CN110183152A - A kind of Phosphorus Slag rubber brick and preparation method thereof - Google Patents
A kind of Phosphorus Slag rubber brick and preparation method thereof Download PDFInfo
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- CN110183152A CN110183152A CN201910369353.1A CN201910369353A CN110183152A CN 110183152 A CN110183152 A CN 110183152A CN 201910369353 A CN201910369353 A CN 201910369353A CN 110183152 A CN110183152 A CN 110183152A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/0481—Other specific industrial waste materials not provided for elsewhere in C04B18/00
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
The invention belongs to the field of building materials more particularly to a kind of Phosphorus Slag rubber brick and preparation method thereof.The present invention is using thin rubbery granule and high temperature resistant cement DTA as upper rubber layer base-material；Using thin rubbery granule and Phosphorus Slag as middle layer articulamentum base-material；Using Phosphorus Slag, cement, water as subjacent backing layer aggregate；Using cement, sand, water as lower layer contacts layer base-material, the comprehensive utilization of industrial residue is realized, opens new approaches for the disposition of Phosphorus Slag, scrap rubber, and it is low in cost, the application effect of product is effectively improved, reduces maintenance cost, and rubber brick of the invention divides multilayered structure to prepare, with good permeable effect, ponding layer will not be generated, integral strength is high, and durability is preferable, cementability is preferable, not easily to fall off after laying.
Description
Technical field
The invention belongs to the field of building materials more particularly to a kind of Phosphorus Slag rubber brick and preparation method thereof.
Background technique
Phosphorus Slag is the waste residue of yellow phosphorus industry discharge, is granular substance of the clinker during Electric Cooker phosphorus after water quenching,
Usual is in canescence, light, mostly vitreum, and granularity is smaller, between generally 0.5-5mm, has porous structure.Main component
It is noncrystalline pseudowollastonite, it is similar to natural wollastonite property, wherein CaO40% or so also contains containing SiO240% or so
F, the chemical components such as Al2O3, Fe2O3, MgO, K2O, Na2O, P2O5, SO3, these compositions with complicated silicide, phosphide,
The forms such as fluoride exist.Carbon is often mixed in phosphorus ore slag.Phosphorus Slag is in neutrality.
Yellow phosphorus is mainly used in production high-concentration phosphoric acid and high concentration phosphate fertilizer.Phosphorus is the indispensable element of biology, China
It is large agricultural country, phosphate industry amount is huge.China's phosphate rock resource occupies second place of the world, and production of phosphate fertilizer ranks first in the world, phosphorus work
Industry plays highly important effect in national economy.Phosphorus chemical industry produces 1 ton of yellow phosphorus, just generates 8-10 tons or so of yellow phosphorus
Slag, it is possible thereby to calculate that waste sludge discharge amount is big.The phosphorus ore slag that phosphorus chemical industry discharges every year largely fails to be used effectively.Phosphorus ore
It can cause environmental pollution in slag containing titanium pigment compound, fluoride etc., so can only be spacious in mountain depression according to Law on Environmental Protection
It is stacked in the fixed-point set of Yezhong, this processing, had both occupied valuable soil, also water source is polluted.
Phosphorus Slag is mainly as cement admixture and rudimentary phosphate fertilizer at present, but dosage is few, and dosage is also extremely unstable, also
Production Wall or floor tile, sanitary ceramics, insulation fibre are used it to, but popularity rate is still inadequate, can not largely digest Phosphorus Slag, Phosphorus Slag
Sufficient utilization is not yet received, and with the continuous development of national phosphorus production enterprise, the Phosphorus Slag of generation is also more and more,
The disposition of Phosphorus Slag is to perplex the problem of each enterprise.
Currently, the processing of waste old is also one of the serious problems that people face.The degradation property of rubber is poor, long-term
It is unable to natural degradation, a large amount of waste old not only causes potential threat to natural environment, wastes resource.It is same with this
When, as the usage amount of plastic products increases, the generation of a large amount of waste plastics also causes serious harm to environment.
Traditional rubber brick is only with the auxiliary agent and adhesive of waste rubber grain addition pollution, and pressing is made, because passing through
Simple bonding pressing is made, between combine loosely, service life is shorter, while the auxiliary agent and adhesive that pollute are to environment
Cause secondary pollution, the corrosion and ageing of rubber also easy environment, intensity is relatively low.
Therefore, one kind is found using Phosphorus Slag and waste rubber as primary raw material, can make full use of Phosphorus Slag and discarded rubber
Glue, and water penetration is preferable, will not forming face table ponding layer, also rubber brick and preparation method thereof not easily to fall off is when business
It is anxious.
Summary of the invention
In order to solve the above technical problems existing in the prior art, the present invention provides a kind of Phosphorus Slag rubber brick and its system
Preparation Method is achieved particular by following art scheme:
A kind of method of Phosphorus Slag rubber brick, includes the following steps:
(1) upper rubber layer base-material is produced: by thin rubbery granule and high temperature resistant cement DTA according to (9-11): 1 weight
Than being uniformly mixing to obtain upper rubber layer base-material after mixing；
(2) articulamentum base-material in middle layer is produced: by thin rubbery granule and Phosphorus Slag according to (2-3): 1 ratio is mixed
It closes, obtains middle layer articulamentum base-material after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 15-20%, water 5-10%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 35-45%, sand
Sub- 35-45%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keep surfacing flawless, corner do not have extra base-material to get.
Preferably, the Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.The Phosphorus Slag of this size can improve brick body
Porosity reduces seeping phenomenon and occurs.
Preferably, the cement is the cement of label P.O 42.5.The cement of label can improve subjacent backing layer aggregate
Adhesive strength is more suitble to this method.
Preferably, the sand is fine sand, middle sand or the two mixing.Fine sand, the granularity of middle sand are more appropriate, gained
Lower layer contacts layer intensity and cementability it is all preferable, it is not easily to fall off.
Preferably, the step (5), control upper rubber layer account for the 15-20% of brick body overall thickness, and middle layer articulamentum accounts for brick
The 5-10% of body overall thickness, subjacent backing layer account for the 65-75% of brick body overall thickness, and lower layer contacts layer accounts for the 5- of brick body overall thickness
10%.The thickness of each layer is relatively mild at this time, can give full play to the effect of each layer, makes into brick good water permeability, and integral strength is high,
Durability is preferable, and compatible degree is also preferable between each layer.
Preferably, the step (5) is compacted at 120-160 DEG C with equipment after middle layer articulamentum base-material is added.Into one
Step is preferred, after being compacted at 120-160 DEG C with equipment, is cooled to room temperature, and stands 30-50min.The temperature is compacted and cools down quiet
Setting can be such that middle layer articulamentum sufficiently merges with subjacent backing layer, avoid the occurrence of separation.
Preferably, the step (5) is compacted at 80-100 DEG C with equipment after upper rubber layer base-material is added.The temperature
Compacting can be such that upper rubber layer sufficiently merges with middle layer articulamentum, avoid the occurrence of separation.
Preferably, the step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 600-900Kg/m.This
When finished surface density it is preferable, durability is higher, and will not influence too much to water permeability.
Preferably, the step (5), after upper rubber layer base-material is added and is compacted with equipment, in 10-40 DEG C of temperature, phase
To natural curing 15-25d in the environment of humidity 60-80%.
Compared with prior art, the technical effect of the invention is embodied in:
(1) present invention does underlayment using Phosphorus Slag and prepares rubber brick, realizes the comprehensive utilization of industrial residue, is yellow phosphorus
The disposition of slag opens new approaches.
(2) rubber brick of the invention divides multilayered structure to prepare, and has good permeable effect, will not generate ponding layer, and
And integral strength is high, durability is also preferable.
(3) present invention prepares rubber brick using Phosphorus Slag and rubber grain, low in cost, effectively improves the application effect of product
Fruit reduces maintenance cost.
(4) cementability is preferable when the laying of the invention at brick lower layer contacts layer, not easily to fall off after laying.
Specific embodiment
It is limited below with reference to specific embodiment technical solution of the present invention is further, but claimed
Range is not only limited to made description.
Embodiment 1
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 10:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2.5:1,
Middle layer articulamentum base-material is obtained after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 17.5%, water 7.5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 40%, sand
40%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keeps surfacing flawless, and corner does not have extra base-material, and control upper rubber layer accounts for brick
The 17.5% of body overall thickness, middle layer articulamentum account for the 7.5% of brick body overall thickness, and subjacent backing layer accounts for the 70% of brick body overall thickness,
Lower layer contacts layer account for the 5% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 750Kg/m.
Embodiment 2
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 9:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2:1,
Middle layer articulamentum base-material is obtained in blender after uniform stirring；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 20%, water 5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 35%, sand
45%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keeps surfacing flawless, and corner does not have extra base-material, and control upper rubber layer accounts for brick
The 15% of body overall thickness, middle layer articulamentum account for the 5% of brick body overall thickness, and subjacent backing layer accounts for the 75% of brick body overall thickness, bottom
Contact layer account for the 5% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 900Kg/m.
Embodiment 3
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 11:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 3:1,
Middle layer articulamentum base-material is obtained in blender after uniform stirring；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 15%, water 10%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 45%, sand
35%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keeps surfacing flawless, and corner does not have extra base-material, and control upper rubber layer accounts for brick
The 20% of body overall thickness, middle layer articulamentum account for the 5% of brick body overall thickness, and subjacent backing layer accounts for the 65% of brick body overall thickness, bottom
Contact layer account for the 10% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 900Kg/m.
Embodiment 4
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 10:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2.5:1,
Middle layer articulamentum base-material is obtained after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 17.5%, water 7.5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 40%, sand
40%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keeps surfacing flawless, and corner does not have extra base-material, and control upper rubber layer accounts for brick
The 15% of body overall thickness, middle layer articulamentum account for the 10% of brick body overall thickness, and subjacent backing layer accounts for the 70% of brick body overall thickness, bottom
Contact layer account for the 5% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 750Kg/m.
Embodiment 5
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 10:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2.5:1,
Middle layer articulamentum base-material is obtained after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 17.5%, water 7.5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 40%, sand
40%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted at 140 DEG C with equipment, keeps surfacing flawless, corner does not have extra base
Material, is cooled to room temperature, and stands 40min；Upper rubber layer base-material is added, is compacted with equipment, keeps surfacing flawless, corner
There is no extra base-material, control upper rubber layer accounts for the 17.5% of brick body overall thickness, and middle layer articulamentum accounts for brick body overall thickness
7.5%, subjacent backing layer accounts for the 70% of brick body overall thickness, lower layer contacts layer account for the 5% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 750Kg/m.
Embodiment 6
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 10:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2.5:1,
Middle layer articulamentum base-material is obtained after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 17.5%, water 7.5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 40%, sand
40%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material is compacted at 90 DEG C with equipment, keeps surfacing flawless, and corner does not have extra base-material, controls upper layer rubber
Glue-line accounts for the 17.5% of brick body overall thickness, and middle layer articulamentum accounts for the 7.5% of brick body overall thickness, and subjacent backing layer accounts for brick body overall thickness
70%, lower layer contacts layer account for the 5% of brick body overall thickness to get.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 750Kg/m.
Embodiment 7
(1) upper rubber layer base-material is produced: thin rubbery granule and high temperature resistant cement DTA mixed according to the weight ratio of 10:1
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: thin rubbery granule and Phosphorus Slag mixed according to the ratio of 2.5:1,
Middle layer articulamentum base-material is obtained after uniform stirring in blender；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water mixed according to following ratio: Phosphorus Slag 75%,
Cement 17.5%, water 7.5%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 40%, sand
40%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, surfacing flawless, side are kept
Angle does not have extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra bone
Material；Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer is added
Rubber layer base-material, is compacted with equipment, keeps surfacing flawless, and corner does not have extra base-material, and control upper rubber layer accounts for brick
The 17.5% of body overall thickness, middle layer articulamentum account for the 7.5% of brick body overall thickness, and subjacent backing layer accounts for the 70% of brick body overall thickness,
Lower layer contacts layer accounts for the 5% of brick body overall thickness, natural curing 20d in the environment of 25-35 DEG C of temperature, relative humidity 60-80%,
To obtain the final product.
The Phosphorus Slag is the Phosphorus Slag of partial size ratio 2.35mm-4mm.
The cement is the cement of label P.O 42.5.
The sand is fine sand, the mixing of middle sand equal proportion.
The step (5), it is therein to be compacted with equipment, it is to be pressed onto finished surface density: 750Kg/m.
Comparative example 1
It is carried out according to the embodiment 1 of patent application CN200810058211.5.
The rubber brick that embodiment 1-7, comparative example 1 obtain is compared with commercially available rubber brick:
By upper data it is found that the yellow phosphorus rubber brick that the present invention obtains, have with good compression deformation rate and infiltration coefficient,
And compression strength, flexural strength are preferable, and make full use of Phosphorus Slag, low in cost, can be reduced environmental pollution.
Finally it is pointed out that above embodiments are only the more representational examples of the present invention.Obviously, technology of the invention
Scheme is not limited to above-described embodiment, and acceptable there are many deformations.Those skilled in the art can be from disclosed by the invention
All deformations that content is directly exported or associated, are considered as protection scope of the present invention.
Claims (10)
1. a kind of method of Phosphorus Slag rubber brick, which comprises the steps of:
(1) upper rubber layer base-material is produced: by thin rubbery granule and high temperature resistant cement DTA according to (9-11): 1 weight ratio is mixed
Upper rubber layer base-material is uniformly mixing to obtain after conjunction；
(2) articulamentum base-material in middle layer is produced: by thin rubbery granule and Phosphorus Slag according to (2-3): 1 ratio mixes,
Middle layer articulamentum base-material is obtained in blender after uniform stirring；
(3) subjacent backing layer aggregate is produced: Phosphorus Slag, cement, water being mixed according to following ratio: Phosphorus Slag 75%, cement
15-20%, water 5-10%, and the uniform stirring in blender form rubber brick lower layer aggregate；
(4) lower layer contacts layer base-material is produced: cement, sand, water being mixed according to following ratio: cement 35-45%, sand
35-45%, water 20%；
(5) prepared by brick body: lower layer contacts layer base-material being evenly arranged, is compacted with equipment, keeps surfacing flawless, corner does not have
There is extra base-material；Subjacent backing layer aggregate is added to be compacted with equipment, keeps surfacing flawless, corner does not have extra aggregate；
Middle layer articulamentum base-material is added, is compacted with equipment, keeps surfacing flawless, corner does not have extra base-material；Upper layer rubber is added
Glue-line base-material, is compacted with equipment, keep surfacing flawless, corner do not have extra base-material to get.
2. the method according to claim 1 for preparing plate using building waste, which is characterized in that the Phosphorus Slag is
The Phosphorus Slag of partial size ratio 2.35mm-4mm.
3. the method according to claim 1 for preparing plate using building waste, which is characterized in that the cement is mark
The cement of number P.O42.5.
4. the method according to claim 1 for preparing plate using building waste, which is characterized in that the sand is thin
Sand, middle sand or the two mixing.
5. the method according to claim 1 for preparing plate using building waste, which is characterized in that the step (5), control
Upper rubber layer processed accounts for the 15-20% of brick body overall thickness, and middle layer articulamentum accounts for the 5-10% of brick body overall thickness, and subjacent backing layer accounts for
The 65-75% of brick body overall thickness, lower layer contacts layer account for the 5-10% of brick body overall thickness.
6. the method according to claim 1 for preparing plate using building waste, which is characterized in that the step (5) adds
After entering middle layer articulamentum base-material, it is compacted at 120-160 DEG C with equipment.
7. the method according to claim 6 for preparing plate using building waste, which is characterized in that the step (5) adds
It after entering middle layer articulamentum base-material and being compacted at 120-160 DEG C with equipment, is cooled to room temperature, stands 30-50min.
8. the method according to claim 1 for preparing plate using building waste, which is characterized in that the step (5) adds
After entering upper rubber layer base-material, it is compacted at 80-100 DEG C with equipment.
9. the method according to claim 1 for preparing plate using building waste, which is characterized in that the step (5),
In be compacted with equipment, be to be pressed onto finished surface density: 600-900Kg/m.
10. the method according to claim 1 for preparing plate using building waste, which is characterized in that the step (5),
After upper rubber layer base-material is added and is compacted with equipment, supported naturally in the environment of 10-40 DEG C of temperature, relative humidity 60-80%
Protect 15-25d.
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| CN201910369353.1A CN110183152A (en) | 2019-05-05 | 2019-05-05 | A kind of Phosphorus Slag rubber brick and preparation method thereof |
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| CN201910369353.1A CN110183152A (en) | 2019-05-05 | 2019-05-05 | A kind of Phosphorus Slag rubber brick and preparation method thereof |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101289310A (en) * | 2008-03-24 | 2008-10-22 | 昆明理工大学 | Low-temperature ceramic permeable bricks and production method thereof |
| CN101774217A (en) * | 2010-01-13 | 2010-07-14 | 贵阳高新伟创麟丰科技实业有限公司 | Preparation method of permeable brick by using phosphorous slag |
| CN102173701A (en) * | 2010-12-28 | 2011-09-07 | 刘丽华 | Non-autoclaved waste residue sand lime brick and preparation method thereof |
| CN102249616A (en) * | 2011-06-10 | 2011-11-23 | 晋宁锐达新型建材有限公司 | Method for producing porous floor tile by using industrial by-product phosphorous slag |
| CN102584154A (en) * | 2011-01-07 | 2012-07-18 | 郭东京 | Concrete block brick mixed with industrial waste residue and manufacture method |
| CN204676385U (en) * | 2014-11-27 | 2015-09-30 | 武汉理工大学 | A kind of high durable environmental and ecological water-permeable brick |
| CN106830834A (en) * | 2017-01-24 | 2017-06-13 | 葛兆明 | Cement polymer base high-performance concrete permeable pavior brick and its manufacture method |
| CN107761500A (en) * | 2017-10-30 | 2018-03-06 | 重庆亲禾建科建材有限公司 | A kind of elastic water-permeable brick |
| CN207210882U (en) * | 2017-08-21 | 2018-04-10 | 云南沃德艾克生态环境技术有限公司 | One kind filtering absorption water-permeable brick |
-
2019
- 2019-05-05 CN CN201910369353.1A patent/CN110183152A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101289310A (en) * | 2008-03-24 | 2008-10-22 | 昆明理工大学 | Low-temperature ceramic permeable bricks and production method thereof |
| CN101774217A (en) * | 2010-01-13 | 2010-07-14 | 贵阳高新伟创麟丰科技实业有限公司 | Preparation method of permeable brick by using phosphorous slag |
| CN102173701A (en) * | 2010-12-28 | 2011-09-07 | 刘丽华 | Non-autoclaved waste residue sand lime brick and preparation method thereof |
| CN102584154A (en) * | 2011-01-07 | 2012-07-18 | 郭东京 | Concrete block brick mixed with industrial waste residue and manufacture method |
| CN102249616A (en) * | 2011-06-10 | 2011-11-23 | 晋宁锐达新型建材有限公司 | Method for producing porous floor tile by using industrial by-product phosphorous slag |
| CN204676385U (en) * | 2014-11-27 | 2015-09-30 | 武汉理工大学 | A kind of high durable environmental and ecological water-permeable brick |
| CN106830834A (en) * | 2017-01-24 | 2017-06-13 | 葛兆明 | Cement polymer base high-performance concrete permeable pavior brick and its manufacture method |
| CN207210882U (en) * | 2017-08-21 | 2018-04-10 | 云南沃德艾克生态环境技术有限公司 | One kind filtering absorption water-permeable brick |
| CN107761500A (en) * | 2017-10-30 | 2018-03-06 | 重庆亲禾建科建材有限公司 | A kind of elastic water-permeable brick |
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