CN110115266A - A kind of Compound Hydrogen Peroxide Disinfectant and preparation method thereof - Google Patents
A kind of Compound Hydrogen Peroxide Disinfectant and preparation method thereof Download PDFInfo
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- CN110115266A CN110115266A CN201910321566.7A CN201910321566A CN110115266A CN 110115266 A CN110115266 A CN 110115266A CN 201910321566 A CN201910321566 A CN 201910321566A CN 110115266 A CN110115266 A CN 110115266A
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- Prior art keywords
- hydrogen peroxide
- dodecyl
- acetic acid
- disinfectant
- hydroxy ethylidene
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to production technology disinfection technology fields in embryo egg production vaccine, disclose a kind of Compound Hydrogen Peroxide Disinfectant, it further include 1-hydroxy ethylidene-1,1-diphosphonic acid and dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide including water, hydrogen peroxide, acetic acid；Its weight percent composition are as follows: hydrogen peroxide 21~25.5%；Acetic acid 9.9~19.8%；1-hydroxy ethylidene-1,1-diphosphonic acid 0.3~1%；Dodecyl benzyl dimethyl ammonium chloride 0.1~1.5%；Remaining is water.Disinfectant sterilizing is rapid, disinfection is thorough, meanwhile, the invention also discloses the preparation methods of the disinfectant.
Description
Technical field
The present invention relates to production technology disinfection technology field in embryo egg production vaccine, in particular to a kind of compound hydrogen peroxide
Disinfectant and preparation method thereof.
Background technique
The prevalence of bird flu at present worldwide to aviculture with while serious blow to public health service
Constitute significant threat.Prevention and control of fowl influenza has become the common responsibility of international community, and prevention and control of fowl influenza is paid much attention in countries in the world,
It puts into a large amount of manpower and material resources and carries out correlative study.Inoculation AI oil-adjuvant inactivated vaccine is proved to be for bird flu epidemic situation
The maximally efficient method of prevention and control.
As the key link in vaccine production process, embryo egg surface sterilization is to be related to one of vaccine quality to Guan Chong
The factor wanted.
Peroxyacetic acid disinfectant is disinfectant commonly used in the art, and with broad spectrum activity, antivirus effect is strong, disinfecting time
Advantage short, decomposition product is nontoxic.
Chinese patent application CN201410311749.8 discloses a kind of binary disinfectant, points out in its background technique,
Traditional unitary disinfectant uses 8-hydroxyquinoline or urea as stabilizer, but the unitary disinfectant storage time is short and has
There is the risk of explosion.Based on the problem, binary disinfectant is proposed, one component is the mixing using acetic acid and sulfuric acid, separately
An outer component is hydrogen peroxide solution.
The program solves the problems, such as storage stability, but it uses the especially inconvenience that just seems.
Based on the above issues, Chinese patent application CN201210209519.1 discloses a kind of peracetic acid in single-ingredient disinfection solution
And preparation method thereof, use HWP integrated collaborative stabilising system based on the more ligand structural composites of the more carboxyls of polyhydroxy and
Storage of the special block nonionic surfactant as the mixed Peracetic acid for stablizing composition raising hydrogen peroxide and acetic acid
Stability is deposited, shows that its storage stability is excellent by test, its storage decaying is less than 4% in 8 months.Meanwhile it is special embedding
Section nonionic surfactant can reduce the surface tension of disinfectant, improves the wetting ability and penetrating power of disinfectant, makes
Its bactericidal effect is more preferable.
So finding more particularly suitable chelating agent is the reliable approach for improving unitary peroxyacetic acid disinfectant.
1-hydroxy ethylidene-1,1-diphosphonic acid is a kind of outstanding hydrogen peroxide stabilizer, in Chinese patent application CN201210587941.0
In disclose its application as hydrogen peroxide stabilizer, cooperate mannitol, sepiolite, montmorillonite, magnesium stannate, magnesium chloride energy
It is enough to be able to maintain the 99.73% of original concentration after storage 15 days；Metal ion removal rate can achieve 99.1%-99.9%.
Although Chinese patent application CN201210587941.0 solves asking for storage stability and metal ion-chelant
Topic, but in peroxyacetic acid disinfectant, there is also the problem of be poor to bacterial action permeability, be easy by organic substance
Influence and ideal Disinfection Effect is not achieved.
Summary of the invention
The purpose of the present invention is to provide a kind of Compound Hydrogen Peroxide Disinfectant, disinfectant sterilizing is rapid, disinfection is thorough,
Meanwhile the invention also discloses the preparation methods of the disinfectant.
To achieve the goals above, present invention provide the technical scheme that a kind of Compound Hydrogen Peroxide Disinfectant, including
Water, hydrogen peroxide, acetic acid further include 1-hydroxy ethylidene-1,1-diphosphonic acid and dodecyl benzyl dimethyl ammonium chloride and/or dodecyl
Dimethylbenzyl ammonium bromide；
Its weight percent composition are as follows:
Hydrogen peroxide 21~25.5%；
Acetic acid 9.9~19.8%；
1-hydroxy ethylidene-1,1-diphosphonic acid 0.3~1%；
Dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide 0.1~1.5%；
Remaining is water.
When selecting dodecyl benzyl dimethyl ammonium chloride and dodecyl dimethyl Benzylphosphonium Bromide compounds, any ratio
Compounding.
In above-mentioned Compound Hydrogen Peroxide Disinfectant, weight percent composition are as follows:
Hydrogen peroxide 21~22%；
Acetic acid 10~15%；
1-hydroxy ethylidene-1,1-diphosphonic acid 0.3~0.5%；
Dodecyl benzyl dimethyl ammonium chloride 0.1~0.5%；
Remaining is water.
Meanwhile the invention also discloses a kind of preparation method of Compound Hydrogen Peroxide Disinfectant as described above, feature exists
In proportionally equivalent sequentially adds acetic acid, hydrogen peroxide, dodecyl dimethyl after mixing water and 1-hydroxy ethylidene-1,1-diphosphonic acid
Benzyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide, stir evenly to obtain the final product.
In the preparation method of above-mentioned Compound Hydrogen Peroxide Disinfectant, the acetic acid is that mass percent concentration is
99% acetic acid；The hydrogen peroxide is the hydrogen peroxide that mass percent concentration is 30%.
In the preparation method of above-mentioned Compound Hydrogen Peroxide Disinfectant, specifically comprise the following steps:
Step 1: under conditions of room temperature, water and 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: acetic acid being added in the solution of step 1, sealing stirring 5~10 minutes；
Step 3: hydrogen peroxide being added in the solution of step 2, sealing stirring 5~10 minutes
Step 4: dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide are added to step
In 3 solution, and stirred evenly in the environment of 20 DEG C~30 DEG C of room temperature.
The beneficial effects of the present invention are:
In the present invention, dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide are as one kind
Surfactant, can also reinforce the permeability of bacterium the permeability of disinfectant in addition to can increase, while be also that a kind of wide spectrum kills
Microbial inoculum plays synergistic effect with Peracetic acid, especially has preferable killing effect to mould.
1-hydroxy ethylidene-1,1-diphosphonic acid makes hydrogen peroxide and dodecyl dimethyl Benzylmagnesium chloride during stable complex system
Ammonium and/or dodecyl dimethyl benzyl ammonium bromide combination bactericidal effect are obviously improved.
Specific embodiment
Illustrate the present invention With reference to embodiment: but it is understood that these specific embodiments are only intended to
Illustrate the present invention, rather than limiting the invention.Those skilled in the art completely can under the inspiration of the present invention, to this
The specific embodiment or technical characteristic of invention improve, but these still belong to by the technical solution improved or replaced
In protection scope of the present invention.
Embodiment one
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 25 DEG C, 82g water and 6g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 200g acetic acid (mass percent concentration 99%) being added in the solution of step 1,5 points of sealing stirring
Clock；
Step 3: 710g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring 5
Minute；
Step 4: 2g dodecyl benzyl dimethyl ammonium chloride being added in the solution of step 3, and is stirred evenly.
Two, of embodiment
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 25 DEG C, 90g water and 3g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 145g acetic acid (mass percent concentration 99%) being added in the solution of step 1, sealing stirring 10
Minute；
Step 3: 750g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring
10 minutes；
Step 4: 12g dodecyl benzyl dimethyl ammonium chloride being added in the solution of step 3, and is stirred evenly i.e.
It can.
Embodiment three
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 25 DEG C, 150g water and 10g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 130g acetic acid (mass percent concentration 99%) being added in the solution of step 1,5 points of sealing stirring
Clock；
Step 3: 700g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring
10 minutes；
Step 4: 10g dodecyl dimethyl benzyl ammonium bromide being added in the solution of step 3, and is stirred evenly i.e.
It can.
Example IV
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 20 DEG C, 80g water and 9g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 110g acetic acid (mass percent concentration 99%) being added in the solution of step 1,6 points of sealing stirring
Clock；
Step 3: 800g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring 8
Minute；
Step 4: 1g dodecyl benzyl dimethyl ammonium chloride being added in the solution of step 3, and is stirred evenly.
Embodiment five
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 20 DEG C, 40g water and 8g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 100g acetic acid (mass percent concentration 99%) being added in the solution of step 1,7 points of sealing stirring
Clock；
Step 3: 850g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring 8
Minute；
Step 4: 2g dodecyl dimethyl benzyl ammonium bromide being added in the solution of step 3, and is stirred evenly.
Embodiment six
A kind of preparation method of Compound Hydrogen Peroxide Disinfectant, specifically comprises the following steps:
Step 1: under conditions of 25 DEG C, 130g water and 5g 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: 150g acetic acid (mass percent concentration 99%) being added in the solution of step 1,9 points of sealing stirring
Clock；
Step 3: 700g hydrogen peroxide (mass percent concentration 30%) being added in the solution of step 2, sealing stirring 6
Minute；
Step 4: 15g dodecyl benzyl dimethyl ammonium chloride being added in the solution of step 3, and is stirred evenly i.e.
It can.
Test data of experiment one
Compound hydrogen peroxide disinfection solution of the invention, our experiments show that, to bacterial propagule, bacterial spore, mould and
The microorganisms such as mycotic spore have very strong killing effect, wherein dodecyl benzyl dimethyl ammonium chloride and dimethyl
Kill effect of the base Benzylphosphonium Bromide ammonium played in compound disinfectant is consistent, and being detailed in following subordinate list one, (table one is using embodiment
The compound Hydrogen Peroxide Disinfectant that one method is prepared):
One disinfectant of table kills concentration and the time of bacterium
Comparative example 1
It is substantially the same with embodiment 1, unlike, dodecyl benzyl dimethyl ammonium chloride is not added, i.e., no step
4。
Test data of experiment two
The bactericidal composition of comparative example 1 has one to microorganisms such as bacterial propagule, bacterial spore, mould and mycotics spore
Fixed killing effect, being detailed in following subordinate list two, (table one disappears using the compound hydrogen peroxide that the method for comparative example 1 is prepared
Toxic agent):
Two disinfectant of table kills concentration and the time of bacterium
By above-mentioned test, we are available such as to draw a conclusion:
1, disinfectant of the invention has the microorganisms such as bacterial propagule, bacterial spore, mould and mycotic spore very strong
Killing effect；
2, dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide be not in disinfectant of the invention
The function of sterilization is only played, collaboration enhancing also is carried out to Peracetic acid bactericidal effect.
3, the chelating agent 1-hydroxy ethylidene-1,1-diphosphonic acid in disinfectant of the invention makes peroxidating during stable complex system
Hydrogen and dodecyl benzyl dimethyl ammonium chloride combination bactericidal effect are obviously improved.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, other any changes, modifications, substitutions, combinations, simplifications made without departing from the spirit and principles of the present invention,
It should be equivalent substitute mode, be included within the scope of the present invention.
Claims (5)
1. a kind of Compound Hydrogen Peroxide Disinfectant, including water, hydrogen peroxide, acetic acid, which is characterized in that further include hydroxy ethylidene two
Phosphonic acids and dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide；
Its weight percent composition are as follows:
Hydrogen peroxide 21~25.5%；
Acetic acid 9.9~19.8%；
1-hydroxy ethylidene-1,1-diphosphonic acid 0.3~1%；
Dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide 0.1~1.5%；
Remaining is water.
2. Compound Hydrogen Peroxide Disinfectant according to claim 1, which is characterized in that its weight percent composition are as follows:
Hydrogen peroxide 21~22%；
Acetic acid 10~15%；
1-hydroxy ethylidene-1,1-diphosphonic acid 0.3~0.5%；
Dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide 0.1~0.5%；
Remaining is water.
3. a kind of preparation method of Compound Hydrogen Peroxide Disinfectant as claimed in claim 1 or 2, which is characterized in that according to than
Example equivalent sequentially adds acetic acid, hydrogen peroxide, dodecyl dimethyl Benzylmagnesium chloride after mixing water and 1-hydroxy ethylidene-1,1-diphosphonic acid
Ammonium and/or dodecyl dimethyl benzyl ammonium bromide, stir evenly to obtain the final product.
4. the preparation method of Compound Hydrogen Peroxide Disinfectant according to claim 3, which is characterized in that the acetic acid is
The acetic acid that mass percent concentration is 99%；The hydrogen peroxide is the hydrogen peroxide that mass percent concentration is 30%.
5. the preparation method of Compound Hydrogen Peroxide Disinfectant according to claim 3 or 4, which is characterized in that specifically include
Following steps:
Step 1: under conditions of room temperature, water and 1-hydroxy ethylidene-1,1-diphosphonic acid being mixed, stirring is to being completely dissolved；
Step 2: acetic acid being added in the solution of step 1, sealing stirring 5~10 minutes；
Step 3: hydrogen peroxide being added in the solution of step 2, sealing stirring 5~10 minutes
Step 4: dodecyl benzyl dimethyl ammonium chloride and/or dodecyl dimethyl benzyl ammonium bromide are added to step 3
In solution, and stirred evenly in the environment of 20 DEG C~30 DEG C of room temperature.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910321566.7A CN110115266A (en) | 2019-04-22 | 2019-04-22 | A kind of Compound Hydrogen Peroxide Disinfectant and preparation method thereof |
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| CN201910321566.7A CN110115266A (en) | 2019-04-22 | 2019-04-22 | A kind of Compound Hydrogen Peroxide Disinfectant and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114190379A (en) * | 2021-11-17 | 2022-03-18 | 陕西环玉食品科技有限公司 | Universal high-stability monoperoxyacetic acid disinfectant and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109418264A (en) * | 2017-09-04 | 2019-03-05 | 上海利康消毒高科技有限公司 | Unitary peroxyacetic acid disinfectant and preparation method thereof |
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- 2019-04-22 CN CN201910321566.7A patent/CN110115266A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109418264A (en) * | 2017-09-04 | 2019-03-05 | 上海利康消毒高科技有限公司 | Unitary peroxyacetic acid disinfectant and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 中国材料研究学会组织编写: "《中国战略性新兴产业-新材料 环境工程材料》", 30 November 2018, 中国铁道出版社 * |
| 郝学安等: "《现代医院感染控制与实用消毒技术》", 31 July 2009 * |
| 陈仪本等: "《工业杀菌剂》", 31 May 2001 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114190379A (en) * | 2021-11-17 | 2022-03-18 | 陕西环玉食品科技有限公司 | Universal high-stability monoperoxyacetic acid disinfectant and preparation method thereof |
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