CN110139835A - The method of operation of water treatment facilities - Google Patents

The method of operation of water treatment facilities Download PDF

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Publication number
CN110139835A
CN110139835A CN201780082243.6A CN201780082243A CN110139835A CN 110139835 A CN110139835 A CN 110139835A CN 201780082243 A CN201780082243 A CN 201780082243A CN 110139835 A CN110139835 A CN 110139835A
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CN
China
Prior art keywords
water
hydrotreater
flowing
treatment facilities
tower
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Pending
Application number
CN201780082243.6A
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Chinese (zh)
Inventor
森田博志
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Kurita Water Industries Ltd
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Kurita Water Industries Ltd
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Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Publication of CN110139835A publication Critical patent/CN110139835A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

A kind of method of operation of water treatment facilities is the method that will there is the water treatment facilities for the hydrotreater multiple of the same race and with processing capacity being set side by side to operate, and passes to identical treated water to each hydrotreater and carries out processing water to adopt water;The method of operation of the water treatment facilities is characterized in that, make the water flowing for the hydrotreater A of a part compared with the water flowing high load capacity for other hydrotreaters B, in the case where water quality deterioration occurs for the processing water of hydrotreater A, the service life of hydrotreater B is predicted according to the cumulative load for hydrotreater A so far, and it is based on this prediction result, the control of water-flowing amount and water flowing time after to(for) each hydrotreater.

Description

The method of operation of water treatment facilities
Technical field
The present invention relates to a kind of water process for being set side by side with the hydrotreaters such as multiple exchange resin towers, activated carbon tower The method of operation of device.
Background technique
High pure water used in the general industry pure water such as boiler feed water, power plant, in semiconductor factory, liquid crystal factory etc. As the ultrapure water that chip, the washing water of substrate, flushing water use, almost all passes through will be contained in multiple pairs of treated waters Water treatment system that the hydrotreater that impurity is removed is applied in combination manufactures.As hydrotreater, be widely used that from Sub-exchange resin tower, activated carbon tower, RO film device, UF film device, ion-exchange filter etc..
As the application method of these hydrotreaters, the method used in addition to repeating impurity removal step and step for regeneration In addition, there are also using the of short duration formula application method etc. that new product is then replaced with to the stage of prescribed level.It is either any Situation, it is generally desirable to maintain impurity removal step (water flowing process) for a long time under conditions of keeping desired water quality treatment.
Even if hydrotreater is still difficult to rapidly in many cases in the case where the deterioration of water quality treatment tendency is identified Ground is transferred to regeneration or is updated to new product.Therefore, actually every defined period or every defined treating capacity, plan Is regenerated, updated to property.
However, the water quality of treated water be not limited in 1 year it is constant, therefore every defined period or every In the case that defined treating capacity is regenerated, updated, with the water quality of treated water severe (impurity concentration that should be removed is high) Condition setting is carried out premised on state, is as a result just to be regenerated, updated at the time of having to a certain degree well-to-do mostly.And And there is the risk that cannot ensure desired water quality if being far from it.
Following methods are recorded in patent document 1: being arranged side by side with the ion exchange resin device of actual machine small The ion exchange resin packed column of type circulates identical raw water (treated water) simultaneously to the small-sized ion exchange resin packed column It monitors its water quality treatment, estimates the residual life of ion exchange resin device.
Existing technical literature
Patent document:
Patent document 1: Japanese Unexamined Patent Publication 2012-154634 bulletin.
In the life prediction carried out using small-sized ion exchange resin filling container, it is however generally that make SV, LV etc. to the greatest extent Amount is close to actual machine, and the water flowing being set as under slightly harsh conditions, it can be difficult to correctly reflecting the load to actual machine Situation, and also it is necessary to account for the processing of well-to-do amount to a certain degree herein.
Summary of the invention
It is operated in a manner of using up the water treatment capacity of hydrotreater sufficiently the object of the present invention is to provide a kind of The method of operation of water treatment facilities.
The gist of the invention is as described below.
[1] a kind of method of operation of water treatment facilities is that will have the processing capacity multiple of the same race and same being set side by side Hydrotreater the method that is operated of water treatment facilities, identical treated water is passed to each hydrotreater and water will be handled It carries out adopting water, the method for operation of the water treatment facilities is characterized in that, keeps the hydrotreater A of water flowing to(for) a part more right In other hydrotreaters B water flowing be high load capacity, hydrotreater A processing water occur water quality deterioration in the case where, according to The cumulative load for hydrotreater A so far predicts service life of hydrotreater B, and is based on this prediction result, control Water-flowing amount for each hydrotreater and water flowing time later.
[2] such as method of operation of the water treatment facilities of [1], wherein until water quality deterioration occurs for above-mentioned hydrotreater, 1.05~1.3 times of water flowing speed for hydrotreater B will be set as the water flowing speed of above-mentioned hydrotreater A.
[3] such as method of operation of the water treatment facilities of [1] or [2], wherein will be by the water of the processing water of hydrotreater A Service life load is set as to the cumulative load of hydrotreater A until at the time of matter deteriorates into specified value, acquires and is by the moment The difference (hereinafter referred to as load difference) of cumulative load to hydrotreater B and the service life load only, after setting the moment Water flowing speed to hydrotreater B and the water flowing time, so as to apply during from the moment until adopting water and terminating Become the load difference in the load of hydrotreater B.
[4] such as method of operation of the water treatment facilities of [1] to any one of [3], wherein after the above-mentioned moment, stopping pair The water flowing of hydrotreater A, by the whole necessary processing water per unit time of water treatment facilities divided by the number of hydrotreater B Obtained from water-flowing amount per unit time, be set as the water flowing speed to each hydrotreater B,
So that the load acquired by the product of the water flowing speed and the water flowing time from the above-mentioned moment until adopting water and terminating As the mode of above-mentioned load difference, the water flowing time is set.
[5] such as method of operation of the water treatment facilities of [1] to any one of [4], wherein above-mentioned hydrotreater has: hold Device, the ion exchange resin for being filled in the container, activated carbon, ion-exchange filter, chelating resin or catalyst.
Invention effect
In the present invention, using the hydrotreater A of a part (1 or a small number of) as the examination low to detection processing water quality Use is tested, to it with compared with load (such as high pass water speed) water flowing slightly higher for other hydrotreaters B, according to the water of the test The sign of the water quality deterioration of the processing water of processor, predicts the service life of hydrotreater.Then, the water flowing condition after setting, with Use up each hydrotreater use to the last service life will.
Accordingly, for general water treatment system, special mensuration machine, control machine etc. can be set without additional In the case where maintain desired water quality, and by each hydrotreater use to last service life will to the greatest extent until.Even if by high load capacity In the case where the sign for detecting water quality deterioration in a part of hydrotreater of water flowing, since water treatment facilities will not be reached at once The whole service life, therefore the correspondence of the regeneration of hydrotreater, update can be made to carry out without difficulty after preparing to reach.
Detailed description of the invention
Fig. 1 is the composition figure using the water treatment facilities of the method for the present invention.
Specific embodiment
Hereinafter, referring to Fig.1, embodiments of the present invention will be described for needle.It should be noted that in this embodiment It can also be activated carbon tower, chelate resin tower, catalyst tower, ion though hydrotreater is set as exchange resin tower in explanation Exchange filter, MF film device, UF film device, RO film device etc..It is preferred that can be exemplified as service life specific exchange resin tower, Ion-exchange filter, chelate resin tower, activated carbon tower, catalyst tower etc..In addition, in addition to going to remove water to manufacture ultrapure water Other than the water process of middle impurity, additionally it is possible to the removing applied to the impurities in liquid other than pure water manufacture.
As shown in Figure 1, being set side by side with multiple exchange resin towers 3 in water treatment facilities.Each exchange resin tower 3 Have: the ion exchange of the container and the identical type filled in the container with equal amount of same shape and same volume Resin.For each exchange resin tower 3, treated water can be passed to via piping 1 and valve 2, processing water can be via valve 4 and piping 5 outflows.The water-flowing amount of each exchange resin tower 3 is measured with flowmeter (illustration omitted), each exchange resin tower 3 The water quality of processing water is measured by water quality detector 6.As water quality detector, it is able to use conductivity meter, nephelometer, residual chlorine Densimeter, pH meter, resistrivity meter etc., but not limited to this.The water quality detector of the type suitable for hydrotreater can suitably be selected.
Among multiple exchange resin towers 3, by a part (in Fig. 1,1 tower of the leftmost side) A as test tower A, Water flowing is carried out using the condition slightly harsh compared with other towers B (this as conditions of high flow rate) in tower A.Moreover, handing over ion The water quality for changing the processing water of resin tower A continuously or intermittently monitors, grasps the sign deteriorated from stable state.It needs to illustrate It is, therebetween for the water flowing SV of tower A, 1.05~1.3 times or so preferably for the water flowing SV of tower B.
It is big compared with the water flowing SV for tower B for the water flowing SV of tower A, therefore tower A more initial failure (processing water compared with tower B Matter deteriorates).
For handling the sign of the water quality deterioration of water in tower A, grasped before the water quality deterioration of the processing water of tower B Afterwards, in order to utilize the whole capability of tower A, B sufficiently (that is, to service life will use up), the residual life of tower B is predicted to carry out flow tune It is whole, so as to which the processing water of fine water can be obtained to the maximum extent until adopting water and terminating.That is, reducing water flowing for tower A Flow, or stop water flowing, the reduction part (or stop section) of the water-flowing amount for this tower A is appended to for other towers The water-flowing amount of B.Impartial can be set as the water-flowing amount of each tower B, it can also chasing after the flow of the tower (tower C) of a part in tower B Add part to be set as slightly higher compared with other towers B, and monitors the deterioration sign of the water quality treatment of tower C and predict the residual life of remaining tower B (mark C omits icon).
The special mensuration machine of additional setting, control can be not required to for general water treatment system by above method Under conditions of machine processed, target is maintained to handle water water quality, and will be to the greatest extent for all exchange resin tower water flowings to the service life Only.Since even in the case where tower A (or tower C) detects water quality deterioration sign, water treatment facilities will not be reached at once The whole service life, therefore the regeneration of hydrotreater, update can be made to carry out without difficulty after preparing to reach.
In Fig. 1,1 exchange resin tower is set as test tower A, but in the system for being set side by side with a large amount of towers, In order to which the precision for predicting residual life more improves, settable multiple test tower A with slightly rigor condition water flowing, and make phase There is difference for the severity (degree of high flow rate) of standard conditions.
[embodiment]
An example of the invention is described below in more detail.
For the service life of the treatment functions material such as ion exchange resin, as long as the water flowings such as flow (SV etc.) Condition in the appropriate range, by load be the treated water to be removed in impurity concentration, with accumulate water flowing flow product it is big It causes to determine.
As shown in Figure 1, starting most in the water treatment facilities for being set side by side with 10 exchange resin towers in water flowing Just, for 1 tower A, with the flow velocity water flowing compared with standard high 10%, and it is directed to other towers B, after the segmentation of rest part equalization Flow velocity water flowing.That is, with 11% water flowing speed of total water-flowing amount per unit time to water treatment facilities to tower A water flowing. For remaining 9 tower B, respectively with water flowing speed (every list after sharing 89% equalization of total water-flowing amount per unit time Respectively 9.89% water flowing speed of total water-flowing amount of the water treatment facilities entirety of position time) water flowing (89/9=9.89).
The feelings that the water flowing time until the water quality of the outflow water by tower A is shown at the time of deteriorating sign is 100 days Under condition, the accumulation water-flowing amount to tower A until the 100th day, compared with standard conditions (by the 10% of total water-flowing amount equably water flowing To the condition of each tower) accumulation water-flowing amount more 10%.Therefore, for tower 3 with the standard conditions water flowing, by place The water flowing time (service life) until reason water quality starts to deteriorate can be estimated as 110 days.
Therefore, after the 100th day, to ensure that 1 tower A and other 9 tower B are the side of total water-flowing amount of total 10 amounts Formula reduces the water-flowing amount of (or stopping) tower A and increases the water-flowing amount of tower B, and so that any one of tower A, B are cumulative loads (water flowing start~adopt water and terminate during cumulative load) respectively becomes the negative of 110 days amounts in the case of standard conditions water flowing The mode of lotus sets the water flowing number of days for each.
For example, the water quality requirement of processing water is harsh, and in the case where being impermissible for the impurity more than slightly sign, needle To above-mentioned 1 tower A, being set as water flowing in this stage (the 100th day) terminates.For other 9 tower B, then it is set as standard conditions 10 Water flowing speed after 9 equal part of unit time water-flowing amount of platform amount, specifically, being set as standard conditions water flowing speed increases by 11.1% Water flowing speed (100%/9=11.1%).
In the cumulative load of the tower B at 100 day moment, the case where being converted into standard conditions water flowing is 98.9 days amounts, is being marked There is the remaining capacity of 11.1 days amounts in the case where floating screed part water flowing.Therefore, to increase by 11.1% water flowing speed, to become this The mode of the cumulative load of 11.1 days amounts of standard conditions sets the 100th day later water flowing number of days.In this case, passing through it The water flowing for carrying out 10 days afterwards, becomes this cumulative load.Therefore, for tower B, water can be adopted until the 110th day.
Life prediction and water-flowing amount control are carried out by the main points more than, each tower can be utilized to the maximum extent A, the service life of B.
The high flow rate water flowing that 1 tower A can also be carried out to increasing in operating 20%, carries out increase by 10% for another 1 tower A High flow rate water flowing, remaining 8 tower B is set as impartial water flowing.
Tower A can not be identical tower always, can be replaced every defined period.For example, being set side by side with 3 Tower a, b, c water treatment facilities in, in the case that standard water flowing speed is set as K, in an example, by the water flowing of tower a, b Speed is set as 1.0K, and tower c is set as 1.2K, and when tower c shows the sign of water quality deterioration, the water flowing speed of tower a, b are set as The water flowing speed of tower c is set as 0.8K by 1.1K, and by the service life use of each tower a, b, c to last.It, can also in other an examples The water flowing speed of tower a, b are set as 1.0K, the water flowing speed of tower c is set as 1.2K, when tower c shows the sign of water quality deterioration, The water flowing speed of tower a is set as 1.0K, the water flowing speed of tower b is set as 1.2K, the water flowing speed of tower c is set as 0.8K, makes tower b The processing water water quality of tower b is monitored for high load capacity compared with tower a.
Though the present invention is described in detail using specific mode, as known to those skilled in the art, the present invention is not being departed from Intention and range in can be carried out various changes.
The application is based on Japanese patent application 2017-001990 filed on January 10th, 2017, entire contents This is applied at by reference.
Description of symbols
2,4: valve;
3: exchange resin tower.

Claims (5)

1. a kind of method of operation of water treatment facilities is that will have at the water multiple of the same race and with processing capacity being set side by side The method that the water treatment facilities of reason device is operated,
Identical treated water is passed to each hydrotreater and carries out processing water to adopt water,
The method of operation of the water treatment facilities is characterized in that,
Make the water flowing for the hydrotreater A of a part compared with the water flowing high load capacity for other hydrotreaters B,
In the case where water quality deterioration occurs for the processing water of hydrotreater A, according to so far for the tired of hydrotreater A Product load predicts service life of hydrotreater B, and is based on this prediction result, after control for the water-flowing amount of each hydrotreater and The water flowing time.
2. the method for operation of water treatment facilities as described in claim 1, wherein water quality deterioration occurs by the hydrotreater Until, 1.05~1.3 times of water flowing speed for hydrotreater B will be set as the water flowing speed of the hydrotreater A.
3. the method for operation of water treatment facilities as claimed in claim 1 or 2, wherein
By being born to the accumulation of hydrotreater A until at the time of the water quality deterioration of the processing water of hydrotreater A is to specified value Lotus is set as service life load,
The difference i.e. load difference of the cumulative load and the service life load to hydrotreater B until the moment is found out,
Set the water flowing speed to hydrotreater B after the moment and water flowing time so that from the moment to adopting Water terminate until during be applied to hydrotreater B load become the load difference.
4. the method for operation of water treatment facilities as claimed any one in claims 1 to 3, wherein after the moment, stop Water flowing to hydrotreater A, by the whole necessary processing water per unit time of water treatment facilities divided by the number of hydrotreater B Water-flowing amount obtained from mesh per unit time is set as the water flowing speed to each hydrotreater B,
So that the load acquired by the product of the water flowing speed and water flowing time from the moment until adopting water and terminating at For the mode of the load difference, the water flowing time is set.
5. the method for operation of the water treatment facilities as described in any one of Claims 1-4 item, wherein the water process utensil It is standby: container, the ion exchange resin being filled in the container, activated carbon, ion-exchange filter, chelating resin or catalyst.
CN201780082243.6A 2017-01-10 2017-09-08 The method of operation of water treatment facilities Pending CN110139835A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2017001990A JP6288319B1 (en) 2017-01-10 2017-01-10 Operation method of water treatment equipment
JP2017-001990 2017-01-10
PCT/JP2017/032489 WO2018131209A1 (en) 2017-01-10 2017-09-08 Method for operating water treatment apparatus

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CN110139835A true CN110139835A (en) 2019-08-16

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KR (1) KR102453719B1 (en)
CN (1) CN110139835A (en)
TW (1) TWI732939B (en)
WO (1) WO2018131209A1 (en)

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MX2021000434A (en) 2018-08-08 2021-02-26 Evoqua Water Tech Llc System and method of deionization of water.
JP7176307B2 (en) 2018-09-07 2022-11-22 いすゞ自動車株式会社 pump gear
WO2022059430A1 (en) * 2020-09-15 2022-03-24 オルガノ株式会社 Ultrapure water supply system, control device, and program

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JPS6384688A (en) * 1986-09-29 1988-04-15 Toshiba Corp Operation of for condensate desalting device
JPH06170367A (en) * 1992-12-01 1994-06-21 Matsushita Electric Works Ltd Ion water producer
JPH09285785A (en) * 1996-04-22 1997-11-04 Kurita Water Ind Ltd Ammonia-type condensate desalter and device for predicting amount of water to be collected
JPH11258219A (en) * 1998-03-09 1999-09-24 Japan Organo Co Ltd Method for monitoring break-through of ion adsorption film for manufacturing extra-pure water
CN1252469C (en) * 2000-08-07 2006-04-19 奥璐佳瑙株式会社 Method and apparatus for estimating performance of anion-exchange resin and condensed-water desalting device
JP2003190950A (en) * 2001-12-25 2003-07-08 Ishikawajima Harima Heavy Ind Co Ltd Changeover method for ion exchange tank and water treatment apparatus
CN101249461A (en) * 2007-12-03 2008-08-27 友达光电股份有限公司 Ion-exchange resin tower and testing system and method of resin service lifetime thereof
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CN205084509U (en) * 2015-11-10 2016-03-16 太原创客空间科技有限公司 Purifier intelligence observing and controlling system

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JP6288319B1 (en) 2018-03-07
WO2018131209A1 (en) 2018-07-19
KR20190100161A (en) 2019-08-28
JP2018111058A (en) 2018-07-19
TWI732939B (en) 2021-07-11
KR102453719B1 (en) 2022-10-11
TW201825406A (en) 2018-07-16

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Application publication date: 20190816