CN110202892A - 一种猪舍保温方法 - Google Patents
一种猪舍保温方法 Download PDFInfo
- Publication number
- CN110202892A CN110202892A CN201910469398.6A CN201910469398A CN110202892A CN 110202892 A CN110202892 A CN 110202892A CN 201910469398 A CN201910469398 A CN 201910469398A CN 110202892 A CN110202892 A CN 110202892A
- Authority
- CN
- China
- Prior art keywords
- layer
- eptfe membrane
- pig house
- fabric
- hemp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000004744 fabric Substances 0.000 claims abstract description 131
- 239000012528 membrane Substances 0.000 claims abstract description 65
- 229920000295 expanded polytetrafluoroethylene Polymers 0.000 claims abstract description 54
- 239000011852 carbon nanoparticle Substances 0.000 claims abstract description 32
- 238000009413 insulation Methods 0.000 claims abstract description 27
- 244000025254 Cannabis sativa Species 0.000 claims description 46
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 46
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 46
- 235000009120 camo Nutrition 0.000 claims description 46
- 235000005607 chanvre indien Nutrition 0.000 claims description 46
- 239000011487 hemp Substances 0.000 claims description 46
- 239000000725 suspension Substances 0.000 claims description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 18
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 16
- 229920001661 Chitosan Polymers 0.000 claims description 16
- 235000010413 sodium alginate Nutrition 0.000 claims description 16
- 229940005550 sodium alginate Drugs 0.000 claims description 16
- 239000000661 sodium alginate Substances 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 15
- 239000012943 hotmelt Substances 0.000 claims description 15
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 14
- 239000011790 ferrous sulphate Substances 0.000 claims description 14
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 14
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 14
- 238000005245 sintering Methods 0.000 claims description 14
- 235000019441 ethanol Nutrition 0.000 claims description 13
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 claims description 12
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 claims description 12
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 claims description 12
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 11
- 238000004544 sputter deposition Methods 0.000 claims description 10
- 239000002759 woven fabric Substances 0.000 claims description 10
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000007598 dipping method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000009987 spinning Methods 0.000 claims description 5
- 239000006228 supernatant Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 239000003610 charcoal Substances 0.000 abstract description 7
- 230000009471 action Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- 238000004332 deodorization Methods 0.000 description 9
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000001877 deodorizing effect Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000005660 chlorination reaction Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 2
- 230000031709 bromination Effects 0.000 description 2
- 238000005893 bromination reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- AJXBTRZGLDTSST-UHFFFAOYSA-N amino 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)ON AJXBTRZGLDTSST-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K1/00—Housing animals; Equipment therefor
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
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- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- B32B7/04—Interconnection of layers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
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- D06M13/2243—Mono-, di-, or triglycerides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/46—Compounds containing quaternary nitrogen atoms
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/03—Polysaccharides or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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Abstract
本发明公开了一种猪舍保温布料及其保温方法,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层上设有一层纳米活性炭膜层。保温布料中设有内层织物层、表层织物层,其中表层织物层和内层织物层之间还设有ePTFE膜层,ePTFE膜层上设有一层纳米活性炭膜层,表层织物层和内层织物层对ePTFE膜层以及纳米活性炭膜层进行保护作用,防止ePTFE膜层以及纳米活性炭膜层在使用过程中被破坏,且ePTFE膜层具有防水、挡风的作用,而纳米活性炭层可对猪舍中的异味进行吸收净化,同时还具有吸收热能的作用,可对猪舍进行保温。猪舍保温效果好。
Description
技术领域
本发明涉及养殖业技术领域,具体涉及一种猪舍保温方法。
背景技术
现有的猪场养殖方法主要采用水帘幕布,对猪舍起到防风作用,但效果不明显,四周漏风严重,冷风吹进猪舍严重影响了前排种猪的生长。为了进一步提高防风效果还在水帘内侧,水帘幕布里侧加装一层塑料布,通过调速风机抽风和铁线的固定,把塑料布严严实实的固定在水帘上,再拉上水帘幕布形成双层保护,使冷风进不到猪舍内。门口加装棉布门帘可以减少冷风从门缝吹进猪舍,起到了对冷风的缓冲作用,同时也起到了保暖作用。
此方法虽然已经做好了两层保护措施,但是墙缝、门缝依然会有风透进来,较猪舍中间位置还是比较冷,所以在前排定位栏加装一层塑料布,对门口的种猪起到了直接的保护作用,使门口的种猪可更自然的生长,提高母猪生产性能。但是现有的水帘幕布仅仅起到挡风的作用,且水席幕布同时还具有遮阴的作用,会降低猪舍的温度,且现有发方法还假设塑料布增加防风效果,操作麻烦。因此,对水帘幕布材料的改进有助于对猪舍保温,且现有技术中采用铁线固定,对塑料布和水帘幕布的造成一定的损坏,因此适宜的固定卡扣设计也很有必要。
发明内容
本发明克服了现有技术中采用水帘幕布的=对猪舍保温效果差的技术问题,提供一种猪舍保温方法。
为解决上述问题,本发明采取如下技术方案:
一种猪舍保温布料,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层上设有一层纳米活性炭膜层;所述内层织物层为大麻纤维织物层:
所述大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于60~80℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌4~5h,在6000~7000r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于60~80℃下干燥至固体物的水分百分含量20~30%;将干燥后的固体物置于乙醇溶液中,搅拌均匀,再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌2~5h即制得所述悬浮液;
(2)大麻纤维预处理:将大麻纤维浸渍于步骤(1)得到的悬浮液中搅拌30~50min,取出后用轧车出去多余的反应液,再将大麻纤维浸渍再次浸渍于步骤(1)得到的悬浮液中搅拌10min,取出后置于恒温干燥箱中于80~100℃下恒温干燥;
(3)织布:将步骤(2)得到的大麻纤维依次通过成条、纺纱以及织布制成大麻纤维织物层。
其中,所述悬浮液由质量份的如下原料组成:海藻酸钠30~40份、壳聚糖1~5份、乙醇1~5份、十六烷基三甲基溴化铵1~2份、十八烷基三甲基氯化铵0.1~1份、单油酸甘油酯0.1~0.6份、硫酸亚铁0.01~0.1份、纳米二氧化硅载银抗菌粉0.01~0.1份、碱式氯化铝0.01~0.1份、水5~10份。
其中,所述ePTFE膜层与内层织物层、表层织物层之间通过柔性胶水,采用热熔热压法或者辊涂方法粘结。
其中,所述ePTFE膜层的ePTFE膜为孔径为5~200nm的纳米多孔膜。
其中,所述纳米活性炭是通过真空溅射设于ePTFE膜层上的,其纳米活性炭膜层的厚度为1~500nm。
其中,所述的纳米活性炭的孔径为0.8nm~2nm。
本发明的另一目的在于保护上述一种猪舍保温布料的制作方法,其包括以下步骤:
制备纳米活性炭膜层:利用真空溅射的方法在ePTFE膜的表面制备一层纳米活性炭膜层;
ePTFE膜与表层织物层粘贴:用柔性胶水将ePTFE膜通过热熔热压法或者辊涂方法均匀平铺粘附于表层织物层上,烘干;
与内层织物层粘贴:用柔性胶水将内层织物层通过热熔热压法或者辊涂方法粘附于ePTFE膜上,烘干。
本发明的另一目的在于保护一种利用上述布料进行猪舍保温方法,其包括如下步骤:
将所述布料固定于猪舍的门、窗;前排定位栏加装一层塑料布,采用卡扣将布料固定于门窗上;所述的卡扣包括定位件、紧固件;所述定位件固定于门、窗边边缘;所述紧固件用于将所述布料固定在所述固定件上。
本发明与现有技术相比较具有以下有益效果:
(1)本发明的猪舍保温布料中设有内层织物层、表层织物层,其中表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层上设有一层纳米活性炭膜层其中表层织物层和内层织物层对ePTFE膜层以及纳米活性炭膜层进行保护作用,防止ePTFE膜层以及纳米活性炭膜层在使用过程中被破坏,且ePTFE膜层具有防水、挡风的作用,而加设的纳米活性炭层可对猪舍中的异味进行吸收净化,同时还具有吸收热能的作用,可对猪舍进行保温。
(2)本发明的内层织物层优选用大麻纤维织物层,其将硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝包埋于海藻酸钠和壳聚糖中,硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝为无机抗菌抑菌除臭成分,具有除臭杀菌效果,本发明将无机抗菌抑菌除臭成分进行微包埋后再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续搅拌形成稳定的悬浮液;再将大麻纤维浸渍于悬浮液中制备得到的大麻纤维织物层充分利用大麻纤维的抑菌作用以及较强的耐热性,一方面与ePTFE膜层上设有一层纳米活性炭膜层粘贴后,在纳米活性炭吸热作用下,温度升高后大麻纤维中含有的抗菌抑菌除臭微球不被破坏,依然能较好的包埋于海藻酸钠和壳聚糖中,可较好与保温布料配合使用,实用性较强。另一方面大麻纤维本身具有抑菌作用,而无机抗菌抑菌除臭成分与十六烷基三甲基溴化铵、十八烷基三甲基氯化铵均有较强的抑菌杀菌除臭作用,含有无机抗菌抑菌除臭成分、十六烷基三甲基溴化铵、十八烷基三甲基氯化铵的大麻纤维层作为保温布料内层,可吸收猪舍中产生的硫化氢、氨气等臭味,具有较好的除臭效果,同时对空气中的微生物菌也起到较好的杀菌作痛。本发明的猪舍保温布料可为猪提供温度适宜、无菌、无臭生长的环境。大麻纤维层的除臭效果,可使猪舍方圆10米闻不到臭味,除臭效果好。
(3)本发明还采用卡扣结构将布料固定在门和窗上,固定效果好,不漏风。
具体实施方式
下面结合实施例和实验对本发明作进一步说明。
实施例1
一种猪舍保温布料,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层与内层织物层、表层织物层之间通过柔性胶水,采用热熔热压法或者辊涂方法粘结。所述ePTFE膜层的ePTFE膜为孔径为200nm的纳米多孔膜,所述ePTFE膜层上设有一层纳米活性炭膜层;所述纳米活性炭是通过真空溅射设于ePTFE膜层上的,其纳米活性炭膜层的厚度为1nm,纳米活性炭的孔径为2nm。
所述内层织物层为大麻纤维织物层:所述大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于60℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌5h,在6000r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于80℃下干燥至固体物的水分百分含量20%;将干燥后的固体物置于乙醇溶液中,搅拌均匀,再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌5h即制得所述悬浮液;其中,所述悬浮液由质量份的如下原料组成:海藻酸钠30份、壳聚糖5份、乙醇1份、十六烷基三甲基溴化铵2份、十八烷基三甲基氯化铵0.1份、单油酸甘油酯0.6份、硫酸亚铁0.01份、纳米二氧化硅载银抗菌粉0.1份、碱式氯化铝0.01份、水10份;
(2)大麻纤维预处理:将大麻纤维浸渍于步骤(1)得到的悬浮液中搅拌30min,取出后用轧车出去多余的反应液,再将大麻纤维浸渍再次浸渍于步骤(1)得到的悬浮液中搅拌10min,取出后置于恒温干燥箱中于100℃下恒温干燥;
(3)织布:将步骤(2)得到的大麻纤维依次通过成条、纺纱以及织布制成大麻纤维织物层。
上述猪舍保温布料的制作方法,包括以下步骤:
制备纳米活性炭膜层:利用真空溅射的方法在ePTFE膜的表面制备一层纳米活性炭膜层;
ePTFE膜与表层织物层粘贴:用柔性胶水将ePTFE膜通过热熔热压法或者辊涂方法均匀平铺粘附于表层织物层上,烘干;
与内层织物层粘贴:用柔性胶水将内层织物层通过热熔热压法或者辊涂方法粘附于ePTFE膜上,烘干。
利用上述布料进行猪舍保温方法,包括如下步骤:
将所述布料固定于猪舍的门、窗;前排定位栏加装一层塑料布,采用卡扣将布料固定于门窗上;所述的卡扣包括定位件、紧固件;所述定位件固定于门、窗边边缘;所述紧固件用于将所述布料固定在所述固定件上。
实施例2
一种猪舍保温布料,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层与内层织物层、表层织物层之间通过柔性胶水,采用热熔热压法或者辊涂方法粘结。所述ePTFE膜层的ePTFE膜为孔径为5nm的纳米多孔膜,所述ePTFE膜层上设有一层纳米活性炭膜层;所述纳米活性炭是通过真空溅射设于ePTFE膜层上的,其纳米活性炭膜层的厚度为500nm,纳米活性炭的孔径为0.8nm。
所述内层织物层为大麻纤维织物层:所述大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于80℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌4h,在7000r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于60℃下干燥至固体物的水分百分含量30%;将干燥后的固体物置于乙醇溶液中,搅拌均匀,再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌2h即制得所述悬浮液;其中,所述悬浮液由质量份的如下原料组成:海藻酸钠40份、壳聚糖1份、乙醇5份、十六烷基三甲基溴化铵1份、十八烷基三甲基氯化铵1份、单油酸甘油酯0.1份、硫酸亚铁0.1份、纳米二氧化硅载银抗菌粉0.01份、碱式氯化铝0.1份、水5份;
(2)大麻纤维预处理:将大麻纤维浸渍于步骤(1)得到的悬浮液中搅拌50min,取出后用轧车出去多余的反应液,再将大麻纤维浸渍再次浸渍于步骤(1)得到的悬浮液中搅拌10min,取出后置于恒温干燥箱中于80℃下恒温干燥;
(3)织布:将步骤(2)得到的大麻纤维依次通过成条、纺纱以及织布制成大麻纤维织物层。
上述猪舍保温布料的制作方法,包括以下步骤:
制备纳米活性炭膜层:利用真空溅射的方法在ePTFE膜的表面制备一层纳米活性炭膜层;
ePTFE膜与表层织物层粘贴:用柔性胶水将ePTFE膜通过热熔热压法或者辊涂方法均匀平铺粘附于表层织物层上,烘干;
与内层织物层粘贴:用柔性胶水将内层织物层通过热熔热压法或者辊涂方法粘附于ePTFE膜上,烘干。
利用上述布料进行猪舍保温方法,包括如下步骤:
将所述布料固定于猪舍的门、窗;前排定位栏加装一层塑料布,采用卡扣将布料固定于门窗上;所述的卡扣包括定位件、紧固件;所述定位件固定于门、窗边边缘;所述紧固件用于将所述布料固定在所述固定件上。
实施例3
一种猪舍保温布料,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层与内层织物层、表层织物层之间通过柔性胶水,采用热熔热压法或者辊涂方法粘结。所述ePTFE膜层的ePTFE膜为孔径为100nm的纳米多孔膜,所述ePTFE膜层上设有一层纳米活性炭膜层;所述纳米活性炭是通过真空溅射设于ePTFE膜层上的,其纳米活性炭膜层的厚度为200nm,纳米活性炭的孔径为1nm。
所述内层织物层为大麻纤维织物层:所述大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于70℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌4.5h,在6500r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于70℃下干燥至固体物的水分百分含量25%;将干燥后的固体物置于乙醇溶液中,搅拌均匀,再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌3h即制得所述悬浮液;其中,所述悬浮液由质量份的如下原料组成:海藻酸钠35份、壳聚糖3份、乙醇4份、十六烷基三甲基溴化铵1.5份、十八烷基三甲基氯化铵0.5份、单油酸甘油酯0.5份、硫酸亚铁0.05份、纳米二氧化硅载银抗菌粉0.05份、碱式氯化铝0.05份、水8份;
(2)大麻纤维预处理:将大麻纤维浸渍于步骤(1)得到的悬浮液中搅拌40min,取出后用轧车出去多余的反应液,再将大麻纤维浸渍再次浸渍于步骤(1)得到的悬浮液中搅拌10min,取出后置于恒温干燥箱中于90℃下恒温干燥;
(3)织布:将步骤(2)得到的大麻纤维依次通过成条、纺纱以及织布制成大麻纤维织物层。
上述猪舍保温布料的制作方法,包括以下步骤:
制备纳米活性炭膜层:利用真空溅射的方法在ePTFE膜的表面制备一层纳米活性炭膜层;
ePTFE膜与表层织物层粘贴:用柔性胶水将ePTFE膜通过热熔热压法或者辊涂方法均匀平铺粘附于表层织物层上,烘干;
与内层织物层粘贴:用柔性胶水将内层织物层通过热熔热压法或者辊涂方法粘附于ePTFE膜上,烘干。
利用上述布料进行猪舍保温方法,包括如下步骤:
将所述布料固定于猪舍的门、窗;前排定位栏加装一层塑料布,采用卡扣将布料固定于门窗上;所述的卡扣包括定位件、紧固件;所述定位件固定于门、窗边边缘;所述紧固件用于将所述布料固定在所述固定件上。
对照组1
对照组1的布料与实施例3布料的基本相同,区别在于,对照组1的ePTFE膜层的纳米活性炭膜层。
对照组2
对照组2的布料与实施例3布料的基本相同,区别在于,对照组2的大麻纤维织物层不经过步骤(1)和步骤(2)处理。
对照组3
对照组3的布料与实施例3布料的基本相同,区别在于,对照组3的大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于60℃的水中,添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌5h即制得所述悬浮液;其中,所述悬浮液由质量份的如下原料组成:海藻酸钠30份、壳聚糖5份、乙醇1份、十六烷基三甲基溴化铵2份、十八烷基三甲基氯化铵0.1份、单油酸甘油酯0.6份、水10份。
步骤(2)和步骤(3)同实施例3。
对照组4
对照组4的布料与实施例3布料的基本相同,区别在于,对照组4的大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于70℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌4.5h,在6500r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于70℃下干燥至固体物的水分百分含量25%;将干燥后的固体物置于乙醇溶液中,搅拌均匀即制得所述悬浮液;其中,所述悬浮液由质量份的如下原料组成:海藻酸钠35份、壳聚糖3份、乙醇4份、硫酸亚铁0.05份、纳米二氧化硅载银抗菌粉0.05份、碱式氯化铝0.05份、水8份。
步骤(2)和步骤(3)同实施例3。
应用效果:
冬季,室外温度为5~15℃的条件下,采用实施例1~实施例3以及对照组1~对照组4于在贵港母猪养殖场进行保温,且不采取任何其他的保温措施。
保温效果:
实施例1~实施例3以及对照组2~对照组4的猪舍内室温保持在22~28℃之间,而对照组1的猪舍内温度为10~15℃,说明本发明对猪舍具有较好的保温效果。
除臭效果:
采用实施例1~实施例3猪舍保温方法保温后,距猪舍方圆8米外闻不到臭味,而对照组1猪舍保温方法保温后,距猪舍方圆10米外闻不到臭味除臭效果好,而对照组2~对照组4的猪舍保温方法保温后,距猪舍方圆20米外仍能闻到浓烈的臭味,由此说明,本发明的猪舍保温效果的除臭效果好。
上述说明是针对本发明较佳可行实施例的详细说明,但实施例并非用以限定本发明的专利申请范围,凡本发明所提示的技术精神下所完成的同等变化或修饰变更,均应属于本发明所涵盖专利范围。
Claims (8)
1.一种猪舍保温布料,其特征在于,其包括内层织物层、表层织物层;所述表层织物层和内层织物层之间还设有ePTFE膜层,所述ePTFE膜层上设有一层纳米活性炭膜层;所述内层织物层为大麻纤维织物层:
所述大麻纤维织物层由如下方法制备得到:
(1)制备悬浮液:将海藻酸钠和壳聚糖溶于60~80℃的水中,再添加硫酸亚铁、纳米二氧化硅载银抗菌粉、碱式氯化铝后继续搅拌4~5h,在6000~7000r/min的转速下离心分离,出去上清液,将固体物置于恒温干燥箱中于60~80℃下干燥至固体物的水分百分含量20~30%;将干燥后的固体物置于乙醇溶液中,搅拌均匀,再添加十六烷基三甲基溴化铵、十八烷基三甲基氯化铵、单油酸甘油酯后继续继续搅拌2~5h即制得所述悬浮液;
(2)大麻纤维预处理:将大麻纤维浸渍于步骤(1)得到的悬浮液中搅拌30~50min,取出后用轧车出去多余的反应液,再将大麻纤维浸渍再次浸渍于步骤(1)得到的悬浮液中搅拌10min,取出后置于恒温干燥箱中于80~100℃下恒温干燥;
(3)织布:将步骤(2)得到的大麻纤维依次通过成条、纺纱以及织布制成大麻纤维织物层。
2.根据权利要求1所述的一种猪舍保温布料,其特征在于,所述悬浮液由质量份的如下原料组成:海藻酸钠30~40份、壳聚糖1~5份、乙醇1~5份、十六烷基三甲基溴化铵1~2份、十八烷基三甲基氯化铵0.1~1份、单油酸甘油酯0.1~0.6份、硫酸亚铁0.01~0.1份、纳米二氧化硅载银抗菌粉0.01~0.1份、碱式氯化铝0.01~0.1份、水5~10份。
3.根据权利要求1所述的一种猪舍保温布料,其特征在于,所述ePTFE膜层与内层织物层、表层织物层之间通过柔性胶水,采用热熔热压法或者辊涂方法粘结。
4.根据权利要求1所述的一种猪舍保温布料,其特征在于,所述ePTFE膜层的ePTFE膜为孔径为5~200nm的纳米多孔膜。
5.根据权利要求1所述的一种猪舍保温布料,其特征在于,所述纳米活性炭是通过真空溅射设于ePTFE膜层上的,其纳米活性炭膜层的厚度为1~500nm。
6.根据权利要求1或5所述的一种猪舍保温布料,其特征在于,所述的纳米活性炭的孔径为0.8nm~2nm。
7.一种如权利要求1~6任一所述的一种猪舍保温布料的制作方法,其特征在于,包括以下步骤:
制备纳米活性炭膜层:利用真空溅射的方法在ePTFE膜的表面制备一层纳米活性炭膜层;
ePTFE膜与表层织物层粘贴:用柔性胶水将ePTFE膜通过热熔热压法或者辊涂方法均匀平铺粘附于表层织物层上,烘干;
与内层织物层粘贴:用柔性胶水将内层织物层通过热熔热压法或者辊涂方法粘附于ePTFE膜上,烘干。
8.一种利用权利要求1所述布料进行猪舍保温方法,其特征在于,包括如下步骤:
将所述布料固定于猪舍的门、窗;前排定位栏加装一层塑料布,采用卡扣将布料固定于门窗上;所述的卡扣包括定位件、紧固件;所述定位件固定于门、窗边边缘;所述紧固件用于将所述布料固定在所述固定件上。
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