CN104449242A - Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability - Google Patents
Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability Download PDFInfo
- Publication number
- CN104449242A CN104449242A CN201410818605.1A CN201410818605A CN104449242A CN 104449242 A CN104449242 A CN 104449242A CN 201410818605 A CN201410818605 A CN 201410818605A CN 104449242 A CN104449242 A CN 104449242A
- Authority
- CN
- China
- Prior art keywords
- gloss oil
- primary coat
- piece
- sticking power
- exempting
- Prior art date
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- Granted
Links
- 239000000853 adhesive Substances 0.000 title abstract description 5
- 230000001070 adhesive effect Effects 0.000 title abstract description 5
- 229920003180 amino resin Polymers 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
- 238000003754 machining Methods 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 8
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims description 8
- 239000012948 isocyanate Substances 0.000 claims description 7
- 150000002513 isocyanates Chemical class 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000003377 acid catalyst Substances 0.000 claims description 3
- 230000029936 alkylation Effects 0.000 claims description 3
- 238000005804 alkylation reaction Methods 0.000 claims description 3
- 239000003849 aromatic solvent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 10
- 239000003973 paint Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 3
- 239000007888 film coating Substances 0.000 abstract description 3
- 238000009501 film coating Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 125000003700 epoxy group Chemical group 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000005028 tinplate Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010023 transfer printing Methods 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000012257 stirred material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability. The sanitary can gloss oil is characterized by being prepared from the following components in percentage by weight: 65-70% of main resin, 14-15% of amino resin, 10-15% of a solvent, 4-6% of ceratum, 0.14-0.16% of a defoaming agent, 0.14-0.16% of a leveling agent and 0.07-0.08% of a catalyst. Compared with the prior art, by adopting the primary-coat-free sanitary can gloss oil disclosed by the invention, the problems about film coating adhesive force and processability can be solved, and the can manufacturing achieves a same effect as that of a primary-coat paint film coating; the use of a primary coat is avoided, the use cost is reduced, the process of coating the primary coat is reduced, energy resources are saved, and the efficiency is improved.
Description
Technical field
The present invention relates to technical field of coatings, especially relate to a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property.
Background technology
The printing in current coatings for tin plate printing field is all generally primary coat, ink, gloss oil three layers, primary coat refers to Bai Keding or end oil, generally, and coatings for tin plate printing bottoming, main effect is exactly the sticking power had between primary coat and tinplate, and the ply adhesion also had between ink, so after Lacquer finish, the sticking power of whole film and processibility all can be relatively good.But along with the trend requirement that Sustainable development requirement and the client of economy reduce costs, the cry exempting to be coated with primary coat is also more and more higher, exempts primary coat and not only can reduce coating use cost, can also reduce by a procedure, energy efficient simultaneously.Existing Three piece Can gloss oil, if remove primary coat, is directly coated with ink back cover light, and not good, the processed tank of sticking power that will be faced with film easily abrades and the problem such as the quick-fried paint of sterilization.Therefore, new requirement is proposed to the performance of the ink and gloss oil of exempting from bottoming coating.Especially the sticking power of gloss oil and processing characteristics are had higher requirement.
Summary of the invention
In order to solve above-mentioned prior art, the invention provides a kind of solve film adhesive and processability problems exempt from primary coat Three piece Can gloss oil.
The present invention realizes above-mentioned purpose by once technical scheme: a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property, it is characterized in that: be prepared from by weight percentage by following ingredients: main resin 65-70%, aminoresin 14-15%, solvent 10-15%, cerate 4-6%, defoamer 0.14-0.16%, flow agent 0.14-0.16%, catalyzer 0.07-0.08%.
Described main resin is modified epoxy, it is main film forming substance, containing active epoxide group in the molecular chain of epoxy resin, epoxide group can be positioned at the end of molecular chain, centre or structure circlewise, they can with polytype solidifying agent generation crosslinking reaction and formed and insoluble, molten not there is the cancellated superpolymer of three-dimensional, owing to there being the existence of polar hydroxyl groups and ehter bond in epoxy molecule chain, it is made to have excellent cohesive strength to metal or other materials surface, hardness is high, snappiness is good, and chemical stability is good.
Described aminoresin is auxiliary film forming matter, aminoresin is mixed for aminoresin resin three by masked isocyanate, urea-formaldehyde resin, benzene, wherein, masked isocyanate has excellent snappiness and curing performance, thus the processibility of assisted Extraction high product and bactericidal property; Containing polar oxygen atom on Structure of UF resin, can improve the bonding force between finish paint, flexibility is better, thus the sticking power of assisted Extraction high product; Benzene is good for the compatibility of aminoresin and various resin, and the chemical resistances such as water-fast salt spray resistance are excellent, and the good transfer printing of snappiness is good, and deep drawability is good, thus the endurance of assisted Extraction high product, suppleness and processibility; Therefore, gloss oil is made to have excellent processing characteristics by masked isocyanate, urea-formaldehyde resin, benzene for the aminoresin that aminoresin three mixes.
Described solvent is aromatic solvent.
Described cerate is polytetrafluoroethylmodified modified polyethylene wax.
Described defoamer is broken the defoamer steeping polymkeric substance and polysiloxane composition.
Described flow agent is organosilyl surface auxiliary agent.
Described catalyzer is dead front type, low polarity, Long carbon chain alkylation sulfonic acid catalyst, has excellent viscosity stability and solvency power, can make lacquer film fast curing when reducing storing temperature.
Beneficial effect of the present invention is: the present invention is compared to prior art, and have excellent cohesive strength, suppleness and processed-type, can solve and exempt from primary coat film adhesive and processability problems, tank processed reaches the effect same with there being the paint film coating of primary coat; Exempt the use of coating primary coat, decrease the operation of coating primary coat, saved the energy, reduce production cost, enhance productivity.
Embodiment
Below by specific embodiment, the present invention is described in detail.
A kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property, comprise component and weight percent is as follows: modified epoxy 65-70%, aminoresin 14-15%, solvent 10-15%, cerate 4-6%, defoamer 0.14-0.16%, flow agent 0.14-0.16%, catalyzer 0.07-0.08%.
Described modified epoxy is main film forming substance, containing active epoxide group in the molecular chain of epoxy resin, epoxide group can be positioned at the end of molecular chain, centre or structure circlewise, they can with polytype solidifying agent generation crosslinking reaction and formed and insoluble, molten not there is the cancellated superpolymer of three-dimensional, owing to there being the existence of polar hydroxyl groups and ehter bond in epoxy molecule chain, it is made to have excellent cohesive strength to metal and other material surfaces, hardness is high, snappiness is good, and chemical stability is good.
Described aminoresin is auxiliary film forming matter, aminoresin is mixed for aminoresin resin three by masked isocyanate, urea-formaldehyde resin, benzene, wherein, masked isocyanate has excellent snappiness and curing performance, thus the processibility of assisted Extraction high product and bactericidal property; Containing polar oxygen atom on Structure of UF resin, can improve the bonding force between finish paint, flexibility is better, thus the sticking power of assisted Extraction high product; Benzene is good for the compatibility of aminoresin and various resin, and the chemical resistances such as water-fast salt spray resistance are excellent, and the good transfer printing of snappiness is good, and deep drawability is good, thus the endurance of assisted Extraction high product, suppleness and processibility; Therefore, gloss oil is made to have excellent processing characteristics by masked isocyanate, urea-formaldehyde resin, benzene for the aminoresin that aminoresin three mixes.
Described solvent is aromatic solvent, and physical and chemical performance is stablized, and solvency power is strong, particularly can play high solvent feature in the final stage of evaporation, make film good leveling property, smooth and without orange peel, coating film gloss is improved.
Described cerate is the polyethylene wax of classification micronized Teflon modification, there is good smooth degree, scratch resistant performance and wear resisting property in coating system, the frictional coefficient of film coated surface can be reduced largely, improve surface slipperiness, thus abrade risk between reduction tank processed and can body.
Described defoamer is broken bubble polymkeric substance and polysiloxane solution, has excellent defoaming capacity.
Described flow agent is organosilyl surface auxiliary agent, and its primary hydroxyl can react with base-material thus anchor on coating surface, effectively can reduce surface tension, improve ground and soak, thus improve levelling property.
Described catalyzer is dead front type, low polarity, Long carbon chain alkylation sulfonic acid catalyst, has excellent viscosity stability and solvency power, can make lacquer film fast curing when reducing storing temperature.
Preparation method of the present invention comprises the steps:
Step 1, takes each component by weight percentage: modified epoxy 65-70%, aminoresin 14-15%, solvent 10-15%, cerate 4-6%, defoamer 0.14-0.16%, flow agent 0.14-0.16%, catalyzer 0.07-0.08%.
Step 2, adds modified epoxy, aminoresin, solvent in order and feeds intake in cylinder, stir 10 minutes, mix material at the quick shelves of stirrer;
Step 3, under stirring at low speed, cerate, defoamer, flow agent, catalyzer are slowly joined step 2 stirred material in, auxiliary agent and material are before fused sufficiently uniformly;
Step 4, after all materials add, reaches quick shelves stirrer, continues to stir half hour.
The present invention, before gloss oil uses on the machine, according to the difference of the on-the-spot temperature of coating, generally can select corresponding thinner to carry out viscosity adjustment, find suitable upper machine viscosity, and coating paint film out can be more attractive in appearance like this, and paint film property can be more superior.
Claims (8)
1. exempt from the Three piece Can gloss oil of primary coat, the sticking power had and excellent machining property for one kind, it is characterized in that: be prepared from by weight percentage by following ingredients: main resin 65-70%, aminoresin 14-15%, solvent 10-15%, cerate 4-6%, defoamer 0.14-0.16%, flow agent 0.14-0.16%, catalyzer 0.07-0.08%.
2. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described main resin is modified epoxy.
3. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described aminoresin is the aminoresin mixed for aminoresin resin three by masked isocyanate, urea-formaldehyde resin, benzene.
4. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described solvent is aromatic solvent.
5. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described cerate is polytetrafluoroethylmodified modified polyethylene wax.
6. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described defoamer is broken to steep the defoamer of polymkeric substance and polysiloxane composition.
7. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described flow agent is organosilyl surface auxiliary agent.
8. a kind of Three piece Can gloss oil of exempting from primary coat, the sticking power had and excellent machining property according to claim 1, is characterized in that: described catalyzer is dead front type, low polarity, Long carbon chain alkylation sulfonic acid catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410818605.1A CN104449242B (en) | 2014-12-25 | 2014-12-25 | It is a kind of to exempt from primary coat, the built-up tin gloss oil with good adhesive force and excellent machining property |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410818605.1A CN104449242B (en) | 2014-12-25 | 2014-12-25 | It is a kind of to exempt from primary coat, the built-up tin gloss oil with good adhesive force and excellent machining property |
Publications (2)
Publication Number | Publication Date |
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CN104449242A true CN104449242A (en) | 2015-03-25 |
CN104449242B CN104449242B (en) | 2017-04-05 |
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CN201410818605.1A Expired - Fee Related CN104449242B (en) | 2014-12-25 | 2014-12-25 | It is a kind of to exempt from primary coat, the built-up tin gloss oil with good adhesive force and excellent machining property |
Country Status (1)
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CN (1) | CN104449242B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104861802A (en) * | 2015-04-28 | 2015-08-26 | 安徽顺驰电缆有限公司 | Water metal printing finishing paint preparation method |
CN105733418A (en) * | 2016-03-01 | 2016-07-06 | 中山市柏顿涂料有限公司 | High-temperature stewing resistant base coat of three-piece can and preparation method of high-temperature stewing resistant base coat |
CN109627903A (en) * | 2018-10-30 | 2019-04-16 | 连云港泽阳装饰材料有限公司 | A kind of printing iron flask transparent yellow polyester baking vanish |
CN110183930A (en) * | 2019-05-21 | 2019-08-30 | 福建合润包装涂料有限公司 | A kind of gloss oil and composite coating of Laser Jet |
CN110204992A (en) * | 2019-05-21 | 2019-09-06 | 福建合润包装涂料有限公司 | A kind of primary coat of Laser Jet and composite coating |
CN111635682A (en) * | 2020-05-30 | 2020-09-08 | 福建合润包装涂料有限公司 | High-wear-resistance iron-permeable coating suitable for long-distance transportation and preparation method and application thereof |
CN115960488A (en) * | 2022-12-22 | 2023-04-14 | 长飞光纤光缆股份有限公司 | UV-cured and thermosetting dual-curing water transfer printing gold stamping base oil |
CN117777828A (en) * | 2023-12-27 | 2024-03-29 | 广东新威新材料技术有限公司 | Energy-saving and environment-friendly laser coding transparent coating |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104861802A (en) * | 2015-04-28 | 2015-08-26 | 安徽顺驰电缆有限公司 | Water metal printing finishing paint preparation method |
CN105733418A (en) * | 2016-03-01 | 2016-07-06 | 中山市柏顿涂料有限公司 | High-temperature stewing resistant base coat of three-piece can and preparation method of high-temperature stewing resistant base coat |
CN109627903A (en) * | 2018-10-30 | 2019-04-16 | 连云港泽阳装饰材料有限公司 | A kind of printing iron flask transparent yellow polyester baking vanish |
CN110183930A (en) * | 2019-05-21 | 2019-08-30 | 福建合润包装涂料有限公司 | A kind of gloss oil and composite coating of Laser Jet |
CN110204992A (en) * | 2019-05-21 | 2019-09-06 | 福建合润包装涂料有限公司 | A kind of primary coat of Laser Jet and composite coating |
CN111635682A (en) * | 2020-05-30 | 2020-09-08 | 福建合润包装涂料有限公司 | High-wear-resistance iron-permeable coating suitable for long-distance transportation and preparation method and application thereof |
CN115960488A (en) * | 2022-12-22 | 2023-04-14 | 长飞光纤光缆股份有限公司 | UV-cured and thermosetting dual-curing water transfer printing gold stamping base oil |
CN115960488B (en) * | 2022-12-22 | 2023-11-03 | 长飞光纤光缆股份有限公司 | UV (ultraviolet) curing and heat curing dual-curing water transfer printing gold stamping base oil |
CN117777828A (en) * | 2023-12-27 | 2024-03-29 | 广东新威新材料技术有限公司 | Energy-saving and environment-friendly laser coding transparent coating |
CN117777828B (en) * | 2023-12-27 | 2024-05-24 | 广东新威新材料技术有限公司 | Energy-saving and environment-friendly laser coding transparent coating |
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Publication number | Publication date |
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