CN110183930A - A kind of gloss oil and composite coating of Laser Jet - Google Patents
A kind of gloss oil and composite coating of Laser Jet Download PDFInfo
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- CN110183930A CN110183930A CN201910425464.XA CN201910425464A CN110183930A CN 110183930 A CN110183930 A CN 110183930A CN 201910425464 A CN201910425464 A CN 201910425464A CN 110183930 A CN110183930 A CN 110183930A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Abstract
The present invention relates to coatings for tin plate printing fields, and in particular to a kind of gloss oil and composite coating of Laser Jet, the gloss oil include the matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5 ~ 15 mass parts；The wax assistant of 1~5 mass parts；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；Wherein, the matrix resin is epoxy resin；The present invention is used by epoxy-resin systems coating as gloss oil, the cooking and wearability of coating can be improved, the gloss oil of Laser Jet is obtained by the chemical compounding of matrix resin, crosslinking agent, solvent, wax assistant, catalyst, defoaming agent, so that in Laser Jet, varnish coating has excellent machinability, entire composite coating will not be punctured, guarantee that packing jar ground is not exposed, rust will not be played after cooking sterilization or long-term placement, guarantee that stamp mark is long-term clear, discrimination is high, greatly improves application of the planar bar code technology on packing jar.
Description
Technical field
The present invention relates to the technical fields of coatings for tin plate printing, and in particular to a kind of gloss oil and composite coating of Laser Jet.
Background technique
It is conventional process that Laser Jet, which makes a check mark, on the packing jars such as can, beverage can, and with Internet technology
Progress, scans the two-dimensional code the information and identity to identify product, more and more common, therefore, two dimensional code is introduced into food, beverage
And on the packing jar of other common consumer products.
Currently, the two dimensional code on packing jar is largely made by way of Laser Jet, on packing jar generally at least
Layer of transparent protective coating, laser, which directly burns coating, gets two dimensional code；Due to coating transparent, compared colour difference is unobvious, and applies
For layer because breakdown has destruction, long-term exposed ground can play rust, easily cause two dimensional code mark unintelligible, discrimination is low.Therefore, producer's meeting
On packing jar after first printing ink layer, then upper layer of transparent protective layer, with the stamp on ink layer, to solve compared colour difference
Unconspicuous problem.But when Laser Jet, laser power control difference equally will appear the problem of puncturing ink layer, especially
It is that after food cans are placed by sterilization process or for a long time, will appear the defects of ground plays rust, two dimensional code is unintelligible.
Therefore the composite coating of existing Laser Jet has much room for improvement.
Summary of the invention
The present invention is directed at least solve one of the technical problems existing in the prior art.For this purpose, one object of the present invention
It is to provide a kind of gloss oil of Laser Jet.The gloss oil cooking is good, wear-resisting excellent, has excellent adhesive force and machining
Performance, the cover for being applicable to resistance to deep drawing quality requirement apply outside.
The second object of the present invention is to provide a kind of composite coating.
In view of this, in one aspect of the invention, the invention proposes a kind of gloss oil of Laser Jet comprising:
The matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5~15 mass parts；The wax of 1~5 mass parts helps
Agent；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；Wherein, the matrix resin is asphalt mixtures modified by epoxy resin
Rouge.
Laser is obtained by the chemical compounding of matrix resin, crosslinking agent, solvent, wax assistant, catalyst, defoaming agent as a result,
The gloss oil of stamp, wherein matrix resin is main film forming substance, and crosslinking agent is subsidiary film forming matter, and the two cross-linking reaction is solid
Change forms coating, and catalyst then promotes crosslinking curing degree, increases coating hardness and boiling resistance, applied by epoxy-resin systems
Material is used as gloss oil, and the cooking and wearability of coating can be improved, so that varnish coating has excellent in Laser Jet
Machinability will not puncture entire composite coating, guarantee that packing jar ground is not exposed, will not after cooking sterilization or placing for a long time
Rust is played, guarantees that stamp mark is long-term clear, discrimination is high, greatly improves application of the planar bar code technology on packing jar.
In addition, the gloss oil of the Laser Jet proposed according to that above embodiment of the present invention, can also have following additional
Technical characteristic:
According to an embodiment of the invention, the matrix resin is the epoxy resin of linear high molecular weight.
According to an embodiment of the invention, the epoxide equivalent of the epoxy resin is 1000~4000g/eq, the asphalt mixtures modified by epoxy resin
The softening point of rouge is greater than 100 DEG C.
According to an embodiment of the invention, the crosslinking agent is selected from benzene for amino resins, ureaformaldehyde amino resins, color inhibition isocyanide
At least one of acid esters.
According to an embodiment of the invention, the solvent be selected from 100# solvent naphtha, 150# solvent naphtha, dibasic acid ester mixture,
Ethylene glycol monobutyl ether, n-butanol, isophorone, several mixtures in ethylene glycol ether acetate.
According to an embodiment of the invention, the wax assistant is spherical polytetrafluoroethylmodified modified polyethylene wax.
According to an embodiment of the invention, the catalyst is selected from organotin catalysts or acid catalyst.
According to an embodiment of the invention, the defoaming agent is selected from one of esters of acrylic acid or organosiloxane class.
In another aspect of the invention, the invention proposes a kind of composite coatings of Laser Jet comprising is suitable for
Priming coat of the roller coating on packing jar ground, roller coating on the priming coat ink layer and roller coating on the ink layer
Light oil reservoir；The light oil reservoir uses the gloss oil of above-mentioned Laser Jet.
Specific embodiment
The embodiment of the present invention is described below in detail.The embodiments described below is exemplary, and is only used for explaining this hair
It is bright, and be not considered as limiting the invention.Particular technique or condition are not specified in embodiment, according to text in the art
It offers described technology or conditions or is carried out according to product description.Reagents or instruments used without specified manufacturer,
For can be with conventional products that are commercially available.
In one aspect of the invention, the invention proposes a kind of gloss oil of Laser Jet.Implementation according to the present invention
Example, the primary coat includes: the matrix resin of 75~85 mass parts；The crosslinking agent of 2~8 mass parts；The solvent of 5~15 mass parts；1
The wax assistant of~5 mass parts；The catalyst of 0.05~0.50 mass parts；The defoaming agent of 0.05~1 mass parts；Wherein, the master
Body resin is epoxy resin.It is used as gloss oil by epoxy-resin systems coating as a result, the cooking of coating and resistance to can be improved
Mill property, obtains Laser Jet by the chemical compounding of matrix resin, crosslinking agent, solvent, wax assistant, catalyst, defoaming agent
Gloss oil will not puncture entire composite coating so that varnish coating has excellent machinability in Laser Jet, guarantee
Packing jar ground is not exposed, will not play rust after cooking sterilization or long-term placement, guarantees that stamp mark is long-term clear, and discrimination is high,
Greatly improve application of the planar bar code technology on packing jar.
According to an embodiment of the invention, in order to improve the flexibility of gloss oil；Matrix resin is the epoxy of linear high molecular weight
Resin.Linearly refer to the molecule catenation of epoxy resin without branching.Specifically, the epoxide equivalent of epoxy resin be 1000~
The softening point of 4000g/eq, epoxy resin are greater than 100 DEG C.Linear high molecular weight epoxy resin is selected, coating repeatedly toasts flexible
Property it is excellent, machinability is good, selects the high resin of softening point, and coating hardness is high, and excellent wear resistance can reduce lid process crimping processed
Scratch.
According to an embodiment of the invention, crosslinking agent is selected from benzene for amino resins, ureaformaldehyde amino resins, color inhibition isocyanates
At least one of.For crosslinking agent using benzene for amino resins, film flexibility, adhesive force are good, can solve after coating repeatedly toasts
Adhesive force declines problem, and smooth degree is high, can reduce coating surface coefficient of friction, reduces scratch；Crosslinking agent uses ureaformaldehyde amino
Resin, coating adhesion is good, and hardness is high, and cooking is good, can reduce scratch resistance；Crosslinking agent uses color inhibition isocyanates, coating
Lustrous surface is good, and cooking is good.Thus, it is possible to flexible choice crosslinking agent appropriate according to actual needs, Lai Tigao gloss oil it is attached
The performances such as property, cooking.
According to an embodiment of the invention, in order to improve the planarization on gloss oil surface, improve glossiness and viscosity stability；It is molten
Agent is selected from 100# solvent naphtha, 150# solvent naphtha, dibasic acid ester mixture, ethylene glycol monobutyl ether, n-butanol, isophorone, second two
Several mixtures in alcohol ethyl ether acetate ester.Wherein, can volatilize gradient according to solvent, in conjunction with practical baking-curing technique, height
Boiling point solvent collocation mixing；Low boiling point solvent can faster volatilize surface drying as a result, and the high boiling solvents such as dibasic acid ester mixture can
Stream bottle of the coating in baking process is improved, guarantees the planarization of coating surface, improves glossiness, ethylene glycol monobutyl ether can reduce
Coating surface tension, improves the wetability of coating, and coating viscosity stability can be improved in n-butanol.
According to an embodiment of the invention, wax assistant is using smooth degree, the polytetrafluoroethylmodified modified polyethylene of spherical shape of excellent wear resistance
Wax.Spherical wax is selected, softening point is high, and deformation is small under high temperature, and smooth degree is excellent, and it is wear-resisting can be obviously improved coating.
According to an embodiment of the invention, catalyst is selected from organotin catalysts or acid catalyst.Specifically, organotin is urged
Agent can be that dibutyl tin or stannous octoate can be improved the crosslink density of coating, promoted and steamed for being catalyzed isocyanate crosslinking
Performance is boiled, while improving coating gloss, acid catalyst is benzene sulfonic acid type or naphthalene sulfonic acids type, it is crosslinked for catalytic amino resin,
Crosslink density is improved, wear-resisting, reduction scratch is promoted.Thus, it is possible to flexible choice catalyst appropriate according to actual needs, to mention
The performances such as the wearability or cooking of high gloss oil.
According to an embodiment of the invention, the defoaming agent is selected from one of esters of acrylic acid or organosiloxane class.By
This, by esters of acrylic acid or the defoaming agent of organosiloxane class, defoaming effect is good, does not cause coating surface abnormal, does not migrate.
In another aspect of the invention, the invention proposes a kind of composite coatings of Laser Jet comprising is suitable for
The priming coat being coated on packing jar ground, the ink layer being coated on the priming coat and is coated on the ink layer
Light oil reservoir；The light oil reservoir uses the gloss oil of above-mentioned Laser Jet.
Wherein, ink material well known in the art can be used in ink layer；Priming coat can be used primary coat as following formula: 70~
The matrix resin of 85 mass parts；The crosslinking agent of 5~15 mass parts, the solvent of 5~15 mass parts；1~5 mass of adhesion promoter
Part；0.05~0.50 part of catalyst；The defoaming agent of 0.05~1 mass parts；1~10 mass parts of tripoli；Each raw material component quality
100 parts of summation of part.So that the resistance to marring of primary coat and high temperature resistance are good, and it is dedicated suitable for Laser Jet, so that Laser Jet
Entire composite coating will not be punctured, guarantee that packing jar ground is not exposed, rust will not be played after cooking sterilization or long-term placement, guarantee is beaten
Code mark is long-term clear, and discrimination is high, greatly improves application of the planar bar code technology on packing jar.
According to an embodiment of the invention, packing jar ground can be cover, cover material can be plating ferrochrome, tinplate or
Aluminium；Priming coat of the invention all has good adhesion on plating ferrochrome, tinplate or aluminium, and ink layer can be good
Good adheres to printing on priming coat.
According to an embodiment of the invention, the matrix resin in the primary coat can be the epoxy resin of linear high molecular weight, ring
The epoxide equivalent of oxygen resin is greater than 100 DEG C in 1000~4000g/eq, softening point.It applies, the repeatedly baking of outer painting needs, makes in cover
With the epoxy resin of linear high molecular weight, coating can be solved after repeatedly toasting, film flexibility decline, attachment is deteriorated, leads
Fall the problem of painting in cause seaming, sterilization process.
According to an embodiment of the invention, the crosslinking agent in the primary coat can be selected from benzene for amino resins, ureaformaldehyde amino resins,
At least one of color inhibition isocyanates.For crosslinking agent using benzene for amino resins, film flexibility, adhesive force are good, can solve
Adhesive force declines problem after coating repeatedly toasts, and smooth degree is high, can reduce coating surface coefficient of friction, reduces scratch；Crosslinking
Agent uses ureaformaldehyde amino resins, and coating adhesion is good, and hardness is high, and cooking is good, can reduce scratch resistance；Crosslinking agent uses color inhibition
Isocyanates, coating surface good luster, cooking are good.Thus, it is possible to which flexible choice crosslinking agent appropriate according to actual needs, comes
Improve the performances such as adhesion, the cooking of primary coat.Solvent in the primary coat can be selected from 100# solvent naphtha, 150# solvent naphtha, two
First acid ester mixtures, ethylene glycol monobutyl ether, n-butanol, isophorone, several mixtures in ethylene glycol ether acetate.Its
In, can volatilize gradient according to solvent, in conjunction with practical baking-curing technique, high low boiling point solvent collocation mixing；Low boiling point is molten as a result,
Agent can faster volatilize surface drying, and stream bottle of the coating in baking process can be improved in the high boiling solvents such as dibasic acid ester mixture, protect
The planarization of coating surface is demonstrate,proved, glossiness is improved, ethylene glycol monobutyl ether can drop light oil reservoir surface tension, improve the wetting of coating
Property, coating viscosity stability can be improved in n-butanol.Catalyst in the primary coat is selected from organotin catalysts or acid catalyst.Tool
For body, coating can be can be improved for being catalyzed isocyanate crosslinking for dibutyl tin or stannous octoate in organotin catalysts
Crosslink density promotes cooking characteristic, while improving coating gloss, and acid catalyst is benzene sulfonic acid type or naphthalene sulfonic acids type, for urging
Change amino resin crosslinked, raising crosslink density, promotes wear-resisting, reduction scratch.Thus, it is possible to which flexible choice is suitable according to actual needs
When catalyst, the performances such as wearability or cooking of Lai Tigao primary coat.Defoaming agent in the primary coat can be selected from acrylate
One of class or organosiloxane class.Pass through esters of acrylic acid or the defoaming agent of organosiloxane class, defoaming effect as a result,
It is good, it does not cause coating surface abnormal, does not migrate.Adhesion promoter is selected from epoxy phosphate ester or low molecular weight ring in the primary coat
One of oxygen resin.Attachment of the epoxy-resin systems primary coat to ground and ink can be improved by epoxy phosphate ester as a result,
Power, small-molecular-weight epoxy resin can promote the flexibility of coating.For adhesion strength, high temperature resistance and the machine for improving primary coat
Processing performance；Tripoli in the primary coat is lithium aluminium silicate powder.Specifically, tripoli is flaky silicic acid aluminium potassium, fineness is less than
10 microns of white powder；Tripoli is added in primary coat as a result, can promote the adhesion strength and machinability of coating,
The high temperature resistance of coating can be promoted.
As a result, in Laser Jet, priming coat first on cover, after drying, ink layer is printed on priming coat, dry
Glazing oil reservoir again after dry, so that can not puncture the priming coat of the bottom under Laser Jet controlled power, so that food cans boiling
Non-rusting after sterilization or long-term placement, stamp mark is clear, and discrimination is high.
Below with reference to embodiment, the present invention is further explained:
Embodiment 1
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 2000 preparation of primary coat raw material: are weighed；Ureaformaldehyde
5 mass parts of amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；2 mass parts of epoxy phosphate ester；
Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 mass parts of acrylate defoaming agent.It is first that epoxy resin, ureaformaldehyde amino resins, 150# is molten
Agent oil and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, epoxy phosphate ester, ten hexichol sulphurs are continuously added
Acid and acrylate defoaming agent, continue to be dispersed with stirring 15~30min, primary coat raw material are made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Spherical shape is poly-
Tetrafluoroethene modified polyethylene wax (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；0.3 matter of organic silicon defoamer
Measure part.Epoxy resin, benzene are mixed for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and dibasic acid ester mixture first, stirred
Mix dispersion 15min；After being dispersed with stirring, spherical polytetrafluoroethylmodified modified polyethylene wax (polytetrafluoroethylmodified modified poly- second is continuously added
Alkene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil raw material be made,
It is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 2
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture；Low point of epoxide equivalent 300~600
Son amount 7 mass parts of epoxy resin, 6 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；Acrylate defoaming agent 0.3
Mass parts.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, low-molecular-weight epoxy resin,
It is mixed with lithium aluminium silicate powder, is dispersed with stirring 15min；After being dispersed with stirring, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Benzene is for amino
5 mass parts of resin, 3 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；Ball
The polytetrafluoroethylmodified modified polyethylene wax of shape (18% solid content) 2 mass parts；Ten diphenyl sulfonic acid, 0.2 mass parts；Organic silicon defoamer
0.3 mass parts.First epoxy resin, benzene are mixed for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and dibasic acid ester mixture
It closes, is dispersed with stirring 15min；After being dispersed with stirring, it is (polytetrafluoroethylmodified modified to continuously add spherical polytetrafluoroethylmodified modified polyethylene wax
Polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil original be made
Material, it is spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 3
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture；Low point of epoxide equivalent 300~600
Son amount 7 mass parts of epoxy resin, 6 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；Acrylate defoaming agent 0.3
Mass parts.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, low-molecular-weight epoxy resin,
It is mixed with lithium aluminium silicate powder, is dispersed with stirring 15min；After being dispersed with stirring, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Color inhibition is different
3 mass parts of cyanate, 6 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；
2 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid, 0.1 mass parts, dibutyl tin
0.1 mass parts of cinnamic acid tin；0.2 mass parts of organic silicon defoamer.First by epoxy resin, color inhibition isocyanates, ureaformaldehyde amino tree
Rouge, 150# solvent naphtha and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoro is continuously added
Ethylene modified polyethylene wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), dibutyl tin dilaurate, ten hexichol sulphurs
Acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil raw material are made, spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 4
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture；Low point of epoxide equivalent 300~600
Son amount 7 mass parts of epoxy resin, 6 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；Acrylate defoaming agent 0.3
Mass parts.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, low-molecular-weight epoxy resin,
It is mixed with lithium aluminium silicate powder, is dispersed with stirring 15min；After being dispersed with stirring, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 81 mass parts of epoxide equivalent 1700；Benzene is for amino
3 mass parts of resin, 3 mass parts of ureaformaldehyde amino；3.5 mass parts of 150# solvent naphtha, 2 mass parts of dibasic acid ester mixture, ethylene glycol
2 mass parts of monobutyl ether；5 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid, 0.2 mass
Part；0.3 mass parts of organic silicon defoamer.First by epoxy resin, benzene for amino resins, ureaformaldehyde amino resins, 150# solvent naphtha and
Dibasic acid ester mixture mixing, is dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoroethylmodified modified polyethylene is continuously added
Wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organic silicon defoamer, continue to be dispersed with stirring 15
Gloss oil raw material is made in~30min, spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Embodiment 5
The packing jar ground of the present embodiment is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of primary coat raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 2000；Ureaformaldehyde amino
5 mass parts of resin；3.5 mass parts of 150# solvent naphtha, 5 mass parts of dibasic acid ester mixture；Low point of epoxide equivalent 300~600
Son amount 7 mass parts of epoxy resin, 6 mass parts of lithium aluminium silicate powder；Ten diphenyl sulfonic acid, 0.2 mass parts；Acrylate defoaming agent 0.3
Mass parts.First by epoxy resin, ureaformaldehyde amino resins, 150# solvent naphtha, dibasic acid ester mixture, low-molecular-weight epoxy resin,
It is mixed with lithium aluminium silicate powder, is dispersed with stirring 15min；After being dispersed with stirring, ten diphenyl sulfonic acid and acrylate defoaming are continuously added
Agent continues to be dispersed with stirring 15~30min, and primary coat raw material is made, spare.
(2) preparation of gloss oil raw material: epoxy resin (40% solid content) 73 mass parts of epoxide equivalent 1700；Benzene is for amino
7 mass parts of resin, 3 mass parts of color inhibition isocyanates, 5 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, two
First 5 mass parts of acid ester mixtures；3 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid
0.2 mass parts；0.3 mass parts of organic silicon defoamer.First by epoxy resin, benzene for amino resins, color inhibition isocyanates, ureaformaldehyde
Amino resins, 150# solvent naphtha and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, spherical shape is continuously added
Polytetrafluoroethylmodified modified polyethylene wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), ten diphenyl sulfonic acid and organosilicon disappear
Infusion continues to be dispersed with stirring 15~30min, and gloss oil raw material is made, spare.
(3) preparation of the composite coating of Laser Jet:
One, on chromium plating iron plate material after the primary coat raw material of roll-coating steps (1) acquisition, 1~15 is toasted at 180~200 DEG C
Minute, make primary coat coating dry film with a thickness of 4~7g/m2, to form priming coat.
Two, after being patterned on priming coat with ink roller, it is placed at 140~160 DEG C and toasts 10~15 minutes, in primary coat
Ink layer is formed on layer.
Three, on ink layer after the gloss oil raw material of roll-coating steps (2) acquisition, 10~15 points are toasted at 190~210 DEG C
Clock makes coating dry film with a thickness of 4~7g/m2, to form light oil reservoir on ink layer, so that being formed on three-piece can cover has
The composite coating of priming coat, ink layer and light oil reservoir.
Comparative example 1
The packing jar ground of this comparative example is three-piece can cover, and the material of cover is chromium plating iron plate.
One, after being patterned on chromium plating iron plate material with ink roller, be placed at 140~160 DEG C and toast 10~15 minutes, with
Ink layer is formed on sheet material.
Two, on ink layer after the commercially available clean oil raw material of roller coating, is toasted 10~15 minutes at 190~210 DEG C, make to apply
Layer thickness of dry film is 6~10g/m2, to form transparent oil reservoir on ink layer, so that being formed on three-piece can cover has ink
The composite coating of layer and transparent oil reservoir.
Comparative example 2
The packing jar ground of this comparative example is three-piece can cover, and the material of cover is chromium plating iron plate.
(1) preparation of gloss oil raw material: epoxy resin (40% solid content) 78 mass parts of epoxide equivalent 1700；Color inhibition is different
3 mass parts of cyanate, 3 mass parts of ureaformaldehyde amino resins；3.5 mass parts of 150# solvent naphtha, 8 mass parts of dibasic acid ester mixture；
4 mass parts of spherical polytetrafluoroethylmodified modified polyethylene wax (18% solid content)；Ten diphenyl sulfonic acid, 0.1 mass parts, dibutyl tin
0.1 mass parts of cinnamic acid tin；0.3 mass parts of organic silicon defoamer.First by epoxy resin, color inhibition isocyanates, ureaformaldehyde amino tree
Rouge, 150# solvent naphtha and dibasic acid ester mixture mixing, are dispersed with stirring 15min；After being dispersed with stirring, spherical polytetrafluoro is continuously added
Ethylene modified polyethylene wax (polytetrafluoroethylmodified modified polyethylene wax will be ground in advance), dibutyl tin dilaurate, ten hexichol sulphurs
Acid and organic silicon defoamer, continue to be dispersed with stirring 15~30min, gloss oil raw material are made, spare
One, after being patterned on chromium plating iron plate material with ink roller, be placed at 140~160 DEG C and toast 10~15 minutes, with
Ink layer is formed on sheet material.
Two, after ink layer upper roller applies gloss oil raw material made from above-mentioned steps (1), 10~15 are toasted at 190~210 DEG C
Minute, make coating dry film with a thickness of 6~10g/m2, to form transparent oil reservoir on ink layer, thus the shape on three-piece can cover
At the composite coating with ink layer and light oil reservoir.
The test result of the coating of each embodiment and comparative example preparation is referring to following table table 1.
Table 1
To sum up, the gloss oil and its composite coating of Laser Jet of the present invention, be used for Laser Jet, two dimensional code after sterilization,
After impregnating copper-bath, no any rust, two dimensional code is clear, can recognize, the solution prior art, which has had rust, leads to two dimensional code
Unsharp problem.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example
Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not
It is interpreted as that identical embodiment or example must be directed to.Moreover, particular features, structures, materials, or characteristics described
It can be combined in any suitable manner in any one or more of the embodiments or examples.In addition, those skilled in the art can
Different embodiments or examples described in this specification are engaged and be combined.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is not considered as limiting the invention, those skilled in the art within the scope of the invention can be to above-mentioned
Embodiment is changed, modifies, replacement and variant.
Claims (9)
1. a kind of gloss oil of Laser Jet characterized by comprising
The matrix resin of 75~85 mass parts；
The crosslinking agent of 5~15 mass parts；
The solvent of 5 ~ 15 mass parts；
The wax assistant of 1~5 mass parts；
The catalyst of 0.05~0.50 mass parts；
The defoaming agent of 0.05~1 mass parts；
Wherein, the matrix resin is epoxy resin.
2. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the matrix resin is linear high molecular weight
Epoxy resin.
3. the gloss oil of Laser Jet as claimed in claim 2, it is characterised in that: the epoxide equivalent of the epoxy resin is
The softening point of 1000 ~ 4000g/eq, the epoxy resin are greater than 100 DEG C.
4. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the crosslinking agent is selected from benzene for amino tree
At least one of rouge, ureaformaldehyde amino resins, color inhibition isocyanates.
5. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the solvent be selected from 100# solvent naphtha,
It is 150# solvent naphtha, dibasic acid ester mixture, ethylene glycol monobutyl ether, n-butanol, isophorone, several in ethylene glycol ether acetate
Kind mixture.
6. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the wax assistant is spherical polytetrafluoroethylene (PTFE)
Modified polyethylene wax.
7. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the catalyst is selected from organotin catalysts
Or acid catalyst.
8. the gloss oil of Laser Jet as described in claim 1, it is characterised in that: the defoaming agent be selected from esters of acrylic acid or
One of organosiloxane class.
9. a kind of composite coating of Laser Jet, it is characterised in that: including being suitable for the priming coat that is coated on packing jar ground,
The ink layer being coated on the priming coat and the light oil reservoir being coated on the ink layer；The light oil reservoir uses such as right
It is required that the gloss oil of Laser Jet described in any one of 1 ~ 8.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910425464.XA CN110183930B (en) | 2019-05-21 | 2019-05-21 | Gloss oil and composite coating for laser coding |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111098036A (en) * | 2019-12-31 | 2020-05-05 | 北京赛腾标识系统股份公司 | Code assigning method and system |
| CN114536920A (en) * | 2022-02-25 | 2022-05-27 | 上海紫江彩印包装有限公司 | Composite membrane and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103122203A (en) * | 2012-12-12 | 2013-05-29 | 孙才清 | Inner layer metal decorating paint and metal decorating method |
| CN104449242A (en) * | 2014-12-25 | 2015-03-25 | 佛山市儒林化工有限公司 | Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability |
| WO2018210144A1 (en) * | 2017-05-19 | 2018-11-22 | 中国科学院化学研究所 | Ink for producing laser light sources |
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2019
- 2019-05-21 CN CN201910425464.XA patent/CN110183930B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103122203A (en) * | 2012-12-12 | 2013-05-29 | 孙才清 | Inner layer metal decorating paint and metal decorating method |
| CN104449242A (en) * | 2014-12-25 | 2015-03-25 | 佛山市儒林化工有限公司 | Primary-coat-free sanitary can gloss oil with good adhesive force and excellent processability |
| WO2018210144A1 (en) * | 2017-05-19 | 2018-11-22 | 中国科学院化学研究所 | Ink for producing laser light sources |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111098036A (en) * | 2019-12-31 | 2020-05-05 | 北京赛腾标识系统股份公司 | Code assigning method and system |
| CN114536920A (en) * | 2022-02-25 | 2022-05-27 | 上海紫江彩印包装有限公司 | Composite membrane and preparation method and application thereof |
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Denomination of invention: A varnish and composite coating for laser coding Effective date of registration: 20220705 Granted publication date: 20211112 Pledgee: Zhangzhou Changtai Branch of Bank of China Ltd. Pledgor: Fujian Herun Packaging Coatings Co.,Ltd. Registration number: Y2022980009892 |