CN209173690U - A kind of desulfurization and denitrification integral absorption tower - Google Patents

A kind of desulfurization and denitrification integral absorption tower Download PDF

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Publication number
CN209173690U
CN209173690U CN201821707516.XU CN201821707516U CN209173690U CN 209173690 U CN209173690 U CN 209173690U CN 201821707516 U CN201821707516 U CN 201821707516U CN 209173690 U CN209173690 U CN 209173690U
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CN
China
Prior art keywords
denitration
absorption tower
desulfurization
level
oxidation
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Expired - Fee Related
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CN201821707516.XU
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Chinese (zh)
Inventor
余旭冬
冉强
田驰
陈勇
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Nanjing Zhongdian Environmental Protection Technology Co Ltd
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Nanjing Zhongdian Environmental Protection Technology Co Ltd
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Priority to CN201821707516.XU priority Critical patent/CN209173690U/en
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Abstract

The utility model discloses a kind of desulfurization and denitrification integral absorption tower, including attracting tower ontology, and it is arranged in and attracts the intrinsic level-one denitration oxidation panel of tower, crystallized region, second level denitration oxidation panel, desulphurization denitration absorber portion, filler washing section, flue gas enters absorption tower ontology through flue entrance, in level-one denitration oxidation panel after ozone oxidation, flue gas after the oxidation of level-one denitration oxidation panel enters crystallized region, second level denitration oxidation panel is entered after crystallized section of cooling, further oxidation unoxidized NO gas in level-one denitration oxidation panel;Flue gas after the oxidation of second level denitration oxidation panel enters desulphurization denitration absorber portion, by sprayed slurry by the sour gas washing absorption after exhaustive oxidation in flue gas, realizes desulphurization denitration.Oxidizing and denitrating ozone combination ammonia desulfurizing process is used by the absorption tower, desulfurization and denitration function are combined into one, while reaching identical desulfuration efficiency, the occupied ground area of equipment is can be reduced, saves electric energy.

Description

A kind of desulfurization and denitrification integral absorption tower
Technical field
The utility model relates to power industry fire coal boiler fume, petrochemical industry fire coal boiler fume, sintering device flue gas, water Mud factory boiler smoke and glass factory's boiler flue gas desulfurization denitrification apparatus.
Background technique
It is increasingly strict due to domestic and international environmental protection standard, the requirement to denitration is increased, the absorption of traditional desulphurization denitration is set Standby produce uses soil larger, and flue gas resistance is larger, the area occupied in place and the power consumption of booster fan is increased, for sound Answer the policy of energy-saving and emission-reduction, it is necessary to occupied ground and flue gas resistance bring energy are reduced with new desulphurization denitration absorption equipment Consumption.
Currently, denitration absorption equipment uses SCR denitration reaction device both at home and abroad in traditional absorption equipment, reducing agent is utilized NO in flue gas is reduced into N2Principle remove NOXGas, denitration efficiency≤85%, flue gas pressures 1000Pa;Desulfurization absorption is set The standby spray absorber used only with desulfurizing function, flue gas resistance is about 1200Pa.It can be seen that traditional desulfurization and denitration are inhaled Receiving unit drag overall is greater than 2200Pa, and resistance is big, and energy consumption is high.
Utility model content
The purpose of this utility model is to provide a set of absorption equipment for being combined into one desulfurization and denitration function, use is smelly Oxygen oxidation and denitration combination ammonia desulfurizing process, making the biggish two equipment concentration in original land occupation place is an absorption efficiency High-quality energy-saving equipment high, resistance is small, while reaching identical desulfuration efficiency, can be reduced the occupied ground area of equipment, save Blower consumes electric energy.
A kind of desulfurization and denitrification integral absorption tower, including attract tower ontology, and be arranged in and attract the intrinsic level-one of tower Denitration oxidation panel, crystallized region, second level denitration oxidation panel, desulphurization denitration absorber portion, filler washing section, in which: level-one denitration oxidation Section is located in the flue entrance for attracting tower body lower part side wall at closely absorption tower tower body;Crystallized region is located at the bottom of absorption tower ontology Portion, second level denitration oxidation panel, desulphurization denitration absorber portion and filler washing section are located above crystallized region and are sequentially arranged from bottom to top; Desulphurization denitration absorber portion is disposed with circulated sprinkling pipe and the first catch tray below circulated sprinkling pipe, first catch tray It is connect by pipeline with outer pulp liquor collecting device, the circulated sprinkling pipe is collected by pipeline and circulating pump and the slurries and filled Set connection;Packing layer and the washing spraying layer above packing layer are configured in filler washing section;Level-one denitration oxidation panel and Second level denitration oxidation panel is laid with ozone even distribution device.
As a preferred embodiment, ozone even distribution device uniformly divides on supervisor including a supervisor and manifold, branch pipe, and The ozone for being connected with airfoil shape is evenly distributed with sheet metal.
As a preferred embodiment, the material of the sheet metal is oxidation resistant 316L.
As a preferred embodiment, it is provided in crystallized region molten for circulated sprinkling ammonium sulfate and the mixing of ammonium nitrate unsaturation The crystallization spray tube of liquid, the crystallization flushing pipe above crystallization spray tube for being rinsed to crystallized region section, and the position and In the crystallization tank for attracting tower body bottom portion to be used to collect ammonium sulfate and ammonium nitrate unsaturation mixed solution after concentration.
As a preferred embodiment, the crystallization tank of crystallized region, crystallization spray tube and crystallization flushing pipe are all made of wear-resisting resistance to height Warm material.
As a preferred embodiment, desulphurization denitration absorber portion is disposed at least two layers of circulated sprinkling pipe.
As a preferred embodiment, further include the demisting section being arranged at the top of absorption tower, be provided in demisting section for going Except the demister and mist eliminator flushing layer of the water droplet in flue gas.
As a preferred embodiment, the demister is ridge type demister.
As a preferred embodiment, it there also is provided the second catch tray below filler washing section, second catch tray is logical Piping is connect with outer pulp liquor collecting device, and the circulated sprinkling pipe passes through pipeline and circulating pump and the slurries collection device Connection.
As a preferred embodiment, attract tower ontology to be adopted as carbon steel lining glass flake material, tower internals is attracted to adopt Use anti-corrosion material.
Based on above-mentioned desulfurization and denitrification integral absorption tower, flue gas enters absorption tower ontology through flue entrance, in level-one denitration In oxidation panel after ozone oxidation, NO gas therein is oxidized to NO2;By level-one denitration oxidation panel oxidation after flue gas into Enter crystallized region, enters second level denitration oxidation panel after crystallized section of cooling, further oxidation non-oxygen in level-one denitration oxidation panel The NO gas of change;Flue gas after the oxidation of second level denitration oxidation panel enters desulphurization denitration absorber portion, in desulphurization denitration absorber portion In, by sprayed slurry by the sour gas washing absorption after exhaustive oxidation in flue gas, realize desulphurization denitration;Volatilization in flue gas It is washed with the substance of decomposition by the packing layer and washing spraying layer configured in filler washing section, and is starched and return to absorption tower It recycles, is removed in flue gas after most droplets finally by demisting section VI, qualified discharge.
Desulfurization and denitrification integral absorption tower disclosed in the utility model has the advantages that
(1) in an absorption equipment can two class pollutant acid gas of absorbing and removing simultaneously, realize desulfurization and denitration, no longer Two independent equipment are needed to complete the function of desulfurization and denitration;Length of flow across of the flue gas in absorption equipment is shortened, is subtracted Small resistance of the flue gas in absorption equipment;And the electric energy loss of blower can be reduced, realize energy-efficient purpose.
(2) denitrating flue gas does not use traditional catalyst reduction method, has evaded original catalytic reduction method denitration to temperature The strict demand of degree increases the randomness of denitration;It is also avoided that original catalytic reduction method denitration is short to service life to consolidate The dependence of body catalyst reduces the cost depletions of catalyst.
(3) SCR reactor must be arranged in 300-400 DEG C of high-temperature flue gas section by changing original catalytic reduction method denitration Status, equipment is arranged in the least significant end of flue gas, corrosion of the corrosivity wet flue gas after reducing desulphurization denitration to other equipment Probability.
(4) a variety of polluted gas are concentrated into absorption processing in an equipment, greatly reduces desulfurization and denitration absorption equipment Occupied ground, reduce one-time investment cost and operating cost.
(5) the integration absorption tower has a wide range of application, and can be used for removing power industry fire coal boiler fume, petrochemical industry combustion Sulphur nitre pollutant acid gas in coal burning boiler flue gas, sintering device flue gas, cement plant boiler smoke and glass factory's boiler smoke.
Detailed description of the invention
Attached drawing 1 is the structural schematic diagram on desulfurization and denitrification integral absorption tower;
Appended drawing reference: I. level-one denitration oxidation panel, II. crystallized region, III. second level denitration oxidation panel, IV. desulphurization denitration are inhaled Receive section, V. filler washing section, VI. demisting section, 1. ozone even distribution devices, 2. flue entrances, 3. crystallization tanks, 4. crystallization spray tubes, 5. crystallizing flushing pipe, 6. ozone even distribution devices, 7. catch trays, 8. circulated sprinkling pipes, 9. catch trays, 10. packing layers, 11. washings Spraying layer, 12. demisters, 13. mist eliminator flushing layers.
Specific embodiment
As shown in Figure 1, a kind of desulfurization and denitrification integral absorption tower (abbreviation absorption tower) is disclosed in embodiment, in absorption tower cigarette Ozone even distribution device 1 is arranged in road entrance 2, forms level-one denitration oxidation panel I, and ozone even distribution device 1 is upper uniform in a supervisor Many branch pipes are distributed, the ozone that airfoil shape is connected on branch pipe is evenly distributed with sheet metal, this sheet metal material is oxidation resistant 316L It is made, can prevent by ozone oxidation.Ozone uniformly sprays into level-one denitration oxidation panel I after ozone even distribution device 1, The flue gas entered with flue entrance 2 is sufficiently mixed, and the NO gas in flue gas can be oxidized to NO by such ozone2, NO2Gas is molten Yu Shui removes NO to enter desulphurization denitration absorber portion IV in the futureXGas does homework.
Flue gas after level-one denitration oxidation panel I oxidation, enters crystallized region II, in crystallized region II, is provided with knot Brilliant slot 3, crystallization spray tube 4 and crystallization flushing pipe 5.The ammonium sulfate and ammonium nitrate that spray tube 4 is crystallized for circulated sprinkling are unsaturated Mixed solution, crystallization tank 3 are used for for temporarily storing ammonium sulfate and ammonium nitrate unsaturation mixed solution, crystallization flushing pipe 5 to this Section is rinsed, and avoids fouling.By the ammonium sulfate and ammonium nitrate unsaturation mixed solution that crystallize the continuous circulated sprinkling of spray tube 4 The heat in high-temperature flue gas is constantly absorbed, after the moisture in solution is constantly evaporated, it is 15- that concentration evaporation, which is improved to solid content, 20%, crystallization tank 3 is used to collect the ammonium sulfate and ammonium nitrate unsaturation mixed solution after concentration, and crystallization flushing pipe 5 is used for pipe Road and tower wall etc. are rinsed, and avoid fouling.
Flue gas after crystallized region cooling, enters second level denitration oxidation panel III, in second level denitration oxidation panel III, is equipped with Ozone even distribution device 6, this oxidation panel can not only be used for the supplement of level-one denitration oxidation panel I, aoxidize and fail in flue gas in level-one denitration The NO gas of oxidation panel I oxidation, achievees the purpose that exhaustive oxidation.Second level denitration oxidation panel III can also conduct in situations The independent denitration oxidation panel of whole system: one is when level-one denitration oxidation panel I is out of order and overhauls, second is that in flue-gas temperature It is excessively high, ozone in the case of a high temperature be easy decompose, and flue gas by crystallized region II cooling after, ozone decompose probability reduce, increase The oxygenation efficiency of NO gas.
Desulphurization denitration absorber portion IV is the core segment of absorption equipment, and absorption tower is obtained because there is the washing absorption function of this section Name, this section are usually disposed with three layers of circulated sprinkling pipe 8, catch tray 7, and the number of plies of circulated sprinkling pipe 8 can be according to the SO2 gas in flue gas Bulk concentration adjustment, catch tray 7 are connect by pipeline with the stock tank near absorption tower, the stock tank further through pipeline and circulating pump with follow Ring spray shower pipe 8 is connected to.The slurries of the continuous circulated sprinkling of circulated sprinkling pipe 8, which wash the sour gas after exhaustive oxidation in flue gas, to be inhaled It receives, achievees the purpose that desulphurization denitration, the slurries after absorbing sour gas are collected into the stock tank of tower side by catch tray 7, then with following Ring pump is beaten to 8 repetitive cycling of circulated sprinkling pipe.
Filler washing section V is located at the top of desulphurization denitration absorber portion IV comprising packing layer 10 and washing spraying layer 11.? During desulfurization, volatile substance in loop slurry, such as the substance meeting that ammonium hydroxide, cigarette ammonium sulfate, ammonium nilrite are unstable Due to high temperature hot fume and volatilize or decompose, these substances cannot be discharged arbitrarily, and material loss can not only be brought to increase, and can also Air is polluted, secondary pollution is caused, the function of filler washing section V is exactly using regular filler and washing sprinkling equipment to flue gas In volatilization and the substance of decomposition washed.
By being also entrained with a large amount of water droplet in the supersaturated flue gas of front four-stage, can be configured by demisting section VI Demister 12 treated that flue gas can be discharged into atmosphere, ridge type demister removal droplet is generallyd use, in order to guarantee demisting The normal use of device 12 reduces system resistance, periodically turns on mist eliminator flushing layer 13 and be rinsed to it.
It, can be in filler washing section V and demisting to realize the recycling to the flushing water of filler washing section V and demisting section VI Section VI arranges catch tray 9, and catch tray 9 is close with 7 setting principle of catch tray, filler is washed layer, the flushing water of demister layer is received It reuses after collection, and is recycled eventually as the supplement water of absorption tower slurries.
The tower wall plate on entire absorption tower is the material production of carbon steel lining glass flake, and the component in tower uses preserving timber Material, the material of crystallized region also need the material using Wear-resistant, high-temperature resistant.
Although the embodiments of the present invention are described in conjunction with attached drawing above, the utility model does not limit to In above-mentioned specific embodiments and applications field, above-mentioned specific embodiment is only schematical, directiveness, without It is restrictive.Those skilled in the art under the enlightenment of this specification, are not departing from the utility model claims In the case where the range protected, a variety of forms can also be made, these belong to the column of the utility model protection.

Claims (10)

1. a kind of desulfurization and denitrification integral absorption tower, which is characterized in that including attraction tower ontology, and be arranged in and attract tower ontology Interior level-one denitration oxidation panel, crystallized region, second level denitration oxidation panel, desulphurization denitration absorber portion, filler washing section, in which: described Level-one denitration oxidation panel is located in the flue entrance for attracting tower body lower part side wall at closely absorption tower tower body, the crystallization section In the bottom of absorption tower ontology, the second level denitration oxidation panel, desulphurization denitration absorber portion and filler washing section are located on crystallized region It is sequentially arranged just and from bottom to top;The desulphurization denitration absorber portion is disposed with circulated sprinkling pipe and below circulated sprinkling pipe First catch tray, first catch tray are connect by pipeline with outer pulp liquor collecting device, and the circulated sprinkling pipe passes through pipe Road and circulating pump are connect with the slurries collection device;Configured with packing layer and above packing layer in the filler washing section Washing spraying layer;The level-one denitration oxidation panel and second level denitration oxidation panel are laid with ozone even distribution device.
2. a kind of desulfurization and denitrification integral absorption tower as described in claim 1, which is characterized in that the ozone even distribution device packet A supervisor and manifold are included, branch pipe uniformly divides on supervisor, and the ozone for being connected with airfoil shape is evenly distributed with sheet metal.
3. a kind of desulfurization and denitrification integral absorption tower as claimed in claim 2, which is characterized in that the material of the sheet metal is Oxidation resistant 316L.
4. a kind of desulfurization and denitrification integral absorption tower as described in claim 1, which is characterized in that be provided in the crystallized region For the crystallization spray tube of circulated sprinkling ammonium sulfate and ammonium nitrate unsaturation mixed solution, be located above crystallization spray tube for pair The crystallization flushing pipe that crystallized region section is rinsed, and and positioned at attract tower body bottom portion be used for collects concentration after ammonium sulfate with The crystallization tank of ammonium nitrate unsaturation mixed solution.
5. a kind of desulfurization and denitrification integral absorption tower as claimed in claim 4, which is characterized in that the crystallization of the crystallized region Slot, crystallization spray tube and crystallization flushing pipe are all made of Wear-resistant, high-temperature resistant material.
6. a kind of desulfurization and denitrification integral absorption tower as described in claim 1, which is characterized in that the desulphurization denitration absorber portion It is disposed at least two layers of circulated sprinkling pipe.
7. a kind of desulfurization and denitrification integral absorption tower as described in claim 1, which is characterized in that further include being arranged in absorption tower The demisting section at top is provided with demister and mist eliminator flushing layer for removing the water droplet in flue gas in demisting section.
8. a kind of desulfurization and denitrification integral absorption tower as claimed in claim 7, which is characterized in that the demister is ridge type Demister.
9. a kind of desulfurization and denitrification integral absorption tower as described in claim 1, which is characterized in that below filler washing section also It is disposed with the second catch tray, second catch tray is connect by pipeline with outer pulp liquor collecting device, the circulated sprinkling pipe It is connect by pipeline and circulating pump with the slurries collection device.
10. a kind of desulfurization and denitrification integral absorption tower as claimed in any one of claims 1 to 9, which is characterized in that the suction Draw tower ontology and be adopted as carbon steel lining glass flake material, tower internals is attracted to be all made of anti-corrosion material.
CN201821707516.XU 2018-10-22 2018-10-22 A kind of desulfurization and denitrification integral absorption tower Expired - Fee Related CN209173690U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110508039A (en) * 2019-08-23 2019-11-29 上海中芬新能源投资有限公司 A kind of absorption tower demisting device flushing water collecting device with primary defrosting function
CN111514736A (en) * 2020-05-29 2020-08-11 广东佳德环保科技有限公司 Flue gas desulfurization and denitrification system and method combining ozone oxidation with ammonia spraying

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110508039A (en) * 2019-08-23 2019-11-29 上海中芬新能源投资有限公司 A kind of absorption tower demisting device flushing water collecting device with primary defrosting function
CN111514736A (en) * 2020-05-29 2020-08-11 广东佳德环保科技有限公司 Flue gas desulfurization and denitrification system and method combining ozone oxidation with ammonia spraying

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Granted publication date: 20190730

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