CN110128774A - 一种热塑性弹性体复合材料、其制备方法及应用 - Google Patents
一种热塑性弹性体复合材料、其制备方法及应用 Download PDFInfo
- Publication number
- CN110128774A CN110128774A CN201910445617.7A CN201910445617A CN110128774A CN 110128774 A CN110128774 A CN 110128774A CN 201910445617 A CN201910445617 A CN 201910445617A CN 110128774 A CN110128774 A CN 110128774A
- Authority
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- China
- Prior art keywords
- thermoplastic elastomer
- composite material
- acrylic resin
- elastomer composite
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 78
- 239000002131 composite material Substances 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 73
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 73
- 238000002844 melting Methods 0.000 claims abstract description 60
- 230000008018 melting Effects 0.000 claims abstract description 60
- 238000001125 extrusion Methods 0.000 claims abstract description 48
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 41
- 239000006057 Non-nutritive feed additive Substances 0.000 claims abstract description 33
- 230000005496 eutectics Effects 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 23
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims abstract description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 16
- 150000003440 styrenes Chemical class 0.000 claims description 46
- 239000000203 mixture Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- -1 benzene Ethylene-ethylene-propylene-styrene Chemical class 0.000 claims description 15
- 229920001169 thermoplastic Polymers 0.000 claims description 12
- 239000004416 thermosoftening plastic Substances 0.000 claims description 12
- 238000010894 electron beam technology Methods 0.000 claims description 11
- 238000004806 packaging method and process Methods 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 239000002530 phenolic antioxidant Substances 0.000 abstract description 18
- 238000001802 infusion Methods 0.000 abstract description 10
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000002861 polymer material Substances 0.000 abstract description 2
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 description 43
- 239000000463 material Substances 0.000 description 32
- 239000000047 product Substances 0.000 description 22
- 238000012360 testing method Methods 0.000 description 17
- 238000001816 cooling Methods 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 12
- 229920001155 polypropylene Polymers 0.000 description 12
- 238000005469 granulation Methods 0.000 description 11
- 230000003179 granulation Effects 0.000 description 11
- 229920002633 Kraton (polymer) Polymers 0.000 description 10
- 238000012660 binary copolymerization Methods 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 238000005265 energy consumption Methods 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 238000007493 shaping process Methods 0.000 description 5
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 4
- 239000000088 plastic resin Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- RLRINNKRRPQIGW-UHFFFAOYSA-N 1-ethenyl-2-[4-(2-ethenylphenyl)butyl]benzene Chemical compound C=CC1=CC=CC=C1CCCCC1=CC=CC=C1C=C RLRINNKRRPQIGW-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 210000002445 nipple Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000010412 perfusion Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000037384 skin absorption Effects 0.000 description 1
- 231100000274 skin absorption Toxicity 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201910445617.7A CN110128774B (zh) | 2019-05-27 | 2019-05-27 | 一种热塑性弹性体复合材料、其制备方法及应用 |
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CN201910445617.7A CN110128774B (zh) | 2019-05-27 | 2019-05-27 | 一种热塑性弹性体复合材料、其制备方法及应用 |
Publications (2)
Publication Number | Publication Date |
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CN110128774A true CN110128774A (zh) | 2019-08-16 |
CN110128774B CN110128774B (zh) | 2021-10-08 |
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CN201910445617.7A Active CN110128774B (zh) | 2019-05-27 | 2019-05-27 | 一种热塑性弹性体复合材料、其制备方法及应用 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113999535A (zh) * | 2022-01-04 | 2022-02-01 | 浙江金仪盛世生物工程有限公司 | 热塑性弹性体材料及热塑性弹性体管路 |
CN114276612A (zh) * | 2020-09-27 | 2022-04-05 | 合肥杰事杰新材料股份有限公司 | 一种用于食品包装的透明聚丙烯组合物及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1219679A1 (en) * | 2000-12-29 | 2002-07-03 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved processing and physical property balance |
US20080132645A1 (en) * | 2004-12-24 | 2008-06-05 | Xavier Muyldermans | High Melt Strength Thermoplastic Elastomer Composition |
CN102731956A (zh) * | 2012-06-28 | 2012-10-17 | 江苏苏云医疗器材有限公司 | 一种医用热塑性弹性体复合材料及其制备方法 |
CN105175977A (zh) * | 2015-09-29 | 2015-12-23 | 广东波斯科技股份有限公司 | 一种低析出透明tpe弹性体及其制备方法 |
-
2019
- 2019-05-27 CN CN201910445617.7A patent/CN110128774B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1219679A1 (en) * | 2000-12-29 | 2002-07-03 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved processing and physical property balance |
US20080132645A1 (en) * | 2004-12-24 | 2008-06-05 | Xavier Muyldermans | High Melt Strength Thermoplastic Elastomer Composition |
CN102731956A (zh) * | 2012-06-28 | 2012-10-17 | 江苏苏云医疗器材有限公司 | 一种医用热塑性弹性体复合材料及其制备方法 |
CN105175977A (zh) * | 2015-09-29 | 2015-12-23 | 广东波斯科技股份有限公司 | 一种低析出透明tpe弹性体及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114276612A (zh) * | 2020-09-27 | 2022-04-05 | 合肥杰事杰新材料股份有限公司 | 一种用于食品包装的透明聚丙烯组合物及其制备方法 |
CN114276612B (zh) * | 2020-09-27 | 2024-01-05 | 合肥杰事杰新材料股份有限公司 | 一种用于食品包装的透明聚丙烯组合物及其制备方法 |
CN113999535A (zh) * | 2022-01-04 | 2022-02-01 | 浙江金仪盛世生物工程有限公司 | 热塑性弹性体材料及热塑性弹性体管路 |
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CN110128774B (zh) | 2021-10-08 |
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Effective date of registration: 20230925 Address after: No. 1-9 Weigao Road, Chucun Town, Torch High tech Industrial Development Zone, Weihai City, Shandong Province, 264200 Patentee after: Weihai Weigao Import and Export Co.,Ltd. Address before: No.18 Xingshan Road, torch hi tech Industrial Development Zone, Weihai City, Shandong Province Patentee before: WEIGAO HOLDING CO.,LTD. |
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Effective date of registration: 20240312 Address after: No. 1-34 Weigao West Road, Torch High tech Industrial Development Zone, Weihai City, Shandong Province, 264200 Patentee after: Shandong Weihong Medical Technology Co.,Ltd. Country or region after: China Address before: No. 1-9 Weigao Road, Chucun Town, Torch High tech Industrial Development Zone, Weihai City, Shandong Province, 264200 Patentee before: Weihai Weigao Import and Export Co.,Ltd. Country or region before: China |
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