CN110143639A - A kind of active carbon water purification catridge - Google Patents

A kind of active carbon water purification catridge Download PDF

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Publication number
CN110143639A
CN110143639A CN201910443835.7A CN201910443835A CN110143639A CN 110143639 A CN110143639 A CN 110143639A CN 201910443835 A CN201910443835 A CN 201910443835A CN 110143639 A CN110143639 A CN 110143639A
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parts
tube
active carbon
water
revolving speed
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刘岳定
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/12Halogens or halogen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/32Hydrocarbons, e.g. oil
    • C02F2101/322Volatile compounds, e.g. benzene
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/36Organic compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/004Seals, connections
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of active carbon water purification catridges, including water receiving pipe, filter tube and outlet pipe, the filter tube is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, the outlet pipe is detachably connected on the lower end of the filter tube, and the water receiving pipe and outlet pipe are L-shaped.Active carbon water purification catridge of the present invention; the heterochromatic peculiar smell in raw water is adsorbed by seed activity layer of charcoal; it removes organic matter and improves water tasting; by being improved to the material that elastic rubber covers; with excellent flame and mechanical property; pass through the S-type flow velocity that can slow down water flow of filter tube; to improve water purification efficiency; by water receiving pipe, three parts of filter tube and outlet pipe it is individually designed; it can reduce cost; filter tube is only needed to change when needing replacing, water receiving pipe and outlet pipe can also continue to use.

Description

A kind of active carbon water purification catridge
Technical field
The invention belongs to water purification catridge technical fields, and in particular to a kind of active carbon water purification catridge.
Background technique
With the rapid development of industry, water, air, soil pollution are got worse, and China's source quality constantly deteriorates, many Urban groundwater, superficial water all receive serious pollution, and source quality deteriorates the fast development for exacerbating water purification market.
At present due to the continuous improvement of present living standard, requirement of the people for drinking-water is also higher and higher, and scientific skill Art works it out huge change in order to keep up with the requirement of people, to drinking-water this aspect, has invented the equipment for capableing of water purification, The quality of water can not only be made to be more in line with health standards, moreover it is possible to make cycling utilization of wastewater, meets the policy of country's water conservation, But traditional water purifying apparatus structure is complicated, cost is again high, and water purification efficiency is not also high.
It usually will use the purification that easy water purifier carries out water resource in the purifier of household, and water purification catridge is The core component of water purifier, the quality of filter core directly affect the ability of water purifier purification water resource, water purification catridge typically now Structure is complex, is not easy to install, and in order to ensure purifying water effect, needs often to clean water purification catridge, general net Water filter core is inconvenient to install and dismantle to be cleaned, and uses the quality of clean-up effect variation influence water purification for a long time.
Active carbon is that hole is more, large specific surface area (up to more than 1800 meters squared per grams), the very strong charcoal of adsorption activity, extensively Applied to national defence, pharmacy, chemical industry, food and environmental protection etc..It is original that active carbon, which is with sawdust, branch, charcoal, coal etc., Material, it is obtained by carbonizing and activating.It is divided into chemical carbon (rotary furnace and simple under zinc chloride process according to activation method different activities charcoal Method) and physics charcoal (steam method and method of smouldering), powdery carbon and particle charcoal can be divided by geometry difference.By purposes difference point For sugared charcoal, medical charcoal, water purification charcoal, desulfurization charcoal etc..The element of active carbon forms based on carbon, also contains a small amount of hydrogen, oxygen and ash Point.Active carbon water purification technology is largely effective for removing some pollutants in water removal.The removable substance of active carbon filter core includes: Chlorine, benzene, radon, soluble haloform compound, volatile organic compounds (such as Insecticides (tech) & Herbicides (tech)) and other are hundreds of Kind meeting passes through the artificial hazardous compound of tap water and human contact.In addition, active carbon filter core can remove the peculiar smell of water removal, and The bigger harmful microorganism in some volume ratio active carbons gap such as causes Giardiasis, the Cryptosporidium of pandemic.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of active carbon water purification catridges, and structure is simple, and purifying water effect is good.
In order to achieve the above objectives, the present invention is implemented according to following technical scheme:
A kind of active carbon water purification catridge, including water receiving pipe, filter tube and outlet pipe, the filter tube is S-type, the water receiving Pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the lower end of the filter tube, described to connect Water pipe and outlet pipe are L-shaped, and the filter tube is mutually detachably connected by symmetrical first and second U-tube and is formed, described First U-tube is located at the top of second U-tube, and first U-tube is connect with the water receiving pipe, second U-tube It connect with the outlet pipe, is filtered in first U-tube filled with PP cotton, active carbon is filled in second U-tube, it is described The upper end of water receiving pipe is fixed with the elastic rubber set that can be sheathed in outer water tube.
Further, between first U-tube and the water receiving pipe and second U-tube and the outlet pipe it Between be screwed on by screw thread.
Further, mutual by docking fiber tube between the lower end of first U-tube and the upper end of second U-tube Connection.
Further, the diameter of the filter tube is 10-30mm.
Further, the L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
Further, the material of the elastic rubber set is fire retardant elastic rubber.
Further, the preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 50-70 parts of natural rubber, 10-20 parts of butadiene-styrene rubber, butadiene rubber 5- are weighed by weight 15 parts, 0.7-1.5 parts of stearic acid, 10-20 parts of green mud mountain flour, 5-15 parts of white carbon black, 0.8-1.5 parts of anti-aging agent RD, promotor 1- 2 parts, 4-10 parts of zinc oxide, 1-3 parts of fire retardant, 10-20 parts of precipitated calcium carbonate, 1-3 parts of sulphur;
(2) will be 60-100 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 300-600r/min carries out mixing 8-14min, adds stearic acid, green mud mountain flour, white carbon black, anti-aging agent RD, zinc oxide, fire-retardant Agent, precipitated calcium carbonate temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 15-20min, then be added promote Into agent, sulphur temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 5-10min, obtain mixing glue;It will be close Refining glue is put into vulcanizing press after being placed at room temperature for 10-20h, is vulcanized, and 140-180 DEG C of curing temperature, pressure 0.5- 1.5MPa, time 30-50min then cool to room temperature to get fire retardant elastic rubber.
Further, the preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 50-70 parts of natural rubber, 10-20 parts of butadiene-styrene rubber, butadiene rubber 5- are weighed by weight 15 parts, 0.7-1.5 parts of stearic acid, 10-20 parts of green mud mountain flour modifier, 5-15 parts of white carbon black, 0.8-1.5 parts of anti-aging agent RD, rush Into 1-2 parts of agent, 4-10 parts of zinc oxide, 1-3 parts of fire retardant, 10-20 parts of precipitated calcium carbonate, 1-3 parts of sulphur;
(2) will be 60-100 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 300-600r/min carries out mixing 8-14min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, oxidation Zinc, fire retardant, precipitated calcium carbonate temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 15-20min, then Be added promotor, sulphur temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 5-10min, obtain mixing Glue;Mixing glue is put into vulcanizing press after being placed at room temperature for 10-20h, is vulcanized, 140-180 DEG C of curing temperature, pressure Power 0.5-1.5MPa, time 30-50min then cool to room temperature to get fire retardant elastic rubber.
Further, the promotor is dibenzothiazyl disulfide.
Further, the green mud mountain flour modifier is prepared by following methods: by sodium tripolyphosphate, polyethylene glycol 400, water In mass ratio it is 1:(0.4-0.6): (3-7) is that 100-400r/min is stirred 5-15min and obtains sodium tripolyphosphate with revolving speed Mixed liquor;10-20L water, 2-4kg green mud mountain flour are stirred 5-15min with revolving speed for 100-400r/min, add 800- 900g melamine, 800-900g cyanuric acid, 1-2L sodium tripolyphosphate mixed liquor are stirred with revolving speed for 100-400r/min 5-15min, being warming up to 90-105 DEG C with revolving speed is that 50-150r/min is stirred to react 2-5h, is then centrifuged for separating, and abandoning supernatant will Precipitating is dry to get green mud mountain flour modifier.
Further, the fire retardant is that dodecyl silicic acid ring phosphino- ester compounds and/or tris hydroxymethyl phosphine caged are sub- Phosphate.Further, the fire retardant is by 60-70wt% dodecyl silicic acid ring phosphino- ester compounds and 30-40wt% Tris hydroxymethyl phosphine caged phosphite ester composition.
Active carbon water purification catridge of the present invention adsorbs the heterochromatic peculiar smell in raw water by seed activity layer of charcoal, removes organic matter There is excellent flame and mechanical property, pass through filter core by being improved to the material that elastic rubber covers with improvement water tasting The S-type flow velocity that can slow down water flow is managed, to improve water purification efficiency, passes through three water receiving pipe, filter tube and outlet pipe parts It is individually designed, can reduce cost, filter tube only needed to change when needing replacing, water receiving pipe and outlet pipe can also continue to make With.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of active carbon water purification catridge of the present invention.
Specific embodiment
Each raw material introduction in embodiment: zinc oxide is the model TZP-50's that Jiangsu Tian Hang new material Co., Ltd provides Zinc oxide, primary particle size 30nm.Precipitated calcium carbonate is the 325 mesh level-one lightweight carbon that Lingshou County YaoXin mineral products processing factory provides Sour calcium.Natural rubber is the natural rubber for the model SCR 5 that Hengshui dual force rubber Science and Technology Ltd. provides.White carbon black is spirit The fume colloidal silica for the model A150 that Shou County Kai Yao mineral products processing factory provides, granularity are 3000 mesh.Anti-aging agent RD, CAS Number: 26780-96-1.Butadiene-styrene rubber is that the trade mark that Jilin Petroleum and Chemical Branch of China National Petroleum Corp provides is The butadiene-styrene rubber of SBR1502.Stearic acid, No. CAS: 57-11-4.Sulphur, No. CAS: 7704-34-9.Butadiene rubber is South Korea The trade mark that Seoul branch company, petrochemical industry Co., Ltd provides is the butadiene rubber of BR1208.Dibenzothiazyl disulfide, No. CAS: 120-78-5.Tris hydroxymethyl phosphine caged phosphite ester is according to embodiment 1 in the Chinese patent application No. is 201510404516.7 Shown method preparation.Sodium tripolyphosphate is the industrial sodium tripolyphosphate that Yuan Li Chemical Co., Ltd. in Suzhou provides.Melamine, No. CAS: 108-78-1.Cyanuric acid, No. CAS: 108-80-5.Dodecyl silicic acid ring phosphino- ester compounds according to application No. is 201510707742.2 Chinese patent in the preparation of method shown in embodiment 6.Polyethylene glycol 400 is Jiangsu Province Hai'an petrochemical industry The polyethylene glycol 400 for the model PEG-400 that factory provides.Green mud mountain flour is 1250 that Lingshou County Shuo Long mineral products processing factory provides Mesh green mud mountain flour.
Embodiment 1
Such as Fig. 1, a kind of active carbon water purification catridge of the invention, including water receiving pipe 1, filter tube 2 and outlet pipe 3, the filter Core pipe is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter The lower end of core pipe, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is by symmetrical first and second U-tube 6,7 phases It is mutually detachably connected composition, first U-tube is located at the top of second U-tube, first U-tube and the water receiving Pipe connection, second U-tube are connect with the outlet pipe, are filtered in first U-tube filled with PP cotton, described second is U-shaped Active carbon is filled in pipe.
The upper end of the water receiving pipe is fixed with the elastic rubber set 4 that can be sheathed in outer water tube.
Pass through between first U-tube and the water receiving pipe and between second U-tube and the outlet pipe Screw thread is screwed on.
By docking the interconnection of fiber tube 5 between the lower end of first U-tube and the upper end of second U-tube.
The diameter of the filter tube is 10-30mm.
The L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
The material of the elastic rubber set 4 is fire retardant elastic rubber.
The preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 60 parts of natural rubber, 15 parts of butadiene-styrene rubber, 10 parts of butadiene rubber, tristearin are weighed by weight Sour 1.1 parts, 15 parts of green mud mountain flour, 10 parts of white carbon black, 1.2 parts of anti-aging agent RD, 1.5 parts of promotor, 7 parts of zinc oxide, fire retardant 2 Part, 15 parts of precipitated calcium carbonate, 2 parts of sulphur;
(2) will be 90 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 500r/min carries out mixing 10min, adds stearic acid, green mud mountain flour, white carbon black, anti-aging agent RD, zinc oxide, fire retardant, light It with revolving speed is that 500r/min carries out mixing 16min that matter calcium carbonate, which is 90 DEG C in temperature, promotor then is added, sulphur in temperature is 90 DEG C are that 500r/min carries out mixing 8min with revolving speed, obtain mixing glue;Mixing glue is put into after 25 DEG C of placement 15h of room temperature In vulcanizing press, vulcanized, 160 DEG C of curing temperature, pressure 1MPa, time 40min then cool to room temperature 25 DEG C, i.e., Obtain fire retardant elastic rubber.
The promotor is dibenzothiazyl disulfide.
The fire retardant is dodecyl silicic acid ring phosphino- ester compounds.
Embodiment 2
Such as Fig. 1, a kind of active carbon water purification catridge of the invention, including water receiving pipe 1, filter tube 2 and outlet pipe 3, the filter Core pipe is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter The lower end of core pipe, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is by symmetrical first and second U-tube 6,7 phases It is mutually detachably connected composition, first U-tube is located at the top of second U-tube, first U-tube and the water receiving Pipe connection, second U-tube are connect with the outlet pipe, are filtered in first U-tube filled with PP cotton, described second is U-shaped Active carbon is filled in pipe.
The upper end of the water receiving pipe is fixed with the elastic rubber set 4 that can be sheathed in outer water tube.
Pass through between first U-tube and the water receiving pipe and between second U-tube and the outlet pipe Screw thread is screwed on.
By docking the interconnection of fiber tube 5 between the lower end of first U-tube and the upper end of second U-tube.
The diameter of the filter tube is 10-30mm.
The L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
The material of the elastic rubber set 4 is fire retardant elastic rubber.
The preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 60 parts of natural rubber, 15 parts of butadiene-styrene rubber, 10 parts of butadiene rubber, tristearin are weighed by weight 1.1 parts of acid, 15 parts of green mud mountain flour modifier, 10 parts of white carbon black, 1.2 parts of anti-aging agent RD, 1.5 parts of promotor, 7 parts of zinc oxide, resistance Fire 2 parts of agent, 15 parts of precipitated calcium carbonate, 2 parts of sulphur;
(2) will be 90 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 500r/min carries out mixing 10min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, zinc oxide, fire-retardant It with revolving speed is that 500r/min carries out mixing 16min that agent, precipitated calcium carbonate, which are 90 DEG C in temperature, and promotor, sulphur is then added and exists Temperature be 90 DEG C with revolving speed be 500r/min carry out mixing 8min, obtain mixing glue;By mixing glue after 25 DEG C of placement 15h of room temperature It is put into vulcanizing press, is vulcanized, 160 DEG C of curing temperature, pressure 1MPa, time 40min then cool to room temperature 25 DEG C to get fire retardant elastic rubber.
The promotor is dibenzothiazyl disulfide.
The green mud mountain flour modifier is prepared by following methods: in mass ratio by sodium tripolyphosphate, polyethylene glycol 400, water It with revolving speed is that 300r/min is stirred 10min and obtains sodium tripolyphosphate mixed liquor for 1:0.5:5;By 15L water, 3kg chlorite Powder is that 300r/min is stirred 10min with revolving speed, adds 860g melamine, 850g cyanuric acid, 1.5L sodium tripolyphosphate Mixed liquor is that 300r/min is stirred 10min with revolving speed, and being warming up to 95 DEG C with revolving speed is that 60r/min is stirred to react 3h, then It is that 8000r/min is centrifugated 20min with revolving speed, abandoning supernatant and being deposited in temperature is 90 DEG C of dry 30h to get green mud mountain flour Modifier.
The fire retardant is dodecyl silicic acid ring phosphino- ester compounds.
Embodiment 3
Such as Fig. 1, a kind of active carbon water purification catridge of the invention, including water receiving pipe 1, filter tube 2 and outlet pipe 3, the filter Core pipe is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter The lower end of core pipe, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is by symmetrical first and second U-tube 6,7 phases It is mutually detachably connected composition, first U-tube is located at the top of second U-tube, first U-tube and the water receiving Pipe connection, second U-tube are connect with the outlet pipe, are filtered in first U-tube filled with PP cotton, described second is U-shaped Active carbon is filled in pipe.
The upper end of the water receiving pipe is fixed with the elastic rubber set 4 that can be sheathed in outer water tube.
Pass through between first U-tube and the water receiving pipe and between second U-tube and the outlet pipe Screw thread is screwed on.
By docking the interconnection of fiber tube 5 between the lower end of first U-tube and the upper end of second U-tube.
The diameter of the filter tube is 10-30mm.
The L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
The material of the elastic rubber set 4 is fire retardant elastic rubber.
The preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 60 parts of natural rubber, 15 parts of butadiene-styrene rubber, 10 parts of butadiene rubber, tristearin are weighed by weight 1.1 parts of acid, 15 parts of green mud mountain flour modifier, 10 parts of white carbon black, 1.2 parts of anti-aging agent RD, 1.5 parts of promotor, 7 parts of zinc oxide, resistance Fire 2 parts of agent, 15 parts of precipitated calcium carbonate, 2 parts of sulphur;
(2) will be 90 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 500r/min carries out mixing 10min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, zinc oxide, fire-retardant It with revolving speed is that 500r/min carries out mixing 16min that agent, precipitated calcium carbonate, which are 90 DEG C in temperature, and promotor, sulphur is then added and exists Temperature be 90 DEG C with revolving speed be 500r/min carry out mixing 8min, obtain mixing glue;By mixing glue after 25 DEG C of placement 15h of room temperature It is put into vulcanizing press, is vulcanized, 160 DEG C of curing temperature, pressure 1MPa, time 40min then cool to room temperature 25 DEG C to get fire retardant elastic rubber.
The promotor is dibenzothiazyl disulfide.
The green mud mountain flour modifier is prepared by following methods: being in mass ratio 0.5:5 to turn by polyethylene glycol 400, water Speed is stirred 10min for 300r/min and obtains sodium tripolyphosphate mixed liquor;It is with revolving speed by 15L water, 3kg green mud mountain flour 300r/min is stirred 10min, adds 860g melamine, 850g cyanuric acid, 1.5L sodium tripolyphosphate mixed liquor to turn Speed is that 300r/min is stirred 10min, and being warming up to 95 DEG C with revolving speed is that 60r/min is stirred to react 3h, is then with revolving speed 8000r/min is centrifugated 20min, and abandoning supernatant and being deposited in temperature is 90 DEG C of dry 30h to get green mud mountain flour modifier.
The fire retardant is dodecyl silicic acid ring phosphino- ester compounds.
Embodiment 4
Such as Fig. 1, a kind of active carbon water purification catridge of the invention, including water receiving pipe 1, filter tube 2 and outlet pipe 3, the filter Core pipe is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter The lower end of core pipe, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is by symmetrical first and second U-tube 6,7 phases It is mutually detachably connected composition, first U-tube is located at the top of second U-tube, first U-tube and the water receiving Pipe connection, second U-tube are connect with the outlet pipe, are filtered in first U-tube filled with PP cotton, described second is U-shaped Active carbon is filled in pipe.
The upper end of the water receiving pipe is fixed with the elastic rubber set 4 that can be sheathed in outer water tube.
Pass through between first U-tube and the water receiving pipe and between second U-tube and the outlet pipe Screw thread is screwed on.
By docking the interconnection of fiber tube 5 between the lower end of first U-tube and the upper end of second U-tube.
The diameter of the filter tube is 10-30mm.
The L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
The material of the elastic rubber set 4 is fire retardant elastic rubber.
The preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 60 parts of natural rubber, 15 parts of butadiene-styrene rubber, 10 parts of butadiene rubber, tristearin are weighed by weight 1.1 parts of acid, 15 parts of green mud mountain flour modifier, 10 parts of white carbon black, 1.2 parts of anti-aging agent RD, 1.5 parts of promotor, 7 parts of zinc oxide, resistance Fire 2 parts of agent, 15 parts of precipitated calcium carbonate, 2 parts of sulphur;
(2) will be 90 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 500r/min carries out mixing 10min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, zinc oxide, fire-retardant It with revolving speed is that 500r/min carries out mixing 16min that agent, precipitated calcium carbonate, which are 90 DEG C in temperature, and promotor, sulphur is then added and exists Temperature be 90 DEG C with revolving speed be 500r/min carry out mixing 8min, obtain mixing glue;By mixing glue after 25 DEG C of placement 15h of room temperature It is put into vulcanizing press, is vulcanized, 160 DEG C of curing temperature, pressure 1MPa, time 40min then cool to room temperature 25 DEG C to get fire retardant elastic rubber.
The promotor is dibenzothiazyl disulfide.
The green mud mountain flour modifier is prepared by following methods: in mass ratio by sodium tripolyphosphate, polyethylene glycol 400, water It with revolving speed is that 300r/min is stirred 10min and obtains sodium tripolyphosphate mixed liquor for 1:0.5:5;By 15L water, 3kg chlorite Powder is that 300r/min is stirred 10min with revolving speed, adds 860g melamine, 850g cyanuric acid, 1.5L sodium tripolyphosphate Mixed liquor is that 300r/min is stirred 10min with revolving speed, and being warming up to 95 DEG C with revolving speed is that 60r/min is stirred to react 3h, then It is that 8000r/min is centrifugated 20min with revolving speed, abandoning supernatant and being deposited in temperature is 90 DEG C of dry 30h to get green mud mountain flour Modifier.
The fire retardant is tris hydroxymethyl phosphine caged phosphite ester.
Embodiment 5
Such as Fig. 1, a kind of active carbon water purification catridge of the invention, including water receiving pipe 1, filter tube 2 and outlet pipe 3, the filter Core pipe is S-type, and the water receiving pipe is detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter The lower end of core pipe, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is by symmetrical first and second U-tube 6,7 phases It is mutually detachably connected composition, first U-tube is located at the top of second U-tube, first U-tube and the water receiving Pipe connection, second U-tube are connect with the outlet pipe, are filtered in first U-tube filled with PP cotton, described second is U-shaped Active carbon is filled in pipe.
The upper end of the water receiving pipe is fixed with the elastic rubber set 4 that can be sheathed in outer water tube.
Pass through between first U-tube and the water receiving pipe and between second U-tube and the outlet pipe Screw thread is screwed on.
By docking the interconnection of fiber tube 5 between the lower end of first U-tube and the upper end of second U-tube.
The diameter of the filter tube is 10-30mm.
The L-type vertical portion of the water receiving pipe and outlet pipe is 30-50mm in length.
The material of the elastic rubber set 4 is fire retardant elastic rubber.
The preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) following raw materials: 60 parts of natural rubber, 15 parts of butadiene-styrene rubber, 10 parts of butadiene rubber, tristearin are weighed by weight 1.1 parts of acid, 15 parts of green mud mountain flour modifier, 10 parts of white carbon black, 1.2 parts of anti-aging agent RD, 1.5 parts of promotor, 7 parts of zinc oxide, resistance Fire 2 parts of agent, 15 parts of precipitated calcium carbonate, 2 parts of sulphur;
(2) will be 90 DEG C in temperature in natural rubber, butadiene-styrene rubber, butadiene rubber addition mixer is with revolving speed 500r/min carries out mixing 10min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, zinc oxide, fire-retardant It with revolving speed is that 500r/min carries out mixing 16min that agent, precipitated calcium carbonate, which are 90 DEG C in temperature, and promotor, sulphur is then added and exists Temperature be 90 DEG C with revolving speed be 500r/min carry out mixing 8min, obtain mixing glue;By mixing glue after 25 DEG C of placement 15h of room temperature It is put into vulcanizing press, is vulcanized, 160 DEG C of curing temperature, pressure 1MPa, time 40min then cool to room temperature 25 DEG C to get fire retardant elastic rubber.
The promotor is dibenzothiazyl disulfide.
The green mud mountain flour modifier is prepared by following methods: in mass ratio by sodium tripolyphosphate, polyethylene glycol 400, water It with revolving speed is that 300r/min is stirred 10min and obtains sodium tripolyphosphate mixed liquor for 1:0.5:5;By 15L water, 3kg chlorite Powder is that 300r/min is stirred 10min with revolving speed, adds 860g melamine, 850g cyanuric acid, 1.5L sodium tripolyphosphate Mixed liquor is that 300r/min is stirred 10min with revolving speed, and being warming up to 95 DEG C with revolving speed is that 60r/min is stirred to react 3h, then It is that 8000r/min is centrifugated 20min with revolving speed, abandoning supernatant and being deposited in temperature is 90 DEG C of dry 30h to get green mud mountain flour Modifier.
The fire retardant is sub- by 70wt% dodecyl silicic acid ring phosphino- ester compounds and 30wt% tris hydroxymethyl phosphine caged Phosphate mixes.
Test case 1
The fire retardant elastic rubber prepared in embodiment 1-5 is tested for the property, concrete outcome is shown in Table 1.
Shao Er A type hardness tester is tested with reference to GB/T 531-1983, and test equipment is limited using upper Helen's victory electromechanical meters The rubber hardness instrument for the model LX-D that company provides.
Tensile property is carried out with reference to ASTMD412, and test temperature is 23 DEG C, tensile speed 500mm/min.It will before test Sample is adjusted 24 hours in the environment of 23 DEG C of temperature, relative humidity are 50%.Test equipment is set using Dongguan City east instrument precision The electronic tensile machine for the model Instron IX 4465 that standby Co., Ltd provides.
Flame retardant test: flame retardant property test is carried out according to the method for GB/T2406.2-2009.
Table 1: test result table
Active carbon water purification catridge of the present invention adsorbs the heterochromatic peculiar smell in raw water by seed activity layer of charcoal, removes organic matter There is excellent flame and mechanical property, pass through filter core by being improved to the material that elastic rubber covers with improvement water tasting The S-type flow velocity that can slow down water flow is managed, to improve water purification efficiency, passes through three water receiving pipe, filter tube and outlet pipe parts It is individually designed, can reduce cost, filter tube only needed to change when needing replacing, water receiving pipe and outlet pipe can also continue to make With being mutually detachably connected and formed by symmetrical first and second U-tube by filter tube, when replacement can be according to practical feelings Condition replaces first or second U-tube, does not need whole replacements, reduces use cost.

Claims (10)

1. a kind of active carbon water purification catridge, which is characterized in that including water receiving pipe, filter tube and outlet pipe, the filter tube is in S Type, the water receiving pipe are detachably connected on the upper end of the filter tube, and the outlet pipe is detachably connected on the filter tube Lower end, the water receiving pipe and outlet pipe are L-shaped, and the filter tube is mutually detachably connected by symmetrical first and second U-tube Composition is connect, first U-tube is located at the top of second U-tube, and first U-tube is connect with the water receiving pipe, institute It states the second U-tube to connect with the outlet pipe, be filtered in first U-tube filled with PP cotton, is filled in second U-tube Active carbon, the upper end of the water receiving pipe are fixed with the elastic rubber set that can be sheathed in outer water tube.
2. active carbon water purification catridge as described in claim 1, which is characterized in that between first U-tube and the water receiving pipe And it is screwed on by screw thread between second U-tube and the outlet pipe.
3. active carbon water purification catridge as described in claim 1, which is characterized in that the lower end of first U-tube and the 2nd U It is connected with each other between the upper end of type pipe by docking fiber tube.
4. active carbon water purification catridge as described in claim 1, which is characterized in that the diameter of the filter tube is 10-30mm.
5. active carbon water purification catridge as described in claim 1, which is characterized in that the L-type vertical portion of the water receiving pipe and outlet pipe It is 30-50mm in length.
6. active carbon water purification catridge as described in claim 1, which is characterized in that the material of the elastic rubber set is fire retardant elastic Rubber, the preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) weigh following raw materials by weight: 50-70 parts of natural rubber, 10-20 parts of butadiene-styrene rubber, 5-15 parts of butadiene rubber, 0.7-1.5 parts of stearic acid, 10-20 parts of green mud mountain flour, 5-15 parts of white carbon black, 0.8-1.5 parts of anti-aging agent RD, 1-2 parts of promotor, 4-10 parts of zinc oxide, 1-3 parts of fire retardant, 10-20 parts of precipitated calcium carbonate, 1-3 parts of sulphur;
(2) by natural rubber, butadiene-styrene rubber, butadiene rubber be added mixer in temperature be 60-100 DEG C with revolving speed for 300- 600r/min carry out mixing 8-14min, add stearic acid, green mud mountain flour, white carbon black, anti-aging agent RD, zinc oxide, fire retardant, Precipitated calcium carbonate temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 15-20min, then be added promote Agent, sulphur temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 5-10min, obtain mixing glue;By mixing Glue is put into vulcanizing press after being placed at room temperature for 10-20h, is vulcanized, and 140-180 DEG C of curing temperature, pressure 0.5- 1.5MPa, time 30-50min then cool to room temperature to get fire retardant elastic rubber.
7. active carbon water purification catridge as described in claim 1, which is characterized in that the material of the elastic rubber set is fire retardant elastic Rubber, the preparation method of the fire retardant elastic rubber, comprising the following steps:
(1) weigh following raw materials by weight: 50-70 parts of natural rubber, 10-20 parts of butadiene-styrene rubber, 5-15 parts of butadiene rubber, 0.7-1.5 parts of stearic acid, 10-20 parts of green mud mountain flour modifier, 5-15 parts of white carbon black, 0.8-1.5 parts of anti-aging agent RD, promotor 1-2 parts, 4-10 parts of zinc oxide, 1-3 parts of fire retardant, 10-20 parts of precipitated calcium carbonate, 1-3 parts of sulphur;
(2) by natural rubber, butadiene-styrene rubber, butadiene rubber be added mixer in temperature be 60-100 DEG C with revolving speed for 300- 600r/min carries out mixing 8-14min, adds stearic acid, green mud mountain flour modifier, white carbon black, anti-aging agent RD, zinc oxide, resistance Combustion agent, precipitated calcium carbonate temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 15-20min, be then added Promotor, sulphur temperature be 60-100 DEG C with revolving speed be 300-600r/min carry out mixing 5-10min, obtain mixing glue;It will Mixing glue is put into vulcanizing press after being placed at room temperature for 10-20h, is vulcanized, and 140-180 DEG C of curing temperature, pressure 0.5-1.5MPa, time 30-50min then cool to room temperature to get fire retardant elastic rubber.
8. active carbon water purification catridge as claimed in claim 7, which is characterized in that the promotor is dibenzothiazyl disulfide.
9. active carbon water purification catridge as claimed in claim 7, which is characterized in that the green mud mountain flour modifier is by following methods system It is standby: to be in mass ratio 1:(0.4-0.6 by sodium tripolyphosphate, polyethylene glycol 400, water): (3-7) is with revolving speed for 100-400r/min It is stirred 5-15min and obtains sodium tripolyphosphate mixed liquor;It with revolving speed is 100-400r/ by 10-20L water, 2-4kg green mud mountain flour Min is stirred 5-15min, adds 800-900g melamine, 800-900g cyanuric acid, 1-2L sodium tripolyphosphate mixed liquor It is that 100-400r/min is stirred 5-15min with revolving speed, is warming up to 90-105 DEG C and is stirred to react with revolving speed for 50-150r/min 2-5h is then centrifuged for separating, and abandons supernatant precipitating is dry to get green mud mountain flour modifier.
10. active carbon water purification catridge as claimed in claim 7, which is characterized in that the fire retardant is dodecyl silicic acid ring phosphine Base ester compound and/or tris hydroxymethyl phosphine caged phosphite ester.
CN201910443835.7A 2019-05-27 2019-05-27 A kind of active carbon water purification catridge Withdrawn CN110143639A (en)

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Application publication date: 20190820