CN110117199A - A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique - Google Patents

A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique Download PDF

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Publication number
CN110117199A
CN110117199A CN201910448867.6A CN201910448867A CN110117199A CN 110117199 A CN110117199 A CN 110117199A CN 201910448867 A CN201910448867 A CN 201910448867A CN 110117199 A CN110117199 A CN 110117199A
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heavy metal
house refuse
workshop section
boiler
compost
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吴昌垣
肖伟超
熊建英
谢光辉
汪志斌
卢伟
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China Electric Construction Group Jiangxi Electric Power Construction Co Ltd
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China Electric Construction Group Jiangxi Electric Power Construction Co Ltd
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Priority to CN201910448867.6A priority Critical patent/CN110117199A/en
Publication of CN110117199A publication Critical patent/CN110117199A/en
Priority to CN201911002994.XA priority patent/CN110606774A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00767Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
    • C04B2111/00784Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes for disposal only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Engineering & Computer Science (AREA)
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  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique, including following three parts: anaerobic fermentation workshop section, compost workshop section and boiler burn workshop section.The present invention can obtain a variety of byproducts (biogas, Water soluble fertilizer, solid organic fertilizer) of anaerobic ferment process, organic fertilizer fertilizer efficiency is promoted using composting process and realize that low energy consumption reduces moisture content, the safety processing that burning process realizes heavy metal to pollutant realization minimizing and enriching heavy metal into flying dust can be used;Solves the technical problem that anaerobic fermentation and compost product heavy metal can not be controlled effectively, less economical and feces of livestock and poultry anhydration and incineration is burned when can make up biomass or the single insufficient raw material of house refuse simultaneously to consume energy high disadvantage, veritably realizes waste resource recovery, innoxious, minimizing and economization processing.

Description

A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique
Technical field
The present invention relates to ecological, environmental protective technical field, specifically a kind of farming animals waste, house refuse collaboration utilize and again Metal control technique.
Background technique
Currently, animal husbandry, agricultural wastes and living garbage pollution problem have become the focus of global concern.Animal husbandry side Face, 2017 according to statistics, the feces of livestock and poultry that China generates was up to 3,800,000,000 tons, but only half or so is comprehensively utilized, this meaning Taste fail to be dealt carefully with there are also nearly 2,000,000,000 tons of feces of livestock and poultry, this will be to ecological environment, human health, regional appearance etc. Etc. various aspects cause huge negative effect.In terms of agriculture, in 8.2 hundred million tons of agricultural crop straws that the whole nation generates every year, there is 2.15 hundred million Ton is incinerated and discards.The energy is not only wasted, declines the content of organic matter of soil, causes under soil hardening and water-holding capacity Drop, while serious pollution atmosphere and water environment.In terms of living garbage pollution, it is more than 65 that China's domestic waste, which accumulates volume of cargo in storage, Hundred million tons, occupy about 3,500,000,000 square metres of soils, in national more than 660 a cities, existing 2/3 big and medium-sized cities are surrounded by rubbish, there is 1/4 City be forced the approach for solving rubbish crisis extending to rural area, lead to rubbish secondary pollution, the ecology of town and country bond area Environment deteriorates rapidly.
To solve the problems, such as animal husbandry, agricultural wastes and living garbage pollution, country has put into effect " state, National Development and Reform Commission Bureau of Energy, family is about the notice for printing and distributing energy development planning ", it is indicated that positive Developing Biomass liquid fuel, gaseous fuel, solid Shaped fuel pushes marsh gas power generation, Biomass Gasification & Power Generation.2017, Jiangxi, Fujian and Guizhou San Sheng were set as the whole nation by country First batch of conservation culture trial zone indicates that conservation culture trial zone construction in China enters the fully under way and acceleration propulsion phase.? Under this background, carry out what animal husbandry, agricultural and house refuse waste remediation were highly desirable.
For agricultural wastes and house refuse, direct combustion power generation is presently most mature processing technique, but biological Matter and garbage power need to just have feasibility in the preferable area of endowment of resources, power generation small scale warp when single resource material quantity is few Ji property is poor.And feces of livestock and poultry higher for moisture content, the mode of anhydration and incineration need to consume more external energy, influence project warp Ji benefit.Therefore, the method for taking direct combustion burning disposal agricultural, animal husbandry and house refuse is subject to many limitations.
The feces of livestock and poultry Land use systems currently generally taken are anaerobic fermentation and compost.Although excrement can be converted to natural pond fertilizer Or biogas, it realizes resource utilization, but due to being added in feed compared with multi-metal, leads to content of beary metal in feces of livestock and poultry It has generally exceeded the standard.On the one hand it will affect natural pond fertilizer quality, reduce project yield, the natural pond fertilizer on the other hand applying heavy metals exceeding standard will lead to Soil pollution, heavy metal eventually enter into human body by agricultural product and endanger health.Passivation is current with wider heavy metal Processing mode, but be only stable insoluble compound by the Morphological Transitions of heavy metal, and the separation removal of heavy metal is not implemented. After the fertilizer returning to the field of natural pond, heavy metal will face the risk of secondary release.A natural pond fertilizer huge sum of money is really realized in industrial application so far Belong to the effectively report that controls and safely remove there is not yet.Meet environmental requirement it is therefore proposed that a kind of new, technology and economically Feasible feces of livestock and poultry heavy metal effectively controls and removes scheme and is particularly important.
To sum up, in the region perplexed by a variety of waste pollutions such as biomass, feces of livestock and poultry, house refuse, exploitation one The novel multi-pollutant of kind cooperates with the effective technology controlled with qualified discharge for utilizing and realizing heavy metal, can thoroughly solve area Domain ecological environmental pollution problem, had both met the requirement of national Ecological Civilization Construction and sustainable development, but also with very strong reality Demand.
Summary of the invention
The purpose of the present invention is to overcome the deficiency in the prior art, provides a kind of farming animals waste, house refuse collaboration utilizes And heavy metal control technique, it is therefore intended that by the collaboration resource utilization of biomass, feces of livestock and poultry and house refuse, to reach Comprehensive agricultural, animal husbandry and the domestic waste multi-pollutant for solving the problems, such as that region faces perplexs, and solve biomass or Less economical and feces of livestock and poultry anhydration and incineration is burned when the single insufficient raw material of house refuse to consume energy high problem, meanwhile, it is another A purpose also resides in the effective control for realizing heavy metals in by-product, it is ensured that qualified discharge solves feces of livestock and poultry heavy metal pollution The problem of.
In order to achieve the above objectives, the present invention adopts the following technical scheme:
A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique, including following three parts form: detesting Aerobe fermentation workshop section, compost workshop section and boiler burn workshop section;
The step of anaerobic fermentation workshop section, is as follows: biomass being crushed, is mixed with feces of livestock and poultry, inoculum is added, is mixed Medium temperature wet type anaerobic fermentation is carried out after closing uniformly, generates biogas and residue;
The step of compost workshop section, is as follows: the biogas residue being uniformly mixed with biomass, is conveyed into trough type fermentation equipment During High-Temperature Composting processing is carried out, after compost, and heavy metal analysis is carried out to biogas residue and transports biogas residue if heavy metal is up to standard To organic fertilizer production workshop, organic fertilizer sale is made, if biogas residue heavy metal is not up to standard, workshop section is burned in transport to boiler;
It is as follows that the boiler burns the step of workshop section: biogas residue is sent directly into boiler together with biomass and house refuse and burns It burns, meanwhile, compost gas is passed through boiler aid fuel combustion, and heating boiler water generates steam;Heavy metal accumulation after burning In flying dust, chelating solidification.
Above-mentioned technical proposal is further arranged, specific step is as follows for the anaerobic fermentation workshop section:
Biomass powder is broken to 1.5~2.5mm, mixed in proportion with feces of livestock and poultry to fermentation raw material C/N ratio be (25~ 30): 1,20% inoculum is added, optionally plus water adjusts moisture content to 88~92%, and CSTR hair is sent into after being sufficiently mixed uniformly Fermentation tank carries out medium temperature wet type anaerobic fermentation 10~20 days, and fermentation generates biogas and residue.
Preferably, the temperature of medium temperature wet type anaerobic fermentation is 30~35 DEG C, and pH is between 6.5~8.0.
Above-mentioned technical proposal is further arranged, the residue enters filters pressing solid-liquid separating equipment, separates the biogas slurry of acquisition Through precipitation/filtration, ozonization, pH and incorporation nutritional ingredient preparation Water soluble fertilizer sale are adjusted, the moisture content for separating generation is 55 ~65% biogas residue then carries out heavy metal analysis, if heavy metal is up to standard, biogas residue is transported to organic fertilizer production workshop, is formed with Machine fertilizer is sold, if biogas residue heavy metal is not up to standard, is delivered to compost workshop section.
Preferably, the biogas produces CNG or power generation sale for purifying.
Above-mentioned technical proposal is further arranged, specific step is as follows for the compost workshop section:
The biogas residue is mixed in proportion with biomass, adjusting C/N ratio is (25~30): 1, it is conveyed into trough type fermentation and sets Standby to carry out During High-Temperature Composting processing, temperature is controlled at 45~60 DEG C, is kept for 55 DEG C of temperature of charge or more at least maintain 5 days, starting material Expect moisture control in 50~60%, pH between 6.0~8.0;
Biogas residue moisture is down to 18~22% after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, Biogas residue is transported to organic fertilizer production workshop, organic fertilizer sale is made, if biogas residue heavy metal is not up to standard, transport to boiler is burned Workshop section.
Above-mentioned technical proposal is further arranged, the bottom ventilation oxygen supply of the trough type fermentation equipment, every 1~3 day benefit It is primary to material turning with turner.
Above-mentioned technical proposal is further arranged, to prevent composting process from generating odor pollution, closed workshop is taken to force Draft type, compost gas are sent to boiler as combustion air.
Above-mentioned technical proposal is further arranged, the boiler burns workshop section, and specific step is as follows:
The biogas residue of moisture content 18~22% is not required to additionally consume energy to dry to be sent directly into pot together with biomass and house refuse Furnace burns, meanwhile, compost gas is passed through boiler aid fuel combustion, and heating boiler water generates steam;Heavy metal after burning It accumulates in flying dust, realizes great minimizing processing, heavy metal can be ensured not using the cement chelating solidification of low cost It secondary can be discharged into soil.
Preferably, the steam can be used in heat supply, steam supply or power generation.
Compared with prior art, the advantages and positive effects of the present invention are as follows:
(1) it has been provided simultaneously with anaerobic fermentation, compost and the advantage for burning three kinds of technique, the more of anaerobic ferment process can be obtained Kind byproduct (biogas, Water soluble fertilizer, solid organic fertilizer) promotes organic fertilizer fertilizer efficiency using composting process and realizes that low energy consumption reduces Moisture content, can be used burning process to pollutant realize minimizing and enriching heavy metal realized into flying dust heavy metal it is low at Safety processing;Meanwhile the disadvantage of three kinds of technique is in turn avoided, it solves anaerobic fermentation and compost product heavy metal can not be effective The technical problem of control veritably realizes waste resource recovery, innoxious, minimizing and economization processing;Life can be made up simultaneously Less economical and feces of livestock and poultry anhydration and incineration is burned when substance or the single insufficient raw material of house refuse to consume energy high disadvantage.
(2) biomass material (such as region stalk), feces of livestock and poultry (such as pig manure) and a variety of pollutions of house refuse are realized The collaboration resource utilization of object;It can get organic fertilizer, biogas, steam, a variety of byproducts of electric energy, and available abundant benefit With, resource utilization is high, and it is good in economic efficiency, meet circular economy concept, has technology and economic feasibility.
Detailed description of the invention
Fig. 1 farming animals waste of the present invention, house refuse collaboration utilize and heavy metal controls process principle figure;
Specific embodiment
Specific embodiments of the present invention will now be described in detail with reference to the accompanying drawings.
Embodiment 1
A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique, as shown in Figure 1, by following three Be grouped as: anaerobic fermentation workshop section, compost workshop section and boiler burn workshop section.
Specific step is as follows for the anaerobic fermentation workshop section:
Corn stalk powder is broken to 2.0mm, according to the TS content and elemental analysis of pig manure and stalk as a result, by corn stover To 27: 1 20% inoculum is added, optionally plus water adjusts moisture content extremely in Mixed adjustment C/N ratio in proportion with fresh pig manure 90%, CSTR fermentor is sent into after being sufficiently mixed uniformly and is carried out medium temperature wet type anaerobic fermentation 20 days, and fermentation generates biogas and residue.
The temperature of medium temperature wet type anaerobic fermentation is 33 DEG C, and pH is equal to 7.2.
The residue enters filters pressing solid-liquid separating equipment, separates the biogas slurry of acquisition through precipitation/filtration, ozonization, adjusting PH and incorporation nutritional ingredient preparation Water soluble fertilizer are sold, and the biogas residue that the moisture content for separating generation is 60% then carries out heavy metal analysis, If heavy metal is up to standard, biogas residue is transported to organic fertilizer production workshop, is made and meets NY525-2012 " organic fertilizer " standard Organic fertilizer is sold, if biogas residue heavy metal is not up to standard, is delivered to compost workshop section.
Power generation is sold after the biogas produces CNG (bio-natural gas) or pretreatment for purification.
Specific step is as follows for the compost workshop section:
The biogas residue and smashed corn stover are mixed in proportion, C/N ratio is adjusted to 26.5: 1, is conveyed into slot Formula Zymolysis Equipment carries out During High-Temperature Composting processing, and temperature is controlled at 45~60 DEG C, is kept for 60 DEG C of temperature of charge maintain 5 days, starting material Expect that moisture control is equal to 7.0 in 55%, pH;
Biogas residue moisture is down to 20% after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, by natural pond Slag, which is transported, the organic fertilizer for meeting NY525-2012 " organic fertilizer " standard is made to organic fertilizer production workshop to be sold, if weight Metal is not up to standard, then workshop section is burned in transport to boiler.
The bottom ventilation of the trough type fermentation equipment supplies oxygen, primary to material turning using turner every 2 days.
To prevent composting process from generating odor pollution, closed workshop forced ventilation mode is taken, compost gas is sent to boiler As combustion air.
The boiler burns workshop section, and specific step is as follows:
The biogas residue of moisture content 20% is not required to additionally consume energy to dry to be sent directly into bubbling together with corn stover and house refuse Fluidized-bed combustion boiler burns, meanwhile, compost gas is passed through boiler aid fuel combustion, solves odor pollution, and heating boiler water generates Steam heat supply, steam supply or power generation are carried out according to local demand;Heavy metal after burning accumulates in flying dust, realizes greatly Minimizing processing, using low cost cement chelating solidification can ensure that heavy metal secondary will not be discharged into soil.
Embodiment 2
A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique, as shown in Figure 1, by following three Be grouped as: anaerobic fermentation workshop section, compost workshop section and boiler burn workshop section.
Specific step is as follows for the anaerobic fermentation workshop section:
Corn stalk powder is broken to 2.5mm, according to the TS content and elemental analysis of cow dung and stalk as a result, by corn stover To 30: 1 20% inoculum is added, optionally plus water adjusts moisture content extremely in Mixed adjustment C/N ratio in proportion with fresh cow dung 92%, CSTR fermentor is sent into after being sufficiently mixed uniformly and is carried out medium temperature wet type anaerobic fermentation 20 days, and fermentation generates biogas and residue.
The temperature of medium temperature wet type anaerobic fermentation is 35 DEG C, and pH is equal to 8.0.
The residue enters filters pressing solid-liquid separating equipment, separates the biogas slurry of acquisition through precipitation/filtration, ozonization, adjusting PH and incorporation nutritional ingredient preparation Water soluble fertilizer are sold, and the biogas residue that the moisture content for separating generation is 65% then carries out heavy metal analysis, If heavy metal is up to standard, biogas residue is transported to organic fertilizer production workshop, is made and meets NY525-2012 " organic fertilizer " standard Organic fertilizer is sold, if biogas residue heavy metal is not up to standard, is delivered to compost workshop section.
Power generation is sold after the biogas produces CNG (bio-natural gas) or pretreatment for purification.
Specific step is as follows for the compost workshop section:
The biogas residue and smashed corn stover are mixed in proportion, C/N ratio is adjusted to 29.5: 1, is conveyed into slot Formula Zymolysis Equipment carries out During High-Temperature Composting processing, and temperature is controlled at 45~60 DEG C, is kept for 55 DEG C of temperature of charge maintain 5 days, starting material Expect that moisture control is equal to 8.0 in 60%, pH;
Biogas residue moisture is down to 22% after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, by natural pond Slag, which is transported, the organic fertilizer for meeting NY525-2012 " organic fertilizer " standard is made to organic fertilizer production workshop to be sold, if weight Metal is not up to standard, then workshop section is burned in transport to boiler.
The bottom ventilation of the trough type fermentation equipment supplies oxygen, primary to material turning using turner every 1 day.
To prevent composting process from generating odor pollution, closed workshop forced ventilation mode is taken, compost gas is sent to boiler As combustion air.
The boiler burns workshop section, and specific step is as follows:
The biogas residue of moisture content 22% is not required to additionally consume energy to dry to be sent directly into bubbling together with corn stover and house refuse Fluidized-bed combustion boiler burns, meanwhile, compost gas is passed through boiler aid fuel combustion, solves odor pollution, and heating boiler water generates Steam heat supply, steam supply or power generation are carried out according to local demand;Heavy metal after burning accumulates in flying dust, realizes greatly Minimizing processing, using low cost cement chelating solidification can ensure that heavy metal secondary will not be discharged into soil.
Embodiment 3
A kind of farming animals waste, house refuse collaboration utilizes and heavy metal control technique, as shown in Figure 1, by following three Be grouped as: anaerobic fermentation workshop section, compost workshop section and boiler burn workshop section.
Specific step is as follows for the anaerobic fermentation workshop section:
Wheat stalk is crushed to 1.5mm, according to the TS content and elemental analysis of pig manure and stalk as a result, by wheat stalk To 25: 1 20% inoculum is added, optionally plus water adjusts moisture content extremely in Mixed adjustment C/N ratio in proportion with fresh pig manure 88%, CSTR fermentor is sent into after being sufficiently mixed uniformly and is carried out medium temperature wet type anaerobic fermentation 20 days, and fermentation generates biogas and residue.
The temperature of medium temperature wet type anaerobic fermentation is 35 DEG C, and pH is equal to 7.0.
The residue enters filters pressing solid-liquid separating equipment, separates the biogas slurry of acquisition through precipitation/filtration, ozonization, adjusting PH and incorporation nutritional ingredient preparation Water soluble fertilizer are sold, and the biogas residue that the moisture content for separating generation is 55% then carries out heavy metal analysis, If heavy metal is up to standard, biogas residue is transported to organic fertilizer production workshop, is made and meets NY525-2012 " organic fertilizer " standard Organic fertilizer is sold, if biogas residue heavy metal is not up to standard, is delivered to compost workshop section.
Power generation is sold after the biogas produces CNG (bio-natural gas) or pretreatment for purification.
Specific step is as follows for the compost workshop section:
The biogas residue and smashed wheat stalk are mixed in proportion, C/N ratio is adjusted to 24.5: 1, is conveyed into slot Formula Zymolysis Equipment carries out During High-Temperature Composting processing, and temperature is controlled at 45~60 DEG C, is kept for 55 DEG C of temperature of charge maintain 5 days, starting material Expect that moisture control is equal to 6.0 in 50%, pH;
Biogas residue moisture is down to 18% after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, by natural pond Slag, which is transported, the organic fertilizer for meeting NY525-2012 " organic fertilizer " standard is made to organic fertilizer production workshop to be sold, if weight Metal is not up to standard, then workshop section is burned in transport to boiler.
The bottom ventilation of the trough type fermentation equipment supplies oxygen, primary to material turning using turner every 3 days.
To prevent composting process from generating odor pollution, closed workshop forced ventilation mode is taken, compost gas is sent to boiler As combustion air.
The boiler burns workshop section, and specific step is as follows:
The biogas residue of moisture content 18% is not required to additionally consume energy to dry to be sent directly into bubbling together with wheat stalk and house refuse Fluidized-bed combustion boiler burns, meanwhile, compost gas is passed through boiler aid fuel combustion, solves odor pollution, and heating boiler water generates Steam heat supply, steam supply or power generation are carried out according to local demand;Heavy metal after burning accumulates in flying dust, realizes greatly Minimizing processing, using low cost cement chelating solidification can ensure that heavy metal secondary will not be discharged into soil.
Above-described embodiment is only more excellent embodiment of the invention, is implemented according to the technical essence of the invention to above Any simple modification, modification and the alternate variation that example is made, belong in the range of technical solution of the present invention.

Claims (10)

1. the collaboration of a kind of farming animals waste, house refuse utilizes and heavy metal control technique, which is characterized in that including following three Be grouped as: anaerobic fermentation workshop section, compost workshop section and boiler burn workshop section;
The step of anaerobic fermentation workshop section, is as follows: biomass being crushed, is mixed with feces of livestock and poultry, inoculum is added, mixing is equal Medium temperature wet type anaerobic fermentation is carried out after even, generates biogas and residue;
The step of compost workshop section, is as follows: the biogas residue being uniformly mixed with biomass, is conveyed into the progress of trough type fermentation equipment During High-Temperature Composting processing after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, biogas residue is transported to having Between machine fertilizer production vehicle, organic fertilizer sale is made, if biogas residue heavy metal is not up to standard, workshop section is burned in transport to boiler;
It is as follows that the boiler burns the step of workshop section: biogas residue is sent directly into boiler burning together with biomass and house refuse, together When, compost gas is passed through boiler aid fuel combustion, and heating boiler water generates steam;Heavy metal after burning accumulates in flying dust In, chelating solidification.
2. the collaboration of a kind of farming animals waste according to claim 1, house refuse utilizes and heavy metal control technique, special Sign is that specific step is as follows for the anaerobic fermentation workshop section:
Biomass powder is broken to 1.5~2.5mm, being mixed in proportion with feces of livestock and poultry to fermentation raw material C/N ratio is (25~30): 1, 20% inoculum is added, optionally plus water adjusts moisture content to 88~92%, be sent into after being sufficiently mixed uniformly CSTR fermentor into Row medium temperature wet type anaerobic fermentation 10~20 days, fermentation generated biogas and residue.
3. the collaboration of a kind of farming animals waste according to claim 2, house refuse utilizes and heavy metal control technique, special Sign is that the temperature of medium temperature wet type anaerobic fermentation is 30~35 DEG C, and pH is between 6.5~8.0.
4. the collaboration of a kind of farming animals waste according to claim 3, house refuse utilizes and heavy metal control technique, special Sign is that the residue enters filters pressing solid-liquid separating equipment, separates the biogas slurry of acquisition through precipitation/filtration, ozonization, adjusting pH It is sold with incorporation nutritional ingredient preparation Water soluble fertilizer, the biogas residue that the moisture content for separating generation is 55~65% then carries out heavy metal inspection It surveys, if heavy metal is up to standard, biogas residue is transported to organic fertilizer production workshop, organic fertilizer sale is made, if biogas residue heavy metal does not reach Mark, then be delivered to compost workshop section.
5. the collaboration of a kind of farming animals waste according to claim 2, house refuse utilizes and heavy metal control technique, special Sign is that the biogas produces CNG or power generation sale for purifying.
6. the collaboration of a kind of farming animals waste according to claim 4 or 5, house refuse utilizes and heavy metal control technique, It is characterized in that, specific step is as follows for the compost workshop section:
The biogas residue is mixed in proportion with biomass, adjust C/N ratio be (25~30): 1, be conveyed into trough type fermentation equipment into The processing of row During High-Temperature Composting, temperature are controlled at 45~60 DEG C, are kept for 55 DEG C of temperature of charge or more at least maintain 5 days, starting material contains The control of water rate is in 50~60%, pH between 6.0~8.0;
Biogas residue moisture is down to 18~22% after compost, and carries out heavy metal analysis to biogas residue, if heavy metal is up to standard, by natural pond Slag is transported to organic fertilizer production workshop, and organic fertilizer sale is made, if biogas residue heavy metal is not up to standard, work is burned in transport to boiler Section.
7. the collaboration of a kind of farming animals waste according to claim 6, house refuse utilizes and heavy metal control technique, special Sign is that the bottom ventilation oxygen supply of the trough type fermentation equipment is primary to material turning using turner every 1~3 day.
8. the collaboration of a kind of farming animals waste according to claim 7, house refuse utilizes and heavy metal control technique, special Sign is, to prevent composting process from generating odor pollution, takes closed workshop forced ventilation mode, compost gas, which is sent to boiler, to be made For combustion air.
9. the collaboration of a kind of farming animals waste according to claim 8, house refuse utilizes and heavy metal control technique, special Sign is that the boiler burns workshop section, and specific step is as follows:
The drying that is not required to additionally to consume energy of the biogas residue of moisture content 18~22% is sent directly into boiler together with biomass and house refuse and burns It burns, meanwhile, compost gas is passed through boiler aid fuel combustion, and heating boiler water generates steam;Heavy metal accumulation after burning In flying dust, is chelated and solidified using cement.
10. the collaboration of a kind of farming animals waste according to claim 9, house refuse utilizes and heavy metal control technique, It is characterized in that, the steam can be used in heat supply, steam supply or power generation.
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CN111153749A (en) * 2019-12-28 2020-05-15 卢一念 Agricultural waste treatment processing technology
CN112119972A (en) * 2020-09-22 2020-12-25 安徽大学 Ecological mode of multi-energy complementary large-scale intelligent pig raising industry
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CN101270003B (en) * 2008-04-09 2010-06-16 李克彦 Biological organic fertilizer and method for producing the same
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CN110950516A (en) * 2019-11-27 2020-04-03 中国电建集团江西省电力建设有限公司 Comprehensive treatment system and method for livestock and poultry manure and household garbage
CN110950516B (en) * 2019-11-27 2023-12-22 中国电建集团江西省电力建设有限公司 System and method for comprehensively treating livestock and poultry manure and household garbage
CN111153749A (en) * 2019-12-28 2020-05-15 卢一念 Agricultural waste treatment processing technology
CN112119972A (en) * 2020-09-22 2020-12-25 安徽大学 Ecological mode of multi-energy complementary large-scale intelligent pig raising industry
CN113500080A (en) * 2021-05-23 2021-10-15 华北理工大学 Biomass multi-element coupling gasification system

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