CN110171956A - The method for preparing revetment brick using low concentration oil-polluted soils - Google Patents

The method for preparing revetment brick using low concentration oil-polluted soils Download PDF

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Publication number
CN110171956A
CN110171956A CN201910429664.2A CN201910429664A CN110171956A CN 110171956 A CN110171956 A CN 110171956A CN 201910429664 A CN201910429664 A CN 201910429664A CN 110171956 A CN110171956 A CN 110171956A
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CN
China
Prior art keywords
revetment brick
low concentration
polluted soils
concentration oil
brick
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910429664.2A
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Chinese (zh)
Inventor
王勇
洪静
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Fudao United (tianjin) Big Data Co Ltd
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Fudao United (tianjin) Big Data Co Ltd
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Priority to CN201910429664.2A priority Critical patent/CN110171956A/en
Publication of CN110171956A publication Critical patent/CN110171956A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1328Waste materials; Refuse; Residues without additional clay
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02BHYDRAULIC ENGINEERING
    • E02B3/00Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
    • E02B3/04Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
    • E02B3/12Revetment of banks, dams, watercourses, or the like, e.g. the sea-floor
    • E02B3/14Preformed blocks or slabs for forming essentially continuous surfaces; Arrangements thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567Treatment time
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to contaminated soil process fields, and in particular to a kind of application low concentration oil-polluted soils prepare revetment brick method, comprising the following steps: (1) by petroleum soil breaking to 80 mesh hereinafter, and passing through vibrating screen and carrying out partial size screening;(2) Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and raw material is uniformly mixed;(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain adobe;(4) high-temperature roasting;(5) wait be burnt into molding revetment brick natural cooling;(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.Application low concentration oil-polluted soils through the invention prepare revetment brick method; low concentration oil-polluted soils can be recycled; and obtain revetment brick, solve the problems, such as the technology of the haydite of the preparation resource utilization of China's contaminated soil now or revetment brick there are it is at high cost, by territory restriction.

Description

The method for preparing revetment brick using low concentration oil-polluted soils
Technical field
The invention belongs to contaminated soil process fields, and in particular to a kind of application low concentration oil-polluted soils prepare slope protection Brick method.
Background technique
Low concentration oil-polluted soils fecund is raw in industries such as oil refining, coal gas, coal tar processing, pitch processing.With me The transition of state's development, such plant area gradually moves, is transformed, but the low concentration oil-polluted soils earth volume carried over is huge Greatly, the restorative procedure of low concentration oil-polluted soils (total petroleum hydrocarbon concentration is no more than 5mg/kg) is more mature, but repairs Soil outlet afterwards is always the problem that government, enterprise face.The processing mode of soil after China is repaired at present mainly has green Change, backfill, paving the way, making 4 kinds of cement.Wherein afforest more demanding to soil soil property and the content of organic matter, and dosage is less; Whether backfill is higher to the mechanical property requirements of soil, furthermore backfill and also need to be determined according to the requirement of owner;It paves the way by soil The limitation of earth transportation range, cost improves rapidly when long-distance transport;Production cement products then have strictly the chemical component of soil It is required that additionally demand of the heavy dependence locality to cement products.In summary 4 kinds of methods, it can be seen that the pollution after reparation Soil outlet is limited, and now the contaminated soil after many site remediations in China take concentration bank up also demonstrate its be difficult to again it is sharp Difficulty.
In order to solve the problems, such as to dispose after soil after repairing, low concentration oil-polluted soils are prepared as gently by present invention proposition The method of matter revetment brick, so that low concentration oil-polluted soils can be with disposal of resources.Publication No. CN10235870A's is special Benefit discloses a kind of method with high chromium-polluted soil sintering preparing ceramsite, and briquetting pressure is high, calcining time is long, roasting temperature Degree is high, causes the cost of manufacture of haydite very high, and the haydite density produced is high, deficiency in economic performance;Publication No. The patent of CN102173850A discloses the energy-saving contaminated soil of one kind and desilting sediment disposes potting grain technology jointly, Demand to river bottom mud seriously limits the application region of the technology, and its calcining time is long, leads to ceramic product cost It improves.In conclusion now China's contaminated soil preparation resource utilization haydite or revetment brick technology there are it is at high cost, by The problem of to territory restriction.
Summary of the invention
The purpose of the present invention is to provide a kind of application low concentration oil-polluted soils to prepare revetment brick method.
The present invention to achieve the above object, using following technical scheme:
A kind of disposal of resources method of low concentration oil-polluted soils, comprising the following steps:
(1) petroleum soil is crushed to 80 mesh by physics mode hereinafter, and carrying out partial size screening by vibrating screen;
(2) different according to soil chemistry component, the Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and will be former Material is uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) it by the life brick blank drying in step (3) and is sent into rotary kiln and roasts certain time at high temperature.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.
(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.
In the present invention, it is preferred to, physics crumbling method described in step (1) is refered in particular to using ball milling to low concentration petroleum Contaminated soil is ground.
In the present invention, it is preferred to, Extra-fine sand in step (2), coarse sand additive amount test obtain in accordance with the following methods: will Low concentration oil-polluted soils are separately added into the Extra-fine sand of 0-40% and the coarse sand of 0-10%, form after mixing, are placed in a furnace Roasting, maturing temperature are selected as 850-1250 DEG C, and calcining time is 10-25 minutes.Natural cooling after roasting obtains lightweight slope protection Brick product.Oil content, revetment brick product quality in revetment brick are detected, when the former is up to standard, the latter is product demand value, at this time Proportion scale, temperature, the time be actual demand value.Preferably, low concentration oil-polluted soils, Extra-fine sand, coarse sand and water Ratio are as follows: 100:10:3:5-100:20:5:0;Maturing temperature is 1000-1250 DEG C;Calcining time is 15min;
In the present invention, it is preferred to, Extra-fine sand described in step (2) is that desiccation Extra-fine sand is often used in architectural engineering.
In the present invention, it is preferred to, rotary kiln described in step (4) is revetment brick rotary kiln special.
In the present invention, it is preferred to, revetment brick described in step (5) refers in particular to lightweight revetment brick.
Compared with prior art, the beneficial effects of the present invention are:
Application low concentration oil-polluted soils through the invention prepare revetment brick method, can be by low concentration oil pollution Soil is recycled, and obtains revetment brick, solve the preparation resource utilization of China's contaminated soil now haydite or The technology of revetment brick there are problems that it is at high cost, by territory restriction.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, implement below with reference to best The present invention is described in further detail for example.
Embodiment 1: certain place petroleum silty clay soil, preparation lightweight revetment brick method are as follows:
(1) contaminated soil of site is milled to 80 now using ball mill, and soil particle diameter sieve is carried out by vibrating screen Choosing;
(2) add 10% Extra-fine sand, 3% coarse sand, 5% water, and be uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) the life brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature.Firing temperature is 1250 DEG C, calcining time 25min.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.Through detecting Volatility, nonvolatile organic compound content are lower than detection limit (GB 5085) in slope protection brick product, and slope protection brick product belongs to 800 grades (GB/T 17431)。
(6) tail gas that step (4) generates reaches standard (GB 16297) by cooling, dust removal process, detection indices After discharge.
Embodiment 2: certain place petroleum sand, preparation lightweight revetment brick method are as follows:
(1) contaminated soil of site is milled to 80 now using ball mill, and soil particle diameter sieve is carried out by vibrating screen Choosing;
(2) add 20% Extra-fine sand, 5% coarse sand, 0% water, and be uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) the life brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature.Firing temperature is 1000 DEG C, calcining time 15min.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.Through detecting Volatility, nonvolatile organic compound content are lower than detection limit (GB 5085) in slope protection brick product, and slope protection brick product belongs to 600 grades (GB/T 17431)。
(6) tail gas that step (4) generates reaches standard (GB 16297) by cooling, dust removal process, detection indices After discharge.
The above is only a preferred embodiment of the present invention, for those of ordinary skill in the art, according to the present invention Thought, there will be changes in the specific implementation manner and application range, and the content of the present specification should not be construed as to the present invention Limitation.

Claims (6)

1. a kind of application low concentration oil-polluted soils prepare revetment brick method, which comprises the following steps:
(1) total petroleum hydrocarbon concentration is crushed to 80 mesh hereinafter, and leading to by physics mode for the petroleum soil no more than 5mg/kg It crosses vibrating screen and carries out partial size screening;
(2) different according to soil chemistry component, the Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and raw material is mixed It closes uniform;
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain adobe;
(4) brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature;
(5) after being burnt into molding revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained;
(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.
2. according to the method described in claim 1, it is characterized in that physics crumbling method described in step (1) is refered in particular to using ball Mill grinds low concentration oil-polluted soils.
3. according to the method described in claim 1, it is characterized in that the additive amount of Extra-fine sand, coarse sand is according to following in step (2) Method test obtains: low concentration oil-polluted soils being separately added into the Extra-fine sand of 0-40% and the coarse sand of 0-10%, after mixing Molding is placed in a kiln roasting, and maturing temperature is selected as 850-1250 DEG C, and calcining time is 10-25 minutes;It is naturally cold after roasting But, lightweight slope protection brick product is obtained;Oil content, revetment brick product quality in revetment brick are detected, when the former is up to standard, the latter is to produce When product requirements, proportion scale at this time, temperature, time are actual demand value.
4. according to the method described in claim 1, it is characterized in that Extra-fine sand described in step (2) is that architectural engineering is common dry Change Extra-fine sand.
5. according to the method described in claim 1, it is characterized in that rotary kiln described in step (4) is revetment brick Special rotating Kiln.
6. according to the method described in claim 1, it is characterized in that revetment brick described in step (5) refers in particular to lightweight revetment brick.
CN201910429664.2A 2019-05-22 2019-05-22 The method for preparing revetment brick using low concentration oil-polluted soils Pending CN110171956A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111516128A (en) * 2020-04-14 2020-08-11 广西博世科环保科技股份有限公司 Resource treatment method for high-concentration petroleum hydrocarbon contaminated soil
CN111825425A (en) * 2020-07-07 2020-10-27 广州市第一市政工程有限公司 Method and equipment for repairing and safely utilizing organic contaminated soil

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02503690A (en) * 1988-08-05 1990-11-01 トーマス ビーゼングルント A method for producing components, elements or compounds from mixtures of substances
US20100199808A1 (en) * 1993-12-03 2010-08-12 Geobiotics, Llc Method for recovering metal values from refractory sulfide ore
CN101913842A (en) * 2010-07-23 2010-12-15 广州绿由工业弃置废物回收处理有限公司 Baked light-weight environmental-friendly bricks prepared from paper mill sludge and manufacturing method thereof
CN102642241A (en) * 2012-05-07 2012-08-22 王梅农 Comprehensive treatment of soil containing much waste
CN106560461A (en) * 2016-05-17 2017-04-12 中科鼎实环境工程有限公司 Repairing and resourceful treatment method of contaminated soil
CN107082607A (en) * 2017-06-03 2017-08-22 合肥慧林建材有限公司 A kind of road ecological revetment brick and preparation method thereof
CN107583945A (en) * 2017-10-31 2018-01-16 爱土工程环境科技有限公司 A kind of method of organic polluted soil production fired brick
CN108585937A (en) * 2018-07-11 2018-09-28 合肥尚涵装饰工程有限公司 A kind of light-weight insulating brick of pressure resistance anticracking
CN108675709A (en) * 2018-04-23 2018-10-19 中科鼎实环境工程股份有限公司 It is a kind of repaired using thermal desorption after soil processing revetment brick method and products thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02503690A (en) * 1988-08-05 1990-11-01 トーマス ビーゼングルント A method for producing components, elements or compounds from mixtures of substances
US20100199808A1 (en) * 1993-12-03 2010-08-12 Geobiotics, Llc Method for recovering metal values from refractory sulfide ore
CN101913842A (en) * 2010-07-23 2010-12-15 广州绿由工业弃置废物回收处理有限公司 Baked light-weight environmental-friendly bricks prepared from paper mill sludge and manufacturing method thereof
CN102642241A (en) * 2012-05-07 2012-08-22 王梅农 Comprehensive treatment of soil containing much waste
CN106560461A (en) * 2016-05-17 2017-04-12 中科鼎实环境工程有限公司 Repairing and resourceful treatment method of contaminated soil
CN107082607A (en) * 2017-06-03 2017-08-22 合肥慧林建材有限公司 A kind of road ecological revetment brick and preparation method thereof
CN107583945A (en) * 2017-10-31 2018-01-16 爱土工程环境科技有限公司 A kind of method of organic polluted soil production fired brick
CN108675709A (en) * 2018-04-23 2018-10-19 中科鼎实环境工程股份有限公司 It is a kind of repaired using thermal desorption after soil processing revetment brick method and products thereof
CN108585937A (en) * 2018-07-11 2018-09-28 合肥尚涵装饰工程有限公司 A kind of light-weight insulating brick of pressure resistance anticracking

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111516128A (en) * 2020-04-14 2020-08-11 广西博世科环保科技股份有限公司 Resource treatment method for high-concentration petroleum hydrocarbon contaminated soil
CN111825425A (en) * 2020-07-07 2020-10-27 广州市第一市政工程有限公司 Method and equipment for repairing and safely utilizing organic contaminated soil

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Application publication date: 20190827