CN110066139A - A kind of the radiation polycondensation melamine resin material and preparation method of high solid waste filling - Google Patents
A kind of the radiation polycondensation melamine resin material and preparation method of high solid waste filling Download PDFInfo
- Publication number
- CN110066139A CN110066139A CN201910453368.6A CN201910453368A CN110066139A CN 110066139 A CN110066139 A CN 110066139A CN 201910453368 A CN201910453368 A CN 201910453368A CN 110066139 A CN110066139 A CN 110066139A
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- Prior art keywords
- melamine resin
- solid waste
- radiation
- polycondensation
- preparation
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/125—Melamine-formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
A kind of the radiation polycondensation melamine resin material and preparation method of high solid waste filling, are made of the inorganics filled material of 1%-4% melamine resin and 99%-96%.Material waterproofing, the non-ignitable flexural strength with 15MPa or more, 2GPa-5GPa elasticity modulus, can continuous extrusion.Efficiently use Industrial Solid Waste.Product has cost and environment-friendly advantage.
Description
Technical field
A kind of the radiation polycondensation melamine resin material and preparation method of the filling of high solid waste, by 1%-4% melamine resin and
The inorganics filled material of 99%-96% forms.Material waterproofing, the non-ignitable flexural strength with 15MPa or more, 2GPa-5GPa
Elasticity modulus, can continuous extrusion.Efficiently use Industrial Solid Waste.Product has cost and environment-friendly advantage.
Background technique
Inorganic filler ratio is increased to improve intensity and elasticity modulus, reduce the hot spot technology that production cost is plastic applications.
Such as PVC industry increases strength reduction cost as filler using calcium carbonate, flyash and passes through to formula, stuffing surface modification, technique
It improves and the additive amount of equipment improvement filler material is continuously improved to 80% or more.But incident plasticizing is difficult, and equipment is quick
The problems such as abrasion and additive toxicity, while intensity and elasticity modulus also offset from demand section, gradually lose using valence
Value.Therefore Polymer Industry inorganic filler be more than 90% it is very rare.Melamine resin has excellent intensity, water-fast, resistance to
It waits, non-ignitable performance, the materials such as excellent colloid, foam can be prepared by the modification such as phenol, alcohol.Powder melamine resin and cellulose
Fiber and a small amount of inorganic filler can be pressed into exquisite articles.But inorganic fill is greater than 90% and still keeps going back for good strength
It did not saw.Having in Industrial Solid Waste much has hydration activity, dissolves in water and the material that recrystallizes but in macromolecule material
Material field is all ignored, or is not utilized, and traces it to its cause and is difficult to introduce water during thermoplastic material plasticizing forming
Composition, although thermosetting plastics can introduce water composition acidity polycondensation reaction condition and most hydration reactions needed for weak base
Property condition be difficult to coordinate and the compositions such as curing agent, regulator seriously affect the hydration reaction of inorganic material, and it is uncontrollable, very
Difficulty accomplishes that polycondensation reaction is synchronous with hydration reaction.Filler is needed in order to reach 15MPa or more intensity and 2GPa-5GPa elasticity modulus
It forms complete aquation crystalline solid and forms ideal three-dimensional structure with the complete melamine resin condensation polymer interted, and this difference
Step causes the crystallization of filler aquation to be crystallized body blocking by resinite blocking or polycondensation, can not form complete structure.This difference
The trouble and be fatal to the destruction of intensity that step manufactures, therefore conventional method is unable to get the system of this structural integrity,
It is all often failure in experiment.
Summary of the invention
With the radiation device of controllable radiation power, realization is controllable without curing agent melamine resin polycondensation reaction, and can follow
The hydration reaction of filler forms synchronization, to obtain aquation crystalline solid and intert complete melamine resin condensation polymer and formed preferably
Three-dimensional structure is the core of the technical program.
The melamine resin synthesis that calcium hydroxide solution adjusts agent is had studied, 100 seconds sides to 100 millisecond periods are had studied
The radiant power output that wave, triangular wave, biradial pipe sine wave control.Have studied 2450MHz, 900MHZ microwave and 780nm-
The near-infrared light waves of 3um wavelength can obtain ideal three-dimensional structure.Have studied steel mill's grain slag, clinker, flyash, gangue,
Desulphurization, carbide slag, solid waste gypsum, the hydration reaction of silicon ash and fraction compositions aquation synchronous reaction, it is determined that 15W/
The radiant power domain of Kg-1.5KW/Kg.Have studied influence of the melamine resin to above-mentioned filler aquation and to integral material object
Manage Index Influence, it is determined that melamine resin total amount accounting can obtain physical index in 1%-4% and economic indicator is all ideal
Material.Have studied the preceding basic demand to idiosome of radiation: it must be the mixture of raw materials of well dispersed homogeneous, and total Body Water is answered
Meet filler hydration reaction demand, and idiosome flatness, finish, shape have to comply with requirement, parallel double-screw has been selected to squeeze
Machine completes mixing plasticizing out, and screw slenderness ratio is in 32:1 or more, and there are two the above fluxing zones, have obtained ideal mixing
Material, squeezes out to have obtained the idiosome for meeting basic demand through die orifice.Before irradiating raw material be finely dispersed water, it is melamine resin, inorganic
Filler, via radiation, dehydration, to have obtained filler hydration reaction after curing complete, the well-crystallized and normal filler aquation of overlap joint is anti-
Ying Tiyu polycondensation is complete, overlaps the three-dimensional structure that normal melamine resin intersects to form.It realizes 90% or more inorganic filler and protects
The melamine resin contracting of the high solid waste filling of 15Mp or more the flexural strength and 2GPa-5GPa elasticity modulus that stay thermosetting plastics just to have
Poly- material.Since Lauxite, phenolic resin have similar reaction mechanism but consider the invertibity and phenolic resin of pollopas
Expensive price do not do in-depth explanation herein.
Material is prepared by melamine resin, mixing extrusion molding, radiates polycondensation, dehydration cures 4 processing steps and completes preparation.
Specifically (1) prepared by melamine resin: 1 mass parts of melamine, the first of 37% concentration being added in water-bath device or normal-pressure reaction kettle
Aldehyde 0.5-1.2 mass parts adjust pH value to 9 with limpid calcium hydroxide solution, are warming up to 60 DEG C of stirrings to melamine whole
60 DEG C of water 15-150 mass parts are added in dissolution, and 85 DEG C or more reactions are warmed to after being sufficiently stirred and obtain melamine resin within 2 hours,
It is spare after cooling.(2) mix extrusion molding: being completed in double screw extruder, by cooling 1 mass of liquid completed of above-mentioned preparation
Double screw extruder is added in the inorganic fillings of part and 3-8 mass parts, completes after mixing is plasticized through die orifice extrusion molding.Specifically
Inorganic fillings are steel mill's grain slag, clinker, flyash, gangue, Desulphurization, carbide slag, solid waste gypsum, one kind of silicon ash or one
Kind or more combination.(3) crosslinking with radiation: irradiating above-mentioned material with the radiant power of 15W/Kg-1.5KW/Kg, specific to radiate
It is the microwave of 2450MHz or the near-infrared light waves of 780nm to 3um wavelength.(4) dehydration curing: spontaneously drying or 80 DEG C or less drying
And place 24 hours or more.
Example one
Addition 1 mass parts of melamine, 1 mass parts of formaldehyde of 37% concentration, use are limpid in water-bath device or normal-pressure reaction kettle
Calcium hydroxide solution adjust pH value and be warming up to 60 DEG C of stirrings to 9 and all dissolved to melamine, 60 DEG C of 30 mass of water is added
Part, it is warmed to 85 DEG C or more reactions after being sufficiently stirred and obtains melamine resin within 2 hours, it is spare after cooling.Take steel mill grain slag 1000g de-
Centrifugal dehydration is dried for standby after sulphur ash 1000g gangue 1000g adds water 6000g to react taking-up in 4 hours under the conditions of 95 DEG C.It takes
It states glass of the above-mentioned powder 800g and 80g of liquid 200g with amino and double screw extruder extrusion 10mm thickness plate is added, it will
Above-mentioned plate is put into adjusting power 15W irradiation 48 hours in 2450MHz microwave and obtains plate through 80 DEG C of drying in 4 hours again, stands 24
Through detecting flexural strength 15.5MPa, elasticity modulus 4000MPa after hour.
Example two
Addition 1 mass parts of melamine, 1 mass parts of formaldehyde of 37% concentration, use are limpid in water-bath device or normal-pressure reaction kettle
Calcium hydroxide solution adjust pH value to 9, be warming up to 60 DEG C of stirrings and all dissolved to melamine, 60 DEG C of 25 mass of water is added
Part, it is warmed to 85 DEG C or more reactions after being sufficiently stirred and obtains melamine resin within 2 hours, it is spare after cooling.Desulfurized gypsum 5000g is taken to enter
It is spare that baking oven takes out cooling after being warming up to 200 DEG C of bakings 1 hour.Take the above-mentioned powder 1000g and 90g of aforesaid liquid 300g with ammonia
The glass of base is added double screw extruder and squeezes out 10mm thickness plate, and above-mentioned plate standing is put into after five minutes on 900nm wavelength
Under near-infrared radiation ambient illumination 10 minutes of each 300W, then plate is obtained through 80 DEG C of drying in 4 hours, through examining after standing 24 hours
Survey flexural strength 18.6MPa, elasticity modulus 3700MPa.
Example three
Addition 1 mass parts of melamine, 1 mass parts of formaldehyde of 37% concentration, use are limpid in water-bath device or normal-pressure reaction kettle
Calcium hydroxide solution adjust pH value to 9, be warming up to 60 DEG C of stirrings and all dissolved to melamine, 60 DEG C of 50 mass of water is added
Part, it is warmed to 85 DEG C or more reactions after being sufficiently stirred and obtains melamine resin within 2 hours, it is spare after cooling.Take steel mill Desulphurization 1000g
Flyash 1000g carbide slag 500g clinker 1000g silicon ash 500g add water 6000g reacted under the conditions of 95 DEG C 8 hours take out after from
Heart dewatered drying is spare.Take glass of the above-mentioned powder 2500g and 200g of aforesaid liquid 500g with amino that twin-screw extrusion is added
Machine squeezes out 10mm thickness plate, and the near-infrared radiation ambient illumination 24 that above-mentioned plate is put into 1.2um wavelength each 60W up and down is small
When, then plate is obtained through 80 DEG C of drying in 4 hours, through detecting flexural strength 22.2MPa, elasticity modulus after standing 24 hours
4600MPa。
Above example is a concrete scheme of the invention, does not represent invention full content.Right of the present invention is shown in " power
Sharp claim ".
Claims (2)
1. a kind of the radiation polycondensation melamine resin material and preparation method of the filling of high solid waste, it is characterized in that the material have 15Mp with
On flexural strength, 2GPa-5GPa elasticity modulus, material is by the melamine resin of 1wt%-4wt% and the steel mill of 90wt% or more
Grain slag, clinker, flyash, gangue, Desulphurization, carbide slag, solid waste gypsum, silicon ash Industrial Solid Waste filler material composition, through double spiral shells
Bar extruder mixing plasticating extrusion, then via radiation prepared by polycondensation.
2. according to claim 1, a kind of radiation polycondensation melamine resin material of high solid waste filling and preparation method specifically by: it is (1) close
Polyimide resin preparation: 1 mass parts of melamine, the formaldehyde 0.5-1.2 of 37% concentration are added in water-bath device or normal-pressure reaction kettle
Mass parts adjust pH value to 9 with limpid calcium hydroxide solution, are warming up to 60 DEG C of stirrings and all dissolve to melamine, be added
60 DEG C of water 15-150 mass parts are warmed to 85 DEG C or more reactions and obtain within 2 hours melamine resin after being sufficiently stirred, cool down standby
With;(2) mix extrusion molding: being completed in double screw extruder, by cooling 1 mass parts of liquid and 3-8 matter completed of above-mentioned preparation
The inorganic fillings for measuring part are added double screw extruder and complete after mixing is plasticized through die orifice extrusion molding, specific inorganic fillings
Be steel mill's grain slag, clinker, flyash, gangue, Desulphurization, carbide slag, solid waste gypsum, silicon ash one or more kinds of groups
It closes;(3) radiate polycondensation: the material is irradiated with the radiant power of 15W/Kg-1.5KW/Kg to above-mentioned material, specific radiation is
The microwave of 900MHz-2450MHz or the near-infrared light waves of 780nm-3um wavelength;Dehydration curing: spontaneously dry or 80 DEG C with
It lower drying and places 24 hours or more and completes.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112358268A (en) * | 2020-10-29 | 2021-02-12 | 新疆雪峰科技(集团)股份有限公司 | Composite gypsum board and manufacturing method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112358268A (en) * | 2020-10-29 | 2021-02-12 | 新疆雪峰科技(集团)股份有限公司 | Composite gypsum board and manufacturing method thereof |
CN112358268B (en) * | 2020-10-29 | 2022-03-11 | 雪峰创新(北京)科技有限公司 | Composite gypsum board and manufacturing method thereof |
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