CN110195492A - One kind having the function of VOC light degradation ASA synthetic resin watt and its preparation process - Google Patents
One kind having the function of VOC light degradation ASA synthetic resin watt and its preparation process Download PDFInfo
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- CN110195492A CN110195492A CN201910451048.7A CN201910451048A CN110195492A CN 110195492 A CN110195492 A CN 110195492A CN 201910451048 A CN201910451048 A CN 201910451048A CN 110195492 A CN110195492 A CN 110195492A
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- China
- Prior art keywords
- synthetic resin
- asa
- watt
- resin watt
- parts
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- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 89
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 89
- 230000015556 catabolic process Effects 0.000 title claims abstract description 37
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical group O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 44
- 239000002131 composite material Substances 0.000 claims abstract description 28
- 239000011238 particulate composite Substances 0.000 claims abstract description 20
- 238000001125 extrusion Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 238000007493 shaping process Methods 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims description 45
- 239000011347 resin Substances 0.000 claims description 45
- 239000000463 material Substances 0.000 claims description 43
- 229960000892 attapulgite Drugs 0.000 claims description 37
- 229910052625 palygorskite Inorganic materials 0.000 claims description 37
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 29
- 239000004611 light stabiliser Substances 0.000 claims description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000010410 layer Substances 0.000 claims description 19
- 239000002344 surface layer Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000012153 distilled water Substances 0.000 claims description 16
- 239000002994 raw material Substances 0.000 claims description 16
- 239000003381 stabilizer Substances 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 14
- 239000003963 antioxidant agent Substances 0.000 claims description 14
- 230000003078 antioxidant effect Effects 0.000 claims description 14
- 239000011734 sodium Substances 0.000 claims description 14
- 229910052708 sodium Inorganic materials 0.000 claims description 14
- 239000004408 titanium dioxide Substances 0.000 claims description 14
- 239000000243 solution Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 10
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 10
- 239000010881 fly ash Substances 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000002689 soil Substances 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 7
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000012792 core layer Substances 0.000 claims description 4
- -1 irgasfos 168 Chemical compound 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000000344 soap Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000008301 phosphite esters Chemical class 0.000 claims description 3
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- OKOBUGCCXMIKDM-UHFFFAOYSA-N Irganox 1098 Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OKOBUGCCXMIKDM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000001914 filtration Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229940098458 powder spray Drugs 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D1/00—Roof covering by making use of tiles, slates, shingles, or other small roofing elements
- E04D1/28—Roofing elements comprising two or more layers, e.g. for insulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses one kind to have the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the particulate composite on the ASA synthetic resin watt surface；The particulate composite is montmorillonite/TIO2Composite material.The invention also discloses a kind of preparation processes with VOC light degradation ASA synthetic resin watt, by passing through spraying during the extrusion molding of ASA synthetic resin watt, particulate composite is attached to ASA synthetic resin watt surface, cooling and shaping obtains having the function of VOC light degradation ASA synthetic resin watt.One kind disclosed by the invention has the function of VOC light degradation ASA synthetic resin watt, and not only intensity is high, and VOC light degradation function is significant, practical durable, and simple process, is convenient for practical operation, at low cost.
Description
Technical field
The present invention relates to ASA synthetic resin watt technical fields, more particularly to one kind to have the function of VOC light degradation ASA synthesis
Resin tile and its preparation process.
Background technique
Synthetic resin watt is the New Building Materials developed with high-new chemical Chemical Engineering Technology, synthetic resin watt tool
Have that lasting color, light, self waterproofing, tough and tensile, insulation, sound insulation, corrosion-resistant, wind resistance is shockproof, anti-ice hail, anti-pollution, green ring
The advantages that protecting, prevent fires, insulating, is easy for installation, and three-dimensional sense handsome in appearance is strong, the great Chinese Elements of color, so that it is wide
It is general to be applied to the market of farm produce, market, residential quarters, new countryside construction resident Deluxe villa, canopy, awning, pseudo-classic architecture etc.
All kinds of permanent structure roof decorations.
The main component of synthetic resin watt is synthetic resin, that is, has artificial synthesized a kind of high molecular polymer.In external force
It can be in Plastic Flow state under effect, certain properties are similar to natural resin.The surface material of synthetic resin watt is the most key, face
The selection of layer material directly affects the service life of resin tile, and the weatherability of product directly results in the use longevity of synthetic resin watt
Life, synthetic resin watt in most cases selects outstanding extra-weather-proof materials A SA or PMMA, by surface co-extrusion finally at
The quality of type, synthetic resin watt also has relationship with the usage amount of surfacing and co-extrusion technology.Synthetic resin watt is used as Building wood
Material, use environment and people's lives environment are closely bound up, and synthetic resin itself is easy slow in long-time use process
Part small molecule organic compound is discharged, people's living environment is damaged.
Summary of the invention
Technical problems based on background technology, the invention proposes one kind to have the function of VOC light degradation ASA synthesis tree
Rouge watt and its preparation process, the present invention, which coats one layer on conventional synthetic resin watt surface, has the compound of light degradation VOC function
Catalysis material, outdoors have excellent resistance to UV aging, long service life, the good mechanical properties of material, not only
The pollution problem of material itself can be solved, the VOC substance being harmful to the human body in environment can be also solved, is that a kind of real environmental protection is built
Material.
One kind proposed by the present invention has the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and spray
It is coated in the particulate composite on the ASA synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material.
Preferably, the montmorillonite/TIO2Composite material is prepared using following technique:
A, montmorillonite is sent into sodium chloride solution, is stirred, stood, filtered, washing is added distilled water and is uniformly mixed, obtains
To sodium-based montmorillonite mixed liquor；
B, titanium tetrachloride is added into hydrochloric acid, stirs, obtains the titanium dioxide acidic sol of pale yellow transparent；
C, titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred, stood, filtered, washed, drying,
350-480 DEG C of temperature calcining, obtains montmorillonite/TIO2Composite material.
The present invention utilizes the montmorillonite/TIO prepared2Composite material carries out composite material with ASA synthetic resin watt, covers
De- soil/TIO2Composite material has biggish specific surface area and stronger adsorption capacity, as photochemical catalyst, and utilizes it
Unique crystal structure and nano-scale, can be improved TIO2Degree of scatter, be obviously improved the functioning efficiency of photochemical catalyst.
Preferably, the ASA synthetic resin watt includes sandwich layer, and is coated on the surface layer of core layer surface；
Preferably, the raw material of the sandwich layer includes: 60-80 parts of polyvinyl chloride resin, CPE4-10 parts, modified attapulgite by weight
4-10 parts native, 5-15 parts of flyash, 4-8 parts of calcium carbonate, 6-8 parts of compound stabilizer, 0.5-0.8 parts of lubricant；
The raw material on the surface layer includes: 50-75 parts of ASA resin, 25-40 parts of AS resin, EBS 0.3-0.5 by weight
Part, 5-10 parts of EVA, 0.4-0.6 parts of light stabilizer, 0.2-0.4 parts of antioxidant；
Preferably, in the preparation process of ASA synthetic resin watt, sandwich layer and surface layer is obtained into ASA by coextrusion mold and synthesized
Resin tile；It is further preferred that in the preparation process of ASA synthetic resin watt:
S1, polyvinyl chloride resin, CPE, attapulgite modified, flyash, calcium carbonate, compound stabilizer, lubricant mixed according to the ratio
It closes, obtains material A；
S2, ASA resin, AS resin are dried；
S3, ASA resin, the AS resin after drying mixed with EBS, EVA, light stabilizer, antioxidant according to the ratio, obtains object
Expect B；
S4, material A is added to main extruder, material B is added co-extrusion extruder, extrusion molding together, wherein main extruder
Temperature is 165-175 DEG C, and for coextruder temperature at 190-195 DEG C, head temperature obtains ASA synthetic resin at 190-210 DEG C
Watt.
Preferably, in the raw material on surface layer, the ASA resin, melting means is 4-8g/10min (220 DEG C, 10kg), is stretched strong
Degree >=50Mpa, impact strength >=400J/m.
Preferably, in the raw material on surface layer, the AS resin, melting means is 6-15g/10min (220 DEG C, 10kg), is stretched strong
Degree >=65Mpa.
Preferably, in the raw material on surface layer, the light stabilizer is light stabilizer UV-944, light stabilizer UV-622, light
At least one of stabilizer UV-770 and light stabilizer UV-2020.
Preferably, in the raw material on surface layer, the antioxidant is antioxidant 1010, antioxidant 1076, irgasfos 168, resists
At least one of oxygen agent 1098.
Preferably, in the raw material of sandwich layer, in the attapulgite modified preparation process: attapulgite is placed in stirring
Machine stirring, obtains loose attapulgite, uses ethyl alcohol as solvent by KH-570 dissolved dilution, is filled with pine with Sprayable addition
In the blender for dissipating attapulgite, stir, it is dry, it obtains attapulgite modified.
Preferably, in the raw material of sandwich layer, the compound stabilizer is alkali formula lead salt, metallic soap, organotin, epoxy compound
At least two of object, phosphite ester and polyalcohol.
The invention also provides a kind of preparation processes with VOC light degradation ASA synthetic resin watt, including walk as follows
It is rapid: by spraying during the extrusion molding of ASA synthetic resin watt, particulate composite being attached to ASA synthetic resin watt
Surface, cooling and shaping obtain having the function of VOC light degradation ASA synthetic resin watt.
TIO2Material has many advantages, such as good photocatalysis, and chemical stability, nontoxic and inexpensive.Turn in photoelectricity
Change, photochemical syntheses and photochemical catalytic oxidation environmental contaminants etc. have broad application prospects.But TiO2Have again only
Have the shortcomings that absorption, particle are smaller and difficult to recycle under ultraviolet light, limits TIO2Application, core of the invention exists
In utilization montmorillonite/TIO2Optic catalytic composite material makes synthetic resin watt construction timber have the function of VOC light degradation, pass through by
TIO2It is carried on different carriers and loaded photocatalyst is made can further improve efficiency of light absorption, enhance the utilization to light source
Rate and the immobilization for solving the problems, such as catalyst；Montmorillonite is the chief component of bentonite mineral, is that a kind of interlayer has and can hand over
The two-dimensional layer silicate mineral of cation is changed, there is good dilatancy, adsorptivity and cation exchange property, is inserted to be many
Layer substance carries out the compound insertion reaction of interlayer and provides advantageous condition.For comprehensive TIO2Efficient photocatalytic activity and montmorillonite
Superior texture property introduces titanium hydroxyl in montmorillonite interlamination region, so that it is converted to TIO by calcining2It is pillared to prepare titanium
Montmorillonite composite material.This material has the interlayer support column of big specific surface area and preferable catalytic activity, on the one hand can be real
Existing TIO2Stablize it is immobilized, it is on the other hand compound after the increase of specific surface area also enhance the contact of catalyst with VOC substance,
So as to rapid photocatalytic degradation of contaminant.
Specific embodiment
In the following, technical solution of the present invention is described in detail by specific embodiment.
Embodiment 1
One kind having the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the ASA
The particulate composite on synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material, the montmorillonite/TIO2Composite material is using as follows
Technique preparation:
A, it weighs 0.5kg montmorillonite, pour into the sodium chloride solution of 80L concentration 0.2%, stir 2min, stand 15h, mistake
Filter, is washed with distilled water, and solid is added into 50L distilled water and is uniformly mixed, sodium-based montmorillonite mixed liquor is obtained；
B, 200mL titanium tetrachloride is added into the hydrochloric acid solution of 10L concentration 0.2mol/L, stirs 20min, obtains faint yellow
Transparent titanium dioxide acidic sol；
C, 5mL titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred evenly, stood at 30 DEG C of temperature
15h, filtering, is washed with distilled water, and dries in temperature 50 C, is put into Muffle furnace, in 380 DEG C of calcining 0.5h of temperature, is covered
De- soil/TIO2Composite material.
Embodiment 2
One kind having the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the ASA
The particulate composite on synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material, the montmorillonite/TIO2Composite material is using as follows
Technique preparation:
A, it weighs 2kg montmorillonite, pour into the sodium chloride solution of 200L concentration 1.6%, stir 20min, stand 48h, mistake
Filter, is washed with distilled water, and solid is added into 200L distilled water and is uniformly mixed, sodium-based montmorillonite mixed liquor is obtained；
B, 450mL titanium tetrachloride is added into the hydrochloric acid solution of 30L concentration 1.5mol/L, stirs 3h, obtains faint yellow
Bright titanium dioxide acidic sol；
C, 30mL titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred evenly, stood at 80 DEG C of temperature
60h, filtering, is washed with distilled water, and dries, is put into Muffle furnace at 90 DEG C of temperature, in 450 DEG C of calcining 4h of temperature, obtains covering de-
Soil/TIO2Composite material.
Embodiment 3
One kind having the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the ASA
The particulate composite on synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material, the montmorillonite/TIO2Composite material is using as follows
Technique preparation:
A, it weighs 0.5kg montmorillonite, pour into the sodium chloride solution of 80L concentration 0.8%, stir 6min, stand 12h, mistake
Filter, is washed with distilled water, and solid is added into 80L distilled water and is uniformly mixed, sodium-based montmorillonite mixed liquor is obtained；
B, 320mL titanium tetrachloride is added into the hydrochloric acid solution of 15L concentration 0.8mol/L, stirs 0.5h, obtains faint yellow
Transparent titanium dioxide acidic sol；
C, 10mL titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred evenly, stood in temperature 50 C
36h, filtering, is washed with distilled water, and dries, is put into Muffle furnace at 72 DEG C of temperature, in 350 DEG C of calcining 1h of temperature, obtains covering de-
Soil/TIO2Composite material.
The ASA synthetic resin watt includes sandwich layer, and is coated on the surface layer of core layer surface；
The raw material of the sandwich layer includes: 60 parts of polyvinyl chloride resin, CPE4 parts, 4 parts attapulgite modified, flyash 5 by weight
Part, 4 parts of calcium carbonate, 6 parts of compound stabilizer, 0.5 part of lubricant；The compound stabilizer includes alkali formula lead salt, metallic soap.It is described
In attapulgite modified preparation process:
(1) attapulgite is placed in high-speed mixer, first low rate start, then high-speed stirred 2min, makes attapulgite
Loosely；
(2) use a small amount of ethyl alcohol as solvent by KH-570 dissolved dilution, KH-570 dosage is attapulgite quality
0.6%, it is added in high-speed mixer with Sprayable, stirs 21min；
(3) modified attapulgite is obtained attapulgite modified in 105 DEG C of dryings.
The raw material on the surface layer include: by weight 50 parts of ASA resin, 25 parts of AS resin, 0.3 part of EBS, 5 parts of EVA,
0.4 part of light stabilizer, 0.2 part of antioxidant；The ASA resin melting means be 8g/10min (220 DEG C, 10kg), tensile strength >=
50Mpa, impact strength >=400J/m.The AS resin, melting means be 15g/10min (220 DEG C, 10kg), tensile strength >=
65Mpa.The light stabilizer is light stabilizer UV-944.The antioxidant is antioxidant 1010.
In the preparation process of ASA synthetic resin watt:
S1, polyvinyl chloride resin, CPE, attapulgite modified, flyash, calcium carbonate, compound stabilizer, lubricant are weighed according to the ratio
Equal materials, are put into batch mixer, are stirred mixing 20min, obtain material A；
S2, materials such as ASA, AS, under the conditions of 60 DEG C, dry 3h；
S3, the materials such as ASA resin, AS resin, EBS, EVA, light stabilizer, antioxidant are weighed according to the ratio, be put into batch mixer
In, it is stirred mixing 20min, obtains material B；
S4, material A is added to main extruder, co-extrusion extruder, together extrusion molding is added in material B.Wherein main extruder
Temperature is at 165 DEG C, and for coextruder temperature at 190 DEG C, head temperature obtains ASA synthetic resin watt at 180 DEG C.
In the preparation process for having the function of VOC light degradation ASA synthetic resin watt: in the extrusion of ASA synthetic resin watt
By powder spray in forming process, particulate composite is attached to ASA synthetic resin watt surface, cooling and shaping is had
There is VOC light degradation function ASA synthetic resin watt.
Embodiment 4
One kind having the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the ASA
The particulate composite on synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material, the montmorillonite/TIO2Composite material is using as follows
Technique preparation:
A, it weighs 1.6kg montmorillonite, pour into the sodium chloride solution of 130L concentration 1.4%, stir 18min, stand 36h,
Filtering, is washed with distilled water, and solid is added into 200L distilled water and is uniformly mixed, sodium-based montmorillonite mixed liquor is obtained；
B, 400mL titanium tetrachloride is added into the hydrochloric acid solution of 20L concentration 1.6mol/L, stirs 2h, obtains faint yellow
Bright titanium dioxide acidic sol；
C, 18mL titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred evenly, stood at 72 DEG C of temperature
50h, filtering, is washed with distilled water, and dries, is put into Muffle furnace at 84 DEG C of temperature, in 480 DEG C of calcining 4h of temperature, obtains covering de-
Soil/TIO2Composite material.
The ASA synthetic resin watt includes sandwich layer, and is coated on the surface layer of core layer surface；
The raw material of the sandwich layer includes: 80 parts of polyvinyl chloride resin, CPE10 parts, 10 parts attapulgite modified, fine coal by weight
Grey 15 parts, 8 parts of calcium carbonate, 8 parts of compound stabilizer, 0.8 part of lubricant；The compound stabilizer include alkali formula lead salt, metallic soap,
Organotin, epoxide, phosphite ester and polyalcohol.In the attapulgite modified preparation process:
(1) attapulgite is placed in high-speed mixer, first low rate start, then high-speed stirred 15min, makes attapulgite
Loosely；
(2) use a small amount of ethyl alcohol as solvent by KH-570 dissolved dilution, KH-570 dosage is attapulgite quality
1.8%, it is added in high-speed mixer with Sprayable, stirs 50min；
(3) modified attapulgite is obtained attapulgite modified in 120 DEG C of dryings.
The raw material on the surface layer include: by weight 75 parts of ASA resin, 40 parts of AS resin, 0.5 part of EBS, 10 parts of EVA,
0.6 part of light stabilizer, 0.4 part of antioxidant；The ASA resin melting means be 4g/10min (220 DEG C, 10kg), tensile strength >=
50Mpa, impact strength >=400J/m.The AS resin, melting means are 6g/10min (220 DEG C, 10kg), tensile strength >=65Mpa.
The light stabilizer includes light stabilizer UV-944, light stabilizer UV-622.The antioxidant includes antioxidant 1010, antioxidant
1076, irgasfos 168, antioxidant 1098.
In the preparation process of ASA synthetic resin watt:
S1, polyvinyl chloride resin, CPE, attapulgite modified, flyash, calcium carbonate, compound stabilizer, lubricant are weighed according to the ratio
Equal materials, are put into batch mixer, are stirred mixing 60min, obtain material A；
S2, materials such as ASA, AS, under the conditions of 96 DEG C, dry 6h；
S3, the materials such as ASA resin, AS resin, EBS, EVA, light stabilizer, antioxidant are weighed according to the ratio, be put into batch mixer
In, it is stirred mixing 40min, obtains material B；
S4, material A is added to main extruder, co-extrusion extruder, together extrusion molding is added in material B.Wherein main extruder
Temperature is at 175 DEG C, and for coextruder temperature at 195 DEG C, head temperature obtains ASA synthetic resin watt at 240 DEG C.
In the preparation process for having the function of VOC light degradation ASA synthetic resin watt: in the extrusion of ASA synthetic resin watt
By powder spray in forming process, particulate composite is attached to ASA synthetic resin watt surface, cooling and shaping is had
There is VOC light degradation function ASA synthetic resin watt.
Embodiment 5
One kind having the function of VOC light degradation ASA synthetic resin watt, including ASA synthetic resin watt, and is sprayed on the ASA
The particulate composite on synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material, montmorillonite/TIO2Composite material passes through following technique
Preparation:
(1) 1kg montmorillonite is weighed, pours into the sodium chloride solution that 100L concentration is 1%, is stirred 10min, stand
For 24 hours, filter, be washed with distilled water for several times, the solid after washing in 100L distilled water be uniformly mixed obtain 1% sodium base illiteracy
De- soil mixed liquor.
(2), the titanium tetrachloride of 350mL will be added in the hydrochloric acid solution of 18L1mol/L, stir 1h, obtain pale yellow transparent
Titanium dioxide acidic sol.
(3) 12mL titanium dioxide acidic sol is added in 1% sodium-based montmorillonite mixed liquor and is stirred evenly, in temperature 60
DEG C stand 40h, filtering, distill water washing after, 80 DEG C drying.
(4) obtained product is put into Muffle furnace, in 400 DEG C of calcination 2h of temperature, obtains montmorillonite/TIO2Composite wood
Material.
One kind having the function of that VOC light degradation ASA synthetic resin watt, the raw material on surface layer include: ASA resin 65 by weight
Part, 25 parts of AS resin, 0.5 part of EBS, 9 parts of EVA, 0.3 part of light stabilizer, 0.2 part of antioxidant.The raw material of sandwich layer is by weight
It include: 70 parts of polyvinyl chloride resin, CPE10 parts, 5 parts attapulgite modified, 5 parts of flyash, 5 parts of calcium carbonate, 4.5 parts of compound stabilizer,
0.5 part of lubricant.
Wherein, attapulgite modified to be prepared using following steps: attapulgite to be placed in high-speed mixer, first low speed opens
Dynamic, then high-speed stirred 5min, keeps attapulgite loose；Use a small amount of ethyl alcohol as solvent by KH-570 dissolved dilution, KH-570
Dosage is the 1% of attapulgite quality, is added in high-speed mixer with Sprayable, and 30min is stirred；By modified concave convex rod
Soil obtains attapulgite modified in 105 DEG C of dryings of temperature.
A kind of preparation process with VOC light degradation ASA synthetic resin watt, includes the following steps:
(1) polyvinyl chloride resin, CPE, attapulgite modified, flyash, calcium carbonate, compound stabilizer, lubricant are weighed according to the ratio
It is put into batch mixer, is stirred 30min, obtain material A；
(2) ASA, AS in 90 DEG C of temperature dry 5h；
(3) ASA resin by step (2) after dry, AS resin and EBS, EVA, light stabilizer, antioxidant are put into according to the ratio
In batch mixer, it is stirred 30min, obtains material B；
(4) material A is added main extruder, material B is added co-extrusion extruder, extrusion molding together, wherein main extruder
Temperature is at 170 DEG C, and for coextruder temperature at 192 DEG C, head temperature obtains ASA synthetic resin watt at 200 DEG C；
(5) at die head out, using powder spray coating device, montmorillonite/TIO2Composite material is sprayed on ASA synthetic resin
Watt surface, cooling and shaping obtain having the function of VOC light degradation ASA synthetic resin watt.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. one kind has the function of VOC light degradation ASA synthetic resin watt, which is characterized in that including ASA synthetic resin watt, and spraying
Particulate composite on the ASA synthetic resin watt surface；
The particulate composite is montmorillonite/TIO2Composite material.
2. according to claim 1 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that described cover takes off
Soil/TIO2Composite material is prepared using following technique:
A, montmorillonite is sent into sodium chloride solution, is stirred, stood, filtered, washing is added distilled water and is uniformly mixed, obtains sodium
Base montmorillonite mixed liquor；
B, titanium tetrachloride is added into hydrochloric acid, stirs, obtains the titanium dioxide acidic sol of pale yellow transparent；
C, titanium dioxide acidic sol is added in sodium-based montmorillonite mixed liquor and is stirred, stood, filtered, washed, drying, in temperature
350-480 DEG C of calcining, obtains montmorillonite/TIO2Composite material.
3. according to claim 1 or 2 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that the ASA
Synthetic resin watt includes sandwich layer, and is coated on the surface layer of core layer surface；
Preferably, the raw material of the sandwich layer by weight include: 60-80 parts of polyvinyl chloride resin, it is 4-10 parts of CPE, attapulgite modified
4-10 parts, 5-15 parts of flyash, 4-8 parts of calcium carbonate, 6-8 parts of compound stabilizer, 0.5-0.8 parts of lubricant；
The raw material on the surface layer includes: 50-75 parts of ASA resin, 25-40 parts of AS resin, 0.3-0.5 parts of EBS, EVA by weight
5-10 parts, 0.4-0.6 parts of light stabilizer, 0.2-0.4 parts of antioxidant；
Preferably, in the preparation process of ASA synthetic resin watt, sandwich layer and surface layer are obtained into ASA synthetic resin by coextrusion mold
Watt；It is further preferred that in the preparation process of ASA synthetic resin watt:
S1, according to the ratio by polyvinyl chloride resin, CPE, attapulgite modified, flyash, calcium carbonate, compound stabilizer, mix lubricant,
Obtain material A；
S2, ASA resin, AS resin are dried；
S3, ASA resin, the AS resin after drying mixed with EBS, EVA, light stabilizer, antioxidant according to the ratio, obtains material B；
S4, material A is added to main extruder, material B is added co-extrusion extruder, extrusion molding together, wherein main extruder temperature
It is 165-175 DEG C, for coextruder temperature at 190-195 DEG C, head temperature obtains ASA synthetic resin watt at 190-210 DEG C.
4. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that the original on surface layer
In material, the ASA resin, melting means 4-8g/10min, tensile strength >=50Mpa, impact strength >=400J/m.
5. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that the original on surface layer
In material, the AS resin, melting means 6-15g/10min, tensile strength >=65Mpa.
6. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that the original on surface layer
In material, the light stabilizer is light stabilizer UV-944, light stabilizer UV-622, light stabilizer UV-770 and light stabilizer UV-
2020 at least one.
7. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that the original on surface layer
In material, the antioxidant is at least one of antioxidant 1010, antioxidant 1076, irgasfos 168, antioxidant 1098.
8. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that in the original of sandwich layer
In material, in the attapulgite modified preparation process: attapulgite is placed in blender stirring, obtains loose attapulgite,
Ethyl alcohol is used, by KH-570 dissolved dilution, to be filled in the blender of loose attapulgite, stir with Sprayable addition as solvent
It mixes, it is dry, it obtains attapulgite modified.
9. according to claim 3 have the function of VOC light degradation ASA synthetic resin watt, which is characterized in that in the original of sandwich layer
In material, the compound stabilizer be alkali formula lead salt, metallic soap, organotin, epoxide, phosphite ester and polyalcohol at least
Two kinds.
10. a kind of -9 described in any item preparation works with VOC light degradation ASA synthetic resin watt according to claim 1
Skill, which comprises the steps of: by spraying during the extrusion molding of ASA synthetic resin watt, powder is compound
Material is attached to ASA synthetic resin watt surface, and cooling and shaping obtains having the function of VOC light degradation ASA synthetic resin watt.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101069846A (en) * | 2006-05-09 | 2007-11-14 | 北京化工大学 | Preparation of high-activity silver-carried/titanium dioxide pillar braced montomorillonite composite nano catalyst |
| CN101407617A (en) * | 2008-11-21 | 2009-04-15 | 上海锦湖日丽塑料有限公司 | High-performance extrusion grade ASA resin composition and preparation thereof |
| CN101876193A (en) * | 2010-06-09 | 2010-11-03 | 安徽鸿路钢结构(集团)股份有限公司 | Double-layer resin glazed tile |
| CN106188940A (en) * | 2016-07-15 | 2016-12-07 | 无锡市天聚科技有限公司 | A kind of novel polrvinyl chloride (PVC) watt and preparation method thereof |
| CN107686608A (en) * | 2017-08-11 | 2018-02-13 | 秦皇岛市地维建材有限公司 | Hollow glass micropearl blending and modifying PVB/ABS resin tiles and preparation method thereof |
| CN108299760A (en) * | 2017-09-29 | 2018-07-20 | 吉林中科金盛新材料科技发展有限公司 | Photocatalyst and acid induction double-unit system remove the environment-friendly polyvinyl chloride foam wood/plastic composite material and preparation method thereof of VOC |
| CN109627622A (en) * | 2018-12-04 | 2019-04-16 | 广东天雄新材料科技股份有限公司 | Superelevation flows weather-proof ASA co-extrusion material of high-impact and preparation method thereof |
-
2019
- 2019-05-28 CN CN201910451048.7A patent/CN110195492A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101069846A (en) * | 2006-05-09 | 2007-11-14 | 北京化工大学 | Preparation of high-activity silver-carried/titanium dioxide pillar braced montomorillonite composite nano catalyst |
| CN101407617A (en) * | 2008-11-21 | 2009-04-15 | 上海锦湖日丽塑料有限公司 | High-performance extrusion grade ASA resin composition and preparation thereof |
| CN101876193A (en) * | 2010-06-09 | 2010-11-03 | 安徽鸿路钢结构(集团)股份有限公司 | Double-layer resin glazed tile |
| CN106188940A (en) * | 2016-07-15 | 2016-12-07 | 无锡市天聚科技有限公司 | A kind of novel polrvinyl chloride (PVC) watt and preparation method thereof |
| CN107686608A (en) * | 2017-08-11 | 2018-02-13 | 秦皇岛市地维建材有限公司 | Hollow glass micropearl blending and modifying PVB/ABS resin tiles and preparation method thereof |
| CN108299760A (en) * | 2017-09-29 | 2018-07-20 | 吉林中科金盛新材料科技发展有限公司 | Photocatalyst and acid induction double-unit system remove the environment-friendly polyvinyl chloride foam wood/plastic composite material and preparation method thereof of VOC |
| CN109627622A (en) * | 2018-12-04 | 2019-04-16 | 广东天雄新材料科技股份有限公司 | Superelevation flows weather-proof ASA co-extrusion material of high-impact and preparation method thereof |
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Application publication date: 20190903 |