CN110065149A - Produce jet printing type release agent, preparation method and its application method of artificial stone - Google Patents
Produce jet printing type release agent, preparation method and its application method of artificial stone Download PDFInfo
- Publication number
- CN110065149A CN110065149A CN201910301362.7A CN201910301362A CN110065149A CN 110065149 A CN110065149 A CN 110065149A CN 201910301362 A CN201910301362 A CN 201910301362A CN 110065149 A CN110065149 A CN 110065149A
- Authority
- CN
- China
- Prior art keywords
- parts
- release agent
- artificial stone
- jet printing
- camellia oil
- Prior art date
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Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 95
- 239000002969 artificial stone Substances 0.000 title claims abstract description 87
- 238000007639 printing Methods 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000010495 camellia oil Substances 0.000 claims abstract description 84
- 238000004519 manufacturing process Methods 0.000 claims abstract description 50
- 239000012188 paraffin wax Substances 0.000 claims abstract description 46
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 45
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 41
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 41
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 40
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 40
- 244000132059 Carica parviflora Species 0.000 claims abstract description 34
- 235000014653 Carica parviflora Nutrition 0.000 claims abstract description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 34
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 claims abstract description 31
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 29
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 claims abstract description 28
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 26
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000001913 cellulose Substances 0.000 claims abstract description 23
- 229920002678 cellulose Polymers 0.000 claims abstract description 23
- 229940009868 aluminum magnesium silicate Drugs 0.000 claims abstract description 21
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 21
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 21
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 21
- 239000011787 zinc oxide Substances 0.000 claims abstract description 21
- 230000000181 anti-adherent effect Effects 0.000 claims abstract description 18
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 18
- 239000000230 xanthan gum Substances 0.000 claims abstract description 18
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 18
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 18
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 18
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 17
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 16
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 14
- HTVLPUUYTJEEEZ-UHFFFAOYSA-N 1-dodecyl-3-methylimidazol-3-ium nitrate Chemical compound [O-][N+]([O-])=O.CCCCCCCCCCCC[N+]=1C=CN(C)C=1 HTVLPUUYTJEEEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000010980 cellulose Nutrition 0.000 claims abstract description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 8
- 229910001051 Magnalium Inorganic materials 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- 125000005587 carbonate group Chemical group 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 claims description 6
- 229940005642 polystyrene sulfonic acid Drugs 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- OVYTZAASVAZITK-UHFFFAOYSA-M sodium;ethanol;hydroxide Chemical compound [OH-].[Na+].CCO OVYTZAASVAZITK-UHFFFAOYSA-M 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- DVNFMHWKXQEEAH-UHFFFAOYSA-N 1-dodecyl-3-methyl-2h-imidazole Chemical compound CCCCCCCCCCCCN1CN(C)C=C1 DVNFMHWKXQEEAH-UHFFFAOYSA-N 0.000 claims description 3
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- ROCSHSZSMXCFAN-UHFFFAOYSA-N [N+](=O)(O)[O-].C(CCCCCCCCCCC)N1CN(C=C1)C Chemical compound [N+](=O)(O)[O-].C(CCCCCCCCCCC)N1CN(C=C1)C ROCSHSZSMXCFAN-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract description 17
- 238000001035 drying Methods 0.000 abstract description 16
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000002787 reinforcement Effects 0.000 abstract description 4
- 235000017550 sodium carbonate Nutrition 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 23
- 239000000853 adhesive Substances 0.000 description 13
- 230000001070 adhesive effect Effects 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 238000004945 emulsification Methods 0.000 description 9
- 239000000123 paper Substances 0.000 description 8
- 239000004575 stone Substances 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 229920002892 amber Polymers 0.000 description 7
- 239000011777 magnesium Substances 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XALWTPNRISPPIZ-UHFFFAOYSA-O 1-methyl-1h-imidazol-1-ium;nitrate Chemical compound [O-][N+]([O-])=O.C[N+]=1C=CNC=1 XALWTPNRISPPIZ-UHFFFAOYSA-O 0.000 description 5
- QSWSKDXFOIOXKW-UHFFFAOYSA-N 1h-imidazole;nitric acid Chemical compound O[N+]([O-])=O.C1=CNC=N1 QSWSKDXFOIOXKW-UHFFFAOYSA-N 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000004317 sodium nitrate Substances 0.000 description 5
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 5
- 235000010344 sodium nitrate Nutrition 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 240000001238 Gaultheria procumbens Species 0.000 description 3
- 235000007297 Gaultheria procumbens Nutrition 0.000 description 3
- 235000010394 Solidago odora Nutrition 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000006735 epoxidation reaction Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 239000002608 ionic liquid Substances 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 239000002655 kraft paper Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
- 239000011439 engineered stone Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000002271 resection Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/384—Treating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/38—Treating surfaces of moulds, cores, or mandrels to prevent sticking
- B28B7/388—Treating surfaces of moulds, cores, or mandrels to prevent sticking with liquid material, e.g. lubricating
Abstract
The invention discloses a kind of jet printing type release agent, preparation method and its application methods for producing artificial stone, including following raw material: polyvinyl alcohol, paraffin, hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, magnesium hydroxide, polytetrafluoroethylene (PTFE), cellulose, xanthan gum, sodium tripolyphosphate, sodium carbonate, modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium, the release agent be mixed by polyvinyl alcohol dissolution, with additive and etc. it is manufactured.Application method is that release agent is sprayed on to the surface of artificial stone production mould, is spontaneously dried, is solidified, and forms anti-Adhesive Coating on the surface of mold.The present invention is using polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium as reinforcement system, play synergistic effect, collaboration shortens the drying and forming-film time, shortens the production cycle, improves efficiency.
Description
[technical field]
The invention belongs to release agent preparation technical fields, and in particular to a kind of jet printing type release agent for producing artificial stone,
Preparation method and its application method.
[background technique]
Artificial stone is the materials such as filling steel, wooden after mixing the aggregates such as calcium carbonate, aluminium oxide, silica with adhesive
In the mold of matter, cured a kind of construction material after vacuum press or vacuum pressed vibration moulding.It is general to use in mold table
The contact with die surface of face pad brown paper, the isolation artificial stone material such as kraft liner and achieve the purpose that demoulding.Also have in mould
Coating oil-based release agent in tool surface prevents artificial stone material cohering in die surface.Use brown paper, kraft liner as demoulding
Agent, in vacuum press, vacuum pressed vibration moulding, brown paper or kraft liner are easy gauffer and cause stone surface bumps not
Flat or insertion stone surface, greatly improves stone surface resection (polishing amount).Oil-based release agent stripping result is unstable,
Film formation time is long, it is therefore desirable to be further improved.
[summary of the invention]
The technical problem to be solved in the present invention is to provide a kind of jet printing type release agent for producing artificial stone, preparation method and
Its application method, adhesive capacity big the problems such as long with the release agent film formation time for solving existing production artificial stone.It is prepared by the present invention
The release agent drying and forming-film time is short, and adhesive capacity is small, easy to use.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of jet printing type release agent producing artificial stone, including following raw material: polyvinyl alcohol, paraffin, hydrotalcite powder, silicon
Sour magnesium, aluminum magnesium silicate, zinc oxide, magnesium hydroxide, polytetrafluoroethylene (PTFE), cellulose, xanthan gum, sodium tripolyphosphate, sodium carbonate, modification
Camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium；
The polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber
The weight ratio of sour monoamides sulfonic acid dipotassium is (38-56): (18-27): (6-15): (126-218): (2-5).
Technical principle of the invention: hydrotalcite powder can be improved to be formed anti-and cohere coating surface lubricity, improve demoulding effect
Fruit；In addition anti-Adhesive Coating is promoted to solidify at normal temperature, form a film.The wearability of anti-Adhesive Coating can be improved in magnesium silicate, prevents
Adhesive Coating is frangible, easy to fall off.The stability of release agent can be improved in aluminum magnesium silicate, improves dispersibility.Zinc oxide can improve anti-stick
Tie the compactness of coating and the impact resistance of anti-Adhesive Coating.When magnesium hydroxide can be shortened anti-Adhesive Coating and solidify at room temperature
Between, it improves stability and extends storage time.Anti- Adhesive Coating water resistant ability can be improved in polytetrafluoroethylene (PTFE), reduces the original of release agent
Expect cost.The adhesive force of anti-Adhesive Coating Yu mold materials surface can be improved in cellulose, is not easy out in its drying, solidification process
It splits and falls off；The mobility of release agent is improved simultaneously.Xanthan gum can make the polytetrafluoroethylene (PTFE) in release agent be uniformly dispersed, it is not easy to
Occur spraying non-uniform phenomenon.Sodium tripolyphosphate and sodium carbonate can adjust the viscosity and mobility of release agent.Polyvinyl alcohol tool
There are good film forming, emulsibility and cohesive force etc., paraffin film forming can be effectively facilitated, promotes modified camellia oil emulsification, shorten
The drying and forming-film time.Paraffin has the characteristics that anisotropic lubricity, chemical resistance, while oily based on paraffin, can be resistant to
By the high temperature of artificial stone, the intermiscibility with modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate can be improved.1- ten
Dialkyl group -3- methylimidazole sodium nitrate is ionic liquid, has good permeability, 1- dodecyl -3- methylimidazole nitric acid
The addition of sodium enables to paraffin, modified camellia oil preferably to mix, shortens the drying and forming-film time.Camellia oil is modified,
Mobile performance, oxidation stability and the abrasion resistance for enhancing camellia oil, improve the stripping result and wear-resisting property of release agent；To mountain
Tea oil, which carries out epoxidation modification, makes one shape in conjunction with oxygen atom using the carbon-carbon double bond in hydrogen peroxide oxidation camellia oil
At epoxy bonds, number of double bonds are reduced, the stability of camellia oil is improved, low molecular ethyl alcohol is added, isomerization is carried out to camellia oil,
The viscosity of camellia oil can be reduced.Octadecyl coral amber acid monoamides sulfonic acid dipotassium has excellent infiltration and emulsification, makes
It is good to obtain paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate intermiscibility, so that being in emulsification, stablizes
Property it is high.It is single with polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, octadecyl coral amber acid
Amidosulfonic acid dipotassium plays synergistic effect as reinforcement system, and collaboration shortens the drying and forming-film time, shortens production week
Phase improves efficiency.
Further, the polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, ten
The weight ratio of eight alkyl coral amber acid monoamides sulfonic acid dipotassiums is 48:23:12:176:4.
Further, the jet printing type release agent of the production artificial stone, as unit of parts by weight, including following original
Material: 38-56 parts of polyvinyl alcohol, 18-27 parts of paraffin, 53-72 parts of hydrotalcite powder, 64-85 parts of magnesium silicate, 16-22 parts of aluminum magnesium silicate,
5-10 parts of zinc oxide, 8-14 parts of magnesium hydroxide, 2-9 parts of polytetrafluoroethylene (PTFE), 3-8 parts of cellulose, 1-3 parts of xanthan gum, tripolyphosphate
1-2 parts of sodium, 1-2 parts of sodium carbonate, modified camellia oil 6-15 parts, 126-218 parts of 1- dodecyl -3- methylimidazolium nitrate, ten
Eight 2-5 parts of sulfonic acid dipotassium of acid monoamides of alkyl coral ambers.
Further, the jet printing type release agent of the production artificial stone, as unit of parts by weight, including following original
Material: 48 parts of polyvinyl alcohol, 23 parts of paraffin, 65 parts of hydrotalcite powder, 72 parts of magnesium silicate, 20 parts of aluminum magnesium silicate, 8 parts of zinc oxide, hydrogen-oxygen
Change 12 parts of magnesium, 5 parts of polytetrafluoroethylene (PTFE), 6 parts of cellulose, 2 parts of xanthan gum, 1.4 parts of sodium tripolyphosphate, 1.8 parts of sodium carbonate, modified mountain
12 parts of tea oil, 176 parts of 1- dodecyl -3- methylimidazolium nitrate, 4 parts of dipotassium of acid monoamides sulfonic acid of octadecyl coral amber.
Further, the hydrotalcite powder is magnalium carbonate form hydrotalcite powder, and partial size is less than 3.6 μm.
Further, the partial size of the polytetrafluoroethylene (PTFE) is less than 1.8 μm.
Further, the cellulose is lignocellulosic.
Further, the preparation method of the modified camellia oil, comprising the following steps: the camellia oil for being 63 parts to parts by weight
Middle addition parts by weight are the acetic acid solution that 18 parts of volumetric concentrations are 26% and the polystyrene sulfonic acid resin that parts by weight are 2 parts catalysis
Agent, it is the hydrogen peroxide that 40 parts of volumetric concentrations are 32% that parts by weight are added dropwise after being warming up to 52 DEG C, after dripping hydrogen peroxide, is kept
Temperature is that 50 DEG C of sodium bicarbonate solution washs in 52 DEG C of reaction 5.5h, then with temperature, after with saturated sodium chloride solution wash to
PH value is 7, then evaporation water removal, followed by the sodium hydroxide ethanol solution that parts by weight are 65 parts is added into mixture, is controlled
Temperature is to react 45min at 62 DEG C, and modified camellia oil is made.
The present invention also provides a kind of preparation methods of jet printing type release agent for producing artificial stone, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methyl are added in a kettle
Imidazole nitrate, stirring are warming up to 85-87 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: it is single that sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid are added into mixture A made from step S1
Amidosulfonic acid dipotassium is 100-120W in microwave power, and temperature is 73-80 DEG C, and revolving speed is to stir 0.5- under 300-400r/min
Mixture B is made in 1h；
S3: hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, hydroxide are added into mixture B made from step S2
Magnesium, polytetrafluoroethylene (PTFE) are 150-180W in microwave power, and temperature is 60-65 DEG C, and revolving speed is to stir 0.4- under 200-300r/min
The jet printing type release agent of production artificial stone is made in 0.6h.
The present invention also provides a kind of application methods of jet printing type release agent for producing artificial stone, and step is, using spray
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould by the method for painting, is spontaneously dried, is solid
Change, forms 146.2-182.4 μm of anti-Adhesive Coating on the surface of mold.
The invention has the following advantages:
(1) from the data of embodiment 1-3 and comparative example 7 as it can be seen that adding polyvinyl alcohol, paraffin, modified mountain into release agent
Tea oil, 1- dodecyl -3- methylimidazole sodium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium, drying and forming-film time are aobvious
It writes and shortens, apparent viscosity significantly becomes smaller；By the data of embodiment 1-3 and comparative example 7 as it can be seen that release agent of the invention is dried to
Film time, apparent viscosity are superior to comparative example 7 (prior art), illustrate compared with prior art, the present invention have significantly into
Step；By the data of embodiment 1-3 as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecane
Base -3- methylimidazole sodium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium play synergistic effect in preparing release agent,
Collaboration shortens the drying and forming-film time；This is:
Polyvinyl alcohol has good film forming, emulsibility and cohesive force etc., can be effectively facilitated paraffin film forming, promote to change
Property camellia oil emulsification, shorten the drying and forming-film time.Paraffin has the characteristics that anisotropic lubricity, chemical resistance, while with paraffin
Based on oil, be resistant to the high temperature of artificial stone, can be improved and modified camellia oil, 1- dodecyl -3- methylimidazole nitre
The intermiscibility of sour sodium.1- dodecyl -3- methylimidazole sodium nitrate is ionic liquid, has good permeability, 1- dodecane
The addition of base -3- methylimidazole sodium nitrate enables to paraffin, modified camellia oil preferably to mix, shortens the drying and forming-film time.
Camellia oil is modified, the mobile performance, oxidation stability and abrasion resistance of camellia oil are enhanced, improves the demoulding effect of release agent
Fruit and wear-resisting property；Carrying out epoxidation modification to camellia oil makes one using the carbon-carbon double bond in hydrogen peroxide oxidation camellia oil
It is a that epoxy bond is formed in conjunction with oxygen atom, number of double bonds are reduced, the stability of camellia oil is improved, low molecular ethyl alcohol is added to mountain
Tea oil carries out isomerization, can reduce the viscosity of camellia oil.Octadecyl coral amber acid monoamides sulfonic acid dipotassium has excellent infiltration
Saturating and emulsification, so that paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate intermiscibility are good, so that being in
In emulsification, stability is high.With polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, ten
Eight alkyl coral amber acid monoamides sulfonic acid dipotassiums play synergistic effect as reinforcement system, and collaboration shortens the drying and forming-film time,
The production cycle is shortened, efficiency is improved.
(3) adhesive force of the release agent in embodiment 1-3 is formed anti-Adhesive Coating and artificial stone's quarry stone surface compares
The adhesive force of ratio 7 is low, illustrates the stripping result of the stripping result of the release agent in embodiment 1-3 than the release agent of comparative example 7
More preferably.
(4) present invention is able to solve the problem of holding paper skin among Engineered stone products, while can effectively solve the problem that artificial stone exists
The problem of leatheroid is excessive during pit saw is cut, and recirculated water leatheroid used is caused excessively to lead to water-pipe blockage.
(5) present invention is modified camellia oil, enhances the mobile performance of camellia oil, oxidation stability, wear resistence and steady
It is qualitative, the stripping result and wear-resisting property of release agent are improved, efficiently solves in the prior art that oil-based release agent stripping result is not
Stablize, the long technical problem of film formation time.
[Detailed description of the invention]
Fig. 1 is that production artificial stone uses leatheroid as release materials, and leatheroid is affixed on the artificial stone mould surrounding figure of production；
Fig. 2 is to produce artificial stone to be sprayed at artificial stone mould four using the release agent and application method of the embodiment of the present invention 1
Zhou Tu；
Fig. 3 is that production artificial stone uses leatheroid as release materials, and leatheroid is affixed on the artificial stone mould surrounding of production, production
Product surface out is stained with more leatheroid figure；
Fig. 4 is to produce artificial stone to be sprayed at artificial stone mould four using the release agent and application method of the embodiment of the present invention 1
Week, the product surface produced more completely are schemed.
[specific embodiment]
To facilitate a better understanding of the present invention, it is illustrated by the following examples, these examples belong to protection of the invention
Range, but do not limit the scope of the invention.
In embodiment, the jet printing type release agent of the production artificial stone, as unit of parts by weight, including following original
Material: 38-56 parts of polyvinyl alcohol, 18-27 parts of paraffin, 53-72 parts of hydrotalcite powder, 64-85 parts of magnesium silicate, 16-22 parts of aluminum magnesium silicate,
5-10 parts of zinc oxide, 8-14 parts of magnesium hydroxide, 2-9 parts of polytetrafluoroethylene (PTFE), 3-8 parts of cellulose, 1-3 parts of xanthan gum, tripolyphosphate
1-2 parts of sodium, 1-2 parts of sodium carbonate, modified camellia oil 6-15 parts, 126-218 parts of 1- dodecyl -3- methylimidazolium nitrate, ten
Eight 2-5 parts of sulfonic acid dipotassium of acid monoamides of alkyl coral ambers；
The hydrotalcite powder is magnalium carbonate form hydrotalcite powder, and partial size is less than 3.6 μm；
The partial size of the magnesium silicate is less than 2.4 μm；
The partial size of the aluminum magnesium silicate is less than 20.1 μm；
The partial size of the zinc oxide is less than 0.08 μm；
The partial size of the magnesium hydroxide is less than 0.05 μm；
The partial size of the polytetrafluoroethylene (PTFE) is less than 1.8 μm；
The cellulose is lignocellulosic；
The preparation method of the modified camellia oil, comprising the following steps: weight is added in the camellia oil for being 63 parts to parts by weight
Amount part is the acetic acid solution that 18 parts of volumetric concentrations are 26% and the polystyrene sulfonic acid resin catalyst that parts by weight are 2 parts, heating
It is the hydrogen peroxide that 40 parts of volumetric concentrations are 32% that parts by weight are added dropwise after to 52 DEG C, after dripping hydrogen peroxide, is maintained the temperature at
52 DEG C of reaction 5.5h, then with temperature be that 50 DEG C of sodium bicarbonate solution washs, after washed with saturated sodium chloride solution to pH value and be
7, then evaporation water removal is 65 parts of sodium hydroxide ethanol solution followed by parts by weight are added into mixture, controlled at
45min is reacted at 62 DEG C, modified camellia oil is made；
1- dodecyl -3- the methylimidazolium nitrate is 1- dodecyl -3- methylimidazole sodium nitrate；
The preparation method of the jet printing type release agent of the production artificial stone, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methyl are added in a kettle
Imidazole nitrate, stirring are warming up to 85-87 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: it is single that sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid are added into mixture A made from step S1
Amidosulfonic acid dipotassium is 100-120W in microwave power, and temperature is 73-80 DEG C, and revolving speed is to stir 0.5- under 300-400r/min
Mixture B is made in 1h；
S3: hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, hydroxide are added into mixture B made from step S2
Magnesium, polytetrafluoroethylene (PTFE) are 150-180W in microwave power, and temperature is 60-65 DEG C, and revolving speed is to stir 0.4- under 200-300r/min
The jet printing type release agent of production artificial stone is made in 0.6h.
The application method of the jet printing type release agent of above method preparation production artificial stone, step is, using spraying
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould, is spontaneously dried, solidified by method,
146.2-182.4 μm of anti-Adhesive Coating is formed on the surface of mold.
Below by more specifically examples illustrate the present invention.
Embodiment 1
A kind of jet printing type release agent producing artificial stone, as unit of parts by weight, including following raw material: polyvinyl alcohol 48
Part, 23 parts of paraffin, 65 parts of hydrotalcite powder, 72 parts of magnesium silicate, 20 parts of aluminum magnesium silicate, 8 parts of zinc oxide, 12 parts of magnesium hydroxide, poly- four
5 parts of vinyl fluoride, 6 parts of cellulose, 2 parts of xanthan gum, 1.4 parts of sodium tripolyphosphate, 1.8 parts of sodium carbonate, modified 12 parts of camellia oil, 1- ten
176 parts of dialkyl group -3- methylimidazolium nitrate, 4 parts of dipotassium of acid monoamides sulfonic acid of octadecyl coral amber；
The hydrotalcite powder is magnalium carbonate form hydrotalcite powder, and partial size is less than 1.7 μm；
The partial size of the magnesium silicate is less than 1.2 μm；
The partial size of the aluminum magnesium silicate is less than 12.3 μm；
The partial size of the zinc oxide is less than 0.07 μm；
The partial size of the magnesium hydroxide is less than 0.04 μm；
The partial size of the polytetrafluoroethylene (PTFE) is less than 1.1 μm；
The cellulose is lignocellulosic；
The preparation method of the modified camellia oil, comprising the following steps: weight is added in the camellia oil for being 63 parts to parts by weight
Amount part is the acetic acid solution that 18 parts of volumetric concentrations are 26% and the polystyrene sulfonic acid resin catalyst that parts by weight are 2 parts, heating
It is the hydrogen peroxide that 40 parts of volumetric concentrations are 32% that parts by weight are added dropwise after to 52 DEG C, after dripping hydrogen peroxide, is maintained the temperature at
52 DEG C of reaction 5.5h, then with temperature be that 50 DEG C of sodium bicarbonate solution washs, after washed with saturated sodium chloride solution to pH value and be
7, then evaporation water removal is 65 parts of sodium hydroxide ethanol solution followed by parts by weight are added into mixture, controlled at
45min is reacted at 62 DEG C, modified camellia oil is made；
1- dodecyl -3- the methylimidazolium nitrate is 1- dodecyl -3- methylimidazole sodium nitrate；
The preparation method of the jet printing type release agent of the production artificial stone, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methyl are added in a kettle
Imidazole nitrate, stirring are warming up to 86 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: it is single that sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid are added into mixture A made from step S1
Amidosulfonic acid dipotassium is 115W in microwave power, and temperature is 76 DEG C, and revolving speed is to stir 0.9h under 400r/min, and mixture is made
B；
S3: hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, hydroxide are added into mixture B made from step S2
Magnesium, polytetrafluoroethylene (PTFE) are 170W in microwave power, and temperature is 63 DEG C, and revolving speed is to stir 0.4h under 300r/min, and production people is made
Make the jet printing type release agent of stone.
The application method of the jet printing type release agent of above method preparation production artificial stone, step is, using spraying
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould, is spontaneously dried, solidified by method,
150.3-180.1 μm of anti-Adhesive Coating is formed on the surface of mold.
Embodiment 2
A kind of jet printing type release agent producing artificial stone, as unit of parts by weight, including following raw material: polyvinyl alcohol 40
Part, 25 parts of paraffin, 55 parts of hydrotalcite powder, 66 parts of magnesium silicate, 16 parts of aluminum magnesium silicate, 5 parts of zinc oxide, 8 parts of magnesium hydroxide, polytetrafluoro
2 parts of ethylene, 3 parts of cellulose, 1 part of xanthan gum, 1 part of sodium tripolyphosphate, 1 part of sodium carbonate, modified 7 parts of camellia oil, 1- dodecyl-
132 parts of 3- methylimidazolium nitrate, 2 parts of dipotassium of acid monoamides sulfonic acid of octadecyl coral amber；
The hydrotalcite powder is magnalium carbonate form hydrotalcite powder, and partial size is less than 3.5 μm；
The partial size of the magnesium silicate is less than 2.4 μm；
The partial size of the aluminum magnesium silicate is less than 18.7 μm；
The partial size of the zinc oxide is less than 0.08 μm；
The partial size of the magnesium hydroxide is less than 0.03 μm；
The partial size of the polytetrafluoroethylene (PTFE) is less than 1.5 μm；
The cellulose is lignocellulosic；
The preparation method of the modified camellia oil, comprising the following steps: weight is added in the camellia oil for being 63 parts to parts by weight
Amount part is the acetic acid solution that 18 parts of volumetric concentrations are 26% and the polystyrene sulfonic acid resin catalyst that parts by weight are 2 parts, heating
It is the hydrogen peroxide that 40 parts of volumetric concentrations are 32% that parts by weight are added dropwise after to 52 DEG C, after dripping hydrogen peroxide, is maintained the temperature at
52 DEG C of reaction 5.5h, then with temperature be that 50 DEG C of sodium bicarbonate solution washs, after washed with saturated sodium chloride solution to pH value and be
7, then evaporation water removal is 65 parts of sodium hydroxide ethanol solution followed by parts by weight are added into mixture, controlled at
45min is reacted at 62 DEG C, modified camellia oil is made；
1- dodecyl -3- the methylimidazolium nitrate is 1- dodecyl -3- methylimidazole sodium nitrate；
The preparation method of the jet printing type release agent of the production artificial stone, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methyl are added in a kettle
Imidazole nitrate, stirring are warming up to 85 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: it is single that sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid are added into mixture A made from step S1
Amidosulfonic acid dipotassium is 100W in microwave power, and temperature is 73 DEG C, and revolving speed is to stir 1h under 300r/min, and mixture B is made；
S3: hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, hydroxide are added into mixture B made from step S2
Magnesium, polytetrafluoroethylene (PTFE) are 150W in microwave power, and temperature is 60 DEG C, and revolving speed is to stir 0.6h under 200r/min, and production people is made
Make the jet printing type release agent of stone.
The application method of the jet printing type release agent of above method preparation production artificial stone, step is, using spraying
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould, is spontaneously dried, solidified by method,
158.4-175.9 μm of anti-Adhesive Coating is formed on the surface of mold.
Embodiment 3
A kind of jet printing type release agent producing artificial stone, as unit of parts by weight, including following raw material: polyvinyl alcohol 52
Part, 26 parts of paraffin, 70 parts of hydrotalcite powder, 80 parts of magnesium silicate, 20 parts of aluminum magnesium silicate, 9 parts of zinc oxide, 12 parts of magnesium hydroxide, poly- four
8 parts of vinyl fluoride, 7 parts of cellulose, 3 parts of xanthan gum, 2 parts of sodium tripolyphosphate, 1 part of sodium carbonate, modified 12 parts of camellia oil, 1- dodecane
204 parts of base -3- methylimidazolium nitrate, 4 parts of dipotassium of acid monoamides sulfonic acid of octadecyl coral amber；
The hydrotalcite powder is magnalium carbonate form hydrotalcite powder, and partial size is less than 3.6 μm；
The partial size of the magnesium silicate is less than 1.8 μm；
The partial size of the aluminum magnesium silicate is less than 17.9 μm；
The partial size of the zinc oxide is less than 0.05 μm；
The partial size of the magnesium hydroxide is less than 0.01 μm；
The partial size of the polytetrafluoroethylene (PTFE) is less than 0.7 μm；
The cellulose is lignocellulosic；
The preparation method of the modified camellia oil, comprising the following steps: weight is added in the camellia oil for being 63 parts to parts by weight
Amount part is the acetic acid solution that 18 parts of volumetric concentrations are 26% and the polystyrene sulfonic acid resin catalyst that parts by weight are 2 parts, heating
It is the hydrogen peroxide that 40 parts of volumetric concentrations are 32% that parts by weight are added dropwise after to 52 DEG C, after dripping hydrogen peroxide, is maintained the temperature at
52 DEG C of reaction 5.5h, then with temperature be that 50 DEG C of sodium bicarbonate solution washs, after washed with saturated sodium chloride solution to pH value and be
7, then evaporation water removal is 65 parts of sodium hydroxide ethanol solution followed by parts by weight are added into mixture, controlled at
45min is reacted at 62 DEG C, modified camellia oil is made；
1- dodecyl -3- the methylimidazolium nitrate is 1- dodecyl -3- methylimidazole sodium nitrate；
The preparation method of the jet printing type release agent of the production artificial stone, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methyl are added in a kettle
Imidazole nitrate, stirring are warming up to 86 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: it is single that sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid are added into mixture A made from step S1
Amidosulfonic acid dipotassium is 120W in microwave power, and temperature is 76 DEG C, and revolving speed is to stir 0.5h under 400r/min, and mixture is made
B；
S3: hydrotalcite powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, hydroxide are added into mixture B made from step S2
Magnesium, polytetrafluoroethylene (PTFE) are 180W in microwave power, and temperature is 65 DEG C, and revolving speed is to stir 0.4h under 300r/min, and production people is made
Make the jet printing type release agent of stone.
The application method of the jet printing type release agent of above method preparation production artificial stone, step is, using spraying
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould, is spontaneously dried, solidified by method,
146.8-181.4 μm of anti-Adhesive Coating is formed on the surface of mold.
Comparative example 1
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, octadecyl coral in the raw material of agent
Amber acid monoamides sulfonic acid dipotassium.
Comparative example 2
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack polyvinyl alcohol in the raw material of agent.
Comparative example 3
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack paraffin in the raw material of agent.
Comparative example 4
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack modified camellia oil in the raw material of agent.
Comparative example 5
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack 1- dodecyl -3- methylimidazole sodium nitrate in the raw material of agent.
Comparative example 6
It is essentially identical with the preparation process of embodiment 1, have the jet printing type demoulding the difference is that preparation production artificial stone only
Lack octadecyl coral amber acid monoamides sulfonic acid dipotassium in the raw material of agent.
Comparative example 7
Using Chinese patent literature " a kind of artificial stone release agent and its application method (and Authorization Notice No.: CN:
105563631B) " technique of embodiment 1-6 prepares artificial stone release agent.
Experiment one: performance test
In order to compare the performance of release agent, test specimen is prepared according to relevant same standard, and be tested for the property, tried
It is as shown in the table to test data.
As seen from the above table: (1) from the data of embodiment 1-3 and comparative example 7 as it can be seen that into release agent add polyvinyl alcohol,
Paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium, it is dry
Film formation time significantly shortens, and apparent viscosity significantly becomes smaller；By the data of embodiment 1-3 and comparative example 7 as it can be seen that demoulding of the invention
The drying and forming-film time of agent, apparent viscosity are superior to comparative example 7 (prior art), illustrate compared with prior art, the present invention having
There is significant progress；By the data of embodiment 1-3 as it can be seen that embodiment 1 is optimum embodiment.
(2) by embodiment 1 and the data of comparative example 1-6 as it can be seen that polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecane
Base -3- methylimidazole sodium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium play synergistic effect in preparing release agent,
Collaboration shortens the drying and forming-film time；This is:
Polyvinyl alcohol has good film forming, emulsibility and cohesive force etc., can be effectively facilitated paraffin film forming, promote to change
Property camellia oil emulsification, shorten the drying and forming-film time.Paraffin has the characteristics that anisotropic lubricity, chemical resistance, while with paraffin
Based on oil, be resistant to the high temperature of artificial stone, can be improved and modified camellia oil, 1- dodecyl -3- methylimidazole nitre
The intermiscibility of sour sodium.1- dodecyl -3- methylimidazole sodium nitrate is ionic liquid, has good permeability, 1- dodecane
The addition of base -3- methylimidazole sodium nitrate enables to paraffin, modified camellia oil preferably to mix, shortens the drying and forming-film time.
Camellia oil is modified, the mobile performance, oxidation stability and abrasion resistance of camellia oil are enhanced, improves the demoulding effect of release agent
Fruit and wear-resisting property；Carrying out epoxidation modification to camellia oil makes one using the carbon-carbon double bond in hydrogen peroxide oxidation camellia oil
It is a that epoxy bond is formed in conjunction with oxygen atom, number of double bonds are reduced, the stability of camellia oil is improved, low molecular ethyl alcohol is added to mountain
Tea oil carries out isomerization, can reduce the viscosity of camellia oil.Octadecyl coral amber acid monoamides sulfonic acid dipotassium has excellent infiltration
Saturating and emulsification, so that paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate intermiscibility are good, so that being in
In emulsification, stability is high.With polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazole sodium nitrate, ten
Eight alkyl coral amber acid monoamides sulfonic acid dipotassiums play synergistic effect as reinforcement system, and collaboration shortens the drying and forming-film time,
The production cycle is shortened, efficiency is improved.
Experiment two: adhesive force grading evaluation
The artificial stone anti-Adhesive Coating that release agent is formed in embodiment 1-3 and comparative example 7 is evaluated using cross-hatching to exist
The adhesive force on raw artificial stone surface.
Sample prepares:
It is cut on raw artificial stone with a thickness of 100mm × 100mm × 14mm sample.With No. 800 waterproof abrasive papers by sample
After surface grinding, dried behind its surface wash with distilled water.
The release agent prepared in embodiment 1-3 and comparative example 7 is coated in artificial stone specimen surface with hairbrush.It is anti-to cohere painting
Layer is able to dry, hardening.The anti-coating layer thickness that coheres is 146.2-182.4 μm.To the de- of each embodiment 1-3 and comparative example 7
Mould agent prepares 3 samples in parallel.
The evaluation of adhesive force:
6 cutting lines are marked on the surface of above-mentioned anti-Adhesive Coating with the cross hatch device for being divided into 3mm between blade, then are cut with this
Line square crossing in 90 ° marks 6 parallel cutting lines and forms grid.
It is swept several times before and after each cutting line of grid with hairbrush, and is purged dust completely with hair dryer.
It cuts width and is placed on pressing above above-mentioned grid for the adhesive force test tape of 24mm, length 40mm.Adhesive tape one end
Length is more than grid 20mm, and hanging.
Hold the hanging one end of adhesive tape, and to cohere coating surface with anti-and smoothly adhesive tape is torn off at 60 ° of angle, then
The phenomenon that amplification sem observation coating shedding for being 3 times with amplification factor, the coating shedding area for drawing lattice region is evaluated.
Evaluation result is as shown in the table.
It can be seen that from table, the anti-Adhesive Coating that the release agent in embodiment 1-3 is formed and artificial stone's quarry stone surface
Adhesive force is lower than the adhesive force of comparative example 7, illustrates release agent of the stripping result than comparative example 7 of the release agent in embodiment 1-3
Stripping result it is more preferable.
Experiment three: production artificial stone uses leatheroid as release materials compared with using release agent of the present invention
Comparative example 8
Artificial stone is produced using leatheroid as release materials, leatheroid is affixed on the artificial stone mould surrounding of production, such as Fig. 1 institute
Show, it is as shown in Figure 3 using result.
Comparative example 9
The release agent that artificial stone uses the embodiment of the present invention 1 is produced, the application method of release agent, step is, using spray
The jet printing type release agent for producing artificial stone is sprayed on the surface of artificial stone production mould by the method for painting, is spontaneously dried, is solid
Change, forms 150.3-180.1 μm of anti-Adhesive Coating on the surface of mold.As shown in Fig. 2, as shown in Figure 4 using result.
From the result of Fig. 3 it is found that production artificial stone uses scheme of the leatheroid as release materials, it is viscous to cause product surface
Have more leatheroid, influence product quality, and increase the difficulty of cleaned in situ, in addition go back sticker paper also waste it is more artificial
Cost.
From the result of Fig. 4 it is found that production artificial stone produces product table using the scheme of the release agent of the embodiment of the present invention 1
Face is relatively cleaner, environmentally friendly, saves cost of labor.The present invention is able to solve holding paper among Engineered stone products using release agent scheme
The problem of skin, while can effectively solve the problem that artificial stone leatheroid during pit saw is cut is excessive, lead to recirculated water paper used
Skin excessively leads to the problem of water-pipe blockage.
The specific implementation of the invention is not to be limited to these illustrations for the above content, and technology belonging to the present invention is led
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, a number of simple deductions or replacements can also be made,
It all shall be regarded as belonging to present invention scope of patent protection determined by the appended claims.
Claims (10)
1. a kind of jet printing type release agent for producing artificial stone, which is characterized in that including following raw material: polyvinyl alcohol, paraffin, water
Talcum powder, magnesium silicate, aluminum magnesium silicate, zinc oxide, magnesium hydroxide, polytetrafluoroethylene (PTFE), cellulose, xanthan gum, sodium tripolyphosphate, carbon
Sour sodium, modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium；
The polyvinyl alcohol, paraffin, modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid are single
The weight ratio of amidosulfonic acid dipotassium is (38-56): (18-27): (6-15): (126-218): (2-5).
2. the jet printing type release agent of production artificial stone according to claim 1, which is characterized in that the polyvinyl alcohol,
Paraffin, the weight for being modified camellia oil, 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid monoamides sulfonic acid dipotassium
Amount is than being 48:23:12:176:4.
3. the jet printing type release agent of production artificial stone according to claim 1, which is characterized in that with parts by weight for singly
Position, including following raw material: 38-56 parts of polyvinyl alcohol, 18-27 parts of paraffin, 53-72 parts of hydrotalcite powder, 64-85 parts of magnesium silicate, silicon
Sour magnalium 16-22 parts, 5-10 parts of zinc oxide, 8-14 parts of magnesium hydroxide, 2-9 parts of polytetrafluoroethylene (PTFE), 3-8 parts of cellulose, xanthan gum
1-3 parts, 1-2 parts of sodium tripolyphosphate, 1-2 parts of sodium carbonate, modified camellia oil 6-15 parts, 1- dodecyl -3- methylimidazole nitric acid
126-218 parts of salt, 2-5 parts of sulfonic acid dipotassium of acid monoamides of octadecyl coral amber.
4. the jet printing type release agent of production artificial stone according to claim 3, which is characterized in that with parts by weight for singly
Position, including following raw material: 48 parts of polyvinyl alcohol, 23 parts of paraffin, 65 parts of hydrotalcite powder, 72 parts of magnesium silicate, 20 parts of aluminum magnesium silicate, oxygen
Change 8 parts of zinc, 12 parts of magnesium hydroxide, 5 parts of polytetrafluoroethylene (PTFE), 6 parts of cellulose, 2 parts of xanthan gum, 1.4 parts of sodium tripolyphosphate, sodium carbonate
1.8 parts, modified 12 parts of camellia oil, 176 parts of 1- dodecyl -3- methylimidazolium nitrate, octadecyl coral amber acid monoamides sulphur
4 parts of sour dipotassium.
5. according to claim 1, producing the jet printing type release agent of artificial stone described in 3 or 4, which is characterized in that the neatly
Mountain flour is magnalium carbonate form hydrotalcite powder, and partial size is less than 3.6 μm.
6. according to claim 1, producing the jet printing type release agent of artificial stone described in 3 or 4, which is characterized in that described poly- four
The partial size of vinyl fluoride is less than 1.8 μm.
7. according to claim 1, producing the jet printing type release agent of artificial stone described in 3 or 4, which is characterized in that the fiber
Element is lignocellulosic.
8. according to claim 1, producing the jet printing type release agent of artificial stone described in 3 or 4, which is characterized in that the modification
The preparation method of camellia oil, comprising the following steps: it is that 18 parts of volumes are dense that parts by weight are added in the camellia oil for being 63 parts to parts by weight
The polystyrene sulfonic acid resin catalyst that the acetic acid solution and parts by weight that degree is 26% are 2 parts, is added dropwise weight after being warming up to 52 DEG C
Part is the hydrogen peroxide that 40 parts of volumetric concentrations are 32%, after dripping hydrogen peroxide, maintains the temperature at 52 DEG C of reaction 5.5h, then use
Temperature be 50 DEG C sodium bicarbonate solution wash, after with saturated sodium chloride solution wash to pH value be 7, then evaporation water removal, then
Then it is 65 parts of sodium hydroxide ethanol solution that parts by weight are added into mixture, controlled at 45min is reacted at 62 DEG C, is made
Camellia oil must be modified.
9. a kind of preparation method of the jet printing type release agent of production artificial stone according to claim 1-8,
It is characterized in that, comprising the following steps:
S1: cellulose, xanthan gum, polyvinyl alcohol, modified camellia oil and 1- dodecyl -3- methylimidazole are added in a kettle
Nitrate, stirring are warming up to 85-87 DEG C, are completely dissolved polyvinyl alcohol, and mixture A is made；
S2: sodium tripolyphosphate, sodium carbonate, paraffin, octadecyl coral amber acid monoamides are added into mixture A made from step S1
Sulfonic acid dipotassium is 100-120W in microwave power, and temperature is 73-80 DEG C, and revolving speed is to stir 0.5-1h under 300-400r/min, is made
Obtain mixture B；
S3: hydrotalcite powder is added into mixture B made from step S2, magnesium silicate, aluminum magnesium silicate, zinc oxide, magnesium hydroxide, gathers
Tetrafluoroethene is 150-180W in microwave power, and temperature is 60-65 DEG C, and revolving speed is to stir 0.4-0.6h under 200-300r/min,
The jet printing type release agent of production artificial stone is made.
10. a kind of application method of the jet printing type release agent of the preparation of method according to claim 9 production artificial stone, step
It suddenly is, using the method for spraying, the jet printing type release agent for producing artificial stone to be sprayed on to the surface of artificial stone production mould, warp
It spontaneously dries, solidification, forms 146.2-182.4 μm of anti-Adhesive Coating on the surface of mold.
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Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070131140A1 (en) * | 2004-08-31 | 2007-06-14 | Aoki Science Institute Co., Ltd. | Oil type release agent for die casting method for getting solvent mixing ratio, casting method, and spray unit |
| US20120308678A1 (en) * | 2010-03-08 | 2012-12-06 | Sharp Kabushiki Kaisha | Mold release treatment method, mold, method for producing anti-reflective film, mold release treatment device, and washing/drying device for mold |
| CN105563631A (en) * | 2015-12-21 | 2016-05-11 | 嘉善美节陶瓷科技有限公司 | Demolding material for artificial stone and application method of demolding material |
| CN106318578A (en) * | 2016-08-19 | 2017-01-11 | 桂林华越环保科技有限公司 | Novel mold release agent for concrete |
| CN106393402A (en) * | 2016-08-19 | 2017-02-15 | 桂林华越环保科技有限公司 | Novel concrete release agent and preparation method thereof |
| CN106833062A (en) * | 2016-12-28 | 2017-06-13 | 广西利升石业有限公司 | Release materials of leatheroid and preparation method thereof are substituted in a kind of artificial stone manufacturing process |
| CN107163771A (en) * | 2017-07-04 | 2017-09-15 | 江苏时代鑫新环保科技有限公司 | A kind of artificial stone release materials and its preparation method and application |
| KR20170109354A (en) * | 2016-03-21 | 2017-09-29 | 이승열 | Aqueous stripping composition for concrete formwork and manufacturing method thereof |
| WO2017173484A1 (en) * | 2016-04-04 | 2017-10-12 | Veedol Lubricants Australia | Release agent composition |
| CN107447579A (en) * | 2017-10-11 | 2017-12-08 | 广西南宁荣威德新能源科技有限公司 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
| WO2018035850A1 (en) * | 2016-08-24 | 2018-03-01 | 曹玲玲 | Water-soluble greasy mould release agent for concrete and preparation method therefor |
| WO2018064490A1 (en) * | 2016-09-30 | 2018-04-05 | Xenamed Corporation | Compositions of midodrine and methods of using the same |
| KR20180087114A (en) * | 2017-01-23 | 2018-08-01 | (주)동구바이오제약 | Pharmaceutical composition comprising Mosapride or salt thereof and preparation method for the same |
| CN108913318A (en) * | 2018-07-25 | 2018-11-30 | 刘滔 | A kind of concrete parting agent and preparation method thereof |
| CN109233945A (en) * | 2018-10-24 | 2019-01-18 | 江苏正祥新材料有限公司 | A kind of plastic building template release agent and preparation method thereof |
| CN109370755A (en) * | 2018-11-29 | 2019-02-22 | 中建西部建设股份有限公司 | A kind of concrete water-based release agent and preparation method thereof |
| CN109517659A (en) * | 2017-09-17 | 2019-03-26 | 简慧娟 | A kind of concrete parting agent |
-
2019
- 2019-04-15 CN CN201910301362.7A patent/CN110065149B/en active Active
Patent Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070131140A1 (en) * | 2004-08-31 | 2007-06-14 | Aoki Science Institute Co., Ltd. | Oil type release agent for die casting method for getting solvent mixing ratio, casting method, and spray unit |
| US20120308678A1 (en) * | 2010-03-08 | 2012-12-06 | Sharp Kabushiki Kaisha | Mold release treatment method, mold, method for producing anti-reflective film, mold release treatment device, and washing/drying device for mold |
| CN105563631A (en) * | 2015-12-21 | 2016-05-11 | 嘉善美节陶瓷科技有限公司 | Demolding material for artificial stone and application method of demolding material |
| KR20170109354A (en) * | 2016-03-21 | 2017-09-29 | 이승열 | Aqueous stripping composition for concrete formwork and manufacturing method thereof |
| WO2017173484A1 (en) * | 2016-04-04 | 2017-10-12 | Veedol Lubricants Australia | Release agent composition |
| CN106393402A (en) * | 2016-08-19 | 2017-02-15 | 桂林华越环保科技有限公司 | Novel concrete release agent and preparation method thereof |
| CN106318578A (en) * | 2016-08-19 | 2017-01-11 | 桂林华越环保科技有限公司 | Novel mold release agent for concrete |
| WO2018035850A1 (en) * | 2016-08-24 | 2018-03-01 | 曹玲玲 | Water-soluble greasy mould release agent for concrete and preparation method therefor |
| WO2018064490A1 (en) * | 2016-09-30 | 2018-04-05 | Xenamed Corporation | Compositions of midodrine and methods of using the same |
| CN106833062A (en) * | 2016-12-28 | 2017-06-13 | 广西利升石业有限公司 | Release materials of leatheroid and preparation method thereof are substituted in a kind of artificial stone manufacturing process |
| KR20180087114A (en) * | 2017-01-23 | 2018-08-01 | (주)동구바이오제약 | Pharmaceutical composition comprising Mosapride or salt thereof and preparation method for the same |
| CN107163771A (en) * | 2017-07-04 | 2017-09-15 | 江苏时代鑫新环保科技有限公司 | A kind of artificial stone release materials and its preparation method and application |
| CN109517659A (en) * | 2017-09-17 | 2019-03-26 | 简慧娟 | A kind of concrete parting agent |
| CN107447579A (en) * | 2017-10-11 | 2017-12-08 | 广西南宁荣威德新能源科技有限公司 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
| CN108914689A (en) * | 2017-10-11 | 2018-11-30 | 天津中天精科科技有限公司 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN108913318A (en) * | 2018-07-25 | 2018-11-30 | 刘滔 | A kind of concrete parting agent and preparation method thereof |
| CN109233945A (en) * | 2018-10-24 | 2019-01-18 | 江苏正祥新材料有限公司 | A kind of plastic building template release agent and preparation method thereof |
| CN109370755A (en) * | 2018-11-29 | 2019-02-22 | 中建西部建设股份有限公司 | A kind of concrete water-based release agent and preparation method thereof |
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Denomination of invention: Spray release agent for producing artificial stones, preparation method and usage method Granted publication date: 20210525 Pledgee: Guangxi SME Financing Guarantee Co.,Ltd. Pledgor: GUANGXI LISHENG STONE Co.,Ltd. Registration number: Y2024980001572 |
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