CN110105721A - A kind of new glass fibre reinforced plastic and preparation process - Google Patents
A kind of new glass fibre reinforced plastic and preparation process Download PDFInfo
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- CN110105721A CN110105721A CN201910468013.4A CN201910468013A CN110105721A CN 110105721 A CN110105721 A CN 110105721A CN 201910468013 A CN201910468013 A CN 201910468013A CN 110105721 A CN110105721 A CN 110105721A
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- reinforced plastic
- glass reinforced
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- glass
- fragile stem
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
The invention belongs to airport special equipment fields, and in particular to a kind of new glass fibre reinforced plastic and preparation process.The specific technical proposal is: a kind of glass reinforced plastic, formula includes: by mass fraction, 30~40 parts of bispenol epoxy vinyl base resin, 25~30 parts of phenolic resin, 10~15 parts of calcium carbonate, 15~20 parts of aluminium hydroxide, 30~40 parts of glass fibre.Glass reinforced plastic provided by the invention, flexural strength are up to 462MPa, and shear strength only has 11MPa；The product prepared with the glass reinforced plastic, it is more difficult when by high wind to fracture, it is very easy to fracture when being hit, occurs to be crushed, be highly suitable to be applied on the related facility of Flying Area in Airport.
Description
Technical field
The invention belongs to field of compound material, and in particular to a kind of new glass fibre reinforced plastic and preparation process.
Background technique
In the various equipment that airport uses, there should be certain franglibility.According to " airport design manual " the 6th part pair
The introduction of franglibility, the various facilities in all movement areas, such as meteorological equipment, radio navigation device, because it may be to flying
Row constitutes security risk, it requires that these equipment must be crushed immediately when receiving collision, i.e., should have franglibility.
But since all kinds of objective and subjective reasons limit, the numerous equipment in movement area still use steel frame construction as support, are unable to satisfy easy to break
Property.If can provide it is a kind of can be applied to movement area, there is good franglibility, while will not fracture under conventional environment state
Material, flight safety will be greatly improved.
Glass reinforced plastic, i.e. fiber-reinforced plastic make the reinforced plastics of reinforcing material with glass fibre or its product.Because it has
The advantages that light intensity is high, corrosion-resistant, hot property and electrical property are good, is used widely in multiple fields.Though this kind of material
Right intensity is higher, but bending strength generally only has 150~200MPa, and shearing strength is generally in 30MPa or more；Encounter high wind day
Gas, the risk for still remaining bending, fractureing；Meanwhile when receiving shock, it can not necessarily be crushed at once.Therefore, it is necessary to further
It promotes bending strength, reduce shearing strength simultaneously.But the performance of bending strength and shearing strength increases and decreases often correlation,
It is difficult to reduce another intensity while promoting an intensity.
Summary of the invention
That the object of the present invention is to provide a kind of outdoor adaptive faculties is strong, be impacted after the easily broken dedicated wind sleeve in airplane parking area.
For achieving the above object, the technical scheme adopted by the invention is that: a kind of glass reinforced plastic, the glass reinforced plastic are matched
Side include: by mass fraction, 30~40 parts of bispenol epoxy vinyl base resin, 25~30 parts of phenolic resin, 10~15 parts of calcium carbonate,
15~20 parts of aluminium hydroxide, 30~40 parts of glass fibre.
Preferably, the formula of the glass reinforced plastic further includes 0.5~3 part of ultraviolet absorbing agent.
Preferably, the formula of the glass reinforced plastic includes: by mass fraction, 30~40 parts of bispenol epoxy vinyl base resin, phenol
25~30 parts of urea formaldehyde, 10~15 parts of calcium carbonate, 15~20 parts of aluminium hydroxide, 30~40 parts of glass fibre, ultraviolet absorbing agent
0.5~3 part, 1~2 part of curing agent, 1~3 part of release agent.
Preferably, the curing agent is made of in mass ratio for 2:1 benzoyl peroxide and peroxidized t-butyl perbenzoate.
Correspondingly, the preparation method of the glass reinforced plastic, characterized by the following steps:
(1) by bispenol epoxy vinyl base resin, phenolic resin, calcium carbonate, aluminium hydroxide with high speed mixer stir 0.5~
1.5h is sufficiently mixed uniformly, and temperature is 50~80 DEG C when stirring；
(2) when there are ultraviolet absorbing agent, curing agent, release agent, ultraviolet absorbing agent, curing agent, demoulding are added
Agent is kept for 50~80 DEG C of temperature, is stirred 0.5h~1.5h, is obtained mixture；
(3) mixture is prepared as required shape, it is cooling up to required glass reinforced plastic.
Preferably, the method that mixture is prepared as required shape is pultrusion, the temperature when pultrusion
Degree is 200~220 DEG C, and environment temperature is 10~30 degrees Celsius.
Preferably, pultrusion speed=25+ when the pultrusion (20- environment temperature) × 0.85, unit: cm/min.
Correspondingly, application of the glass reinforced plastic on the facility of Flying Area in Airport.
Correspondingly, using the airport indication device for wind direction for having the glass reinforced plastic, including the hollow fragile stem being vertically arranged, institute
Fragile stem is stated to be made of the glass reinforced plastic；Wind sleeve, the wind sleeve and fragile stem connection position is arranged in the fragile stem middle and upper part
It sets, in the fragile stem, is correspondingly arranged the rotary connector that wind sleeve can be made around fragile stem axial-rotation.
Preferably, uniformly distributed several frangible points in the fragile stem.
The invention has the following advantages:
The present invention provides a kind of glass reinforced plastic for being exclusively used in Flying Area in Airport related facility, flexural strength is up to
462MPa, shear strength only have 11MPa.It is more difficult when by high wind to fracture, and folding is very easy to when being hit
Disconnected, generation is crushed.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention；
Fig. 2 is a kind of embodiment schematic diagram of the frangible point of the present invention；
Fig. 3 is the perspective view of broken bar device at frangible point in Fig. 2；
Fig. 4 is the another embodiment schematic diagram of the frangible point of the present invention.
Specific embodiment
The formula of the special glass steel are as follows: press mass fraction, 30~40 parts of bispenol epoxy vinyl base resin, phenolic resin
25~30 parts, 10~15 parts of calcium carbonate, 15~20 parts of aluminium hydroxide, 30~40 parts of glass fibre, ultraviolet absorbing agent 0.5~3
Part, 1~2 part of curing agent, 1~3 part of release agent.
Wherein, the ultraviolet absorbing agent is the conventional commercially available ultraviolet absorbing agent that can be used for glass reinforced plastic on the market,
Such as UV-9 (ESCALOL 567), UV-531 (2-hydroxy-4-n-octoxybenzophenone), RMB (single benzene
Formic acid resorcinol) etc.；For convenience of implementation, UV-531 is used in following embodiments.The curing agent can be used
Common Curing Agents in glass reinforced plastic preparation, are preferably 2:1 by benzoyl peroxide and peroxidized t-butyl perbenzoate in mass ratio
Composition；Release agent herein refers mainly to inner pattern releasing agent applicable, and the glass reinforced plastics such as zinc stearate can be used and often use release agent, for convenience of real
It applies, in following embodiments, release agent is zinc stearate, and dosage is 2 parts.
The glass reinforced plastic the preparation method comprises the following steps:
(1) by bispenol epoxy vinyl base resin, phenolic resin, calcium carbonate, aluminium hydroxide with high speed mixer stir 0.5~
1.5h is sufficiently mixed uniformly, and temperature is 50~80 DEG C when stirring.
(2) it then adds ultraviolet absorbing agent, curing agent, release agent, is kept for 50~80 DEG C of temperature, stirring 0.5h~
1.5h obtains mixture.
(3) mixture is placed in dragging-squeezing machine for fiberglass and carries out pultrusion to get required glass reinforced plastic.The drawing
The temperature of extrusion forming is 200~220 DEG C, and environment temperature need to be maintained at 10~30 degrees Celsius, pultrusion speed=25+ (20- environment temperature
Degree) × 0.85, unit: cm/min.
Combined with specific embodiments below, the preparation method of glass reinforced plastic is further explained.
Embodiment
1,16 groups of glass reinforced plastics are prepared according to the above method, carry out extrusion forming under the conditions of 210 DEG C of pultrusion temperature.Each group
The practical preparation parameter of glass reinforced plastic is as shown in table 1, and the numerical value of each component refers to mass fraction in table.The curing agent 1, curing agent 2
It is purchased from Changzhou Chang Sheng glass-reinforced plastic material Co., Ltd, curing agent 1 is unsaturated-resin curing agent, and curing agent 2 is epoxy resin
Curing agent.
The preparation parameter of 1 each group glass reinforced plastic of table is referring to table
2, the bending strength and shearing strength of each group glass reinforced plastic are tested, the results are shown in Table 2.
The performance of 2 each group glass reinforced plastic of table shows table
Glass reinforced plastic prepared by the present invention is also applied to specific Flying Area in Airport relevant device by inventor, and combines glass
The characteristic of steel provides a kind of indication device for wind direction using the glass reinforced plastic.
As shown in Figure 1, a kind of indication device for wind direction, the pedestal 2 including being fixed on ground is solid vertically on the pedestal 2
Fixed hollow fragile stem 1, certainly, fragile stem 1 can also be fixed on other required positions or be directly fixed on ground.The fragile stem
1 material is the glass reinforced plastic, has stronger bending resistance, will not be rolled in the normal outdoor environment such as blowing and raining
It is disconnected；Its anti-shear ability is weaker simultaneously, is very easy to fracture when by external force collision, be crushed, (i.e. to avoid damage impacting body
Aircraft).Wind sleeve 4 is arranged in 1 middle and upper part of fragile stem.The wind sleeve 4 and 1 link position of fragile stem, the fragile stem 1
On, it is correspondingly arranged the rotary connector that wind sleeve 4 can be made around 1 axial-rotation of fragile stem.
Preferred scheme are as follows: uniformly distributed several frangible points 3 in the fragile stem 1, each frangible point 3 can be further improved frangible
Frangible performance easy to break when bar 1 is impacted.Fig. 2,3 illustrate a kind of embodiment of the frangible point 3, wherein Fig. 2 is only opened up
The side wall construction of fragile stem 1 is shown, arrow direction is external force direction.The frangible point 3 includes being arranged in 1 bar wall of fragile stem
Interior broken bar device 31.As shown in figure 3, the broken bar device 31 is in funnel-shaped structure, broken 31 cross section of bar device is in 1 wall of fragile stem
In thickness across with a thickness of the 2/3~3/4 of 1 wall thickness of fragile stem；It should be understood that the funnel depth of the broken bar device 31 is easy
The 2/3~3/4 of broken 1 wall thickness of bar.Broken 31 cross section of bar device is in V-shape, and opening direction is described towards outside fragile stem 1
The hardness of broken bar device 31 is greater than the hardness of fragile stem 1, can be made of the strong material of stainless steel or other rigidity, weatherability.Make
When with this embodiment, because frangible point 3 is combined closely with fragile stem 1, outside fragile stem 1, with not set frangible point 3
It is identical.In the masterpiece used time by large area such as wind-force in environment, when the stress condition of fragile stem 1 and not set frangible point 3
It is identical, still flexural strength with higher；When by external force collision, stress is relatively concentrated, the broken bar device 31 at frangible point 3
The funnel bottom that shock stress is focused on to broken bar device 31 further speeds up the broken of fragile stem 1.
Fig. 4 illustrates the another embodiment of frangible point 3.For in elliposoidal inside fragile stem 1 at the frangible point 3
Hollow structure, the wall thickness of the hollow structure circumferential direction are 2/3~5/6 of remaining position wall thickness in fragile stem 1.It should be understood that
It is externally, identical when the pattern of fragile stem 1 is with not set frangible point 3 in this embodiment.In by environment
When the effects of wind-force, the stress of fragile stem 1 also with not set frangible point 3 when it is identical；When by external force collision, stress collection
In, it is more easily broken provided with the fragile stem 1 at frangible point 3.
Preferred scheme are as follows: the diameter of the wind sleeve 4 is different.Wind sleeve 4 from 1 connecting pin of fragile stem to outstanding
End extends, and diameter successively decreases, in the small taper of mouth outsole.This structure makes the side windage area of wind sleeve 4 be greater than opening
The wind area at (outstanding end).When blowing, wind sleeve 4 carries out axial direction under the action of the wind, by rotary connector around fragile stem 1
Rotation, until going to the opening direction face wind direction of wind sleeve 4, to play the role of identifying wind direction.
Preferred scheme are as follows: the rotary connector includes two the first swivel bearings for being fixed on 1 top of fragile stem
61 and it is fixed on two the second swivel bearings 62 of 1 middle and upper part of fragile stem.Pass through first between described two first swivel bearings 61
Connecting rod 71 connects.Second connecting rod 72 connects between described two second swivel bearings 62.
First swivel bearing 61 positioned at 1 the top of fragile stem is located at 4 lower end corresponding position of wind sleeve, remaining
Three swivel bearings are respectively positioned on the not corresponding position of wind sleeve 4.It should be understood that being located at position in first swivel bearing 61
Higher bearing is set, position is in the lower section corresponding position of wind sleeve 4；Another first swivel bearing 61 is located at wind sleeve 4
The position being not directed to；The a part of first connecting rod 71 in fragile stem 1 is corresponding with 4 present position of wind sleeve, another part position
In the position that wind sleeve 4 is not directed to.Two the second swivel bearings 62 and corresponding second connecting rod 72 are respectively positioned on wind sleeve 4 and do not relate to
And position.Such positional relationship is more advantageous to the progress of wind sleeve 4 itself rotation, is also beneficial to fragile stem 1 to wind sleeve 4
Load-bearing.Meanwhile the rotation connection that 4 swivel bearings and two connecting rods are realized, preferable waterproof and dustproof can be played and made
With avoiding water or impurity from entering inside the body of rod of fragile stem 1, to extend the service life of fragile stem 1.
Preferred scheme are as follows: be additionally provided with warning lamp 5 at the top of the indication device for wind direction.The warning lamp 5 can be electricity
Pond power supply, or power supply is routed from outside by connecting to power supply power supply inside 1 body of rod of fragile stem, or directly.Warning lamp 5 and power supply
Between be additionally provided with switch, or remote control is opened and closed by other remote controllers, to play a warning role.
Claims (10)
1. a kind of glass reinforced plastic, it is characterised in that: the formula of the glass reinforced plastic includes: by mass fraction, bispenol epoxy vinyl Ji Shu
30~40 parts of rouge, 25~30 parts of phenolic resin, 10~15 parts of calcium carbonate, 15~20 parts of aluminium hydroxide, 30~40 parts of glass fibre.
2. glass reinforced plastic according to claim 1, it is characterised in that: the formula of the glass reinforced plastic further includes 0.5~3 part ultraviolet
Light absorbers.
3. glass reinforced plastic according to claim 1, it is characterised in that: the formula of the glass reinforced plastic include: by mass fraction, it is double
30~40 parts of phenol epoxy vingl ester resin, 25~30 parts of phenolic resin, 10~15 parts of calcium carbonate, 15~20 parts of aluminium hydroxide, glass
30~40 parts of glass fiber, 0.5~3 part of ultraviolet absorbing agent, 1~2 part of curing agent, 1~3 part of release agent.
4. glass reinforced plastic according to claim 3, it is characterised in that: the curing agent is by benzoyl peroxide and benzoyl peroxide first
Tert-butyl acrylate is 2:1 composition in mass ratio.
5. the preparation method of glass reinforced plastic described in Claims 1 to 4 any one, characterized by the following steps:
(1) by bispenol epoxy vinyl base resin, phenolic resin, calcium carbonate, aluminium hydroxide with high speed mixer stir 0.5~
1.5h is sufficiently mixed uniformly, and temperature is 50~80 DEG C when stirring；
(2) when there are ultraviolet absorbing agent, curing agent, release agent, ultraviolet absorbing agent, curing agent, release agent are added, is protected
50~80 DEG C of temperature are held, 0.5h~1.5h is stirred, obtains mixture；
(3) mixture is prepared as required shape, it is cooling up to required glass reinforced plastic.
6. the preparation method of glass reinforced plastic according to claim 5, it is characterised in that: described that mixture is prepared as required shape
The method of shape is pultrusion, and the temperature when pultrusion is 200~220 DEG C, and environment temperature is 10~30 degrees Celsius.
7. the preparation method of glass reinforced plastic according to claim 6, it is characterised in that: the pultrusion speed when pultrusion
=25+ (20- environment temperature) × 0.85, unit: cm/min.
8. application of the glass reinforced plastic described in Claims 1 to 4 any one on the facility of Flying Area in Airport.
9. application has the right to require the airport indication device for wind direction of glass reinforced plastic described in 1~4 any one, it is characterised in that: including
The hollow fragile stem (1) being vertically arranged, the fragile stem (1) are made of the glass reinforced plastic；Fragile stem (1) the middle and upper part setting
On wind sleeve (4), the wind sleeve (4) and fragile stem (1) link position, the fragile stem (1), wind sleeve can be made by being correspondingly arranged
(4) around the rotary connector of fragile stem (1) axial-rotation.
10. airport indication device for wind direction according to claim 9, it is characterised in that: uniformly distributed several on the fragile stem (1)
Frangible point (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910468013.4A CN110105721B (en) | 2019-05-31 | 2019-05-31 | Glass fiber reinforced plastic and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910468013.4A CN110105721B (en) | 2019-05-31 | 2019-05-31 | Glass fiber reinforced plastic and preparation process thereof |
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| Publication Number | Publication Date |
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| CN110105721A true CN110105721A (en) | 2019-08-09 |
| CN110105721B CN110105721B (en) | 2022-04-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910468013.4A Active CN110105721B (en) | 2019-05-31 | 2019-05-31 | Glass fiber reinforced plastic and preparation process thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751324A (en) * | 2016-12-05 | 2017-05-31 | 东华大学 | A kind of preparation method of crystal waste slag vinylite composite |
| CN109096689A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of flame resistant glass steel pipe and preparation method thereof |
| CN109096688A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of glass reinforced plastic pipe resistant to high temperatures |
| CN109705521A (en) * | 2017-10-26 | 2019-05-03 | 青岛海大智汇科技管理咨询有限公司 | A kind of pyroceram steel composite material |
-
2019
- 2019-05-31 CN CN201910468013.4A patent/CN110105721B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751324A (en) * | 2016-12-05 | 2017-05-31 | 东华大学 | A kind of preparation method of crystal waste slag vinylite composite |
| CN109705521A (en) * | 2017-10-26 | 2019-05-03 | 青岛海大智汇科技管理咨询有限公司 | A kind of pyroceram steel composite material |
| CN109096689A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of flame resistant glass steel pipe and preparation method thereof |
| CN109096688A (en) * | 2018-04-09 | 2018-12-28 | 南通德瑞森复合材料有限公司 | A kind of glass reinforced plastic pipe resistant to high temperatures |
Non-Patent Citations (1)
| Title |
|---|
| 章美华: "《新世纪青少年科普经典化学揭秘》", 31 December 2000 * |
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