CN110171956A - The method for preparing revetment brick using low concentration oil-polluted soils - Google Patents
The method for preparing revetment brick using low concentration oil-polluted soils Download PDFInfo
- Publication number
- CN110171956A CN110171956A CN201910429664.2A CN201910429664A CN110171956A CN 110171956 A CN110171956 A CN 110171956A CN 201910429664 A CN201910429664 A CN 201910429664A CN 110171956 A CN110171956 A CN 110171956A
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- CN
- China
- Prior art keywords
- revetment brick
- low concentration
- polluted soils
- concentration oil
- brick
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1328—Waste materials; Refuse; Residues without additional clay
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02B—HYDRAULIC ENGINEERING
- E02B3/00—Engineering works in connection with control or use of streams, rivers, coasts, or other marine sites; Sealings or joints for engineering works in general
- E02B3/04—Structures or apparatus for, or methods of, protecting banks, coasts, or harbours
- E02B3/12—Revetment of banks, dams, watercourses, or the like, e.g. the sea-floor
- E02B3/14—Preformed blocks or slabs for forming essentially continuous surfaces; Arrangements thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Civil Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention belongs to contaminated soil process fields, and in particular to a kind of application low concentration oil-polluted soils prepare revetment brick method, comprising the following steps: (1) by petroleum soil breaking to 80 mesh hereinafter, and passing through vibrating screen and carrying out partial size screening;(2) Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and raw material is uniformly mixed;(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain adobe;(4) high-temperature roasting;(5) wait be burnt into molding revetment brick natural cooling;(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.Application low concentration oil-polluted soils through the invention prepare revetment brick method; low concentration oil-polluted soils can be recycled; and obtain revetment brick, solve the problems, such as the technology of the haydite of the preparation resource utilization of China's contaminated soil now or revetment brick there are it is at high cost, by territory restriction.
Description
Technical field
The invention belongs to contaminated soil process fields, and in particular to a kind of application low concentration oil-polluted soils prepare slope protection
Brick method.
Background technique
Low concentration oil-polluted soils fecund is raw in industries such as oil refining, coal gas, coal tar processing, pitch processing.With me
The transition of state's development, such plant area gradually moves, is transformed, but the low concentration oil-polluted soils earth volume carried over is huge
Greatly, the restorative procedure of low concentration oil-polluted soils (total petroleum hydrocarbon concentration is no more than 5mg/kg) is more mature, but repairs
Soil outlet afterwards is always the problem that government, enterprise face.The processing mode of soil after China is repaired at present mainly has green
Change, backfill, paving the way, making 4 kinds of cement.Wherein afforest more demanding to soil soil property and the content of organic matter, and dosage is less;
Whether backfill is higher to the mechanical property requirements of soil, furthermore backfill and also need to be determined according to the requirement of owner;It paves the way by soil
The limitation of earth transportation range, cost improves rapidly when long-distance transport;Production cement products then have strictly the chemical component of soil
It is required that additionally demand of the heavy dependence locality to cement products.In summary 4 kinds of methods, it can be seen that the pollution after reparation
Soil outlet is limited, and now the contaminated soil after many site remediations in China take concentration bank up also demonstrate its be difficult to again it is sharp
Difficulty.
In order to solve the problems, such as to dispose after soil after repairing, low concentration oil-polluted soils are prepared as gently by present invention proposition
The method of matter revetment brick, so that low concentration oil-polluted soils can be with disposal of resources.Publication No. CN10235870A's is special
Benefit discloses a kind of method with high chromium-polluted soil sintering preparing ceramsite, and briquetting pressure is high, calcining time is long, roasting temperature
Degree is high, causes the cost of manufacture of haydite very high, and the haydite density produced is high, deficiency in economic performance;Publication No.
The patent of CN102173850A discloses the energy-saving contaminated soil of one kind and desilting sediment disposes potting grain technology jointly,
Demand to river bottom mud seriously limits the application region of the technology, and its calcining time is long, leads to ceramic product cost
It improves.In conclusion now China's contaminated soil preparation resource utilization haydite or revetment brick technology there are it is at high cost, by
The problem of to territory restriction.
Summary of the invention
The purpose of the present invention is to provide a kind of application low concentration oil-polluted soils to prepare revetment brick method.
The present invention to achieve the above object, using following technical scheme:
A kind of disposal of resources method of low concentration oil-polluted soils, comprising the following steps:
(1) petroleum soil is crushed to 80 mesh by physics mode hereinafter, and carrying out partial size screening by vibrating screen;
(2) different according to soil chemistry component, the Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and will be former
Material is uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) it by the life brick blank drying in step (3) and is sent into rotary kiln and roasts certain time at high temperature.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.
(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.
In the present invention, it is preferred to, physics crumbling method described in step (1) is refered in particular to using ball milling to low concentration petroleum
Contaminated soil is ground.
In the present invention, it is preferred to, Extra-fine sand in step (2), coarse sand additive amount test obtain in accordance with the following methods: will
Low concentration oil-polluted soils are separately added into the Extra-fine sand of 0-40% and the coarse sand of 0-10%, form after mixing, are placed in a furnace
Roasting, maturing temperature are selected as 850-1250 DEG C, and calcining time is 10-25 minutes.Natural cooling after roasting obtains lightweight slope protection
Brick product.Oil content, revetment brick product quality in revetment brick are detected, when the former is up to standard, the latter is product demand value, at this time
Proportion scale, temperature, the time be actual demand value.Preferably, low concentration oil-polluted soils, Extra-fine sand, coarse sand and water
Ratio are as follows: 100:10:3:5-100:20:5:0;Maturing temperature is 1000-1250 DEG C;Calcining time is 15min;
In the present invention, it is preferred to, Extra-fine sand described in step (2) is that desiccation Extra-fine sand is often used in architectural engineering.
In the present invention, it is preferred to, rotary kiln described in step (4) is revetment brick rotary kiln special.
In the present invention, it is preferred to, revetment brick described in step (5) refers in particular to lightweight revetment brick.
Compared with prior art, the beneficial effects of the present invention are:
Application low concentration oil-polluted soils through the invention prepare revetment brick method, can be by low concentration oil pollution
Soil is recycled, and obtains revetment brick, solve the preparation resource utilization of China's contaminated soil now haydite or
The technology of revetment brick there are problems that it is at high cost, by territory restriction.
Specific embodiment
In order to make those skilled in the art more fully understand technical solution of the present invention, implement below with reference to best
The present invention is described in further detail for example.
Embodiment 1: certain place petroleum silty clay soil, preparation lightweight revetment brick method are as follows:
(1) contaminated soil of site is milled to 80 now using ball mill, and soil particle diameter sieve is carried out by vibrating screen
Choosing;
(2) add 10% Extra-fine sand, 3% coarse sand, 5% water, and be uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) the life brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature.Firing temperature is 1250
DEG C, calcining time 25min.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.Through detecting
Volatility, nonvolatile organic compound content are lower than detection limit (GB 5085) in slope protection brick product, and slope protection brick product belongs to 800 grades
(GB/T 17431)。
(6) tail gas that step (4) generates reaches standard (GB 16297) by cooling, dust removal process, detection indices
After discharge.
Embodiment 2: certain place petroleum sand, preparation lightweight revetment brick method are as follows:
(1) contaminated soil of site is milled to 80 now using ball mill, and soil particle diameter sieve is carried out by vibrating screen
Choosing;
(2) add 20% Extra-fine sand, 5% coarse sand, 0% water, and be uniformly mixed.
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain raw adobe.
(4) the life brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature.Firing temperature is 1000
DEG C, calcining time 15min.
(5) after being burnt into revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained.Through detecting
Volatility, nonvolatile organic compound content are lower than detection limit (GB 5085) in slope protection brick product, and slope protection brick product belongs to 600 grades
(GB/T 17431)。
(6) tail gas that step (4) generates reaches standard (GB 16297) by cooling, dust removal process, detection indices
After discharge.
The above is only a preferred embodiment of the present invention, for those of ordinary skill in the art, according to the present invention
Thought, there will be changes in the specific implementation manner and application range, and the content of the present specification should not be construed as to the present invention
Limitation.
Claims (6)
1. a kind of application low concentration oil-polluted soils prepare revetment brick method, which comprises the following steps:
(1) total petroleum hydrocarbon concentration is crushed to 80 mesh hereinafter, and leading to by physics mode for the petroleum soil no more than 5mg/kg
It crosses vibrating screen and carries out partial size screening;
(2) different according to soil chemistry component, the Extra-fine sand of 0-40%, the coarse sand of 0-10%, suitable quantity of water are added, and raw material is mixed
It closes uniform;
(3) mixed raw material is sent into brickmaking machine and carries out brickmaking, obtain adobe;
(4) brick blank drying in step (3) and being sent into rotary kiln is roasted at high temperature;
(5) after being burnt into molding revetment brick natural cooling, the revetment brick prepared with low concentration oil-polluted soils is obtained;
(6) tail gas that step (4) generates discharges after reaching standard by cooling, dust removal process, detection indices.
2. according to the method described in claim 1, it is characterized in that physics crumbling method described in step (1) is refered in particular to using ball
Mill grinds low concentration oil-polluted soils.
3. according to the method described in claim 1, it is characterized in that the additive amount of Extra-fine sand, coarse sand is according to following in step (2)
Method test obtains: low concentration oil-polluted soils being separately added into the Extra-fine sand of 0-40% and the coarse sand of 0-10%, after mixing
Molding is placed in a kiln roasting, and maturing temperature is selected as 850-1250 DEG C, and calcining time is 10-25 minutes;It is naturally cold after roasting
But, lightweight slope protection brick product is obtained;Oil content, revetment brick product quality in revetment brick are detected, when the former is up to standard, the latter is to produce
When product requirements, proportion scale at this time, temperature, time are actual demand value.
4. according to the method described in claim 1, it is characterized in that Extra-fine sand described in step (2) is that architectural engineering is common dry
Change Extra-fine sand.
5. according to the method described in claim 1, it is characterized in that rotary kiln described in step (4) is revetment brick Special rotating
Kiln.
6. according to the method described in claim 1, it is characterized in that revetment brick described in step (5) refers in particular to lightweight revetment brick.
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CN201910429664.2A CN110171956A (en) | 2019-05-22 | 2019-05-22 | The method for preparing revetment brick using low concentration oil-polluted soils |
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CN201910429664.2A CN110171956A (en) | 2019-05-22 | 2019-05-22 | The method for preparing revetment brick using low concentration oil-polluted soils |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111516128A (en) * | 2020-04-14 | 2020-08-11 | 广西博世科环保科技股份有限公司 | Resource treatment method for high-concentration petroleum hydrocarbon contaminated soil |
CN111825425A (en) * | 2020-07-07 | 2020-10-27 | 广州市第一市政工程有限公司 | Method and equipment for repairing and safely utilizing organic contaminated soil |
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JPH02503690A (en) * | 1988-08-05 | 1990-11-01 | トーマス ビーゼングルント | A method for producing components, elements or compounds from mixtures of substances |
US20100199808A1 (en) * | 1993-12-03 | 2010-08-12 | Geobiotics, Llc | Method for recovering metal values from refractory sulfide ore |
CN101913842A (en) * | 2010-07-23 | 2010-12-15 | 广州绿由工业弃置废物回收处理有限公司 | Baked light-weight environmental-friendly bricks prepared from paper mill sludge and manufacturing method thereof |
CN102642241A (en) * | 2012-05-07 | 2012-08-22 | 王梅农 | Comprehensive treatment of soil containing much waste |
CN106560461A (en) * | 2016-05-17 | 2017-04-12 | 中科鼎实环境工程有限公司 | Repairing and resourceful treatment method of contaminated soil |
CN107082607A (en) * | 2017-06-03 | 2017-08-22 | 合肥慧林建材有限公司 | A kind of road ecological revetment brick and preparation method thereof |
CN107583945A (en) * | 2017-10-31 | 2018-01-16 | 爱土工程环境科技有限公司 | A kind of method of organic polluted soil production fired brick |
CN108585937A (en) * | 2018-07-11 | 2018-09-28 | 合肥尚涵装饰工程有限公司 | A kind of light-weight insulating brick of pressure resistance anticracking |
CN108675709A (en) * | 2018-04-23 | 2018-10-19 | 中科鼎实环境工程股份有限公司 | It is a kind of repaired using thermal desorption after soil processing revetment brick method and products thereof |
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2019
- 2019-05-22 CN CN201910429664.2A patent/CN110171956A/en active Pending
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JPH02503690A (en) * | 1988-08-05 | 1990-11-01 | トーマス ビーゼングルント | A method for producing components, elements or compounds from mixtures of substances |
US20100199808A1 (en) * | 1993-12-03 | 2010-08-12 | Geobiotics, Llc | Method for recovering metal values from refractory sulfide ore |
CN101913842A (en) * | 2010-07-23 | 2010-12-15 | 广州绿由工业弃置废物回收处理有限公司 | Baked light-weight environmental-friendly bricks prepared from paper mill sludge and manufacturing method thereof |
CN102642241A (en) * | 2012-05-07 | 2012-08-22 | 王梅农 | Comprehensive treatment of soil containing much waste |
CN106560461A (en) * | 2016-05-17 | 2017-04-12 | 中科鼎实环境工程有限公司 | Repairing and resourceful treatment method of contaminated soil |
CN107082607A (en) * | 2017-06-03 | 2017-08-22 | 合肥慧林建材有限公司 | A kind of road ecological revetment brick and preparation method thereof |
CN107583945A (en) * | 2017-10-31 | 2018-01-16 | 爱土工程环境科技有限公司 | A kind of method of organic polluted soil production fired brick |
CN108675709A (en) * | 2018-04-23 | 2018-10-19 | 中科鼎实环境工程股份有限公司 | It is a kind of repaired using thermal desorption after soil processing revetment brick method and products thereof |
CN108585937A (en) * | 2018-07-11 | 2018-09-28 | 合肥尚涵装饰工程有限公司 | A kind of light-weight insulating brick of pressure resistance anticracking |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111516128A (en) * | 2020-04-14 | 2020-08-11 | 广西博世科环保科技股份有限公司 | Resource treatment method for high-concentration petroleum hydrocarbon contaminated soil |
CN111825425A (en) * | 2020-07-07 | 2020-10-27 | 广州市第一市政工程有限公司 | Method and equipment for repairing and safely utilizing organic contaminated soil |
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Application publication date: 20190827 |