CN110093024A - Ocean regenerative PET is modified PC/ABS alloy - Google Patents
Ocean regenerative PET is modified PC/ABS alloy Download PDFInfo
- Publication number
- CN110093024A CN110093024A CN201910318784.5A CN201910318784A CN110093024A CN 110093024 A CN110093024 A CN 110093024A CN 201910318784 A CN201910318784 A CN 201910318784A CN 110093024 A CN110093024 A CN 110093024A
- Authority
- CN
- China
- Prior art keywords
- ocean
- weight
- parts
- modified
- regenerative pet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of modified PC/ABS alloys of ocean regenerative PET, including polycarbonate (PC), acrylonitritrile-styrene resin (AS), acrylonitrile-butadiene-styrene copolymer (ABS), toughener, ocean regenerative PET, compatilizer, fire retardant and inorganic filler.The modified PC/ABS alloy of ocean regenerative PET provided by the present invention, with good processing performance, it is a kind of injection grade high polymer alloy, good mechanical performance is had both simultaneously, utilize polymer modification technology, ocean regenerative PET particle is used for PC/ABS, resulting materials can be used for the shell of the products such as electric appliance.
Description
Technical field
The present invention relates to a kind of recovery and reuse technologies of regenerated plastics more particularly to a kind of utilization ocean regenerative PET to change
Property PC/ABS alloy.
Background technique
Plastic garbage Gathering area in ocean is increasing at present, these plastic garbages originate from all over the world, in the work of ocean current
It flocks together under, wherein one nearly 1,700,000 square kilometres of ocean plastic garbage area maximum, ocean is to synthetic resin
Capacity of decomposition is excessively poor.Since 2018, Main Countries began to focus on ocean plastic pollution, and Coca-Cola irrigates
You irrigate automobile, and Hewlett-Packard's electronics is all expressed ocean plastic applications in the wish of oneself Products, and Procter & Gamble is in Malta
Announced in ocean meeting (Our Ocean Conference), be formally proposed can be used for making plastic bottle by it is post-consumer again
Raw plastics and ocean plastics.
PET (polyethylene terephthalate) is a kind of using very extensive high molecular material, and PET product is very at present
All it is mostly one-time consumption product, generates a large amount of waste PET materials, be not easy to cause dirt by air or microbial degradation in the short time
Dye.Therefore, the waste PET material resources to recycling are encouraged, are recycled, for environmental protection, are economized on resources significant.Its
In, ocean regenerative PET is to recycle the PET resin discarded in ocean, and the recycling of ocean regenerative PET has very heavy
The meaning wanted.
Summary of the invention
The present invention provides a kind of modified PC/ABS alloys of ocean regenerative PET.
The modified PC/ABS alloy of ocean regenerative PET of the present invention, including polycarbonate (PC), acrylonitrile-styrene are total
Polymers (AS), acrylonitrile-butadiene-styrene copolymer (ABS), toughener, ocean regenerative PET, compatilizer, fire retardant and nothing
Machine filler.
Preferably, with the total weight of the modified PC/ABS alloy of the ocean regenerative PET, the ocean regenerative PET is modified
PC/ABS alloy includes:
Polycarbonate 60-80 parts by weight,
Acrylonitritrile-styrene resin 1-10 parts by weight,
Acrylonitrile-butadiene-styrene copolymer 5-10 parts by weight,
Toughener 5-10 parts by weight,
Ocean regenerative PET 5-15 parts by weight,
Compatilizer 1-10 parts by weight,
Fire retardant 5-15 parts by weight,
Inorganic filler 10-20 parts by weight.
Preferably, with the total weight of the modified PC/ABS alloy of the ocean regenerative PET, the ocean regenerative PET is modified
PC/ABS alloy includes:
Polycarbonate 60-80 parts by weight, such as 65 parts by weight, 70 parts by weight, 75 parts by weight etc.；
Acrylonitritrile-styrene resin 3-8 parts by weight, such as 5 parts by weight, 7 parts by weight etc.；
Acrylonitrile-butadiene-styrene copolymer 5-8 parts by weight；
Toughener 5-10 parts by weight, such as 6 parts by weight, 7 parts by weight, 8 parts by weight, 9 parts by weight etc.；
Ocean regenerative PET 5-15 parts by weight, such as 6-14 parts by weight, 7-12 parts by weight, 8-10 parts by weight etc.；
Compatilizer 3-8 parts by weight, such as 4 parts by weight, 5 parts by weight, 6 parts by weight, 7 parts by weight etc.；
Fire retardant 6-12 parts by weight, such as 8-11 parts by weight, 9-10 parts by weight etc.；
Inorganic filler 10-20 parts by weight, such as 12-18 parts by weight, 14-17 parts by weight, 15-16 parts by weight.
In an advantageous embodiment, the compatilizer is preferably maleic anhydride grafted ABS, maleic anhydride grafting PE, horse
One or more of maleic anhydride grafted PP.
In a kind of more preferred embodiment, the toughener is preferably esters of acrylic acid toughener, such as methacrylic acid
Methyl esters-butadiene-styrene terpolymer.
In more preferred embodiment, the toughener is preferably the esters of acrylic acid toughener with nucleocapsid structure, more excellent
Selection of land, in the esters of acrylic acid toughener with nucleocapsid structure, acrylic acid, methacrylic acid, acrylate, methyl-prop
The copolymer of one of the olefin(e) acid ester homopolymer of monomer or more monomer is shell.
It is highly preferred that the acrylate or methacrylate are separately preferably methyl esters, ethyl ester, propyl ester, fourth
In ester any one or more.
It is highly preferred that the core is preferably polyacrylate in the esters of acrylic acid toughener with nucleocapsid structure
In (more preferably butyl polyacrylate), polymethacrylates (polybutyl methacrylate), alkylation nano silica
One or more.
In an advantageous embodiment, the modified PC/ABS alloy of the ocean regenerative PET can also include other auxiliary agents, institute
Stating other auxiliary agents can be antioxidant, ultraviolet absorbing agent, fire retardant, antistatic agent, pigment, fungicide, anti-wear agent, lubrication
One of agent, release agent, toughener, reinforcing agent, plasticizer, anti-impact modifier or more.
In an advantageous embodiment, the polycarbonate can be preferably aromatic copolycarbonate.
In an advantageous embodiment, the fire retardant is preferably phosphorus flame retardant, be more selected as phosphate ester flame retardants,
One of phosphorous acid esters fire resistant agent, Organophosphonate based flame retardant or more.
In an advantageous embodiment, the inorganic filler, also referred to as inorganic filler can be carbon black, talcum powder, oxygen
Change aluminium powder, calcium carbonate, silica flour, mica powder, flake asbestos, diamond dust, glass powder, glass fibre, carbon fiber, clay, calcium silicates,
One of white carbon black or more.
In an advantageous embodiment, polycarbonate viscosity-average molecular weight is 15000-40000.
In an advantageous embodiment, acrylonitritrile-styrene resin position injection grade.
In an advantageous embodiment, in acrylonitrile-butadiene-styrene copolymer, butadiene unit molar percentage
At least 50%, preferably position 50-70%, more preferably 50-60%, more preferably 55-60%.
The modified PC/ABS alloy of ocean regenerative PET provided by the present invention, using commercially available ocean regenerative PET, by specific
Component is matched, and is had good processing performance, is a kind of injection grade high polymer alloy, while having both good mechanicalness
Can, using polymer modification technology, ocean regenerative PET particle is used for PC/ABS, resulting materials can be used for the products such as electric appliance
Shell.
Specific embodiment
Embodiment 1
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 60kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 5kg；
Acrylonitrile-butadiene-styrene copolymer 5kg；Butadiene unit molar percentage 55%；
Esters of acrylic acid toughener 5kg；
Ocean regenerative PET particle 8kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 5kg；
Pearl filler 15kg；
Phosphate flame retardant 6kg.
Embodiment 2
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 70kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 5kg；
Acrylonitrile-butadiene-styrene copolymer 8kg；Butadiene unit molar percentage 50%；
Esters of acrylic acid toughener 6kg；
Ocean regenerative PET particle 10kg,
Maleic anhydride grafted ABS compatilizer 4kg, it is commercially available；
Pearl filler 15kg；
Phosphate flame retardant 8kg.
Embodiment 3
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 65kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 8kg；
Acrylonitrile-butadiene-styrene copolymer 8kg；Butadiene unit molar percentage 65%；
Esters of acrylic acid toughener 10kg；
Ocean regenerative PET particle 15kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 6kg；
Pearl filler 15kg；
Phosphate flame retardant 10kg.
Embodiment 4
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 80kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 8kg；
Acrylonitrile-butadiene-styrene copolymer 6kg；Butadiene unit molar percentage 60%；
Esters of acrylic acid toughener 10kg；
Ocean regenerative PET particle 15kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 8kg；
Pearl filler 15kg；
Phosphate flame retardant 12kg.
Embodiment 5
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 60kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 3kg；
Acrylonitrile-butadiene-styrene copolymer 3kg；Butadiene unit molar percentage 55%；
Esters of acrylic acid toughener 5kg；
Ocean regenerative PET particle 8kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 5kg；
Pearl filler 15kg；
Phosphate flame retardant 6kg.
Embodiment 6
In the present embodiment, regenerative PET modified PC/ABS alloy composite weight proportion in ocean is as follows:
Polycarbonate 75kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 8kg；
Acrylonitrile-butadiene-styrene copolymer 4kg；Butadiene unit molar percentage 55%；
Esters of acrylic acid toughener 5kg；
Ocean regenerative PET particle 5kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 5kg；
Pearl filler 15kg；
Phosphate flame retardant 12kg.
Comparative example 1
In this comparative example, PC/ABS alloy composite weight proportion is as follows:
Polycarbonate 80kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitrile-butadiene-styrene copolymer 6kg；Butadiene unit molar percentage 55%；
Esters of acrylic acid toughener 10kg；
Ocean regenerative PET particle 15kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 8kg；
Pearl filler 15kg；
Phosphate flame retardant 12kg.
Comparative example 2
In this comparative example, PC/ABS alloy composite weight proportion is as follows:
Polycarbonate 80kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 8kg；
Acrylonitrile-butadiene-styrene copolymer 6kg；Butadiene unit molar percentage 55%；
EP rubbers toughener 10kg；
Ocean regenerative PET particle 15kg, it is commercially available；
Maleic anhydride grafted ABS compatilizer 8kg；
Pearl filler 15kg；
Phosphate flame retardant 12kg.
Comparative example 3
In this comparative example, ABS alloy composition weight proportion is as follows:
Polycarbonate 80kg；Viscosity-average molecular weight is 20000-21000；
Acrylonitritrile-styrene resin 8kg；
Acrylonitrile-butadiene-styrene copolymer 6kg；Butadiene unit molar percentage 55%；
Esters of acrylic acid toughener 10kg；
New synthesis PET particle 15kg,
Maleic anhydride grafted ABS compatilizer 8kg；
Pearl filler 15kg；
Phosphate flame retardant 12kg.
The above embodiments of the present application and comparative example A BS alloy, 80-90 DEG C drying 4 hours, squeeze out injection molding, technique is joined
Number is as follows: screw speed 40-75rpm, 230-255 DEG C of temperature of extruder rear end (close to feed opening one end, compression section), intermediate temperature
240-265 DEG C of degree, 250-275 DEG C of temperature of front end (close to extrusion one end, extruding zone), 250-275 DEG C of nozzle temperature, forming temperature
Spend 60-80 DEG C of (mold temperature), back pressure (back pressure) 0.3-0.7MPa.Products obtained therefrom performance detection knot
See Table 1 for details and table 2 for fruit.Detection method:
Density: ASTM D792
Melt index: ASTM D1238, condition: 260 DEG C, 2.16kg
Elongation at break, tensile strength: ASTM D638
Bending modulus, bending strength: ASTM D790
Impact strength: ASTM D256,23 DEG C of condition, 0.125in
Temperature of deflection under load (DTUL@264psi-unannealed): ASTM D648, condition 0.125in
Mold shrinkage: ASTM D955
Resistance to combustion grade: UL94
ABS alloy performance test results in table 1, embodiment 1-6 and comparative example 1-2
ABS alloy performance test results in table 2, embodiment 1-6 and comparative example 1-2
Embodiment 1-6 is with comparative example 3 as can be seen that the application ocean regenerative PET particle can be real in comparison Tables 1 and 2
Now modified effect similar with new synthesis PET.Comparing embodiment 1-6 and comparative example 1,2 in Tables 1 and 2 can be seen that the application
Using the combination of esters of acrylic acid toughener, acrylonitritrile-styrene resin and ocean regenerative PET, ABS can be preferably improved
Processing performance and mechanical performance.
Specific embodiments of the present invention are described in detail above, but it is merely an example, the present invention is simultaneously unlimited
It is formed on particular embodiments described above.To those skilled in the art, any couple of present invention carries out equivalent modifications and
Substitution is also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention made by equal transformation and
Modification, all should be contained within the scope of the invention.
Claims (10)
1. a kind of modified PC/ABS alloy of ocean regenerative PET, which is characterized in that including polycarbonate, acrylonitrile-styrene copolymerized
Object, acrylonitrile-butadiene-styrene copolymer, toughener, ocean regenerative PET, compatilizer, fire retardant and inorganic filler.
2. the modified PC/ABS alloy of ocean regenerative PET according to claim 1, which is characterized in that with ocean regeneration
The total weight of the modified PC/ABS alloy of PET, the modified PC/ABS alloy of the ocean regenerative PET include:
Polycarbonate 60-80 parts by weight,
Acrylonitritrile-styrene resin 1-10 parts by weight,
Acrylonitrile-butadiene-styrene copolymer 5-10 parts by weight,
Toughener 5-10 parts by weight,
Ocean regenerative PET 5-15 parts by weight,
Compatilizer 1-10 parts by weight,
Fire retardant 5-15 parts by weight,
Inorganic filler 10-20 parts by weight.
3. the modified PC/ABS alloy of ocean regenerative PET according to claim 2, which is characterized in that with ocean regeneration
The total weight of the modified PC/ABS alloy of PET, the modified PC/ABS alloy of the ocean regenerative PET include:
Polycarbonate 60-80 parts by weight；
Acrylonitritrile-styrene resin 3-8 parts by weight；
Acrylonitrile-butadiene-styrene copolymer 5-8 parts by weight；
Toughener 5-10 parts by weight；
Ocean regenerative PET 5-15 parts by weight；
Compatilizer 3-8 parts by weight；
Fire retardant 6-12 parts by weight；
Inorganic filler 10-20 parts by weight.
4. the modified PC/ABS alloy of ocean regenerative PET according to claim 1, which is characterized in that the compatilizer is horse
One or more of maleic anhydride grafted ABS, maleic anhydride grafting PE, maleic anhydride graft PP.
5. the modified PC/ABS alloy of ocean regenerative PET according to claim 1, which is characterized in that the toughener is third
Olefin(e) acid esters toughener.
6. the modified PC/ABS alloy of ocean regenerative PET according to claim 5, which is characterized in that the toughener is tool
There is the esters of acrylic acid toughener of nucleocapsid structure.
7. the modified PC/ABS alloy of ocean regenerative PET according to claim 6, which is characterized in that described that there is core-shell structure copolymer knot
In the esters of acrylic acid toughener of structure, one of acrylic acid, methacrylic acid, acrylate, methacrylate monomer
The copolymer of homopolymer or more monomer is shell.
8. the modified PC/ABS alloy of ocean regenerative PET according to claim 6, which is characterized in that described that there is core-shell structure copolymer knot
In the esters of acrylic acid toughener of structure, the core is polyacrylate, polymethacrylates, is alkylated in nano silica
One or more.
9. the modified PC/ABS alloy of ocean regenerative PET according to claim 1, which is characterized in that the fire retardant is phosphorus
Flame retardant.
10. the modified PC/ABS alloy of ocean regenerative PET according to claim 1, which is characterized in that the inorganic filler is
Carbon black, talcum powder, alumina powder, calcium carbonate, silica flour, mica powder, flake asbestos, diamond dust, glass powder, glass fibre, carbon fiber
One of dimension, clay, calcium silicates, white carbon black or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910318784.5A CN110093024A (en) | 2019-04-19 | 2019-04-19 | Ocean regenerative PET is modified PC/ABS alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910318784.5A CN110093024A (en) | 2019-04-19 | 2019-04-19 | Ocean regenerative PET is modified PC/ABS alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110093024A true CN110093024A (en) | 2019-08-06 |
Family
ID=67445327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910318784.5A Pending CN110093024A (en) | 2019-04-19 | 2019-04-19 | Ocean regenerative PET is modified PC/ABS alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110093024A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343378A (en) * | 2019-07-10 | 2019-10-18 | 东莞市国亨塑胶科技有限公司 | A kind of high flowing environment-friendlyflame-retardant flame-retardant material and preparation method thereof prepared by regenerated resources |
| CN112266537A (en) * | 2020-11-10 | 2021-01-26 | 山东星达新材料有限公司 | Marine recycled PP/PET alloy |
| CN115491014A (en) * | 2022-09-29 | 2022-12-20 | 丁长松 | Modified PC plastic and preparation process thereof |
| CN115895225A (en) * | 2022-11-17 | 2023-04-04 | 东莞市宇捷实业投资有限公司 | Environment-friendly regenerated PET modified PC/ABS alloy and preparation method thereof |
| CN115895173A (en) * | 2022-11-29 | 2023-04-04 | 东莞市宇捷实业投资有限公司 | Ocean recycled plastic modified ABS alloy and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101173089A (en) * | 2006-10-31 | 2008-05-07 | 佛山市顺德区汉达精密电子科技有限公司 | Modified PC/ABS alloy |
| CN101508833A (en) * | 2008-11-28 | 2009-08-19 | 上海锦湖日丽塑料有限公司 | Chemically-resistant excellent PC//ABS alloy |
| CN103467960A (en) * | 2013-09-05 | 2013-12-25 | 上海迅扬塑料有限公司 | Environment-friendly and flame retardant PC (polycarbonate)/ABS (acrylonitrile-butadiene-styrene) modified engineering plastic |
| CN103540105A (en) * | 2012-07-10 | 2014-01-29 | 晋德塑料科技(东莞)有限公司 | Composition of polycarbonate, polyethylene terephthalate and acrylonitrile-butadiene-styrene and preparation method thereof |
| CN104559115A (en) * | 2014-12-31 | 2015-04-29 | 上海锦湖日丽塑料有限公司 | PC/PET halogen-free flame retarding alloy containing regenerative resin, and preparation method of PC/PET halogen-free flame retarding alloy |
| CN106543659A (en) * | 2016-11-25 | 2017-03-29 | 广东国立科技股份有限公司 | A kind of recycled plastic granules and its preparation method |
| CN107118534A (en) * | 2017-06-13 | 2017-09-01 | 上海长伟锦磁工程塑料有限公司 | Excellent PC/ABS alloys of a kind of cracking performance of resistance to automotive paints and preparation method thereof |
| CN108291082A (en) * | 2016-01-26 | 2018-07-17 | Umg Abs株式会社 | Enhance thermoplastic resin composition and its molded product |
-
2019
- 2019-04-19 CN CN201910318784.5A patent/CN110093024A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101173089A (en) * | 2006-10-31 | 2008-05-07 | 佛山市顺德区汉达精密电子科技有限公司 | Modified PC/ABS alloy |
| CN101508833A (en) * | 2008-11-28 | 2009-08-19 | 上海锦湖日丽塑料有限公司 | Chemically-resistant excellent PC//ABS alloy |
| CN103540105A (en) * | 2012-07-10 | 2014-01-29 | 晋德塑料科技(东莞)有限公司 | Composition of polycarbonate, polyethylene terephthalate and acrylonitrile-butadiene-styrene and preparation method thereof |
| CN103467960A (en) * | 2013-09-05 | 2013-12-25 | 上海迅扬塑料有限公司 | Environment-friendly and flame retardant PC (polycarbonate)/ABS (acrylonitrile-butadiene-styrene) modified engineering plastic |
| CN104559115A (en) * | 2014-12-31 | 2015-04-29 | 上海锦湖日丽塑料有限公司 | PC/PET halogen-free flame retarding alloy containing regenerative resin, and preparation method of PC/PET halogen-free flame retarding alloy |
| CN108291082A (en) * | 2016-01-26 | 2018-07-17 | Umg Abs株式会社 | Enhance thermoplastic resin composition and its molded product |
| CN106543659A (en) * | 2016-11-25 | 2017-03-29 | 广东国立科技股份有限公司 | A kind of recycled plastic granules and its preparation method |
| CN107118534A (en) * | 2017-06-13 | 2017-09-01 | 上海长伟锦磁工程塑料有限公司 | Excellent PC/ABS alloys of a kind of cracking performance of resistance to automotive paints and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王国全: "《十三五"普通高等学校教育本科规划教材 高分子材料与工程专业系列教材 聚合物改性》", 31 May 2016 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343378A (en) * | 2019-07-10 | 2019-10-18 | 东莞市国亨塑胶科技有限公司 | A kind of high flowing environment-friendlyflame-retardant flame-retardant material and preparation method thereof prepared by regenerated resources |
| CN110343378B (en) * | 2019-07-10 | 2021-04-20 | 东莞市国亨塑胶科技有限公司 | High-fluidity environment-friendly flame-retardant material prepared from renewable resources and preparation method thereof |
| CN112266537A (en) * | 2020-11-10 | 2021-01-26 | 山东星达新材料有限公司 | Marine recycled PP/PET alloy |
| CN115491014A (en) * | 2022-09-29 | 2022-12-20 | 丁长松 | Modified PC plastic and preparation process thereof |
| CN115491014B (en) * | 2022-09-29 | 2023-12-26 | 万星塑胶制品（上海）有限公司 | Modified PC plastic and preparation process thereof |
| CN115895225A (en) * | 2022-11-17 | 2023-04-04 | 东莞市宇捷实业投资有限公司 | Environment-friendly regenerated PET modified PC/ABS alloy and preparation method thereof |
| CN115895173A (en) * | 2022-11-29 | 2023-04-04 | 东莞市宇捷实业投资有限公司 | Ocean recycled plastic modified ABS alloy and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110093024A (en) | Ocean regenerative PET is modified PC/ABS alloy | |
| US5484835A (en) | Heat-resistant, propylene resin-based molding materials and molded products obtained therefrom | |
| CN106543659A (en) | A kind of recycled plastic granules and its preparation method | |
| CN103589058A (en) | Reinforced polypropylene composite material and preparation method thereof | |
| Várdai et al. | Impact modification of PP/wood composites: A new approach using hybrid fibers | |
| CN102850659A (en) | Thermoplastic resin composite material for mine safety helmet | |
| CN101250303A (en) | Mineral/whisker reinforced polypropylene composite material having good spraying property | |
| CN101003675A (en) | High flexible flame retardant PC(polycarbonate)/ABS alloy | |
| KR20110058124A (en) | Environment friendly resin composition for hollow molding product and hollow molding product using the same | |
| CN100528961C (en) | High flexible flame retardant PC(polycarbonate)/ABS alloy | |
| KR101000658B1 (en) | Recycling polyethyleneterephthalate composite and manufacturing method of thereof | |
| CN104558818B (en) | Polypropene composition of dimensionally stable and preparation method thereof | |
| CN105219050A (en) | Low cost mineral strengthen halogen-free flame retardant PC/ABS material and preparation method thereof | |
| CN102770489B (en) | Resin composition for irregular shape extrusion molding and irregularly shaped extrusion molded resin article | |
| CN103589060A (en) | Glass fiber reinforced polypropylene/polystyrene alloy composite material and its preparation and application thereof | |
| CN101024720B (en) | PC/ABB alloy modified from PC (polycarbonate) substandard material | |
| CN110157131A (en) | Ocean regenerated plastics modified ABS alloy | |
| CN100528962C (en) | High flexible flame retardant PC(polycarbonate)/ABS alloy | |
| CN102532691A (en) | Mica modified polypropylene composite material | |
| CN104861283A (en) | Impact-resistant modified plastic hollow plate and preparation method thereof | |
| KR100949377B1 (en) | Polyactic acid composition | |
| CN103951874A (en) | Super-strength and super-toughness polypropylene modified resin and its preparation technology | |
| CN1208386C (en) | Specific meterial for modified polypropylene TV housing and production method thereof | |
| JPH11166054A (en) | Recycled resin composition and molding method thereof | |
| CA2001726A1 (en) | Nucleating systems |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190806 |
|
| RJ01 | Rejection of invention patent application after publication |