greatly promote application of the planar bar code technology on the packing jars such as food cans.
The second object of the present invention is to provide a kind of composite coating of Laser Jet.
In view of this, in one aspect of the invention, the invention proposes a kind of primary coats of Laser Jet comprising:
The matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5~15 mass parts；The attachment of 1~5 mass parts
Power promotor；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；The tripoli of 1~10 mass parts.
Pass through the chemistry of matrix resin, crosslinking agent, solvent, adhesion promoter, catalyst, defoaming agent and tripoli as a result,
Compounding obtains the primary coat of Laser Jet, wherein and matrix resin is main film forming substance, and crosslinking agent is subsidiary film forming matter, two
Person's cross-linking reaction is formed by curing coating, and catalyst then promotes crosslinking curing degree, increases coating hardness and boiling resistance, adhesive force
Promotor promotes ply adhesion of the coating to the adhesive force and ink layer of ground, and tripoli can promote the scoring resistance energy of coating
Guarantee that packing jar ground is not exposed so that entire primary coat will not be punctured in Laser Jet with temperature tolerance, cook sterilization or length
Phase will not play rust after placing, and guarantee that stamp mark is long-term clear, discrimination is high, greatly improves planar bar code technology on packing jar
Using.
In addition, the primary coat of the Laser Jet proposed according to that above embodiment of the present invention, can also have following additional
Technical characteristic:
According to an embodiment of the invention, the matrix resin is the epoxy resin of linear high molecular weight.
According to an embodiment of the invention, the epoxide equivalent of the epoxy resin is 1000~4000g/eq, the asphalt mixtures modified by epoxy resin
The softening point of rouge is greater than 100 DEG C.
According to an embodiment of the invention, the crosslinking agent is selected from benzene for amino resins, ureaformaldehyde amino resins, color inhibition isocyanide
At least one of acid esters.
According to an embodiment of the invention, the solvent be selected from 100# solvent naphtha, 150# solvent naphtha, dibasic acid ester mixture,
Ethylene glycol monobutyl ether, n-butanol, isophorone, several mixtures in ethylene glycol ether acetate.
According to an embodiment of the invention, the adhesion promoter is in epoxy phosphate ester or low-molecular-weight epoxy resin
One kind.
According to an embodiment of the invention, the tripoli is lithium aluminium silicate powder.
According to an embodiment of the invention, the catalyst is selected from organotin catalysts or acid catalyst.
According to an embodiment of the invention, the defoaming agent is selected from one of esters of acrylic acid or organosiloxane class.
In another aspect of the invention, the invention proposes a kind of composite coatings of Laser Jet comprising is suitable for
Priming coat of the roller coating on packing jar ground, roller coating on the priming coat ink layer and roller coating on the ink layer
Light oil reservoir；The priming coat uses the primary coat of above-mentioned Laser Jet.
Specific embodiment
The embodiment of the present invention is described below in detail.The embodiments described below is exemplary, and is only used for explaining this hair
It is bright, and be not considered as limiting the invention.Particular technique or condition are not specified in embodiment, according to text in the art
It offers described technology or conditions or is carried out according to product description.Reagents or instruments used without specified manufacturer,
For can be with conventional products that are commercially available.
In one aspect of the invention, the invention proposes a kind of primary coats of Laser Jet.Implementation according to the present invention
Example, the primary coat includes: the matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5~15 mass parts；1
The adhesion promoter of~5 mass parts；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；1~10
The tripoli of mass parts, 100 parts of each raw material component mass parts summation.As a result, by the addition of tripoli, promoted the scratch resistant of primary coat with
Heat-resisting quantity passes through the chemical compounding of matrix resin, crosslinking agent, solvent, adhesion promoter, catalyst, defoaming agent and tripoli
The primary coat of Laser Jet is obtained, so that entire primary coat will not be punctured in Laser Jet, guarantees that packing jar ground is not exposed,
Rust will not be played after cooking sterilization or long-term placement, guarantees that stamp mark is long-term clear, discrimination is high, greatly improves planar bar code technology
Application on packing jar.
According to an embodiment of the invention, in order to improve the flexibility of primary coat；Matrix resin is the epoxy of linear high molecular weight
Resin.Linearly refer to the molecule catenation of epoxy resin without branching.Specifically, the epoxide equivalent of epoxy resin be 1000~
The softening point of 4000g/eq, epoxy resin are greater than 100 DEG C.Because being applied in packing jar, the repeatedly baking of outer painting needs, using linear
The epoxy resin of high molecular weight can solve coating after repeatedly toasting, and flexibility decline, attachment is deteriorated, and lead to seaming, sterilization
Fall the problem of painting in process, thereby it is ensured that the adhesion and flexibility of primary coat.
According to an embodiment of the invention, crosslinking agent is selected from benzene for amino resins, ureaformaldehyde amino resins, color inhibition isocyanates
At least one of.For crosslinking agent using benzene for amino resins, film flexibility, adhesive force are good, can solve after coating repeatedly toasts
Adhesive force declines problem, and smooth degree is high, can reduce coating surface coefficient of friction, reduces scratch；Crosslinking agent uses ureaformaldehyde amino
Resin, coating adhesion is good, and hardness is high, and cooking is good, can reduce scratch resistance；Crosslinking agent uses color inhibition isocyanates, coating
Lustrous surface is good, and cooking is good.Thus, it is possible to flexible choice crosslinking agent appropriate according to actual needs, Lai Tigao primary coat it is attached
The performances such as property, cooking.
According to an embodiment of the invention, in order to improve the planarization of primed surface, improve glossiness and viscosity stability；It is molten
Agent is selected from 100# solvent naphtha, 150# solvent naphtha, dibasic acid ester mixture, ethylene glycol monobutyl ether, n-butanol, isophorone, second two
Several mixtures in alcohol ethyl ether acetate ester.Wherein, can volatilize gradient according to solvent, in conjunction with practical baking-curing technique, height
Boiling point solvent collocation mixing；Low boiling point solvent can faster volatilize surface drying as a result, and the high boiling solvents such as dibasic acid ester mixture can
Stream bottle of the coating in baking process is improved, guarantees the planarization of coating surface, improves glossiness, ethylene glycol monobutyl ether can reduce
Coating surface tension, improves the wetability of coating, and coating viscosity stability can be improved in n-butanol.
According to an embodiment of the invention, to further increase the adhesive force or flexibility of primary coat；Adhesion promoter is selected from
One of epoxy phosphate ester or low-molecular-weight epoxy resin.Epoxy-resin systems can be improved by epoxy phosphate ester as a result,
Primary coat can promote the flexibility of coating to the adhesive force of ground and ink, small-molecular-weight epoxy resin.
According to an embodiment of the invention, to improve adhesion strength, high temperature resistance and the machinability of primary coat；It is described
Tripoli is lithium aluminium silicate powder.Specifically, tripoli is flaky silicic acid aluminium potassium, white powder of the fineness less than 10 microns；As a result,
Tripoli is added in primary coat can promote the adhesion strength and machinability of coating, can also promote the heat-resisting quantity of coating
Energy.
According to an embodiment of the invention, catalyst is selected from organotin catalysts or acid catalyst.Specifically, organotin is urged
Agent can be that dibutyl tin or stannous octoate can be improved the crosslink density of coating, promoted and steamed for being catalyzed isocyanate crosslinking
Performance is boiled, while improving coating gloss, acid catalyst is benzene sulfonic acid type or naphthalene sulfonic acids type, it is crosslinked for catalytic amino resin,
Crosslink density is improved, wear-resisting, reduction scratch is promoted.Thus, it is possible to flexible choice catalyst appropriate according to actual needs, to mention
The performances such as the wearability or cooking of high primary coat.
According to an embodiment of the invention, the defoaming agent is selected from one of esters of acrylic acid or organosiloxane class.By
This, by esters of acrylic acid or the defoaming agent of organosiloxane class, defoaming effect is good, does not cause coating surface abnormal, does not migrate.
In another aspect of the invention, the invention proposes a kind of composite coatings of Laser Jet comprising is suitable for
The priming coat being coated on packing jar ground, the ink layer being coated on the priming coat and is coated on the ink layer
Light oil reservoir；The priming coat uses the primary coat of above-mentioned Laser Jet.
Wherein, ink material well known in the art can be used in ink layer；Gloss oil material well known in the art can be used in light oil reservoir
Matter；Gloss oil as following formula: the matrix resin of 70~85 mass parts can also be used；The crosslinking agent of 5~15 mass parts, 5~15 matter
Measure the solvent of part；0.05~0.50 part of catalyst；The wax assistant of 1~5 mass parts；The defoaming agent of 0.05~1 mass parts, each original
Expect 100 parts of constituent mass part summation.So that the cooking of gloss oil is good, wear-resisting excellent, Laser Jet is further prevented to burn coating,
Lead to the problem that two dimensional code is unintelligible, discrimination is low, it is scratch resistance compared to the mechanical resistant of current single-layer and transparent protective coating have it is bright
Aobvious promotion can greatly reduce the scratch of system lid.
According to an embodiment of the invention, packing jar ground can be three-piece can cover, cover material can be plating ferrochrome, horse
Mouth iron or aluminium；Priming coat of the invention all has good adhesion, and ink layer on plating ferrochrome, tinplate or aluminium
Good it can adhere to printing on priming coat.
According to an embodiment of the invention, the matrix resin in the gloss oil can be the epoxy resin of linear high molecular weight, ring
The epoxide equivalent of oxygen resin is greater than 100 DEG C in 1000~4000g/eq, softening point.Linear high molecular weight epoxy resin is selected, is applied
Repeatedly baking flexibility is excellent for layer, and machinability is good, the resin for selecting softening point high, and coating hardness is high, and excellent wear resistance can subtract
Lid process crimping scratch processed less.
According to an embodiment of the invention, the crosslinking agent in the gloss oil can be selected from benzene for amino resins, ureaformaldehyde amino resins,
At least one of color inhibition isocyanates.For crosslinking agent using benzene for amino resins, film flexibility, adhesive force are good, can solve
Adhesive force declines problem after coating repeatedly toasts, and smooth degree is high, can reduce coating surface coefficient of friction, reduces scratch；Crosslinking
Agent uses ureaformaldehyde amino resins, and coating adhesion is good, and hardness is high, and cooking is good, can reduce scratch resistance；Crosslinking agent uses color inhibition
Isocyanates, coating surface good luster, cooking are good.Thus, it is possible to which flexible choice crosslinking agent appropriate according to actual needs, comes
Improve the performances such as adhesion, the cooking of gloss oil.Solvent in the gloss oil can be selected from 100# solvent naphtha, 150# solvent naphtha, two
First acid ester mixtures, ethylene glycol monobutyl ether, n-butanol, isophorone, several mixtures in ethylene glycol ether acetate.Its
In, can volatilize gradient according to solvent, in conjunction with practical baking-curing technique, high low boiling point solvent collocation mixing；Low boiling point is molten as a result,
Agent can faster volatilize surface drying, and stream bottle of the coating in baking process can be improved in the high boiling solvents such as dibasic acid ester mixture, protect
The planarization of coating surface is demonstrate,proved, glossiness is improved, ethylene glycol monobutyl ether can drop light oil reservoir surface tension, improve the wetting of coating
Property, coating viscosity stability can be improved in n-butanol.Catalyst in the gloss oil is selected from organotin catalysts or acid catalyst.Tool
For body, coating can be can be improved for being catalyzed isocyanate crosslinking for dibutyl tin or stannous octoate in organotin catalysts
Crosslink density promotes cooking characteristic, while improving coating gloss, and acid catalyst is benzene sulfonic acid type or naphthalene sulfonic acids type, for urging
Change amino resin crosslinked, raising crosslink density, promotes wear-resisting, reduction scratch.Thus, it is possible to which flexible choice is suitable according to actual needs
When catalyst, the performances such as wearability or cooking of Lai Tigao gloss oil.Defoaming agent in the gloss oil can be selected from acrylate
One of class or organosiloxane class.Pass through esters of acrylic acid or the defoaming agent of organosiloxane class, defoaming effect as a result,
It is good, it does not cause coating surface abnormal, does not migrate.Candle agent in the gloss oil can be selected from spherical polytetrafluoroethylmodified modified polyethylene
Wax selects spherical wax, and softening point is high, and deformation is small under high temperature, and smooth degree is excellent, and it is wear-resisting can be obviously improved coating.
As a result, in Laser Jet, priming coat first on cover, after drying, ink layer is printed on priming coat, dry
Glazing oil reservoir again after dry, so that can not puncture the priming coat of the bottom under Laser Jet controlled power, so that food cans boiling
Non-rusting after sterilization or long-term placement, stamp mark is clear, and discrimination is high.
Below with reference to embodiment, the present invention is further explained:
Embodiment 1
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 2000 preparation of primary coat raw material: are weighed；Ureaformaldehyde
5 mass parts of amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；2 mass parts of epoxy phosphate ester；
Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 mass parts of acrylate defoaming agent.It is first that epoxy resin, ureaformaldehyde amino resins, 150# is molten
Agent oil and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, epoxy phosphate ester, ten hexichol sulphurs are continuously added
Acid and acrylate defoaming agent, continue to be dispersed with stirring 15~30min, primary coat raw material are made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Spherical shape is poly-
Tetrafluoroethene modified polyethylene wax (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 matter of organic silicon defoamer
Measure part.Epoxy resin, benzene are mixed for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and dibasic acid ester mixture first, stirred
Mix dispersion 15min；After being dispersed with stirring, spherical polytetrafluoroethylmodified modified polyethylene wax (polytetrafluoroethylmodified modified poly- second is continuously added
Alkene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil raw material be made,
It is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 2
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 77 mass parts of epoxide equivalent 1700；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture, 4 mass parts of ethylene glycol monobutyl ether；Ring
2 mass parts of oxygen phosphate；Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 mass parts of acrylate defoaming agent.First by epoxy resin, ureaformaldehyde
Amino resins, 150# solvent naphtha, dibasic acid ester mixture and ethylene glycol monobutyl ether mixing, are dispersed with stirring 15min；It is dispersed with stirring
Afterwards, epoxy phosphate ester, ten diphenyl sulfonic acid and acrylate defoaming agent are continuously added, continues to be dispersed with stirring 15~30min, bottom is made
Raw material is applied, it is spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Ball
The polytetrafluoroethylmodified modified polyethylene wax of shape (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；Organic silicon defoamer
0.3 mass parts.First epoxy resin, benzene are mixed for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and dibasic acid ester mixture
It closes, is dispersed with stirring 15min；After being dispersed with stirring, it is (polytetrafluoroethylmodified modified to continuously add spherical polytetrafluoroethylmodified modified polyethylene wax
Polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil original be made
Material, it is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 3
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 4 mass parts of dibasic acid ester mixture；6 mass parts of lithium aluminium silicate powder；Ten
0.2 mass parts of diphenyl sulfonic acid；0.3 mass parts of acrylate defoaming agent.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent
Oil, dibasic acid ester mixture and the mixing of lithium aluminium silicate powder, are dispersed with stirring 15min；After being dispersed with stirring, ten hexichol sulphurs are continuously added
Acid and acrylate defoaming agent, continue to be dispersed with stirring 15~30min, primary coat raw material are made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 75 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 7 mass parts of ureaformaldehyde amino；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture, n-butanol 2
Mass parts；2 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid, 0.2 mass parts；It is organic
0.3 mass parts of silicon defoaming agent, in total 100 mass parts.It is first that epoxy resin, benzene is molten for amino resins, ureaformaldehyde amino resins, 150#
Agent oil, dibasic acid ester mixture and n-butanol mixing, are dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoroethyl-ne is continuously added
Alkene modified polyethylene wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, after
It is continuous to be dispersed with stirring 15~30min, gloss oil raw material is made, it is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 4
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
4 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture, 2 mass parts of ethylene glycol monobutyl ether；Ring
1 mass parts of oxygen phosphate, 3 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 mass of acrylate defoaming agent
Part.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, ethylene glycol monobutyl ether and lithium aluminium silicate
Powder mixing, is dispersed with stirring 15min；After being dispersed with stirring, epoxy phosphate ester, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Spherical shape is poly-
Tetrafluoroethene modified polyethylene wax (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 matter of organic silicon defoamer
Part is measured, in total 100 mass parts.First by epoxy resin, benzene for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and binary acid
Ester admixture mixing, is dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoroethylmodified modified polyethylene wax (poly- four is continuously added
Fluoride modified polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min,
Gloss oil raw material is made, it is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 5
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture；Low point of epoxide equivalent 300~600
Son amount 7 mass parts of epoxy resin, 6 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；Acrylate defoaming agent 0.3
Mass parts.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, low-molecular-weight epoxy resin,
It is mixed with lithium aluminium silicate powder, is dispersed with stirring 15min；After being dispersed with stirring, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Ball
The polytetrafluoroethylmodified modified polyethylene wax of shape (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；Organic silicon defoamer
0.3 mass parts.First epoxy resin, benzene are mixed for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and dibasic acid ester mixture
It closes, is dispersed with stirring 15min；After being dispersed with stirring, it is (polytetrafluoroethylmodified modified to continuously add spherical polytetrafluoroethylmodified modified polyethylene wax
Polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil original be made
Material, it is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 6
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；2 mass parts of epoxy phosphate ester；12
0.2 mass parts of benzene sulfonic acid；0.3 mass parts of acrylate defoaming agent.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha
It is mixed with dibasic acid ester mixture, is dispersed with stirring 15min；After being dispersed with stirring, continuously add epoxy phosphate ester, ten diphenyl sulfonic acid and
Acrylate defoaming agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Color inhibition is different
3 mass parts of cyanate, 6 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；
2 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid, 0.1 mass parts, dibutyl tin
0.1 mass parts of cinnamic acid tin；0.3 mass parts of organic silicon defoamer.First by epoxy resin, color inhibition isocyanates, ureaformaldehyde amino tree
Rouge, 150# solvent naphtha and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoro is continuously added
Ethylene modified polyethylene wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), dibutyl tin dilaurate, ten hexichol sulphurs
Acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil raw material are made, spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Comparative example 1
The packing jar ground of this comparative example is three-piece can cover, and the material of cover is chromium plating iron plate.
One, after being patterned on chromium plating iron plate material with ink roller, be placed at 140~160 DEG C and toast 10~15 minutes, with
Ink layer is formed on sheet material.
Two, on ink layer after the commercially available clean oil raw material of roller coating, is toasted 10~15 minutes at 190~210 DEG C, make to apply
Layer thickness of dry film is 6~10g/m2, to form transparent oil reservoir on ink layer, so that being formed on three-piece can cover has ink
The composite coating of layer and transparent oil reservoir.
The test result of the composite coating of each embodiment and comparative example preparation is referring to following table table 1.
Table 1
To sum up, the primary coat of Laser Jet of the present invention and its composite coating, be used for Laser Jet, two dimensional code after sterilization,
After impregnating copper-bath, no any rust, two dimensional code is clear, recognizable, and the solution prior art, which has had rust, leads to two dimensional code
Unsharp problem.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
It is interpreted as that identical embodiment or example must be directed to.Moreover, particular features, structures, materials, or characteristics described
It can be combined in any suitable manner in any one or more of the embodiments or examples.In addition, those skilled in the art can
Different embodiments or examples described in this specification are engaged and be combined.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is not considered as limiting the invention, those skilled in the art within the scope of the invention can be to above-mentioned
Embodiment is changed, modifies, replacement and variant.
Claims (10)
1. a kind of primary coat of Laser Jet characterized by comprising
The matrix resin of 75~85 mass parts；
The crosslinking agent of 2~8 mass parts；
The solvent of 5 ~ 15 mass parts；
The adhesion promoter of 1~5 mass parts；
The catalyst of 0.05~0.50 mass parts；
The defoaming agent of 0.05~1 mass parts；
The tripoli of 1 ~ 10 mass parts.
2. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the matrix resin is linear high molecular weight
Epoxy resin.
3. the primary coat of Laser Jet as claimed in claim 2, it is characterised in that: the epoxide equivalent of the epoxy resin is
The softening point of 1000 ~ 4000g/eq, the epoxy resin are greater than 100 DEG C.
4. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the crosslinking agent is selected from benzene for amino tree
At least one of rouge, ureaformaldehyde amino resins, color inhibition isocyanates.
5. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the solvent be selected from 100# solvent naphtha,
It is 150# solvent naphtha, dibasic acid ester mixture, ethylene glycol monobutyl ether, n-butanol, isophorone, several in ethylene glycol ether acetate
Kind mixture.
6. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the adhesion promoter is selected from epoxy phosphorus
One of acid esters or low-molecular-weight epoxy resin.
7. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the tripoli is lithium aluminium silicate powder.
8. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the catalyst is selected from organotin catalysts
Or acid catalyst.
9. the primary coat of Laser Jet as described in claim 1, it is characterised in that: the defoaming agent be selected from esters of acrylic acid or
One of organosiloxane class.
10. a kind of composite coating of Laser Jet, it is characterised in that: including being suitable for primary coat of the roller coating on packing jar ground
Layer, roller coating is in the light oil reservoir of ink layer and roller coating on the ink layer on the priming coat；The priming coat is using such as
The primary coat of Laser Jet described in any one of claims 1 to 9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910425472.4A CN110204992A (en) | 2019-05-21 | 2019-05-21 | A kind of primary coat of Laser Jet and composite coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910425472.4A CN110204992A (en) | 2019-05-21 | 2019-05-21 | A kind of primary coat of Laser Jet and composite coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110204992A true CN110204992A (en) | 2019-09-06 |
Family
ID=67788032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910425472.4A Pending CN110204992A (en) | 2019-05-21 | 2019-05-21 | A kind of primary coat of Laser Jet and composite coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110204992A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111098036A (en) * | 2019-12-31 | 2020-05-05 | 北京赛腾标识系统股份公司 | Code assigning method and system |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449242A (en) * | 2014-12-25 | 2015-03-25 | 佛山市儒林化工有限公司 | Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability |
| CN204990354U (en) * | 2015-09-17 | 2016-01-20 | 佛山市儒林化工有限公司 | UV printing exempt from glazing two -dimensional code printing ink coating |
| JP2017075222A (en) * | 2015-10-14 | 2017-04-20 | Ｄｉｃグラフィックス株式会社 | Uv-curable offset ink composition for laser marking |
-
2019
- 2019-05-21 CN CN201910425472.4A patent/CN110204992A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449242A (en) * | 2014-12-25 | 2015-03-25 | 佛山市儒林化工有限公司 | Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability |
| CN204990354U (en) * | 2015-09-17 | 2016-01-20 | 佛山市儒林化工有限公司 | UV printing exempt from glazing two -dimensional code printing ink coating |
| JP2017075222A (en) * | 2015-10-14 | 2017-04-20 | Ｄｉｃグラフィックス株式会社 | Uv-curable offset ink composition for laser marking |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111098036A (en) * | 2019-12-31 | 2020-05-05 | 北京赛腾标识系统股份公司 | Code assigning method and system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101695689B (en) | Coating method for wind generating blade, used base paint and preparation method for base paint | |
| CN106752829B (en) | Corium non-ionic water polyurethane finishing agent and preparation method | |
| CN104540744A (en) | Container coating system | |
| CN106700844B (en) | A kind of preparation of weather-proof heatproof corrosion-inhibiting coating | |
| US6034225A (en) | Organopolysiloxanes having aliphatically unsaturated radicals, the preparation thereof and the use thereof in crosslinkable materials | |
| CN110183930A (en) | A kind of gloss oil and composite coating of Laser Jet | |
| CN104449242B (en) | It is a kind of to exempt from primary coat, the built-up tin gloss oil with good adhesive force and excellent machining property | |
| JPS5984953A (en) | Peeling power-controlled solvent-free silicone peeling composition | |
| CN110003763A (en) | Bi-component aqueous epoxy lacquer type organic coating | |
| CN110204992A (en) | A kind of primary coat of Laser Jet and composite coating | |
| CN105874021A (en) | Culinary utensil provided with a hybrid coating and process for producing such a utensil | |
| CN110982382A (en) | High-corrosion-resistance coating and preparation process thereof | |
| EP0953004A1 (en) | Polymeric organosilicon compounds, their production and use | |
| CN103980804A (en) | Method for forming dual-layer coating | |
| CN108641515A (en) | High-adhesion primer coating | |
| CN101798378A (en) | Transparent epoxy resin curing agent | |
| Minisini et al. | Influence of the chemical composition and formulation of fluorinated epoxy resin on its surface characteristics | |
| RU2401823C2 (en) | Method and composition of hardening coated or decorated ceramic substrates | |
| KR100332702B1 (en) | New coating material based on urushiol and curing method | |
| CN107652943A (en) | A kind of ultraviolet resistance high-low temperature resistant organosilicon adhesive and preparation method thereof | |
| CN1077458C (en) | Method for forming paint coating | |
| RU2378230C2 (en) | Method and compositions for depositing on glass and ceramic substrates | |
| CN104169324A (en) | Packaging paint composition | |
| CN106280991B (en) | A kind of organosilicon suitable for ship underwater connects coating and preparation method thereof | |
| CN110330878A (en) | Deep-draw coating for canned luncheon meat inner wall formula, preparation and the technique for applying that height stretches |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190906 |