CN110117436A - Multi-functional environment-protection compound oil ink - Google Patents
Multi-functional environment-protection compound oil ink Download PDFInfo
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- CN110117436A CN110117436A CN201810118574.7A CN201810118574A CN110117436A CN 110117436 A CN110117436 A CN 110117436A CN 201810118574 A CN201810118574 A CN 201810118574A CN 110117436 A CN110117436 A CN 110117436A
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- parts
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- compound oil
- functional environment
- protection compound
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of BK570 multi-functional environment-protection compound oil inks, it is by following mass fraction at being grouped as, 25-40 parts of polyurethane resin, 10-15 parts of polyvinyl acetate ethylene, 30-45 parts of ester alcohol solvent, 0.6-1 parts of propylene glycol methyl ether acetate, 1-3 parts of amylalcohol, 15-25 parts of polyethylene glycol diamines, 5-15 parts of pigment, 0.3-0.6 parts of dispersing agent, 0.3-0.6 parts of polyethylene wax powder, 0.8-1.5 parts of adhesion promoter, 0.8-1.5 parts of antistatic agent, 5-8 parts of deglossing liquid, 0.5-1 parts of isophorone diamine, 0.5-1 parts of benzoyl peroxide, 1-3 parts and defoaming agent 0.3-0.6 parts of flatting silica.The present invention has excellent photostability and chemical resistance, and xanthochromia does not occur for ink, and defoaming agent is used in ink, bubble is less, brokenly bubble is easier in production process, no shrinkage cavity, and ink product quality is higher, its bright-colored, high solid bottom is viscous, dot reproduction is excellent, levelability is fabulous, is very suitable to chromaticity printing, and have extremely strong adhesive force, excellent solvent release and excellent freeze-proof, heat resistance, is suitble to different print speed printing speeds.
Description
Technical field
The present invention relates to Printing ink producing technical field more particularly to a kind of BK570 multi-functional environment-protection compound oil inks.
Background technique
Ink is important materials used for printing packaging materials, it is expressed the pattern and text on stock by printing.
It include main component and auxiliary element in ink, they uniformly mix and form a kind of sticky colloidal fluid through repeat-rolling.
It is made of pigment, link stuff, auxiliary agent and solvent.For the various printings such as books and periodicals, packing and decorating, building decoration.As society needs
Ask increase, ink variety and yield also respective extension and growth.With printing technology development and press to production efficiency,
The attention for the problems such as energy consumption is saved, country's press just quickly develops to high speed printing field at present.General traditional handicraft system
The ink of work can only adapt to the print speed printing speed of 150~200m/min, and light resistance and chemical resistance are also poor, are easy to produce Huang
Become, can not adapt to the needs produced now.
Summary of the invention
The purpose of the invention is to overcome the deficiencies of the prior art and provide a kind of BK570 multi-functional environment-protection compound oil
Ink.
The present invention is achieved through the following technical solutions:
BK570 multi-functional environment-protection compound oil ink is by polyurethane resin, polyvinyl acetate ethylene, ester alcohol solvent, propylene glycol
Methyl ether acetate, polyethylene glycol diamines, pigment, dispersing agent, polyethylene wax powder, adhesion promoter, antistatic agent, disappears at amylalcohol
Light liquid, isophorone diamine, benzoyl peroxide, flatting silica and defoaming agent composition, the mass fraction of above-mentioned each component are respectively as follows:
25-40 parts of polyurethane resin, 10-15 parts of polyvinyl acetate ethylene, 30-45 parts of ester alcohol solvent, propylene glycol methyl ether acetate 0.6-
1 part, 1-3 parts of amylalcohol, 15-25 parts of polyethylene glycol diamines, 5-15 parts of pigment, 0.3-0.6 parts of dispersing agent, polyethylene wax powder 0.3-
0.6 part, 0.8-1.5 parts of adhesion promoter, 0.8-1.5 parts of antistatic agent, 5-8 parts of deglossing liquid, isophorone diamine 0.5-1
Part, 0.5-1 parts of benzoyl peroxide, 1-3 parts of flatting silica and 0.3-0.6 parts of defoaming agent.
Further, the polyurethane resin is by isophorone diisocyanate and polypropylene -1,2- glycol ether
Polymer.
Further, the ester alcohol solvent is by n-propyl, isopropanol, ethyl ester and normal propyl alcohol according to mass parts ratio 30:
10:8:2 is mixed.
Further, the adhesion promoter is modified chlorinated polypropylene.
Further, the antistatic agent is by following mass fraction at being grouped as: the quaternary ammonium salt sun of 45%-50% from
Sub- surfactant, the ethylaminoethanol of 15%-18%, the acetic acid of 15%-18%, the isopropanol of 15%-18% and 3%-5%
Water.
Further, the deglossing liquid and the flatting silica are the liquid and powdery of model OK-412 delustering agent.
Further, the dispersing agent is polyester-polyamide copolymer.
Further, the polyethylene wax powder is 3620 wax powders.
Further, the defoaming agent is the polymer-type defoaming agent without organosilicon, model BYK-052.
Compared with prior art, the beneficial effects of the present invention are: the present invention uses special polyurethane resin, ink
Printing adaptability improves 50%, and traditional ink can only adapt to the print speed printing speed of 150-200m/min, and the present invention can adapt to
The high speed printing of 300m/min, while the present invention has excellent photostability and chemical resistance, xanthochromia does not occur for ink,
Defoaming agent is used in ink, bubble is less, and brokenly bubble is easier in production process, and no shrinkage cavity, ink product quality is higher, color
Bright-coloured, high solid bottom is viscous, and dot reproduction is excellent, levelability is fabulous, is very suitable to chromaticity printing, and have extremely strong adhesive force,
Excellent solvent release and excellent freeze-proof, heat resistance, is suitble to different print speed printing speeds.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
BK570 multi-functional environment-protection compound oil ink is by following mass fraction at being grouped as: 30 parts of polyurethane resin,
12 parts of polyvinyl acetate ethylene, 35.7 parts of ester alcohol solvent, 10 parts of pigment, 0.6 part of propylene glycol methyl ether acetate, 1 part of amylalcohol, poly- second
Two 15 parts of hydro diamines, 0.5 part of polyamide copolymer (dispersing agent), 0.5 part of polyethylene wax powder, modified chlorinated polypropylene (adhesive force
Promotor) 1 part, 1 part of antistatic agent, 6 parts of deglossing liquid, 0.5 part of isophorone diamine, 0.5 part of benzoyl peroxide, flatting silica 2
Part and 0.5 part of defoaming agent.Wherein, polyurethane resin is by isophorone diisocyanate and polypropylene -1,2- glycol ether
Polymer;Ester alcohol solvent is to be mixed by n-propyl, isopropanol, ethyl ester and normal propyl alcohol according to mass parts ratio 30:10:8:2;
Antistatic agent is by 48% quaternary cationics, 16% ethylaminoethanol, 16% acetic acid, 16% isopropyl
Pure and mild 4% water composition;Deglossing liquid and flatting silica are the liquid and powdery of model OK-412 delustering agent;Polyethylene wax powder is
3620 wax powders;Defoaming agent is the polymer-type defoaming agent without organosilicon, model BYK-052.
The BK570 multi-functional environment-protection compound oil ink of above-mentioned constituent, is prepared by the following steps:
1) resin liquid is configured, the polyurethane resin dissolution in above-mentioned formulation weight number is become into polyurethane liquid;
2) pre-dispersed, by the polyurethane liquid weight of one third and step 1) configuration of ester alcohol solvent in above-mentioned mass fraction
1/10th be added to premixing dispersion cylinder in, open dispersion machine mixed slowly uniformly, then by polyvinyl acetate ethylene,
Pigment, polyester-polyamide copolymer and deglossing liquid are added gradually to wherein in whipping process, are then opened dispersion machine and are sufficiently stirred
It mixes uniformly, forms pre-dispersed mill base;
3) pre-dispersed mill base is carried out grinding distribution, makes up to fineness needed for ink technique, obtain pigment by grinding distribution
Mill base;
4) viscosity, form and aspect are adjusted, by remaining polyurethane liquid, ester alcohol solvent, polyethylene wax powder, propylene glycol monomethyl ether acetic acid
Ester, amylalcohol, polyethylene glycol diamines, isophorone diamine, benzoyl peroxide, modified chlorinated polypropylene, antistatic agent, different Fo Er
Ketone diamines, benzoyl peroxide, flatting silica and defoaming agent are added in dispersible pigment color paste, adjust the viscosity and form and aspect of ink, are made into
Product ink;
5) it filters and packages, finished product ink is filtered, is then packed and stored.
Embodiment 2
BK570 multi-functional environment-protection compound oil ink is by following mass fraction at being grouped as: 35 parts of polyurethane resin,
15 parts of polyvinyl acetate ethylene, 40 parts of ester alcohol solvent, 3 parts of amylalcohol, 25 parts of polyethylene glycol diamines, 1 part of propylene glycol methyl ether acetate,
2 parts of amylalcohol, 20 parts of polyethylene glycol diamines, 12 parts of pigment, 0.6 part of polyester-polyamide copolymer (dispersing agent), polyethylene wax powder 0.6
Part, 1.5 parts of modified chlorinated polypropylene (adhesion promoter), 1.2 parts of antistatic agent, 6.5 parts of deglossing liquid, 2.2 parts of flatting silica and
0.6 part of defoaming agent.Wherein, polyurethane resin is by the polymerization of isophorone diisocyanate and polypropylene -1,2- glycol ether
Object;Ester alcohol solvent is to be mixed by n-propyl, isopropanol, ethyl ester and normal propyl alcohol according to mass parts ratio 30:10:8:2;Resist quiet
Electric agent be by 48% quaternary cationics, 16% ethylaminoethanol, 16% acetic acid, 16% isopropanol and
4% water composition;Deglossing liquid and flatting silica are the liquid and powdery of model OK-412 delustering agent;Polyethylene wax powder is 3620 waxes
Powder;Defoaming agent is the polymer-type defoaming agent without organosilicon, model BYK-052.
The BK570 multi-functional environment-protection compound oil ink of said components ingredient, is prepared into according to the preparation step in embodiment 1
Finished product ink.
Embodiment 3
BK570 multi-functional environment-protection compound oil ink is by following mass fraction at being grouped as: 30 parts of polyurethane resin,
12 parts of polyvinyl acetate ethylene, 33 parts of ester alcohol solvent, 0.6 part of propylene glycol methyl ether acetate, 8 parts of pigment, polyester-polyamide copolymerization
0.45 part of object (dispersing agent), 0.45 part of polyethylene wax powder, 0.9 part of modified chlorinated polypropylene (adhesion promoter), antistatic agent
0.9 part, 5.5 parts of deglossing liquid, 1 part of isophorone diamine, 1 part of benzoyl peroxide, 1.8 parts of flatting silica and defoaming agent 0.45
Part.Wherein, polyurethane resin is by the polymer of isophorone diisocyanate and polypropylene -1,2- glycol ether;Ester alcohol is molten
Agent is to be mixed by n-propyl, isopropanol, ethyl ester and normal propyl alcohol according to mass parts ratio 30:10:8:2;Antistatic agent be by
50% quaternary cationics, 15% ethylaminoethanol, 16% acetic acid, 15% isopropanol and 4% water
Composition;Deglossing liquid and flatting silica are the liquid and powdery of model OK-412 delustering agent;Polyethylene wax powder is 3620 wax powders;Defoaming agent
For the polymer-type defoaming agent of no organosilicon, model BYK-052.
The BK570 multi-functional environment-protection compound oil ink of said components ingredient, is prepared into according to the preparation step in embodiment 1
Finished product ink.
As stated above, the present invention uses special polyurethane resin, and the printing adaptability of ink improves 50%, traditional oils
Ink can only adapt to the print speed printing speed of 150-200m/min, and the present invention can adapt to the high speed printing of 300m/min, while this hair
Bright to have excellent photostability and chemical resistance, xanthochromia does not occur for ink, uses defoaming agent in ink, bubble compared with
Few, brokenly bubble is easier in production process, and no shrinkage cavity, ink product quality is higher, and bright-colored, high solid bottom is viscous, dot reproduction
It is excellent, levelability is fabulous, be very suitable to chromaticity printing, and there is extremely strong adhesive force, excellent solvent release and excellent
Freeze-proof, heat resistance are suitble to different print speed printing speeds.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (9)
1.BK570 multi-functional environment-protection compound oil ink, which is characterized in that be molten by polyurethane resin, polyvinyl acetate ethylene, ester alcohol
Agent, amylalcohol, polyethylene glycol diamines, pigment, dispersing agent, polyethylene wax powder, adhesion promoter, resists propylene glycol methyl ether acetate
Electrostatic agent, deglossing liquid, isophorone diamine, benzoyl peroxide, flatting silica and defoaming agent composition, the mass parts of above-mentioned each component
Number is respectively as follows: 25-40 parts of polyurethane resin, 10-15 parts of polyvinyl acetate ethylene, 30-45 parts of ester alcohol solvent, propylene glycol monomethyl ether vinegar
0.6-1 parts of acid esters, 1-3 parts of amylalcohol, 15-25 parts of polyethylene glycol diamines, 5-15 parts of pigment, 0.3-0.6 parts of dispersing agent, polyethylene wax
0.3-0.6 parts of powder, 0.8-1.5 parts of adhesion promoter, 0.8-1.5 parts of antistatic agent, 5-8 parts of deglossing liquid, isophorone diamine
0.5-1 parts, 0.5-1 parts of benzoyl peroxide, 1-3 parts of flatting silica and 0.3-0.6 parts of defoaming agent.
2. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the polyurethane resin is
By the polymer of isophorone diisocyanate and polypropylene -1,2- glycol ether.
3. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the ester alcohol solvent be by
N-propyl, isopropanol, ethyl ester and normal propyl alcohol are mixed according to mass parts ratio 30:10:8:2.
4. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the adhesion promoter
For modified chlorinated polypropylene.
5. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the antistatic agent be by
Following mass fraction at being grouped as: the quaternary cationics of 45%-50%, 15%-18% ethylaminoethanol,
The water of the acetic acid of 15%-18%, the isopropanol of 15%-18% and 3%-5%.
6. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the deglossing liquid with it is described
Flatting silica is the liquid and powdery of model OK-412 delustering agent.
7. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the dispersing agent is polyester
Polyamide copolymer.
8. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the polyethylene wax powder is
3620 wax powders.
9. BK570 multi-functional environment-protection compound oil ink according to claim 1, which is characterized in that the defoaming agent is that nothing has
The polymer-type defoaming agent of machine silicon, model BYK-052.
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CN201810118574.7A CN110117436A (en) | 2018-02-06 | 2018-02-06 | Multi-functional environment-protection compound oil ink |
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CN201810118574.7A CN110117436A (en) | 2018-02-06 | 2018-02-06 | Multi-functional environment-protection compound oil ink |
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CN201810118574.7A Withdrawn CN110117436A (en) | 2018-02-06 | 2018-02-06 | Multi-functional environment-protection compound oil ink |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110561935A (en) * | 2019-09-10 | 2019-12-13 | 金石包装(嘉兴)有限公司 | gravure printing method adopting water-based ink |
CN113059877A (en) * | 2019-12-31 | 2021-07-02 | 苏州瑞高新材料有限公司 | Novel wood-like decoration leather for automobile interior and preparation method thereof |
CN117965053A (en) * | 2024-03-29 | 2024-05-03 | 蓬莱新光颜料化工有限公司 | C.i. pigment red 57 for aqueous ink: 1 and a process for the preparation thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
-
2018
- 2018-02-06 CN CN201810118574.7A patent/CN110117436A/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103992690A (en) * | 2014-04-24 | 2014-08-20 | 苏州中亚油墨有限公司 | Novel environmentally-friendly high-speed gravure printing compound ink |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110561935A (en) * | 2019-09-10 | 2019-12-13 | 金石包装(嘉兴)有限公司 | gravure printing method adopting water-based ink |
CN113059877A (en) * | 2019-12-31 | 2021-07-02 | 苏州瑞高新材料有限公司 | Novel wood-like decoration leather for automobile interior and preparation method thereof |
CN113059877B (en) * | 2019-12-31 | 2023-02-28 | 苏州瑞高新材料有限公司 | Novel wood-like decorative leather for automobile interior and preparation method thereof |
CN117965053A (en) * | 2024-03-29 | 2024-05-03 | 蓬莱新光颜料化工有限公司 | C.i. pigment red 57 for aqueous ink: 1 and a process for the preparation thereof |
CN117965053B (en) * | 2024-03-29 | 2024-06-04 | 蓬莱新光颜料化工有限公司 | C.i. pigment red 57 for aqueous ink: 1 and a process for the preparation thereof |
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