CN110174485A - A kind of syringe for trace species analysis - Google Patents

A kind of syringe for trace species analysis Download PDF

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Publication number
CN110174485A
CN110174485A CN201910567871.4A CN201910567871A CN110174485A CN 110174485 A CN110174485 A CN 110174485A CN 201910567871 A CN201910567871 A CN 201910567871A CN 110174485 A CN110174485 A CN 110174485A
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CN
China
Prior art keywords
filter
electric pushrod
suction chamber
suction
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910567871.4A
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Chinese (zh)
Inventor
朱洁
胡园
周朝生
柯爱英
陆荣茂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Mariculture Research Institute
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Zhejiang Mariculture Research Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Mariculture Research Institute filed Critical Zhejiang Mariculture Research Institute
Priority to CN201910567871.4A priority Critical patent/CN110174485A/en
Publication of CN110174485A publication Critical patent/CN110174485A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • G01N30/04Preparation or injection of sample to be analysed
    • G01N30/06Preparation
    • G01N30/14Preparation by elimination of some components
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • G01N30/04Preparation or injection of sample to be analysed
    • G01N30/16Injection
    • G01N30/18Injection using a septum or microsyringe
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02Column chromatography
    • G01N30/04Preparation or injection of sample to be analysed
    • G01N30/06Preparation
    • G01N30/14Preparation by elimination of some components
    • G01N2030/146Preparation by elimination of some components using membranes

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Sampling And Sample Adjustment (AREA)

Abstract

The invention discloses a kind of syringes for trace species analysis, including injection device and filter, injection device includes the electric pushrod from top to bottom set gradually, to install the fixed block of electric pushrod, inject cavity and suction connector, the side of fixed block is provided with the glove hole to accommodate electric pushrod, there is solution suction chamber in injecting cavity body, it is equipped between fixed block and injection cavity to separate glove hole, the sealing element of solution suction chamber, spring is equipped in solution suction chamber, the bottom of solution suction chamber is fixed in one end of spring, the other end is abutted against with sealing element, suction connector side is provided with the suction channel being connected with solution suction chamber, the free end of electric pushrod is protruded into glove hole and presses sealing element so that the pressure size of solution suction chamber changes.Syringe of the invention avoids being lost in injection importing internal lining pipe, while to being filtered in injection, chromatographic column being avoided to block.

Description

A kind of syringe for trace species analysis
Technical field
The present invention relates to a kind of syringes, more particularly, to a kind of syringe for trace species analysis.
Background technique
With the development of agriculture industrialization, the production of agricultural product is increasingly dependent on the substances such as pesticide, antibiotic and hormone To obtain more industrial values.Excessive because launching, tie substance level seriously threatens agriculture beyond limitation in environment, agricultural product Product quality and safety.Therefore agricultural product quality and safety is ensured, the accurate trace materials level analyzed in environment or agricultural product is base Plinth, pre-treating method are premises.
Hormone is broadly divided into external source and endogenous hormones, the improper use of exogenous hormone or abuse in aquatic products, causes it in water There is residual in product, human health is caused centainly to endanger.And aquatic products Endogenous Hormone Contents in Vitro and aquatic products own growth are sent out Educate locating growing environment, edible bait, accelerating mode related (usual Endogenous Hormones are lower, are million/level-one Not, belong to trace analysis scope), and reasonable, efficient pretreatment mode is the premise of trace species analysis.
According to existing standard GB/T21981-2008 " hormone multi-residue determination method liquid chromatogram-in animal-derived food Mass spectrum/mass spectrography " in point out, gas chromatograph can be used or liquid phase is penetrated spectrometer and detected.Its analytical procedure can be divided into: sample Preparation extracts, purification, is concentrated and measures, wherein generally need constant volume in the autosampler sample bottle of 2ml after concentration, For chromatographic determination.If the sample solution after constant volume must be measured again after 0.22 μm of membrane filtration, to remove in solvent Molecule, to avoid blocking chromatographic column.
However, remaining for hormone or agricultural and veterinary chemicals, especially trace materials is detected, because its background concentration is relatively low, therefore It is quantitative convenient for analysis to improve solution concentration to be measured that constant volume can be accordingly reduced when constant volume, but due to the sample volume of solvent compared with It is small so that liquid level can not be lifted, be not easy to chromatograph and tested and analyzed.Therefore, the prior art is by using in sample injection bottle The interior sample internal lining pipe that adds is to raise the liquid level of solvent, which is located in sample injection bottle, and the opening direction of internal lining pipe It is identical as the opening direction of sample injection bottle.The spout diameter of the internal lining pipe is less than sample injection bottle, therefore can be lifted the liquid level of solvent, And then it is tested and analyzed convenient for chromatograph.But because the nozzle of internal lining pipe becomes smaller, so that liquid pole when entering internal lining pipe Easily because own tension reason rests at internal lining pipe nozzle position, and then subsequent solution is caused to cannot be introduced into internal lining pipe, very To spilling, thus have much room for improvement.
Summary of the invention
It, should the purpose of the present invention is overcoming the deficiencies of the prior art and provide a kind of syringe for trace species analysis Syringe can avoid injection import internal lining pipe in is lost, while can in injection foreign matter and particle be filtered, Filter effect is good and can avoid chromatographic column blocking.
The invention adopts the following technical scheme: a kind of syringe for trace species analysis, including injection device and Filter, the injection device include the electric pushrod from top to bottom set gradually, the fixed block to install electric pushrod, note Cavity and suction connector are penetrated, the side of the fixed block is provided with the glove hole to accommodate electric pushrod, the injecting cavity There is solution suction chamber in vivo, be equipped between the fixed block and injection cavity to separate glove hole, solution suction chamber Sealing element, spring is equipped in the solution suction chamber, the bottom of solution suction chamber, institute are fixed in one end of the spring It states the spring other end to abut against with sealing element, the side of the suction connector is provided with the suction being connected with solution suction chamber Channel, the free end of the electric pushrod are protruded into glove hole and press sealing element so that the space size of solution suction chamber is sent out Changing is to change the indoor pressure of solution suction chamber, and the side of the suction connector and filter are mating, the filtering Device is provided with suction liquid injection port far from the side of suction connector.
As an improvement the filter is provided with the drainage matched with suction liquid injection port far from one end of injection device Pipe, the both ends open that the drainage tube is is up big and down small structure, the side cross section that the drainage tube is matched with sample injection bottle Less than the side cross section matched with the suction liquid injection port at filter.
As an improvement the sealing element is made of rubber material.
As an improvement the filter includes shell, the shell is built-in with and can be connected with suction connector It is connected to chamber, the side of the shell is removably connected with Microporous filter elements, and the side of the shell is additionally provided with can be with micropore mistake The recessing groove that filter component matches;When in Microporous filter elements insertion recessing groove, the Microporous filter elements are placed in company It is matched in cavity and with suction connector, the side of the shell is provided with connector that can be mating with suction connector.
As an improvement the Microporous filter elements include the micropore filtering film matched with suction connector, and Mutually matched upper filter holder, lower filter holder, the upper filter holder and lower filter holder are in circle body shape, and are being enclosed The middle part of body is equipped with the grid to set off micropore filtering film, and the micropore filtering film is a sheet body, is placed in the upper filter membrane branch Match between frame and lower filter holder and with grid position.
As an improvement the filter further includes the pick-and-place components having to install Microporous filter elements, the inserting Part includes the grip block and the film circle intracavitary positioned at connection for protruding from hull outside and being affectedly bashful for human hands, described micro- Hole filter assemblies are placed in film circle and fix with film circle hot pressing, are provided with link block between the film circle and grip block.
As an improvement electric pushrod or its electricity with coding motor of the electric pushrod using servo electric machine type Dynamic push rod.
Beneficial effects of the present invention: the present invention is different from the existing syringe using mode of injecting, and passes through electric pushrod The variation of free end, to eject to sealing element and be matched with spring, to reach by changing solution suction chamber interior pressure The function of suction liquid.And existing electric pushrod standard stroke is between 100-400mm, but its maximum thrust to sealing element Up to 6000N, feature controllable with stroke and big thrust, and then sample injection bottle is determined in Detecting Pesticide environment Rong Shi first passes through big stroke and draws external solution, then molten will gradually be located at by the stroke control to electric pushrod The indoor solution of liquid suction chamber is slowly discharged.The solution of discharge is introduced directly into sample injection bottle.
When in use, sealing element is ejected by the free end of electric pushrod so that the indoor space of solution suction chamber becomes Small, spring is squeezed, and then will inhale liquid injection port and stretch to in draw solution, subsequent start-up electric pushrod, so that electric pushrod Free end retraction, solution suction chamber expand its space size under the action of the spring, form negative pressure in solution suction chamber, To be aspirated to external solution.When needing to exclude liquid, the free end of electric pushrod is stretched out, again to sealing element ejection, spring Compression, so that the indoor space of solution suction chamber becomes smaller and is pressurized, which is conducive to solution by being filtered in filter, So as to in injection foreign matter and particle be filtered, filter effect it is good and can avoid chromatographic column blocking.Using this method, It can also be achieved and micro liquid is operated.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the embodiment of the present invention;
Fig. 2 is Fig. a kind suction connector and the structural schematic diagram of filter, drainage tube in the engagement condition;
Fig. 3 is the structural schematic diagram after Fig. 2 removal drainage tube;
Fig. 4 is the structural blast schematic diagram of Fig. 3;
Fig. 5 is the structural schematic diagram of Microporous filter elements in Fig. 4;
Fig. 6 is the structural blast schematic diagram of Fig. 5.
Appended drawing reference: 1, injection device;2, filter;3, electric pushrod;4, fixed block;5, cavity is injected;6, suction connects Head;7, glove hole;8, solution suction chamber;9, sealing element;10, spring;11, suction channel;12, liquid injection port is inhaled;13, it drains Pipe;14, shell;15, it is connected to chamber;16, Microporous filter elements;17, connector;18, recessing groove;19, micropore filtering film;20, on Filter holder;21, lower filter holder;22, grid;23, pick-and-place components;24, block is held;25, film circle;26, link block.
Specific embodiment
It elaborates below in conjunction with attached drawing to specific embodiments of the present invention.
As shown in figs 1 to 6, a kind of syringe for trace species analysis, including injection device 1 and filter 2, Injection device 1 includes the electric pushrod 3 from top to bottom set gradually, the fixed block 4 to install electric pushrod 3, injection cavity 5 And suction connector 6, the side of fixed block 4 are provided with the glove hole 7 to accommodate electric pushrod 3, have in injection cavity 5 molten Liquid suction chamber 8 is equipped with the sealing element 9 to separate glove hole 7, solution suction chamber 8 between fixed block 4 and injection cavity 5, Spring 10 is equipped in solution suction chamber 8, the bottom of solution suction chamber 8, the other end and sealing are fixed in one end of spring 10 Part 9 abuts against.The side of suction connector 6 is provided with the suction channel 11 being connected with solution suction chamber 8, electric pushrod 3 Free end is protruded into glove hole 7 and presses sealing element 9 so that the space size of solution suction chamber 8 changes to change solution Pressure in suction chamber 8, to complete suction movement.And spring 10 facilitate sealing element 9 no electric pushrod 3 force under it is extensive Again to original state.The side of suction connector 6 and filter 2 are mating, and filter 2 is arranged far from the side of suction connector 6 Have and inhales liquid injection port 12.
The present invention is different from the existing syringe using mode of injecting, by the variation of 3 free end of electric pushrod, with right Sealing element 9 is ejected and is matched with spring 10, to reach the function of suction liquid by changing 8 internal pressure of solution suction chamber Energy.And existing 3 standard stroke of electric pushrod is between 100-400mm, but its to the maximum thrust of sealing element 9 up to 6000N, The controllable and big thrust feature with stroke, and then when Detecting Pesticide environment carries out constant volume to sample injection bottle, first lead to Excessive stroke draws external solution, then is controlled by the stroke to electric pushrod 3 will gradually be located at solution suction chamber Solution in room 8 is slowly discharged.The solution of discharge is introduced directly into the internal lining pipe of sample injection bottle.
When in use, the space so that in solution suction chamber 8 is ejected to sealing element 9 by the free end of electric pushrod 3 Become smaller, spring 10 is squeezed, then will inhale liquid injection port 12 and stretch to in draw solution, subsequent start-up electric pushrod 3, so that electric Dynamic 3 free end of push rod retraction, solution suction chamber 8 expands its space size under the action of spring 10, in solution suction chamber 8 Interior formation negative pressure, to be aspirated to external solution.When needing to exclude liquid, the free end of electric pushrod 3 is stretched out, again to sealing The ejection of part 9, spring 10 compress, so that the space in solution suction chamber 8 becomes smaller and is pressurized, which is conducive to solution and passed through Be filtered in filter 2, so as to in injection foreign matter and particle be filtered, filter effect it is good and can avoid chromatographic column Blocking.Using this method, it can also be achieved and micro liquid is operated.
Further, filter 2 is provided with the drainage tube matched with suction liquid injection port 12 far from one end of injection device 1 13, sample solution to be detected can be drained in the internal lining pipe in sample injection bottle and carry out constant volume by drainage tube 13.Drainage tube 13 Both ends open be up big and down small structure, the side cross section matched with the internal lining pipe in sample injection bottle be less than at filter 2 The side cross section that matches of suction liquid injection port 12 so that by the solution of the filtering discharge of filter 2 via drainage tube 13 at When, of short duration overstocked (since the feed speed of drainage tube 13 is greater than liquid speed degree) can be carried out in drainage tube 13, can be convenient for making User accurately carries out constant volume to sample injection bottle, gives the fault-tolerant chance of user, extends the reaction time of fault-tolerant redemption.
Further, sealing element 9 is made of rubber material.So that the raw material of sealing element 9 are honest, are easy to get and are easy to add Work.
Further, filter 2 includes shell 14, and shell 14 is built-in with the connection chamber that can be connected with suction connector 6 15, the side of shell 14 is removably connected with Microporous filter elements 16.The side of shell 14 is additionally provided with can be with Microporous filter elements 16 recessing grooves 18 matched.When Microporous filter elements 16 are inserted into recessing groove 18, Microporous filter elements 16 are placed in connection chamber It is matched in 15 and with suction connector 6.The side of shell 14 is provided with connector 17 that can be mating with liquid injection port 12 is inhaled.It is logical It crosses and shell 14 is removably mounted at the suction connector 6 of 1 one end of injection device, and Microporous filter elements 16 are detachable On installation to shell 14, user can replace the Microporous filter elements 16 of respective aperture according to actual needs, not of the same race to meet The micro porous filtration of class chromatographic column needs.Meanwhile two Microporous filter elements 16 can be used respectively in two links of imbibition and fluid injection, To realize the molecule in high-precision removal solution, to avoid to the solution secondary filter in the sample injection bottle of being imported Chromatographic column blocking.It is thus not necessarily to entirely abandon filter 2 after a single use, only needs to change Microporous filter elements 16, Realization is used repeatedly.
Further, Microporous filter elements 16 include the micropore filtering film 19 matched with suction connector 6, and mutually Upper filter holder 20, the lower filter holder 21 of cooperation, upper filter holder 20 and lower filter holder 21 are in circle body shape, and are being enclosed The middle part of body is equipped with the grid 22 to set off micropore filtering film 19.Micropore filtering film 19 is a sheet body, is placed in filter holder Match between 20 and lower filter holder 21 and with 22 position of grid.When injection device 1 carries out injecting fluid, in the work of pressure With the lower solvent in injection device 1 micro porous filtration can be carried out via filter 2.
Further, filter 2 further includes the pick-and-place components 23 having to install Microporous filter elements 16, and pick-and-place components 23 include Have and protrudes from the grip block 24 being affectedly bashful outside shell 14 for human hands and the film circle 25 in connection chamber 15, micropore Filter assemblies 16 are placed in film circle 25 and fix with 25 hot pressing of film circle, are provided with link block 26 between film circle 25 and grip block 24. When needing replacing, installing Microporous filter elements 16, grip block 24 need to be only affectedly bashful by human hands, and then control micro porous filtration Component 16 is mounted and taken out.
Further, electric pushrod 3 can be used servo electric machine type electric pushrod or its have coding the electronic of motor push away Bar, such electric pushrod may make the Telescopic Fixed distance in free end, preferably to eject to sealing element 9, to adjust solution suction Arrange the pressure in chamber 8.This is the prior art, is not described in detail herein.
The above is only the preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment, All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (6)

1. a kind of syringe for trace species analysis, including injection device (1) and filter (2), it is characterised in that: institute Stating injection device (1) includes electric pushrod (3), the fixed block to install electric pushrod (3) from top to bottom set gradually (4), cavity (5) are injected and suction connector (6), the side of the fixed block (4) is provided with to accommodate electric pushrod (3) Glove hole (7), the injection cavity (5) is interior to have solution suction chamber (8), between the fixed block (4) and injection cavity (5) Equipped with the sealing element (9) to separate glove hole (7), solution suction chamber (8), bullet is equipped in the solution suction chamber (8) The bottom of solution suction chamber (8), spring (10) other end and sealing are fixed in spring (10), one end of the spring (10) Part (9) abuts against, and the side of the suction connector (6) is provided with the suction channel (11) being connected with solution suction chamber (8), The free end of the electric pushrod (3) is protruded into glove hole (7) to sealing element (9) pressure so that the sky of solution suction chamber (8) Between size change to change the pressure in solution suction chamber (8), the side and filter (2) of the suction connector (6) Mating, the filter (2) is provided with far from the side of suction connector (6) inhales liquid injection port (12), and the filter (2) is remote One end from injection device (1) is provided with the drainage tube (13) matched with suction liquid injection port (12), the drainage tube (13) Both ends open is up big and down small structure, and the side cross section that the drainage tube (13) matches with internal lining pipe is less than and filter (2) the side cross section that the suction liquid injection port (12) at matches.
2. a kind of syringe for trace species analysis according to claim 1, it is characterised in that: the sealing element (9) it is made of rubber material.
3. a kind of syringe for trace species analysis according to claim 1, it is characterised in that: the filter It (2) include shell (14), the shell (14) is built-in with the connection chamber (15) that can be connected with suction connector (6), the shell The side of body (14) is removably connected with Microporous filter elements (16), and the side of the shell (14) is additionally provided with can be with micro porous filtration The recessing groove (18) that component (16) matches;When the Microporous filter elements (16) insertion recessing groove (18) is interior, the micropore Filter assemblies (16) are placed in connection chamber (15) and match with suction connector (6), and the side of the shell (14) is provided with can The connector (17) mating with suction connector (6).
4. a kind of syringe for trace species analysis according to claim 3, it is characterised in that: the micro porous filtration Component (16) includes the micropore filtering film (19) and mutually matched upper filter holder matched with suction connector (6) (20), lower filter holder (21), the upper filter holder (20) and lower filter holder (21) are in circle body shape, and in circle body Middle part is equipped with the grid (22) to set off micropore filtering film (19), and the micropore filtering film (19) is a sheet body, is placed in described Match between upper filter holder (20) and lower filter holder (21) and with grid (22) position.
5. a kind of syringe for trace species analysis according to claim 4, it is characterised in that: the filter It (2) further include the pick-and-place components (23) having to install Microporous filter elements (16), the pick-and-place components (23) include to protrude from shell The external grip block (24) being affectedly bashful for human hands of body (14) and the film circle (25) being located in connection chamber (15), it is described micro- Hole filter assemblies (16) are placed in film circle (25) and fix with film circle (25) hot pressing, between the film circle (25) and grip block (24) It is provided with link block (26).
6. a kind of syringe for trace species analysis according to claim 1, it is characterised in that: the electric pushrod (3) using the electric pushrod of servo electric machine type or its electric pushrod with coding motor.
CN201910567871.4A 2019-06-27 2019-06-27 A kind of syringe for trace species analysis Pending CN110174485A (en)

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Application Number Priority Date Filing Date Title
CN201910567871.4A CN110174485A (en) 2019-06-27 2019-06-27 A kind of syringe for trace species analysis

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Application Number Priority Date Filing Date Title
CN201910567871.4A CN110174485A (en) 2019-06-27 2019-06-27 A kind of syringe for trace species analysis

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Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2691598Y (en) * 2004-04-28 2005-04-13 刘超 Multipurpose puncture draining apparatus
JP2011000490A (en) * 2009-06-16 2011-01-06 Nichiryo Co Ltd Pipette
CN202666105U (en) * 2012-06-07 2013-01-16 杨昌燕 Disposable aseptic particle entrapment injector
CN203935254U (en) * 2014-07-01 2014-11-12 刘京 The puncture injection integral type syringe that draws water
CN104623768A (en) * 2015-03-11 2015-05-20 张亚平 Simple safety injection syringe
CN105588740A (en) * 2014-10-20 2016-05-18 中国石油天然气股份有限公司 Sample flushing device and crude oil extraction and content determination method of oil-containing rock
CN107014937A (en) * 2017-04-10 2017-08-04 新疆农业科学院农业质量标准与检测技术研究所 A kind of filter and its application
CN206642443U (en) * 2017-04-17 2017-11-17 浙江利民化工有限公司 A kind of filtering device for diesel
CN207036784U (en) * 2017-08-01 2018-02-23 安徽省化工研究院 A kind of removable fast filtering head
CN107971051A (en) * 2017-12-08 2018-05-01 王光勇 A kind of canister bottle with control valve
CN207394931U (en) * 2017-09-15 2018-05-22 绍兴凯森厨卫有限公司 A kind of pullable strainer
CN207468463U (en) * 2017-11-13 2018-06-08 江苏双盈纺织科技有限公司 A kind of printing and dyeing mill's sludge treatment equipment for having anti-scaling structure
CN207675712U (en) * 2018-01-10 2018-07-31 中华人民共和国日照出入境检验检疫局 A kind of automatic microporous filter of sample for ion chromatograph detection
CN208617346U (en) * 2018-07-12 2019-03-19 李荫柱 A kind of drainage funnel
CN210199036U (en) * 2019-06-27 2020-03-27 浙江省海洋水产养殖研究所 Injector for trace substance analysis

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2691598Y (en) * 2004-04-28 2005-04-13 刘超 Multipurpose puncture draining apparatus
JP2011000490A (en) * 2009-06-16 2011-01-06 Nichiryo Co Ltd Pipette
CN202666105U (en) * 2012-06-07 2013-01-16 杨昌燕 Disposable aseptic particle entrapment injector
CN203935254U (en) * 2014-07-01 2014-11-12 刘京 The puncture injection integral type syringe that draws water
CN105588740A (en) * 2014-10-20 2016-05-18 中国石油天然气股份有限公司 Sample flushing device and crude oil extraction and content determination method of oil-containing rock
CN104623768A (en) * 2015-03-11 2015-05-20 张亚平 Simple safety injection syringe
CN107014937A (en) * 2017-04-10 2017-08-04 新疆农业科学院农业质量标准与检测技术研究所 A kind of filter and its application
CN206642443U (en) * 2017-04-17 2017-11-17 浙江利民化工有限公司 A kind of filtering device for diesel
CN207036784U (en) * 2017-08-01 2018-02-23 安徽省化工研究院 A kind of removable fast filtering head
CN207394931U (en) * 2017-09-15 2018-05-22 绍兴凯森厨卫有限公司 A kind of pullable strainer
CN207468463U (en) * 2017-11-13 2018-06-08 江苏双盈纺织科技有限公司 A kind of printing and dyeing mill's sludge treatment equipment for having anti-scaling structure
CN107971051A (en) * 2017-12-08 2018-05-01 王光勇 A kind of canister bottle with control valve
CN207675712U (en) * 2018-01-10 2018-07-31 中华人民共和国日照出入境检验检疫局 A kind of automatic microporous filter of sample for ion chromatograph detection
CN208617346U (en) * 2018-07-12 2019-03-19 李荫柱 A kind of drainage funnel
CN210199036U (en) * 2019-06-27 2020-03-27 浙江省海洋水产养殖研究所 Injector for trace substance analysis

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