CN110129740A - The preparation of coated cutting tool and coating surface processing method and coated cutting tool - Google Patents

The preparation of coated cutting tool and coating surface processing method and coated cutting tool Download PDF

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Publication number
CN110129740A
CN110129740A CN201910330858.7A CN201910330858A CN110129740A CN 110129740 A CN110129740 A CN 110129740A CN 201910330858 A CN201910330858 A CN 201910330858A CN 110129740 A CN110129740 A CN 110129740A
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Prior art keywords
coating
cutting tool
coated cutting
hard conating
substrate
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CN201910330858.7A
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Inventor
李玉强
谭秋虹
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Wald Beijing Diamond Tool Ltd Co
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Wald Beijing Diamond Tool Ltd Co
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Priority to CN201910330858.7A priority Critical patent/CN110129740A/en
Publication of CN110129740A publication Critical patent/CN110129740A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23DPLANING; SLOTTING; SHEARING; BROACHING; SAWING; FILING; SCRAPING; LIKE OPERATIONS FOR WORKING METAL BY REMOVING MATERIAL, NOT OTHERWISE PROVIDED FOR
    • B23D79/00Methods, machines, or devices not covered elsewhere, for working metal by removal of material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021Reactive sputtering or evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641Nitrides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/16Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/32Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C23C14/325Electric arc evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5873Removal of material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

The present invention provides a kind of preparation of coated cutting tool and coating surface processing method and coated cutting tools.Wherein, the preparation of coated cutting tool and coating surface processing method include the following steps: step S10, and coating is deposited on substrate using multi-Arc Ion Plating;Step S20, the furnace chamber for controlling multi-Arc Ion Plating is in vacuum state, performs etching processing to the surface of coating, to reduce the surface roughness of coating surface.Technical solution of the present invention solves the problems, such as that the high production cost and production efficiency of the preparation of coated cutting tool in the prior art and coating surface processing method are low.

Description

The preparation of coated cutting tool and coating surface processing method and coated cutting tool
Technical field
The present invention relates to cutting tool technical fields, preparation and coating surface in particular to a kind of coated cutting tool Processing method and coated cutting tool.
Background technique
With the fast development of processing manufacturing industry and the expansion of industrial requirement, there are some unmanageable green woods Material, so that requirement of the processing enterprise to cutting tool is higher and higher.Coated cutting tool because of it with good machining property and Cheap price, is widely used in machining.
Coating is deposited on substrate using multi-Arc Ion Plating in the related technology and obtains coated cutting tool, but production in this way The roughness of the coating surface of obtained coated cutting tool is larger, and glossiness is poor.In order to solve this technical problem, the prior art Increase equipment for after-treatment is generallyd use, by coated cutting tool by being post-processed after being taken out in multi-Arc Ion Plating to it, thus Promote the surface quality of coated cutting tool.But the preparation of above-mentioned coated cutting tool and coating surface processing method, which exist, leads to coated cutting tool The production cost increases, reduces the problem of coated cutting tool production efficiency.
Summary of the invention
The main purpose of the present invention is to provide a kind of preparation of coated cutting tool and coating surface processing method and coating knives Tool, with solve coated cutting tool in the prior art preparation and coating surface processing method high production cost and production efficiency it is low The problem of.
To achieve the goals above, according to an aspect of the invention, there is provided preparation and the coating of a kind of coated cutting tool Surface treatment method includes the following steps: step S10, and coating is deposited on substrate using multi-Arc Ion Plating;Step S20, the furnace chamber for controlling multi-Arc Ion Plating are in vacuum state, processing are performed etching to the surface of coating, to reduce coating The surface roughness on surface.
Further, in step S20, the furnace chamber for controlling multi-Arc Ion Plating is in vacuum state, leads into furnace chamber The Ar for entering predetermined amount of flow ionizes Ar under conditions of predetermined bias, and the Ar+ for ionizing generation carves the surface of coating Erosion processing, to reduce the surface roughness of coating surface.
Further, in step S20, vacuumize process is carried out to furnace chamber and make vacuum degree 1.33Pa in furnace chamber~ 3.99Pa;The flow that Ar is passed through into furnace chamber is 80ml/min~150ml/min, right under conditions of bias is 400V~600V Ar is ionized, and the Ar+ for ionizing generation performs etching processing to the surface of coating.
Further, step S10 includes the following steps: step S11, installs Cr target and/or Ti target, is passed through Ar, Deposited on substrates Cr coating and/or Ti coating;Step S12 installs TiAl target, is passed through N2, applied in deposited on substrates AlTiN Layer;Step S13 installs the SiTi target containing Er, is passed through N2, in deposited on substrates TiSiErN coating;Step S14 installs Cr Target and/or Ti target, are passed through N2, in deposited on substrates CrN coating and/or TiN coating.
Further, control depositing temperature is 400 DEG C~550 DEG C;In step s 11, control coating bias be 600V~ 1000V, control arc current are 50A~100A, and the flow for being passed through Ar is 40ml/min~90ml/min, and sedimentation time is 15min~25min, the Cr coating of deposition and/or Ti coating with a thickness of 0.02 μm~0.05 μm;In step s 12, TiAl target The mass fraction ratio of material is Ti:Al=40/60, and control coating bias is 30V~50V, is passed through N2Flow be 80ml/min~ 120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the AlTiN coating of deposition With a thickness of 0.2 μm~0.4 μm;In step s 13, the SiTi target containing 0.5wt%Er~3wt%Er, and SiTi target are installed The mass fraction ratio of material is Si:Ti=20/80, and control coating bias is 30V~50V, is passed through N2Flow be 80ml/min~ 120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the TiSiErN coating of deposition With a thickness of 0.4 μm~1 μm;In step S14, control coating bias is 30V~50V, is passed through N2Flow be 80ml/min ~120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the CrN coating of deposition And/or TiN coating with a thickness of 0.2 μm~0.4 μm.
According to another aspect of the present invention, a kind of coated cutting tool is provided, coated cutting tool utilizes above-mentioned coated cutting tool Preparation and coating surface processing method are prepared, and coated cutting tool includes: substrate;Hard conating, hard conating are arranged on substrate, firmly Coating is made of the material with Er element.
Further, hard conating is AlTiErN coating and/or TiSiErN coating.
Further, along the direction far from matrix surface, coated cutting tool further include: be arranged between substrate and hard conating Tie coat, and the lubricant coating of the separate tie coat side of hard conating is set;Hard conating includes two straton hard conatings, Sub- hard conating close to tie coat is AlTiN coating, and the sub- hard conating close to lubricant coating is TiSiErN coating.
Further, the coating layer thickness of AlTiN coating be 0.2 μm~0.4 μm, TiSiErN coating with a thickness of 0.4 μm~ 1μm。
Further, tie coat with a thickness of 0.02 μm~0.05 μm, lubricant coating with a thickness of 0.2 μm~0.4 μm.
Using the technical solution of the application, the preparation and coating surface processing method of a kind of new coated cutting tool are provided, After coating is deposited on substrate using multi-Arc Ion Plating, not by the substrate of depositing coating by multi-Arc Ion Plating Middle taking-up, but directly the surface for adhering to coating on base material is performed etching using multi-Arc Ion Plating, it solves more Arc ion plating equipment, which deposits the coating surface to be formed, has drop phenomenon, thus obtain coating surface quality preferably and table The lesser coated cutting tool of surface roughness, due to do not need increase after-treatment device, can reduce the production cost of coated cutting tool, by It is post-processed in not needing to take out coated cutting tool, is able to ascend the production efficiency of coated cutting tool.
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide further understanding of the present invention, and of the invention shows Examples and descriptions thereof are used to explain the present invention for meaning property, does not constitute improper limitations of the present invention.In the accompanying drawings:
Fig. 1 shows a kind of structural schematic diagram of the coated cutting tool of alternative embodiment according to the present invention.
Wherein, the above drawings include the following reference numerals:
10, substrate;20, composite coating;21, tie coat;22, hard conating;221, sub- hard conating;23, lubricant coating.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that the described embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.It is right below The description only actually of at least one exemplary embodiment be it is illustrative, never as to the present invention and its application or use Any restrictions.Based on the embodiments of the present invention, those of ordinary skill in the art are without creative efforts Every other embodiment obtained, shall fall within the protection scope of the present invention.
In order to solve the preparation of coated cutting tool in the prior art and the high production cost and life of coating surface processing method The problem of producing low efficiency, the present invention provides a kind of preparation of coated cutting tool and coating surface processing method and coated cutting tools.
As shown in Figure 1, coated cutting tool includes substrate 10 and the coating that is deposited on substrate 10.This application provides a kind of paintings The preparation and coating surface processing method of layer cutter, include the following steps: step S10, using multi-Arc Ion Plating by coating It is deposited on substrate 10;Step S20, the furnace chamber for controlling multi-Arc Ion Plating are in vacuum state, carry out to the surface of coating Etching processing, to reduce the surface roughness of coating surface.
Using the technical solution of the application, the preparation and coating surface processing method of a kind of new coated cutting tool are provided, After coating is deposited on substrate using multi-Arc Ion Plating, not by the substrate of depositing coating by multi-Arc Ion Plating Middle taking-up, but directly the surface for adhering to coating on base material is performed etching using multi-Arc Ion Plating, it solves more Arc ion plating equipment, which deposits the coating surface to be formed, has drop phenomenon, thus obtain coating surface quality preferably and table The lesser coated cutting tool of surface roughness, due to do not need increase after-treatment device, can reduce the production cost of coated cutting tool, by It is post-processed in not needing to take out coated cutting tool, is able to ascend the production efficiency of coated cutting tool.
Optionally, in step S20, the furnace chamber for controlling multi-Arc Ion Plating is in vacuum state, is passed through into furnace chamber The inert gas of predetermined amount of flow ionizes the inert gas under conditions of predetermined bias, and the ion pair for ionizing generation applies The surface of layer performs etching processing, to reduce the surface roughness of coating surface.It, will not since inert gas performance is more stable It reacts with coating material, impurity phase will not be generated, to ensure that the stabilization of coating composition, while gas etching compares Mildly, biggish stress will not be generated.It is obtained by the preparation and coating surface processing method of coated cutting tool provided by the present application Coated cutting tool have the advantages that surface quality is good, surface roughness is small, glossiness is good, not only beautiful but also corrosion resistant.
Specifically, in step S20, the furnace chamber for controlling multi-Arc Ion Plating is in vacuum state, is passed through into furnace chamber The Ar of predetermined amount of flow ionizes Ar under conditions of predetermined bias, and the Ar+ for ionizing generation performs etching the surface of coating Processing, to reduce the surface roughness of coating surface.Ar is more easier in inert gas, and cost is relatively low.
Optionally, in step S20, vacuumize process is carried out to furnace chamber and make vacuum degree 1.33Pa in furnace chamber~ 3.99Pa;The Ar that flow is 80ml/min~150ml/min is passed through into furnace chamber;It is right under conditions of bias is 400V~600V Ar is ionized, and the Ar+ for ionizing generation performs etching processing to the surface of coating, to reduce the surface roughness of coating surface.
As shown in Figure 1, coated cutting tool provided by the present application includes substrate 10 and coating, coating is composite coating 20, compound Coating 20 is arranged on the surface of substrate 10, along far from matrix surface direction, composite coating 20 successively include tie coat 21, Hard conating 22 and lubricant coating 23, tie coat 21 is used to remove the oxide on 10 surface of substrate, convenient for adhering to hard conating 22 On tie coat 21, hard conating 22 is used to enhance the hardness of coated cutting tool, lubricant coating 23 for reduce coated cutting tool with to Frictional force between cutting workpiece.
In this application, a kind of coated cutting tool with composite coating is devised, so as to improve the use of coated cutting tool Performance, specifically, along the direction far from matrix surface, composite coating successively includes tie coat, hard conating and lubricant coating, Wherein, tie coat is used to remove the oxide of substrate surface, convenient for hard conating to be attached on tie coat;Hard conating is used for The hardness for enhancing coated cutting tool improves between hard conating and substrate since tie coat is arranged between substrate and hard conating Bond strength, can be avoided hard conating and fall off in use;Lubricant coating is for reducing coated cutting tool and work to be cut Frictional force between part, lubricant coating can be avoided the problems such as crushing knife occurs when coated cutting tool is contacted with turning work piece to be cut.Therefore, Coated cutting tool provided by the present application has good service performance and service life.Utilize the preparation and painting of above-mentioned coated cutting tool When layer surface treatment method produces the cutter shown in fig. 1 with composite coating 20, the coated cutting tool prepared also has Have the advantages that coating surface is high-quality.
Optionally, tie coat 21 be Cr coating and/or Ti coating, lubricant coating 23 be TiN coating and/or CrN coating, Hard conating 22 includes two straton hard conatings 221, and the sub- hard conating 221 close to tie coat 21 is AlTiN coating, is applied close to lubrication The sub- hard conating 221 of layer 23 is TiSiErN coating.Using the preparation and coating surface processing method of above-mentioned coated cutting tool to this When coated cutting tool is produced, step S10 includes the following steps: step S11, installs Cr target and/or Ti target, is passed through Ar, Cr coating and/or Ti coating are deposited on substrate 10;Step S12 installs TiAl target, is passed through N2, deposited on substrate 10 AlTiN coating;Step S13 installs the SiTi target containing Er, is passed through N2, the depositing Ti SiErN coating on substrate 10;Step S14 installs Cr target and/or Ti target, is passed through N2, CrN coating and/or TiN coating are deposited on substrate 10.
In this application, the material for also optimizing hard conating 22, by being added to rare earth member in the material of hard conating 22 The performance and used life of plain Er, Lai Tisheng coated cutting tool.The results showed addition rare earth element er has refinement crystal grain, mentions The consistency of high coating, the microhardness for improving coating, the toughness for enhancing coating, the bond strength for enhancing coating and enhancing coating Thermal stability effect.
Optionally, control overall deposition temperature is 400 DEG C~550 DEG C;In step s 11, control coating bias is 600V ~1000V, control arc current are 50A~100A, and the flow for being passed through Ar is 40ml/min~90ml/min, and sedimentation time is 15min~25min, the Cr coating of deposition and/or Ti coating with a thickness of 0.02 μm~0.05 μm;In step s 12, TiAl target The mass fraction ratio of material is Ti:Al=40/60, and control coating bias is 30V~50V, is passed through N2Flow be 80ml/min~ 120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the AlTiN coating of deposition With a thickness of 0.2 μm~0.4 μm;In step s 13, the SiTi target containing 0.5wt%Er~3wt%Er, and SiTi target are installed The mass fraction ratio of material is Si:Ti=20/80, and control coating bias is 30V~50V, is passed through N2Flow be 80ml/min~ 120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the TiSiErN coating of deposition With a thickness of 0.4 μm~1 μm;In step S14, control coating bias is 30V~50V, is passed through N2Flow be 80ml/min ~120ml/min, controlling pressure in furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the CrN coating of deposition And/or TiN coating with a thickness of 0.2 μm~0.4 μm.
The preparation of coated cutting tool provided by the present application and coating surface processing method early period are bombarded using Ti/Cr target, the later period It is etched using Ar, the roughness of the coating surface of obtained coated cutting tool wants small, and glossiness will be got well.
As shown in Figure 1, embodiments herein provides a kind of coated cutting tool, including substrate 10 and composite coating 20, it is multiple It closes coating 20 to be arranged on the surface of substrate 10, along the direction far from matrix surface, composite coating 20 successively includes: tie coat 21;Hard conating 22, hard conating 22 are used to enhance the hardness of coated cutting tool;Lubricant coating 23, lubricant coating 23 is for reducing coating Frictional force between cutter and turning work piece to be cut;Wherein, tie coat 21 is used to remove the oxide on 10 surface of substrate, and being convenient for will Hard conating 22 is attached on tie coat 21.
In this application, a kind of coated cutting tool with composite coating 20 is devised, so as to improve making for coated cutting tool With performance, specifically, along the direction far from 10 surface of substrate, composite coating 20 successively includes tie coat 21, hard conating 22 With lubricant coating 23, wherein tie coat 21 is used to remove the oxide of substrate surface, activates workpiece surface, promotes compound painting The formation and attachment of layer 20 are convenient for for hard conating 22 being attached on tie coat 21;Hard conating is for enhancing coated cutting tool Hardness improves the bond strength between hard conating and substrate since tie coat is arranged between substrate and hard conating, can Hard conating is avoided to fall off in use;Lubricant coating is used to reduce the frictional force between coated cutting tool and turning work piece to be cut, Lubricant coating can be avoided the problems such as crushing knife occurs when coated cutting tool is contacted with turning work piece to be cut.Therefore, painting provided by the present application Layer cutter has good service performance and service life.
Optionally, composite coating 20 with a thickness of 0.8 μm~1.8 μm.
Optionally, tie coat 21 is Cr coating.Cr coating has the advantages that high rigidity, anti-oxidation and high-wearing feature.
Optionally, tie coat 21 is Ti coating.Ti coating has good caking property, high-wearing feature and highly corrosion resistant The advantages of.
Optionally, tie coat 21 is the Cr/Ti coating that Cr coating and Ti coating are alternatively formed.
Optionally, tie coat 21 with a thickness of 0.02 μm~0.05 μm.
Optionally, hard conating 22 is AlTiN coating and/or TiSiN coating.AlTiN coating has high rigidity, high-fire resistance And high tenacity, TiSiN coating have high heat resistance, are suitble to hard machining, workhardness is up to 65HRC.
Optionally, hard conating 22 includes the sub- hard conating 221 of multilayer being made from a different material.
Optionally, AlTiN coating and/or TiSiN coating alternating deposit form the sub- hard conating 221 of multilayer.
Optionally, hard conating 22 with a thickness of 0.6 μm~1.4 μm.
Optionally, lubricant coating 23 is TiN coating.TiN coating has good wearability, reduction coefficient of friction and prevents from bonding The advantages of.
Optionally, lubricant coating 23 is CrN coating.CrN coating has low stress, high adhesion force, high tenacity and high anti-corrosion The advantages of property.
Optionally, lubricant coating 23 is the TiN/CrN coating that TiN coating and CrN coating are alternatively formed.
Optionally, lubricant coating 23 with a thickness of 0.2 μm~0.4 μm.
Optionally, hard conating 22 is made of the material with Er element.Hard painting is also optimized in the technical solution of the application The material of layer 22, by being added to rare earth element er, the performance and used life of Lai Tisheng coated cutting tool in the material of coating. The results showed addition rare earth element er has refinement crystal grain, the consistency of raising coating, the microhardness of raising coating, increases The effect of the toughness of strong coating, the bond strength for enhancing coating and the thermal stability for enhancing coating.
Optionally, hard conating 22 is AlTiErN coating and/or TiSiErN coating.By in AlTiN coating or TiSiN painting Er element is added in layer, to promote the bond strength between two sub- hard conatings 221.
Optionally, hard conating 22 includes the sub- hard conating 221 of multilayer.
Optionally, hard conating 22 includes two straton hard conatings 221, and is close to the sub- hard conating 221 of tie coat 21 AlTiN coating, the sub- hard conating 221 close to lubricant coating 23 are TiSiErN coating.
Optionally, the coating layer thickness of AlTiN coating be 0.2 μm~0.4 μm, TiSiErN coating with a thickness of 0.4 μm~1 μ m。
In alternative embodiment shown in fig. 1, along the direction far from 10 surface of substrate, composite coating 20 successively includes Ti/ Cr tie coat, AlTiN hard conating, TiSiErN hard conating and TiN/CrN lubricant coating.The painting that embodiments herein provides Layer cutter has many advantages, such as hardness height, stable chemical performance and heat-resistant oxidized, treats cutting when cutting workpiece is cut Speed, machining accuracy and service life have promotion.
It should be noted that the coat type of coated cutting tool provided by the present application is not limited to the above-mentioned coat type enumerated, As long as can be realized its corresponding function.
The application implemented using multi-Arc Ion Plating preparation and the coating surface processing method of above-mentioned coated cutting tool come Above-mentioned coated cutting tool is prepared, specifically, multi-Arc Ion Plating is used to composite coating 20 being deposited on substrate 10, also uses Processing is performed etching in the outer surface to composite coating 20, to reduce the surface roughness of 20 outer surface of composite coating.In this way, After composite coating 20 is deposited on substrate using multi-Arc Ion Plating, will not deposited the substrate 10 of composite coating 20 by It is taken out in multi-Arc Ion Plating, but directly using multi-Arc Ion Plating to the composite coating 20 being attached on substrate 10 Surface performs etching, and solves outer surface the asking there are drop phenomenon that multi-Arc Ion Plating deposits the composite coating 20 to be formed Topic, thus obtain coating surface quality preferably and the lesser coated cutting tool of surface roughness, due to do not need increase post-processing fill It sets, can reduce the production cost of coated cutting tool, post-processed due to not needing to take out coated cutting tool, be able to ascend coating The production efficiency of cutter.
Optionally, the upstream of multi-Arc Ion Plating is arranged in hydrocarbon cleaning machine, carries out for the surface to substrate 10 clear Wash drying process.In this way, cleaning using surface of the hydrocarbon cleaning machine to substrate 10, the greasy dirt on its surface is removed, thus just It is attached on substrate 10 in composite coating 20, is conducive to the quality for promoting coated cutting tool.
The coated cutting tool that the application is prepared has that surface quality is good, hardness is high, stable chemical performance and heat-resisting oxytolerant The advantages that change, treating cutting speed when cutting workpiece is cut, machining accuracy and service life has promotion.
Embodiments herein additionally provides a kind of coated cutting tool, including substrate 10 and coating, and coating is arranged in substrate 10 Surface on, coating includes the hard conating 22 made of the material with Er element.
In some embodiments of the present application, the material of coating is also optimized, it is dilute by being added in the material of coating The performance and used life of earth elements Er, Lai Tisheng coated cutting tool.Adding rare earth element er has refinement crystal grain, improves coating Consistency, the microhardness for improving coating, the toughness for enhancing coating, the bond strength for enhancing coating and the thermostabilization for enhancing coating The effect of property.
Optionally, hard conating 22 includes the sub- hard conating 221 of multilayer, and at least one layer in the sub- hard conating 221 of multilayer is by having The material of Er element is made.
Optionally, the material with Er element is AlTiErN or TiSiErN.
Optionally, coating with a thickness of 0.8 μm~1.8 μm.
Optionally, coating is composite coating 20, and composite coating 20 further includes tie coat 21, and tie coat 21 is arranged in base Between material 10 and hard conating 22, tie coat 21 is used to remove the oxide on 10 surface of substrate, convenient for hard conating 22 to be attached to On tie coat 21, hard conating 22 is used to enhance the hardness of coated cutting tool.
Optionally, coating is composite coating 20, and composite coating 20 further includes lubricant coating 23, and lubricant coating 23 is arranged hard On coating 22, lubricant coating 23 is used to reduce the frictional force between coated cutting tool and turning work piece to be cut, and lubricant coating 23 can be kept away Exempt from the problems such as crushing knife occurs when coated cutting tool is contacted with turning work piece to be cut.
Optionally, coating is composite coating 20, and along the direction far from 10 surface of substrate, composite coating 20 successively includes transition Coating 21, hard conating 22 and lubricant coating 23.Wherein, tie coat 21 is used to remove the oxide on 10 surface of substrate, activates work Part surface promotes the formation and attachment of composite coating 20, convenient for hard conating 22 to be attached on tie coat 21;Hard conating 22 is used Hard conating 22 is improved since tie coat 21 is arranged between substrate 10 and hard conating 22 in the hardness of enhancing coated cutting tool With the bond strength between substrate 10, it can be avoided hard conating 22 and fall off in use;Lubricant coating 23 is applied for reducing Frictional force between layer cutter and turning work piece to be cut, lubricant coating 23 can be avoided hair when coated cutting tool is contacted with turning work piece to be cut The problems such as raw crushing knife.Therefore, coated cutting tool provided by the present application has good service performance and service life.
Optionally, hard conating 22 with a thickness of 0.6 μm~1.4 μm.
Specifically, along the direction far from 10 surface of substrate, composite coating 20 is successively hard including Ti/Cr tie coat, AlTiN Coating, TiSiErN hard conating and TiN/CrN lubricant coating.
Optionally, Ti/Cr tie coat with a thickness of 0.02 μm~0.05 μm.
Optionally, the coating layer thickness of AlTiN coating be 0.2 μm~0.4 μm, TiSiErN coating with a thickness of 0.4 μm~1 μ m。
Optionally, TiN/CrN lubricant coating with a thickness of 0.2 μm~0.4 μm.
Coated cutting tool provided by the present application is with surface quality is good, glossiness is good, hardness is high, high-densit, good toughness, chemistry The advantages that performance is stable and heat-resistant oxidized treats cutting speed when cutting workpiece is cut, machining accuracy and uses the longevity Life has promotion.Coated cutting tool provided by the present application can be applied to the machining of the high rigidity hard-cutting material such as hardened steel, mention The high quality of cutting-tool's used life and material machining.Coated cutting tool provided by the present application has biggish using model It encloses, has great meaning to the development of Machining Technology for Cutting.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
Unless specifically stated otherwise, positioned opposite, the digital table of the component and step that otherwise illustrate in these embodiments It is not limited the scope of the invention up to formula and numerical value.Simultaneously, it should be appreciated that for ease of description, each portion shown in attached drawing The size divided not is to draw according to actual proportionate relationship.For technology, side known to person of ordinary skill in the relevant Method and equipment may be not discussed in detail, but in the appropriate case, and the technology, method and apparatus should be considered as authorizing explanation A part of book.In shown here and discussion all examples, any occurrence should be construed as merely illustratively, and Not by way of limitation.Therefore, the other examples of exemplary embodiment can have different values.It should also be noted that similar label Similar terms are indicated in following attached drawing with letter, therefore, once it is defined in a certain Xiang Yi attached drawing, then subsequent attached It does not need that it is further discussed in figure.
In the description of the present invention, it is to be understood that, the noun of locality such as " front, rear, top, and bottom, left and right ", " it is laterally, vertical, Vertically, orientation or positional relationship indicated by level " and " top, bottom " etc. is normally based on orientation or position shown in the drawings and closes System, is merely for convenience of description of the present invention and simplification of the description, in the absence of explanation to the contrary, these nouns of locality do not indicate that It must have a particular orientation or be constructed and operated in a specific orientation with the device or element for implying signified, therefore cannot manage Solution is limiting the scope of the invention;The noun of locality " inside and outside " refers to inside and outside the profile relative to each component itself.
For ease of description, spatially relative term can be used herein, as " ... on ", " ... top ", " ... upper surface ", " above " etc., for describing such as a device shown in the figure or feature and other devices or spy The spatial relation of sign.It should be understood that spatially relative term is intended to comprising the orientation in addition to device described in figure Except different direction in use or operation.For example, being described as if the device in attached drawing is squeezed " in other devices It will be positioned as " under other devices or construction after part or construction top " or the device of " on other devices or construction " Side " or " under other devices or construction ".Thus, exemplary term " ... top " may include " ... top " and " in ... lower section " two kinds of orientation.The device can also be positioned with other different modes and (is rotated by 90 ° or in other orientation), and And respective explanations are made to the opposite description in space used herein above.
In addition, it should be noted that, limiting components using the words such as " first ", " second ", it is only for be convenient for Corresponding components are distinguished, do not have Stated otherwise such as, there is no particular meanings for above-mentioned word, therefore should not be understood as to this The limitation of invention protection scope.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, work, device, component and/or their combination.
It should be noted that the description and claims of this application and term " first " in above-mentioned attached drawing, " Two " etc. be to be used to distinguish similar objects, without being used to describe a particular order or precedence order.It should be understood that using in this way Data be interchangeable under appropriate circumstances, so that presently filed embodiment described herein can be in addition to illustrating herein Or the sequence other than those of description is implemented.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. the preparation and coating surface processing method of a kind of coated cutting tool, which comprises the steps of:
Coating is deposited on substrate (10) by step S10 using multi-Arc Ion Plating;
Step S20, the furnace chamber for controlling the multi-Arc Ion Plating are in vacuum state, perform etching to the surface of the coating Processing, to reduce the surface roughness of the coating surface.
2. the preparation and coating surface processing method of coated cutting tool according to claim 1, which is characterized in that in the step In rapid S20, the furnace chamber for controlling the multi-Arc Ion Plating is in vacuum state, is passed through predetermined amount of flow in Xiang Suoshu furnace chamber Ar ionizes Ar under conditions of predetermined bias, and the Ar+ for ionizing generation performs etching processing to the surface of the coating, To reduce the surface roughness of the coating surface.
3. the preparation and coating surface processing method of coated cutting tool according to claim 2, which is characterized in that in the step In rapid S20, vacuumize process is carried out to the furnace chamber and makes vacuum degree 1.33Pa~3.99Pa in the furnace chamber;To described The flow that Ar is passed through in furnace chamber is 80ml/min~150ml/min, carries out electricity to Ar under conditions of bias is 400V~600V From the Ar+ for ionizing generation performs etching processing to the surface of the coating.
4. the preparation of coated cutting tool according to any one of claim 1 to 3 and coating surface processing method, feature exist In the step S10 includes the following steps:
Step S11 installs Cr target and/or Ti target, is passed through Ar, and Cr coating is deposited on the substrate (10) and/or Ti is applied Layer;
Step S12 installs TiAl target, is passed through N2, the depositing Al TiN coating on the substrate (10);
Step S13 installs the SiTi target containing Er, is passed through N2, the depositing Ti SiErN coating on the substrate (10);
Step S14 installs Cr target and/or Ti target, is passed through N2, CrN coating is deposited on the substrate (10) and/or TiN is applied Layer.
5. the preparation and coating surface processing method of coated cutting tool according to claim 4, which is characterized in that control deposition Temperature is 400 DEG C~550 DEG C;
In the step S11, control coating bias is 600V~1000V, and control arc current is 50A~100A, is passed through Ar Flow be 40ml/min~90ml/min, sedimentation time be 15min~25min, the Cr coating of deposition and/or the Ti Coating with a thickness of 0.02 μm~0.05 μm;
In the step S12, the mass fraction ratio of TiAl target is Ti:Al=40/60, control coating bias for 30V~ 50V is passed through N2Flow be 80ml/min~120ml/min, controlling in the furnace chamber pressure is 1Pa~5Pa, control electric arc electricity Stream be 100A~150A, the AlTiN coating of deposition with a thickness of 0.2 μm~0.4 μm;
In the step S13, the SiTi target containing 0.5wt%Er~3wt%Er, and the mass fraction of SiTi target are installed Than for Si:Ti=20/80, control coating bias is 30V~50V, it is passed through N2Flow be 80ml/min~120ml/min, control Making pressure in the furnace chamber is 1Pa~5Pa, and control arc current is 100A~150A, the thickness of the TiSiErN coating of deposition Degree is 0.4 μm~1 μm;
In the step S14, control coating bias is 30V~50V, is passed through N2Flow be 80ml/min~120ml/min, Controlling in the furnace chamber pressure is 1Pa~5Pa, and control arc current is 100A~150A, the CrN coating of deposition and/or The TiN coating with a thickness of 0.2 μm~0.4 μm.
6. a kind of coated cutting tool, which is characterized in that the coated cutting tool utilizes coating described in any one of any one of claims 1 to 55 The preparation of cutter and coating surface processing method are prepared, and the coated cutting tool includes:
Substrate (10);
Hard conating (22), the hard conating (22) are arranged on the substrate (10), and the hard conating (22) is by with Er element Material be made.
7. coated cutting tool according to claim 6, which is characterized in that the hard conating (22) be AlTiErN coating and/or TiSiErN coating.
8. coated cutting tool according to claim 7, which is characterized in that along the direction far from matrix surface, the coating knife Tool further include: the tie coat (21) being arranged between the substrate (10) and the hard conating (22), and be arranged described The lubricant coating (23) far from the tie coat (21) side of hard conating (22);The hard conating (22) includes that two stratons are hard Coating (221), the sub- hard conating (221) close to the tie coat (21) is AlTiN coating, close to the lubricant coating (23) Sub- hard conating (221) be TiSiErN coating.
9. coated cutting tool according to claim 8, which is characterized in that the coating layer thickness of the AlTiN coating be 0.2 μm~ 0.4 μm, the TiSiErN coating with a thickness of 0.4 μm~1 μm.
10. coated cutting tool according to claim 8 or claim 9, which is characterized in that the tie coat (21) with a thickness of 0.02 μm~0.05 μm, the lubricant coating (23) with a thickness of 0.2 μm~0.4 μm.
CN201910330858.7A 2019-04-23 2019-04-23 The preparation of coated cutting tool and coating surface processing method and coated cutting tool Pending CN110129740A (en)

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CN101691654A (en) * 2007-09-26 2010-04-07 山特维克知识产权股份有限公司 Method of making a coated cutting tool
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