CN110062619A - Remove the solid water-free composition containing hydrophobic polymer of cosmetics on skin - Google Patents
Remove the solid water-free composition containing hydrophobic polymer of cosmetics on skin Download PDFInfo
- Publication number
- CN110062619A CN110062619A CN201680091039.6A CN201680091039A CN110062619A CN 110062619 A CN110062619 A CN 110062619A CN 201680091039 A CN201680091039 A CN 201680091039A CN 110062619 A CN110062619 A CN 110062619A
- Authority
- CN
- China
- Prior art keywords
- composition
- ester
- oil
- hydrocarbon
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Abstract
A kind of solid water-free composition is selected from the group that poly- (ester-acid amide) that is blocked by ester and its mixture form comprising a) at least one hydrophobic polymer, the hydrophobic polymer；B) at least one hydrocarbon-type oil；And c) at least one nonionic surfactant.The composition is for cleaning keratin material and/or removing ornaments and formal dress from keratin material.
Description
Technical field
The present invention relates to a kind of solid water-free composition comprising hydrophobic polymer, it is especially suitable for cleaning keratin
Material and/or cosmetics are removed from keratin material.
The invention further relates to the beauty sides for using the composition to clean and/or remove the cosmetics on keratin material
Method.
Background technique
In the field of cleaning and/or cleansing composition, " soft solid " composition constitutes a kind of product, and consumer appreciates it
The effect of in terms of cleaning, makeup removing, rinse capability and its beauty performance (softness, dry feeling, easy to use etc.).They are referred to as
Solid composite softens under the action of stress, such as extends on the surface of skin, such as via with perforated wall
The device of (grid) squeezes out.
Consumer seeks the composition for cleaning skin and/or " soft solid " type for removing cosmetics, this combination
Object makes not having any residue on skin and skin is made to have pure and fresh skin modification (skin finish), while being easy to apply
For skin.
Some known soft solid compositions for cleaning skin and/or removal cosmetics include aerosil
Grain, wax, hydrocarbon-type oil and nonionic surfactant.
However it remains to having the solid compositions for being suitable for cleaning skin and/or removing cosmetics for improving property
The demand of object.
Specifically, however it remains to can particularly easily and quickly apply, that is, be easy to extend on the skin is improved solid
The demand of body composition.
Preferably being expected these compositions makes do not have any residue on skin.
Summary of the invention
The object of the present invention is to provide a kind of solid and anhydrous composition, with good effects, such as good
Cosmetics ability and rinse capability are removed, and there is improved beauty performance, such as easy to use.
Preferably, the object of the present invention is to provide as described above with good effects solid and anhydrous composition,
And its have improveds beauty performance, such as easy to use, noresidue sense, and while it is stable at any time.
It is a further object to provide a kind of solid and anhydrous composition, be easy to be applied to keratin material
On material, especially on skin.
It is a further object to provide it is a kind of especially for from skin remove cosmetics solid and nothing
The composition of water can be carried easily in a device.
Therefore, the present invention relates to a kind of solid water-free compositions, and the solid water-free composition includes:
A) at least one hydrophobic polymer, the hydrophobic polymer be selected from poly- (ester-acid amide) blocked by ester and its
The group of mixture composition；
B) at least one hydrocarbon-type oil；With
C) at least one nonionic surfactant；
Its condition is that the nonionic surfactant is not PEG-30 dimerization hydroxy stearic acid ester.
The invention further relates to a kind of for handling and/or nursing the beauty of keratin material, especially skin and/or lip
Method, which is characterized in that this method includes at least one composition according to the present invention of surface applied to keratin material
Step.
The invention further relates to a kind of for cleaning and/or removing the beauty method of the cosmetics on keratin material, the party
Method include the surface to keratin material, especially skin surface on apply the step of at least one composition according to the present invention
Suddenly.
The inventors discovered that composition according to the present invention is on keratin material compared with other solid composites
Scalability and application properties are improved, and the time needed for softening and applying composition is less.
In addition, skin modification is also improved, without residual sense after flushing.
Advantageously, composition according to the present invention can be transparent, to provide the appearance of pleasant for composition.
Composition according to the present invention is also stable.
In addition, the composition have required hardness, to be adapted to tank, equipped with the device of open wall, equipped with ball
The device of dauber or in the form of stick (bar).
Definition
Term " solid " composition indicates the form of the composition at 20 DEG C, and particularly, and term " solid " indicates,
When being measured according to following proposal, the hardness at 20 DEG C and at atmospheric pressure (760mmHg) is greater than or equal to 30Nm-1Combination
Object.
The hardness of solid composite is measured according to following scheme.
Before measuring hardness, the composition of hardness to be determined is stored 24 hours at 20 DEG C.It can be passed through at 20 DEG C
Hardness is measured by " cheese silk " method, this method is by means of diameter to be 250 μm of rigid tungsten wire, by relative to product stick with
The mobile silk of the speed of 100mm/min carrys out transverse cuts product stick, is preferably cylindrical body.
The hardness of the sample of composition of the invention is with Nm-1It indicates, using from Indelco-Chatillon company
DFGS2 cupping machine measures.It measures and is then averaged in triplicate.Providing with gram uses above-mentioned tension test machine-readable
The average value of three values taken, is denoted as Y.The average value is converted to newton and then (it represents the silk and passes through most divided by L
Over long distances).In the case where cylindrical bar, L is equal to diameter (in meters).
Hardness is converted into Nm by following equation-1:
(Y×10-3×9.8)/L
For measurement at different temperatures, before measuring, the stick is stored 24 hours at a temperature of this is newly.
According to preferred embodiment, composition of the invention, which has, is greater than or equal to 40Nm-1, more preferable range be
50Nm-1~300Nm-1, even more preferably range be 60Nm-1~120Nm-1Hardness.
Term " anhydrous composition " is indicated containing the water less than 2wt% or even less than 0.5wt% water, especially not aqueous
Composition, the water is not the remnants for adding during composition preparation and corresponding to be provided by each ingredient for mixing
Water.
" rinse capability " refers to after composition of the invention is administered on skin, is easy by what water rinsed out
Degree.
" noresidue sense " refers to have dry skin and pure and fresh feeling after rinsing out composition of the invention.Implement at one
In mode, after rinsing out composition of the invention, skin does not have greasy feeling or wax sense.
" extended capability " refer to composition on keratin material application (when being applied on keratin material, solid group
Close object " softening ") and/or extend easness.
Term " keratin material " refers to the skin (around body, face and eyes)；Hair；Eyelashes；Eyebrow；Body hair
Hair；Nail；Lip or mucous membrane, preferably skin.
Term " transparent " can be indicated by the turbidity of the present composition, can be used from HACH company
2100P type nephelometer measures at room temperature according to NTU method.
Advantageously, the turbidity of solid water-free composition of the invention be less than 400NTU unit, and preferably 50NTU unit~
350NTU unit.
Specific embodiment
Composition of the invention aims to solve the problem that the problem of being listed above.
More specifically, composition of the invention is the solid for cleaning and/or removing the cosmetics on keratin material
Anhydrous composition.
Preferably, composition of the invention is cosmetic composition, more preferably for from keratin material, especially
The cosmetic composition of cosmetics is removed from skin.In a specific embodiment, cosmetics are removed from skin of face.
In one embodiment, composition according to the present invention does not include wax.In one embodiment, according to this hair
Bright composition is gel form.In one embodiment, composition according to the present invention is transparent.
Hydrophobic polymer
Composition according to the present invention includes the hydrophobic polymer of at least one poly- (ester-acid amide) selected from ester sealing end.
" hydrophobicity " refers to the polymer for repelling water, i.e., water-immiscible polymer.
" ester sealing end " polymer refers to comprising at least one chemical function ester (Ra-C (O)-O-R ' a) as end section
Polymer.For example, this quasi polymer and preparation method thereof is described in 02/092663 patent application of WO.
In one embodiment, the polymer includes at least one optionally hydrogenated dimerization dilinoleic acid ester units.
Preferably, the hydrophobic polymer is stearic bicine diester ethylenediamine/neopentyl glycol/hydrogenation dimerdilinoleate copolymer.It is special
It is not mentioned that (CAS RN is 678991-29- to stearic bicine diester ethylenediamine/neopentyl glycol/hydrogenation dimerdilinoleate copolymer
2), also referred to as polyamide -8, by Arizona Chemical with trade name SylvaclearTMC75V or by Croda, Inc. with
Trade name OleoCraft LP-20 sale.
In one embodiment, composition according to the present invention only includes a kind of hydrophobic polymer.It is specific at one
In embodiment, composition of the invention does not include the polyamide polymer of ester sealing end, such as two Asia of ethylenediamine stearyl alcohol dimerization
Oleic acid ester copolymer.
In one embodiment, based on the total weight of composition, the amount of the hydrophobic polymer for including be 1wt%~
20wt%, it is preferable that the total weight based on composition, the amount for the hydrophobic polymer for including are 5wt%~15wt%, for example,
About 10wt%.
Hydrocarbon-type oil
According to the present invention, the composition includes at least one hydrocarbon-type oil.
Term " oil " refers to the fatty material under room temperature (25 DEG C) and atmospheric pressure (760mmHg, i.e. 105Pa) for liquid.
The oil can be volatile or non-volatile.
For purposes of the present invention, term " ethereal oil " refer at room temperature and atmospheric pressure with skin or keratin fiber
The oil that can be evaporated in less than one hour after contact.Ethereal oil of the invention is the volatility beauty for being at room temperature liquid
With oil, there is non-zero vapor pressure at room temperature and atmospheric pressure, range is specifically for 0.13Pa~40000Pa (10-3MmHg~
300mmHg), especially range be 1.3Pa~13000Pa (0.01mmHg~100mmHg), more particularly range be 1.3Pa~
1300Pa (0.01mmHg~10mmHg).Term " nonvolatile oil " refers to fine in skin or keratin at room temperature and atmospheric pressure
Retain the oil of at least a few hours in dimension, and especially vapour pressure is less than 10-3The oil of mmHg (0.13Pa).
Oil according to the present invention be preferably selected from it is any said in terms of beauty acceptable oil, especially mineral oil, animal oil,
Or mixtures thereof vegetable oil or synthetic oil,.
Term " hydrocarbon-type oil ", which refers to, to be mainly contained carbon and hydrogen atom and may have selected from hydroxyl, ester, ether and carboxyl official
The oil of one of energy group or a variety of functional groups.In general, the viscosity of the oil is 0.5mPas~100000mPas,
Preferably 50mPas~50000mPas, more preferably 100mPas~300000mPas.
As the example of volatile hydrocarbon oil for use in the present invention, can be mentioned that:
Volatile hydrocarbon oil is selected from the hydrocarbon-type oil containing 8~16 carbon atoms, and the C of especially petroleum resources8~C16
Isoalkane (also referred to as different alkane warp), such as: Permethyl 99A (also referred to as 2,2,4,4,6- five methylheptanes), isodecane and different ten
Six alkane, such as with the oil of trade name Isopar or Permethy1 sale, branch C8~C16Ester and isohexyl neopentanoate ester, and its it is mixed
Close object.Other volatile hydrocarbon oil, such as petroleum distillate also can be used, especially by Shell company with title Shell
Those of Solt sale；Volatile linear alkane, such as it is described in the patent application DE10 2,008 012 from Cognis company
Those of in 457.
As the example of non-volatile hydro carbons oil for use in the present invention, can be mentioned that:
The hydrocarbon-type oil of animal origin, such as perhydro squalene；
Hydro carbons vegetable oil, for example, 4~24 carbon atoms fatty acid liquid triglycerides, such as enanthic acid or sad glycerol
Three esters or wheat-germ oil, olive oil, Sweet Almond Oil, palm oil, rapeseed oil, cottonseed oil, alfalfa oil, poppy seed oil, squash oil,
Marrow oil, blackcurrant oil, evening primrose oil, millet oil, big wheat oil, goosefoot oil, rye-seed oil, safflower oil, candlenut oil, passionflower
Oil, musk rose oil, sunflower oil, corn oil, soybean oil, grape seed oil, sesame seed oil, hazelnut oil, apricot oil, Macadamia nut oil,
Castor oil, avocado oil, caprylic/capric triglyceride, for example, by St é arineries Dubois company sell those of or by
Dynamit Nobel company with those of sale of title Miglyol 810,812 and 818, jojoba oil and shea butter,
The linear chain or branched chain hydrocarbon of mineral or synthesis source, for example, it is liquid paraffin and its derivant, petroleum jelly, poly decene, poly-
Butylene, Parleam such as Parleam and saualane,
Synthesis ether containing 10~40 carbon atoms；
The synthetic ester of synthetic ester, especially fatty acid, such as formula R1COOR2Oil, wherein R1It represents and contains 1~40 carbon
The linear chain or branched chain higher fatty acid residue of atom, and R2Hydrocarbon chain, especially branch are represented, 1~40 carbon atom is contained,
Wherein, R1+R2>=10, for example, duck oil gland oily (cetearyl octanoate), isononyl isononanoate, isopropyl myristate,
Isopropyl palmitate, C12~C15Alkyl benzoate, lauric acid hexyl ester, diisopropyl adipate, isononyl isononanoate, palm
Sour 2- ethylhexyl, stearic acid 2- octyldodecyl, erucic acid 2- octyldodecyl, isooctadecanol isostearate or
Trimellitic acid tridecane base ester；Alcohol or polyalcohol caprylate, decylate or ricinoleate, such as two sad propylene glycol esters；Hydroxyl
Base ester, such as isooctadecanol lactate, octyl hydroxystearate, hydroxy stearic acid octyldodecyl, two isooctadecanols
Malate, three different cetanol citrates and fatty alcohol heptanoate, caprylate or decylate；Polyol ester, such as two octanoic acids
Two isononoate of propylene glycol ester, two enanthic acid neopentyl glycol ester or diethylene glycol (DEG)；And pentaerythritol ester, such as the different tristearin of pentaerythrite four
Acid esters,
At room temperature it is the fatty alcohol of liquid, contains branch and/or unsaturated carbon comprising 12~26 carbon atoms
Chain, such as octyldodecanol, isooctadecanol, 2- butyl octanol, 2- hexyl decyl alcohol, 2- undecylpentadecanol or oleyl alcohol,
Higher fatty acids, such as oleic acid, linoleic acid or linolenic acid；
Carbonic ester；
Acetic acid esters；
Citrate.
In one embodiment, hydrocarbon-type oil is selected from the group by following material composition: the C of petroleum resources8~C16Isoalkane；
The C of branch8~C16Ester and isohexyl neopentanoate ester；The non-volatile hydro carbons oil or vegetable oil of animal origin；Mineral or synthesis source
Linear chain or branched chain hydrocarbon；Synthesis ether containing 10~40 carbon atoms；Synthetic ester；It is the fatty alcohol of liquid at 25 DEG C；It is advanced
Fatty acid, such as oleic acid, linoleic acid；Carbonic ester；Acetic acid esters；Citrate and their mixture；It is preferably selected from the conjunction of fatty acid
At ester.
In a specific embodiment, hydrocarbon-type oil is selected from by following material composition group:
Selected from the volatile hydrocarbon oil containing 8~16 carbon atoms, the especially C of petroleum resources8~C16Isoalkane, it is such as different
Dodecane, isodecane and isohexadecane；
The linear chain or branched chain hydrocarbon of mineral or synthesis source, for example, it is liquid paraffin and its derivant, petroleum jelly, poly decene, poly-
Butylene, Parleam and squalene；With
The aliphatic ester of synthesis,
With their mixture.
Using above-mentioned hydrocarbon-type oil, composition according to the present invention is advantageously transparent.
In another embodiment, hydrocarbon-type oil is selected from the group of following material composition: the synthetic ester of fatty acid, such as
Cetearyl octanoate, isononyl isononanoate, isopropyl myristate, isopropyl palmitate, C12-C15Alkyl benzoate,
Lauric acid hexyl ester, diisopropyl adipate, isononyl isononanoate, palmitinic acid 2- ethylhexyl, stearic acid 2- octyldodecyl
Ester, erucic acid 2- octyldodecyl, isooctadecanol isostearate or trimellitic acid tridecane base ester；Alcohol or polyalcohol octanoic acid
Salt, decylate or ricinoleate, such as two sad propylene glycol esters；Hydroxylating ester, such as isooctadecanol lactate, hydroxy stearate
Misery ester, hydroxy stearic acid octyldodecyl, diisooctadecanol malate, three different cetanol citrates, and fat
Alcohol heptanoate, caprylate or decylate；Polyol ester, such as two sad propylene glycol esters, two enanthic acid neopentyl glycol ester or diethylene glycol (DEG)
Two isononoates；And pentaerythritol ester, such as pentaerythritol tetraoctyl stearate or their mixture.
As the explanation for being suitable for the invention oil, it is particularly possible to refer to non-volatile hydro carbons oil, such as synthetic ester.It can be with
Such oil, such as palmitinic acid 2- ethylhexyl are referred to, by Stearinerie Dubois company with trade name Palmitate
D ' ethyl 2Hexyle is sold, or sold by BASF AGC24。
Preferably, the hydrocarbon-type oil is the synthetic ester of fatty acid, more preferably palmitinic acid 2- ethylhexyl.
In one embodiment, based on the total weight of composition, the amount for the hydrocarbon-type oil for including in composition is 55wt%
~98wt%；The amount of total weight based on composition, the hydrocarbon-type oil for including in composition is preferably 65wt%~95wt%, more excellent
It is selected as 80wt%~90wt%, for example, about 85wt%.
Nonionic surfactant
Surfactant is usually amphiphilic organic compound, it means that they contain hydrophobic group (they
Tail portion) and hydrophilic radical (their head)." nonionic surfactant ", which refers to, does not have the table of charged group on its head
Face activating agent (i.e. the charge of hydrophilic radical is neutrality).
Composition of the invention includes at least one nonionic surfactant, and condition is the nonionic surfactant
It is not PEG-30 dimerization hydroxy stearic acid ester (composition i.e. according to the present invention does not include PEG-30 dimerization hydroxy stearic acid ester).
PEG-30 dimerization hydroxy stearic acid ester is the polyethylene glycol di of multi-hydroxy stearic acid.
In one embodiment, composition of the invention includes at least one nonionic surfactant, and condition is institute
Nonionic surfactant is stated without lower formula (I):
Wherein, R and R' indicate C independently of one another10~C20Alkyl, preferably C17Alkyl, the alkyl is by least one hydroxyl
Base replaces, wherein the integer that n is 20~40, preferably from about 30 integer.
Preferably, R and R' is derived from multi-hydroxy stearic acid.In one embodiment, R and R' has lower formula (II) and n
It is about 30:
CH3-(CH2)5-CH(OH)-(CH2)10- (II)。
In a specific embodiment, composition of the invention does not include PEG-30 dimerization hydroxy stearate as described above
Acid esters and diisooctadecanol malate.
More specifically, composition according to the present invention include at least one oxygen alkylene aliphatic ester selected from glycerol it is non-from
Sub- surfactant.
According to the present invention, the oxygen alkene chain of the oxygen alkylene aliphatic ester of glycerol is preferably oxyethylene chain.
It is highly preferred that it can contain, such as 1 to 150 oxyalkylene, especially ethylene oxide group, preferably 2 to 100 oxygen
Change alkene, especially ethylene oxide group.
The composition can also contain one or more other non-ionic emulsifier surfactants.
The mixture of surfactant or surfactant preferably has 5~20, preferably 8~18 HLB (Hydrophile-Lipophile
Balance), and it should dissolve in oily phase.Also the surfactant that HLB is greater than 20 can be used, condition is that one is added thereto
Kind or a variety of other surfactants, so that the HLB of mixture is 5~15.
The example of the oxygen alkylene aliphatic ester for the glycerol that can be mentioned that more specifically includes that (INCI) PEG-20 glycerol three is different
Stearate, PEG-7 glyceryl cocoate, -2 oleate of polyglycereol and their mixture.
As the example of nonionic surfactant, PEG-20 glyceryl triisostearate can be mentioned that, such as by Nihon
Emulsion company is with those of trade name Emalex Gwis-320EX sale.
The example for the other nonionic surfactants that can be mentioned that includes oxygen alkylene aliphatic ester, the fat of anhydrous sorbitol
The ester of acid and polyalcohol；The ether and their mixture of the oxygen alkylene or non-oxygen alkylene of fatty alcohol and polyalcohol.
It can be mentioned that such surfactant more specifically include:
The oxyethylation aliphatic ester of anhydrous sorbitol, for example, it is (INCI) polysorbate20, polysorbate65, poly-
Sorbitol ester 85, PEG-5 anhydrous sorbitol isostearate, three isostearate of PEG-20 anhydrous sorbitol, PEG-20 dehydration
Sorbierite isostearate, seven oleate of PEG-40 anhydrous sorbitol (sorbitan septaoleate), PEG-20 dehydration mountain
Four oleate of pears alcohol and PEG-20 sorbitan trioleate；
The aliphatic ester of polyglycereol, such as three isostearate of (INCI) polyglycereol-3-, the different tristearin of Natrulon H-10-two
Acid esters ,-6 isostearate of polyglycereol, polyglyceryl-3 diisostearate, Natrulon H-10-trioleate or Natrulon H-10-three
Laurate；
The aliphatic ester of polyethylene glycol, such as (INCI) PEG-8 stearate, PEG-6 oleate, the different tristearin of PEG-6
Acid esters, PEG-12 isostearate, PEG-12 diisopstearate, PEG-8 isostearate, PEG-8 diisopstearate or
PEG-10 isostearate；
It is oxygen alkylene, especially oxyethylation and/or oxypropylation, the more particularly fatty alkyl ether of oxyethylation,
Such as ceteareth -12 and ceteareth -20 (INCI), and containing their mixture, such as by
Mixture that Cognis company is sold with title Emulgade CM (cetostearyl alcohol isononoate, ceteareth -20,
Cetostearyl alcohol, tristerin, glycerol, ceteareth -12 and cetin mixture)；
And their mixture.
It can be mentioned that polysorbate20, such as by Croda company with trade name TweenTM20-LQ- (AP) sale that
A bit.
In one embodiment, based on the total weight of composition, the nonionic that includes in composition according to the present invention
The amount of surfactant is 1wt%~20wt%, and the total weight based on composition, include in composition according to the present invention is non-
The amount of ionic surface active agent is preferably 1wt%~10wt%, e.g., about 5wt%.
Adjuvant
Using known mode, composition of the invention is also containing auxiliary common in cosmetics and/or dermatology
Agent, for example, preservative, antioxidant, complexing agent, pH adjusting agent (acid or alkalinity), fragrance, filler, fungicide, odor absorber,
Toner (pigment and dyestuff), film forming polymer, surfactant in addition such as anion, both sexes, cation or nonionic table
Face activating agent；In addition oil such as silicone oil or fluoro oil, thickener and/or gelling agent and active constituent.
Term " silicone oil " refers to oil in its structure comprising carbon atom and at least one silicon atom.
Term " fluoro oil ", which refers to, is based partially on hydrocarbon and/or based on silicone oil comprising carbon atom and fluorine atom.
As the example of non-volatile silicone oil, straight chain or cyclic annular non-volatile dimethicones (PDMS) can be mentioned that；
Dimethyl silicone polymer comprising alkyl, alkoxy or phenyl, group pendency in silicone chains or in the end of silicone chains,
These groups contain 2~24 carbon atoms；Phenyl silicones, for example, phenyl trimethicone, phenyl dimethicones,
Phenyl trimethicone siloxy diphenyl siloxane, diphenyl dimethicone, three silicon oxygen of diphenyl methyl diphenyl
Alkane and 2- phenethyl trimethylsiloxysilicate and their mixture.
Without superfluous words, those skilled in the art will select this or these optional added compounds and/or its amount with caution,
So that the property of composition according to the present invention will not or not will receive the adverse effect for imagining addition substantially.
Galenic form
Composition according to the present invention can for frost, balm, hair cream or gel form, hardness can with it is required apply, to
The region of the human keratin material of processing and it is required conditioning and become.
Composition according to the present invention be adaptable to tank, equipped with open wall equipment (especially grid), equipped with
The equipment (" roll-on ") of ball dauber；In the form of stick (bar).In this regard, they contain commonly used in the type product at
Point, the ingredient is well-known to those skilled in the art.
In a specific embodiment, based on the total weight of composition, composition according to the present invention includes:
The hydrophobic polymer of at least one poly- (ester-acid amide) selected from ester sealing end of 1wt%~20wt%；
The nonionic surfactant of at least one oxygen alkylene aliphatic ester selected from glycerol of 1wt%~20wt%；With
At least one hydrocarbon-type oil.
More particularly it relates to a kind of for cleaning keratin material, especially skin and/or from keratin material
On, the solid water-free composition of cosmetics, the total weight based on composition, the solid water-free combination are removed especially on skin
Object includes:
The hydrophobic polymer of at least one poly- (ester-acid amide) selected from ester sealing end of 1wt%~20wt%；
The nonionic surfactant of at least one oxygen alkylene aliphatic ester selected from glycerol of 1wt%~20wt%；With
At least one hydrocarbon-type oil.
In one embodiment, composition of the invention includes:
Stearic bicine diester ethylenediamine/neopentyl glycol/hydrogenation dimerdilinoleate copolymer,
The synthetic ester of fatty acid, such as palmitinic acid 2- ethylhexyl, and
PEG-20 glyceryl triisostearate.
In one embodiment, based on the total weight of composition, composition of the invention includes:
Stearic bicine diester ethylenediamine/neopentyl glycol/hydrogenation dimerdilinoleate copolymer of 10wt%,
Palmitinic acid 2- ethylhexyl, and
The PEG-20 glyceryl triisostearate of 5wt%.
The invention further relates to a kind of for handling and/or nursing the beauty method of keratin material, it is characterised in that the party
Method includes at least one foregoing composition of surface applied to keratin material.
The invention further relates to a kind of for removing the beauty method of cosmetics from keratin material, and this method includes to angle
At least one foregoing composition of the surface applied of protein material.
Composition according to the present invention has improved scalability, makeup removing ability, rinse capability and skin modification.
In addition, the composition have required hardness, to be adapted to tank, equipped with the device of open wall, equipped with ball
The device of dauber or in the form of stick (bar).
In the disclosure in this patent, unless otherwise specified, otherwise the content relative to the total weight of composition with weight
It indicates.
Following embodiment is intended to illustrate composition according to the present invention and method, but is in no way limiting of the scope of the present invention.
Unless otherwise indicated, all parts and percentages in embodiment are based on weight and all measurement results exist
It is obtained at about 25 DEG C.
Embodiment
Embodiment 1: preparation embodiment
Following formulation is prepared as follows:
Embodiment 2: polyamide -8 is replaced by synthetic wax；
Embodiment 3: polyamide -8 is replaced by the polymer Uniclear from Croda；
Preparation method:
The composition of embodiment 1 to 3 is prepared according to the following steps:
1., using VMI mixer mixed phase A, continuing 1 hour at 85 DEG C；
2. phase B is mixed into phase A at 85 DEG C until uniformly；
3. phase C is added in mixture derived above at 85 DEG C until uniformly.
Then mixture heat is poured into mold to form solid makeup removing stick.The composition of embodiment 1 is transparent solid
Stick, and the composition of embodiment 2 is white, the composition of embodiment 3 is translucent.
Embodiment 5: evaluation embodiment
To the composition of Examples 1 to 3 makeup removing ability and rinse capability and beauty performance (such as using be easy
Property, noresidue sense) it is evaluated.
The composition of Examples 1 to 3 is kept for 2 months at room temperature (25 DEG C) and 45 DEG C.
It is applied to by BB white (OAP Revitalift UV Block BB) on skin 30 minutes after makeup, by embodiment
1~3 composition is applied on the skin of face for having changed adornment of 6 consumers as cleansing product.Consumer's massage applied reality
Apply the skin of face of the composition of example 1~3 30 seconds.Then, consumer's (37 DEG C) flushing skin of face of water, then consumer gives
Out extended capability, makeup removing ability, rinse capability and noresidue sense score.
Particularly, for noresidue sense, if you do not need to further detergent product, consumer thinks noresidue sense
It is acceptable (3 or more score).
5: very good performance；
4: good performance；
3: acceptable performance；
2: poor performance；
1: excessively poor performance；
As a result as follows:
Observe that compared with the composition of embodiment 2 and 3, the composition of the embodiment of the present invention 1 is shown to beauty performance
Improvement, the improvement including easiness and noresidue sense to application.In addition, embodiment 1 shows good effect.
In addition, the composition of embodiment 1 is transparent.
Although exemplary embodiment of the present invention is described above, it will, of course, be understood that retouching according to front
It states, for those of ordinary skill in the related art, many and various improve is it will be apparent that can be with this field
Development and become apparent.Think these modifications in the spirit and scope of the present invention of this disclosure.
Claims (11)
1. a kind of solid water-free composition, the solid water-free composition includes:
A) at least one hydrophobic polymer, the hydrophobic polymer are selected from poly- (ester-acid amide) and its mixing blocked by ester
The group of object composition；
B) at least one hydrocarbon-type oil；With
C) at least one nonionic surfactant；
Condition is that the nonionic surfactant is not PEG-30 dimerization hydroxy stearic acid ester.
2. composition according to claim 1, wherein poly- (ester-acid amide) hydrophobic polymer of ester sealing end includes
At least one dimerization dilinoleic acid ester units；Preferably, the hydrophobic polymer be stearic bicine diester ethylenediamine/neopentyl glycol/
Hydrogenate dimerdilinoleate copolymer.
3. composition according to any one of the preceding claims, wherein the total weight based on composition, the composition
The amount for the hydrophobic polymer for including is 1wt%~20wt%, it is preferable that the total weight based on composition, the composition packet
The amount of the hydrophobic polymer contained is 5wt%~15wt%.
4. composition according to any one of the preceding claims, wherein the nonionic surfactant is selected from the oxygen of glycerol
Alkylene aliphatic ester；It is preferably selected from by PEG-20 glyceryl triisostearate, PEG-7 glyceryl cocoate, -2 oleic acid of polyglycereol
The group of ester and their mixture composition.
5. composition according to any one of the preceding claims, wherein the total weight based on composition, the composition
The amount for the nonionic surfactant for including is 1wt%~20wt%, it is preferable that the total weight based on composition, the combination
The amount for the nonionic surfactant that object includes is 1wt%~10wt%.
6. composition according to any one of the preceding claims, wherein the hydrocarbon-type oil is selected from by following material composition
Group: the C of petroleum resources8~C16Isoalkane；The C of branch8~C16Ester and isohexyl neopentanoate ester；The fixed hydrocarbon of animal origin
Class oil or vegetable oil；The linear chain or branched chain hydrocarbon of mineral or synthesis source；Synthesis ether containing 10~40 carbon atoms；Synthetic ester；25
It is the fatty alcohol of liquid at DEG C；Higher fatty acids, such as oleic acid, linoleic acid；Carbonic ester；Acetic acid esters；Citrate；And theirs is mixed
Close object；It is preferably selected from the synthetic ester of fatty acid.
7. composition according to any one of the preceding claims, the total weight based on composition, the composition include
The amount of hydrocarbon-type oil be 55wt%~98wt%, the amount of the total weight based on composition, the hydrocarbon-type oil that the composition includes is excellent
Selection of land is 65wt%~95wt%, more preferably 80wt%~90wt%.
8. solid water-free composition according to claim 1, relative to the total weight of composition, the solid water-free combination
Object includes:
A) 1wt%~20wt% selected from least one of the group being made of poly- (ester-acid amide) that ester blocks hydrophobic polymerizable
Object；
B) 1wt%~20wt% selected from least one of the group that forms of oxygen alkylene aliphatic ester by glycerol non-ionic surface
Activating agent；With
C) at least one hydrocarbon-type oil.
9. composition according to any one of the preceding claims, wherein the composition is cosmetic composition.
10. the beautifying use of composition according to any one of the preceding claims is used for from keratin material, especially
Cosmetics are removed from skin.
11. the beauty method for cleaning and/or removing the cosmetics on keratin material, the beauty method includes to angle egg
Surface applied at least one composition as defined in any one of preceding claims of the surface of white material, especially skin
The step of.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/106990 WO2018094623A1 (en) | 2016-11-23 | 2016-11-23 | Solid anhydrous composition comprising a hydrophobic polymer for removing makeup on the skin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110062619A true CN110062619A (en) | 2019-07-26 |
Family
ID=62194663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680091039.6A Pending CN110062619A (en) | 2016-11-23 | 2016-11-23 | Remove the solid water-free composition containing hydrophobic polymer of cosmetics on skin |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN110062619A (en) |
| WO (1) | WO2018094623A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115670955A (en) * | 2022-10-24 | 2023-02-03 | 美尚(广州)化妆品股份有限公司 | Makeup removing cream |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3829523A4 (en) * | 2018-06-28 | 2022-05-18 | L'oreal | Oil-in-water composition comprising a hydrophobic polymer |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6552160B2 (en) * | 2001-05-14 | 2003-04-22 | Arizona Chemical Company | Ester-terminated poly(ester-amides) useful for formulating transparent gels in low polarity fluids |
| CN1761696A (en) * | 2003-03-20 | 2006-04-19 | 阿利桑那化学公司 | Polyamide-polyether block copolymer |
| JP2007204762A (en) * | 1996-10-18 | 2007-08-16 | Union Camp Corp | Ester-teminated polyamide of polymerized fatty acid useful for formulating transparent gel in low-polarity liquid |
| CN101563060A (en) * | 2006-12-20 | 2009-10-21 | 雅芳产品公司 | High gloss gel-based lipstick |
| CN101801331A (en) * | 2007-09-17 | 2010-08-11 | 阿利桑那化学公司 | Polyamide and cosmetic composition, by the product of said composition preparation, and preparation and use the method for said composition and product |
| JP2012206974A (en) * | 2011-03-29 | 2012-10-25 | Kao Corp | Solid oily cleansing cosmetic |
| US20130158130A1 (en) * | 2010-05-31 | 2013-06-20 | Bjoern Heuer | Polymer combinations for cosmetic preparations |
| CN105411993A (en) * | 2016-01-13 | 2016-03-23 | 广州丹奇日用化工厂有限公司 | Makeup removing cream and preparation method thereof |
-
2016
- 2016-11-23 WO PCT/CN2016/106990 patent/WO2018094623A1/en active Application Filing
- 2016-11-23 CN CN201680091039.6A patent/CN110062619A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007204762A (en) * | 1996-10-18 | 2007-08-16 | Union Camp Corp | Ester-teminated polyamide of polymerized fatty acid useful for formulating transparent gel in low-polarity liquid |
| US6552160B2 (en) * | 2001-05-14 | 2003-04-22 | Arizona Chemical Company | Ester-terminated poly(ester-amides) useful for formulating transparent gels in low polarity fluids |
| CN1761696A (en) * | 2003-03-20 | 2006-04-19 | 阿利桑那化学公司 | Polyamide-polyether block copolymer |
| CN101563060A (en) * | 2006-12-20 | 2009-10-21 | 雅芳产品公司 | High gloss gel-based lipstick |
| CN101801331A (en) * | 2007-09-17 | 2010-08-11 | 阿利桑那化学公司 | Polyamide and cosmetic composition, by the product of said composition preparation, and preparation and use the method for said composition and product |
| US20130158130A1 (en) * | 2010-05-31 | 2013-06-20 | Bjoern Heuer | Polymer combinations for cosmetic preparations |
| JP2012206974A (en) * | 2011-03-29 | 2012-10-25 | Kao Corp | Solid oily cleansing cosmetic |
| CN105411993A (en) * | 2016-01-13 | 2016-03-23 | 广州丹奇日用化工厂有限公司 | Makeup removing cream and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 佚名: "Aubrey Organics Unscented Sunscreen SPF45 Water Resistant", 《HTTP://WWW.COSDNA.COM/CHS/COSMETIC_487E183596.HTML》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115670955A (en) * | 2022-10-24 | 2023-02-03 | 美尚(广州)化妆品股份有限公司 | Makeup removing cream |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018094623A1 (en) | 2018-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11850295B2 (en) | Anhydrous composition comprising a magnesium salt | |
| CN110366408B (en) | Cosmetic composition comprising one or more polar oils, a C2-C6 aliphatic monohydric and polyhydric alcohol, at least one hydrophilic active agent, and comprising less than 7% by weight of water | |
| CN111356433B (en) | Composition comprising a fatty phase, a lipophilic polymer and a volatile hydrocarbon-based oil | |
| WO2016058180A1 (en) | Solid anhydrous composition for removing the makeup on the skin | |
| WO2014187685A1 (en) | Antiperspirant compositions | |
| AU2017202102B2 (en) | Antiperspirant compositions | |
| US9867765B2 (en) | Antiperspirant compositions | |
| CN110062619A (en) | Remove the solid water-free composition containing hydrophobic polymer of cosmetics on skin | |
| KR20220118489A (en) | A two-phase composition comprising an aqueous phase comprising at least one polyol in a content ranging from 5% to 30% by weight and an oil phase comprising a non-silicone oil | |
| CN111601580B (en) | Solid anhydrous composition comprising a hydrophobic polymer for removing make-up from the skin | |
| TW201815378A (en) | Cosmetic | |
| CN109069387A (en) | Cosmetic composition containing two glycerol, four pelargonate | |
| JP2008137986A (en) | Oleum for cosmetic and cosmetic compounded with the same | |
| CN105307626A (en) | Composition to prevent or decrease skin pigmentation and lighten skin tone and use thereof | |
| RU2780567C2 (en) | Anhydrous composition containing magnesium salt | |
| JP6955255B2 (en) | Oil-in-water emulsified skin cleanser | |
| JP2024044620A (en) | oil-based cosmetics | |
| CN115670955A (en) | Makeup removing cream | |
| JP2023096834A (en) | Solid oily cleansing cosmetic | |
| JP2018100265A (en) | Oily composition | |
| WO2018114787A1 (en) | Cosmetic composition comprising one or more polar oil(s), a c2-c6 aliphatic monoalcohol and a polyol, and comprising less than 5% by weight of water | |
| WO2010070138A2 (en) | Use of water-repellent compounds as agents for the treatment of perspiration and method for the cosmetic treatment of perspiration employing the said agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |