CN110183114A - A kind of anti-reflection coated glass and preparation method thereof - Google Patents

A kind of anti-reflection coated glass and preparation method thereof Download PDF

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Publication number
CN110183114A
CN110183114A CN201910362755.9A CN201910362755A CN110183114A CN 110183114 A CN110183114 A CN 110183114A CN 201910362755 A CN201910362755 A CN 201910362755A CN 110183114 A CN110183114 A CN 110183114A
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CN
China
Prior art keywords
glass
layer
reflection coated
preparation
base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910362755.9A
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Chinese (zh)
Inventor
韩君晖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAICANG YAOHUA GLASS CO Ltd
Original Assignee
TAICANG YAOHUA GLASS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAICANG YAOHUA GLASS CO Ltd filed Critical TAICANG YAOHUA GLASS CO Ltd
Priority to CN201910362755.9A priority Critical patent/CN110183114A/en
Publication of CN110183114A publication Critical patent/CN110183114A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/002General methods for coating; Devices therefor for flat glass, e.g. float glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties

Abstract

The upper surface of a kind of anti-reflection coated glass, including base's glass, base's glass is successively arranged antireflection layer, puigging, thermal baffle layer, decoration layer, rough reflective layer and wear-resistant layer according to sequence from top to bottom;A kind of preparation method of anti-reflection coated glass, comprising the following steps: 1) prepare coated solution;2) it cleans;3) it preheats;4) plated film;5) it dries;6) solidify;7) glass after curing process is cooling.Anti-reflection coated glass of the present invention and preparation method thereof, structure design is simple, reasonable, securely and reliably, long service life, low in cost, easy to clean, appearance looks elegant reduce electronic product outer reflected light indoors, reduce electric quantity consumption, user experience is substantially improved, is applied in photovoltaic module, hence it is evident that improve the power of solar cell, for large public building or have in the building of specific function, reduces reflecting rate.

Description

A kind of anti-reflection coated glass and preparation method thereof
Technical field
The invention belongs to energy conservation and new energy technical field of material, in particular to a kind of anti-reflection coated glass. The invention further relates to a kind of preparation methods of anti-reflection coated glass.
Background technique
Coated glass (Reflectiveglass) is also referred to as reflecting glass, be glass surface coating one or more layers metal, Alloy or metal compound film meet certain particular requirement to change the optical property of glass.Coated glass presses product not Same characteristic can be divided into following a few classes: heat-reflecting glass, low emissivity glass (Low-E), electropane etc..
Antireflective technology realizes that single layer membrane technology is the most normal with porous sio2 film according to light refraction principle See.By the colloidal sol of existing porous sio2, on the glass surface of coating, the heat treatment technics of glass is recycled to solidify film layer, shape At antireflection film.
Summary of the invention
Goal of the invention: the object of the present invention is to provide a kind of anti-reflection coated glass and preparation method thereof, structure design letters Single, rationally, long service life, low in cost, easy to clean, appearance looks elegant reduce electronic product outer reflected light indoors, reduce User experience is substantially improved in electric quantity consumption.
Technical solution: described the present invention provides a kind of anti-reflection coated glass and preparation method thereof, including base's glass The upper surface of base's glass is successively arranged antireflection layer, puigging, thermal baffle layer, decorative pattern according to sequence from top to bottom Layer, rough reflective layer and wear-resistant layer.Antireflection layer and rough reflective layer are set, glass is made to have the function of good antireflective.If Puigging and thermal baffle layer are set, glass is made to have the function of sound insulation and heat insulating function.Decoration layer is set, keeps glass beautiful with dazzling Decorative effect.Anti-reflection coated glass of the invention and preparation method thereof, structure design is simple, reasonable, securely and reliably, uses Service life is long, low in cost, easy to clean, appearance looks elegant, reduces electronic product outer reflected light indoors, reduces electric quantity consumption, greatly Width promotes user experience, is applied in photovoltaic module, hence it is evident that the power for improving solar cell for large public building or has spy In the building of distinguished service energy, reflecting rate is reduced.
Further, above-mentioned anti-reflection coated glass, the antireflection layer are set as silicon dioxide layer, the wear-resistant layer It is set as graphite linings.Graphite linings are set, so that glass is had the function of anti-scratch, glass is more durable.
Further, above-mentioned anti-reflection coated glass, the puigging use sound-proof material.
The present invention also provides a kind of preparation methods of anti-reflection coated glass, comprising the following steps:
1) coated solution is prepared;
2) it cleans: base's glass being cut using cleaning machine, edging, cleaning, be dried after cleaning;
3) it preheats: the pre-heat treatment being carried out to the base's glass cleaned, base's glass temperature is made to be maintained at normal temperature state;
4) coated solution: being uniformly plated on base's glass by plated film using coating process, and the coating process includes spraying, roller It applies, the coating process of showering;
5) it dries: base's glass after plated film being put into dryer and is dried;
6) solidify: 2-3.2 μm of infrared waves just under conditions, to film layer solidification, curing time 20-60s, solidification temperature is 220-380℃;
7) glass after curing process is cooling.
Further, the preparation method of above-mentioned anti-reflection coated glass, the coated solution in the step 1) are porous Silicon dioxide gel.
Further, the preparation method of above-mentioned anti-reflection coated glass, in the cleaning process of the step 2, base's glass Glass until cleaning to glass without soft flocks, it is dustless, without particle.
Further, the preparation method of above-mentioned anti-reflection coated glass, the pre-heat treatment temperature in the step 3) is extremely 20-50℃。
Further, the preparation method of above-mentioned anti-reflection coated glass, the step 4) coating film treatment process Ying Heng It is carried out in the very wet confined space of temperature, the constant temperature is very wet to refer to that temperature is no more than 40 DEG C, and relative humidity is lower than 65%.
Further, the preparation method of above-mentioned anti-reflection coated glass, cooling treatment is using air-cooled in the step 7) Mode, cooling time 2-5min.
Above-mentioned technical proposal can be seen that the invention has the following beneficial effects: antireflective plated film glass of the present invention Glass and preparation method thereof, structure design is simple, reasonable, and securely and reliably, long service life, low in cost, easy to clean, appearance is beautiful It sees, reduces electronic product outer reflected light indoors, reduce electric quantity consumption, user experience is substantially improved, be applied to photovoltaic module In, hence it is evident that the power for improving solar cell for large public building or has in the building of specific function, reduces reflecting rate, It has great popularization value.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of anti-reflection coated glass of the present invention.
In figure: base's glass 1, puigging 3, thermal baffle layer 4, decoration layer 5, rough reflective layer 6, resists antireflection layer 2 Grind layer 7.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
Embodiment
Anti-reflection coated glass as shown in Figure 1 and preparation method thereof, including including base's glass 1, base's glass 1 Upper surface be successively arranged antireflection layer 2, puigging 3, thermal baffle layer 4, decoration layer 5, thick according to sequence from top to bottom Rough reflecting layer 6 and wear-resistant layer 7.The antireflection layer 2 is set as silicon dioxide layer.The puigging 3 uses sound-proof material, described anti- Mill layer 7 is set as graphite linings.Antireflection layer and rough reflective layer are set, glass is made to have the function of good antireflective.Setting every Sound-absorbing layer and thermal baffle layer, make glass have the function of sound insulation and heat insulating function.Decoration layer is set, there is glass and dazzle beautiful dress Adorn effect.Graphite linings are set, so that glass is had the function of anti-scratch, glass is more durable.
A kind of preparation method of anti-reflection coated glass of the present invention, comprising the following steps:
1) coated solution is prepared;
2) it cleans: base's glass 1 being cut using cleaning machine, edging, cleaning, be dried after cleaning;
3) it preheats: the pre-heat treatment being carried out to the base's glass 1 cleaned, 1 temperature of base's glass is made to be maintained at normal temperature state;
4) coated solution: being uniformly plated on base's glass 1 by plated film using coating process, and the coating process includes spraying, roller It applies, the coating process of showering;
5) it dries: base's glass 1 after plated film being put into dryer and is dried;
6) solidify: 2-3.2 μm of infrared waves just under conditions, to film layer solidification, curing time 20-60s, solidification temperature is 220-380℃;
7) glass after curing process is cooling.
Wherein, above-mentioned steps 1) in coated solution be porous silicon dioxide gel.
Above-mentioned steps 2) cleaning process in, base's glass until cleaning to glass without soft flocks, it is dustless, without particle.
Above-mentioned steps 3) in the pre-heat treatment temperature to 20-50 DEG C.
Above-mentioned steps 4) coating film treatment process should carry out in the very wet confined space of constant temperature, and the constant temperature is very wet to refer to temperature Degree is, no more than 40 DEG C, relative humidity is lower than 65%.
Above-mentioned steps 7) in cooling treatment use air-cooled mode, cooling time 2-5min.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as of the invention Protection scope.

Claims (9)

1. a kind of anti-reflection coated glass, including base's glass (1), it is characterised in that: press the upper surface of base's glass (1) Antireflection layer (2), puigging (3), thermal baffle layer (4), decoration layer (5), coarse is successively arranged according to sequence from top to bottom Reflecting layer (6) and wear-resistant layer (7).
2. anti-reflection coated glass according to claim 1, it is characterised in that: the antireflection layer (2) is set as dioxy SiClx layer.
3. anti-reflection coated glass according to claim 1, it is characterised in that: the puigging (3) uses sound-proof material, institute It states wear-resistant layer (7) and is set as graphite linings.
4. it is a kind of according to claim 1 ~ 3 described in anti-reflection coated glass preparation method, which is characterized in that including following step It is rapid:
1) coated solution is prepared;
2) it cleans: base's glass (1) being cut using cleaning machine, edging, cleaning, be dried after cleaning;
3) it preheats: the pre-heat treatment being carried out to the base's glass (1) cleaned, base's glass (1) temperature is made to be maintained at normal temperature state;
4) coated solution: being uniformly plated on base's glass (1) by plated film using coating process, the coating process include spraying, Roller coating, showering coating process;
5) it dries: base's glass (1) after plated film being put into dryer and is dried;
6) solidify: 2-3.2 μm of infrared waves just under conditions, to film layer solidification, curing time 20-60s, solidification temperature is 220-380℃;
7) glass after curing process is cooling.
5. anti-reflection coated glass according to claim 4 and preparation method thereof, it is characterised in that: in the step 1) Coated solution is porous silicon dioxide gel.
6. anti-reflection coated glass according to claim 4 and preparation method thereof, it is characterised in that: the step 2 it is clear During washing, base's glass until cleaning to glass without soft flocks, it is dustless, without particle.
7. anti-reflection coated glass according to claim 4 and preparation method thereof, it is characterised in that: in the step 3) The pre-heat treatment temperature is to 20-50 DEG C.
8. anti-reflection coated glass according to claim 4 and preparation method thereof, it is characterised in that: the step 4) plated film Treatment process should carry out in the very wet confined space of constant temperature, the constant temperature very it is wet refer to temperature be no more than 40 DEG C, it is relatively wet Degree is lower than 65%.
9. anti-reflection coated glass according to claim 4 and preparation method thereof, it is characterised in that: cold in the step 7) But processing use air-cooled mode, cooling time 2-5min.
CN201910362755.9A 2019-04-30 2019-04-30 A kind of anti-reflection coated glass and preparation method thereof Pending CN110183114A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113233784A (en) * 2021-05-12 2021-08-10 翔实光电科技(昆山)有限公司 Rapid spraying process for forming AR film layer on surface of target material

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070259191A1 (en) * 2004-12-10 2007-11-08 W.C. Heraeus Gmbh Sputter target of a silver alloy, its use and glass substrate with thermal insulation layer
CN104609738A (en) * 2013-11-01 2015-05-13 北京有色金属研究总院 Method used for increasing silicon dioxide antireflection film hole stability
CN204382737U (en) * 2014-12-30 2015-06-10 陈奇康 A kind of novel energy-conserving glass
CN207016674U (en) * 2017-08-02 2018-02-16 东莞市银泰玻璃有限公司 A kind of explosion-proof sound insulation coated glass
CN207014909U (en) * 2017-08-02 2018-02-16 东莞市银泰玻璃有限公司 A kind of outdoor use anti-reflection coated glass
CN207345206U (en) * 2017-10-30 2018-05-11 东莞泰升玻璃有限公司 A kind of fluorescence sound insulation compound glass
CN108033689A (en) * 2017-11-24 2018-05-15 太仓耀华玻璃有限公司 A kind of preparation process of plane anti-reflection coated glass
JP2018106054A (en) * 2016-12-27 2018-07-05 スリーエム イノベイティブ プロパティズ カンパニー Film for glass, and glass
CN208324440U (en) * 2018-04-27 2019-01-04 东莞市银泰玻璃有限公司 A kind of High-strength outdoor coated glass

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070259191A1 (en) * 2004-12-10 2007-11-08 W.C. Heraeus Gmbh Sputter target of a silver alloy, its use and glass substrate with thermal insulation layer
CN104609738A (en) * 2013-11-01 2015-05-13 北京有色金属研究总院 Method used for increasing silicon dioxide antireflection film hole stability
CN204382737U (en) * 2014-12-30 2015-06-10 陈奇康 A kind of novel energy-conserving glass
JP2018106054A (en) * 2016-12-27 2018-07-05 スリーエム イノベイティブ プロパティズ カンパニー Film for glass, and glass
CN207016674U (en) * 2017-08-02 2018-02-16 东莞市银泰玻璃有限公司 A kind of explosion-proof sound insulation coated glass
CN207014909U (en) * 2017-08-02 2018-02-16 东莞市银泰玻璃有限公司 A kind of outdoor use anti-reflection coated glass
CN207345206U (en) * 2017-10-30 2018-05-11 东莞泰升玻璃有限公司 A kind of fluorescence sound insulation compound glass
CN108033689A (en) * 2017-11-24 2018-05-15 太仓耀华玻璃有限公司 A kind of preparation process of plane anti-reflection coated glass
CN208324440U (en) * 2018-04-27 2019-01-04 东莞市银泰玻璃有限公司 A kind of High-strength outdoor coated glass

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113233784A (en) * 2021-05-12 2021-08-10 翔实光电科技(昆山)有限公司 Rapid spraying process for forming AR film layer on surface of target material

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Application publication date: 20190830