CN107447579A - A kind of paper for daily use paper pulp releasing agent and preparation method thereof - Google Patents
A kind of paper for daily use paper pulp releasing agent and preparation method thereof Download PDFInfo
- Publication number
- CN107447579A CN107447579A CN201710938508.XA CN201710938508A CN107447579A CN 107447579 A CN107447579 A CN 107447579A CN 201710938508 A CN201710938508 A CN 201710938508A CN 107447579 A CN107447579 A CN 107447579A
- Authority
- CN
- China
- Prior art keywords
- parts
- paper
- releasing agent
- daily use
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001131 Pulp (paper) Polymers 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 47
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- 239000008158 vegetable oil Substances 0.000 claims abstract description 46
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 26
- 239000003899 bactericide agent Substances 0.000 claims abstract description 22
- 239000002608 ionic liquid Substances 0.000 claims abstract description 15
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 12
- 235000013871 bee wax Nutrition 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 12
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 239000012166 beeswax Substances 0.000 claims abstract description 5
- 239000000470 constituent Substances 0.000 claims abstract description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 28
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 15
- 241000196324 Embryophyta Species 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 235000019198 oils Nutrition 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 7
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 230000033228 biological regulation Effects 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 7
- 230000008020 evaporation Effects 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- -1 1- ethyl Chemical group 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003139 biocide Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 235000005687 corn oil Nutrition 0.000 claims description 2
- 239000002285 corn oil Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims 1
- 239000002068 microbial inoculum Substances 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 5
- 230000035807 sensation Effects 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000004537 pulping Methods 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
- 239000002199 base oil Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000002480 mineral oil Substances 0.000 description 9
- 235000010446 mineral oil Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 6
- 150000001768 cations Chemical class 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 229920013639 polyalphaolefin Polymers 0.000 description 4
- 201000004384 Alopecia Diseases 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 208000024963 hair loss Diseases 0.000 description 3
- 230000003676 hair loss Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000010893 paper waste Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 2
- 206010027146 Melanoderma Diseases 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010959 commercial synthesis reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000036228 toxication Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Abstract
The invention belongs to pulping and paper-making processing technique field, and in particular to a kind of paper for daily use paper pulp releasing agent and preparation method thereof.Each constituent and its quality parts ratio of the paper for daily use paper pulp releasing agent be：40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, 10 ~ 20 parts of ionic liquid, 10 ~ 20 parts of plant ash solution, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, 3 ~ 5 parts of bactericide, 5 ~ 10 parts of dodecyl sodium sulfate.The present invention prepares the releasing agent of gained, can improve the bulk and pliability of paper for daily use, strengthens the smooth fine and smooth sensation of paper, and it is dry, wet strength is higher, environmental protection.
Description
Technical field
The invention belongs to pulping and paper-making processing technique field, and in particular to a kind of paper for daily use paper pulp releasing agent and its preparation
Method.
Background technology
Paper for daily use includes roll web, paper extraction, napkin paper, facial tissue, paper handkerchief, kitchen towels etc., is convenient for people to stay at home
Used with the place such as outgoing.With the continuous improvement of people's living standard, paper for daily use is rapidly become in people's life most
For one of close consumer goods, the production of the paper for daily use in China and the market demand also increase rapidly, and people are to paper for daily use
Quality requirement also more and more higher, had not only required the intensity of paper but also had required the light softness of paper.The quality of paper for daily use quality will
The service condition of consumers in general is directly affected, increasing enterprise starts to pay attention to the research and development to new product to meet market need
Ask.It is seldom as the paper mill of raw material using wood pulp merely in China, it is raw material mostly using waste paper, waste paper kind is different, contained by it
Some debris are also different.A large amount of uses of non-wood-fiber in paper industry, the ratio increase that particularly waste paper uses so that
The class foreign matter that sticks together in paper machine increases, and has influence on effective work of paper machine, viscous cylinder, the phenomenon of viscous dry net occurs, and paper is producing
During also there is the problems such as broken end, hair loss, dry linting, blackspot, have a strong impact on the quality of paper.In order to improve the production matter of paper
Amount, some processing aids are usually added in paper-making process to improve the performance of paper and processing technology, assign some spies of paper
Different performance.Releasing agent is a kind of functional materials between mould and finished product, prevents material to be bonded on die surface, is risen
To a kind of processing aid for being easy to the demoulding.
Because Novel paper machine is manufactured paper with pulp, speed is very fast, so to obtain preferable paper peeling effect, many enterprises select
Mineral oil or vegetable oil emulsion, supported the use in the lump with adhesive, corrugation and effective peeling effect can be played.Low speed paper machine one
As to glue cylinder not serious, the auxiliary agents such as some softening agents can be added to improve de- cylinder, cationic macromolecule wax class can be also added in slurry
Remover, so as to improve de- cylinder performance.Conventional inorganic releasing agent has talcum powder, mica powder, sodium thiosulfate etc., organic demoulding
Agent includes carbohydrate, soaps, glycerine, paraffin etc., and this kind of remover film dirt is more, and perishable mould, and polymerization species releasing agent has poly-
Tetrafluoroethene, silicone oil etc., this kind of releasing agent stripping result is good, repeats and utilizes, but price is costly.Make with lubricating release
Base oil, China largely use oil based on mineral oil, and mineral oil is cheap, can meet many property perhaps
Can, but mineral base oil can not be biodegradable or biodegradability is poor, it is slowly gathered so as to ecology in the environment
Environment pollutes and the health of the mankind is damaged.Current most of international businesses begin one's study environmentally friendly green profit
Lubricating oil substitutes traditional mineral base oil, reaches nontoxic pollution-free, what easy natural degradation will not damage to the ecosystem
Purpose.Green Lubricants turn into the ideal substitute of mineral base oil.At present, Green Lubricants mainly by improved poly- α-
The base oils such as alkene, synthetic fat, polyethers and vegetable oil reconcile with additive form respectively.Poly alpha olefin is mainly device in Gas or day
The base oil that the macromolecular that right gas comes out through the cumbersome chemical reactive synthesis such as catalytic polymerization forms, the poly alpha olefin base of low viscosity
Plinth is oily to be easier to degrade compared with highly viscous poly alpha olefin base oil, but generally speaking poly alpha olefin base oil due to its water
Dissolubility is not mostly fine, therefore it is later to be not easy the microbial degradation by environment that it, which is entered in environment, will not be to life yet
Thing is toxic and stimulation, is still green base oil.Synthesizing ester oil is the esterification reaction product of organic acid and alcohol, synthetic fat
There is good ability in terms of boundary lubrication, due to closely similar with the structure of natural oil, all with aliphatic radical structure, therefore its
It is a kind of Green Lubricants with good biological degradability, but synthetic ester is raw materials used to be also from greatly mineral oil,
And its price is higher relative to mineral oil based lubricating oil, polyether oil etc..PPG and referred to as polyethers (PAG),
It is using the compound containing active hydrogen group as initiator, is carried out by monomer of oxirane, expoxy propane or its mixture
Polymer made from ring-opening polymerization.Expressive force of the polyether oil in terms of oxidation stability is not fine, the phase of polyether product
For capacitive nor very good, it is poor with the being mutually dissolved property of mineral oil and artificial oil, and the traditional commercial synthesis of polyether oil uses
Be oxirane, expoxy propane homopolymerization or copolymerization, these materials of tracing to its source still come from mineral oil.Vegetable oil plant oil
It is natural organic-compound easily biological-degradable, itself has very excellent lubricity again, is preferable base oil, but plants
Thing oil is a kind of Unsaturatcd fatty acid glycerides, containing substantial amounts of carbon-carbon double bond, causes its oxidation stability poor, it may occur that
Very serious oxidative phenomena, and more easy to foaming than mineral oil, these defect factors limit oily based on vegetable oil
Development, is modified to vegetable oil, widens the application of vegetable oil.
Substantial amounts of material is reported for preparation about releasing agent, and it is former used by needing according to different processing industries
Material and processing technology carry out the preparation of practicality, and the releasing agent of different performance is made.But these releasing agents are mainly used in
The industries such as rubber, plastics, concrete, using less in paper industry.
The content of the invention
The present invention provides a kind of paper for daily use paper pulp releasing agent and preparation method thereof, it is therefore intended that solves paper for daily use in life
The broken end that occurs during production, hair loss, dry linting phenomenon, solve to produce eye, pockmark point, brocken spectrum and translucent point etc. on paper
Paper defects, improve the bulk and pliability of paper for daily use, strengthen the smooth fine and smooth sensation of paper, and it is dry, wet strength is higher, ring
Protect.
The solution of the present invention is by so realization：Paper for daily use paper pulp releasing agent in one, the paper for daily use paper pulp
Each constituent and its quality parts ratio of releasing agent be：40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, ionic liquid 10 ~
20 parts, 10 ~ 20 parts of plant ash solution, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, sterilization
3 ~ 5 parts of agent, 5 ~ 10 parts of dodecyl sodium sulfate.
The technical principle of the present invention：Vegetable oil has excellent lubricity, good biodegradability, nontoxic to environment
The characteristics of evil, using oily based on green vegetable oil, it can avoid being difficult to the energy that regenerates, and ore deposit using mineral oil etc.
Thing based lubricating oil can not be biodegradable or biodegradability is poor, and it is slowly gathered so as to be made to ecological environment in the environment
Into pollution and the health of the mankind is damaged.Vegetable oil is modified, strengthens mobile performance, the oxidation stability of vegetable oil
And abrasion resistance, it is main to carry out epoxidation modification using to vegetable oil, the carbon-carbon double bond in vegetable oil is aoxidized using peroxycarboxylic acid,
One is combined to form epoxy bond with oxygen atom, reduce number of double bonds, improve plant oil-proofness, add low molecular ethanol
Isomerization is carried out to vegetable oil, the viscosity of vegetable oil can be reduced.Simultaneously beeswax be also the lubricity with the opposite sex, fusing point it is high,
The characteristics of chemical resistance, at the same it is oily based on beeswax, the high temperature of drying cylinder is resistant to, its in releasing agent can also be improved
The intermiscibility of his component.Ionic liquid is " green solvent ", has good a permeability and anti-corrosive properties, the addition of ionic liquid,
Enable to release agent components preferably to mix, moreover it is possible to strengthen the whiteness of paper, ionic liquid can also with it is negatively charged in paper pulp
The fiber of lotus forms electrostatic interaction, so as to strengthen the intensity of paper, can also prevent and treat fiber flocculation.Cationic liquid can also be with
Fiber fines in slurry combine, and improve the retention of fiber fines, improve paper strength to a certain degree.Tristerin energy
Paper is rigidly reduced, reduce the kinematics and static friction factor of fibrous matter, strengthen smooth, submissive, the fine and smooth sense of paper, add
Polyvinyl alcohol can have good film forming, cohesive force and emulsibility etc., can effectively improve the physical strength of paper, simultaneously
The wetness sensation of paper can be strengthened.A kind of cationic polyelectrolyte of polyethyleneimine, side chain is carried in tertiary amine groups, paper can be improved
The wet strength opened, while to having cementation containing filler and fiber fines, can also play good retention aid and filtering aid effect.Add
Bactericide be Dow bactericide 7287, Dow bactericide 8536, the mixing of isothiazolinone biocide agent, Dow bactericide is rapid
Constrain the growth of biology and the synthesis of biopolymer, there is high-efficiency broad spectrum, dosage is low, effect is rapid, kills
Bacterium effect is good, biodegradable, and in the environment without persistence, easy cleaning removing toxic substances, in soluble in water, compatibility is good, no surface
Effect, it is added in releasing agent and adds bactericide and can kill bacterium in paper-making process, suppress pollution of the bacterium to paper.Thiophene
Oxazoline ketone bactericide has the advantages that strong antibacterial, application dose are small, dissolubility is good and hypotoxicity, low-residual, degradable,
And high-efficiency broad spectrum, can quickly it kill livestock, rapid recovery system efficiency is good with the compatibility of the other materials in paper pulp, with Dow
Bactericide is used in mixed way, and can reduce the resistance of bacterium, improves the bactericidal effect in paper-making process.Dodecyl sodium sulfate has
Excellent infiltration, decontamination and emulsification so that the various composition intermiscibility of releasing agent is good, releasing agent is in emulsification,
Stability is high, and dodecyl sodium sulfate biodegradability is good, and environment will not be polluted.The addition of plant ash, it can adjust
The acid-base value in paper production is saved, makes pulp production control in neutral meta-acid, while plant ash also has bactericidal action, energy
It is enough that bactericidal action is played in paper production.
As a further improvement on the present invention, described ionic liquid be 1- butyl -3- methylimidazole villaumites or 1- ethyls -
One or more kinds of combinations in 3- methyl-phosphoric acid dimethyl ester salt.
As a further improvement on the present invention, described bactericide is Dow bactericide 7287, Dow bactericide 8536, different thiophene
The mixing of oxazoline ketone bactericide.
As a further improvement on the present invention, described modified vegetable oil is by rapeseed oil, castor oil, corn oil, soybean oil
In one or more kinds of combinations be modified to obtain.
A kind of method for preparing paper for daily use paper pulp releasing agent, its step include：
(1) the pre- modification of vegetable oil：Take 70 ~ 85 parts of vegetable oil to be put into reactor, add 20 ~ 25 parts of acetic acid solutions and 2 ~ 4 parts strong
Acidic cationic resin catalyst, temperature is raised, while 40 ~ 50 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, protected
Hold temperature and 4 ~ 6h is reacted at 50 ~ 60 DEG C, the washing of reusable heat sodium carbonate liquor, removed afterwards with saturated common salt water washing to neutrality, evaporation
Water, 70 ~ 85 parts of potassium hydroxide-ethanol solution is added in reactor, 30 ~ 60min is reacted at a temperature of 60 ~ 80 DEG C, is produced
Modified vegetable oil；
(2) hybrid reaction：20 ~ 30 parts of beeswaxs are added into vessel in heating to 60 ~ 80 DEG C of fusings, then add modified vegetable oil 40
~ 50 parts, 10 ~ 20 parts of ionic liquid, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, bactericide
3 ~ 5 parts, 5 ~ 10 parts of dodecyl sodium sulfate, 5 ~ 20min is mixed, be eventually adding 10 ~ 20 parts of regulation soda acids of plant ash solution
Degree, mix 5 ~ 20min and produce high energy paper pulp releasing agent.
The present invention possesses following good result：
1. the releasing agent cost is low, application method is simple, usage amount is few, and can repeatedly use, and stability is strong, nuisanceless,
Environment thing is polluted.
2. compatibility in paper between composition can be improved by changing releasing agent, so that its lubricity for not occurring drastically becomes
Change, improve the intensity of paper, there is plasticization.
3. the releasing agent has protective effect to drying cylinder, the pollutant of dryer surface can be cleaned, plays antiseptic and rustproof work
With, there is good lubrication to drying cylinder and creping doctor, effectively improve scraper work stability, extend scraper use the longevity
Life.
4. adding the releasing agent, it can prevent viscous cylinder, paste cylinder, " yellow side " phenomenon from occurring, efficiently solve paper and producing
During occur broken end, hair loss, dry linting phenomenon, effectively improve smoothness, the glossiness of paper, intensity, do not cause paper table
The blackspot in face produces, solves to produce the paper defects such as eye, pockmark point, brocken spectrum and translucent point on paper.
5. the paper for daily use paper pulp releasing agent of the present invention, the bulk and pliability of paper for daily use can be improved, strengthen paper
Smooth fine and smooth sensation, and it is dry, wet strength is higher, environmental protection.
Embodiment
A kind of paper for daily use paper pulp releasing agent of the description present invention and preparation method thereof with reference to embodiments, these descriptions are simultaneously
It is not that present invention is further limited.
Embodiment 1：
The pre- modification of vegetable oil：Take 80 parts of vegetable oil to be put into reactor, add 20 parts of acetic acid solutions and 2 parts of highly acidic cation trees
Fat catalyst, temperature is raised, while 43 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, maintain the temperature at 60 DEG C of reactions
5.5h, the washing of reusable heat sodium carbonate liquor, afterwards with saturated common salt water washing to neutrality, evaporation water removal, add potassium hydroxide second
70 parts of alcoholic solution reacts 30min at a temperature of 75 DEG C, produces modified vegetable oil in reactor；
Hybrid reaction：30 parts of beeswaxs are added into vessel in heating to 75 DEG C of fusings, then add 48 parts of modified vegetable oil, ionic liquid
18 parts of body, 5 parts of tristerin, 4 parts of polyvinyl alcohol, 4 parts of polyethyleneimine, 4 parts of bactericide, 5 parts of dodecyl sodium sulfate,
15min is mixed, 20 parts of regulation acid-base values of plant ash solution is eventually adding, mixes 16min and produce paper for daily use paper pulp
Releasing agent.
Embodiment 2：
The pre- modification of vegetable oil：Take 70 parts of vegetable oil to be put into reactor, add 21 parts of acetic acid solutions and 4 parts of highly acidic cation trees
Fat catalyst, temperature is raised, while 45 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, maintain the temperature at 50 DEG C of reactions
6h, the washing of reusable heat sodium carbonate liquor, afterwards with saturated common salt water washing to neutrality, evaporation water removal, add ethanolic potassium hydroxide
75 parts of solution reacts 40min at a temperature of 60 DEG C, produces modified vegetable oil in reactor；
Hybrid reaction：22 parts of beeswaxs are added into vessel in heating to 60 DEG C of fusings, then add 45 parts of modified vegetable oil, ionic liquid
15 parts of body, 10 parts of tristerin, 3 parts of polyvinyl alcohol, 5 parts of polyethyleneimine, 3 parts of bactericide, dodecyl sodium sulfate 10
Part, 5min is mixed, 10 parts of regulation acid-base values of plant ash solution is eventually adding, mixes 20min and produce paper for daily use paper
Starch releasing agent.
Embodiment 3：
The pre- modification of vegetable oil：Take 85 parts of vegetable oil to be put into reactor, add 23 parts of acetic acid solutions and 3 parts of highly acidic cation trees
Fat catalyst, temperature is raised, while 50 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, maintain the temperature at 52 DEG C of reactions
4h, the washing of reusable heat sodium carbonate liquor, afterwards with saturated common salt water washing to neutrality, evaporation water removal, add ethanolic potassium hydroxide
75 parts of solution reacts 50min at a temperature of 80 DEG C, produces modified vegetable oil in reactor；
Hybrid reaction：20 parts of beeswaxs are added into vessel in heating to 80 DEG C of fusings, then add 50 parts of modified vegetable oil, ionic liquid
10 parts of body, 6 parts of tristerin, 6 parts of polyvinyl alcohol, 2 parts of polyethyleneimine, 5 parts of bactericide, 8 parts of dodecyl sodium sulfate,
20min is mixed, 12 parts of regulation acid-base values of plant ash solution is eventually adding, mixes 8min and produce paper for daily use delignified pulp
Mould agent.
Embodiment 4：
The pre- modification of vegetable oil：Take 80 parts of vegetable oil to be put into reactor, add 25 parts of acetic acid solutions and 4 parts of highly acidic cation trees
Fat catalyst, temperature is raised, while 48 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, maintain the temperature at 55 DEG C of reactions
5h, the washing of reusable heat sodium carbonate liquor, afterwards with saturated common salt water washing to neutrality, evaporation water removal, add ethanolic potassium hydroxide
80 parts of solution reacts 60min at a temperature of 65 DEG C, produces modified vegetable oil in reactor；
Hybrid reaction：28 parts of beeswaxs are added into vessel in heating to 65 DEG C of fusings, then add 42 parts of modified vegetable oil, ionic liquid
12 parts of body, 8 parts of tristerin, 5 parts of polyvinyl alcohol, 3 parts of polyethyleneimine, 4 parts of bactericide, 9 parts of dodecyl sodium sulfate,
10min is mixed, 15 parts of regulation acid-base values of plant ash solution is eventually adding, mixes 5min and produce paper for daily use delignified pulp
Mould agent.
Embodiment 5：
The pre- modification of vegetable oil：Take 75 parts of vegetable oil to be put into reactor, add 24 parts of acetic acid solutions and 2 parts of highly acidic cation trees
Fat catalyst, temperature is raised, while 40 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide, maintain the temperature at 58 DEG C of reactions
4.5h, the washing of reusable heat sodium carbonate liquor, afterwards with saturated common salt water washing to neutrality, evaporation water removal, add potassium hydroxide second
85 parts of alcoholic solution reacts 55min at a temperature of 70 DEG C, produces modified vegetable oil in reactor；
Hybrid reaction：25 parts of beeswaxs are added into vessel in heating to 70 DEG C of fusings, then add 40 parts of modified vegetable oil, ionic liquid
20 parts of body, 7 parts of tristerin, 5 parts of polyvinyl alcohol, 5 parts of polyethyleneimine, 5 parts of bactericide, 7 parts of dodecyl sodium sulfate,
18min is mixed, 18 parts of regulation acid-base values of plant ash solution is eventually adding, mixes 12min and produce paper for daily use paper pulp
Releasing agent.
The paper for daily use paper pulp releasing agent is prepared according to the step method of above example, and the releasing agent is watered, is converted
Change the aqueous emulsion of 3% concentration into, its performance is measured, the performance parameter of the releasing agent of the present invention is as shown in the table：
The releasing agent performance indications of table 1
The paper for daily use paper pulp releasing agent that above example is prepared is respectively added in paper pulp pond, bought with the market
Common remover be added to as control in paper pulp pond, addition is 2.5kg/ ton oven dry stocks, according to the production of toilet paper
Technique is produced.Obtained product properties are determined, the target level of product quality of production is with reference to GB 20810-2006《Health
Paper（Body paper containing toilet paper）》Specifications, measurement result is as shown in the table：
The technical indicator of the paper product of table 2
The above embodiment of the present invention scheme is only the description of the invention and can not limit the present invention, and this is indicated in claim
Invention product form composition, into scope, and above-mentioned explanation does not point out the scope of parameter of the present invention, therefore, with the present invention
Claims it is suitable divide ratio, any change in the implication and scope of preparation method parameter, be all considered to be bag
Include in the range of claims.
The present invention is by multidigit paper production investigative technique personnel's long-term work experience accumulation, and passes through creative work
Create, releasing agent produced by the present invention has good lubricity, stability series, and action effect is good, harmless, green
Environmental protection, easily biological-degradable, pulp production is added to, the brightness of the paper of gained is 85 ~ 90%, tensile index 4.0
~ 4.5N.m/g, pliability are 105 ~ 114N.m/g, and the eye formed is few, and the quality of product effectively improves, and meets national mark
It is accurate.
Claims (3)
1. a kind of paper for daily use paper pulp releasing agent, it is characterized in that, each constituent and its matter of the paper for daily use paper pulp releasing agent
Measuring portion rate is：It is 40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, 10 ~ 20 parts of ionic liquid, 10 ~ 20 parts of plant ash solution, hard
5 ~ 10 parts of glycerol, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, 3 ~ 5 parts of bactericide, dodecyl sodium sulfate 5 ~ 10
Part；
Described ionic liquid is one kind in 1- butyl -3- methylimidazole villaumites or 1- ethyl -3- methyl-phosphoric acid dimethyl ester salt
Or more than one combination；
Described bactericide is Dow bactericide 7287, Dow bactericide 8536, the mixing of isothiazolinone biocide agent.
2. a kind of paper for daily use paper pulp releasing agent according to claim 1, it is characterized in that, described modified vegetable oil is by dish
One or more kinds of combinations in seed oil, castor oil, corn oil, soybean oil are modified to obtain.
3. the method that one kind prepares the paper for daily use paper pulp releasing agent described in any one of claim 1 ~ 2, it is characterized in that, preparation side
Method step includes：
Step 1）The pre- modification of vegetable oil：Take 70 ~ 85 parts of vegetable oil to be put into reactor, add 20 ~ 25 parts of acetic acid solutions and 2 ~ 4 parts
Strong acidic ion resin catalyst, temperature is raised, while 40 ~ 50 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide,
Maintain the temperature at 50 ~ 60 DEG C of 4 ~ 6h of reaction, reusable heat sodium carbonate liquor washing, afterwards with saturated common salt water washing to neutrality, evaporation
Water removal, adds 70 ~ 85 parts of potassium hydroxide-ethanol solution in reactor, 30 ~ 60min is reacted at a temperature of 60 ~ 80 DEG C, i.e.,
Obtain modified vegetable oil；
Step 2）Hybrid reaction：20 ~ 30 parts of beeswaxs are added into vessel in heating to 60 ~ 80 DEG C of fusings, then add improved plant
40 ~ 50 parts of oil, 10 ~ 20 parts of ionic liquid, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, kill
3 ~ 5 parts of microbial inoculum, 5 ~ 10 parts of dodecyl sodium sulfate, 5 ~ 20min is mixed, be eventually adding 10 ~ 20 parts of regulations of plant ash solution
Acid-base value, mix 5 ~ 20min and produce paper for daily use paper pulp releasing agent.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810940860.1A CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940354.2A CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN201710938508.XA CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
| CN201810940361.2A CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710938508.XA CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810940860.1A Division CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940361.2A Division CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
| CN201810940354.2A Division CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107447579A true CN107447579A (en) | 2017-12-08 |
| CN107447579B CN107447579B (en) | 2018-10-09 |
Family
ID=60498744
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710938508.XA Active CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
| CN201810940354.2A Withdrawn CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN201810940860.1A Withdrawn CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940361.2A Withdrawn CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810940354.2A Withdrawn CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN201810940860.1A Withdrawn CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940361.2A Withdrawn CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (4) | CN107447579B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109175222A (en) * | 2018-07-27 | 2019-01-11 | 舒城县金禾油脂科技开发有限公司 | A kind of release agent and its preparation process based on chaff cerolein |
| CN110065149A (en) * | 2019-04-15 | 2019-07-30 | 广西利升石业有限公司 | Produce jet printing type release agent, preparation method and its application method of artificial stone |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110176179A (en) * | 2019-05-17 | 2019-08-27 | 宁波卓越印务有限公司 | A kind of multi-functional adhesive label and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1228467A (en) * | 1998-03-09 | 1999-09-15 | 艾奇逊工业有限公司 | Water-free release/lubricating agents for treating walls of die for original shaping or reshaping |
| CN103764910A (en) * | 2011-08-22 | 2014-04-30 | 巴科曼实验室国际公司 | Oil-based creping release aid formulation |
| CN103774495A (en) * | 2014-02-12 | 2014-05-07 | 南宁飞日润滑油有限公司 | High-energy paper pulp release agent and production method thereof |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5658374A (en) * | 1995-02-28 | 1997-08-19 | Buckman Laboratories International, Inc. | Aqueous lecithin-based release aids and methods of using the same |
| TW200422486A (en) * | 2003-02-18 | 2004-11-01 | Maintech Co Ltd | Method for preventing paper web surface from fraying in papermaking machine, printing paper for use in offset printing, and release agent |
| JP4973040B2 (en) * | 2006-07-12 | 2012-07-11 | 星光Ｐｍｃ株式会社 | Release agent for crepes |
| US8444812B2 (en) * | 2008-11-18 | 2013-05-21 | Nalco Company | Creping adhesives with improved film properties |
| US20110297341A1 (en) * | 2010-06-07 | 2011-12-08 | Dilkus Christopher P | Creping Release Agents |
| CN102504924B (en) * | 2011-11-09 | 2013-07-31 | 合肥工业大学 | Polysilsesquioxane (POSS) modified vegetable oil emulsion mold release agent and preparation method thereof |
| CN102876462B (en) * | 2012-10-15 | 2013-10-09 | 南京工业大学 | Method for preparing high-quality epoxidized soybean oil |
| CN103266016A (en) * | 2013-06-04 | 2013-08-28 | 合肥工业大学 | Method for preparing organic silicon modified plant oil |
| CN103320211B (en) * | 2013-07-10 | 2015-01-14 | 合肥工业大学 | Method for preparing polyether lubricating oil by modified plant oil |
| CN104389232B (en) * | 2014-10-23 | 2016-08-24 | 广东比伦生活用纸有限公司 | The paper for daily use of a kind of super soft perfuming and production method thereof |
| CA2970314C (en) * | 2014-12-12 | 2019-09-24 | Solenis Technologies, L.P. | Method of producing a creping paper and the creping paper thereof |
| CN105479629A (en) * | 2015-12-06 | 2016-04-13 | 刘方旭 | Preparation method of environment-friendly emulsified releasing agent |
| CN105802697B (en) * | 2016-03-24 | 2018-12-18 | 德易普（天津）科技有限公司 | A kind of preparation method of the degradable methanol engine lubricating oil of improved plant oil base |
-
2017
- 2017-10-11 CN CN201710938508.XA patent/CN107447579B/en active Active
- 2017-10-11 CN CN201810940354.2A patent/CN108914689A/en not_active Withdrawn
- 2017-10-11 CN CN201810940860.1A patent/CN108914690A/en not_active Withdrawn
- 2017-10-11 CN CN201810940361.2A patent/CN108978337A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1228467A (en) * | 1998-03-09 | 1999-09-15 | 艾奇逊工业有限公司 | Water-free release/lubricating agents for treating walls of die for original shaping or reshaping |
| CN103764910A (en) * | 2011-08-22 | 2014-04-30 | 巴科曼实验室国际公司 | Oil-based creping release aid formulation |
| CN103774495A (en) * | 2014-02-12 | 2014-05-07 | 南宁飞日润滑油有限公司 | High-energy paper pulp release agent and production method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109175222A (en) * | 2018-07-27 | 2019-01-11 | 舒城县金禾油脂科技开发有限公司 | A kind of release agent and its preparation process based on chaff cerolein |
| CN110065149A (en) * | 2019-04-15 | 2019-07-30 | 广西利升石业有限公司 | Produce jet printing type release agent, preparation method and its application method of artificial stone |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108914690A (en) | 2018-11-30 |
| CN108978337A (en) | 2018-12-11 |
| CN107447579B (en) | 2018-10-09 |
| CN108914689A (en) | 2018-11-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107447579B (en) | A kind of paper for daily use paper pulp releasing agent and preparation method thereof | |
| CN101600788B (en) | Wiping products having enhanced cleaning abilities | |
| DE60131959T2 (en) | ION-SENSITIVE WATER DISPERSIBLE POLYMERS | |
| KR101728576B1 (en) | Water-resistant/oil-resistant agent composition, article treated with the composition, and processes for production of the composition and the article | |
| AU2011263363B2 (en) | Tissue products containing microalgae materials | |
| KR100433328B1 (en) | Method of creping a fibrous web and creped paper | |
| TW213965B (en) | ||
| KR20130054333A (en) | Degradable superabsorbent polymers | |
| KR101877081B1 (en) | Bacteriostatic tissue product | |
| CN107083712B (en) | A kind of high-strength corrugated base paper and preparation method thereof | |
| RU2008110179A (en) | CLEANING COMPOSITIONS CONTAINING FILM | |
| CN102595887A (en) | Antimicrobial composition | |
| Brentin | Soy-based chemicals and materials: growing the value chain | |
| CN101108985B (en) | Paraffin wax emulsions modified with petroleum resin and method of manufacturing the same | |
| CN108166156A (en) | One kind is degradable, easily breaks up vegetable fiber environmental protection material | |
| CN107524049B (en) | High-energy paper pulp release agent and preparation method thereof | |
| CN107675557A (en) | A kind of cultural paper in the office paper pulp releasing agent and preparation method thereof | |
| CN106806255A (en) | A kind of antipollution mask | |
| CN103774495B (en) | High energy paper pulp releasing agent and production method thereof | |
| CN109880177A (en) | A kind of high-strength degradable vegetable fiber environmental protection material and preparation method thereof | |
| CN106580810A (en) | Blueberry extract-containing anti-pollution mask | |
| MXPA97001767A (en) | Topical composition clear spray for care of the skin with insoluble perfume in a | |
| CN110747688B (en) | Mineral oil emulsion stripping agent composition for papermaking dryer and preparation method thereof | |
| JP5475977B2 (en) | Aromatic composition | |
| CN113789233A (en) | Polyester high stretch yarn detergent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180809 Address after: 755000 A center, Zhongguancun science and Technology Industrial Park, the Ningxia Hui Autonomous Region, China. Applicant after: NINGXIA RUISHENG MINGJIE INTELLECTUAL PROPERTY CONSULTING CO.,LTD. Address before: 530028 No. 409, Haotian Plaza, 24 Long Lake Road, Qingxiu District, Nanning, the Guangxi Zhuang Autonomous Region Applicant before: GUANGXI NANNING RONGWEIDE NEW ENERGY TECHNOLOGY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231130 Address after: 324400, No. 9 Dingxin Road East, Zhejiang Longyou Economic Development Zone, Longyou County, Quzhou City, Zhejiang Province Patentee after: Zhejiang Herun Biotechnology Co.,Ltd. Address before: 755000 A center, Zhongguancun science and Technology Industrial Park, the Ningxia Hui Autonomous Region, China. Patentee before: NINGXIA RUISHENG MINGJIE INTELLECTUAL PROPERTY CONSULTING CO.,LTD. |