CN110066692A - Coal hydrogen equipment and control method - Google Patents

Coal hydrogen equipment and control method Download PDF

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Publication number
CN110066692A
CN110066692A CN201910275176.0A CN201910275176A CN110066692A CN 110066692 A CN110066692 A CN 110066692A CN 201910275176 A CN201910275176 A CN 201910275176A CN 110066692 A CN110066692 A CN 110066692A
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China
Prior art keywords
coal
vapor
valve
gas
coal dust
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CN201910275176.0A
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Chinese (zh)
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张英华
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Individual
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Priority to CN201910275176.0A priority Critical patent/CN110066692A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/54Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/723Controlling or regulating the gasification process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

The present invention discloses a kind of coal hydrogen equipment and control method.Coal supply device is sent into coal dust in the cloth drum of coal dust revolving top.Coal dust revolving top makes a gift to someone coal dust reaction kettle.The coal dust come out from reactor bottom side flows to the higher side of recirculating fluidized bed by discharging electronic rotation valve, lights the higher side of recirculating fluidized bed topped with diesel oil or the coal dust of kerosene.The wind come out from air blower supports the burning of the coal dust on recirculating fluidized bed.The lime-ash that the burning of coal dust on recirculating fluidized bed generates is fallen into grey slag bath.Coal dust in the hot fume heating reaction kettle that burning on recirculating fluidized bed topped with the coal dust of diesel oil or kerosene generates.The vapor come out from boiler enters vapor tank, and the vapor come out from vapor tank enters in several foamed ceramics pipes, and vapor and high temperature coal dust occur chemical reaction and generate hydrogen and carbon monoxide.Removing carbon dioxide and vapor are removed in scrubbing CO_2 after coal gas in reaction kettle is sucked out by coal gas suction ventilator, then pressurization cooling.

Description

Coal hydrogen equipment and control method
Technical field:
The present invention relates to a kind of coal hydrogen equipment and control methods.
Background technique:
Hydrogen fuel cell automobile needs the hydrogen of lot of pure.The hydrocracking and reformation of petroleum chemical enterprise are also required to largely Pure hydrogen.And it is difficult to remove containing a large amount of nitrogen and carbon monoxide in the coal gas that existing water-gas method is produced.
Summary of the invention:
Coal hydrogen equipment by reaction kettle, coal supply device, coal dust revolving top, recirculating fluidized bed, air blower, Water tank, water pump, smoke and waste steam boiler, coal gas waste heat boiler, boilers heated electrically, vapor tank, coal gas heater heated by waste heat, flue gas desulfurization Device, gas desulfurizer, coal gas suction ventilator and gas pressing cooled hydrogen purification device composition, are controlled with computer controller System.Reaction kettle is made of shell, smoke pipe, chimney, foamed ceramics pipe, annular foam ceramic filter band and annular pillar.Several cigarettes Manage it is vertically-mounted in a kettle, smoke pipe lower end pass through reactor bottom, smoke pipe upper end is pooled together as chimney.Several bubbles Foam ceramic tube is vertically installed inside reaction kettle, and foamed ceramics tube top portion is closed.Ring is housed at the one third of reaction kettle Shape foam ceramic filter band, annular foam ceramic filter band be it is hollow, vanadic anhydride is housed inside annular foam ceramic band Powder, annular foam ceramic filter band outside are with annular pillar.The pipeline picked out from annular pillar is connected to the coal of gas boiler On tracheae, the pipeline picked out from coal gas waste heat boiler is connected on the gas pipe of coal gas heater heated by waste heat, from coal gas heater heated by waste heat The pipeline picked out is connected on gas desulfurizer, and the pipeline come out from gas desulfurizer is connected on coal gas suction ventilator, from coal gas The pipeline that suction ventilator comes out is connected on gas pressing cooled hydrogen purification device.Coal dust revolving top is by cloth drum, cloth Plectane, cloth motor form.Several circular holes of cloth drum bottom are adapted with several circular holes on following cloth plectane, cloth The output gear of material motor is engaged with the cloth gear at cloth plectane edge, and cloth plectane is flexibly connected with reaction kettle upper end.Instead It answers chimney inside kettle to pass through upwards from the cloth drum center of coal dust revolving top, is then connected to the flue of smoke and waste steam boiler On, the pipeline picked out from the flue of smoke and waste steam boiler is connected on flue gas desulfurization device.The structure of coal supply device is as follows: coal Coal electronic rotation valve is housed on the filler tube of powder funnel, is the machine of coal chain transfer below the filler tube of coal dust funnel Head, coal chain transfer tilt upward installation, and the tail portion of coal chain transfer is above cloth plectane edge.Water tank bottom Water pipe be connected on water pump, the water pipe picked out from water pump is connected to the sump of smoke and waste steam boiler by motorized adjustment water valve, from cigarette The water pipe that the sump of gas waste heat boiler comes out is connected to coal gas waste heat boiler vapor storehouse, comes out from coal gas waste heat boiler vapor storehouse Vapor pipe be connected on vapor tank by vapor check valve.The vapor pipe come out from boilers heated electrically is by vapor electricity Magnet valve is connected on vapor tank, and the vapor pipe come out from vapor tank is connected to several foams pottery by vapor electric control valve Porcelain tube bottom,.The pipeline come out from reactor bottom side is connected to recirculating fluidized bed higher one by discharging electronic rotation valve Upper side is equipped with upper lime-ash electronic rotation dish valve and lower lime-ash electronic rotation dish valve in the lime-ash pipe of recirculating fluidized bed tail portion.From The pipeline that air blower comes out is connected to coal gas heater heated by waste heat cooling duct by motorized adjustment air-valve, cold from coal gas heater heated by waste heat But the pipeline that channel comes out is connected to below recirculating fluidized bed.
The control method of coal hydrogen equipment: the coal electronic rotation being equipped on the filler tube that coal dust passes through coal dust funnel Valve drains in the metal trough of coal chain transfer, and coal dust is transported to the cloth drum of revolving top by coal chain transfer In.Coal dust in cloth drum, which reaches, stops coal electronic rotation valve and coal chain transfer, cloth drum when setting high position In coal dust lower than setting lower position when restarting coal electronic rotation valve and coal chain transfer.The rotation of cloth motor, The output gear of cloth motor drives the rotation of cloth gear, so that cloth plectane be made to rotate.When several circles of cloth drum bottom When hole is aligned with several circular holes on following cloth plectane, the coal dust in cloth drum passes through the cloth drum bottom of alignment Several circular holes of several circular holes and cloth plectane drain in reaction kettle.When coal dust in reaction kettle 1 reaches setting high position, stop cloth Expect motor, when the coal dust in reaction kettle 1 is lower than setting lower position, restarts cloth motor.It is come out from reactor bottom side Coal dust flow to the higher side of recirculating fluidized bed by discharging electronic rotation valve, toward on the coal dust of the higher side of recirculating fluidized bed Spilling some diesel oil, perhaps kerosene lights the higher side of recirculating fluidized bed topped with diesel oil or the coal dust of kerosene.It is come out from air blower Wind enter coal gas heater heated by waste heat cooling duct by motorized adjustment air-valve and be heated, from coal gas heater heated by waste heat cooling duct Wind out enters below recirculating fluidized bed, supports the burning on recirculating fluidized bed topped with diesel oil or the coal dust of kerosene.Circulation The lime-ash that the burning of coal dust on fluidized bed generates is fallen into the lime-ash pipe of recirculating fluidized bed tail portion, lime-ash electronic rotation in opening Dish valve, lime-ash are fallen into the pipeline between lime-ash electronic rotation dish valve and lower lime-ash electronic rotation dish valve, are then shut off ash Slag electronic rotation dish valve opens lower lime-ash electronic rotation dish valve again, and lime-ash flows to grey slag bath by lower lime-ash electronic rotation dish valve In, close lower lime-ash electronic rotation dish valve.The hot cigarette that burning on recirculating fluidized bed topped with the coal dust of diesel oil or kerosene generates Gas enters smoke pipe from reactor bottom, heats the coal dust in reaction kettle.The flue gas come out from chimney enters smoke and waste steam boiler Flue, the flue gas come out from the flue of smoke and waste steam boiler enter flue gas desulfurization device scrubbing CO_2.Boilers heated electrically and water Solenoid valve for steam is powered, and the vapor come out from boilers heated electrically enters vapor tank by vapor solenoid valve, vapor tank The electricity of power failure heat boiler and vapor solenoid valve when pressure reaches setting high pressure intensity values.Coal dust in reaction kettle is by recirculating fluidized bed On topped with the coal dust of diesel oil or kerosene burning generate hot fume be heated to set temperature when, vapor electric control valve is beaten It opens, the vapor come out from vapor tank enters in several foamed ceramics pipes by vapor electric control valve, from foamed ceramics The coal dust of vapor and set temperature that pipe aperture comes out occurs chemical reaction and generates hydrogen and carbon monoxide.Start coal gas air draught Machine, hydrogen, carbon monoxide and part vapor in reaction kettle pass through annular foam ceramic filter band, carbon monoxide and part water Steam is urged when passing through annular foam ceramic filter band by the vanadium pentoxide powder being equipped with inside annular foam ceramic filter band Change and chemical reaction generation hydrogen and carbon dioxide occurs.Water extraction in pump handle water tank, the water come out from water pump 17 is by electricity The sump that dynamic water adjusting valve enters smoke and waste steam boiler is heated, and the water come out from the sump of smoke and waste steam boiler enters more than coal gas Heat boiler vapor storehouse.When the water level in coal gas waste heat boiler vapor storehouse is more than setting high water level, motorized adjustment water valve is turned down, When the water level in coal gas waste heat boiler vapor storehouse is lower than setting low water level, motorized adjustment water valve is tuned up.It is come out from annular pillar Coal gas enter the gas pipe of coal gas waste heat boiler, the water in 11 vapor storehouse of coal gas waste heat boiler is heated into vapor, from The vapor that coal gas waste heat boiler vapor storehouse comes out enters vapor tank by vapor check valve.Water in vapor tank steams Gas reaches the electricity of power failure heat boiler and vapor solenoid valve when setting High Voltage, and the vapor in vapor tank is lower than setting low pressure Boilers heated electrically is powered when strong, and vapor solenoid valves are opened when the vapor pressure in boilers heated electrically reaches setting value, electric heating The vapor of boiler reenters vapor tank.The coal gas come out from coal gas waste heat boiler enters the coal gas of coal gas heater heated by waste heat Wind in pipe heating gas heater heated by waste heat cooling duct, the coal gas come out from coal gas heater heated by waste heat enter gas desulfurizer Scrubbing CO_2, from gas desulfurizer come out coal gas coal gas enter suction ventilator, from coal gas suction ventilator come out coal gas into Enter gas pressing cooled hydrogen purification device, coal gas is added to six atmospheric pressure, the vapor and carbon dioxide in coal gas become Liquid and removed, be left pure hydrogen.If the temperature in reaction kettle is more than setting high temperature value, computer controller can be adjusted Big vapor electric control valve allows more vapor to enter reaction kettle and the coal dust generation chemistry more than setting high temperature value is anti- It answers, suspends the electricity of discharging electronic rotation valve, reduce the coal dust on recirculating fluidized bed, turn motorized adjustment air-valve down.If reaction kettle Interior temperature can turn vapor electric control valve down lower than setting low temperature value, computer controller, and less vapor is allowed to enter Reaction kettle is chemically reacted with the coal dust lower than setting low temperature value, and discharging electronic rotation valve is re-energised rotation, and increase follows Coal dust on ring fluidized bed tunes up motorized adjustment air-valve, and more wind is allowed to support the coal dust firing on fluidized bed.
Detailed description of the invention:
Further specific detailed description is done to the present invention with reference to the accompanying drawings and detailed description.
Fig. 1 is structural schematic diagram of the invention.
Specific embodiment:
Shown in Fig. 1, coal hydrogen equipment.Coal hydrogen equipment is rotated by reaction kettle 1, coal supply device 2, coal dust Distributing device 3, recirculating fluidized bed 5, air blower 24, water tank 16, water pump 17, smoke and waste steam boiler 9, coal gas waste heat boiler 11, electric heating Boiler 21, vapor tank 20, coal gas heater heated by waste heat 12, flue gas desulfurization device 10, gas desulfurizer 13, coal gas suction ventilator 14 It forms with gas pressing cooled hydrogen purification device 15, is controlled with computer controller.Reaction kettle by shell 101, smoke pipe 103, Chimney 102, foamed ceramics pipe 104, annular foam ceramic filter band 105 and annular pillar 103 form.Several smoke pipes 103 are vertical It is mounted in reaction kettle 1,103 lower end of smoke pipe passes through 1 bottom of reaction kettle, and 103 upper end of smoke pipe is pooled together as chimney 102. Several foamed ceramics pipes 104 are vertically installed at 1 the inside of reaction kettle, are closed at the top of foamed ceramics pipe 104.The three of reaction kettle 1 Annular foam ceramic filter band 105 is housed, annular foam ceramic filter band 105 is hollow, annular foam ceramics at/mono- Vanadium pentoxide powder is housed inside band 105, is with annular pillar 106 outside annular foam ceramic filter band 105.It is protected from annular The pipeline that pipe 106 picks out is connected on the gas pipe of gas boiler 11, and the pipeline picked out from coal gas waste heat boiler 11 is connected to more than coal gas On the gas pipe of hot heater 12, the pipeline picked out from coal gas heater heated by waste heat 12 is connected on gas desulfurizer 13, from coal gas The pipeline that desulfurizer 13 comes out is connected on coal gas suction ventilator 14, and it is cold that the pipeline come out from coal gas suction ventilator 14 is connected to gas pressing But on hydrogen purification device 15.Coal dust revolving top 3 is made of cloth drum 301, cloth plectane 302, cloth motor 303. Several circular holes of 301 bottom of cloth drum are adapted with several circular holes on following cloth plectane 302, cloth motor 303 Output gear is engaged with the cloth gear at 302 edge of cloth plectane, and cloth plectane 302 is flexibly connected with 1 upper end of reaction kettle.Reaction 1 the inside chimney 102 of kettle is passed through from 201 center of cloth drum of coal dust revolving top 3 upwards, is then connected to smoke and waste steam boiler On 9 flue, the pipeline picked out from the flue of 9 furnace of fume afterheat pot is connected on flue gas desulfurization device 10.Coal supply device 2 Structure is as follows: coal electronic rotation valve 202 being housed on the filler tube of coal dust funnel 201, is below the filler tube of coal dust funnel 201 The head of coal chain transfer 203, coal chain transfer 203 tilt upward installation, the tail portion of coal chain transfer 203 Above 301 edge of cloth drum.The water pipe of 16 bottom of water tank is connected on water pump 17, and the water pipe picked out from water pump 17 is by electronic Water adjusting valve 18 is connected to the sump of smoke and waste steam boiler 9, and the water pipe come out from the sump of smoke and waste steam boiler 9 is connected to coal gas waste heat 11 vapor storehouse of boiler, the vapor pipe come out from 11 vapor storehouse of coal gas waste heat boiler are connected to water by vapor check valve 19 On steam tank 20.The vapor pipe come out from boilers heated electrically 21 is connected on vapor tank 20 by vapor solenoid valve 22, from water The vapor pipe that steam tank 20 comes out is connected to several 304 bottoms of foamed ceramics pipe by vapor electric control valve 23,.From reaction The pipeline that 1 bottom sides of kettle come out is connected to the higher upper side of recirculating fluidized bed 5, recycle stream by discharging electronic rotation valve 4 Change and upper lime-ash electronic rotation dish valve 6 and lower lime-ash electronic rotation dish valve 7 are housed in the lime-ash pipe of 5 tail portion of bed.Go out from air blower 24 The pipeline come is connected to 12 cooling duct of coal gas heater heated by waste heat by motorized adjustment air-valve 25, cooling from coal gas heater heated by waste heat 12 The pipeline that channel comes out is connected to 5 lower section of recirculating fluidized bed.
Shown in Fig. 1, the control method of coal hydrogen equipment: it is equipped on the filler tube that coal dust passes through coal dust funnel 201 Coal electronic rotation valve 202 drains in the metal trough of coal chain transfer 203, and coal dust is transported to by coal chain transfer 203 In the cloth drum 301 of revolving top 3.Coal dust in cloth drum 301, which reaches, stops coal electronic rotation when setting high position Valve 202 and coal chain transfer 203, restarting coal is electronic when coal dust in cloth drum 301 is lower than setting lower position Rotary valve 202 and coal chain transfer 203.Cloth motor 303 rotates, and the output gear of cloth motor 303 drives cloth tooth Wheel rotation, so that cloth plectane 302 be made to rotate.When on the several circular holes and following cloth plectane 302 of 301 bottom of cloth drum The alignment of several circular holes when, the coal dust in cloth drum 301 passes through the several circular holes and cloth of 301 bottom of cloth drum of alignment Several circular holes of plectane 392 drain in reaction kettle 1.When coal dust in reaction kettle 1 reaches setting high position, stop cloth motor 303, When coal dust in reaction kettle 1 is lower than setting lower position, cloth motor 303 is restarted.The coal come out from 1 bottom sides of reaction kettle Powder flows to the higher side of recirculating fluidized bed 5 by discharging electronic rotation valve 4, toward on the coal dust of the higher side of recirculating fluidized bed 5 Spilling some diesel oil, perhaps kerosene lights the higher side of recirculating fluidized bed 5 topped with diesel oil or the coal dust of kerosene.Go out from air blower 24 The wind come is heated by motorized adjustment air-valve 25 into 12 cooling duct of coal gas heater heated by waste heat, from coal gas heater heated by waste heat 12 The wind that cooling duct comes out enters 5 lower section of recirculating fluidized bed, supports on recirculating fluidized bed 5 topped with the coal dust of diesel oil or kerosene Burning.The lime-ash that the burning of coal dust on recirculating fluidized bed 5 generates is fallen into the lime-ash pipe of 5 tail portion of recirculating fluidized bed, in opening Lime-ash electronic rotation dish valve 6, lime-ash fall into the pipeline between lime-ash electronic rotation dish valve 6 and lower lime-ash electronic rotation dish valve 7 In, it is then shut off lime-ash electronic rotation dish valve 6 and opens lower lime-ash electronic rotation dish valve 7 again, lime-ash passes through the electronic rotation of lower lime-ash Plate-spinning valve 7 flows in grey slag bath 8, closes lower lime-ash electronic rotation dish valve 7.Topped with diesel oil or kerosene on recirculating fluidized bed 5 The hot fume that the burning of coal dust generates enters smoke pipe 103 from reaction kettle bottom 1, heats the coal dust in reaction kettle 1.From chimney 102 Flue gas out enters the flue of 9 furnace of fume afterheat pot, and the flue gas come out from the flue of smoke and waste steam boiler 9 enters flue gas desulfurization 10 scrubbing CO_2 of device.Boilers heated electrically 21 and vapor solenoid valve 22 are powered, the vapor warp come out from boilers heated electrically 21 It crosses vapor solenoid valve 22 and enters vapor tank 20, power failure heat boiler 21 when the pressure of vapor tank 20 reaches setting high pressure intensity values With the electricity of vapor solenoid valve 22.Coal dust in reaction kettle 1 is by the combustion on recirculating fluidized bed 5 topped with diesel oil or the coal dust of kerosene When the hot fume that burning generates is heated to set temperature, vapor electric control valve 23 is opened, and the water come out from vapor tank 20 steams Gas enters in several foamed ceramics pipes 104 by vapor electric control valve 23, and the water come out from 104 aperture of foamed ceramics pipe steams Gas and the coal dust of set temperature occur chemical reaction and generate hydrogen and carbon monoxide.Start coal gas suction ventilator 14, in reaction kettle 1 Hydrogen, carbon monoxide and part vapor pass through annular foam ceramic filter band 105, and carbon monoxide and part vapor are passing through The vanadium pentoxide powder catalytic reaction being equipped with inside annular foam ceramic filter band 105 when annular foam ceramic filter band 105 Biochemical reaction generates hydrogen and carbon dioxide.Water pump 17 extracts the water in water tank 16 out, and the water come out from water pump 17 is by electricity The sump that dynamic water adjusting valve 18 enters smoke and waste steam boiler 9 is heated, and the water come out from the sump of smoke and waste steam boiler 9 enters coal 11 vapor storehouse of gas waste heat boiler.When the water level in 11 vapor storehouse of coal gas waste heat boiler is more than setting high water level, turn down electronic Water adjusting valve 18 tunes up motorized adjustment water valve 18 when the water level in 11 vapor storehouse of coal gas waste heat boiler is lower than setting low water level. The coal gas come out from annular pillar 106 enters the gas pipe of coal gas waste heat boiler 11, in 11 vapor storehouse of coal gas waste heat boiler Water be heated into vapor, from 11 vapor storehouse of coal gas waste heat boiler come out vapor by vapor check valve 19 enter water Steam tank 20.Power failure heat boiler 21 and vapor solenoid valve 22 when vapor in vapor tank 20 reaches setting High Voltage Electricity, boilers heated electrically 21 is powered when vapor in vapor tank 20 is lower than setting low pressure, the water vapor pressure in boilers heated electrically 21 Vapor solenoid valve 22, which is powered, when reaching setting value by force opens, and the vapor of boilers heated electrically 21 reenters vapor tank 20.From The gas pipe heating gas heater heated by waste heat 12 that the coal gas that coal gas waste heat boiler 11 comes out enters coal gas heater heated by waste heat 12 is cooling Wind in channel, the coal gas come out from coal gas heater heated by waste heat 12 enters 13 scrubbing CO_2 of gas desulfurizer, from coal gas The coal gas coal gas that desulfurizer 13 comes out enters suction ventilator 14, and it is cooling that the coal gas come out from coal gas suction ventilator 14 enters gas pressing Coal gas is added to six atmospheric pressure by hydrogen purification device 15, and the vapor and carbon dioxide in coal gas become liquid and removed, It is left pure hydrogen.If the temperature in reaction kettle 1 is more than setting high temperature value, it is electronic that computer controller can tune up vapor Regulating valve 23 allows more vapor to enter reaction kettle 1 and chemically reacts with the coal dust for being more than setting high temperature value, and pause is unloaded Expect the electricity of electronic rotation valve 4, reduces the coal dust on recirculating fluidized bed 5, turn motorized adjustment air-valve 25 down.If in reaction kettle 1 Temperature can turn vapor electric control valve 23 down lower than setting low temperature value, computer controller, allow less vapor to enter anti- Kettle 1 is answered to chemically react with the coal dust lower than setting low temperature value, discharging electronic rotation valve 4 is re-energised rotation, and increase follows Coal dust on ring fluidized bed 5 tunes up motorized adjustment air-valve 25, and more wind is allowed to support the coal dust firing on fluidized bed 5.

Claims (2)

1. a kind of coal hydrogen equipment, it is characterised in that: coal hydrogen equipment is by reaction kettle (1), coal supply device (2), coal dust revolving top (3), recirculating fluidized bed (5), air blower (24), water tank (16), water pump (17), smoke and waste steam boiler (9), coal gas waste heat boiler (11), boilers heated electrically (21), vapor tank (20), coal gas heater heated by waste heat (12), flue gas desulfurization dress Set (10), gas desulfurizer (13), coal gas suction ventilator (14) and gas pressing cooled hydrogen purification device (15) composition, electricity consumption Brain controller controls, and reaction kettle is by shell (101), smoke pipe (103), chimney (102), foamed ceramics pipe (104), annular foam Ceramic filter band (105) and annular pillar (103) form, several smoke pipes (103) are vertically installed in reaction kettle (1), smoke pipe (103) lower end passes through reaction kettle (1) bottom, and smoke pipe (103) upper end is pooled together as chimney (102), several foamed ceramicses Pipe (104) is vertically installed inside reaction kettle (1), be at the top of foamed ceramics pipe (104) it is closed, reaction kettle (1) three/ Annular foam ceramic filter band (105) is housed, annular foam ceramic filter band (105) is hollow, annular foam ceramics at one Vanadium pentoxide powder is housed inside band (105), is with annular pillar (106) outside annular foam ceramic filter band (105);From The pipeline that annular pillar (106) picks out is connected on the gas pipe of gas boiler (11), the pipe picked out from coal gas waste heat boiler (11) Road is connected on the gas pipe of coal gas heater heated by waste heat (12), and the pipeline picked out from coal gas heater heated by waste heat (12) is connected to coal gas desulfurization On device (13), the pipeline come out from gas desulfurizer (13) is connected on coal gas suction ventilator (14), from coal gas suction ventilator (14) Pipeline out is connected on gas pressing cooled hydrogen purification device (15);Coal dust revolving top (3) is by cloth drum (301), cloth plectane (302), cloth motor (303) composition, several circular holes of cloth drum (301) bottom and following cloth Several circular holes on plectane (302) are adapted, the output gear of cloth motor (303) and the cloth at cloth plectane (302) edge Gear engagement, cloth plectane (302) are flexibly connected with reaction kettle (1) upper end, and chimney (102) is upwards from coal inside reaction kettle (1) Cloth drum (20) center of powder revolving top (3) passes through, and is then connected on the flue of smoke and waste steam boiler (9), from flue gas The pipeline that the flue of waste heat pot (9) furnace picks out is connected on flue gas desulfurization device (10);The structure of coal supply device (2) is as follows: Coal electronic rotation valve (202) is housed on the filler tube of coal dust funnel (201), is coal below the filler tube of coal dust funnel (201) The head of charcoal chain transfer (203), coal chain transfer (203) tilt upward installation, coal chain transfer (203) Tail portion is above cloth drum (301) edge;The water pipe of water tank (16) bottom is connected on water pump (17), is picked out from water pump (17) Water pipe is connected to the sump of smoke and waste steam boiler (9) by motorized adjustment water valve (18), comes out from the sump of smoke and waste steam boiler (9) Water pipe be connected to coal gas waste heat boiler (11) vapor storehouse, from coal gas waste heat boiler (11) vapor storehouse come out vapor Guan Jing It crosses vapor check valve (19) to be connected on vapor tank (20), the vapor pipe come out from boilers heated electrically (21) is by vapor electricity Magnet valve (22) is connected on vapor tank (20), and the vapor pipe come out from vapor tank (20) passes through vapor electric control valve (23) several foamed ceramics pipe (304) bottoms are connected to,;The pipeline come out from reaction kettle (1) bottom sides passes through the electronic rotation of discharging Rotary valve (4) is connected to the higher upper side of recirculating fluidized bed (5), and upper lime-ash is housed in the lime-ash pipe of recirculating fluidized bed (5) tail portion Electronic rotation dish valve (6) and lower lime-ash electronic rotation dish valve (7);The pipeline come out from air blower (24) passes through motorized adjustment air-valve (25) it is connected to coal gas heater heated by waste heat (12) cooling duct, the pipeline come out from coal gas heater heated by waste heat (12) cooling duct is connected to Below recirculating fluidized bed (5).
2. the control method of coal hydrogen equipment, it is characterised in that: be equipped on the filler tube that coal dust passes through coal dust funnel (201) Coal electronic rotation valve (202) drain in the metal trough of coal chain transfer (203), coal chain transfer (203) is by coal The cloth drum (301) that powder is transported to revolving top (3) is inner, when the inner coal dust of cloth drum (301) reaches setting high position Stop coal electronic rotation valve (202) and coal chain transfer (203), the inner coal dust of cloth drum (301) is lower than setting low level Coal electronic rotation valve (202) and coal chain transfer (203) are restarted when setting;Cloth motor (303) rotation, cloth electricity The output gear of machine (303) drives the rotation of cloth gear, to make cloth plectane (302) to rotate, when cloth drum (301) bottom Several circular holes when being aligned with several circular holes on following cloth plectane (302), the inner coal dust of cloth drum (301) passes through pair It is inner that neat several circular holes of cloth drum (301) bottom and several circular holes of cloth plectane (302) drain to reaction kettle (1), reaction When the inner coal dust of kettle (1) reaches setting high position, stop cloth motor (303), the inner coal dust of reaction kettle (1) is lower than setting lower position When, it restarts cloth motor (303);The coal dust come out from reaction kettle (1) bottom sides is flowed by discharging electronic rotation valve (4) To recirculating fluidized bed (5) higher side, toward the coal dust of recirculating fluidized bed (5) higher side on spill some diesel oil or kerosene, Recirculating fluidized bed (5) higher side is lighted topped with diesel oil or the coal dust of kerosene;The wind come out from air blower (24) is by electronic Adjusting air valve (25) enters coal gas heater heated by waste heat (12) cooling duct and is heated, from coal gas heater heated by waste heat (12) cooling duct Wind out enters below recirculating fluidized bed (5), supports the combustion on recirculating fluidized bed (5) topped with diesel oil or the coal dust of kerosene It burns;The lime-ash that the burning of coal dust on recirculating fluidized bed (5) generates is fallen into the lime-ash pipe of recirculating fluidized bed (5) tail portion, is opened Upper lime-ash electronic rotation dish valve (6), lime-ash fall into lime-ash electronic rotation dish valve (6) and lower lime-ash electronic rotation dish valve (7) it Between pipeline in, be then shut off lime-ash electronic rotation dish valve (6) and open lower lime-ash electronic rotation dish valve (7) again, lime-ash passes through It is inner that lower lime-ash electronic rotation dish valve (7) flows to grey slag bath (8), closes lower lime-ash electronic rotation dish valve (7);Recirculating fluidized bed (5) On enter smoke pipe (103) topped with the hot fume that generates of burning of the coal dust of diesel oil or kerosene from reaction kettle bottom (1) portion, heating is anti- The coal dust for answering kettle (1) inner;The flue gas come out from chimney (102) enters the flue of fume afterheat pot (9) furnace, from smoke and waste steam boiler (9) flue gas that flue comes out enters flue gas desulfurization device (10) scrubbing CO_2;Boilers heated electrically (21) and vapor electromagnetism Valve (22) is powered, and the vapor come out from boilers heated electrically (21) enters vapor tank (20) by vapor solenoid valve (22), water The electricity of power failure heat boiler (21) and vapor solenoid valve (22) when the pressure of steam tank (20) reaches setting high pressure intensity values;Reaction kettle (1) inner coal dust is heated to set by the hot fume that the burning on recirculating fluidized bed (5) topped with the coal dust of diesel oil or kerosene generates When determining temperature, vapor electric control valve (23) is opened, and the vapor come out from vapor tank (20) passes through vapor electric adjustable It saves valve (23) and enters the vapor and set temperature that several foamed ceramics pipes (104) are inner, come out from foamed ceramics pipe (104) aperture Coal dust chemical reaction occur generate hydrogen and carbon monoxide;Start coal gas suction ventilator (14), the inner hydrogen of reaction kettle (1), one Carbonoxide and part vapor pass through annular foam ceramic filter band (105), carbon monoxide and part vapor and are passing through annular The vanadium pentoxide powder catalytic reaction being equipped with inside annular foam ceramic filter band (105) when foam ceramic filter band (105) Biochemical reaction generates hydrogen and carbon dioxide;Water pump (17) extracts the inner water of water tank (16) out, the water come out from water pump (17) It is heated by the sump that motorized adjustment water valve (18) enter smoke and waste steam boiler (9), goes out from the sump of smoke and waste steam boiler (9) The water come enters coal gas waste heat boiler (11) vapor storehouse;When the water level in coal gas waste heat boiler (11) vapor storehouse is more than that setting is high When water level, motorized adjustment water valve (18) are turned down, when the water level in coal gas waste heat boiler (11) vapor storehouse is lower than setting low water level, Tune up motorized adjustment water valve (18);The coal gas come out from annular pillar (106) enters the gas pipe of coal gas waste heat boiler (11), Water in coal gas waste heat boiler (11) vapor storehouse is heated into vapor, the water come out from coal gas waste heat boiler (11) vapor storehouse Steam enters vapor tank (20) by vapor check valve (19);The inner vapor of vapor tank (20) reaches setting High Voltage When power failure heat boiler (21) and vapor solenoid valve (22) electricity, the inner vapor of vapor tank (20) lower than setting low pressure when Boilers heated electrically (21) is powered, and vapor solenoid valve (22) energization is beaten when the inner vapor pressure of boilers heated electrically (21) reaches setting value It opens, the vapor of boilers heated electrically (21) reenters vapor tank (20);The coal gas come out from coal gas waste heat boiler (11) enters Wind in gas pipe heating gas heater heated by waste heat (12) cooling duct of coal gas heater heated by waste heat (12), from coal gas waste-heat The coal gas that device (12) comes out enters gas desulfurizer (13) scrubbing CO_2, the coal gas come out from gas desulfurizer (13) Coal gas enters suction ventilator (14), and the coal gas come out from coal gas suction ventilator (14) enters gas pressing cooled hydrogen purification device (15), coal gas is added to six atmospheric pressure, the vapor and carbon dioxide in coal gas become liquid and removed, and are left pure Hydrogen;If the temperature in reaction kettle (1) is more than setting high temperature value, computer controller can tune up vapor electric control valve (23), it allows more vapor to enter reaction kettle (1) to chemically react with the coal dust for being more than setting high temperature value, suspends discharging The electricity of electronic rotation valve (4) reduces the coal dust on recirculating fluidized bed (5), turns motorized adjustment air-valve (25) down;If reaction kettle (1) for the temperature in lower than setting low temperature value, computer controller can turn vapor electric control valve (23) down, and less water is allowed to steam Gas enters reaction kettle (1) and chemically reacts with the coal dust lower than setting low temperature value, and discharging electronic rotation valve (4) is re-energised Rotation increases the coal dust on recirculating fluidized bed (5), tunes up motorized adjustment air-valve (25), and more wind is allowed to support on fluidized bed (5) Coal dust firing.
CN201910275176.0A 2019-03-22 2019-03-22 Coal hydrogen equipment and control method Pending CN110066692A (en)

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Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3645700A (en) * 1999-05-27 2000-11-30 Dmt Gmbh Process and device to enable autothermic gasification of solid fuels
CN102260538A (en) * 2011-06-24 2011-11-30 华中科技大学 Method and device for air-floatation flow-state high-temperature heat-transfer gasification of biomass
CN105295967A (en) * 2015-11-12 2016-02-03 盐城工学院 Outer heating pyrolysis reactor for high-moisture carbon-based raw material
CN109133005A (en) * 2018-08-31 2019-01-04 张英华 The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3645700A (en) * 1999-05-27 2000-11-30 Dmt Gmbh Process and device to enable autothermic gasification of solid fuels
CN102260538A (en) * 2011-06-24 2011-11-30 华中科技大学 Method and device for air-floatation flow-state high-temperature heat-transfer gasification of biomass
CN105295967A (en) * 2015-11-12 2016-02-03 盐城工学院 Outer heating pyrolysis reactor for high-moisture carbon-based raw material
CN109133005A (en) * 2018-08-31 2019-01-04 张英华 The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy

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