CN85104114A - Pigment printing assistant - Google Patents

Pigment printing assistant Download PDF

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Publication number
CN85104114A
CN85104114A CN 85104114 CN85104114A CN85104114A CN 85104114 A CN85104114 A CN 85104114A CN 85104114 CN85104114 CN 85104114 CN 85104114 A CN85104114 A CN 85104114A CN 85104114 A CN85104114 A CN 85104114A
Authority
CN
China
Prior art keywords
rare earth
earth element
add
printing
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN 85104114
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Chinese (zh)
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CN85104114B (en
Inventor
徐文娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Inst Of Chemical Industry
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Ningbo Inst Of Chemical Industry
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Publication date
Application filed by Ningbo Inst Of Chemical Industry filed Critical Ningbo Inst Of Chemical Industry
Priority to CN85104114A priority Critical patent/CN85104114B/en
Publication of CN85104114A publication Critical patent/CN85104114A/en
Publication of CN85104114B publication Critical patent/CN85104114B/en
Expired legal-status Critical Current

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Abstract

Pigment printing assistant is to be applied in the fiber product coating printing process, constitute the main component of mill base together with coating, wherein, the adding of rare earth element not only can guarantee the print durability of fibre, and significantly reduces tinctorial yield and vividness that the kerosene consumption significantly improves fibre.Their synthetic and use can promote the complete COAT PRINTING technology of chromatogram to develop rapidly, can reduce energy resource consumption and environmental pollution, also uses in light and textile industries for rare earth element and has opened up a frontier.

Description

Pigment printing assistant
The present invention relates to the COAT PRINTING auxiliary agent that contains rare earth element used in the fiber product coating printing process.
Advantages such as fiber product coating printing process is compared with other printing technology, and it is simple that it has technological process, does not need post processing, and energy resource consumption is few, pollutes and lacks, and chromatogram is complete are so generally all extensively adopt and greatly develop COAT PRINTING technology in recent years.
The COAT PRINTING technological requirement obtains higher stamp vividness and tinctorial yield.Used mill base Main Ingredients and Appearance is coating and COAT PRINTING auxiliary agent in the COAT PRINTING technology, and wherein the COAT PRINTING auxiliary agent comprises adhesive, intensifier, A group slurry, crosslinking agent etc.A group slurry Main Ingredients and Appearance is a kerosene.30%~40% of mill base total amount, kerosene.Kerosene is a kind of energy that is becoming tight day, and a large amount of kerosene that use can serious environment pollution in COAT PRINTING technology.Generally speaking, behind the minimizing kerosene consumption, fibre stamp vividness and tinctorial yield all can significantly reduce.In the production technology, just lack the thickness of mainly regulating mill base with A group slurry in order to reduce the kerosene consumption, but the vividness of fibre and tinctorial yield all do not reach requirement at present with intensifier and water as far as possible.
The objective of the invention is in fiber product coating printing process, to provide pigment printing assistant, reach vividness and the tinctorial yield that improves stamp simultaneously so that reduce the kerosene consumption.
The present invention the invention is characterized in also to comprise rare earth material in the COAT PRINTING auxiliary agent for the used COAT PRINTING auxiliary agent of a kind of fiber product coating printing process comprises adhesive, crosslinking agent, intensifier and A group slurry etc.
Below in conjunction with embodiment the present invention is described in further detail:
Rare earth element can not only add when the synthetic paint printing assistant, also can add when the modulation mill base.The rare earth element that adds can be simple substance elements such as lanthanum, neodymium, cerium and praseodymium, or their mishmetal, also their oxide, or their chloride, also its mixture.The total addition level of rare earth element is 0.01~5%.
In the adhesive in the rare earth element adding COAT PRINTING auxiliary agent, the adhesive proportion that is synthesized is by weight: chitin 2.2~2.7%; Glacial acetic acid 1.0~2.0%, peregal 1%, extraordinary kerosene 3~15%, butadiene-styrene latex 40~43%, mishmetal 0.1~1%, water are surplus.It is at first water, rare earth element, glacial acetic acid, chitin at normal temperatures, fully after the stirring, adds peregal in basic dissolving back, under high-speed stirred, slowly adds kerosene then, and under agitation at last, the adding butadiene-styrene latex mixes.
Rare earth element adds in the crosslinking agent in the COAT PRINTING auxiliary agent, and the crosslinking agent that is synthesized is 0.1~1%(weight ratio) mishmetal and the mixture that mixes of 2 molar epoxychloropropane and 1 molar hexamethylene diamine.
Rare earth element can also add intensifier or add A group slurry or two or more auxiliary agent in, add simultaneously, as long as the total amount of rare earth element reaches necessarily, just can play and answer role.
Pigment printing assistant is owing to added rare earth element, and their stability improves greatly, uses them, can starch with A group less, and then can reduce the kerosene consumption significantly.The fiber product coating print durability be can guarantee again and vividness and tinctorial yield improved effectively.
Below be pigment printing assistant use-case and effect:
Example 1: use in the artificial cotton sample to add adhesive 400 grams that are mixed with rare earth, add the mill base that 100 gram coating blue ffgs, 30 gram EH crosslinking agents and a small amount of A group slurry are modulated into again, dry through stamp, surveying its brushing fastness after 5 minutes through decatize again compares the result with its like product and has protected fastness, improved vividness and tinctorial yield, can reduce by 75% kerosene consumption this moment.
Example 2: the adhesive that in the pure cotton napped fabric sample, uses the present invention to synthesize, adopt the mill base identical with example 1, the result has guaranteed fastness, and has provided vivid color and high tinctorial yield.
Example 3: in the artificial cotton sample, use the above-mentioned adhesive of 400 grams, add 150 gram coating blue ffgs again, 30 gram EH crosslinking agents, 100 gram citric acids, 100 gram glue and a small amount of A group slurry, through the stamp oven dry, oven dry after colour developing and cold and hot washing again, fastness surpasses like product as a result, has also improved vividness and tinctorial yield.
Example 4: after adhesive that the present invention is synthesized and like product adhesive were placed a week respectively, the result showed and contains the rare earth adhesive good stability.
Example 5: the adhesive modulation mill base that synthesizes with the present invention carries out table with test results on colour photometer after the colour developing of fibre stamp bright: compared with similar products, tinctorial yield increases to some extent and has provided high vividness, and can reduce by 50~80% kerosene consumption.
Below description in conjunction with the embodiments is to the invention provides disclosed detailed content, its objective is for the present invention rather than restriction the present invention are described, the personnel that do some training very often for the technology of the present invention field can make various changes and improvements to the present invention, and short of disengaging inner characteristic of the present invention all should belong within the claim scope of the present invention.

Claims (5)

1, the used COAT PRINTING auxiliary agent of a kind of fiber product coating printing process comprises adhesive, crosslinking agent, intensifier and A group slurry.The invention is characterized in and also comprised rare earth material in the COAT PRINTING auxiliary agent.
2, as claimed in claim 1, it is characterized in that said rare earth material is a rare earth element, or their mixture, or the oxide of rare earth element, or the chloride of rare earth element, or their mixture.Its addition is 0.01~5%(weight ratio).
3, according to claim 1, it is characterized in that rare earth material can not only add when the synthetic paint printing assistant, also can when the modulation mill base, add.
4, according to claim 1,3 described, it is characterized in that rare earth element adds in the adhesive, above-mentioned adhesive proportion is: chitin 2.2~2.7% by weight; Glacial acetic acid 1~2%; Peregal 1%; Extraordinary kerosene 3~15%; Butadiene-styrene latex 40~43%; Rare earth element 0.1~1%; All the other are water.
5, as described in the claim 1,3, it is characterized in that rare earth element adds in the crosslinking agent, its proportioning is: 2 gram molecule epoxychloropropane and 1 gram molecule hexamethylene diamine, and add 0.1~1%(weight ratio) rare earth element mix.
CN85104114A 1985-05-25 1985-05-25 Novel pigment printing auxiliary agent Expired CN85104114B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN85104114A CN85104114B (en) 1985-05-25 1985-05-25 Novel pigment printing auxiliary agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN85104114A CN85104114B (en) 1985-05-25 1985-05-25 Novel pigment printing auxiliary agent

Publications (2)

Publication Number Publication Date
CN85104114A true CN85104114A (en) 1986-02-10
CN85104114B CN85104114B (en) 1988-03-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN85104114A Expired CN85104114B (en) 1985-05-25 1985-05-25 Novel pigment printing auxiliary agent

Country Status (1)

Country Link
CN (1) CN85104114B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102864653A (en) * 2012-08-30 2013-01-09 无锡新德印染制品有限公司 Color paste for direct printing of cotton cloths and paste mixing method
CN107869072A (en) * 2017-12-15 2018-04-03 苏州润弘贸易有限公司 Antistatic printing assistant

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102864653A (en) * 2012-08-30 2013-01-09 无锡新德印染制品有限公司 Color paste for direct printing of cotton cloths and paste mixing method
CN107869072A (en) * 2017-12-15 2018-04-03 苏州润弘贸易有限公司 Antistatic printing assistant

Also Published As

Publication number Publication date
CN85104114B (en) 1988-03-23

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