CN110176509A - A kind of flexible solar battery novel stainless steel substrate - Google Patents
A kind of flexible solar battery novel stainless steel substrate Download PDFInfo
- Publication number
- CN110176509A CN110176509A CN201910508945.7A CN201910508945A CN110176509A CN 110176509 A CN110176509 A CN 110176509A CN 201910508945 A CN201910508945 A CN 201910508945A CN 110176509 A CN110176509 A CN 110176509A
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- stainless steel
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- steel substrate
- steel foil
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- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 67
- 239000010935 stainless steel Substances 0.000 title claims abstract description 67
- 239000000758 substrate Substances 0.000 title claims abstract description 39
- 239000011888 foil Substances 0.000 claims abstract description 36
- 238000002360 preparation method Methods 0.000 claims abstract description 30
- 230000001070 adhesive effect Effects 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000010949 copper Substances 0.000 claims description 54
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 22
- 229910052700 potassium Inorganic materials 0.000 claims description 22
- 239000011591 potassium Substances 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 17
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 17
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 15
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 14
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229920006316 polyvinylpyrrolidine Polymers 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- -1 allyl glycidyl ethers Chemical class 0.000 claims description 8
- 239000003377 acid catalyst Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- RSNQKPMXXVDJFG-UHFFFAOYSA-N tetrasiloxane Chemical compound [SiH3]O[SiH2]O[SiH2]O[SiH3] RSNQKPMXXVDJFG-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000005292 vacuum distillation Methods 0.000 claims description 6
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 238000006722 reduction reaction Methods 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 241001062472 Stokellia anisodon Species 0.000 claims 1
- QYSYEILYXGRUOM-UHFFFAOYSA-N [Cl].[Pt] Chemical compound [Cl].[Pt] QYSYEILYXGRUOM-UHFFFAOYSA-N 0.000 claims 1
- SJCBZZSXLNNZOM-UHFFFAOYSA-N [Cu].C(=C)N1CCCC1 Chemical compound [Cu].C(=C)N1CCCC1 SJCBZZSXLNNZOM-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 230000006837 decompression Effects 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 239000010408 film Substances 0.000 abstract description 11
- 239000010409 thin film Substances 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 9
- 229910021641 deionized water Inorganic materials 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 235000013339 cereals Nutrition 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 238000004448 titration Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229960000935 dehydrated alcohol Drugs 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 3
- 229910052927 chalcanthite Inorganic materials 0.000 description 3
- 238000003760 magnetic stirring Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
- H01L31/0392—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
- H01L31/03926—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate comprising a flexible substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The present invention relates to thin-film solar cells flexible base board preparation technical fields, and disclose a kind of flexible solar battery novel stainless steel substrate, including stainless steel foil, the compound one layer of Cu base elasticity adhesion layer of central part in one side surface of stainless steel foil, a side surface of Cu base elasticity adhesion layer and a side surface of stainless steel foil are arranged in the elastic connection of integrated molding formula.The technical issues of present invention solves current flexible solar battery stainless steel substrate, and the adhesive property between the fexible film of solar battery is not good enough, makes it that can not effectively meet requirement.
Description
Technical field
The present invention relates to thin-film solar cells flexible base board preparation technical field, specially a kind of flexible solar electricity
Pond novel stainless steel substrate.
Background technique
Thin-film solar cells belongs to solar battery of new generation, can be divided into hard substrate and flexible substrate two by substrate type
Major class.In the past, flexible thin-film solar cell was mainly using polymer P ET and PEN as conductive substrates, but the study found that polymer
The low melting point of substrate and it is easy to aging the problems such as limit the preparation and use of battery.Therefore, seek a kind of suitable flexible material
Become the important topic on flexible solar battery application study road as substrate used for solar batteries.
In many materials, in view of stainless steel have high temperature resistant, corrosion-resistant, electric conductivity is superior, ductility is good and at
The advantages that this is cheap, stainless steel, which becomes, replaces PET and PEN, as the preferred material of thin-film solar cells flexible substrate.But
Be stainless steel surface roughness it is smaller, show the state of smoother, this makes its fexible film with solar battery
Between adhesive property it is not good enough, cause it that can not effectively meet the requirement used.
The study found that the improvement of Substrate Surface Roughness is conducive to improve the bond properties between film and matrix, and film
The rolling of stainless steel substrate used for solar batteries is a complicated forming process, is having the same of strict demand to substrate flatness
When, substrate topography (including surface roughness, surface texture) is required higher.
Therefore, how to effectively improve between thin-film solar cells stainless steel substrate and the fexible film of solar battery
Adhesive property become current urgent problem.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of flexible solar battery novel stainless steel substrate, solutions
It has determined current flexible solar battery stainless steel substrate, the adhesive property between the fexible film of solar battery is inadequate
Well, the technical issues of making it that can not effectively meet requirement.
(2) technical solution
To achieve the above object, the invention provides the following technical scheme:
A kind of flexible solar battery novel stainless steel substrate, including stainless steel foil, in one side surface of stainless steel foil
The compound one layer of Cu base elasticity adhesion layer of central part, a side surface of Cu base elasticity adhesion layer and a side surface of stainless steel foil are in
The elastic connection of integrated molding formula is arranged；
Wherein, the preparation method of novel stainless steel substrate includes:
Using cupric sulfate pentahydrate as raw material, using potassium borohydride as reducing agent, using polyvinylpyrrolidine copper as dispersing agent, in highly basic
Under the conditions of, Liquid reduction reaction process occurs, nano Cu particle is prepared, the nano Cu particle is first raw with methyl vinyl silicone rubber
Glue be kneaded at uniform mixed system, then with raw material tetramethyl-ring tetrasiloxane, coupling agent allyl glycidyl ether, catalyst
Chloroplatinic acid and adhesive polymethyl methacrylate are reacted under the protective effect of nitrogen, and reaction product is by subtracting
Pressure distillation, prepares thick liquid, which is coated uniformly on to the central part of one side surface of stainless steel foil, Zhi Hou
Curing process is dried under vacuum condition, the Cu base elasticity adhesion layer for being adhered to stainless steel foil surface is prepared, to make
Standby novel stainless steel substrate out.
Preferably, the Cu base elasticity adhesion layer includes the raw material of following parts by weight: 13 parts of potassium borohydrides, 0.1 part of hydrogen
Sodium oxide molybdena, 12.5~25 parts of cupric sulfate pentahydrates, 0.5~1.5 part of polyvinylpyrrolidine copper, 25~40 parts of methyl vinyl silicone rubbers
Raw rubber, 20~35 parts of tetramethyl-ring tetrasiloxanes, 10~20 parts of allyl glycidyl ethers, 0.5 part of chloroplatinic acid, 5~10 parts it is poly-
Methyl methacrylate.
Preferably, the Cu base elasticity adhesion layer includes the raw material of following parts by weight: 13 parts of potassium borohydrides, 0.1 part of hydrogen
Sodium oxide molybdena, 18 parts of cupric sulfate pentahydrates, 1 part of polyvinylpyrrolidine copper, 30 parts of methyl vinyl silicon kautschuks, 30 parts of tetramethyl-rings
Tetrasiloxane, 15 parts of allyl glycidyl ethers, 0.5 part of chloroplatinic acid catalyst and 8 parts of polymethyl methacrylates.
Preferably, the novel stainless steel substrate preparation method the following steps are included:
Step 1: mainly with 13 parts of potassium borohydrides, 0.1 part of sodium hydroxide, 12.5~25 parts of cupric sulfate pentahydrates, 0.5~1.5
Part polyvinylpyrrolidine copper is raw material, prepares Cu particle of the average grain diameter within the scope of 50~100nm；
Step 2: first by 25~40 parts of methyl vinyl silicon kautschuks and the Cu particle of above-mentioned preparation in torque rheometer
It is middle to be kneaded uniformly, it is heat-treated 20~60min at a temperature of 130~170 DEG C, is cooled to room temperature, uniform mix is prepared
Zoarium system；
Step 3: the mixed system of above-mentioned preparation is added to equipped with agitating device, heating device and nitrogen protection device
Reactor in, be passed through nitrogen protection, revolving speed be 120~180rpm stirring rate under, by 20~35 parts of tetramethyl cyclotetrasiloxanes
Siloxanes, 10~20 parts of allyl glycidyl ethers, 0.5 part of chloroplatinic acid catalyst and 5~10 parts of polymethyl methacrylates according to
It is secondary to be added in above-mentioned reactor, switch to stir under 200~300rpm；
Later, 0.5h is reacted at being 20 DEG C in temperature, be warming up to 50~70 DEG C with the rate of 2 DEG C/min and reacts 1~2h,
80~120 DEG C are warming up to the rate of 2 DEG C/min again and reacts 1~3h, and reaction mixture is in 130~150 DEG C of temperature, pressure
Under 4kPa, vacuum distillation is steamed to no low-boiling-point substance, and thick liquid is prepared；
Step 4: the above-mentioned thick liquid prepared is coated uniformly on it is with a thickness of 0.3mm, width 100mm, length
The central part of one side surface of stainless steel foil of 100mm, stainless steel foil is put into vacuum oven, in vacuum degree 133Pa, temperature
It is dried in vacuo 1~3h at 60~80 DEG C of degree, the Cu base elasticity adhesion layer for being adhered to stainless steel foil surface is prepared, to prepare
Novel stainless steel substrate out.
(3) beneficial technical effect
Compared with prior art, the present invention has following beneficial technical effect:
The present invention is with cupric sulfate pentahydrate (CuSO4·5H2O) for raw material, with potassium borohydride (KBH4) it is reducing agent, with poly- second
Alkene pyrrolidines copper (PVP) is dispersing agent, under basic conditions, Liquid reduction reaction process occurs, nano Cu particle is prepared, this is received
Rice Cu particle is first kneaded with methyl vinyl silicon kautschuk into uniform mixed system, then with raw material tetramethyl cyclotetrasiloxane silicon oxygen
Alkane, coupling agent allyl glycidyl ether, catalyst chloroplatinic acid and adhesive polymethyl methacrylate (PMMA), in nitrogen
It under protective effect, is reacted, reaction product prepares thick liquid by vacuum distillation, and the thick liquid is uniform
Central part coated in one side surface of stainless steel foil for being 100mm with a thickness of 0.3mm, width 100mm, length, Zhi Hou
Curing process is dried under vacuum condition, the Cu base elasticity adhesion layer for being adhered to stainless steel foil surface is prepared, to make
Standby novel stainless steel substrate out；
And the volume resistivity of the Cu base elasticity adhesion layer on the novel stainless steel substrate prepared of the present invention be 1.32~
Removing of the peel strength between 147~154N/cm and fexible film (PI) between 1.46 Ω cm and stainless steel foil is strong
Degree is 136~139N/cm, rebound degree is 82~85%；
Therefore, the novel stainless steel substrate that the present invention prepares not only has excellent electric conductivity, but also and solar energy
Adhesive property between the fexible film of battery is also ideal, and the use that can effectively meet solar cell flexible substrate is wanted
It asks.
Detailed description of the invention
Fig. 1 is a kind of main view of flexible solar battery novel stainless steel substrate of the present invention；
Fig. 2 is a kind of top view of flexible solar battery novel stainless steel substrate of the present invention.
It is indicated in figure: 1- stainless steel foil, 2-Cu base elasticity adhesion layer.
Specific embodiment
Raw material used in the following embodiment is as follows:
The specification of stainless steel foil: with a thickness of 0.3mm, width 100mm, length 100mm；
Cupric sulfate pentahydrate (CuSO4·5H2O), pure, Shanghai chemical reagent Co., Ltd is analyzed；
Polyvinylpyrrolidine copper (PVP), trade mark K30, Nanjing Rui Ze Fine Chemical Co., Ltd；
Potassium borohydride (KBH4), analyze pure, fertile soil Chemical Co., Ltd., Anhui Province；
Sodium hydroxide (NaOH) analyzes pure, Tianjin Ke Miou reagent Co., Ltd；
Dehydrated alcohol (C2H5OH), pure, Anhui An Te biochemistry corporation,Ltd. is analyzed；
Methyl vinyl silicon kautschuk, 110 serial raw rubbers, Jia Haixin silicon rubber Co., Ltd, Shenzhen；
Tetramethyl-ring tetrasiloxane, technical grade, Shanghai Gui Shan high molecular material Co., Ltd；
Allyl glycidyl ether, technical grade, Qufu City Huarong new chemical materials Co., Ltd；
Chloroplatinic acid analyzes pure, Shenyang Research Institute of Nonferrous Metals；
Polymethyl methacrylate (PMMA), technical grade, Changsha Jia Zhen Biotechnology Co., Ltd；
Novel stainless steel substrate, referring to Fig. 1 and Fig. 2, including being 100mm's with a thickness of 0.3mm, width 100mm, length
Stainless steel foil 1, the compound one layer of Cu base elasticity adhesion layer 2 of central part in 1 one side surface of stainless steel foil, Cu base elasticity adhesion layer
2 side surface and a side surface of stainless steel foil 1 are arranged in the elastic connection of integrated molding formula；
Wherein, Cu base elasticity adhesion layer 2 the preparation method is as follows:
Embodiment one:
(1) preparation of Cu particle of the average grain diameter within the scope of 50~100nm:
A. 13g potassium borohydride (KBH is first weighed4) be dissolved in 250mL deionized water, then 0.1g sodium hydrate particle is added
Enter in above-mentioned potassium borohydride aqueous solution, adjust PH to 12, preparation obtains alkaline potassium borohydride aqueous solution；
B. the mixed solvent being first made of 300mL deionized water and 200mL dehydrated alcohol, is added to equipped with titration outfit
In the reactor of magnetic stirring apparatus, in the case where revolving speed is the stirring rate of 120rpm, first by 12.5g cupric sulfate pentahydrate
(CuSO4·5H2O it) is added in reactor, then 0.5g polyvinylpyrrolidine copper (PVP) is added in reactor, later, switch to
30min is stirred under 300rpm；
C. in the case where revolving speed is the stirring rate of 120rpm, by the alkaline potassium borohydride aqueous solution of above-mentioned preparation with 0.5mL/s
Titration speed be added drop-wise in reactor, after being added dropwise, switch to stir 10min under 200rpm；
D. after, it is filtered processing, 3 washings are carried out using product of the deionized water to generation, after washing, are put
Enter in vacuum oven, 6h be dried in vacuo under vacuum degree 133Pa, temperature 60 C, that is, be prepared average grain diameter 50~
Cu particle within the scope of 100nm；
(2) first 25g methyl vinyl silicon kautschuk and the Cu particle of above-mentioned preparation are kneaded in torque rheometer
It is even, it is heat-treated 20min at a temperature of 130 DEG C, is cooled to room temperature, uniform mixed system is prepared；
(3) mixed system of above-mentioned preparation is added to equipped with the anti-of agitating device, heating device and nitrogen protection device
It answers in device, is passed through nitrogen protection, in the case where revolving speed is the stirring rate of 120rpm, by 20g tetramethyl-ring tetrasiloxane, 10g allyl
Base glycidol ether, 0.5g chloroplatinic acid catalyst and 5g polymethyl methacrylate (PMMA) sequentially add in above-mentioned reactor,
Switch to stir under 200rpm；
Later, 0.5h is reacted at being 20 DEG C in temperature, 50 DEG C is warming up to the rate of 2 DEG C/min and reacts 1h, then with 2
DEG C/rate of min is warming up to 80 DEG C and reacts 1h, reaction mixture is at 130 DEG C of temperature, pressure 4kPa, vacuum distillation to nothing
Low-boiling-point substance steams, and thick liquid is prepared；
(4) the above-mentioned thick liquid prepared is coated uniformly on and is with a thickness of 0.3mm, width 100mm, length
The central part of 1 one side surface of stainless steel foil of 100mm, stainless steel foil 1 is put into vacuum oven, in vacuum degree 133Pa,
It is dried in vacuo 1h under temperature 60 C, Cu base elasticity adhesion layer 2 is prepared；
(5) the Cu base elasticity adhesion layer 2 of above-mentioned preparation is tested for the property, volume resistivity be 1.32 Ω cm,
The peel strength that peel strength between stainless steel foil is 147N/cm between fexible film (PI) is 136N/cm, rebound
Rate is 82%.
Embodiment two:
(1) preparation of Cu particle of the average grain diameter within the scope of 50~100nm:
A. 13g potassium borohydride (KBH is first weighed4) be dissolved in 250mL deionized water, then 0.1g sodium hydrate particle is added
Enter in above-mentioned potassium borohydride aqueous solution, adjust PH to 12, preparation obtains alkaline potassium borohydride aqueous solution；
B. the mixed solvent being first made of 300mL deionized water and 200mL dehydrated alcohol, is added to equipped with titration outfit
In the reactor of magnetic stirring apparatus, in the case where revolving speed is the stirring rate of 150rpm, first by 18g cupric sulfate pentahydrate (CuSO4·
5H2O it) is added in reactor, then 1g polyvinylpyrrolidine copper (PVP) is added in reactor, later, switch to stir under 400rpm
50min；
C. in the case where revolving speed is the stirring rate of 160rpm, by the alkaline potassium borohydride aqueous solution of above-mentioned preparation with 0.5mL/s
Titration speed be added drop-wise in reactor, after being added dropwise, switch to stir 10min under 250rpm；
D. after, it is filtered processing, 5 washings are carried out using product of the deionized water to generation, after washing, are put
Enter in vacuum oven, be dried in vacuo 7h at vacuum degree 133Pa, 75 DEG C of temperature, that is, be prepared average grain diameter 50~
Cu particle within the scope of 100nm；
(2) first 30g methyl vinyl silicon kautschuk and the Cu particle of above-mentioned preparation are kneaded in torque rheometer
It is even, it is heat-treated 40min at a temperature of 150 DEG C, is cooled to room temperature, uniform mixed system is prepared；
(3) mixed system of above-mentioned preparation is added to equipped with the anti-of agitating device, heating device and nitrogen protection device
It answers in device, is passed through nitrogen protection, in the case where revolving speed is the stirring rate of 150rpm, by 30g tetramethyl-ring tetrasiloxane, 15g allyl
Base glycidol ether, 0.5g chloroplatinic acid catalyst and 8g polymethyl methacrylate (PMMA) sequentially add in above-mentioned reactor,
Switch to stir under 250rpm；
Later, 0.5h is reacted at being 20 DEG C in temperature, 60 DEG C is warming up to the rate of 2 DEG C/min and reacts 1.5h, then with 2
DEG C/rate of min is warming up to 100 DEG C and reacts 1~3h, reaction mixture is at 140 DEG C of temperature, pressure 4kPa, vacuum distillation
It is steamed to no low-boiling-point substance, thick liquid is prepared；
(4) the above-mentioned thick liquid prepared is coated uniformly on and is with a thickness of 0.3mm, width 100mm, length
The central part of 1 one side surface of stainless steel foil of 100mm, stainless steel foil 1 is put into vacuum oven, in vacuum degree 133Pa,
It is dried in vacuo 2h under temperature 70 C, Cu base elasticity adhesion layer 2 is prepared；
(5) the Cu base elasticity adhesion layer 2 of above-mentioned preparation is tested for the property, volume resistivity be 1.38 Ω cm,
The peel strength that peel strength between stainless steel foil is 154N/cm between fexible film (PI) is 139N/cm, rebound
Rate is 83%.
Embodiment three:
(1) preparation of Cu particle of the average grain diameter within the scope of 50~100nm:
A. 13g potassium borohydride (KBH is first weighed4) be dissolved in 250mL deionized water, then 0.1g sodium hydrate particle is added
Enter in above-mentioned potassium borohydride aqueous solution, adjust PH to 12, preparation obtains alkaline potassium borohydride aqueous solution；
B. the mixed solvent being first made of 300mL deionized water and 200mL dehydrated alcohol, is added to equipped with titration outfit
In the reactor of magnetic stirring apparatus, in the case where revolving speed is the stirring rate of 180rpm, first by 25g cupric sulfate pentahydrate (CuSO4·
5H2O it) is added in reactor, then 1.5g polyvinylpyrrolidine copper (PVP) is added in reactor, later, switch to stir under 500rpm
Mix 60min；
C. in the case where revolving speed is the stirring rate of 180rpm, by the alkaline potassium borohydride aqueous solution of above-mentioned preparation with 0.5mL/s
Titration speed be added drop-wise in reactor, after being added dropwise, switch to stir 10min under 300rpm；
D. after, it is filtered processing, 6 washings are carried out using product of the deionized water to generation, after washing, are put
Enter in vacuum oven, be dried in vacuo 8h at vacuum degree 133Pa, 80 DEG C of temperature, that is, be prepared average grain diameter 50~
Cu particle within the scope of 100nm；
(2) first 40g methyl vinyl silicon kautschuk and the Cu particle of above-mentioned preparation are kneaded in torque rheometer
It is even, it is heat-treated 60min at a temperature of 170 DEG C, is cooled to room temperature, uniform mixed system is prepared；
(3) mixed system of above-mentioned preparation is added to equipped with the anti-of agitating device, heating device and nitrogen protection device
It answers in device, is passed through nitrogen protection, in the case where revolving speed is the stirring rate of 180rpm, by 35g tetramethyl-ring tetrasiloxane, 20g allyl
Base glycidol ether, 0.5g chloroplatinic acid catalyst and 10g polymethyl methacrylate (PMMA) sequentially add in above-mentioned reactor,
Switch to stir under 300rpm；
Later, 0.5h is reacted at being 20 DEG C in temperature, 70 DEG C is warming up to the rate of 2 DEG C/min and reacts 2h, then with 2
DEG C/rate of min is warming up to 120 DEG C and reacts 3h, reaction mixture is at 150 DEG C of temperature, pressure 4kPa, vacuum distillation to nothing
Low-boiling-point substance steams, and thick liquid is prepared；
(4) the above-mentioned thick liquid prepared is coated uniformly on and is with a thickness of 0.3mm, width 100mm, length
The central part of 1 one side surface of stainless steel foil of 100mm, stainless steel foil 1 is put into vacuum oven, in vacuum degree 133Pa,
It is dried in vacuo 3h at 80 DEG C of temperature, Cu base elasticity adhesion layer 2 is prepared；
(5) the Cu base elasticity adhesion layer 2 of above-mentioned preparation is tested for the property, volume resistivity be 1.46 Ω cm,
The peel strength that peel strength between stainless steel foil is 149N/cm between fexible film (PI) is 137N/cm, rebound
Rate is 85%.
Claims (4)
1. a kind of flexible solar battery novel stainless steel substrate, which is characterized in that including stainless steel foil (1), in stainless steel
The compound one layer of Cu base elasticity adhesion layer (2) of the central part of (1) one side surface of foil, a side surface of Cu base elasticity adhesion layer (2)
It is arranged with a side surface of stainless steel foil (1) in the elastic connection of integrated molding formula；
Wherein, the preparation method of novel stainless steel substrate includes:
Using cupric sulfate pentahydrate as raw material, using potassium borohydride as reducing agent, using polyvinylpyrrolidine copper as dispersing agent, in basic conditions
Under, Liquid reduction reaction process occurs, nano Cu particle is prepared, the nano Cu particle is first mixed with methyl vinyl silicon kautschuk
Be smelt uniform mixed system, then with raw material tetramethyl-ring tetrasiloxane, coupling agent allyl glycidyl ether, catalyst chlorine platinum
Acid and adhesive polymethyl methacrylate are reacted under the protective effect of nitrogen, and reaction product is steamed by decompression
It evaporates, prepares thick liquid, which is coated uniformly on to the central part of (1) one side surface of stainless steel foil, Zhi Hou
Curing process is dried under vacuum condition, the Cu base elasticity adhesion layer (2) for being adhered to stainless steel foil (1) surface is prepared,
To prepare novel stainless steel substrate.
2. novel stainless steel substrate according to claim 1, which is characterized in that the Cu base elasticity adhesion layer (2) includes
The raw material of following parts by weight: 13 parts of potassium borohydrides, 0.1 part of sodium hydroxide, 12.5~25 parts of cupric sulfate pentahydrates, 0.5~1.5 part
Polyvinylpyrrolidine copper, 25~40 parts of methyl vinyl silicon kautschuks, 20~35 parts of tetramethyl-ring tetrasiloxanes, 10~20 parts
Allyl glycidyl ether, 0.5 part of chloroplatinic acid, 5~10 parts of polymethyl methacrylates.
3. novel stainless steel substrate according to claim 1, which is characterized in that the Cu base elasticity adhesion layer (2) includes
The raw material of following parts by weight: 13 parts of potassium borohydrides, 0.1 part of sodium hydroxide, 18 parts of cupric sulfate pentahydrates, 1 part of polyvinylpyrrolidine
Copper, 30 parts of methyl vinyl silicon kautschuks, 30 parts of tetramethyl-ring tetrasiloxanes, 15 parts of allyl glycidyl ethers, 0.5 part of chlorine
Platinic acid catalyst and 8 parts of polymethyl methacrylates.
4. novel stainless steel substrate according to claim 1, which is characterized in that the preparation side of the novel stainless steel substrate
Method the following steps are included:
Step 1: mainly gathered with 13 parts of potassium borohydrides, 0.1 part of sodium hydroxide, 12.5~25 parts of cupric sulfate pentahydrates, 0.5~1.5 part
Vinyl pyrrolidine copper is raw material, prepares Cu particle of the average grain diameter within the scope of 50~100nm；
Step 2: first 25~40 parts of methyl vinyl silicon kautschuks and the Cu particle of above-mentioned preparation are mixed in torque rheometer
Refining uniformly, 20~60min is heat-treated at a temperature of 130~170 DEG C, is cooled to room temperature, uniform mixture is prepared
System；
Step 3: the mixed system of above-mentioned preparation is added to equipped with the anti-of agitating device, heating device and nitrogen protection device
It answers in device, is passed through nitrogen protection, in the case where revolving speed is the stirring rate of 120~180rpm, by 20~35 parts of tetramethyl cyclotetrasiloxane silicon oxygen
Alkane, 10~20 parts of allyl glycidyl ethers, 0.5 part of chloroplatinic acid catalyst and 5~10 parts of polymethyl methacrylates successively add
Enter in above-mentioned reactor, switchs to stir under 200~300rpm；
Later, 0.5h is reacted at being 20 DEG C in temperature, be warming up to 50~70 DEG C with the rate of 2 DEG C/min and reacts 1~2h, then with
The rate of 2 DEG C/min is warming up to 80~120 DEG C and reacts 1~3h, and reaction mixture is in 130~150 DEG C of temperature, pressure 4kPa
Under, vacuum distillation is steamed to no low-boiling-point substance, and thick liquid is prepared；
Step 4: the above-mentioned thick liquid prepared is coated uniformly on it is with a thickness of 0.3mm, width 100mm, length
The central part of (1) one side surface of stainless steel foil of 100mm, stainless steel foil (1) is put into vacuum oven, in vacuum degree
133Pa, it is dried in vacuo 1~3h at 60~80 DEG C of temperature, the Cu base elasticity adherency for being adhered to stainless steel foil (1) surface is prepared
Layer (2), to prepare novel stainless steel substrate.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113773674A (en) * | 2021-08-30 | 2021-12-10 | 温州瑞银不锈钢制造有限公司 | Production process of surface-coated stainless steel and surface-coated stainless steel |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5878475A (en) * | 1981-11-04 | 1983-05-12 | Kanegafuchi Chem Ind Co Ltd | Thin film solar battery |
| US6268235B1 (en) * | 1998-01-27 | 2001-07-31 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing a photoelectric conversion device |
| CN102770965A (en) * | 2010-01-21 | 2012-11-07 | 富士胶片株式会社 | Solar cell and solar cell manufacturing method |
| WO2012176483A1 (en) * | 2011-06-20 | 2012-12-27 | 富士電機株式会社 | Flexible solar cell module and fire-spread prevention sheet thereof |
| TW201500207A (en) * | 2013-02-19 | 2015-01-01 | Nippon Steel & Sumikin Chem Co | Laminate body, solar cell member, solar cell, display device member, display device, and method for manufacturing laminate body |
| CN109354729A (en) * | 2018-07-24 | 2019-02-19 | 黄山市尚义橡塑制品有限公司 | Graphene enhances rubber and preparation method thereof |
-
2019
- 2019-06-13 CN CN201910508945.7A patent/CN110176509B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5878475A (en) * | 1981-11-04 | 1983-05-12 | Kanegafuchi Chem Ind Co Ltd | Thin film solar battery |
| US6268235B1 (en) * | 1998-01-27 | 2001-07-31 | Semiconductor Energy Laboratory Co., Ltd. | Method for manufacturing a photoelectric conversion device |
| CN102770965A (en) * | 2010-01-21 | 2012-11-07 | 富士胶片株式会社 | Solar cell and solar cell manufacturing method |
| WO2012176483A1 (en) * | 2011-06-20 | 2012-12-27 | 富士電機株式会社 | Flexible solar cell module and fire-spread prevention sheet thereof |
| TW201500207A (en) * | 2013-02-19 | 2015-01-01 | Nippon Steel & Sumikin Chem Co | Laminate body, solar cell member, solar cell, display device member, display device, and method for manufacturing laminate body |
| CN109354729A (en) * | 2018-07-24 | 2019-02-19 | 黄山市尚义橡塑制品有限公司 | Graphene enhances rubber and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113773674A (en) * | 2021-08-30 | 2021-12-10 | 温州瑞银不锈钢制造有限公司 | Production process of surface-coated stainless steel and surface-coated stainless steel |
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