CN107447579B - A kind of paper for daily use paper pulp releasing agent and preparation method thereof - Google Patents
A kind of paper for daily use paper pulp releasing agent and preparation method thereof Download PDFInfo
- Publication number
- CN107447579B CN107447579B CN201710938508.XA CN201710938508A CN107447579B CN 107447579 B CN107447579 B CN 107447579B CN 201710938508 A CN201710938508 A CN 201710938508A CN 107447579 B CN107447579 B CN 107447579B
- Authority
- CN
- China
- Prior art keywords
- parts
- paper
- releasing agent
- vegetable oil
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920001131 Pulp (paper) Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 49
- 239000008158 vegetable oil Substances 0.000 claims abstract description 48
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 21
- 239000000417 fungicide Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 14
- 235000013871 bee wax Nutrition 0.000 claims abstract description 12
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 239000002608 ionic liquid Substances 0.000 claims abstract description 10
- 239000012166 beeswax Substances 0.000 claims abstract description 5
- 239000000470 constituent Substances 0.000 claims abstract description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 27
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 16
- 241000196324 Embryophyta Species 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 11
- 235000019198 oils Nutrition 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- -1 1- ethyl Chemical group 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 claims description 3
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003139 biocide Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 235000005687 corn oil Nutrition 0.000 claims description 2
- 239000002285 corn oil Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002068 microbial inoculum Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims 2
- 230000008020 evaporation Effects 0.000 claims 2
- 238000012545 processing Methods 0.000 abstract description 5
- 238000004537 pulping Methods 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000002199 base oil Substances 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002480 mineral oil Substances 0.000 description 9
- 235000010446 mineral oil Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 229920000570 polyether Polymers 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 229920013639 polyalphaolefin Polymers 0.000 description 4
- 201000004384 Alopecia Diseases 0.000 description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 208000024963 hair loss Diseases 0.000 description 3
- 230000003676 hair loss Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000010687 lubricating oil Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000010893 paper waste Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 206010027146 Melanoderma Diseases 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- GHVZOJONCUEWAV-UHFFFAOYSA-N [K].CCO Chemical compound [K].CCO GHVZOJONCUEWAV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010959 commercial synthesis reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003512 tertiary amines Chemical group 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000036228 toxication Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Paper (AREA)
Abstract
The invention belongs to pulping and paper-making processing technique fields, and in particular to a kind of paper for daily use paper pulp releasing agent and preparation method thereof.Each constituent and its quality parts ratio of the paper for daily use paper pulp releasing agent be：40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, 10 ~ 20 parts of ionic liquid, 10 ~ 20 parts of plant ash solution, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, 3 ~ 5 parts of fungicide, 5 ~ 10 parts of dodecyl sodium sulfate.The present invention prepares the releasing agent of gained, can improve the bulk and pliability of paper for daily use, enhances the feeling of smooth exquisiteness of paper, and it is dry, wet strength is higher, environmentally friendly.
Description
Technical field
The invention belongs to pulping and paper-making processing technique fields, and in particular to a kind of paper for daily use paper pulp releasing agent and its preparation
Method.
Background technology
Paper for daily use includes roll web, paper extraction, napkin paper, facial tissue, paper handkerchief, kitchen towels etc., and people is facilitated to stay at home
It is used with outgoing equal places.With the continuous improvement of people's living standard, paper for daily use rapidly becomes in people's life most
For close one of the consumer goods, the production of the paper for daily use in China and the market demand also increase rapidly, and people are to paper for daily use
Quality requirement is also higher and higher, has not only required the intensity of paper but also has required the light softness of paper.The quality of paper for daily use quality will
The service condition of consumers in general is directly affected, more and more enterprises start to pay attention to the research and development to new product to meet market need
It asks.Seldom using wood pulp as the paper mill of raw material merely in China, it is raw material mostly to use waste paper, and waste paper kind is different, contained by
Some sundries are also different.A large amount of uses of non-wood-fiber in paper industry, the ratio that especially waste paper uses increase so that
The class foreign matter that sticks together in paper machine increases, and influences effective work of paper machine, the phenomenon that gluing cylinder, viscous dry net occurs, paper is producing
Also occur the problems such as broken end, hair loss, picking, blackspot in the process, seriously affects the quality of paper.In order to improve the production matter of paper
Amount usually adds some processing aids to improve the performance and processing technology of paper in paper-making process, assigns the certain spies of paper
Different performance.Releasing agent is a kind of functional materials between mold and finished product, and material is prevented to be bonded on die surface, is risen
To a kind of processing aid for being easy to demoulding.
Since Novel paper machine is manufactured paper with pulp, speed is very fast, so to obtain ideal paper peeling effect, many enterprises select
Mineral oil or vegetable oil lotion match together with adhesive, can play corrugation and effective peeling effect.Low speed paper machine one
As glue cylinder it is not serious, can add the auxiliary agents such as some softening agents improve take off cylinder, cationic macromolecule wax class can be also added in slurry
Remover, so as to improve de- cylinder performance.Common inorganic releasing agent has talcum powder, mica powder, sodium thiosulfate etc., organic demoulding
Agent includes carbohydrate, soaps, glycerine, paraffin etc., and this kind of remover film dirt is more, and perishable mold, and polymerization species releasing agent has poly-
Tetrafluoroethene, silicone oil etc., this kind of releasing agent stripping result is good, repeats and utilizes, but price is costly.Make with lubricating release
Base oil, largely using oil based on mineral oil, mineral oil is cheap in China, can meet various property perhaps
Can, but mineral base oil cannot be biodegradable or biodegradability is poor, slowly gathers to ecology in the environment
Environment is polluted and is caused damages to the health of the mankind.Current most of international business begin one's study environmentally friendly green profit
Lubricating oil replaces traditional mineral base oil, reaches nontoxic and pollution-free, what easy natural degradation will not cause damages to the ecosystem
Purpose.Green Lubricants become the ideal substitute of mineral base oil.Currently, Green Lubricants are mainly by improved poly- α-
The base oils such as alkene, synthetic fat, polyethers and vegetable oil reconcile with additive respectively.Poly alpha olefin is mainly device in Gas or day
The base oil for the macromolecular composition that right gas comes out through the cumbersome chemical reactive synthesis such as catalytic polymerization, the poly alpha olefin base of low viscosity
Plinth oil is easier to degrade compared with highly viscous poly alpha olefin base oil, but generally speaking poly alpha olefin base oil due to its water
Dissolubility is not mostly fine, therefore it is later the microbial degradation being not easy by environment that it, which is entered in environment, will not be to life
Object is toxic and stimulation, is still green base oil.Synthesizing ester oil is the esterification reaction product of organic acid and alcohol, synthetic fat
There is good ability in terms of boundary lubrication, due to closely similar with the structure of natural oil, all with aliphatic radical structure, therefore its
It is a kind of Green Lubricants with good biological degradability, but synthetic ester is raw materials used to be also from greatly mineral oil,
And its price is higher relative to mineral oil based lubricating oil, polyether oil etc..Polyether polyol and referred to as polyethers (PAG),
It is carried out by monomer of ethylene oxide, propylene oxide or its mixture using the compound containing active hydrogen group as initiator
Polymer made from ring-opening polymerization.Expressive force of the polyether oil in terms of oxidation stability is not fine, the phase of polyether product
Capacitive is nor very good, and poor with the being mutually dissolved property of mineral oil and synthetic oil, the traditional commercial synthesis of polyether oil uses
Be ethylene oxide, propylene oxide homopolymerization or copolymerization, these materials of tracing to its source still come from mineral oil.Vegetable oil plant oil
It is natural organic-compound easily biological-degradable, itself has very excellent lubricity again, is ideal base oil, but plants
Object oil is a kind of Unsaturatcd fatty acid glycerides, containing a large amount of carbon-carbon double bond, causes its oxidation stability poor, it may occur that
Very serious oxidative phenomena, and more easy to foaming than mineral oil, these defect factors limit oily based on vegetable oil
Development, is modified vegetable oil, widens the application range of vegetable oil.
Preparation in relation to releasing agent has a large amount of material report, it is needed according to former used by different processing industries
Material and processing technology carry out the preparation of practicability, and the releasing agent of different performance is made.But these releasing agents are mainly used in
The industries such as rubber, plastics, concrete, using less in paper industry.
Invention content
A kind of paper for daily use paper pulp releasing agent of present invention offer and preparation method thereof, it is therefore intended that solve paper for daily use in life
The broken end occurred in the process, hair loss, picking phenomenon are produced, solves to generate hole eye, pockmark point, brocken spectrum and translucent point etc. on paper
Paper defects improves the bulk and pliability of paper for daily use, enhances the feeling of the smooth exquisiteness of paper, and it is dry, wet strength is higher, ring
It protects.
The scheme of the invention is in this way son realize：Paper for daily use paper pulp releasing agent in one, the paper for daily use paper pulp
Each constituent and its quality parts ratio of releasing agent be：40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, ionic liquid 10 ~
20 parts, 10 ~ 20 parts of plant ash solution, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, sterilization
3 ~ 5 parts of agent, 5 ~ 10 parts of dodecyl sodium sulfate.
The technical principle of the present invention：Vegetable oil has excellent lubricity, good biodegradability, nontoxic to environment
Harmful feature can avoid being difficult to the regenerated energy, and mine using mineral oil etc. using oil based on environmentally protective vegetable oil
Object based lubricating oil cannot be biodegradable or biodegradability is poor, slowly gather to make ecological environment in the environment
It causes damages at pollution and to the health of the mankind.Vegetable oil is modified, mobile performance, the oxidation stability of vegetable oil are enhanced
And abrasion resistance, it is main to carry out epoxidation modification using to vegetable oil, the carbon-carbon double bond in vegetable oil is aoxidized using peroxycarboxylic acid,
Make one be combined to form epoxy bond with oxygen atom, reduce number of double bonds, improves plant oil-proofness, low molecular ethyl alcohol is added
Isomerization is carried out to vegetable oil, the viscosity of vegetable oil can be reduced.Simultaneously beeswax be also with anisotropic lubricity, fusing point it is high,
The characteristics of chemical resistance, at the same it is oily based on beeswax, it is resistant to the high temperature of drying cylinder, its in releasing agent can also be improved
The intermiscibility of his component.Ionic liquid is " green solvent ", have good permeability and anti-corrosive properties, the addition of ionic liquid,
Enable to release agent components preferably to mix, moreover it is possible to enhance the whiteness of paper, ionic liquid can also with it is negatively charged in paper pulp
The fiber of lotus forms electrostatic interaction, to enhance the intensity of paper, can also prevent fiber flocculation.Cationic liquid can also be with
Fiber fines in slurry combine, and improve the retention of fiber fines, improve paper strength to a certain degree.Tristerin energy
So that paper is rigidly reduced, reduce the kinematics and static friction factor of fibrous matter, enhance smooth, submissive, the fine and smooth sense of paper, is added
Polyvinyl alcohol can have good film forming, cohesive force and emulsibility etc., can effectively improve the physical strength of paper, simultaneously
The wetness sensation of paper can be enhanced.A kind of cationic polyelectrolyte of polyethyleneimine carries branch in tertiary amine groups, paper can be improved
The wet strength opened, while having cementation to containing filler and fiber fines, it can also play the role of good retention aid and filtering aid.It is added
Fungicide be Dow fungicide 7287, Dow fungicide 8536, isothiazolinone biocide agent mixing, Dow fungicide is rapid
Constrain the synthesis of the growth and biopolymer of biology, there is high-efficiency broad spectrum, dosage is low, effect is rapid, kills
Bacterium effect is good, biodegradable, and in the environment without persistence, easy cleaning removing toxic substances, in soluble easily in water, compatibility is good, no surface
Effect is added in releasing agent and fungicide is added can kill bacterium in paper-making process, inhibit pollution of the bacterium to paper.Thiophene
Oxazoline ketone fungicide has many advantages, such as that strong antibacterial, application dose are small, dissolubility is good and hypotoxicity, low-residual, degradable,
And high-efficiency broad spectrum, it can quickly kill livestock, rapid recovery system efficiency is good with the compatibility of the other materials in paper pulp, with Dow
Fungicide is used in mixed way, and can reduce the resistance of bacterium, improves the bactericidal effect in paper-making process.Dodecyl sodium sulfate has
Excellent infiltration, decontamination and emulsification so that the various composition intermiscibility of releasing agent is good, and releasing agent is made to be in emulsification,
Stability is high, and dodecyl sodium sulfate biodegradability is good, not can cause environmental pollution.The addition of plant ash can adjust
The acid-base value in paper production is saved, makes pulp production control in neutral meta-acid, while plant ash also has bactericidal effect, energy
It is enough that bactericidal effect is played in paper production.
As a further improvement on the present invention, the ionic liquid is 1- butyl -3- methylimidazole villaumites or 1- ethyls -
One or more kinds of combinations in 3- methyl-phosphoric acid dimethyl ester salt.
As a further improvement on the present invention, the fungicide is Dow fungicide 7287, Dow fungicide 8536, different thiophene
The mixing of oxazoline ketone fungicide.
As a further improvement on the present invention, the modified vegetable oil is by rapeseed oil, castor oil, corn oil, soybean oil
In one or more kinds of combinations be modified to obtain.
A method of paper for daily use paper pulp releasing agent being prepared, step includes：
(1) the pre- modification of vegetable oil：It takes 70 ~ 85 parts of vegetable oil to be put into reaction kettle, 20 ~ 25 parts of acetic acid solutions and 2 ~ 4 is added
Part strong acidic ion resin catalyst, increases temperature, while 40 ~ 50 parts of 30% hydrogen peroxide is slowly added dropwise, drips hydrogen peroxide
Afterwards, 50 ~ 60 DEG C of 4 ~ 6h of reaction are maintained the temperature at, the washing of reusable heat sodium carbonate liquor is steamed afterwards with saturated common salt water washing to neutrality
Hair water removal, adds 70 ~ 85 parts of potassium hydroxide-ethanol solution in reaction kettle, and 30 ~ 60min is reacted at a temperature of 60 ~ 80 DEG C,
Up to modified vegetable oil；
(2) hybrid reaction：20 ~ 30 parts of beeswaxs are added to the container and are heated to 60 ~ 80 DEG C of fusings, improved plant is then added
40 ~ 50 parts of oil, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, kills at 10 ~ 20 parts of ionic liquid
5 ~ 20min is mixed in 3 ~ 5 parts of microbial inoculum, 5 ~ 10 parts of dodecyl sodium sulfate, is eventually adding 10 ~ 20 parts of adjustings of plant ash solution
5 ~ 20min is mixed up to high energy paper pulp releasing agent in acid-base value.
The present invention has following good result：
1. the releasing agent is at low cost, application method is simple, usage amount is few, and can repeatedly use, and stability is strong, no public affairs
Evil pollutes environment object.
2. compatibility in paper between ingredient can be improved by changing releasing agent, so that the change of lubricity drastically does not occur for it
It changes, improves the intensity of paper, there is plasticization.
3. the releasing agent has protective effect to drying cylinder, the pollutant of dryer surface can be cleaned, antiseptic and rustproof work is played
With there is good lubricating action to drying cylinder and creping doctor, effectively improve the stability of scraper work, extend scraper and use the longevity
Life.
4. the releasing agent is added, it can prevent viscous cylinder, paste cylinder, " yellow side " phenomenon from occurring, efficiently solve paper and producing
The broken end that occurs in the process, hair loss, picking phenomenon, effectively improve smoothness, the glossiness of paper, intensity does not cause paper table
The blackspot in face generates, solves to generate the paper defects such as hole eye, pockmark point, brocken spectrum and translucent point on paper.
5. the paper for daily use paper pulp releasing agent of the present invention can improve the bulk and pliability of paper for daily use, enhance paper
Smooth exquisiteness feeling, and it is dry, wet strength is higher, environmental protection.
Specific implementation mode
A kind of paper for daily use paper pulp releasing agent of the description present invention and preparation method thereof with reference to embodiments, these descriptions are simultaneously
It is not to be further limited to the content of present invention.
Embodiment 1：
The pre- modification of vegetable oil：Take 80 parts of vegetable oil to be put into reaction kettle, be added 20 parts of acetic acid solutions and 2 parts of highly acid sun from
Sub- resin catalyst increases temperature, while 43 parts of 30% hydrogen peroxide is slowly added dropwise, and after dripping hydrogen peroxide, maintains the temperature at 60 DEG C
5.5h is reacted, the washing of reusable heat sodium carbonate liquor evaporates water removal, add hydroxide afterwards with saturated common salt water washing to neutrality
70 parts of potassium ethanol solution reacts 30min to get modified vegetable oil in reaction kettle at a temperature of 75 DEG C；
Hybrid reaction：30 parts of beeswaxs are added to the container be heated to 75 DEG C fusing, then be added 48 parts of modified vegetable oil, from
18 parts of sub- liquid, 5 parts of tristerin, 4 parts of polyvinyl alcohol, 4 parts of polyethyleneimine, 4 parts of fungicide, dodecyl sodium sulfate
5 parts, 15min is mixed, is eventually adding 20 parts of adjusting acid-base values of plant ash solution, 16min is mixed up to paper for daily use
Paper pulp releasing agent.
Embodiment 2：
The pre- modification of vegetable oil：Take 70 parts of vegetable oil to be put into reaction kettle, be added 21 parts of acetic acid solutions and 4 parts of highly acid sun from
Sub- resin catalyst increases temperature, while 45 parts of 30% hydrogen peroxide is slowly added dropwise, and after dripping hydrogen peroxide, maintains the temperature at 50 DEG C
6h is reacted, the washing of reusable heat sodium carbonate liquor evaporates water removal, add potassium hydroxide afterwards with saturated common salt water washing to neutrality
75 parts of ethanol solution reacts 40min to get modified vegetable oil in reaction kettle at a temperature of 60 DEG C；
Hybrid reaction：22 parts of beeswaxs are added to the container be heated to 60 DEG C fusing, then be added 45 parts of modified vegetable oil, from
15 parts of sub- liquid, 10 parts of tristerin, 3 parts of polyvinyl alcohol, 5 parts of polyethyleneimine, 3 parts of fungicide, dodecyl sodium sulfonate
5min is mixed in 10 parts of sodium, is eventually adding 10 parts of plant ash solution adjusting acid-base values, and 20min is mixed and lives to obtain the final product use
Paper paper pulp releasing agent.
Embodiment 3：
The pre- modification of vegetable oil：Take 85 parts of vegetable oil to be put into reaction kettle, be added 23 parts of acetic acid solutions and 3 parts of highly acid sun from
Sub- resin catalyst increases temperature, while 50 parts of 30% hydrogen peroxide is slowly added dropwise, and after dripping hydrogen peroxide, maintains the temperature at 52 DEG C
4h is reacted, the washing of reusable heat sodium carbonate liquor evaporates water removal, add potassium hydroxide afterwards with saturated common salt water washing to neutrality
75 parts of ethanol solution reacts 50min to get modified vegetable oil in reaction kettle at a temperature of 80 DEG C；
Hybrid reaction：20 parts of beeswaxs are added to the container be heated to 80 DEG C fusing, then be added 50 parts of modified vegetable oil, from
10 parts of sub- liquid, 6 parts of tristerin, 6 parts of polyvinyl alcohol, 2 parts of polyethyleneimine, 5 parts of fungicide, dodecyl sodium sulfate
8 parts, 20min is mixed, is eventually adding 12 parts of adjusting acid-base values of plant ash solution, 8min is mixed up to paper for daily use paper
Starch releasing agent.
Embodiment 4：
The pre- modification of vegetable oil：Take 80 parts of vegetable oil to be put into reaction kettle, be added 25 parts of acetic acid solutions and 4 parts of highly acid sun from
Sub- resin catalyst increases temperature, while 48 parts of 30% hydrogen peroxide is slowly added dropwise, and after dripping hydrogen peroxide, maintains the temperature at 55 DEG C
5h is reacted, the washing of reusable heat sodium carbonate liquor evaporates water removal, add potassium hydroxide afterwards with saturated common salt water washing to neutrality
80 parts of ethanol solution reacts 60min to get modified vegetable oil in reaction kettle at a temperature of 65 DEG C；
Hybrid reaction：28 parts of beeswaxs are added to the container be heated to 65 DEG C fusing, then be added 42 parts of modified vegetable oil, from
12 parts of sub- liquid, 8 parts of tristerin, 5 parts of polyvinyl alcohol, 3 parts of polyethyleneimine, 4 parts of fungicide, dodecyl sodium sulfate
9 parts, 10min is mixed, is eventually adding 15 parts of adjusting acid-base values of plant ash solution, 5min is mixed up to paper for daily use paper
Starch releasing agent.
Embodiment 5：
The pre- modification of vegetable oil：Take 75 parts of vegetable oil to be put into reaction kettle, be added 24 parts of acetic acid solutions and 2 parts of highly acid sun from
Sub- resin catalyst increases temperature, while 40 parts of 30% hydrogen peroxide is slowly added dropwise, and after dripping hydrogen peroxide, maintains the temperature at 58 DEG C
4.5h is reacted, the washing of reusable heat sodium carbonate liquor evaporates water removal, add hydroxide afterwards with saturated common salt water washing to neutrality
85 parts of potassium ethanol solution reacts 55min to get modified vegetable oil in reaction kettle at a temperature of 70 DEG C；
Hybrid reaction：25 parts of beeswaxs are added to the container be heated to 70 DEG C fusing, then be added 40 parts of modified vegetable oil, from
20 parts of sub- liquid, 7 parts of tristerin, 5 parts of polyvinyl alcohol, 5 parts of polyethyleneimine, 5 parts of fungicide, dodecyl sodium sulfate
7 parts, 18min is mixed, is eventually adding 18 parts of adjusting acid-base values of plant ash solution, 12min is mixed up to paper for daily use
Paper pulp releasing agent.
The paper for daily use paper pulp releasing agent is prepared according to the step method of above example, and the releasing agent is watered, is converted
The aqueous emulsion for changing 3% concentration into is measured its performance, and the performance parameter of the releasing agent of the present invention is as shown in the table：
1 releasing agent performance indicator of table
The paper for daily use paper pulp releasing agent that above example is prepared is respectively added in paper pulp pond, to purchase in the market
The common remover bought is added to as a contrast in paper pulp pond, and additive amount is 2.5kg/ tons of oven dry stocks, according to toilet paper
Production technology is produced.Obtained product properties are measured, the target level of product quality of production is with reference to GB 20810-2006
《Toilet paper（Body paper containing toilet paper）》Specifications, measurement result is as shown in the table：
The technical indicator of 2 paper product of table
The above embodiment of the present invention scheme is only the description of the invention and cannot limit the present invention, is pointed out in claim
Product form ingredient of the present invention, at range, and above-mentioned explanation does not point out the range of parameter of the present invention, therefore, with this
Any change in comparable point of ratio of claims of invention, the meaning and scope of preparation method parameter, all it will be understood that
It is included in the range of claims.
The present invention is and to pass through creative work by multidigit paper production investigative technique personnel's long-term work experience accumulation
It creates, releasing agent produced by the present invention has good lubricity, stability series, and function and effect are good, harmless, green
Environmental protection, easily biological-degradable are added to pulp production, and the brightness of the paper of gained is 85 ~ 90%, tensile index 4.0
~ 4.5N.m/g, pliability are 105 ~ 114N.m/g, are formed by that hole eye is few, the quality of product effectively improves, and meets national mark
It is accurate.
Claims (3)
1. a kind of paper for daily use paper pulp releasing agent, characterized in that each constituent and its matter of the paper for daily use paper pulp releasing agent
Measuring portion rate is：It is 40 ~ 50 parts of modified vegetable oil, 20 ~ 30 parts of beeswax, 10 ~ 20 parts of ionic liquid, 10 ~ 20 parts of plant ash solution, hard
5 ~ 10 parts of glycerol, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, 3 ~ 5 parts of fungicide, dodecyl sodium sulfate 5 ~ 10
Part；
The ionic liquid is one kind in 1- butyl -3- methylimidazole villaumites or 1- ethyl -3- methyl-phosphoric acid dimethyl ester salt
Above combination；
The fungicide be Dow fungicide 7287, Dow fungicide 8536, isothiazolinone biocide agent mixing；
The modified vegetable oil is prepared by following steps：70 ~ 85 parts of vegetable oil are taken to be put into reaction kettle, addition 20 ~
25 parts of acetic acid solutions and 2 ~ 4 parts of strong acidic ion resin catalyst increase temperature, while 30% hydrogen peroxide 40 ~ 50 are slowly added dropwise
Part, after dripping hydrogen peroxide, maintain the temperature at 50 ~ 60 DEG C reaction 4 ~ 6h, reusable heat sodium carbonate liquor washing, after use saturated common salt
Water washing to neutrality, evaporation water removal adds 70 ~ 85 parts of potassium hydroxide-ethanol solution in reaction kettle, in 60 ~ 80 DEG C of temperature
30 ~ 60min is to get modified vegetable oil for lower reaction.
2. a kind of paper for daily use paper pulp releasing agent according to claim 1, characterized in that the modified vegetable oil is by dish
The combination of one or more of seed oil, castor oil, corn oil, soybean oil is modified to obtain.
3. a kind of method preparing claim 1 ~ 2 any one of them paper for daily use paper pulp releasing agent, characterized in that preparation side
Method step includes：
Step 1）The pre- modification of vegetable oil：It takes 70 ~ 85 parts of vegetable oil to be put into reaction kettle, 20 ~ 25 parts of acetic acid solutions and 2 ~ 4 parts is added
Strong acidic ion resin catalyst increases temperature, while 40 ~ 50 parts of 30% hydrogen peroxide is slowly added dropwise, after dripping hydrogen peroxide,
Maintain the temperature at 50 ~ 60 DEG C of 4 ~ 6h of reaction, reusable heat sodium carbonate liquor washing, afterwards with saturated common salt water washing to neutrality, evaporation
Water removal, adds 70 ~ 85 parts of potassium hydroxide-ethanol solution in reaction kettle, 30 ~ 60min is reacted at a temperature of 60 ~ 80 DEG C, i.e.,
Obtain modified vegetable oil；
Step 2）Hybrid reaction：20 ~ 30 parts of beeswaxs are added to the container and are heated to 60 ~ 80 DEG C of fusings, improved plant is then added
40 ~ 50 parts of oil, 5 ~ 10 parts of tristerin, 3 ~ 6 parts of polyvinyl alcohol, 2 ~ 6 parts of polyethyleneimine, kills at 10 ~ 20 parts of ionic liquid
5 ~ 20min is mixed in 3 ~ 5 parts of microbial inoculum, 5 ~ 10 parts of dodecyl sodium sulfate, is eventually adding 10 ~ 20 parts of adjustings of plant ash solution
5 ~ 20min is mixed up to paper for daily use paper pulp releasing agent in acid-base value.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810940860.1A CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940361.2A CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
| CN201810940354.2A CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN201710938508.XA CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710938508.XA CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810940354.2A Division CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
| CN201810940860.1A Division CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940361.2A Division CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107447579A CN107447579A (en) | 2017-12-08 |
| CN107447579B true CN107447579B (en) | 2018-10-09 |
Family
ID=60498744
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710938508.XA Active CN107447579B (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp releasing agent and preparation method thereof |
| CN201810940361.2A Withdrawn CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
| CN201810940860.1A Withdrawn CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940354.2A Withdrawn CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
Family Applications After (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810940361.2A Withdrawn CN108978337A (en) | 2017-10-11 | 2017-10-11 | Paper for daily use paper pulp release agent and preparation method thereof |
| CN201810940860.1A Withdrawn CN108914690A (en) | 2017-10-11 | 2017-10-11 | A kind of manufacture craft of paper for daily use paper pulp release agent |
| CN201810940354.2A Withdrawn CN108914689A (en) | 2017-10-11 | 2017-10-11 | A kind of paper for daily use paper pulp release agent and its preparation process |
Country Status (1)
| Country | Link |
|---|---|
| CN (4) | CN107447579B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109175222B (en) * | 2018-07-27 | 2020-08-14 | 舒城县金禾油脂科技开发有限公司 | Mold release agent based on bran wax oil and preparation process thereof |
| CN110065149B (en) * | 2019-04-15 | 2021-05-25 | 广西利升石业有限公司 | Spray type release agent for producing artificial stone, preparation method and use method thereof |
| CN110176179A (en) * | 2019-05-17 | 2019-08-27 | 宁波卓越印务有限公司 | A kind of multi-functional adhesive label and preparation method thereof |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5658374A (en) * | 1995-02-28 | 1997-08-19 | Buckman Laboratories International, Inc. | Aqueous lecithin-based release aids and methods of using the same |
| DE19810031A1 (en) * | 1998-03-09 | 1999-09-16 | Acheson Ind Inc | Anhydrous release agent / lubricant for treating the walls of a mold for primary shaping or forming |
| TW200422486A (en) * | 2003-02-18 | 2004-11-01 | Maintech Co Ltd | Method for preventing paper web surface from fraying in papermaking machine, printing paper for use in offset printing, and release agent |
| JP4973040B2 (en) * | 2006-07-12 | 2012-07-11 | 星光Ｐｍｃ株式会社 | Release agent for crepes |
| US8444812B2 (en) * | 2008-11-18 | 2013-05-21 | Nalco Company | Creping adhesives with improved film properties |
| US20110297341A1 (en) * | 2010-06-07 | 2011-12-08 | Dilkus Christopher P | Creping Release Agents |
| US20130048238A1 (en) * | 2011-08-22 | 2013-02-28 | Buckman Laboratories International, Inc. | Oil-Based Creping Release Aid Formulation |
| CN102504924B (en) * | 2011-11-09 | 2013-07-31 | 合肥工业大学 | Polysilsesquioxane (POSS) modified vegetable oil emulsion mold release agent and preparation method thereof |
| CN102876462B (en) * | 2012-10-15 | 2013-10-09 | 南京工业大学 | Method for preparing high-quality epoxidized soybean oil |
| CN103266016A (en) * | 2013-06-04 | 2013-08-28 | 合肥工业大学 | Method for preparing organic silicon modified plant oil |
| CN103320211B (en) * | 2013-07-10 | 2015-01-14 | 合肥工业大学 | Method for preparing polyether lubricating oil by modified plant oil |
| CN103774495B (en) * | 2014-02-12 | 2015-12-30 | 南宁飞日润滑油有限公司 | High energy paper pulp releasing agent and production method thereof |
| CN104389232B (en) * | 2014-10-23 | 2016-08-24 | 广东比伦生活用纸有限公司 | The paper for daily use of a kind of super soft perfuming and production method thereof |
| KR102574848B1 (en) * | 2014-12-12 | 2023-09-06 | 솔레니스 테크놀러지스 케이맨, 엘.피. | Method of producing a creping paper and the creping paper thereof |
| CN105479629A (en) * | 2015-12-06 | 2016-04-13 | 刘方旭 | Preparation method of environment-friendly emulsified releasing agent |
| CN105802697B (en) * | 2016-03-24 | 2018-12-18 | 德易普（天津）科技有限公司 | A kind of preparation method of the degradable methanol engine lubricating oil of improved plant oil base |
-
2017
- 2017-10-11 CN CN201710938508.XA patent/CN107447579B/en active Active
- 2017-10-11 CN CN201810940361.2A patent/CN108978337A/en not_active Withdrawn
- 2017-10-11 CN CN201810940860.1A patent/CN108914690A/en not_active Withdrawn
- 2017-10-11 CN CN201810940354.2A patent/CN108914689A/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CN108914690A (en) | 2018-11-30 |
| CN108914689A (en) | 2018-11-30 |
| CN107447579A (en) | 2017-12-08 |
| CN108978337A (en) | 2018-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107447579B (en) | A kind of paper for daily use paper pulp releasing agent and preparation method thereof | |
| CN104736749B (en) | Fibril, fiber non-woven fibre web comprising micro- fibril cellulose with and preparation method thereof | |
| CN101600788B (en) | Wiping products having enhanced cleaning abilities | |
| TW213965B (en) | ||
| CN101633781B (en) | Emulsion composition, method for softening fiber structure and fiber containing base material | |
| KR101728576B1 (en) | Water-resistant/oil-resistant agent composition, article treated with the composition, and processes for production of the composition and the article | |
| AU2011263363B2 (en) | Tissue products containing microalgae materials | |
| KR101877081B1 (en) | Bacteriostatic tissue product | |
| KR20130054333A (en) | Degradable superabsorbent polymers | |
| JPWO2013005247A1 (en) | Antifouling composition | |
| CN103183995A (en) | Water-based paint composition | |
| CN106580837A (en) | Whitening and moisture supplementing mask | |
| Brentin | Soy-based chemicals and materials: growing the value chain | |
| KR101274792B1 (en) | Oil control paper containing marine algae for removing skin oil and the method for manufacturing thereof | |
| CN101108985B (en) | Paraffin wax emulsions modified with petroleum resin and method of manufacturing the same | |
| CN108166156A (en) | One kind is degradable, easily breaks up vegetable fiber environmental protection material | |
| JP2007303028A (en) | Moisture-retaining paper and method for producing the same | |
| CN107524049B (en) | High-energy paper pulp release agent and preparation method thereof | |
| CN112900146A (en) | Impregnated adhesive film paper with fragrance and preparation method thereof | |
| CN107177148A (en) | Modified starch PVA bases are combined express packaging bag film and preparation method | |
| CN107675557A (en) | A kind of cultural paper in the office paper pulp releasing agent and preparation method thereof | |
| CN103774495B (en) | High energy paper pulp releasing agent and production method thereof | |
| CN101883832B (en) | Water-holding material and water-absorbing gel composition excellent in light resistance | |
| MXPA97001767A (en) | Topical composition clear spray for care of the skin with insoluble perfume in a | |
| CN107476102A (en) | A kind of hydrolyzable can break up the preparation technology of hygenic towelette |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180809 Address after: 755000 A center, Zhongguancun science and Technology Industrial Park, the Ningxia Hui Autonomous Region, China. Applicant after: NINGXIA RUISHENG MINGJIE INTELLECTUAL PROPERTY CONSULTING CO.,LTD. Address before: 530028 No. 409, Haotian Plaza, 24 Long Lake Road, Qingxiu District, Nanning, the Guangxi Zhuang Autonomous Region Applicant before: GUANGXI NANNING RONGWEIDE NEW ENERGY TECHNOLOGY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231130 Address after: 324400, No. 9 Dingxin Road East, Zhejiang Longyou Economic Development Zone, Longyou County, Quzhou City, Zhejiang Province Patentee after: Zhejiang Herun Biotechnology Co.,Ltd. Address before: 755000 A center, Zhongguancun science and Technology Industrial Park, the Ningxia Hui Autonomous Region, China. Patentee before: NINGXIA RUISHENG MINGJIE INTELLECTUAL PROPERTY CONSULTING CO.,LTD. |
|
| TR01 | Transfer of patent right |