CN109133005A - The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy - Google Patents

The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy Download PDF

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Publication number
CN109133005A
CN109133005A CN201811041806.XA CN201811041806A CN109133005A CN 109133005 A CN109133005 A CN 109133005A CN 201811041806 A CN201811041806 A CN 201811041806A CN 109133005 A CN109133005 A CN 109133005A
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foamed alloy
alloy
pipe
foamed
cloth
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张英华
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10—Sintering only
    • B22F3/11—Making porous workpieces or articles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/061—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of metal oxides with water
    • C01B3/063—Cyclic methods
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/50—Fuel charging devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Catalysts (AREA)

Abstract

The production method that the present invention discloses a kind of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy.The stalk of chopping is sent into the gap between foamed alloy return bend and foamed alloy revolution cone.Coal dust is sent into the gap between foamed alloy pipe and foamed alloy return bend.Toothed gearing electric motor, which is powered to rotating, drives foamed alloy return bend and foamed alloy revolution cone rotation, it is filled with crushing straw in the gap for turning round foamed alloy return bend and foamed alloy between cone, makes to be filled with coal dust in the gap between foamed alloy pipe and foamed alloy return bend.Diesel oil is sprayed on coal dust and crushing straw from outer casing back.The flame that start-up burner generates lights the coal dust for being sprayed with diesel oil and stalk.By being blown into from hollow rotating shaft, foamed alloy revolution cone crushing straw burns the wind of air blower blowout and coal dust is smouldered.The vapor that boiler generates is bored across foamed alloy, is reacted with the coal dust smouldered and is generated hydrogen, carbon monoxide.Hydrogen-containing gas removes impurity by desulfurization and compression condensation exclusion device.

Description

The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy
Technical field:
The present invention relates to a kind of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and the production methods of foamed alloy.
Background technique:
Catalytic reforming in petrochemical industry needs a large amount of hydrogen.Hydrogen fuel cell automobile needs a large amount of hydrogen.Ammonia Gas production needs a large amount of hydrogen.Contain a large amount of hydrogen in the combustion gas that semiwater gas method is produced.But semiwater gas method is raw Temperature required for the coal gas of output is too high.
Carbon dioxide, which accounts for 5%, carbon monoxide and accounts for 19%, nitrogen, in the coal gas that semiwater gas method is produced accounts for 25%, hydrogen Account for 50%, that is to say, that fuel gas accounts for 69%, so the firepower of coal gas gas-cooker is very violent.Semiwater gas method Gas Production is set It is standby huge, be not suitable for using in the natural village of only hundreds of people.After the combustion gas that semiwater gas method is produced is coal full combustion, Unburned coal is heated to 800 DEG C, vapor is intermittently sprayed on 800 DEG C of coal, vapor and 800 DEG C of coal Chemical reaction occurs to generate carbon monoxide and hydrogen and absorb a large amount of thermal energy.Vanadic anhydride is heated to 500 DEG C, then is led to Enter carbon monoxide, carbon monoxide and vanadic anhydride occur chemical reaction and generate vanadium dioxide and carbon dioxide.By vanadium dioxide 500 DEG C are heated to, then is passed through vapor, vapor and vanadium dioxide occur chemical reaction and generate vanadic anhydride and hydrogen, simultaneously Absorb a large amount of thermal energy.Currently, country is promoting a kind of clean energy vehicle -- hydrogen cell automobile.Use hydrogen fuel electricity Pond automobile, it is necessary to produce a large amount of hydrogen.
Application number: 201610544773.5 " device for generating power by waste heat and control method and its applications " describe multidigit circulating picture-changing To the structure of valve.The structure of the multidigit circulation reversal valve in 12 holes is as follows: round 12 hole ceramics fixed valve plates are fixed on a basin Bottom is connected on the steel basin of 12 steel pipes, and the valve opening on round 12 hole ceramic valve plates is the Kong Xinwei origin with centre bore Central symmetry, the nozzle for 12 steel pipes being connected on steel basin respectively with 12 valve openings pair on round 12 hole ceramic valve plates It connects, bearing is housed on the centre bore of steel basin.Round three hole ceramics moving valve plates are fixed in three hole steel protection plates, and round three hole ceramics are dynamic Three valve ports on valve block are with the centrosymmetric image of the Kong Xinwei origin of the centre bore of round three hole ceramics moving valve plates, three holes Three circular holes in steel protection plate are using the center of circle of the centre bore in three hole steel protection plates as the centrosymmetric image of origin.In steel protection plate Three circular holes are adapted with three valve openings in round three hole ceramics moving valve plate evenings respectively, the centre bore and circle in three hole steel protection plates Centre bore on three hole ceramics moving valve plate of shape is adapted.The shaft of the multidigit circulation reversal valve in 12 holes sequentially passes through downwards steel shield The centre bore of the centre bore of disk and round three hole ceramics moving valve plate evenings, then three hole steel protection plates and round three hole ceramic valve plates are consolidated It is scheduled in the shaft of multidigit circulation reversal valve in 12 holes, then the shaft of the multidigit circulation reversal valve in 12 holes is then passed through circle The centre bore of 12 hole ceramics fixed valve plates is finally inserted and secured on the lower end of the shaft of the multidigit circulation reversal valve in 12 holes On bearing in steel basin centre bore.The shaft of the multidigit circulation reversal valve in 12 holes is mounted on the center in three hole steel protection plates Hole, the centre bore of round three hole ceramics moving valve plates, round 12 hole ceramics fixed valve plates centre bore and steel basin centre bore in axis After holding, there are outer diameter washer identical with three hole steel protection plate sizes or spring to be pressed in three hole protection plate of steel.12 holes Multidigit circulation reversal valve shaft upper end pass through isolation board centre bore after, isolation board is pressed on washer or spring, isolation There are many aperture on plate, the shaft of the multidigit circulation reversal valve in 12 holes is then passed through the centre bore of end cap upwards, then uses screw End cap is fixed on steel basin.Gas or liquid more than set temperature are followed from the multidigit that the pipeline on end cap enters 12 holes The output shaft of ring reversal valve, toothed gearing electric motor drives the multidigit in 12 holes to recycle reversal valve rotation by shaft coupling.
Summary of the invention:
High temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention is by high temperature vanadium dioxide catalytic water gas shift device, inclination devulcanizer Or spiral devulcanizer and compression condensation exclusion device form.High temperature vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body It is successively shell, foamed alloy pipe, foamed alloy cone, foamed alloy return bend and foamed alloy revolution cone composition from outside to inside. The front is high and the back is low is mounted on first support frame and second support frame for furnace body.It is equipped between foamed alloy pipe front end and shell First metal partion (metp), between foamed alloy pipe middle section and shell be equipped with second metal partion (metp), the back segment of foamed alloy pipe with Third metal partion (metp) is housed between shell.The leading inside of foam compo pipe is equipped with multiple idler wheels, and idler wheel is pressed in foamed alloy and returns On the endless metal track of tube front end outer side section.Multiple foamed alloys cone rear end is fixed on outer casing back, foamed alloy bore to It is preceding to be protruded into after metal mesh in the gap bubble alloy porcelain tube and foamed alloy return bend.Contain five oxygen in foamed alloy cone Change two vanadium catalysts, the back segment of foamed alloy pipe contains vanadium pentoxide catalyst, and the back segment of foamed alloy return bend contains five V 2 O catalyst.The rear end of foamed alloy revolution cone is equipped with annular metal sheet, and foamed alloy return bend rear end and foam close Metal spoke is housed between the rear end of gold revolution cone, foamed alloy pipe rear end equipped with endless metal net by foamed alloy return bend and The spoke and annular metal sheet that the rear end of foamed alloy revolution cone is equipped with cover on the inside.Coal ash and straw ash are after foamed alloy pipe It holds the metal mesh being equipped with to drain in the lime-ash pipe that casing ends are equipped with, upper lime-ash electronic rotation dish valve and lower ash is housed in lime-ash pipe Slag electronic rotation dish valve.Hollow rotating shaft is then passed through the centre bore of annular metal sheet, annular after the centre bore of endless metal net Metal plate is fixed on hollow rotating shaft, and hollow rotating shaft back segment passes through the bearing of outer casing back.Hollow rotating shaft back segment is equipped with driven tooth It takes turns, the driving gear being equipped on driven gear and toothed gearing electric motor shaft engages.Hollow rotating shaft is fixed on by bearing block On three support frames, toothed gearing electric motor is fixed on third support frame, hollow rotating shaft rear end by silicone sealant circle with Combustion-supporting air hose is flexibly connected.Case nose is equipped with revolving top, and revolving top is by cloth drum, cloth plectane, cloth circle The cloth gear at the edge of plate, cloth motor, cloth motor output gear formed with outer elbow.The number of cloth drum bottom A circular hole is adapted with several circular holes on following cloth plectane, the edge of the output gear and cloth plectane of cloth motor The engagement of cloth gear.Outer elbow upper end is flexibly connected with cloth plectane, and the lower end of outer elbow is connect with foamed alloy pipe front end, outside Elbow upper end is fixed on case nose.Stalk Spiral extrusion conveyor is made of helical-blade, stalk drum and interior elbow.Helical-blade Protrude into stalk drum, the stalk drum of stalk Spiral extrusion conveyor passes through the cloth drum and cloth plectane of revolving top Middle centre bore, then stalk drum is fixedly connected with the upper end of interior elbow, and the lower end of interior elbow is sealed by Ceramic fiber blanket Circle and foamed alloy return bend front end active link.The stalk electricity being equipped on the filler tube that smashed stalk passes through stalk funnel Dynamic rotary valve drains in stalk chain transfer metal trough, and smashed stalk is transported to stalk spiral and squeezed by stalk chain transfer In the stalk drum for pressing conveyer, the helical-blade rotation of stalk Spiral extrusion conveyor conveys the stalk of crushing from stalk drum To interior elbow, subsequently into the gap between foamed alloy return bend and foamed alloy revolution cone.Coal dust passes through coal dust funnel Filler tube on the coal electronic rotation valve that is equipped with drain in the metal trough of coal chain transfer, coal chain transfer is by coal dust It is transported in the cloth drum of revolving top.The rotation of cloth motor, the output gear of cloth motor drive the rotation of cloth gear, To make cloth plectane rotate, when several circular holes of cloth drum bottom are aligned with several circular holes on following cloth plectane When, the coal dust in cloth drum passes through several circular holes of cloth drum bottom of alignment and several circular holes of cloth plectane drain to it is outer In gap between elbow and interior elbow, subsequently into the gap between foamed alloy pipe and foamed alloy return bend.Shell Fume pipe is housed at the top of leading portion, hydrogen-containing gas pipe is housed at the top of shell back segment, the shell by hydrogen-containing gas pipe is provided with temperature biography Sensor.Boiler, flue gas heater and air heater are sequentially arranged on hydrogen-containing gas pipe, hydrogen-containing gas sequentially passes through the heat of boiler Channel, the passage of heat of flue gas heater and air heater the passage of heat.The wind of air blower blowout passes through the cold of air heater Channel enters combustion-supporting air hose using motorized adjustment air-valve, and combustion-supporting air hose front end passes through silicone sealant circle and hollow rotating shaft rear end It is flexibly connected.The flue gas that flue gas suction ventilator generates foamed alloy bar leading portion is after fume pipe extraction by flue gas electric control valve It is then passed through the cold passage of flue gas heater, subsequently into the smoke nozzle that combustion air tube hub position is equipped with, is sprayed into hollow rotating shaft. Fresh water pump takes out the cold passage for entering boiler by motorized adjustment water valve after water from water tank, and the water vapour that boiler generates enters storage vapour Tank bobs up like a cork out from vapour storage tank and enters foamed alloy cone by electronic multidigit circulation reversal valve, pressure is housed on vapour storage tank Sensor.Outer casing back is equipped with liquefied petroleum gas burner and diesel fuel nozzle.Hydrogen-containing gas goes out from the passage of heat of air heater Come, then enters tilted tube devulcanizer by hydrogen-containing gas suction ventilator.The structure of tilted tube devulcanizer is as follows: tilted tube Devulcanizer is by inclination lime water pipe, inclination quick lime tube cell, calcium lime powder funnel, electronic rotation butterfly valve, lime water pump and lime Pond composition.Inclination lime water pipe and inclination quick lime tube cell are joined together to form the pipe tilted upward, limewash Pump above inclination limewash pipe end inclination lime water pipe is entered after the limewash extraction in lime pond, from inclination lime The limewash that the outlet pipe of water pipe front end comes out flows in lime pond.It tilts and is leaked above quick lime tube cell rear end equipped with calcium lime powder It struggles against, electronic rotation butterfly valve, the filler tube lower end of calcium lime powder funnel and inclination raw stone is housed on the filler tube of calcium lime powder funnel The connection of ash pipe rear end.Hydrogen-containing gas enters inclination lime water pipe from the front end of inclination lime water pipe, across there is lime water flowing By most of sulfur dioxide removal when tilting lime water pipe, it is then passed through moisture content after the oblique quick lime tube cell equipped with calcium lime powder With remaining sulfur dioxide removal.Or hydrogen-containing gas enters helical pipe devulcanizer by hydrogen-containing gas suction ventilator.Helix tube The structure of road devulcanizer is as follows: helical pipe devulcanizer by spiral lime water pipe, inclination quick lime tube cell, calcium lime powder funnel, Electronic rotation butterfly valve, lime water pump and lime pond composition.Spiral lime water pipe is the upward pipe of a spiral, tilts raw stone Grey tube cell is the pipe tilted upward, and the rear end of spiral lime water pipe and the front end of inclination quick lime tube cell are connected to one It rises, enters spiral lime water pipe above spiral limewash pipe end after the limewash extraction in lime pump handle lime pond, The limewash come out from the outlet pipe of spiral lime water pipe front end flows in lime pond.Tilt dress above quick lime tube cell rear end There is a calcium lime powder funnel, electronic rotation butterfly valve is housed on the filler tube of calcium lime powder funnel, under the filler tube of calcium lime powder funnel End is connected to inclination quick lime pipe rear end.Hydrogen-containing gas enters spiral lime water pipe from the front end of spiral lime water pipe, across having By most of sulfur dioxide removal when the spiral lime water pipe of lime water flowing, it is then passed through the oblique calcium lime powder equipped with calcium lime powder By moisture content and remaining sulfur dioxide removal after pipe.From tilted tube devulcanizer or the calcium lime powder of screwed pipe road rotation devulcanizer Pipe come out hydrogen-containing gas successively pass through compression condensation exclusion device first order compressor compression through first order check valve into Enter the cooling removal vapor of first order cooling tank, condensed water is discharged from the electromagnetic water valve opened that is powered；It is removed by compression condensation Removing carbon dioxide, liquid are removed in the cooling that the compression of the high stage compressor of miscellaneous device enters second level cooling tank through second level check valve State carbon dioxide is discharged from the electromagnetism carbon dioxide valve opened that is powered；By the third level compressor of compression condensation exclusion device Compression enters the cooling removal carbon monoxide of third level cooling tank through third level check valve, and liquid CO is opened from energization The discharge of electromagnetism carbon monoxide valve；Compression by the fourth stage compressor of compression condensation exclusion device enters through fourth stage check valve The cooling removal nitrogen of fourth stage cooling tank, liquid nitrogen are discharged from the electromagnetism nitrogen valve opened that is powered；Hydrogen is from fourth stage cooling tank Out.
Using this structure high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment use process is as follows: the stalk of chopping is put into straw Stalk funnel, the stalk electronic rotation valve being equipped on the filler tube of stalk funnel are powered rotation, and crushing straw drains to the conveying of stalk chain In machine metal trough, stalk chain transfer will be transported to broken stalk in the stalk drum of stalk Spiral extrusion conveyor.Stalk spiral The motor for squeezing conveyer drives helical-blade to rotate in stalk drum, and the crushing straw in stalk drum enters along interior elbow In gap between foamed alloy return bend and foamed alloy revolution cone.Coal dust is put into coal dust funnel, in coal dust funnel Coal dust is drained in the metal trough of coal chain transfer by the coal electronic rotation valve that rotation has that is powered, and coal chain transfer will Coal dust is transported in the cloth drum of revolving top.The output gear of the rotation of cloth motor, cloth motor drives cloth gear Rotation, so that cloth plectane is rotated, several circular holes on the several circular holes and following cloth plectane of cloth drum bottom When alignment, the coal dust in cloth drum passes through several circular holes leakage of the several circular holes and cloth plectane of the cloth drum bottom of alignment To in the gap between outer elbow and interior elbow, subsequently into the gap between foamed alloy pipe and foamed alloy return bend. Toothed gearing electric motor, which is powered, to be rotated, and is equipped on the driving gear drive hollow rotating shaft being equipped in toothed gearing electric motor shaft driven Gear rotation.Hollow rotating shaft rotation drives foamed alloy return bend and foamed alloy revolution cone rotation, makes foamed alloy return bend It is filled with crushing straw in gap between foamed alloy revolution cone, makes the sky between foamed alloy pipe and foamed alloy return bend Coal dust is filled in gap.Diesel oil from the diesel oil pipe of outer casing back be sprayed onto foamed alloy pipe and foamed alloy return bend rear end it Between gap in coal dust on foamed alloy return bend and foamed alloy revolution cone rear end between gap in crushing straw on. The igniting of start-up burner that outer casing back is equipped with, the flame that start-up burner generates will be sprayed with the foamed alloy pipe rear end of diesel oil with Coal dust in gap and foamed alloy return bend rear end and foamed alloy revolution cone rear end between foamed alloy return bend rear end Between gap in crushing straw light.The wind-powered electricity generation that the wind of air blower blowout passes through the cold passage of air heater moves adjusting air valve Into combustion-supporting air hose, it then is blown into foamed alloy revolution cone from hollow rotating shaft, foamed alloy revolution cone is passed through and supports foamed alloy The crushing straw burning in gap, generation hydrogen, carbon monoxide and vapor between return bend and foamed alloy revolution cone.One oxygen Change carbon and generate vanadium dioxide with vanadic anhydride generation chemical reaction when passing through foamed alloy return bend back segment, vapor is being worn Chemical reaction occurs with vanadium dioxide when crossing foamed alloy return bend back segment and generates vanadic anhydride and hydrogen；Remaining air is worn Coal dust in the gap crossed between foamed alloy return bend support foamed alloy pipe and foamed alloy return bend smoulders, generates hydrogen And carbon monoxide, carbon monoxide occur chemical reaction with vanadic anhydride when passing through foamed alloy cone and generate vanadium dioxide.Cigarette The flue gas that foamed alloy bar leading portion generates is then passed through flue gas by flue gas electric control valve after fume pipe extraction by gas suction ventilator The cold passage of heater, subsequently into the smoke nozzle that combustion air tube hub position is equipped with, the cigarette containing carbon monoxide and vapor Gas blowout enters in hollow rotating shaft.Fresh water pump takes out the cold passage for entering boiler by motorized adjustment water valve after water from water tank, and boiler produces Raw water vapour enters vapour storage tank.Computer controller adjusts motorized adjustment according to the data for the pressure sensor being equipped on vapour storage tank Water valve controls the inflow of boiler.The vapor recurrence come out from vapour storage tank enters foam by electronic multidigit circulation reversal valve Alloy cone, vapor pass through and generate vanadic anhydride and hydrogen with vanadium dioxide generation chemical reaction when foamed alloy is bored.One oxygen Change to occur to chemically react with vanadic anhydride when carbon passes through foamed alloy pipe back segment and generate vanadium dioxide, vapor is closed across foam Chemical reaction occurs with vanadium dioxide when golden pipe back segment and generates vanadic anhydride and hydrogen；After hydrogen-containing gas enters hydrogen-containing gas pipe Sequentially pass through the passage of heat of the passage of heat of boiler, the passage of heat of flue gas heater and air heater.Hydrogen-containing gas adds from air The passage of heat of hot device by hydrogen-containing gas suction ventilator enters tilted tube devulcanizer after coming out.In lime pump handle lime pond Enter inclination lime water pipe after limewash extraction above inclination limewash pipe end, goes out from the outlet pipe of inclination lime water pipe front end The limewash come flows in lime pond.Calcium lime powder is put into calcium lime powder funnel, electronic rotation butterfly valve, which is powered, to be rotated, raw Pulverized limestone drains to inclination quick lime pipe rear end from the filler tube lower end of calcium lime powder funnel, then flows to along inclination quick lime pipe Tilt lime water pipe.Hydrogen-containing gas enters inclination lime water pipe from the front end of inclination lime water pipe, across there is lime water flowing By most of sulfur dioxide removal when tilting lime water pipe, it is then passed through moisture content after the oblique quick lime tube cell equipped with calcium lime powder With remaining sulfur dioxide removal.Or hydrogen-containing gas from the passage of heat of air heater come out after by hydrogen-containing gas suction ventilator Into helical pipe devulcanizer.In lime pump handle lime pond limewash extraction after above spiral limewash pipe end into Enter spiral lime water pipe, the limewash come out from the outlet pipe of spiral lime water pipe front end flows in lime pond.By calcium lime powder It is put into calcium lime powder funnel, electronic rotation butterfly valve, which is powered, to be rotated, and calcium lime powder is leaked from the filler tube lower end of calcium lime powder funnel To inclination quick lime pipe rear end, spiral lime water pipe then is flowed to along inclination quick lime pipe.Hydrogen-containing gas is from spiral limewash The front end of pipe enters spiral lime water pipe, takes off most of sulfur dioxide when across the spiral lime water pipe for having lime water flowing It removes, is then passed through moisture content and remaining sulfur dioxide removal after the oblique quick lime tube cell equipped with calcium lime powder.From tilted tube The hydrogen-containing gas that the quick lime tube cell of devulcanizer or helical pipe devulcanizer comes out successively passes through compression condensation exclusion device The compression of first order compressor enters the cooling removal vapor of first order cooling tank through first order check valve, and condensed water is from energization The electromagnetic water valve of opening is discharged；Compression by the high stage compressor of compression condensation exclusion device enters through second level check valve Removing carbon dioxide is removed in the cooling of second level cooling tank, and liquid carbon dioxide is discharged from the electromagnetism carbon dioxide valve opened that is powered；Through The cooling that the compression of the third level compressor of overcompression condensation exclusion device enters third level cooling tank through third level check valve is gone Except carbon monoxide, liquid CO is discharged from the electromagnetism carbon monoxide valve opened that is powered；By compression condensation exclusion device The compression of fourth stage compressor enters the cooling removal nitrogen of fourth stage cooling tank through fourth stage check valve, and liquid nitrogen is beaten from being powered The electromagnetism nitrogen valve discharge opened；Hydrogen comes out from fourth stage cooling tank.The gold that coal ash and straw ash are equipped with from foamed alloy pipe rear end Belong to net to drain in the lime-ash pipe that casing ends are equipped with, then sequentially passes through the upper lime-ash electronic rotation dish valve and lower ash opened in turn Slag electronic rotation dish valve is fallen to the ground.
High temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention is by high temperature vanadium dioxide catalytic water gas shift device, inclination devulcanizer Or spiral devulcanizer and compression condensation exclusion device form.High temperature vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body It is successively shell, foamed alloy pipe, foamed alloy cone, foamed alloy return bend and foamed alloy revolution cone composition from outside to inside. The front is high and the back is low is mounted on first support frame and second support frame for furnace body.It is equipped between foamed alloy pipe front end and shell First metal partion (metp), between foamed alloy pipe middle section and shell be equipped with second metal partion (metp), the back segment of foamed alloy pipe with Third metal partion (metp) is housed between shell.The leading inside of foam compo pipe is equipped with multiple idler wheels, and idler wheel is pressed in foamed alloy and returns On the endless metal track of tube front end outer side section.Multiple foamed alloys cone rear end is fixed on outer casing back, foamed alloy bore to It is preceding to be protruded into after metal mesh in the gap bubble alloy porcelain tube and foamed alloy return bend.Contain five oxygen in foamed alloy cone Change two vanadium catalysts, the back segment of foamed alloy pipe contains vanadium pentoxide catalyst, and the back segment of foamed alloy return bend contains five V 2 O catalyst.The rear end of foamed alloy revolution cone is equipped with annular metal sheet, and foamed alloy return bend rear end and foam close Metal spoke is housed between the rear end of gold revolution cone, foamed alloy pipe rear end equipped with endless metal net by foamed alloy return bend and The spoke and annular metal sheet that the rear end of foamed alloy revolution cone is equipped with cover on the inside.Coal ash and straw ash are after foamed alloy pipe It holds the metal mesh being equipped with to drain in the lime-ash pipe that casing ends are equipped with, upper lime-ash electronic rotation dish valve and lower ash is housed in lime-ash pipe Slag electronic rotation dish valve.Hollow rotating shaft is then passed through the centre bore of annular metal sheet, annular after the centre bore of endless metal net Metal plate is fixed on hollow rotating shaft, and hollow rotating shaft back segment passes through the bearing of outer casing back.Hollow rotating shaft back segment is equipped with driven tooth It takes turns, the driving gear being equipped on driven gear and toothed gearing electric motor shaft engages.Hollow rotating shaft is fixed on by bearing block On three support frames, toothed gearing electric motor is fixed on third support frame, hollow rotating shaft rear end by silicone sealant circle with Combustion-supporting air hose is flexibly connected.Case nose is equipped with revolving top, and revolving top is by cloth drum, cloth plectane, cloth circle The cloth gear at the edge of plate, cloth motor, cloth motor output gear formed with outer elbow.The number of cloth drum bottom A circular hole is adapted with several circular holes on following cloth plectane, the edge of the output gear and cloth plectane of cloth motor The engagement of cloth gear.Outer elbow upper end is flexibly connected with cloth plectane, and the lower end of outer elbow is connect with foamed alloy pipe front end, outside Elbow upper end is fixed on case nose.The coal electronic rotation valve being equipped on the filler tube that coal dust passes through coal dust funnel drains to coal In the metal trough of chain transfer, coal dust is transported in the cloth drum of revolving top by coal chain transfer.Cloth motor Rotation, the output gear of cloth motor drives the rotation of cloth gear, to make cloth plectane rotate, when the number of cloth drum bottom When a circular hole is aligned with several circular holes on following cloth plectane, the coal dust in cloth drum passes through the cloth drum bottom of alignment Several circular holes in portion and several circular holes of cloth plectane drain to excurvation in front, turn round subsequently into foamed alloy pipe and foamed alloy In gap between pipe and foamed alloy revolution cone.Fume pipe is housed at the top of shell leading portion, hydrogen is housed at the top of shell back segment Body pipe, the shell by hydrogen-containing gas pipe are provided with temperature sensor.Be sequentially arranged on hydrogen-containing gas pipe boiler, flue gas heater and Air heater, the heat that hydrogen-containing gas sequentially passes through the passage of heat of boiler, the passage of heat of flue gas heater and air heater are logical Road.The cold passage that the wind of air blower blowout passes through air heater enters combustion-supporting air hose, combustion air using motorized adjustment air-valve Pipe front end is connect by silicone sealant circle with hollow rotating shaft back end activity.Flue gas suction ventilator generates foamed alloy bar leading portion Flue gas is then passed through the cold passage of flue gas heater after fume pipe extraction by flue gas electric control valve, subsequently into combustion-supporting air hose The smoke nozzle that center is equipped with sprays into hollow rotating shaft.Fresh water pump is taken out from water tank to be entered after water by motorized adjustment water valve The cold passage of boiler, the water vapour that boiler generates enter vapour storage tank.It comes out to bob up like a cork from vapour storage tank and be recycled by electronic multidigit Reversal valve enters foamed alloy cone, and pressure sensor is housed on vapour storage tank.Outer casing back is equipped with liquefied petroleum gas burner and bavin Oil burner nozzle.Hydrogen-containing gas comes out from the passage of heat of air heater, and it is de- then to enter tilted tube by hydrogen-containing gas suction ventilator Sulphur device.The structure of tilted tube devulcanizer is as follows: tilted tube devulcanizer is by inclination lime water pipe, inclination quick lime tube cell, life Pulverized limestone funnel, electronic rotation butterfly valve, lime water pump and lime pond composition.It tilts lime water pipe and inclination quick lime tube cell connects It is connected together to form the pipe tilted upward, from inclination limewash after the limewash extraction in lime pump handle lime pond Enter inclination lime water pipe above pipe end, the limewash come out from the outlet pipe of inclination lime water pipe front end flows to lime pond In.It tilts and calcium lime powder funnel is housed above quick lime tube cell rear end, electronic rotation is housed on the filler tube of calcium lime powder funnel The filler tube lower end of butterfly valve, calcium lime powder funnel is connected to inclination quick lime pipe rear end.Hydrogen-containing gas is from inclination lime water pipe Front end enters inclination lime water pipe, by most of sulfur dioxide removal when across the inclination lime water pipe for having lime water flowing, then By moisture content and remaining sulfur dioxide removal after the oblique quick lime tube cell equipped with calcium lime powder.Or hydrogen-containing gas passes through Hydrogen-containing gas suction ventilator enters helical pipe devulcanizer.The structure of helical pipe devulcanizer is as follows: helical pipe devulcanizer is by spiral shell Revolve lime water pipe, inclination quick lime tube cell, calcium lime powder funnel, electronic rotation butterfly valve, lime water pump and lime pond composition.Spiral shell Revolving lime water pipe is the upward pipe of a spiral, and inclination quick lime tube cell is the pipe tilted upward, spiral limewash The rear end of pipe and the front end for tilting quick lime tube cell link together, after the extraction of limewash in lime pump handle lime pond from Enter spiral lime water pipe above spiral limewash pipe end, the lime water flow come out from the outlet pipe of spiral lime water pipe front end To in lime pond.It tilts and calcium lime powder funnel is housed above quick lime tube cell rear end, filled on the filler tube of calcium lime powder funnel There is electronic rotation butterfly valve, the filler tube lower end of calcium lime powder funnel is connected to inclination quick lime pipe rear end.Hydrogen-containing gas is from spiral The front end of lime water pipe enters spiral lime water pipe, by most of titanium dioxide when across the spiral lime water pipe for having lime water flowing Sulphur removing, is then passed through moisture content and remaining sulfur dioxide removal after the oblique quick lime tube cell equipped with calcium lime powder.From inclination The hydrogen-containing gas that the quick lime tube cell of pipeline devulcanizer or screwed pipe road rotation devulcanizer comes out successively passes through compression condensation removal of impurities dress The compression for the first order compressor set enters the cooling removal vapor of first order cooling tank through first order check valve, condensed water from Be powered the electromagnetic water valve discharge opened；By compression condensation exclusion device high stage compressor compression through second level check valve Removing carbon dioxide is removed in cooling into second level cooling tank, and liquid carbon dioxide is arranged from the electromagnetism carbon dioxide valve opened that is powered Out；Compression by the third level compressor of compression condensation exclusion device enters the cold of third level cooling tank through third level check valve But carbon monoxide is removed, liquid CO is discharged from the electromagnetism carbon monoxide valve opened that is powered；It cleans and fills by compression condensation The compression for the fourth stage compressor set enters the cooling removal nitrogen of fourth stage cooling tank through fourth stage check valve, and liquid nitrogen is from logical The electromagnetism nitrogen valve discharge that electricity is opened；Hydrogen comes out from fourth stage cooling tank.
Using this structure high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment use process is as follows: coal dust is put into coal dust funnel In, the coal dust in coal dust funnel is drained in the metal trough of coal chain transfer by the coal electronic rotation valve that rotation has that is powered, Coal dust is transported in the cloth drum of revolving top by coal chain transfer.The rotation of cloth motor, the output of cloth motor Gear drives the rotation of cloth gear, to make cloth plectane rotate, when the several circular holes and following cloth of cloth drum bottom When several circular holes on plectane are aligned, the coal dust in cloth drum passes through the several circular holes and cloth of the cloth drum bottom of alignment Several circular holes of plectane drain to excurvation in front, bore subsequently into foamed alloy pipe and the revolution of foamed alloy return bend and foamed alloy Between gap in.Toothed gearing electric motor, which is powered, to be rotated, and the driving gear being equipped in toothed gearing electric motor shaft drives hollow turn The driven gear rotation being equipped on axis, hollow rotating shaft rotation drive foamed alloy return bend and foamed alloy revolution cone rotation, make Coal dust is filled in gap between foamed alloy pipe and foamed alloy return bend and foamed alloy revolution cone.Diesel oil is after shell The diesel oil pipe at end is sprayed onto the gap between foamed alloy pipe and foamed alloy return bend and foamed alloy revolution cone rear end Coal dust on.The start-up burner igniting that outer casing back is equipped with, the flame that start-up burner generates close the foam for being sprayed with diesel oil The coal dust in gap between golden pipe rear end and foamed alloy return bend and foamed alloy revolution cone rear end.The wind of air blower blowout Adjusting air valve is moved across the wind-powered electricity generation of the cold passage of air heater and enters combustion-supporting air hose, is then blown into foamed alloy from hollow rotating shaft Revolution cone turns round cone across foamed alloy and supports foamed alloy pipe and foamed alloy return bend and foamed alloy revolution cone Coal dust in gap smoulders, generates hydrogen and carbon monoxide, and carbon monoxide is sent out when passing through foamed alloy cone with vanadic anhydride Biochemical reaction generates vanadium dioxide.The flue gas that flue gas suction ventilator generates foamed alloy bar leading portion from fume pipe extraction after by Flue gas electric control valve is then passed through the cold passage of flue gas heater, subsequently into the smoke nozzle that combustion air tube hub position is equipped with, It is sprayed into hollow rotating shaft containing the flue gas of carbon monoxide and vapor；High-temperature flue gas passes through the passage of heat and sky of boiler on fume pipe It is sucked out after the passage of heat of hot-air heater by smoking blower.Fresh water pump is taken out from water tank enters boiler by motorized adjustment water valve after water Cold passage, boiler generate water vapour enter storage vapour., computer controller is according to the number of the pressure sensor being equipped on vapour storage tank According to motorized adjustment water valve is adjusted, the inflow of boiler is controlled.The vapor recurrence come out from vapour storage tank is recycled by electronic multidigit Reversal valve enters foamed alloy cone, and vapor passes through and generates five oxidations two with vanadium dioxide generation chemical reaction when foamed alloy is bored Vanadium and hydrogen.Chemical reaction occurs with vanadic anhydride when carbon monoxide passes through foamed alloy pipe back segment and generates vanadium dioxide, water Chemical reaction occurs with vanadium dioxide when steam passes through foamed alloy pipe back segment and generates vanadic anhydride and hydrogen.Hydrogen-containing gas into The passage of heat for entering to sequentially pass through after hydrogen-containing gas pipe the passage of heat of boiler, the passage of heat of flue gas heater and air heater, contains Hydrogen by hydrogen-containing gas suction ventilator enters tilted tube devulcanizer after coming out from the passage of heat of air heater.Lime water pump Inclination lime water pipe is entered above inclination limewash pipe end after the limewash extraction in lime pond, from inclination limewash The limewash that the outlet pipe of pipe front end comes out flows in lime pond.Calcium lime powder is put into calcium lime powder funnel, electronic rotation Turn butterfly valve energization rotation, calcium lime powder drains to inclination quick lime pipe rear end from the filler tube lower end of calcium lime powder funnel, then suitable Inclination quick lime pipe flow to inclination lime water pipe.Hydrogen-containing gas enters inclination lime water pipe from the front end of inclination lime water pipe, By most of sulfur dioxide removal when across the inclination lime water pipe for having lime water flowing, it is then passed through the oblique life equipped with calcium lime powder By moisture content and remaining sulfur dioxide removal after lime tube cell.Or hydrogen-containing gas from the passage of heat of air heater come out after Enter helical pipe devulcanizer by hydrogen-containing gas suction ventilator.From spiral after limewash extraction in lime pump handle lime pond Enter spiral lime water pipe above limewash pipe end, the limewash come out from the outlet pipe of spiral lime water pipe front end flows to stone In grey pond.Calcium lime powder is put into calcium lime powder funnel, electronic rotation butterfly valve is powered rotation, and calcium lime powder is from calcium lime powder The filler tube lower end of funnel drains to inclination quick lime pipe rear end, then flows to spiral lime water pipe along inclination quick lime pipe.Contain Hydrogen enters spiral lime water pipe from the front end of spiral lime water pipe, will when across the spiral lime water pipe for having lime water flowing Most of sulfur dioxide removal is then passed through moisture content and remaining sulfur dioxide after the oblique quick lime tube cell equipped with calcium lime powder Removing.The hydrogen-containing gas come out from the quick lime tube cell of tilted tube devulcanizer or helical pipe devulcanizer is successively through overcompression The cooling that the compression for condensing the first order compressor of exclusion device enters first order cooling tank through first order check valve goes water removal to steam Gas, condensed water are discharged from the electromagnetic water valve opened that is powered；By the compression warp of the high stage compressor of compression condensation exclusion device Removing carbon dioxide, electromagnetism two of the liquid carbon dioxide from the opening that is powered are removed in the cooling that second level check valve enters second level cooling tank The discharge of carbonoxide valve；Compression by the third level compressor of compression condensation exclusion device enters the third level through third level check valve The cooling removal carbon monoxide of cooling tank, liquid CO are discharged from the electromagnetism carbon monoxide valve opened that is powered；Through overcompression The compression for condensing the fourth stage compressor of exclusion device enters the cooling removal nitrogen of fourth stage cooling tank through fourth stage check valve, Liquid nitrogen is discharged from the electromagnetism nitrogen valve opened that is powered；Hydrogen comes out from fourth stage cooling tank.Coal ash is filled from foamed alloy pipe rear end Some metal meshes drain in the lime-ash pipe that casing ends are equipped with, and then sequentially pass through the upper lime-ash electronic rotation dish valve opened in turn It is fallen to the ground with lower lime-ash electronic rotation dish valve.
The production method of the foamed alloy pipe of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment: with vinyl alcohol aqueous solution and setting ratio The iron alloy powder of example, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud indentation arcuate die in, after dry Taking out from arcuate die becomes alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, oxygen Change aluminium refractory raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry after from arcuate die Middle take out becomes foamed alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, five oxidations two Vanadium powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry after from Taking out in arcuate die, which becomes the foam containing vanadic anhydride, closes arc gold blank watt.Alloy arc blank watt, foam are closed Golden arc blank watt and containing vanadic anhydride foamed alloy arc blank watt drying, the alloy arc blank after drying Watt, foamed alloy arc blank watt and containing vanadic anhydride foamed alloy arc blank watt baking be put into trolley, then small Alloy arc shaped tile, foamed alloy arc shaped tile are sintered at 1200 DEG C~1400 DEG C in vehicle push-in tunnel oven and contain vanadic anhydride Foamed alloy arc shaped tile.The frame that a foamed alloy pipe is welded with angle steel, is embedded in foamed alloy pipe for alloy arc shaped tile Frame front end and and end, foamed alloy arc shaped tile is embedded in leading portion and the middle section of the frame of foamed alloy pipe, will be contained The foamed alloy watt of vanadic anhydride is embedded in the frame of foamed alloy pipe and section, alloy arc shaped tile, foamed alloy arc Watt and the foamed alloy arc shaped tile containing vanadic anhydride be embedded on the frame of foamed alloy pipe after just become foamed alloy Pipe.
The production method of the foamed alloy cone of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment: with vinyl alcohol aqueous solution and setting ratio The iron alloy powder of example, coal dust, vanadium pentoxide powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal In powder mud indentation taper die, leave that tail portion is a bit of vacant, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, oxidation Aluminium refractory raw material and at iron powder mud, with and good iron powder mud indentation taper die tail portion, it is dry after from taper die Taking out becomes the foamed alloy taper blank watt containing vanadic anhydride.The foamed alloy taper blank containing vanadic anhydride Watt drying, the foamed alloy taper blank watt containing vanadic anhydride after drying is put into trolley, trolley is then pushed into tunnel It is bored in road kiln in 1200 DEG C~1400 DEG C foamed alloys sintered into containing vanadic anhydride.
The production method of the foamed alloy return bend of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment: with vinyl alcohol aqueous solution with set The iron alloy powder of certainty ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud indentation arcuate die in, do Taking out from arcuate die after dry becomes alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal Powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry after from arc Taking out in mold becomes foamed alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, five oxygen Change two vanadium powders, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry Taking out from arcuate die afterwards, which becomes the foam containing vanadic anhydride, closes arc gold blank watt.Alloy arc blank watt, bubble Foam alloy arc blank watt and containing vanadic anhydride foamed alloy arc blank watt drying, the alloy bracket-hairs after drying Base watt, foamed alloy arc blank watt and containing vanadic anhydride foamed alloy arc blank watt baking be put into trolley, then Sinter alloy arc shaped tile, foamed alloy arc shaped tile in trolley push-in tunnel oven at 1200 DEG C~1400 DEG C and containing five oxidations two The foamed alloy arc shaped tile of vanadium.The frame that a foamed alloy return bend is welded with angle steel, is embedded in foam for alloy arc shaped tile The front end of the frame of alloy return bend and and end, foamed alloy arc shaped tile is embedded in the leading portion of the frame of foamed alloy return bend And middle section, the foamed alloy watt containing vanadic anhydride is embedded in the frame of foamed alloy return bend and section, alloy arc Shape watt, foamed alloy arc shaped tile and the foamed alloy arc shaped tile containing vanadic anhydride are embedded in the frame of foamed alloy return bend Just become foamed alloy return bend after upper.
High temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment foamed alloy revolution cone production method: with vinyl alcohol aqueous solution with set The iron alloy powder of certainty ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud indentation arcuate die in, do Taking out from arcuate die after dry becomes alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal Powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry after from arc Foamed alloy arc blank watt is taken out in mold, with and good iron coal dust mud indentation taper die in, it is dry after from taper die Middle take out becomes foamed alloy taper blank watt.Alloy arc blank watt, foamed alloy arc blank watt and foamed alloy are bored Shape blank watt drying, alloy arc blank watt, foamed alloy arc blank watt and the foamed alloy taper blank watt after drying Baking is put into trolley, and then trolley is pushed into tunnel oven and sinters alloy arc shaped tile, foamed alloy arc at 1200 DEG C~1400 DEG C Shape watt and foamed alloy taper watt.The frame that a foamed alloy revolution cone is welded with angle steel, is embedded in bubble for alloy arc shaped tile Foamed alloy arc shaped tile is embedded in the middle section of the frame of foamed alloy revolution cone with after by the rear end of the frame of foam alloy revolution cone Foamed alloy taper watt is embedded in the leading portion of the frame of foamed alloy revolution cone, alloy arc shaped tile, foamed alloy arc by section Watt and foamed alloy taper watt be embedded in foamed alloy cone frame on after just become foamed alloy revolution cone (4).
Detailed description of the invention:
Further specific detailed description is done to the present invention with reference to the accompanying drawings and detailed description.
Fig. 1 is equipped with inclination devulcanizer and is set using the high temperature vanadium dioxide catalyzing manufacturing of hydrogen of the present invention of stalk and Pulverized Coal Standby structural schematic diagram.
Fig. 2 is equipped with spiral and takes off the high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention that device uses stalk and Pulverized Coal The structural schematic diagram of device.
Fig. 3 is the toothed gearing electric motor of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention and the Section A-A of bearing block Schematic diagram.
Fig. 4 is the section B-B schematic diagram of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Fig. 5 is the C-C schematic cross-section of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Fig. 6 is the D-D schematic cross-section of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Fig. 7 is equipped with inclination devulcanizer and uses the knot of the high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention of Pulverized Coal Structure schematic diagram.
Fig. 8 is equipped with spiral and takes off the knot that device uses the high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment device of the present invention of Pulverized Coal Structure schematic diagram.
Fig. 9 is the toothed gearing electric motor of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention and the section E-E of bearing block Schematic diagram.
Figure 10 is the F-F schematic cross-section of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Figure 11 is the G-G schematic cross-section of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Figure 12 is the H-H schematic cross-section of the furnace body of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention.
Specific embodiment:
Shown in Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5 and Fig. 6, high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention is by high temperature dioxy Change vanadium catalytic water gas shift device, tilted tube devulcanizer or helical pipe devulcanizer and compression condensation exclusion device composition.It is high Warm vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body is successively shell 1, foamed alloy pipe 2, foamed alloy from outside to inside 4 composition of cone 5, foamed alloy return bend 3 and foamed alloy revolution cone.The front is high and the back is low is mounted on first 10 He of support frame for furnace body On second support frame 10.First metal partion (metp), 2 middle section of foamed alloy pipe are housed between 2 front end of foamed alloy pipe and shell 1 Second metal partion (metp) is housed between shell 1, third metal partion (metp) is housed between the back segment and shell 1 of foamed alloy pipe 2. The leading inside of foam compo pipe 2 is equipped with multiple idler wheels 9, and idler wheel 9 is pressed in the endless metal of 3 front end outer side section of foamed alloy return bend On track.Multiple foamed alloys bore 5 rear ends and are fixed on 1 rear end of shell, and foamed alloy cone 5 protrudes into bubble conjunction after advancing through metal mesh In gap between golden porcelain tube 2 and foamed alloy return bend 3.Contain vanadium pentoxide catalyst in foamed alloy cone 5, foam closes The back segment of golden pipe 2 contains vanadium pentoxide catalyst, and the back segment of foamed alloy return bend 3 contains vanadium pentoxide catalyst.Bubble The rear end of foam alloy revolution cone 4 is equipped with annular metal sheet 7, the rear end of 3 rear end of foamed alloy return bend and foamed alloy revolution cone 4 Between metal spoke 8 is housed, foamed alloy return bend 3 and foamed alloy are returned equipped with endless metal net in 2 rear end of foamed alloy pipe The spoke 8 that is equipped with of rear end and annular metal sheet 7 for turning cone 4 cover on the inside.Coal ash and straw ash are equipped with from 2 rear end of foamed alloy pipe Metal mesh drain in the lime-ash pipe that 1 end of shell is equipped with, in lime-ash pipe equipped with upper lime-ash electronic rotation dish valve and lower lime-ash electricity Dynamic rotation dish valve.Hollow rotating shaft 6 is then passed through the centre bore of annular metal sheet, endless metal after the centre bore of endless metal net Plate is fixed on hollow rotating shaft, and 6 back segment of hollow rotating shaft passes through the bearing of 1 rear end of shell.6 back segment of hollow rotating shaft is equipped with driven gear 38, the driving gear being equipped on driven gear 38 and 37 shaft of toothed gearing electric motor engages.Hollow rotating shaft 6 is solid by bearing block 36 It is scheduled on third support frame 10, toothed gearing electric motor 37 is fixed on third support frame 10.1 front end of shell is equipped with rotation cloth Glassware, revolving top is by cloth drum 20, cloth plectane, the cloth gear 23 at the edge of cloth plectane, cloth motor 22, cloth Expect the output gear of motor 22 and is formed with outer elbow 21.On several circular holes of 20 bottom of cloth drum and following cloth plectane Several circular holes be adapted, the output gear of cloth motor 22 is engaged with the cloth gear 23 at the edge of cloth plectane.Outer elbow Upper end is flexibly connected with cloth plectane, and the lower end of outer elbow 21 is connect with 2 front end of foamed alloy pipe, and outer 21 upper end of elbow is fixed on Case nose.Stalk Spiral extrusion conveyor is made of helical-blade 14, stalk drum 15 and interior elbow 16.Helical-blade 14 protrudes into straw Stalk drum 15, the stalk drum 15 of stalk Spiral extrusion conveyor pass through the cloth drum 20 and cloth plectane of revolving top Middle centre bore, then stalk drum is fixedly connected with the upper end of interior elbow 16, and the lower end of interior elbow 16 passes through Ceramic fiber blanket Sealing ring and 3 front end active link of foamed alloy return bend.It is equipped on the filler tube that smashed stalk passes through stalk funnel 11 Stalk electronic rotation valve 12 drain in 13 metal trough of stalk chain transfer, stalk chain transfer 13 is defeated by smashed stalk It is sent in the stalk drum 15 of stalk Spiral extrusion conveyor, the helical-blade 14 of stalk Spiral extrusion conveyor is rotated crushing Stalk is transported to interior elbow 16 from stalk drum 15, subsequently between foamed alloy return bend 3 and foamed alloy revolution cone 4 In gap.The coal electronic rotation valve 18 being equipped on the filler tube that coal dust passes through coal dust funnel 17 drains to coal chain transfer 19 Metal trough in, coal dust is transported in the cloth drum 20 of revolving top by coal chain transfer 19.Cloth motor 22 rotates, The output gear of cloth motor 22 drives cloth gear 23 to rotate, to make cloth plectane rotate, when 20 bottom of cloth drum When several circular holes are aligned with several circular holes on following cloth plectane, the coal dust in cloth drum 20 passes through the cloth circle of alignment The several circular holes and several circular holes of cloth plectane of bucket bottom drain in the gap between outer elbow 21 and interior elbow 16, then into Enter in the gap between foamed alloy pipe 2 and foamed alloy return bend 3.Fume pipe, 1 back segment of shell are housed at the top of 1 leading portion of shell Top is equipped with hydrogen-containing gas pipe, and the shell 1 by hydrogen-containing gas pipe is provided with temperature sensor.Pot is sequentially arranged on hydrogen-containing gas pipe Furnace 27, flue gas heater 32 and air heater 34, hydrogen-containing gas sequentially pass through the passage of heat of boiler 27, flue gas heater 32 The passage of heat of the passage of heat and air heater 34.The wind that air blower 33 is blown out passes through the cold passage of air heater 34 using electricity Dynamic adjusting air valve 35 enters combustion-supporting air hose, and combustion-supporting air hose front end is connect by silicone sealant circle with hollow rotating shaft back end activity. Flue gas suction ventilator 30 wears the flue gas that foamed alloy bar leading portion generates again after fume pipe extraction by flue gas electric control valve 31 The cold passage for crossing flue gas heater 32 sprays into hollow rotating shaft 6 subsequently into the smoke nozzle that combustion air tube hub position is equipped with. Fresh water pump 25 takes out the cold passage for entering boiler 27 by motorized adjustment water valve 26 after water from water tank 24, and the water that boiler 27 generates steams Vapour enters vapour storage tank 28, comes out to bob up like a cork from vapour storage tank 28 and bores 5 into foamed alloy by electronic multidigit circulation reversal valve 29, Pressure sensor is housed on vapour storage tank.1 rear end of shell is equipped with liquefied petroleum gas burner and diesel fuel nozzle.Hydrogen-containing gas is from air The passage of heat of heater 34 comes out, and then enters tilted tube devulcanizer by hydrogen-containing gas suction ventilator 39.Tilted tube desulfurization The structure of device is as follows: tilted tube devulcanizer by inclination lime water pipe 40, inclination quick lime tube cell 44, calcium lime powder funnel 45, Electronic rotation butterfly valve 46, lime water pump 42 and lime pond 41 form.It tilts lime water pipe 40 and inclination quick lime tube cell 44 connects Be connected together to form the pipe tilted upward, lime water pump 42 in lime pond 41 limewash extract out after from inclination stone Enter inclination lime water pipe 40 above grey 40 end of water pipe, the limewash come out from the outlet pipe 43 of inclination 40 front end of lime water pipe It flows in lime pond 41.It tilts and calcium lime powder funnel 45 is housed above 44 pipe rear end of calcium lime powder, calcium lime powder funnel 45 Electronic rotation butterfly valve 46 is housed, the filler tube lower end and inclination 44 rear end of quick lime pipe of calcium lime powder funnel 45 connect on filler tube It is logical.Hydrogen-containing gas enters inclination lime water pipe 40 from the front end of inclination lime water pipe 40, across the inclination stone for having lime water flowing By most of sulfur dioxide removal when grey water pipe 40, be then passed through moisture content after the oblique quick lime tube cell 44 equipped with calcium lime powder and Remaining sulfur dioxide removal.Or hydrogen-containing gas enters helical pipe devulcanizer by hydrogen-containing gas suction ventilator.Helical pipe The structure of devulcanizer is as follows: helical pipe devulcanizer is leaked by spiral lime water pipe 40 ', inclination quick lime tube cell 44, calcium lime powder Bucket 45, electronic rotation butterfly valve 46, lime water pump 42 and lime pond 41 form.Spiral lime water pipe 40 ' is that a spiral is upward Pipe, inclination quick lime tube cell 44 is the pipe tilted upward, the rear end of spiral lime water pipe 40 ' and inclination quick lime The front end of tube cell 44 links together, lime water pump 42 limewash in lime pond 41 is extracted out after from spiral lime water pipe Enter spiral lime water pipe 40 ' above 40 ' ends, the lime water flow come out from the outlet pipe 43 of 40 ' front end of spiral lime water pipe To in lime pond 41.It tilts and calcium lime powder funnel 45, the leakage of calcium lime powder funnel 45 is housed above 44 rear end of quick lime tube cell Electronic rotation butterfly valve 46 is housed, the filler tube lower end of calcium lime powder funnel 45 is connected to inclination 44 rear end of quick lime pipe on bucket pipe. Hydrogen-containing gas enters spiral lime water pipe 40 ' from the front end of spiral lime water pipe 40 ', across the spiral lime for having lime water flowing By most of sulfur dioxide removal when water pipe 40 ', be then passed through moisture content after the oblique quick lime tube cell 44 equipped with calcium lime powder and Remaining sulfur dioxide removal.The hydrogen come out from the quick lime tube cell of tilted tube devulcanizer or screwed pipe road rotation devulcanizer The compression that body successively passes through the first order compressor 47 of compression condensation exclusion device enters first order cooling through first order check valve The cooling removal vapor of tank 48, condensed water are discharged from the electromagnetic water valve 49 opened that is powered；By compression condensation exclusion device Removing carbon dioxide, liquid two are gone in the cooling that the compression of high stage compressor 50 enters second level cooling tank 51 through second level check valve Carbonoxide is discharged from the electromagnetism carbon dioxide valve 52 opened that is powered；By the third level compressor 53 of compression condensation exclusion device Compression enters the cooling removal carbon monoxide of third level cooling tank 54 through third level check valve, and liquid CO is opened from being powered Electromagnetism carbon monoxide valve 55 be discharged；Compression by the fourth stage compressor 56 of compression condensation exclusion device is unidirectional through the fourth stage Valve enters the cooling removal nitrogen of fourth stage cooling tank 57, and liquid nitrogen is discharged from the electromagnetism nitrogen valve 58 opened that is powered；Hydrogen is from Level Four cooling tank 57 comes out.
Shown in Fig. 1, Fig. 2, Fig. 3, Fig. 4, Fig. 5 and Fig. 6, made using the high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of this structure It is as follows with process: the stalk of chopping to be put into stalk funnel 11, the stalk electronic rotation valve being equipped on the filler tube of stalk funnel 12, which are powered, rotates, and crushing straw drains in 13 metal trough of stalk chain transfer, and broken stalk will be transported to straw by stalk chain transfer 13 In the stalk drum 15 of stalk Spiral extrusion conveyor.The motor of stalk Spiral extrusion conveyor drives helical-blade 14 in stalk circle 15 inner rotations of bucket, the crushing straw in stalk drum 15 enters foamed alloy return bend 3 along interior elbow 16 and foamed alloy turns round In gap between cone 4.Coal dust is put into coal dust funnel 17, the coal that the coal dust in coal dust funnel 17 has by the rotation that is powered Electronic rotation valve 18 drains in the metal trough of coal chain transfer 19, and coal dust is transported to rotation cloth by coal chain transfer 19 In the cloth drum 20 of device.The output gear of the rotation of cloth motor, cloth motor 22 drives cloth gear 23 to rotate, to make cloth Expect plectane rotation, when several circular holes of 20 bottom of cloth drum are aligned with several circular holes on following cloth plectane, cloth Coal dust in drum 20 passes through several circular holes of 20 bottom of cloth drum of alignment and several circular holes of cloth plectane drain to excurvation In gap between first 21 and interior elbow 16, subsequently into the gap between foamed alloy pipe 2 and foamed alloy return bend 3. Toothed gearing electric motor 37, which is powered, to be rotated, and the driving gear being equipped in 37 shaft of toothed gearing electric motor drives and is equipped on hollow rotating shaft 6 Driven gear 38 rotate.The rotation of hollow rotating shaft 6 drives 4 rotation of foamed alloy return bend 3 and foamed alloy revolution cone, makes foam It is filled with crushing straw in gap between alloy return bend 3 and foamed alloy revolution cone 4, makes foamed alloy pipe 2 and foamed alloy Coal dust is filled in gap between return bend 3.Diesel oil is sprayed onto foamed alloy pipe 2 and bubble from the diesel oil pipe of 1 rear end of shell On the coal dust in gap between 3 rear end of foam alloy return bend and foamed alloy return bend 3 and foamed alloy revolution cone 4 rear ends it Between gap in crushing straw on.The start-up burner igniting that 1 rear end of shell is equipped with, the flame that start-up burner generates will be sprayed with The coal dust and foamed alloy return bend 3 in gap between 3 rear end of 2 rear end of foamed alloy pipe and foamed alloy return bend of diesel oil The crushing straw in gap between 4 rear ends of rear end and foamed alloy revolution cone is lighted.The wind that air blower 33 is blown out adds across air The wind-powered electricity generation of the cold passage of hot device 34 moves adjusting air valve 35 and enters combustion-supporting air hose, is then blown into foamed alloy revolution from hollow rotating shaft 6 Cone 4, the broken straw in the gap that foamed alloy revolution cone 4 is supported foamed alloy return bend 3 and foamed alloy revolution cone 4 Stalk burning generates hydrogen, carbon monoxide and vapor, and carbon monoxide is aoxidized when passing through 3 back segment of foamed alloy return bend with five Two vanadium occur chemical reaction and generate vanadium dioxide, and vapor occurs when passing through 3 back segment of foamed alloy return bend with vanadium dioxide Chemical reaction generates vanadic anhydride and hydrogen；Remaining air passes through foamed alloy return bend 3 and supports foamed alloy pipe 2 and bubble The coal dust in gap between foam alloy return bend 3 smoulders, generates hydrogen and carbon monoxide, and carbon monoxide is passing through foamed alloy Chemical reaction occurs with vanadic anhydride when boring 5 and generates vanadium dioxide.Flue gas suction ventilator 30 generates foamed alloy bar leading portion Flue gas is then passed through the cold passage of flue gas heater 32 after fume pipe extraction by flue gas electric control valve 31, subsequently into combustion-supporting The smoke nozzle that air hose center is equipped with sprays into hollow rotating shaft 6 containing the flue gas of carbon monoxide and vapor.Fresh water pump 25 from Water tank 24 takes out the cold passage for entering boiler 27 by motorized adjustment water valve 26 after water, and the water vapour that boiler 27 generates enters storage vapour Tank 26.Computer controller adjusts motorized adjustment water valve 26 according to the data for the pressure sensor being equipped on vapour storage tank 28, controls pot The inflow of furnace 27.The vapor recurrence come out from vapour storage tank 28 enters foamed alloy by electronic multidigit circulation reversal valve 29 and bores 5, chemical reaction occurs with vanadium dioxide when vapor passes through foamed alloy cone 5 and generates vanadic anhydride and hydrogen.Carbon monoxide Chemical reaction occurs with vanadic anhydride when across foamed alloy 2 back segment of pipe and generates vanadium dioxide, vapor passes through foamed alloy Chemical reaction occurs with vanadium dioxide when 2 back segment of pipe and generates vanadic anhydride and hydrogen.After hydrogen-containing gas enters hydrogen-containing gas pipe Sequentially pass through the passage of heat of the passage of heat of boiler 27, the passage of heat of flue gas heater 32 and air heater 34, hydrogen-containing gas from The passage of heat of air heater 34 come out after by hydrogen-containing gas suction ventilator 39 enter tilted tube devulcanizer.42, lime water pump Enter inclination lime water pipe 40 above inclination 40 end of lime water pipe after limewash extraction in lime pond 41, from inclination stone The limewash that the outlet pipe 43 of grey 40 front end of water pipe comes out flows in lime pond 41.Calcium lime powder is put into calcium lime powder funnel In 45, electronic rotation butterfly valve 46, which is powered, to be rotated, and calcium lime powder drains to the raw stone of inclination from the filler tube lower end of calcium lime powder funnel 45 Then 44 rear end of ash pipe flows to inclination lime water pipe 40 along inclination quick lime pipe 44.Hydrogen-containing gas from inclination lime water pipe 40 Front end enter inclination lime water pipe 40, most of sulfur dioxide is taken off when across the inclination lime water pipe 40 for having lime water flowing It removes, is then passed through moisture content and remaining sulfur dioxide removal after the oblique quick lime tube cell 44 equipped with calcium lime powder.Or it is hydrogeneous Gas from the passage of heat of air heater 34 come out after by hydrogen-containing gas suction ventilator 39 enter helical pipe devulcanizer.Limewash Pump 42 enters spiral lime water pipe 40 ' after the limewash in lime pond 41 is extracted out above 40 ' end of spiral lime water pipe, The limewash come out from the outlet pipe 43 of 40 ' front end of spiral lime water pipe flows in lime pond 41.Calcium lime powder is put into life In pulverized limestone funnel 45, electronic rotation butterfly valve 46, which is powered, to be rotated, and calcium lime powder is leaked from the filler tube lower end of calcium lime powder funnel 45 To inclination 44 rear end of quick lime pipe, spiral lime water pipe 40 ' then is flowed to along inclination quick lime pipe.Hydrogen-containing gas is from spiral stone The front end of grey water pipe 40 ' enters spiral lime water pipe 40 ', by big portion when across spiral lime water pipe 40 ' for having lime water flowing Divide sulfur dioxide removal, takes off moisture content and remaining sulfur dioxide after being then passed through the oblique quick lime tube cell 44 equipped with calcium lime powder It removes.The hydrogen-containing gas come out from the inclination quick lime tube cell 44 of tilted tube devulcanizer or helical pipe devulcanizer successively passes through The compression of the first order compressor 47 of compression condensation exclusion device enters the cooling of first order cooling tank 48 through first order check valve Vapor is removed, condensed water is discharged from the electromagnetic water valve 49 opened that is powered；It is compressed by the second level of compression condensation exclusion device Removing carbon dioxide is removed in the cooling that the compression of machine 50 enters second level cooling tank 51 through second level check valve, and liquid carbon dioxide is from logical The electromagnetism carbon dioxide valve 52 that electricity is opened is discharged；By compression condensation exclusion device third level compressor 53 compression through third Grade check valve enters the cooling removal carbon monoxide of third level cooling tank 54, electromagnetism one oxygen of the liquid CO from the opening that is powered Change carbon valve 55 to be discharged；Compression by the fourth stage compressor 56 of compression condensation exclusion device enters the 4th through fourth stage check valve The cooling removal nitrogen of grade cooling tank 57, liquid nitrogen are discharged from the electromagnetism nitrogen valve 58 opened that is powered；Hydrogen is from fourth stage cooling tank 57 come out；Further compression and condensation hydrogen can obtain liquified hydrogen.Coal ash and straw ash are equipped with from 2 rear end of foamed alloy pipe Metal mesh drain in the lime-ash pipe that 1 end of shell is equipped with, then sequentially pass through the upper lime-ash electronic rotation dish valve opened in turn It is fallen to the ground with lower lime-ash electronic rotation dish valve.
Shown in Fig. 7, Fig. 8, Fig. 9, Figure 10, Figure 11 and Figure 12, high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment of the present invention is by high temperature Vanadium dioxide catalytic water gas shift device, tilted tube devulcanizer or helical pipe devulcanizer and compression condensation exclusion device group At.High temperature vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body is successively shell 1, foamed alloy pipe 2, bubble from outside to inside 4 composition of foam alloy cone 5, foamed alloy return bend 3 and foamed alloy revolution cone.The front is high and the back is low is mounted on first support for furnace body On frame 10 and second support frame 10.First metal partion (metp), foamed alloy are housed between 2 front end of foamed alloy pipe and shell 1 Second metal partion (metp) is housed, equipped with third gold between the back segment and shell 1 of foamed alloy pipe 2 between 2 middle section of pipe and shell 1 Belong to partition.The leading inside of foam compo pipe 2 is equipped with multiple idler wheels 9, and idler wheel 9 is pressed in 3 front end outer side section of foamed alloy return bend On endless metal track.Multiple foamed alloys bore 5 rear ends and are fixed on 1 rear end of shell, after foamed alloy cone 5 advances through metal mesh It protrudes into the gap between bubble alloy porcelain tube 2 and foamed alloy return bend 3.It is catalyzed in foamed alloy cone 5 containing vanadic anhydride Agent, the back segment of foamed alloy pipe 2 contain vanadium pentoxide catalyst, and the back segment of foamed alloy return bend 3 contains vanadic anhydride Catalyst.The rear end of foamed alloy revolution cone 4 is equipped with annular metal sheet 7, and 3 rear end of foamed alloy return bend and foamed alloy turn round Metal spoke 8 is housed, 2 rear end of foamed alloy pipe by foamed alloy return bend 3 and is steeped equipped with endless metal net between the rear end of cone 4 The spoke 8 and annular metal sheet 7 that the rear end of foam alloy revolution cone 4 is equipped with cover on the inside.Coal ash and straw ash are from foamed alloy pipe 2 The metal mesh that rear end is equipped with drains in the lime-ash pipe that 1 end of shell is equipped with, in lime-ash pipe equipped with upper lime-ash electronic rotation dish valve and Lower lime-ash electronic rotation dish valve.Hollow rotating shaft 6 is then passed through the centre bore of annular metal sheet after the centre bore of endless metal net, Annular metal sheet is fixed on hollow rotating shaft, and 6 back segment of hollow rotating shaft passes through the bearing of 1 rear end of shell.6 back segment of hollow rotating shaft is equipped with The driving gear being equipped in driven gear 38, driven gear 38 and 37 shaft of toothed gearing electric motor engages.Hollow rotating shaft 6 passes through axis It holds seat 36 to be fixed on third support frame 10, toothed gearing electric motor 37 is fixed on third support frame 10.1 front end of shell dress Have a revolving top, revolving top by cloth drum 20, cloth plectane, cloth plectane edge cloth gear 23, cloth Motor 22, cloth motor 22 output gear with outer elbow 21 form.Several circular holes of 20 bottom of cloth drum and following Several circular holes on cloth plectane are adapted, and the output gear of cloth motor 22 is nibbled with the cloth gear 23 at the edge of cloth plectane It closes.Outer elbow upper end is flexibly connected with cloth plectane, and the lower end of outer elbow 21 is connect with 2 front end of foamed alloy pipe, outer elbow 21 Upper end is fixed on case nose.The coal electronic rotation valve 18 being equipped on the filler tube that coal dust passes through coal dust funnel 17 drains to coal In the metal trough of chain transfer 19, coal dust is transported in the cloth drum 20 of revolving top by coal chain transfer 19.Cloth Expect that motor 22 rotates, the output gear of cloth motor 22 drives cloth gear 23 to rotate, so that cloth plectane be made to rotate, works as cloth When several circular holes of 20 bottom of drum are aligned with several circular holes on following cloth plectane, the coal dust in cloth drum 20 is passed through The several circular holes of 20 bottom of cloth drum and several circular holes of cloth plectane of alignment drain in outer elbow 21, subsequently into foam In gap between compo pipe 2 and foamed alloy return bend 3 and foamed alloy revolution cone 4.Flue gas is housed at the top of 1 leading portion of shell Pipe, 1 back segment of shell top are equipped with hydrogen-containing gas pipe, and the shell 1 by hydrogen-containing gas pipe is provided with temperature sensor.Hydrogen-containing gas pipe On be sequentially arranged with boiler 27, flue gas heater 32 and air heater 34, hydrogen-containing gas sequentially passes through the passage of heat of boiler 27, cigarette The passage of heat of hot-air heater 32 and the passage of heat of air heater 34.The wind that air blower 33 is blown out passes through the cold of air heater 34 Channel enters combustion-supporting air hose using motorized adjustment air-valve 35, after combustion-supporting air hose front end is by silicone sealant circle and hollow rotating shaft End is flexibly connected.The flue gas that flue gas suction ventilator 30 generates foamed alloy bar leading portion is after fume pipe extraction by flue gas electric adjustable Section valve 31 is then passed through the cold passage of flue gas heater 32, subsequently into the smoke nozzle that combustion air tube hub position is equipped with, sprays into empty In heart shaft 6.Fresh water pump 25 takes out the cold passage for entering boiler 27 by motorized adjustment water valve 26 after water, boiler 27 from water tank 24 The water vapour of generation enters vapour storage tank 28, comes out to bob up like a cork to enter by electronic multidigit circulation reversal valve 29 from vapour storage tank 28 and steep Foam alloy bores 5, and pressure sensor is housed on vapour storage tank.1 rear end of shell is equipped with liquefied petroleum gas burner and diesel fuel nozzle.It is hydrogeneous Gas comes out from the passage of heat of air heater 34, then enters tilted tube devulcanizer by hydrogen-containing gas suction ventilator 39.Incline The structure of inclined tube road devulcanizer is as follows: tilted tube devulcanizer is by inclination lime water pipe 40, inclination quick lime tube cell 44, quick lime Powder funnel 45, electronic rotation butterfly valve 46, lime water pump 42 and lime pond 41 form.Tilt lime water pipe 40 and inclination quick lime Tube cell 44 is joined together to form the pipe tilted upward, after lime water pump 42 extracts the limewash in lime pond 41 out Enter inclination lime water pipe 40 above inclination 40 end of lime water pipe, is come out from the outlet pipe 43 of inclination 40 front end of lime water pipe Limewash flow in lime pond 41.It tilts and calcium lime powder funnel 45, calcium lime powder is housed above 44 pipe rear end of calcium lime powder Electronic rotation butterfly valve 46, the filler tube lower end of calcium lime powder funnel 45 and inclination quick lime pipe 44 are housed on the filler tube of funnel 45 Rear end connection.Hydrogen-containing gas enters inclination lime water pipe 40 from the front end of inclination lime water pipe 40, across there is lime water flowing By most of sulfur dioxide removal when tilting lime water pipe 40, incited somebody to action after being then passed through the oblique quick lime tube cell 44 equipped with calcium lime powder Moisture content and remaining sulfur dioxide removal.Or hydrogen-containing gas enters helical pipe devulcanizer by hydrogen-containing gas suction ventilator.Spiral shell The structure of coil road devulcanizer is as follows: helical pipe devulcanizer is by spiral lime water pipe 40 ', inclination quick lime tube cell 44, raw stone Ashes funnel 45, electronic rotation butterfly valve 46, lime water pump 42 and lime pond 41 form.Spiral lime water pipe 40 ' is a spiral shell The pipe spun up, inclination quick lime tube cell 44 is the pipe tilted upward, the rear end of spiral lime water pipe 40 ' and inclination The front end of quick lime tube cell 44 links together, lime water pump 42 limewash in lime pond 41 is extracted out after from spiral lime Enter spiral lime water pipe 40 ' above 40 ' end of water pipe, the lime come out from the outlet pipe 43 of 40 ' front end of spiral lime water pipe Water flows in lime pond 41.It tilts and calcium lime powder funnel 45, calcium lime powder funnel 45 is housed above 44 rear end of quick lime tube cell Filler tube on electronic rotation butterfly valve 46 is housed, the filler tube lower end of calcium lime powder funnel 45 and inclination 44 rear end of quick lime pipe connect It is logical.Hydrogen-containing gas enters spiral lime water pipe 40 ' from the front end of spiral lime water pipe 40 ', across the spiral for having lime water flowing By most of sulfur dioxide removal when lime water pipe 40 ', it is then passed through water after the oblique quick lime tube cell 44 equipped with calcium lime powder Part and remaining sulfur dioxide removal.Contain from what the quick lime tube cell of tilted tube devulcanizer or screwed pipe road rotation devulcanizer came out The compression that hydrogen successively passes through the first order compressor 47 of compression condensation exclusion device enters the first order through first order check valve The cooling removal vapor of cooling tank 48, condensed water are discharged from the electromagnetic water valve 49 opened that is powered；It cleans and fills by compression condensation Removing carbon dioxide, liquid are removed in the cooling that the compression for the high stage compressor 50 set enters second level cooling tank 51 through second level check valve State carbon dioxide is discharged from the electromagnetism carbon dioxide valve 52 opened that is powered；By the third level compressor of compression condensation exclusion device 53 compression enters the cooling removal carbon monoxide of third level cooling tank 54 through third level check valve, and liquid CO is from energization The electromagnetism carbon monoxide valve 55 of opening is discharged；By compression condensation exclusion device fourth stage compressor 56 compression through the fourth stage Check valve enters the cooling removal nitrogen of fourth stage cooling tank 57, and liquid nitrogen is discharged from the electromagnetism nitrogen valve 58 opened that is powered；Hydrogen It is come out from fourth stage cooling tank 57.
Shown in Fig. 7, Fig. 8, Fig. 9, Figure 10, Figure 11 and Figure 12, set using the high temperature vanadium dioxide catalyzing manufacturing of hydrogen of this structure It is standby use process is as follows: coal dust is put into coal dust funnel 17, the coal dust in coal dust funnel 17 passes through the coal that has of rotation that is powered Electronic rotation valve 18 drains in the metal trough of coal chain transfer 19, and coal dust is transported to rotation cloth by coal chain transfer 19 In the cloth drum 20 of device.The output gear of the rotation of cloth motor, cloth motor 22 drives cloth gear 23 to rotate, to make cloth Expect plectane rotation, when several circular holes of 20 bottom of cloth drum are aligned with several circular holes on following cloth plectane, cloth Coal dust in drum 20 passes through several circular holes of 20 bottom of cloth drum of alignment and several circular holes of cloth plectane drain to excurvation In first 21, subsequently into the gap between foamed alloy pipe 2 and foamed alloy return bend 3 and foamed alloy revolution cone 4.Gear Decelerating motor 37, which is powered, to be rotated, and is equipped on the driving gear drive hollow rotating shaft being equipped in 37 shaft of toothed gearing electric motor driven Gear 38 rotates.The rotation of hollow rotating shaft 6 drives 4 rotation of foamed alloy return bend 3 and foamed alloy revolution cone, makes foamed alloy pipe Coal dust is filled in gap between 2 and foamed alloy return bend 3 and foamed alloy revolution cone 4.Bavin of the diesel oil from outer casing back Oil pipe is sprayed onto the sky between 2 rear end of foamed alloy pipe and 3 rear end of foamed alloy return bend and 4 rear ends of foamed alloy revolution cone On coal dust in gap.The start-up burner igniting that 1 rear end of shell is equipped with, the flame that start-up burner generates will be sprayed with the bubble of diesel oil The coal powder point in gap between 2 rear end of foam compo pipe and 3 rear end of foamed alloy return bend and 4 rear ends of foamed alloy revolution cone Combustion.The wind-powered electricity generation that the wind that air blower 33 is blown out passes through the cold passage of air heater 34 moves adjusting air valve 35 and enters combustion-supporting air hose, so It is blown into foamed alloy revolution cone 4 from hollow rotating shaft 6 afterwards, foamed alloy revolution cone 4 is passed through and supports foamed alloy return bend 3 and foam The broken coal dust firing in gap between alloy revolution cone 4, generates hydrogen, carbon monoxide；Remaining air passes through foamed alloy Return bend 3 supports the coal dust in the gap between foamed alloy pipe 2 and foamed alloy return bend 3 to smoulder, generate hydrogen and an oxygen Change carbon, carbon monoxide occurs chemical reaction with vanadic anhydride when passing through foamed alloy cone 5 and generates vanadium dioxide.Flue gas air draught The flue gas that foamed alloy bar leading portion generates is then passed through flue gas by flue gas electric control valve 31 after fume pipe extraction and added by machine 30 The cold passage of hot device 32, subsequently into the smoke nozzle that combustion air tube hub position is equipped with, the cigarette containing carbon monoxide and vapor Gas blowout enters in hollow rotating shaft 6.Fresh water pump 25 is taken out from water tank 24 enters the cold logical of boiler 27 by motorized adjustment water valve 26 after water Road, the water vapour that boiler 27 generates enter vapour storage tank 26.Computer controller is according to the pressure sensor being equipped on vapour storage tank 28 Data adjust motorized adjustment water valve 26, control the inflow of boiler 27.The vapor recurrence come out from vapour storage tank 28 is by electronic Multidigit recycles reversal valve 29 and enters foamed alloy cone 5, and vapor chemically reacts when passing through foamed alloy cone 5 with vanadium dioxide Generate vanadic anhydride and hydrogen.Chemical reaction life occurs when carbon monoxide passes through 2 back segment of foamed alloy pipe with vanadic anhydride Occur at vanadium dioxide, when vapor passes through 2 back segment of foamed alloy pipe with vanadium dioxide chemical reaction generate vanadic anhydride and Hydrogen；Hydrogen-containing gas sequentially passes through the passage of heat of boiler 27, the passage of heat and sky of flue gas heater 32 after entering hydrogen-containing gas pipe The passage of heat of hot-air heater 34.Hydrogen-containing gas from the passage of heat of air heater 34 come out after by hydrogen-containing gas suction ventilator 39 into Enter tilted tube devulcanizer.Lime water pump 42 in lime pond 41 limewash extraction after from inclination 40 end of lime water pipe on Side enters inclination lime water pipe 40, and the limewash come out from the outlet pipe 43 of inclination 40 front end of lime water pipe flows to lime pond 41 In.Calcium lime powder is put into calcium lime powder funnel 45, electronic rotation butterfly valve 46, which is powered, to be rotated, and calcium lime powder is leaked from calcium lime powder The filler tube lower end of bucket 45 drains to inclination 44 rear end of quick lime pipe, then flows to inclination lime water pipe along inclination quick lime pipe 44 40.Hydrogen-containing gas enters inclination lime water pipe 40 from the front end of inclination lime water pipe 40, across the inclination stone for having lime water flowing By most of sulfur dioxide removal when grey water pipe 40, be then passed through moisture content after the oblique quick lime tube cell 44 equipped with calcium lime powder and Remaining sulfur dioxide removal.Or hydrogen-containing gas from the passage of heat of air heater come out after by hydrogen-containing gas suction ventilator 39 Into helical pipe devulcanizer.Lime water pump 42 is last from spiral lime water pipe 40 ' after the limewash extraction in lime pond 41 End top enters spiral lime water pipe 40 ', and the limewash come out from the outlet pipe 43 of 40 ' front end of spiral lime water pipe flows to lime In pond 41.Calcium lime powder is put into calcium lime powder funnel 45, electronic rotation butterfly valve 46 is powered rotation, and calcium lime powder is from raw stone The filler tube lower end of ashes funnel 45 drains to inclination 44 rear end of quick lime pipe, then flows to spiral lime along inclination quick lime pipe Water pipe 40 '.Hydrogen-containing gas enters spiral lime water pipe 40 ' from the front end of spiral lime water pipe 40 ', across there is lime water flowing By most of sulfur dioxide removal when spiral lime water pipe 40 ', after being then passed through the oblique quick lime tube cell 44 equipped with calcium lime powder By moisture content and remaining sulfur dioxide removal.From tilted tube devulcanizer or the inclination quick lime tube cell of helical pipe devulcanizer 44 hydrogen-containing gas come out successively pass through the compression of the first order compressor 47 of compression condensation exclusion device through first order check valve Into the cooling removal vapor of first order cooling tank 48, condensed water is discharged from the electromagnetic water valve 49 opened that is powered；Through overcompression The compression for condensing the high stage compressor 50 of exclusion device enters the cooling of second level cooling tank 51 through second level check valve and removes Carbon dioxide, liquid carbon dioxide are discharged from the electromagnetism carbon dioxide valve 52 opened that is powered；By compression condensation exclusion device The compression of third level compressor 53 enters the cooling removal carbon monoxide of third level cooling tank 54, liquid one through third level check valve Carbonoxide is discharged from the electromagnetism carbon monoxide valve 55 opened that is powered；By the fourth stage compressor 56 of compression condensation exclusion device Compression enters the cooling removal nitrogen of fourth stage cooling tank 57, electromagnetism nitrogen valve of the liquid nitrogen from the opening that is powered through fourth stage check valve 58 discharges；Hydrogen comes out from fourth stage cooling tank 57；Further compression and condensation hydrogen can obtain liquified hydrogen.Coal ash and straw Then stalk ash sequentially passes through in turn in the lime-ash pipe that the metal mesh that 2 rear end of foamed alloy pipe is equipped with drains to that 1 end of shell is equipped with The upper lime-ash electronic rotation dish valve and lower lime-ash electronic rotation dish valve opened are fallen to the ground.
Shown in Fig. 1, Fig. 2, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, Figure 10, Figure 11 and Figure 12, high temperature vanadium dioxide catalyzing manufacturing of hydrogen The production method of the foamed alloy pipe of equipment: with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, alumina setter ceramics Raw material and at iron powder mud, with and good iron powder mud indentation arcuate die in, taking out from arcuate die after dry becomes alloy arc Shape blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, alumina setter ceramic raw material and at iron coal dust Mud, with and good iron coal dust mud indentation arcuate die in, taking out from arcuate die after dry becomes foamed alloy arc blank Watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, vanadium pentoxide powder, alumina setter ceramic raw material With at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, take out to become from arcuate die after dry and contain five The foam of V 2 O closes arc gold blank watt.Alloy arc blank watt, foamed alloy arc blank watt and contain five oxidations The foamed alloy arc blanks watt of two vanadium is dried, after drying alloy arc blank watt, foamed alloy arc blank watt and contain Have vanadic anhydride foamed alloy arc blank watt baking be put into trolley, then trolley push-in tunnel oven in 1200 DEG C~ 1400 DEG C sinter alloy arc shaped tile, foamed alloy arc shaped tile and the foamed alloy arc shaped tile containing vanadic anhydride into.Use angle steel The frame for welding a foamed alloy pipe, by alloy arc shaped tile be embedded in the frame of foamed alloy pipe front end and and end, will steep Foam alloy arc shaped tile is embedded in leading portion and the middle section of the frame of foamed alloy pipe, and the foamed alloy watt containing vanadic anhydride is inlayed Embedded in foamed alloy pipe frame and section, alloy arc shaped tile, foamed alloy arc shaped tile and contain the foam of vanadic anhydride Alloy arc shaped tile just becomes foamed alloy pipe 2 after being embedded on the frame of foamed alloy pipe.
Shown in Fig. 1, Fig. 2, Fig. 4, Fig. 5, Fig. 7, Fig. 8, Figure 10 and Figure 11, the foam of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment The production method of alloy cone: with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, vanadium pentoxide powder, oxidation Aluminium refractory raw material and at iron coal dust mud, with and good iron coal dust mud indentation taper die in, to leave tail portion a bit of vacant, With vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder Mud is pressed into the tail portion of taper die, and taking out from taper die after dry becomes the foamed alloy taper hair containing vanadic anhydride Base watt；The foamed alloy taper blank watt drying containing vanadic anhydride, the foam containing vanadic anhydride after drying Alloy taper blank watt is put into trolley, and then trolley is pushed into tunnel oven and is sintered at 1200 DEG C~1400 DEG C containing five oxidations The foamed alloy cone 5 of two vanadium.
Shown in Fig. 1, Fig. 2, Fig. 4, Fig. 5, Fig. 6, Fig. 7, Fig. 8, Figure 10, Figure 11 and Figure 12, high temperature vanadium dioxide catalyzing manufacturing of hydrogen The production method of the foamed alloy return bend of equipment: with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, alumina setter Ceramic raw material and at iron powder mud, with and good iron powder mud indentation arcuate die in, take out to become from arcuate die after dry and close Golden arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, alumina setter ceramic raw material and at iron Coal dust mud, with and good iron coal dust mud indentation arcuate die in, taking out from arcuate die after dry becomes foamed alloy arc Blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, coal dust, vanadium pentoxide powder, alumina setter ceramics Raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, take out to become from arcuate die after dry and contain There is the foam of vanadic anhydride to close arc gold blank watt.Alloy arc blank watt, foamed alloy arc blank watt and contain five The foamed alloy arc blank watt of V 2 O is dried, alloy arc blank watt, the foamed alloy arc blank watt after drying It is put into trolley with the foamed alloy arc blank watt baking containing vanadic anhydride, then trolley is pushed into tunnel oven at 1200 DEG C ~1400 DEG C sinter alloy arc shaped tile, foamed alloy arc shaped tile and the foamed alloy arc shaped tile containing vanadic anhydride into.Use angle Steel weld a foamed alloy return bend frame, by alloy arc shaped tile be embedded in the frame of foamed alloy return bend front end and And end, foamed alloy arc shaped tile is embedded in leading portion and the middle section of the frame of foamed alloy return bend, vanadic anhydride will be contained Foamed alloy watt be embedded in foamed alloy return bend frame and section, alloy arc shaped tile, foamed alloy arc shaped tile and contain It is just returned as foamed alloy after thering is the foamed alloy arc shaped tile of vanadic anhydride to be embedded on the frame of foamed alloy return bend Tube 3.
Shown in Fig. 1, Fig. 2, Fig. 5, Fig. 7, Fig. 8 and Figure 11, the foamed alloy of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment is turned round The production method of cone: with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, alumina setter ceramic raw material and at iron powder mud, It is pressed into arcuate die with good iron powder mud, taking out from arcuate die after dry becomes alloy arc blank watt, uses ethylene Alcohol solution and the iron alloy powder of setting ratio, coal dust, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal Powder mud is pressed into arcuate die, and foamed alloy arc blank watt is taken out from arcuate die after dry, with and good iron coal dust mud It is pressed into taper die, taking out from taper die after dry becomes foamed alloy taper blank watt.Alloy arc blank watt, Foamed alloy arc blank watt and foamed alloy taper blank watt are dried, alloy arc blank watt, the foamed alloy after drying Arc blank watt and the baking of foamed alloy taper blank watt are put into trolley, and then trolley is pushed into tunnel oven 1200 DEG C~1400 DEG C sinter alloy arc shaped tile, foamed alloy arc shaped tile and foamed alloy taper watt into.A foamed alloy revolution is welded with angle steel Alloy arc shaped tile is embedded in the rear end of the frame of foamed alloy revolution cone, foamed alloy arc shaped tile is embedded in by the frame of cone Foamed alloy taper watt is embedded in the frame of foamed alloy revolution cone by the middle section of the frame of foamed alloy revolution cone and back segment Leading portion, after alloy arc shaped tile, foamed alloy arc shaped tile and foamed alloy taper watt are embedded on the frame of foamed alloy cone Just become foamed alloy revolution cone 4.

Claims (6)

1. a kind of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment, it is characterised in that: high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment is by high temperature Vanadium dioxide catalytic water gas shift device, tilted tube devulcanizer or helical pipe devulcanizer and compression condensation exclusion device group At high temperature vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body is successively shell (1), foamed alloy pipe from outside to inside (2), foamed alloy cone (5), foamed alloy return bend (3) and foamed alloy revolution cone (4) composition, furnace body the front is high and the back is low ground install On first support frame (10) and second support frame (10)；First is equipped between foamed alloy pipe (2) front end and shell (1) A metal partion (metp) is equipped with second metal partion (metp), after foamed alloy pipe (2) between foamed alloy pipe (2) middle section and shell (1) Third metal partion (metp) is housed between section and shell (1)；The leading inside of foam compo pipe (2) is equipped with multiple idler wheels (9), idler wheel (9) it is pressed on the endless metal track of foamed alloy return bend (3) front end outer side section, multiple foamed alloy cones (5) rear end is fixed In shell (1) rear end, foamed alloy cone (5) protrudes into bubble alloy porcelain tube () and foamed alloy return bend after advancing through metal mesh (3) in the gap between, (5) are inner contains vanadium pentoxide catalyst for foamed alloy cone, and the back segment of foamed alloy pipe (2) contains five The back segment of V 2 O catalyst, foamed alloy return bend (3) contains vanadium pentoxide catalyst；Foamed alloy revolution cone (4) Rear end be equipped with annular metal sheet (7), foamed alloy return bend (3) rear end and foamed alloy revolution bore (4) rear end between fill Have metal spoke (8), foamed alloy return bend (3) and foamed alloy are returned equipped with endless metal net in foamed alloy pipe (2) rear end Inside the spoke (8) that is equipped with of rear end and annular metal sheet (7) for turning cone (4) cover on, coal ash and straw ash are from foamed alloy pipe (2) The metal mesh that rear end is equipped with drains in the lime-ash pipe that shell (1) end is equipped with, and upper lime-ash electronic rotation dish valve is housed in lime-ash pipe With lower lime-ash electronic rotation dish valve；Hollow rotating shaft (6) is then passed through annular metal sheet (7) after the centre bore of endless metal net Centre bore, annular metal sheet (7) are fixed on hollow rotating shaft, and hollow rotating shaft (6) back segment passes through the bearing of shell (1) rear end, empty Heart shaft (6) back segment is equipped with driven gear (38), the active being equipped on driven gear (38) and toothed gearing electric motor (37) shaft Gear engagement, hollow rotating shaft (6) are fixed on third support frame (10) by bearing block (36), and toothed gearing electric motor (37) is solid It is scheduled on third support frame (10)；Shell (1) front end is equipped with revolving top, and revolving top is by cloth drum (20), cloth Expect plectane, the cloth gear (23) at the edge of cloth plectane, cloth motor (22), cloth motor (22) output gear with and outside Elbow (21) composition, several circular holes of cloth drum (20) bottom are adapted with several circular holes on following cloth plectane, cloth The output gear of material motor (22) is engaged with the cloth gear (23) at the edge of cloth plectane, outer elbow (21) upper end and cloth circle Plate is flexibly connected, and the lower end of outer elbow (21) is connect with foamed alloy pipe (2) front end, before outer elbow (21) upper end is fixed on shell End；Stalk Spiral extrusion conveyor is made of helical-blade (14), stalk drum (15) and interior elbow (16), and helical-blade (14) protrudes into Stalk drum (15), the stalk drum (15) of stalk Spiral extrusion conveyor pass through the cloth drum (20) and cloth of revolving top Expect the middle centre bore of plectane, then stalk drum (15) is fixedly connected with the upper end of interior elbow (16), the lower end of interior elbow (16) Pass through Ceramic fiber blanket sealing ring and foamed alloy return bend (3) front end active link；Smashed stalk is leaked by stalk The stalk electronic rotation valve (12) being equipped on the filler tube of bucket (11) drains in stalk chain transfer (13) metal trough, stalk chain The stalk drum (15) that smashed stalk is transported to stalk Spiral extrusion conveyor by conveyer (13) is inner, stalk screw extrusion The helical-blade (14) of conveyer, which is rotated, is transported to interior elbow (16) from stalk drum for the stalk of crushing, subsequently into foamed alloy In gap between return bend (3) and foamed alloy revolution cone (4)；It is equipped on the filler tube that coal dust passes through coal dust funnel (17) Coal electronic rotation valve (18) drains in the metal trough of coal chain transfer (19), and coal chain transfer (19) conveys coal dust Cloth drum (20) to revolving top is inner, and the output gear of cloth motor (22) rotation, cloth motor (22) drives cloth Gear (23) rotation, to make cloth plectane rotate, when on the several circular holes and following cloth plectane of cloth drum bottom When several circular holes are aligned, the inner coal dust of cloth drum (20) passes through the several circular holes and cloth plectane of the cloth drum bottom of alignment Several circular holes drain in the gap between outer elbow (21) and interior elbow (16), subsequently into foamed alloy pipe (2) and foam In gap between alloy return bend (3)；Fume pipe is housed at the top of shell (1) leading portion, hydrogen is housed at the top of shell (1) back segment Body pipe, the shell (1) by hydrogen-containing gas pipe are provided with temperature sensor, boiler (27), flue gas are sequentially arranged on hydrogen-containing gas pipe Heater (32) and air heater (34), hydrogen-containing gas sequentially pass through the passage of heat of boiler (27), flue gas heater (32) The wind of the passage of heat of the passage of heat and air heater (34), air blower (33) blowout passes through the cold passage of air heater (34) again Enter combustion-supporting air hose by motorized adjustment air-valve (35), after combustion-supporting air hose front end is by silicone sealant circle and hollow rotating shaft (6) End is flexibly connected；The flue gas that flue gas suction ventilator (30) generates foamed alloy pipe (2) section is after fume pipe extraction by flue gas electricity Dynamic regulating valve (31) are then passed through the cold passage of flue gas heater (32), the aerosol spraying being equipped with subsequently into combustion air tube hub position Pipe sprays into hollow rotating shaft (6)；Fresh water pump (25) is taken out from water tank (24) enters boiler by motorized adjustment water valve (26) after water (27) cold passage, boiler (27) generate water vapour enter vapour storage tank (28), from vapour storage tank (28) come out bob up like a cork by Electronic multidigit circulation reversal valve (29) enters foamed alloy cone (5), and pressure sensor is housed on vapour storage tank (28)；After shell (1) End is equipped with liquefied petroleum gas burner and diesel fuel nozzle；Hydrogen-containing gas comes out from the passage of heat of air heater (34), then passes through Hydrogen-containing gas suction ventilator (39) are crossed into tilted tube devulcanizer or helical pipe devulcanizer by sulfur dioxide removal, from inclination The hydrogen-containing gas that pipeline devulcanizer or helical pipe devulcanizer come out successively passes through the first order pressure of compression condensation exclusion device The compression of contracting machine (47) enters the cooling removal vapor of first order cooling tank (48) through first order check valve, and condensed water is from energization The electromagnetic water valve (49) of opening is discharged；Compression by the high stage compressor (50) of compression condensation exclusion device is single through the second level Removing carbon dioxide, electromagnetism titanium dioxide of the liquid carbon dioxide from the opening that is powered are gone in the cooling for entering second level cooling tank (51) to valve Carbon valve (52) discharge；Compression by the third level compressor (53) of compression condensation exclusion device enters the through third level check valve The cooling removal carbon monoxide of three-level cooling tank (54), liquid CO are arranged from the electromagnetism carbon monoxide valve (55) opened that is powered Out；Compression by the fourth stage compressor (56) of compression condensation exclusion device enters fourth stage cooling tank through fourth stage check valve (57) cooling removal nitrogen, liquid nitrogen are discharged from the electromagnetism nitrogen valve (58) opened that is powered；Hydrogen goes out from fourth stage cooling tank () Come.
2. a kind of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment, it is characterised in that: high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment is by high temperature Vanadium dioxide catalytic water gas shift device, tilted tube devulcanizer or helical pipe devulcanizer and compression condensation exclusion device group At high temperature vanadium dioxide catalytic water gas shift apparatus structure is as follows: furnace body is successively shell (1), foamed alloy pipe from outside to inside (2), foamed alloy cone (5), foamed alloy return bend (3) and foamed alloy revolution cone (4) composition, furnace body the front is high and the back is low ground install On first support frame (10) and second support frame (10)；First is equipped between foamed alloy pipe (2) front end and shell (1) A metal partion (metp) is equipped with second metal partion (metp), after foamed alloy pipe (2) between foamed alloy pipe (2) middle section and shell (1) Third metal partion (metp) is housed between section and shell (1)；The leading inside of foam compo pipe (2) is equipped with multiple idler wheels (9), idler wheel (9) it is pressed on the endless metal track of foamed alloy return bend (3) front end outer side section, multiple foamed alloy cones (5) rear end is fixed In shell (1) rear end, foamed alloy cone (5) protrudes into bubble alloy porcelain tube () and foamed alloy return bend after advancing through metal mesh (3) in the gap between, (5) are inner contains vanadium pentoxide catalyst for foamed alloy cone, and the back segment of foamed alloy pipe (2) contains five The back segment of V 2 O catalyst, foamed alloy return bend (3) contains vanadium pentoxide catalyst；Foamed alloy revolution cone (4) Rear end be equipped with annular metal sheet (7), foamed alloy return bend (3) rear end and foamed alloy revolution bore (4) rear end between fill Have metal spoke (9), foamed alloy return bend (3) and foamed alloy are returned equipped with endless metal net in foamed alloy pipe (2) rear end Inside the spoke (8) that is equipped with of rear end and annular metal sheet (7) for turning cone (4) cover on, coal ash and straw ash are from foamed alloy pipe (2) The metal mesh that rear end is equipped with drains in the lime-ash pipe that shell (1) end is equipped with, and upper lime-ash electronic rotation dish valve is housed in lime-ash pipe With lower lime-ash electronic rotation dish valve；Hollow rotating shaft (6) is then passed through in annular metal sheet after the centre bore of endless metal net Heart hole, annular metal sheet (7) are fixed on hollow rotating shaft, and hollow rotating shaft (6) back segment passes through the bearing of shell (1) rear end, hollow Shaft (6) back segment is equipped with driven gear, and the driving gear being equipped on driven gear (38) and toothed gearing electric motor (37) shaft is nibbled It closes, hollow rotating shaft (6) is fixed on third support frame (10) by bearing block (36), and toothed gearing electric motor (37) is fixed on the On three support frames (10)；Shell (1) front end be equipped with revolving top, revolving top by cloth drum (20), cloth plectane, The cloth gear (23) at the edge of cloth plectane, cloth motor (22), cloth motor (22) output gear with and outer elbow (21) it forms, several circular holes of cloth drum (20) bottom are adapted with several circular holes on following cloth plectane, cloth electricity The output gear of machine (22) is engaged with the cloth gear (23) at the edge of cloth plectane, and outer elbow (21) upper end and cloth plectane are living Dynamic connection, the lower end of outer elbow (21) is connect with foamed alloy pipe (2) front end, before outer elbow (21) upper end is fixed on shell (1) End；The coal electronic rotation valve (18) being equipped on the filler tube that coal dust passes through coal dust funnel (17) drains to coal chain transfer (19) in metal trough, the cloth drum (20) that coal dust is transported to revolving top by coal chain transfer (19) is inner, cloth electricity Machine rotation, the output gear of cloth motor (22) drives cloth gear (23) rotation, to make cloth plectane rotate, when cloth circle When several circular holes of bucket (20) bottom are aligned with several circular holes on following cloth plectane, the inner coal dust of cloth drum (20) is worn It is inner that the several circular holes of cloth drum (20) bottom and several circular holes of cloth plectane for crossing alignment drain to outer elbow (21), then into Enter in the gap between foamed alloy pipe (2) and foam alloy return bend (3) and foamed alloy revolution cone (4)；Shell (1) leading portion top Portion is equipped with fume pipe, and hydrogen-containing gas pipe is housed at the top of shell (1) back segment, and the shell (1) by hydrogen-containing gas pipe is provided with temperature biography Sensor is sequentially arranged with boiler (27), flue gas heater (32) and air heater (34) on hydrogen-containing gas pipe, and hydrogen-containing gas is successively Across the passage of heat of boiler (27), the passage of heat of the passage of heat of flue gas heater (32) and air heater (34), air blower (33) cold passage that the wind blown out passes through air heater (34) enters combustion-supporting air hose using motorized adjustment air-valve (35), combustion-supporting Air hose front end is connect by silicone sealant circle with hollow rotating shaft (6) back end activity；Flue gas suction ventilator (30) is by foamed alloy pipe (2) flue gas that leading portion generates is then passed through the cold of flue gas heater (32) by flue gas electric control valve (31) after fume pipe extraction Channel sprays into hollow rotating shaft (6) subsequently into the smoke nozzle that combustion air tube hub position is equipped with；Fresh water pump (25) is from water tank (24) cold passage for entering boiler (27) by motorized adjustment water valve (26) after water is taken out, the water vapour that boiler (27) generates enters Vapour storage tank (28) comes out to bob up like a cork from vapour storage tank (28) and bore by electronic multidigit circulation reversal valve (29) into foamed alloy (5), pressure sensor is housed on vapour storage tank (28)；Shell (1) rear end is equipped with liquefied petroleum gas burner and diesel fuel nozzle；It is hydrogeneous Gas comes out from the passage of heat of air heater, then by hydrogen-containing gas suction ventilator (39) enter tilted tube devulcanizer or Helical pipe devulcanizer is by sulfur dioxide removal, from the hydrogen-containing gas of tilted tube devulcanizer or helical pipe devulcanizer out It is cooling successively to enter the first order through first order check valve by the compression of the first order compressor (47) of compression condensation exclusion device The cooling removal vapor of tank (48), condensed water are discharged from the electromagnetic water valve (49) opened that is powered；It cleans and fills by compression condensation The compression for the high stage compressor (50) set enters the cooling removal titanium dioxide of second level cooling tank (51) through second level check valve Carbon, liquid carbon dioxide are discharged from the electromagnetism carbon dioxide valve (52) opened that is powered；By the third of compression condensation exclusion device The compression of grade compressor (53) enters the cooling removal carbon monoxide of third level cooling tank (54), liquid one through third level check valve Carbonoxide is discharged from the electromagnetism carbon monoxide valve (55) opened that is powered；By the fourth stage compressor of compression condensation exclusion device (56) compression enters the cooling removal nitrogen of fourth stage cooling tank (57) through fourth stage check valve, and liquid nitrogen is opened from energization Electromagnetism nitrogen valve (58) discharge；Hydrogen comes out from fourth stage cooling tank.
3. the production method of the foamed alloy pipe of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment, it is characterised in that: water-soluble with vinyl alcohol Liquid and the iron alloy powder of setting ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud be pressed into arc mould In tool, taking out from arcuate die after dry becomes alloy arc blank watt, is closed with vinyl alcohol aqueous solution and the iron of setting ratio Bronze, coal dust, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, it is dry Taking out from arcuate die afterwards becomes foamed alloy arc blank watt, with vinyl alcohol aqueous solution and the iron alloy powder of setting ratio, Coal dust, vanadium pentoxide powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud be pressed into arc mould In tool, taking out from arcuate die after dry, which becomes the foam containing vanadic anhydride, closes arc gold blank watt；Alloy arc Blank watt, foamed alloy arc blank watt and the foamed alloy arc blank watt drying containing vanadic anhydride, after drying Alloy arc blank watt, foamed alloy arc blank watt and the foamed alloy arc blank watt baking containing vanadic anhydride are put into small Then vehicle is pushed into trolley and sinters alloy arc shaped tile, foamed alloy arc shaped tile at 1200 DEG C~1400 DEG C in tunnel oven and contain There is the foamed alloy arc shaped tile of vanadic anhydride, the frame of a foamed alloy pipe is welded with angle steel, alloy arc shaped tile is inlayed The frame of foamed alloy pipe front end and and end, by foamed alloy arc shaped tile be embedded in the frame of foamed alloy pipe leading portion and Middle section, the foamed alloy watt containing vanadic anhydride is embedded in the frame of foamed alloy pipe and section, alloy arc shaped tile, bubble Foam alloy arc shaped tile and foamed alloy arc shaped tile containing vanadic anhydride be embedded on the frame of foamed alloy pipe after just at For foamed alloy pipe (2).
4. the production method that the foamed alloy of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment is bored, it is characterised in that: water-soluble with vinyl alcohol Liquid and the iron alloy powder of setting ratio, coal dust, vanadium pentoxide powder, alumina setter ceramic raw material and at iron coal dust mud, are used It is pressed into taper die with good iron coal dust mud, leaves that tail portion is a bit of vacant, with the iron of vinyl alcohol aqueous solution and setting ratio Alloyed powder, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud indentation taper die tail portion, it is dry after from Taking out in taper die becomes the foamed alloy taper blank watt containing vanadic anhydride；Foam containing vanadic anhydride is closed The foamed alloy taper blank watt containing vanadic anhydride after drying, is put into trolley by the drying of golden taper blank watt, then Trolley, which is pushed into tunnel oven, bores (5) in 1200 DEG C~1400 DEG C foamed alloys sintered into containing vanadic anhydride.
5. the production method of the foamed alloy return bend of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment, it is characterised in that: use vinyl alcohol Aqueous solution and the iron alloy powder of setting ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud be pressed into arc In shape mold, taking out from arcuate die after dry becomes alloy arc blank watt, with vinyl alcohol aqueous solution and setting ratio Iron alloy powder, coal dust, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, Taking out from arcuate die after drying becomes foamed alloy arc blank watt, with the ferroalloy of vinyl alcohol aqueous solution and setting ratio Powder, coal dust, vanadium pentoxide powder, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud be pressed into arc In shape mold, taking out from arcuate die after dry, which becomes the foam containing vanadic anhydride, closes arc gold blank watt；Alloy Arc blank watt, foamed alloy arc blank watt and the foamed alloy arc blank watt drying containing vanadic anhydride, drying Alloy arc blank watt, foamed alloy arc blank watt and the foamed alloy arc blank watt baking containing vanadic anhydride afterwards is put Enter trolley, then trolley is pushed into tunnel oven and sinters alloy arc shaped tile, foamed alloy arc shaped tile at 1200 DEG C~1400 DEG C With the foamed alloy arc shaped tile containing vanadic anhydride, the frame of a foamed alloy return bend is welded with angle steel, by alloy arc Shape watt be embedded in the frame of foamed alloy return bend front end and and end, by foamed alloy arc shaped tile be embedded in foamed alloy revolution Foamed alloy watt containing vanadic anhydride is embedded in the frame of foamed alloy return bend by the leading portion of the frame of pipe and middle section And section, alloy arc shaped tile, foamed alloy arc shaped tile and foamed alloy arc shaped tile containing vanadic anhydride are embedded in foam and closed Just become foamed alloy return bend (3) after on the frame of golden return bend.
6. the production method of the foamed alloy revolution cone of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment, it is characterised in that: use vinyl alcohol Aqueous solution and the iron alloy powder of setting ratio, alumina setter ceramic raw material and at iron powder mud, with and good iron powder mud be pressed into arc In shape mold, taking out from arcuate die after dry becomes alloy arc blank watt, with vinyl alcohol aqueous solution and setting ratio Iron alloy powder, coal dust, alumina setter ceramic raw material and at iron coal dust mud, with and good iron coal dust mud indentation arcuate die in, Foamed alloy arc blank watt is taken out after drying from arcuate die, with and good iron coal dust mud indentation taper die in, it is dry Taking out from taper die afterwards becomes foamed alloy taper blank watt；Alloy arc blank watt, foamed alloy arc blank watt It is dried with foamed alloy taper blank watt, alloy arc blank watt, foamed alloy arc blank watt and the foam after drying is closed Golden taper blank watt baking is put into trolley, and then trolley is pushed into tunnel oven and sinters alloy arc at 1200 DEG C~1400 DEG C Watt, foamed alloy arc shaped tile and foamed alloy taper watt, the frame of a foamed alloy revolution cone is welded with angle steel, by alloy arc Shape watt is embedded in the rear end of the frame of foamed alloy revolution cone, and foamed alloy arc shaped tile is embedded in the frame of foamed alloy revolution cone The middle section of frame and back segment, by foamed alloy taper watt be embedded in foamed alloy revolution cone frame leading portion, alloy arc shaped tile, Foamed alloy arc shaped tile and foamed alloy taper watt just become foamed alloy after being embedded on the frame of foamed alloy cone and turn round It bores (4).
CN201811041806.XA 2018-08-31 2018-08-31 The production method of high temperature vanadium dioxide catalyzing manufacturing of hydrogen equipment and foamed alloy Pending CN109133005A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066692A (en) * 2019-03-22 2019-07-30 张英华 Coal hydrogen equipment and control method

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
于瑞生等: "《电厂化学》", 31 January 2006 *
吴晓东等: "《稀土催化材料》", 30 June 2017 *
廖世明，柏谈论: "《国外钒冶金》", 28 February 1985 *
梁杰等: "《煤炭地下气化基础 基于三区分布的煤炭地下气化物料与能量平衡模型》", 31 October 2017 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110066692A (en) * 2019-03-22 2019-07-30 张英华 Coal hydrogen equipment and control method

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Application publication date: 20190104