CN110078984A - A kind of latex containing graphene zinc oxide composites - Google Patents
A kind of latex containing graphene zinc oxide composites Download PDFInfo
- Publication number
- CN110078984A CN110078984A CN201910473614.4A CN201910473614A CN110078984A CN 110078984 A CN110078984 A CN 110078984A CN 201910473614 A CN201910473614 A CN 201910473614A CN 110078984 A CN110078984 A CN 110078984A
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- zinc oxide
- oxide composites
- graphene zinc
- latex
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of latexes containing graphene zinc oxide composites, are made of following components and parts by weight: 100 parts of natural emulsion, 0.2-0.5 parts of graphene zinc oxide composites, 0.2-1 parts of stabilizer, 0.8-2 parts of anti-aging agent, 1-5 parts of vulcanizing agent, 0.2-1 parts of dispersing agent, 0.2-1 parts of promotor.Graphene zinc oxide composites of the invention are uniformly dispersed in latex, can improve the mechanical property of latex product, improve durability and durability, enhance toughness and anti-virus performance, and have the effect of antibacterial bacteriostatic.
Description
Technical field
The present invention relates to the technical field of latex, especially a kind of latex containing graphene zinc oxide composites.
Background technique
Latex refers to polymer particles and is dispersed in water the colloid emulsion to be formed.Claim cream by product made of raw material of latex
Glue product, common such as sponge, gloves, toy, sebific duct.
Latex product is all widely used in agricultural, industry, medical treatment, military project style and daily life, with society
Be constantly progressive, the demand of latex product is gradually increased, also the quality of latex product and safety also proposed higher
Requirement.
Common latex product is easy can be poor by air oxidation durability and durability, and spoilage is high, while latex product
It is often in contact with the skin of human body, latex product here is only simple to have the function of barrier, itself can not be to disease
Bacterium and bacterium have an impact, so existing latex product does not adapt to the increasingly developed step of modern society.
Summary of the invention
The technical problem to be solved by the present invention is it is of the existing technology in above-mentioned background technique in order to solve the problems, such as,
A kind of improved latex containing graphene zinc oxide composites is provided.
The technical solution adopted by the present invention to solve the technical problems is: a kind of cream containing graphene zinc oxide composites
Glue is made of following components and parts by weight: 100 parts of natural emulsion, 0.2-0.5 parts of graphene zinc oxide composites, stabilizer
0.2-1 parts, 0.8-2 parts of anti-aging agent, 1-5 parts of vulcanizing agent, 0.2-1 parts of dispersing agent, 0.2-1 parts of promotor.
The antioxidant DBH: 2,5- di-tert-butyl hydroquinones.
The dispersing agent is casein, in triethanolamine, cetyl benzenesulfonic acid sodium, cetyl benzenesulfonic acid, peregal 0
One or more.
The vulcanizing agent is sulphur.
The promotor is promotor PX:N- ethyl, N-phenyl zinc dithiocarbamate.
It, can be with the invention has the advantages that graphene zinc oxide composites of the invention are uniformly dispersed in latex
Improve the mechanical property of latex product, improve durability and durability, enhances tough venereal disease and malicious barrier property, and there is antibacterial
Antibacterial effect.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still
It should be appreciated that these descriptions are intended merely to further illustrate the features and advantages of the present invention, rather than to invention claim
Limitation.
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.2-0.5 parts of graphene zinc oxide composites, 0.2-1 parts of stabilizer, 0.8-2 parts of anti-aging agent, 1-5 parts of vulcanizing agent, dispersing agent
0.2-1 parts, 0.2-1 parts of promotor.
Anti-aging agent is antioxidant DBH: 2,5- di-tert-butyl hydroquinones.
Dispersing agent is one of casein, triethanolamine, cetyl benzenesulfonic acid sodium, cetyl benzenesulfonic acid, peregal 0
Or it is several.
Vulcanizing agent is sulphur.
Promotor is promotor PX:N- ethyl, N-phenyl zinc dithiocarbamate.
Embodiment 1:
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.2 part of graphene zinc oxide composites, 0.3 part of stabilizer, antioxidant DBH: 2,5- 0.8 part of di-tert-butyl hydroquinones, sulphur
2 parts of sulphur, 1 part of casein, 0.3 part of zinc dithiocarbamate of promotor PX:N- ethyl, N-phenyl.
Wherein graphene zinc oxide composites are using graphene as carrier, and zinc acetate is semiconductor precursor, pass through hydro-thermal
Method prepares zinc oxide graphene complex.
All raw materials are mixed, latex is prepared by sulfidization molding.
Embodiment 2:
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.4 part of graphene zinc oxide composites, 0.5 part of stabilizer, antioxidant DBH: 2,5- 1 part of di-tert-butyl hydroquinones, sulphur
3 parts, 0.4 part of cetyl benzenesulfonic acid sodium, 0.4 part of zinc dithiocarbamate of promotor PX:N- ethyl, N-phenyl.
Wherein graphene zinc oxide composites are using graphene as carrier, and zinc acetate is semiconductor precursor, pass through hydro-thermal
Method prepares zinc oxide graphene complex.
All raw materials are mixed, latex is prepared by sulfidization molding.
Embodiment 3:
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.5 part of graphene zinc oxide composites, 0.8 part of stabilizer, antioxidant DBH: 2,5- 0.9 part of di-tert-butyl hydroquinones, sulphur
4 parts of sulphur, 0.6 part of triethanolamine, 1 part of zinc dithiocarbamate of promotor PX:N- ethyl, N-phenyl.
Wherein graphene zinc oxide composites are using graphene as carrier, and zinc acetate is semiconductor precursor, pass through hydro-thermal
Method prepares zinc oxide graphene complex.
All raw materials are mixed, latex is prepared by sulfidization molding.
Embodiment 4:
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.3 part of graphene zinc oxide composites, 1 part of stabilizer, antioxidant DBH: 2,5- 1.5 parts of di-tert-butyl hydroquinones, sulphur
4.5 parts, 0.7 part of cetyl benzenesulfonic acid, 0.6 part of zinc dithiocarbamate of promotor PX:N- ethyl, N-phenyl.
Wherein graphene zinc oxide composites are using graphene as carrier, and zinc acetate is semiconductor precursor, pass through hydro-thermal
Method prepares zinc oxide graphene complex.
All raw materials are mixed, latex is prepared by sulfidization molding.
Embodiment 5:
A kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: natural emulsion 100
Part, 0.35 part of graphene zinc oxide composites, 0.7 part of stabilizer, antioxidant DBH: 2,5- 1.7 parts of di-tert-butyl hydroquinones,
5 parts of sulphur, 0 0.5 parts of peregal, 0.8 part of zinc dithiocarbamate of promotor PX:N- ethyl, N-phenyl.
Wherein graphene zinc oxide composites are using graphene as carrier, and zinc acetate is semiconductor precursor, pass through hydro-thermal
Method prepares zinc oxide graphene complex.
All raw materials are mixed, latex is prepared by sulfidization molding.
Emgloves, sheath, sponge, pillow etc. can be made in prepared latex, the graphene zinc oxide in latex
Compound can kill germ in contact with life, while also have the function of antibacterial.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.
Claims (5)
1. a kind of latex containing graphene zinc oxide composites, is made of following components and parts by weight: 100 parts of natural emulsion,
0.2-0.5 parts of graphene zinc oxide composites, 0.2-1 parts of stabilizer, 0.8-2 parts of anti-aging agent, 1-5 parts of vulcanizing agent, dispersing agent
0.2-1 parts, 0.2-1 parts of promotor.
2. a kind of latex containing graphene zinc oxide composites according to claim 1, it is characterized in that: described is anti-old
Agent is antioxidant DBH: 2,5- di-tert-butyl hydroquinones.
3. a kind of latex containing graphene zinc oxide composites according to claim 1, it is characterized in that: the dispersion
Agent is one or more of casein, triethanolamine, cetyl benzenesulfonic acid sodium, cetyl benzenesulfonic acid, peregal 0.
4. a kind of latex containing graphene zinc oxide composites according to claim 1, it is characterized in that: the vulcanization
Agent is sulphur.
5. a kind of latex containing graphene zinc oxide composites according to claim 1, it is characterized in that: the promotion
Agent is promotor PX:N- ethyl, N-phenyl zinc dithiocarbamate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910473614.4A CN110078984A (en) | 2019-06-01 | 2019-06-01 | A kind of latex containing graphene zinc oxide composites |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910473614.4A CN110078984A (en) | 2019-06-01 | 2019-06-01 | A kind of latex containing graphene zinc oxide composites |
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| Publication Number | Publication Date |
|---|---|
| CN110078984A true CN110078984A (en) | 2019-08-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910473614.4A Pending CN110078984A (en) | 2019-06-01 | 2019-06-01 | A kind of latex containing graphene zinc oxide composites |
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| CN (1) | CN110078984A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112341646A (en) * | 2020-11-16 | 2021-02-09 | 广州双一乳胶制品有限公司 | Self-antibacterial anti-mildew household glove and preparation method thereof |
| CN112375266A (en) * | 2020-11-16 | 2021-02-19 | 广州双一乳胶制品有限公司 | Self-antibacterial condom and preparation method thereof |
| CN112480494A (en) * | 2020-11-16 | 2021-03-12 | 广州双一乳胶制品有限公司 | Self-antibacterial medical gloves and preparation method thereof |
-
2019
- 2019-06-01 CN CN201910473614.4A patent/CN110078984A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112341646A (en) * | 2020-11-16 | 2021-02-09 | 广州双一乳胶制品有限公司 | Self-antibacterial anti-mildew household glove and preparation method thereof |
| CN112375266A (en) * | 2020-11-16 | 2021-02-19 | 广州双一乳胶制品有限公司 | Self-antibacterial condom and preparation method thereof |
| CN112480494A (en) * | 2020-11-16 | 2021-03-12 | 广州双一乳胶制品有限公司 | Self-antibacterial medical gloves and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190802 |
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| WD01 | Invention patent application deemed withdrawn after publication |