CN110157367A - A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof - Google Patents

A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof Download PDF

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Publication number
CN110157367A
CN110157367A CN201910497152.XA CN201910497152A CN110157367A CN 110157367 A CN110157367 A CN 110157367A CN 201910497152 A CN201910497152 A CN 201910497152A CN 110157367 A CN110157367 A CN 110157367A
Authority
CN
China
Prior art keywords
hot melt
melt adhesive
mosquito repellent
disposable sanitary
sanitary articles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910497152.XA
Other languages
Chinese (zh)
Inventor
彭军
钟蓉
范培军
黎明
余刚树
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Jujiao Adhesive Co Ltd
Original Assignee
Guangdong Jujiao Adhesive Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Jujiao Adhesive Co Ltd filed Critical Guangdong Jujiao Adhesive Co Ltd
Priority to CN201910497152.XA priority Critical patent/CN110157367A/en
Publication of CN110157367A publication Critical patent/CN110157367A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02Vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J157/00Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09J157/02Copolymers of mineral oil hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof, the hot melt adhesive is made of main polymer, tackifying resin, White Mineral Oil, culicifuge and antioxidant, preparation method includes the following steps: 1) reaction kettle is added in main polymer, White Mineral Oil and antioxidant, 145~160 DEG C are heated to, stirring is vacuumized and is melted completely to material;2) reaction kettle is added in tackifying resin, constant temperature is stirred to material and melted completely, adds culicifuge, and constant temperature stirs evenly, then stops stirring, and is evacuated to bubble-free in material.Disposable sanitary articles mosquito repellent hot melt adhesive of the invention has apparent expelling mosquito, causes the unresponsive effect of mosquito, and adhesion strength is high, peeling force is big.

Description

A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof
Technical field
The present invention relates to a kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof.
Background technique
Hot melt adhesive is a kind of adhesive of plasticity, its physical state changes with temperature and changed in certain temperature range Become, and chemical characteristic is constant, it is non-toxic and tasteless, belong to environmental-protecting chemical product, is widely used in hygienic articles, packaging, book Nationality bookbinding, clothes, adhesive tape, shoemaking, refrigerator, cable, automobile and other industries.
The state of development in domestic hot melt adhesive market and developed country are widely different, on the developed countries such as America and Europe, Japan and ground Area, the industry for accounting for 4 before hot melt adhesive market is packaging, hygienic articles, bookbinding, carpenter or assembling respectively, wherein packaging row Industry accounts for the 30%~40% of market aggregate demand, and domestic hot melt adhesive market account for former industries be respectively hygienic articles, clothes, Glue stick, books and packaging, wherein hygienic articles are ranked first with glue, and it is sanitary napkin and baby that accounting is maximum in hygienic articles Both disposable sanitary articles of paper diaper.
Disposable sanitary articles are the market of a high speed development with hot melt adhesive market, and the past 10 years compound growth rates are high Up to 16%.With the relieving of national two tire policies, the market demand of baby paper diaper is very big, and hot melt adhesive is baby paper diaper Basic material, therefore have broad application prospects.Along with the fast development and consumption upgrading in market, not only to disposably defending The quality of raw articles has higher requirement, and to the function of disposable sanitary articles, there has also been some new requirements, such as urinate Aobvious, sterilization, repelling effect etc..
Therefore, a kind of disposable sanitary articles mosquito repellent hot melt adhesive product is developed for pushing the upgrading of downstream product function The replacement is of great significance.
Summary of the invention
The purpose of the present invention is to provide a kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof.
The technical solution used in the present invention is:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, consists of the following mass percentage components:
Main polymer: 10%~25%;
Tackifying resin: 40%~55%;
White Mineral Oil: 10%~20%;
Culicifuge: 5%~20%;
Antioxidant: 0.1%~0.5%.
Preferably, a kind of disposable sanitary articles mosquito repellent hot melt adhesive, consists of the following mass percentage components:
Main polymer: 14%~25%;
Tackifying resin: 45%~55%;
White Mineral Oil: 10%~20%;
Culicifuge: 8%~20%;
Antioxidant: 0.1%~0.5%.
Preferably, the main polymer is that Styrene-Butadiene-Styrene Block Copolymer (SBS), styrene-are different Isoprene-styrene block copolymer (SIS), styrene-ethylene-butylene-styrene block copolymer (SEBS), ethylene-vinegar At least one of sour ethylene copolymer (EVA).
Preferably, the mass percentage of styrene is less than in the Styrene-Butadiene-Styrene Block Copolymer 30%.
Preferably, the mass percentage of styrene is less than in the styrene-isoprene-styrene block copolymer 30%.
Preferably, the tackifying resin is at least one of Petropols, hydrogenated petroleum resin.
Preferably, the Petropols are at least one of C5 Petropols, C9 Petropols, DCPD Petropols.
Preferably, the hydrogenated petroleum resin is C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin, DCPD hydrotreated petroleum tree At least one of rouge.
Preferably, the mass percentage of cycloalkane is greater than 40% in the White Mineral Oil.
Preferably, the culicifuge is at least one of mosquito repellent rouge, Peppermint essential oil, eucalyptus leaf oil.
Preferably, the antioxidant is antioxidant 1010, irgasfos 168, antioxidant CA, at least one in antioxidant BHT Kind.
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) reaction kettle is added in main polymer, White Mineral Oil and antioxidant, is heated to 145~160 DEG C, vacuumize stirring extremely Material melts completely;
2) reaction kettle is added in tackifying resin, constant temperature is stirred to material and melted completely, adds culicifuge, and constant temperature stirring is equal It is even,
Stop stirring again, be evacuated to bubble-free in material, obtains disposable sanitary articles mosquito repellent hot melt adhesive.
The beneficial effects of the present invention are: disposable sanitary articles mosquito repellent hot melt adhesive of the invention, which has, significantly drives mosquito Worm causes the unresponsive effect of mosquito, and adhesion strength is high, peeling force is big.
Detailed description of the invention
Fig. 1 is the infrared spectrogram of the disposable sanitary articles mosquito repellent hot melt adhesive of embodiment 3.
Specific embodiment
The present invention will be further explained combined with specific embodiments below and explanation.
Embodiment 1:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, raw material composition are as shown in the table:
A kind of raw material of the disposable sanitary articles of table 1 mosquito repellent hot melt adhesive forms table
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) reaction kettle, heating is added in Styrene-Butadiene-Styrene Block Copolymer, White Mineral Oil and antioxidant 1010 To 150 DEG C, vacuumizes stirring and melted completely to material;
2) reaction kettle is added in C5 Petropols, constant temperature is stirred to material and melted completely, adds Peppermint essential oil, constant temperature stirs It mixes uniformly, then stops stirring, be evacuated to bubble-free in material, obtain disposable sanitary articles mosquito repellent hot melt adhesive (infrared light Spectrogram is as shown in Figure 1).
Above-mentioned disposable sanitary articles are tested for the property with mosquito repellent hot melt adhesive, test result is as follows shown in table:
The performance test results of table 2 disposable sanitary articles mosquito repellent hot melt adhesive
Note:
SUMMIT: spiral glue spraying mode.
Embodiment 2:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, raw material composition are as shown in the table:
A kind of raw material of the disposable sanitary articles of table 3 mosquito repellent hot melt adhesive forms table
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) reaction kettle is added in styrene-ethylene-butylene-styrene block copolymer, White Mineral Oil and antioxidant 1010, added Heat vacuumizes stirring and melts completely to material to 150 DEG C;
2) reaction kettle is added in C9 hydrogenated petroleum resin, constant temperature is stirred to material and melted completely, adds eucalyptus leaf oil, permanent Temperature stirs evenly, then stops stirring, and is evacuated to bubble-free in material, obtains disposable sanitary articles mosquito repellent hot melt adhesive.
Above-mentioned disposable sanitary articles are tested for the property with mosquito repellent hot melt adhesive, test result is as follows shown in table:
The performance test results of table 4 disposable sanitary articles mosquito repellent hot melt adhesive
Note:
SUMMIT: spiral glue spraying mode.
Embodiment 3:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, raw material composition are as shown in the table:
A kind of raw material of the disposable sanitary articles of table 5 mosquito repellent hot melt adhesive forms table
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) by Styrene-Butadiene-Styrene Block Copolymer, ethylene-vinyl acetate copolymer, White Mineral Oil and antioxidant 1010 are added reaction kettle, are heated to 160 DEG C, vacuumize stirring and melt completely to material;
2) reaction kettle is added in DCPD Petropols, constant temperature is stirred to material and melted completely, adds mosquito repellent rouge, constant temperature stirs It mixes uniformly, then stops stirring, be evacuated to bubble-free in material, obtain disposable sanitary articles mosquito repellent hot melt adhesive.
Above-mentioned disposable sanitary articles are tested for the property with mosquito repellent hot melt adhesive, test result is as follows shown in table:
The performance test results of table 6 disposable sanitary articles mosquito repellent hot melt adhesive
Note:
SUMMIT: spiral glue spraying mode.
Embodiment 4:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, raw material composition are as shown in the table:
A kind of raw material of the disposable sanitary articles of table 7 mosquito repellent hot melt adhesive forms table
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) reaction kettle is added in styrene-isoprene-styrene block copolymer, White Mineral Oil and antioxidant 1010, added Heat vacuumizes stirring and melts completely to material to 155 DEG C;
2) reaction kettle being added in C5 Petropols and C9 hydrogenated petroleum resin, constant temperature is stirred to material and is melted completely, then plus Enter Peppermint essential oil and eucalyptus leaf oil, constant temperature stirs evenly, then stops stirring, and is evacuated to bubble-free in material, obtains disposable Amenities mosquito repellent hot melt adhesive.
Above-mentioned disposable sanitary articles are tested for the property with mosquito repellent hot melt adhesive, test result is as follows shown in table:
The performance test results of table 8 disposable sanitary articles mosquito repellent hot melt adhesive
Note:
SUMMIT: spiral glue spraying mode.
Embodiment 5:
A kind of disposable sanitary articles mosquito repellent hot melt adhesive, raw material composition are as shown in the table:
A kind of raw material of the disposable sanitary articles of table 9 mosquito repellent hot melt adhesive forms table
The preparation method of above-mentioned disposable sanitary articles mosquito repellent hot melt adhesive the following steps are included:
1) reaction kettle is added in styrene-isoprene-styrene block copolymer, White Mineral Oil and antioxidant 1010, added Heat vacuumizes stirring and melts completely to material to 155 DEG C;
2) reaction kettle being added in C5 Petropols and C9 hydrogenated petroleum resin, constant temperature is stirred to material and is melted completely, then plus Enter dimethyl phthalate and eucalyptus leaf oil, constant temperature stirs evenly, then stops stirring, and is evacuated to bubble-free in material, is disposably defended Raw articles mosquito repellent hot melt adhesive.
Above-mentioned disposable sanitary articles are tested for the property with mosquito repellent hot melt adhesive, test result is as follows shown in table:
The performance test results of table 10 disposable sanitary articles mosquito repellent hot melt adhesive
Note:
SUMMIT: spiral glue spraying mode.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention, It should be equivalent substitute mode, be included within the scope of the present invention.

Claims (10)

1. a kind of disposable sanitary articles mosquito repellent hot melt adhesive, it is characterised in that: consist of the following mass percentage components:
Main polymer: 10%~25%;
Tackifying resin: 40%~55%;
White Mineral Oil: 10%~20%;
Culicifuge: 5%~20%;
Antioxidant: 0.1%~0.5%.
2. disposable sanitary articles according to claim 1 mosquito repellent hot melt adhesive, it is characterised in that: the main polymer For Styrene-Butadiene-Styrene Block Copolymer, styrene-isoprene-styrene block copolymer, styrene-second At least one of alkene-butylene-styrene block copolymer, ethylene-vinyl acetate copolymer.
3. disposable sanitary articles according to claim 2 mosquito repellent hot melt adhesive, it is characterised in that: the styrene-fourth The mass percentage of styrene is less than 30% in styrene block copolymer.
4. disposable sanitary articles according to claim 2 mosquito repellent hot melt adhesive, it is characterised in that: the styrene-is different The mass percentage of styrene is less than 30% in isoprene-styrene block copolymer.
5. disposable sanitary articles according to claim 1 or 2 mosquito repellent hot melt adhesive, it is characterised in that: the thickening tree Rouge is at least one of Petropols, hydrogenated petroleum resin.
6. disposable sanitary articles according to claim 5 mosquito repellent hot melt adhesive, it is characterised in that: the Petropols are At least one of C5 Petropols, C9 Petropols, DCPD Petropols.
7. disposable sanitary articles according to claim 5 mosquito repellent hot melt adhesive, it is characterised in that: the non-hydrogenated petroleum tree Rouge is at least one of C5 hydrogenated petroleum resin, C9 hydrogenated petroleum resin, DCPD hydrogenated petroleum resin.
8. disposable sanitary articles according to claim 1 or 2 mosquito repellent hot melt adhesive, it is characterised in that: the White Mineral Oil The mass percentage of middle cycloalkane is greater than 40%.
9. disposable sanitary articles according to claim 1 or 2 mosquito repellent hot melt adhesive, it is characterised in that: the culicifuge For at least one of mosquito repellent rouge, Peppermint essential oil, eucalyptus leaf oil.
10. the preparation method of mosquito repellent hot melt adhesive of disposable sanitary articles described in any one of claim 1~9, special Sign is: the following steps are included:
1) reaction kettle is added in main polymer, White Mineral Oil and antioxidant, is heated to 145~160 DEG C, vacuumize stirring to material Melting completely;
2) reaction kettle being added in tackifying resin, constant temperature is stirred to material and is melted completely, adds culicifuge, and constant temperature stirs evenly, Stop stirring again, be evacuated to bubble-free in material, obtains disposable sanitary articles mosquito repellent hot melt adhesive.
CN201910497152.XA 2019-06-06 2019-06-06 A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof Pending CN110157367A (en)

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CN201910497152.XA CN110157367A (en) 2019-06-06 2019-06-06 A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201910497152.XA CN110157367A (en) 2019-06-06 2019-06-06 A kind of disposable sanitary articles mosquito repellent hot melt adhesive and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111978897A (en) * 2020-09-04 2020-11-24 上海路嘉胶粘剂有限公司 Defluorination pressure-sensitive hot melt adhesive for sanitary towel breathable film back adhesive and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646656A (en) * 2002-04-17 2005-07-27 于尔戈实验室 Novel hydrophilic adhesive compositions
CN101186794A (en) * 2007-12-03 2008-05-28 周飞鹏 Adhesive tape for mosquito eradication lamp, hot-melt adhesive of the adhesive tap and preparation method of the hot-melt adhesive
CN102170917A (en) * 2008-08-06 2011-08-31 英威达技术有限公司 Preparation of elastic composite structures useful for components of disposable hygiene products and articles of apparel
WO2015195613A1 (en) * 2014-06-16 2015-12-23 Ingevity South Carolina, Llc Composite polymer materials for modification of adhesive compositions and associated methods of manufacture
CN106085306A (en) * 2016-08-24 2016-11-09 泉州市嘉华卫生用品有限公司 A kind of diaper PUR and preparation method thereof
CN106281150A (en) * 2016-09-07 2017-01-04 李金平 A kind of diaper hot melt adhesive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1646656A (en) * 2002-04-17 2005-07-27 于尔戈实验室 Novel hydrophilic adhesive compositions
CN101186794A (en) * 2007-12-03 2008-05-28 周飞鹏 Adhesive tape for mosquito eradication lamp, hot-melt adhesive of the adhesive tap and preparation method of the hot-melt adhesive
CN102170917A (en) * 2008-08-06 2011-08-31 英威达技术有限公司 Preparation of elastic composite structures useful for components of disposable hygiene products and articles of apparel
WO2015195613A1 (en) * 2014-06-16 2015-12-23 Ingevity South Carolina, Llc Composite polymer materials for modification of adhesive compositions and associated methods of manufacture
CN106085306A (en) * 2016-08-24 2016-11-09 泉州市嘉华卫生用品有限公司 A kind of diaper PUR and preparation method thereof
CN106281150A (en) * 2016-09-07 2017-01-04 李金平 A kind of diaper hot melt adhesive

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111978897A (en) * 2020-09-04 2020-11-24 上海路嘉胶粘剂有限公司 Defluorination pressure-sensitive hot melt adhesive for sanitary towel breathable film back adhesive and preparation method thereof

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Application publication date: 20190823