CN110102155A - The detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system - Google Patents
The detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system Download PDFInfo
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- CN110102155A CN110102155A CN201910477502.6A CN201910477502A CN110102155A CN 110102155 A CN110102155 A CN 110102155A CN 201910477502 A CN201910477502 A CN 201910477502A CN 110102155 A CN110102155 A CN 110102155A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/40—Acidic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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Abstract
The present invention relates to smoke comprehensive process fields, more particularly to being a kind of detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system includes air inlet pipe, exhaust gases passes and NaOH water tank, pH value controller, pH sensor and neutralization pond, air inlet pipe is connected to the inlet end of exhaust gases passes, NaOH water tank is connected to by the second connecting tube with exhaust gases passes, exhaust gases passes bottom is provided with the water-soluble liquid pool of NaOH, pH value controller is connect by transmission line with pH sensor and solenoid valve, first inlet of neutralization pond is connected to by overflow pipe with the overflow port of the water-soluble liquid pool of NaOH, second inlet of neutralization pond is connected to a condensate pipe.Pass through the real value monitoring of structures being made of NaOH water tank, the water-soluble liquid pool of NaOH, pH value controller, pH sensor and neutralization pond, pH value controller passes through the pH value of pH sensor real-time monitoring NaOH water-soluble liquid pool and neutralization pond, when fluctuating by the flow of solenoid valve control NaOH water tank, it is allowed to the dynamic equilibrium of one, whole system region.
Description
Technical field
The present invention relates to smoke comprehensive process fields, and in particular to is a kind of natural gas boiler condensed water pH real value detection
And waste water neutralisation treatment exhaust system.
Background technique
As natural gas condensing boiler is promoted the use of, contain NO in the flue gas of discharge2Equal sour gas, cause environment
Certain harm can be adsorbed and be removed to sour gas by spraying some alkaline solutions at present, but actually be made
Do not accomplish that pH real value detects in, whole system is caused to be unable to reach dynamic equilibrium, does not make unification to waste liquid after neutralization yet
Processing, is not easy to manage.
Summary of the invention
The present invention, which is directed to, can adsorb and remove to sour gas by spraying some alkaline solutions at present, but
Do not accomplish that pH real value detects in actual use, whole system is caused to be unable to reach dynamic equilibrium, not to waste liquid after neutralization yet
The problem of being uniformly processed, being not easy to management provides in a kind of detection of natural gas boiler condensed water pH real value and waste water and locates
Manage exhaust system.
The present invention solves above-mentioned technical problem, the technical solution adopted is that, the detection of natural gas boiler condensed water pH real value
And waste water neutralisation treatment exhaust system include air inlet pipe, exhaust gases passes and NaOH water tank, pH value controller, pH sensor and in
And pond, air inlet pipe are connected to the inlet end of exhaust gases passes, NaOH water tank is connected to by the second connecting tube with exhaust gases passes, and flue gas is logical
Road bottom is provided with the water-soluble liquid pool of NaOH, and pH value controller is connect by transmission line with pH sensor and solenoid valve, and pH value passes
Sensor is set in the water-soluble liquid pool of NaOH and neutralization pond, and solenoid valve is set in the second connecting tube, and the first inlet of neutralization pond passes through
Overflow pipe is connected to the overflow port of the water-soluble liquid pool of NaOH, and the second inlet of neutralization pond is connected to a condensate pipe.
Further, the inlet of NaOH water tank is connected to NaOH supplement liquid pipe, and the leakage fluid dram and sewage pipe of neutralization pond connect
It is logical.
Further, pH sensor includes the first pH sensor and the second pH sensor, the first pH sensor
In the water-soluble liquid pool of NaOH, the second pH sensor is set in neutralization pond.
Further, pH value controller model SIN-pH3.0, the first pH sensor and the second pH sensor are
Tetra- fluoride electrode of pH.
Optionally, first pH sensor one end is perforated from the pool wall of the water-soluble liquid pool of NaOH is inserted into the water-soluble liquid pool of NaOH
Interior, the first pH sensor other end is connect with transmission line, and the probe of the first pH sensor is located in the water-soluble liquid pool of NaOH.
Optionally, perforation inner wall is provided with water proof set made of acid and alkali-resistance material.
Optionally, the second pH sensor is soaked in neutralization pond, and second pH sensor one end is connect with transmission line, the
The two pH sensor other ends are socketed with protective cover, and the probe of the second pH sensor is located in protective cover.
Optionally, protective cover is horn structure, and stub end is equipped with opening, and microcephaly end is socketed in the company of the second pH sensor
On joint chair.
Beneficial effects of the present invention include at least following one；
1, it is examined by the real value being made of NaOH water tank, the water-soluble liquid pool of NaOH, pH value controller, pH sensor and neutralization pond
Geodesic structure, pH value controller pass through the pH value of pH sensor real-time detection NaOH water-soluble liquid pool and neutralization pond, are fluctuating
When by the flow of solenoid valve control NaOH water tank, be allowed to the dynamic equilibrium of one, whole system region.
2, by the water-soluble liquid pool of NaOH, neutralization pond and overflow pipe, liquid extra in the water-soluble liquid pool of NaOH is passed through into overflow
Pipe imports neutralization pond and carries out neutralization reaction with the acid condensate water imported from a condensate pipe, is arranged after reaching discharge standard
It puts.
3, solving can be adsorbed and be removed to sour gas by spraying some alkaline solutions at present, but in reality
Border does not accomplish that pH real value detects in, causes whole system to be unable to reach dynamic equilibrium, does not make to waste liquid after neutralization yet
The problem of being uniformly processed, being not easy to management.
Detailed description of the invention
Fig. 1 is the detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system structural schematic diagram；
Fig. 2 is a kind of pH sensor structural schematic diagram；
Fig. 3 is another pH sensor structural schematic diagram；
Fig. 4 is that flue gas heat-exchange system and NO are increased on the basis of Fig. 12The structural schematic diagram of spray-absorption system；
Fig. 5 is heat pump unit structural schematic diagram；
In the figure, it is marked as 1 being air inlet pipe, 2 being exhaust gases passes, 3 be water fender, 4 be NaOH water tank, 5 being the water-soluble liquid pool of NaOH, 6
For heat pump unit, 7 be neutralization pond, 8 be pH value controller, 9 be first group of nozzle, 10 be second group of nozzle, 11 be third group spray
Mouth, 12 be the first connecting tube, 13 be the second connecting tube, 14 be NaOH supplement liquid pipe, 15 be solenoid valve, 16 be condenser feed liquor
Pipe, 17 be the first drain pipe, 18 be condenser drain pipe, 19 be the first pH sensor, 20 be the second pH sensor, 21 be
Overflow pipe, 22 be condenser, 23 be evaporator, 24 be throttle valve, 25 be compressor, 32 be pH sensor, 33 be transmission line,
34 it is perforation, 35 be water proof set, 36 be probe, 37 be attachment base, 38 is protective cover.
Specific embodiment
It is clear in order to enable the objectives, technical solutions, and advantages of the present invention to be more clear, below in conjunction with attached drawing and implementation
The present invention will be described in further detail for example.It should be appreciated that specific embodiment described herein is only used to explain this hair
It is bright, it is not intended to limit the present invention protection content.
As shown in Figure 1, the detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system include air inlet
Pipe 1, exhaust gases passes 2 and NaOH water tank 4, pH value controller 8, pH sensor 32 and neutralization pond 7, air inlet pipe 1 and exhaust gases passes 2
Inlet end connection, NaOH water tank 4 is connected to by the second connecting tube 13 with exhaust gases passes 2, and 2 bottom of exhaust gases passes is provided with NaOH
Water-soluble liquid pool 5, pH value controller 8 are connect by transmission line 33 with pH sensor 32 and solenoid valve 15, and pH sensor 32 is set
In in the water-soluble liquid pool 5 of NaOH and neutralization pond 7, solenoid valve 15 is set in the second connecting tube 13, and the first inlet of neutralization pond 7 passes through
Overflow pipe 21 is connected to the overflow port of the water-soluble liquid pool 5 of NaOH, and the second inlet of neutralization pond 7 is connected to a condensate pipe 4.
In use, by being made of NaOH water tank, the water-soluble liquid pool of NaOH, pH value controller, pH sensor and neutralization pond
Real value detection structure, pH value controller by the pH value of pH sensor real-time detection NaOH water-soluble liquid pool and neutralization pond,
When fluctuating by the flow of solenoid valve control NaOH water tank, it is allowed to the dynamic equilibrium of one, whole system region.Pass through
The water-soluble liquid pool of NaOH, neutralization pond and overflow pipe, by liquid extra in the water-soluble liquid pool of NaOH by overflow pipe import neutralization pond with
The acid condensate water imported from a condensate pipe carries out neutralization reaction, is discharged after reaching discharge standard.It solves at present
Sour gas can be adsorbed and be removed by spraying some alkaline solutions, but not accomplish pH reality in actual use
Duration detection, causes whole system to be unable to reach dynamic equilibrium, waste liquid after neutralization is not also uniformly processed, is not easy to management
Problem.
In the present embodiment, the inlet of NaOH water tank 4 is connected to NaOH supplement liquid pipe 14, the leakage fluid dram of neutralization pond 7 and row
Dirty pipe 22 is connected to, and the leakage fluid dram of the water-soluble liquid pool 5 of NaOH is connected to the first drain pipe, and wherein NaOH replenisher pipe is for supplementing NaOH
The NaOH aqueous solution consumed in water tank, sewage pipe are used to the waste liquid being more than after neutralization reaction carrying out uniform effluent.
In the present embodiment, as shown in Fig. 2, 8 model SIN-pH3.0 of pH value controller, the first pH sensor 19 and
Two pH sensors 20 are tetra- fluoride electrode of pH, and pH sensor 32 includes the first pH sensor 19 and the second pH sensor
20, the first pH sensor 19 is set in the water-soluble liquid pool 5 of NaOH, and the second pH sensor 20 is set in neutralization pond 7.First pH value
19 one end of sensor is perforated from the pool wall of the water-soluble liquid pool 5 of NaOH in the 34 insertion water-soluble liquid pools 5 of NaOH, the first pH sensor 19
The other end is connect with transmission line 33, and the probe 36 of the first pH sensor 19 is located in the water-soluble liquid pool 5 of NaOH.34 inner walls of perforating are set
It is equipped with the set of water proof made of acid and alkali-resistance material 35.
Label " 32 " is pH sensor in Fig. 2, can may be in actual use for the first pH sensor
Two pH sensors are sentenced the first pH sensor to describe this and are stated, and pH value controller 8 monitors the first pH value in real time
20 numerical value of sensor 19 and the second pH sensor, when slant acidity in the water-soluble liquid pool of NaOH, control solenoid valve is improved from NaOH
Water tank is input to the NaOH solution flow of the water-soluble liquid pool of NaOH, and when meta-alkalescence in the water-soluble liquid pool of NaOH, control solenoid valve is reduced
The NaOH solution flow of the water-soluble liquid pool of NaOH is input to from NaOH water tank, when slant acidity in neutralization pond, control solenoid valve is improved
The NaOH solution flow of the water-soluble liquid pool of NaOH is input to from NaOH water tank, from overflow pipe to enter neutralization pond neutral and alkali molten to increase
Liquid measure, when meta-alkalescence in neutralization pond, control solenoid valve reduces the NaOH solution that the water-soluble liquid pool of NaOH is input to from NaOH water tank
Flow enters neutralization pond neutral and alkali amount of solution to reduce from overflow pipe, or increases a condensed water inlet.
The probe segment of first pH sensor is inserted into the water-soluble liquid pool of NaOH, due to the pool wall in the water-soluble liquid pool of NaOH
On be provided with perforation, and in perforation be arranged acid and alkali-resistance material made of water proof set, the first pH sensor can be effectively prevent
The phenomenon that being to shake in real-time detection, the collision of the pool wall of probe segment and the water-soluble liquid pool of NaOH is caused to damage,
The water proof set made of acid and alkali-resistance material is able to bear NaOH aqueous corrosion simultaneously, and prevents liquid from therefrom leaking, testing number
Value is delivered to pH value controller by transmission line.
In the present embodiment, as shown in figure 3, the second pH sensor 20 is soaked in neutralization pond 7, the second pH sensor 20
One end is connect with transmission line 33, and 20 other end of the second pH sensor is socketed with protective cover 38, the spy of the second pH sensor 20
First 36 are located in protective cover 38.Protective cover 38 is horn structure, and stub end is equipped with opening, and microcephaly end is socketed in the second pH value sensing
On the attachment base 37 of device 20.
Label " 32 " is pH sensor in Fig. 3, can may be in actual use for the first pH sensor
Two pH sensors are sentenced the second pH sensor to describe this and are stated, the second pH sensor is immersed in neutralization
In the neutralizer in pond, since the probe in the second pH sensor is located in protective cover, in floating will not because of in collision and
Pond inner wall causes probe to damage, while in order to improve liquid interaction in protective cover, sensor overall sensitivity is improved, in protective cover
On open up through-hole, be allowed to outside liquid it is more convenient enter protective cover in.
It is cold in natural gas boiler in order to further remove sour gas and the flue gas heat exchange in flue gas in the present embodiment
Increase NO on the basis of the detection of condensate pH real value and waste water neutralisation treatment exhaust system2Spray-absorption system and flue gas heat exchange
System is provided with nozzle in the middle part of exhaust gases passes 2 as shown in Figure 4 and Figure 5.First drain pipe, 17 one end and the water-soluble liquid pool 5 of NaOH
Leakage fluid dram connection, the other end are connected to heat pump unit 6, and the first connecting tube 12 is connected to heat pump unit 6, after completing heat exchange
Liquid is delivered to nozzle, and condenser inlet tube 16 and condenser drain pipe 18 are connected to heat pump unit 6, on exhaust gases passes 2
Portion is provided with water fender 3.
Pass through NO2The NaOH water mist that spray-absorption system is ejected absorbs natural gas condensing boiler flue gas.It is logical
Flue gas heat-exchange system is crossed to spray-absorption NO2Aqueous solution afterwards cools down, and is allowed to temperature decline, realizes recuperation of heat.
Since whole system has heat recovery function, smog discharge temperature is greatly lowered, cold air and discharge flue gas temperature
Difference is simultaneously little, therefore natural gas boiler burner can suitably increase air inlet amount, improve excess air factor, be conducive to fire
Gas completely burned, CO in flue gas2And NO2Content ratio rises, the decline of CO and NO content ratio, and because passes through NO2Spray-absorption
System is by NO2It is dissolved in water and is reacted with NaOH, flue gas nitrogen oxide discharge is greatly lowered to realize.
Its reaction equation are as follows:
3NO2+H20=2HNO3+NO
2NO2+2NaOH=NaNO3+NaNO2+H2O
HNO3+NaOH=NaNO3+H20
In the present embodiment, nozzle includes that first group of nozzle, 9, second groups of nozzles 10 and third group nozzle 11, first group of nozzle 9 are located at
5 top of the water-soluble liquid pool of NaOH, and the jet port of first group of nozzle 9 is vertically upward, second group of nozzle 10 and third group nozzle 11 are equal
Positioned at 2 inner wall two sides of exhaust gases passes, and the jet port of the jet port of second group of nozzle 10 and third group nozzle 11 is obliquely, and
Three groups of nozzles 11 are located at second group of nozzle, 10 top.Wherein nozzle is stainless steel spiral spray head DN15-DN25.
Three groups of nozzles are arranged in exhaust gases passes vertical component in setting in this way, wherein the liquid-drop diameter of first group of nozzle spray is most
It is small, it is sprayed along smoke movement direction, it, can to offset second group of nozzle and third group nozzle spray water mist to the resistance of flue gas
The parameter request of the stabilization pressurized operation of effective guarantee natural gas boiler burner, while the water mist and flue gas sprayed from nozzle
Mixing directly absorbs the heat of flue gas, and the liquid-drop diameter that second group of nozzle and third group nozzle spray is relative to first group of nozzle
The liquid-drop diameter of spray is sequentially increased, and continues to cool down to mixed flue gas, while the water droplet in spray droplet and flue gas is again
Mutually fusion, diameter are further increased, are finally dropped under gravity in the water-soluble liquid pool of NaOH of exhaust gases passes bottom.
In the present embodiment, heat pump unit 6 includes throttle valve 24, evaporator 23, compressor 25 and condenser 22, the first drain
Pipe 17 is connected to 23 liquid feeding end of evaporator, and the first connecting tube 12 is connected to 23 drain side of evaporator, condenser inlet tube 16 with it is cold
The connection of 22 liquid feeding end of condenser, condenser drain pipe 18 are connected to 22 drain side of condenser, carry out between evaporator 23 and condenser 22
Heat exchange.Wherein 23 liquid feeding end temperature of evaporator is 12 DEG C, and 23 drain side temperature of evaporator is 7 DEG C, 22 liquid feeding end temperature of condenser
Degree is 35 DEG C, and 22 drain side temperature of condenser is 40 DEG C.Circulation pump group is provided on first drain pipe 17.
Solution temperature evaporator and the condenser heat exchange in 12 DEG C, landscape heat pump unit being discharged from the water-soluble liquid pool of NaOH
Temperature is reduced to 7 DEG C after effect, is delivered to nozzle again and is sprayed, at the same the fluid temperature imported by condenser inlet tube from
35 DEG C are promoted to 40 DEG C, realize whole heat exchange.
It should be noted that NaOH water tank from the point of view of single, each component such as evaporator and condenser, neutralization pond in heat pump unit
Etc. structures be the prior art, in order to realize that its fixed function necessarily contains required structure, such as in order to enable evaporator and cold
Condenser completes heat exchange, and compressor is necessarily controlled to a power supply, and those skilled in the art also being capable of voluntarily group according to actual needs
Fill the connection structure between compatible hardware above.
Claims (8)
1. the monitoring of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system, it is characterised in that: including air inlet
Manage (1), exhaust gases passes (2) and NaOH water tank (4), pH value controller (8), pH sensor (32) and neutralization pond (7)；
The air inlet pipe (1) is connected to the inlet end of exhaust gases passes (2), and the NaOH water tank (4) passes through the second connecting tube (13)
It is connected to exhaust gases passes (2), exhaust gases passes (2) bottom is provided with the water-soluble liquid pool of NaOH (5), the pH value controller (8)
It is connect by transmission line (33) with pH sensor (32) and solenoid valve (15), it is water-soluble that the pH sensor (32) is set to NaOH
In liquid pool (5) and neutralization pond (7), the solenoid valve (15) is set on the second connecting tube (13), the neutralization pond (7) first into
Liquid mouth is connected to by overflow pipe (21) with the overflow port of the water-soluble liquid pool of NaOH (5), the second inlet of neutralization pond (7) with it is once cold
Condensate pipe (4) connection.
2. natural gas boiler condensed water pH real value monitoring according to claim 1 and waste water neutralisation treatment exhaust system,
It is characterized by: the inlet of the NaOH water tank (4) is connected to NaOH supplement liquid pipe (14), the drain of the neutralization pond (7)
Mouth is connected to sewage pipe (22).
3. natural gas boiler condensed water pH real value monitoring according to claim 2 and waste water neutralisation treatment exhaust system,
It is characterized by: pH value controller (8) the model SIN-pH3.0, first pH sensor (19) and the second pH value
Sensor (20) is tetra- fluoride electrode of pH.
4. according to claim 1 to the monitoring of natural gas boiler condensed water pH real value described in 3 any claims and waste water
Neutralisation treatment exhaust system, it is characterised in that: the pH sensor (32) includes the first pH sensor (19) and the 2nd pH
It is worth sensor (20), first pH sensor (19) is set in the water-soluble liquid pool of NaOH (5), second pH sensor
(20) it is set in neutralization pond (7).
5. natural gas boiler condensed water pH real value monitoring according to claim 4 and waste water neutralisation treatment exhaust system,
It is characterized by: described first pH sensor (19) one end is perforated from the pool wall of the water-soluble liquid pool of NaOH (5), (34) are inserted into
In the water-soluble liquid pool of NaOH (5), the first pH sensor (19) other end is connect with transmission line (33), the first pH sensor (19)
Probe (36) be located in the water-soluble liquid pool of NaOH (5).
6. natural gas boiler condensed water pH real value monitoring according to claim 5 and waste water neutralisation treatment exhaust system,
It is characterized by: described perforation (34) inner wall is provided with water proof set (35) made of acid and alkali-resistance material.
7. natural gas boiler condensed water pH real value monitoring according to claim 4 and waste water neutralisation treatment exhaust system,
It is characterized by: second pH sensor (20) is soaked in neutralization pond (7), the second pH sensor (20) one end and biography
Defeated line (33) connection, the second pH sensor (20) other end are socketed with protective cover (38), the spy of the second pH sensor (20)
Head (36) is located in protective cover (38).
8. natural gas boiler condensed water pH real value monitoring according to claim 7 and waste water neutralisation treatment exhaust system,
It is characterized by: the protective cover (38) is horn structure, stub end is equipped with opening, and microcephaly end is socketed in the second pH sensor
(20) on attachment base (37).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910477502.6A CN110102155A (en) | 2019-06-03 | 2019-06-03 | The detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910477502.6A CN110102155A (en) | 2019-06-03 | 2019-06-03 | The detection of natural gas boiler condensed water pH real value and waste water neutralisation treatment exhaust system |
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| JPH11179145A (en) * | 1997-12-22 | 1999-07-06 | Ishikawajima Harima Heavy Ind Co Ltd | Absorbent supply control method and apparatus for flue gas desulfurization facility |
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| CN103721538A (en) * | 2013-12-30 | 2014-04-16 | 清华大学 | Integrated treatment and utilizing device for recovering and denitrating smoke waste heat and condensate water of natural gas |
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| CN108452658A (en) * | 2018-04-28 | 2018-08-28 | 苏州华烯环保科技有限公司 | A kind of high vertical PP soda acids exhaust gas washing tower of gas flow rate |
| CN208082199U (en) * | 2018-01-31 | 2018-11-13 | 青岛海安生物环保有限公司 | Graphite waste gas absorption and resources apparatus |
| CN208244434U (en) * | 2018-04-03 | 2018-12-18 | 中金嵩县嵩原黄金冶炼有限责任公司 | A kind of double spray sulfur-containing tail gas processing units |
-
2019
- 2019-06-03 CN CN201910477502.6A patent/CN110102155A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11179145A (en) * | 1997-12-22 | 1999-07-06 | Ishikawajima Harima Heavy Ind Co Ltd | Absorbent supply control method and apparatus for flue gas desulfurization facility |
| CN202460400U (en) * | 2012-02-28 | 2012-10-03 | 郭灿明 | Boiler desulfurization device |
| CN103721538A (en) * | 2013-12-30 | 2014-04-16 | 清华大学 | Integrated treatment and utilizing device for recovering and denitrating smoke waste heat and condensate water of natural gas |
| CN206463762U (en) * | 2016-12-13 | 2017-09-05 | 深圳市捷晶能源科技有限公司 | A kind of flue gas recirculation carrying out washing treatment system |
| CN208082199U (en) * | 2018-01-31 | 2018-11-13 | 青岛海安生物环保有限公司 | Graphite waste gas absorption and resources apparatus |
| CN208244434U (en) * | 2018-04-03 | 2018-12-18 | 中金嵩县嵩原黄金冶炼有限责任公司 | A kind of double spray sulfur-containing tail gas processing units |
| CN108452658A (en) * | 2018-04-28 | 2018-08-28 | 苏州华烯环保科技有限公司 | A kind of high vertical PP soda acids exhaust gas washing tower of gas flow rate |
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Application publication date: 20190809 |
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