CN1100833C - Black dye for granite and marble - Google Patents
Black dye for granite and marble Download PDFInfo
- Publication number
- CN1100833C CN1100833C CN00111211A CN00111211A CN1100833C CN 1100833 C CN1100833 C CN 1100833C CN 00111211 A CN00111211 A CN 00111211A CN 00111211 A CN00111211 A CN 00111211A CN 1100833 C CN1100833 C CN 1100833C
- Authority
- CN
- China
- Prior art keywords
- marble
- granite
- black dye
- hydrochloric acid
- aniline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004579 marble Substances 0.000 title claims abstract description 18
- 239000010438 granite Substances 0.000 title claims abstract description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 34
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 12
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 15
- 239000004575 stone Substances 0.000 abstract description 12
- 238000004043 dyeing Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 3
- 238000007605 air drying Methods 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 239000009261 D 400 Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Coloring (AREA)
Abstract
The present invention provides a black dye for granite and marble, which comprises the raw materials and the weight percents of 5 to 20% of p-phenylene diamine, 10 to 20% of aniline, 5 to 20% of sodium chloride, 25 to 40% of hydrochloric acid and 10 to 30% of water. Compared with the prior art, the black dye for granite and marble has the characteristics of reasonable technological design, universal chemical products as raw materials, convenient operation and use, no environmental pollution, uniform stone dyeing, high durability and no fading, etc. and can widen and increase the use range and the use value of stone. The black dye for granite and marble has favorable popularization and use values.
Description
The present invention relates to a kind of tinting material of material of construction, specifically a kind of black dye for granite and marble.
Natural marble, granite in the building materials market except processing quality, only the color relation that it had divides a lot of grades, such as first-class be red or (green grass or young crops) black, other color is taken second place, some famous marble granite producer is red according to the place of production of stone material and its distinctive color and luster Mount Taishan of having given a name, Jinan green grass or young crops or the like, though some stone material is of good quality, processing quality becomes on also, so but on the building materials market, do not sell good price because of its color is assorted, people play the purpose of mixing the spurious with the genuine for the class that improves the granitic class of marble especially improve stone material on color often adopts in the stone surface method of colouring, to satisfy the needs of building materials market.The existing in actual applications deficiency of the marble granite coloring technology of prior art or illuminating colour is: cost height, dyeing complexity, dyeing are inhomogeneous, the easy regression of color etc.
The purpose of this invention is to provide the black dye for granite and marble that a kind of use cost is low, manufacture craft simple, the color strong adhesion does not fade, do not fade in various environment environment uses.
The objective of the invention is to realize in the following manner, Ursol D, aniline, sodium-chlor, hydrochloric acid and water are that raw material mixes and makes staining agent, during use staining agent sprayed to the granitic surface of marble, staining agent just may penetrate among the lattice of stone material, can make stone surface have the granitic color and luster of natural black marble, to reach the effect of mixing the spurious with the genuine.
Black dye for granite and marble of the present invention, raw material comprise Ursol D, aniline, sodium-chlor, hydrochloric acid and water, and the weight percent of various raw materials is Ursol D 5-20%, aniline 10-20%, sodium-chlor 5-20%, hydrochloric acid 25-40%, water 10-30%, the concentration of hydrochloric acid is 30%.
The preferred weight percent of various raw materials is Ursol D 8-15%, aniline 12-18%, sodium-chlor 8-18%, hydrochloric acid 30-35%, water 20-25%.
The optimum weight per-cent of various raw materials is Ursol D 10%, aniline 15%, sodium-chlor 15%, hydrochloric acid 35%, water 25%.
Embodiment:
Prescription one,
Take by weighing Ursol D 400 grams, aniline 600 grams, sodium-chlor 600 grams, hydrochloric acid 1400 grams, water 1000 grams.
It is to dissolve in 33% the hydrochloric acid that phenylenediamine, aniline and sodium-chlor are joined concentration, add water then and stir and both can spray or brush, spraying or brush and both be finished product after well natural air drying was rinsed excess dyestuff with clear water after 4-12 hour in the back stone surface.
Prescription two,
Take by weighing Ursol D 400 grams, aniline 550 grams, sodium-chlor 650 grams, hydrochloric acid 1500 grams, water 1100 grams.
It is to dissolve in 33% the hydrochloric acid that phenylenediamine, aniline and sodium-chlor are joined concentration, add water then and stir and both can spray or brush, spraying or brush and both be finished product after well natural air drying was rinsed excess dyestuff with clear water after 4-12 hour in the back stone surface.
Prescription three,
Take by weighing Ursol D 450 grams, aniline 550 grams, sodium-chlor 600 grams, hydrochloric acid 1500 grams, water 900 grams.
It is to dissolve in 33% the hydrochloric acid that phenylenediamine, aniline and sodium-chlor are joined concentration, add water then and stir and both can spray or brush, spraying or brush and both be finished product after well natural air drying was rinsed excess dyestuff with clear water after 4-12 hour in the back stone surface.
Waste water after the flushing is reused because of containing the recyclable back of a spot of staining agent.
Black dye for granite and marble of the present invention is compared with existing technology, and has technological design and closes Reason, raw material are that generalization chemical product, easy for operation, environmentally safe and dyeing stone are even , durable, the characteristics such as fade that do not fade, thereby, have good value for applications.
Claims (3)
1. black dye for granite and marble, raw material comprises Ursol D, aniline, sodium-chlor, hydrochloric acid and water, the weight percent that it is characterized in that raw material is Ursol D 5-20%, aniline 10-20%, sodium-chlor 5-20%, hydrochloric acid 25-40%, water 10-30%.
2. black dye for granite and marble according to claim 1, the weight percent that it is characterized in that raw material is Ursol D 8-15%, aniline 12-18%, sodium-chlor 8-18%, hydrochloric acid 30-35%, water 20-25%.
3. black dye for granite and marble according to claim 1, the weight percent that it is characterized in that raw material is a Ursol D 10%, aniline 15%, sodium-chlor 15%, hydrochloric acid 35%, water 25%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00111211A CN1100833C (en) | 2000-07-14 | 2000-07-14 | Black dye for granite and marble |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00111211A CN1100833C (en) | 2000-07-14 | 2000-07-14 | Black dye for granite and marble |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1334294A CN1334294A (en) | 2002-02-06 |
| CN1100833C true CN1100833C (en) | 2003-02-05 |
Family
ID=4581142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN00111211A Expired - Fee Related CN1100833C (en) | 2000-07-14 | 2000-07-14 | Black dye for granite and marble |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1100833C (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088597A (en) * | 1992-12-07 | 1994-06-29 | Basf公司 | Comprise the dye mixture that has from the azoic dyestuff of the coupling component of diamino-pyridine series |
-
2000
- 2000-07-14 CN CN00111211A patent/CN1100833C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088597A (en) * | 1992-12-07 | 1994-06-29 | Basf公司 | Comprise the dye mixture that has from the azoic dyestuff of the coupling component of diamino-pyridine series |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1334294A (en) | 2002-02-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhang Yanzhao Inventor after: Zhang Zengmeng Inventor after: Zhang Lei Inventor before: Zhang Yanzhao Inventor before: Xiu Aitian Inventor before: Zhang Lei |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: ZHANG YANZHAO; XIU TIANAI; ZHANG LEI TO: ZHANG YANZHAO; ZHANG ZENGMENG; ZHANG LEI |
|
| ASS | Succession or assignment of patent right |
Owner name: ZHANG ZENGBO Free format text: FORMER OWNER: ZHANG YANZHAO Effective date: 20060113 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20060113 Address after: 271000 No. 24, Wenhua Road, Taishan District, Shandong, Tai'an Patentee after: Zhang Zengbo Address before: 250100 Shandong province Huashan Zhen Meng home source granite factory Patentee before: Zhang Yanzhao |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20030205 Termination date: 20090814 |